Thomas J. Barton
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American chemist
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Chemistry
Thomas J. Barton's Degrees
- PhD Chemistry Stanford University
- Masters Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is Thomas J. Barton Influential?
(Suggest an Edit or Addition)According to Wikipedia, Thomas J. Barton is an American chemist who served as the president of the American Chemical Society in 2014. Biography He graduated from Lamar University, and from University of Florida in 1967. He was a post-doctoral fellow with National Institutes of Health at the Ohio State University.
Thomas J. Barton's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Tailored Porous Materials (1999) (581)
- Electroabsorption spectroscopy of luminescent and nonluminescent π-conjugated polymers (1997) (128)
- DELAYED FLUORESCENCE AND TRIPLET-TRIPLET ANNIHILATION IN PI -CONJUGATED POLYMERS (1999) (125)
- Synthesis and study of silylene-diacetylene polymers (1990) (87)
- Efficient, “one‐pot” synthesis of silylene–acetylene and disilylene–acetylene preceramic polymers from trichloroethylene (1990) (79)
- 1,1,2-Trimethylsilaethylene (1976) (66)
- Unambiguous generation and trapping of a silabenzene (1978) (65)
- Evidence for the generation and trapping of a silabenzene (1977) (54)
- Sterically hindered silyl perchlorates as blocking reagents (1978) (54)
- The role of trimethylsilylmethylsilylene in the gas-phase reactions of tetramethyldisilene (1978) (54)
- AN ALTERNATIVE MECHANISM FOR THE FORMATION OF 1,4-DISILACYCLOHEXA-2,5-DIENES FROM ACETYLENES AND SILYLENES (1976) (52)
- Two-photon absorption spectra of luminescent conducting polymers (1997) (52)
- Spectroscopic observation of matrix-isolated silatoluene (1980) (46)
- Catalytic synthesis of silylene-vinylene preceramic polymers from ethynylsilanes (1993) (45)
- ANALYSIS AND OPTIMIZATION OF GAS-PHASE REACTIONS. 13. SILATOLUENE (1980) (43)
- Syntheses and Structure of 8-, 7-, and 6-Membered Silacycloallenes (1993) (42)
- Evidence for a germanium-carbon (p-p).pi. double bond (1973) (40)
- Bis(trimethylsilyl)-, trimethylsilyltrimethylgermyl-, and bis(trimethylgermyl)diazomethane. Synthesis and chemistry of quantitative silene and germene precursors (1980) (39)
- Thermal and catalytic polymerization of diethynyldiphenylsilane (1991) (36)
- Gas-phase thermal rearrangements of potential vinylidene precursors to silylbenzofurans and silylbenzopyrans (1985) (35)
- Synthesis and study of a polysilole (1989) (32)
- Thermally-induced 1,2-shifts to convert olefins to carbenes: Does silicon do it? If so, why not carbon? (1995) (32)
- Adducts of acetylenes and sulfur dichlorides (1970) (31)
- Dispersion of Resonant Raman Scattering in π-Conjugated Polymers: Role of the Even Parity Excitons (1997) (31)
- Directions of the dipole moments of aromatic heterocyclopentadienes (1972) (31)
- Mechanism of the decomposition of silacyclobutane to silylene and propene (1987) (29)
- Femtosecond dynamics of the nonlinear optical response in polydiethynylsilane (1991) (28)
- A rearrangement-elimination sequence to 1-silatoluene (1981) (27)
- Pyrolysis of 1,1,2-trimethyl-1-silacyclobutane. Site of initial ring cleavage (1975) (27)
- Thermochemistry of di- and trisilanyl radicals. Observations and comments on silene-to-silylene rearrangements (1982) (26)
- Direct conversion of 2,3-dihydrofurans to silylsiloxyalkynes and bis(silyl)ketenes (1987) (26)
- Electrically Symmetric Poly(Phenylene Acetylene) Diodes (1994) (26)
- Generation and trapping of 6,6-dimethyl-6-silafulvene (1981) (26)
- Photoluminescence, electroluminescence, and optically detected magnetic resonance study of 2,5-dialkoxy derivatives of poly(p-phenyleneacetylene) (PPA) and PPA-based light-emitting diodes (1993) (26)
- Reactive intermediates in the synthesis and chemistry of organosilacycles (1980) (25)
- Processible poly[(p-phenyleneethynylene)-alt-(2,5-thienyleneethynylene)]s of high luminescence: their synthesis and physical properties (1998) (25)
- Hydroxyl-directed cyclizations of 1,6-enynes. (2011) (25)
- A reconsideration of the generation of silylenium ions in solution (1976) (24)
- Ring Opening of Silacyclobutane (1997) (23)
- Unexpected chemistry in an attempted generation of a sterically hindered silene (1979) (23)
- Kinetics and mechanism of the pyrolysis of allyltrimethylsilane (1984) (23)
- Actual Effects Controlling the Acidity of Carboxylic Acids. (1971) (23)
- Regiochemistry of alkenylsilyl and alkenyldisilanyl radical cyclizations (1984) (23)
- Synthesis of silaindenes by thermally induced acetylene-vinylidene rearrangements (1985) (22)
- Conductivity, optical absorption, photoluminescence, and X-band optically detected magnetic resonance of novel poly(2,5-dibutoxyparaphenyleneacetylene) (PDBOPA) (1992) (22)
- Mechanism of 1,4-disilacyclohexa-2,5-diene formation from acetylenes and silylenes (1974) (22)
- Direct thermal and photochemical generation of silanones (1983) (22)
- Synthesis and thermochemistry of 4-diazo-1,1-dimethyl-1-silacyclohexa-2,5-diene (1978) (21)
- Kinetics and mechanism of pyrolysis of hydridosilacyclobutanes (1984) (21)
- Reaction of a disilene and benzaldehyde (1976) (20)
- Symmetric light emitting devices from poly(p‐di ethynylene phenylene) (p‐di phenylene vinylene) derivatives (1995) (20)
- Organosilicon chemistry. Part II (1980) (20)
- Facile bridge expulsion of sulfur heterocycles. 7-Thiabicyclo[2.2.1]hepta-2,5-diene and 7-thiabicyclo[4.1.0]hepta-2,4-diene systems in thiepin synthesis (1972) (20)
- 2,3-Bis(trifluoromethyl)-7,7-dimethyl-7-silabicyclo[2.2.2] octa-2,5-diene. A silaalkene generator. (1972) (20)
- Observations and comments on the thermal behavior of 7-silanorbornadienes (1982) (19)
- Gas-phase pyrolysis of phenyltrimethylsilyldiazomethane. Intramolecular chemistry of phenyltrimethylsilylcarbene (1977) (19)
- Heterocyclopentadienes. II. Reaction of benzenediazonium-2-carboxylate with 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene (1972) (19)
- Thermal decomposition of 1,4-diphenyl-2,3-bis(trifluoromethyl)-7-dimethylsilabicyclo[2.2.1]heptadiene (1972) (19)
- Silicon-carbon double-bond formation via 1,5-sigmatropic migration of trimethylsilyl from silicon to carbon (1979) (19)
- Synthesis and Structure of a Tetrasilacyclohexyne (1992) (18)
- Synthesis and structure of strained, cyclic bisallenes (1993) (18)
- Radical rearrangements in the pyrolysis of allyldisilanes (1980) (18)
- Unsaturated heterocyclic systems. LX. Homotropylium cations. Substituent control on their generation and subsequent reactions (1969) (18)
- Azabullvalenes and benzazabullvalenes. Unsaturated heterocyclic systems. LX (1969) (17)
- Orchestrated silylene to silene to silylene rearrangement. The unusual behavior of C3H5 silylsilylenes (1982) (17)
- Silapyran and silacyclobutene formation in the gas-phase pyrolysis of 2-(dimethylsilyl)furan (1985) (17)
- Theoretical structural characterization of polydiethynylsilane — a new nonlinear optical material (1992) (16)
- Serendipitous synthesis of a sila-.alpha.-pyran - convenient, penultimate precursor to dimethylsilanone (1979) (16)
- Thermal extrusion of dimethylsilanone from (hydridosilyt)ketenes. A retro-Wolff rearrangement (1985) (16)
- Synthesis of the azabullvalene system (1967) (15)
- UV-Excited Optically Detected Magnetic Resonance (UV-ODMR) Study of π-Conjugated Polymers (1994) (15)
- EXTRAORDINARY PHOTOREARRANGEMENT OF SILYLFURANS AND SUBSEQUENT THERMAL REARRANGEMENTS (1983) (15)
- A convenient synthesis of tellurophene (1972) (15)
- 1,1-Dimethylsilole☆ (1981) (15)
- A novel synthesis of a C-unsubstituted silole (1979) (15)
- Kinetics of radical-forming homolyses in alkenyl- and tert-butylsilanes. The stability of .alpha.- and .beta.-silicon-substituted alkyl radicals (1987) (15)
- Poly(p-phenyleneacetylene)-based light-emitting diodes (1993) (15)
- The photochemistry of 2-phenylselenophene and 2-phenyltellurophene (1976) (14)
- Dimethylsilanone (Me2Si:O) generation by retroene decomposition of allyloxysilanes (1988) (14)
- Sigmatropic [1,3] hydrogen migration in a 1-silapropene. (1986) (14)
- Synthesis and Structure of an Octasila[4.4]betweenallene (1993) (13)
- Generation and rearrangement of a 1-norbornene in pyrolysis of 1-sila-2-oxynorbornanes (1987) (13)
- Synthesis of 1,1-dimethyl-2,7-diphenyl-1-silacyclohepta-2,4,6-triene. Nonannulated silepin (1974) (13)
- Vinylsilylene rearrangement. A possible silacyclopropanylidene intermediate (1983) (13)
- Kinetics and mechanisms of. cap alpha. - and. beta. -eliminations of alkoxysilanes from saturated and unsaturated carbon frameworks (1988) (13)
- Topics in nonbenzenoid aromatic chemistry Volume 1 (Nozoe, Testuo; Breslow, Ronald; Ito, Sho; Hafner, Klaus; Murata, Ichiro, eds.) (1976) (12)
- Silacyclobutene synthesis via intramolecular cyclization of unsaturated silylenes (1983) (12)
- Silylene to silene thermal rearrangement. Generation and rearrangement of cyclopropylsilylene and vinylsilylene (1982) (12)
- Silacyclopropylcarbinyl and cyclopropylsilylenium cations in the aluminum chloride-induced rearrangements of (chloromethyl)vinylsilanes (1985) (12)
- Pyrolytic, Kinetic, and Theoretical Studies on the Isomerization of Me2HSiCH2' to Me3Si' (1986) (12)
- ADDITION OF N-CHLOROSULFONYL ISOCYANATE TO 1,1-DIMETHYL-2,5-DIPHENYL-1-SILACYCLOPENTA-2,4-DIENE (1975) (12)
- Temperature-dependent behavior of 3-methoxy-4-azatricyclo[3.3.2.02,8]deca-3,6,9-triene (methoxyazabullvalene) (1967) (11)
- Spectroscopic evidence for a silicon–carbon double-bond (1972) (11)
- Reaction of sulfur dichloride with o-divinylbenzene (1972) (11)
- Thermal decomposition of sulfenyl chlorides (1970) (11)
- On the synthesis and valence isomerization of substituted 5H-1,2-diazepines (1967) (11)
- Trityl cation-catalyzed intramolecular cyclizations of saturated and unsaturated .gamma.- and .delta.-alkoxysilyl hydrides (1987) (11)
- 1,2-Silaoxetane. An alternative view (1983) (11)
- Silathione (Me2Si:S) extrusion in the thermolysis of silylthioketenes (1987) (11)
- Reaction of dimethylsilylene with cyclooctene oxide (1980) (11)
- Silene generation from a silyl 1,3-migration (1979) (11)
- Optical properties of polydiethynylsilanes : a quasi (AB)x polymer (1991) (10)
- Evidence for the generation of silicon-silicon, silicon-oxygen, and silicon-carbon double bonds in a single reaction (1974) (10)
- Photoisomerization of 2-(trimethylsilyl)pyrroles (1985) (9)
- Alleged intermediacy of a silacyclopropane in the pyrolysis of phenyltrimethylsilyldiazomethane (1975) (9)
- Organic Chemistry: An Overview (1983) (9)
- Convenient Synthesis of Trimethylsilyldiazomethane - A Silene Generator (1979) (8)
- Initial β-lactam formation in the addition of N-chlorosulfonyl isocyanate to diphenylmethylenecyclopropane (1972) (8)
- A convenient synthesis of silacyclobutenes (1981) (8)
- Convenient Synthesis of 1,1-Dimethyl-2, 5-Diphenyl-1-Silacyclopentadiene (1973) (8)
- Electroabsorption and Charged-Excitation Spectroscopy of II-Conjugated Polymers (1994) (8)
- The addition of dimethylsilylene to cyclooctatetraene (1975) (8)
- Organosilicon chemistry: a brief overview (1990) (7)
- Reaction of diphenylcyclopropenone with activated isocyanates. A facile synthesis of selected iminocyclopropenes (1967) (7)
- 2,2-Dimethoxyhexamethyltrisilane. A “One-pot” Silicon Atom Synthon (1983) (7)
- Some observations on the thermal interconversion of silanediyls (silylenes) and sila-olefins (silenes) (1984) (6)
- New silene rearrangements from a study of the mechanism of silacyclopentene formation from [3.3]silaspirocycloheptane (1983) (6)
- Initial β-lactam formation from 2-cyclopropylpropene and chlorosulphonyl isocyanate (1972) (6)
- EVIDENCE FOR THE GENERATION OF SILICON‐SILICON, SILICON‐OXYGEN, AND SILICON‐CARBON DOUBLE BONDS IN A SINGLE REACTION (1974) (6)
- Decamethylpentasilacycloheptyne·Mo2(CO)4(η5-C5H5)2 and cycloheptyne·Mo2(CO)4(η5-C5H5)2 (1998) (6)
- Experimental search for the silanone-to-silylene rearrangement (1985) (6)
- Silylene-to-silanone thermal isomerization (1986) (5)
- SILACYCLOPROPENE-TO-VINYLSILYLENE ISOMERIZATION IN REACTIONS OF SILYL- AND HYDRIDOSILYLENES WITH ACETYLENES (1983) (5)
- Two-photon absorption spectra of luminescent conducting polymers measured over wide spectral range (1997) (5)
- Novel two-step synthesis of 10H-benz[b]indeno[2,1-d]thiophene. Heterocyclopentadienes. III. (1971) (5)
- REχ(3), REχ(5), and REχ(7) Measured in Poly(Phenylene Ethynyl Silane)S by the Z Scan Technique (1994) (5)
- Optically detected magnetic resonance (ODMR) study of poly(3-hexylthiophenacetylene (P3HTA) films (1993) (5)
- Synthesis and chemistry of 9,9-dimethyl-9-silabicyclo[4.2.1]nona-2,4,7-triene (1975) (4)
- 9.2 – Carbacyclic Silanes (1982) (4)
- The molecular structure of 1-methyl-1-silabicyclo[2.2.2]octatriene as determined by gas phase electron diffraction (1980) (4)
- 4-Methyl-2,6,7-trioxabicyclo[2,2,2]octane: a convenient ring current probe (1972) (4)
- Molecular second hyperpolarizability measured in cumulene-containing polymers (1997) (4)
- Photoisomerization of 2-(Trimethylsilyl)pyrroles. (1986) (4)
- Polarons and triplet excitons in C60 glasses and films: An optically detected magnetic resonance (ODMR) study (1993) (3)
- SYNTHESIS OF 1,1-DIMETHYL-2,7-DIPHENYL-1-SILACYCLOHEPTA-2,4,6-TRIENE, A NONANNULATED SILEPIN (1974) (3)
- Optical probes of polydiethynylsilanes (1992) (3)
- X-Band Optically Detected Magnetic Resonance (ODMR) Study of C60-Doped π-Conjugated Polymers (1994) (3)
- Synthesis and relative stabilities of hexaphenyl- and 1,2,3,4-tetraphenyltropylium cations (1968) (3)
- Mechanism of silanone extrusion from alkoxyvinylsilanes (1987) (3)
- A novel solid-state molecular complex of diphenylacetylene and 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene (1972) (3)
- 1,5-SILYL MIGRATIONS AS A ROUTE TO ACYCLIC 1-SILA-1,3-BUTADIENES (1983) (3)
- Nonlinear Optical Susceptibilities Measured in Poly(Paraphenylene Cumulene[3]) by the Z Scan Technique (1994) (3)
- INTRAMOLECULAR REACTIONS OF ALKENYLSILYLENES (1983) (3)
- Picosecond to millisecond photoexcitations in poly(phenylene acetylene) (1994) (3)
- COMMENTS ON THE FORMATION OF SILANONES IN THE THERMOLYSIS OF HYDRIDOSILYL PEROXIDES (1982) (2)
- Stepwise addition of chlorosulfonyl isocyanate to cyclopropenes (1970) (2)
- 1-Methyl-1-silatricyclo[3.3.0.0]octa-2,6-diene. A silasemibullvalene (1982) (2)
- PYROLYTIC GENERATION AND THERMAL REARRANGEMENT OF A 2-SILAINDENE (1982) (2)
- Long-lived polarons and triplet excitons in ladder-type poly(p-phenylenes) and poly(p-phenylene ethynylenes) (1997) (2)
- Silylene‐Acetylene Polymers as Precursors to SiC Fibers (2008) (1)
- Reviews Tailored Porous Materials (1999) (1)
- Optical probes of pristine and C60-doped silicon-bridged PT polymer: a novel highly luminescent low-bandgap polymer (1997) (1)
- Trityl Cation Catalyzed Intramolecular Cyclizations of Saturated and Unsaturated γ- and δ-Alkoxysilyl Hydrides- (1988) (1)
- Investigation of an Acrylate Lynchpin Approach toward the Synthesis of Stolonidiol (2012) (1)
- Studies of photoexcitations in poly(phenylene-ethynylene-silane) (1994) (1)
- Pyrolytic, Kinetic, and Theoretical Studies on the Isomerization of Me2HSiCH2to Me3Si*. (1986) (0)
- Frequency Resolved Photoluminescence (PL), Delayed Fluorescence and Triplet-Triplet Annihilation In 7Φ-Conjugated Polymers (1999) (0)
- Studies toward the total synthesis of (–)-stolonidiol : a small molecule inducer of choline acetyltransferase (2012) (0)
- SERENDIPITOUS SYNTHESIS OF A SILA-α-PYRAN - CONVENIENT, PENULTIMATE PRECURSOR TO DIMETHYLSILANONE (1979) (0)
- Direct Conversion of 2,3‐Dihydrofurans to Silylsiloxyalkynes and Bis(silyl)ketenes. (1988) (0)
- Two-photon absorption measured in the presence of strong one-photon saturation in cumulene-containing polymer (1997) (0)
- Additions and Corrections - Kinetics and Mechanism of Pyrolysis of Hydridosilacylobutanes (1985) (0)
- NEW SILENE REARRANGEMENTS FROM A STUDY OF THE MECHANISM OF SILACYCLOPENTENE FORMATION FROM (3.3)SILASPIROCYCLOHEPTANE (1983) (0)
- REACTION OF BICYCLO(2,1,0)PENTANE AND 1,3-DIMETHYLBICYCLO(1,1,0)BUTANE WITH CHLOROSULPHONYL ISOCYANATE (1975) (0)
- PYROLYSIS OF 1,1,2-TRIMETHYL-1-SILACYCLOBUTANE, SITE OF INITIAL RING CLEAVAGE (1975) (0)
- Ultrafast femtosecond relaxation processes in luminescent and nonluminescent conducting polymers (1997) (0)
- Near-infrared ps transient photoinduced absorption in conjugated systems (1997) (0)
- Sigmatropic (1,3)-Hydrogen Migration in a 1-Silapropene. (1987) (0)
- Surprising photochemical and thermal isomerizations of a cyclic 1,2,3-butatriene (1997) (0)
- Synthesis and Structure of Strained, Cyclic Bisallenes. (1993) (0)
- Interchain Polaron Pairs and Instrinsically Trapped Triplet Excitons in Poly(P-Phenylene Ethynylenes) (PPEs). (1998) (0)
- Poly (p-phenyleneacetylene) light-emitting diodes (1994) (0)
- SYNTHESIS AND CHEMISTRY OF 9,9-DIMETHYL-9-SILABICYCLO(4,2,1)NONA-2,4,7-TRIENE (1975) (0)
- Syntheses and Structure of 8‐, 7‐, and 6‐Membered Silacycloallenes. (1993) (0)
- Polarons and Triplet Excitons in C 60 : An Optically Detected Magnetic Resonance (Odmr) and Light-Induced Esr (Lesr) Study (1992) (0)
- VINYLSILYLENE REARRANGEMENT. A POSSIBLE SILACYCLOPROPANYLIDENE INTERMEDIATE. (1983) (0)
- Silylene-to-Silanone Thermal Isomerization. (1986) (0)
- CONVENIENT SYNTHESIS OF 1,1‐DIMETHYL‐2,5‐DIPHENYL‐1‐SILACYCLOPENTADIENE (1973) (0)
- Nonlinear optical and conductive polymeric material (2016) (0)
- Poly ( silylene ) vinylenes from ethynylhydridosilanes (2016) (0)
- Generation and Rearrangement of a 1-Norbornene in Pyrolyis of 1-Silyl-2-oxynorbornanes. (1988) (0)
- 2,2-DIMETHOXYHEXAMETHYLTRISILANE. A ONE-POT SILICON ATOM SYNTHON (1984) (0)
- ADDITION OF DIMETHYLSILYLENE TO CYCLOOCTATETRAENE (1976) (0)
- Resource Paper: Organosilicon Chemistry: Part II. (1980) (0)
- Silathione (Me2Si=S) Extrusion in the Thermolysis of Silylthioketenes. (1987) (0)
- Mechanism of the Decomposition of Silacyclobutane to Silylene and Propene. (1988) (0)
- Unsaturated organosilicon polymers as preceramic and electrooptic materials (1993) (0)
- Palladium-Catalyzed Enyne Cyclization towards Complex Cyclopentanes (2011) (0)
- MECHANISM OF 1,4-DISILACYCLOHEXA-2,5-DIENE, FORMATION FROM ACETYLENES AND SILYLENES (1975) (0)
- Dimethylsilanone (Me2Si=O) Generation by Retroene Decomposition of Allyloxysilanes. (1988) (0)
- Optical Absorption, Luminescence, and UV-Excited Optically Detected Magnetic Resonance (UV-ODMR) Study of Poly(P-Phenyleneethynyleneaniline) (PPEA) Derivatives (1994) (0)
- SILACYCLOPROPYLCARBINYL AND CYCLOPROPYLSILYLENIUM CATIONS IN THE ALUMINUM CHLORIDE‐INDUCED REARRANGEMENTS OF (CHLOROMETHYL)VINYLSILANES (2002) (0)
- Optical probe of polydiethynylsilane (1992) (0)
- Silapyran and Silacyclobutene Formation in the Gas-Phase Pyrolysis of 2-(Dimethylsilyl)furan. (1986) (0)
- Kinetics and Mechanisms of α- and β-Eliminations of Alkoxysilanes from Saturated and Unsaturated Carbon Frameworks. (1988) (0)
- More Compelling Evidence That Silicon Is Better than Carbon: The Thermal Isomerization of Olefins to Carbenes (2008) (0)
- Thermal Extrusion of Dimethylsilanone from (Hydridosilyl)ketenes. (1986) (0)
- Experimental Search for the Silanone-to-Silylene Rearrangement. (1986) (0)
- The discovery of the [2{sub s}+2{sub a}] reaction of dislanes and acetylenes and their applications (1997) (0)
- Synthesis and Structure of an Octasila(4.4)betweenallene. (1993) (0)
- 1-METHYL-1-SILATRICYCLO(3.3.0.0)OCTA-2,6-DIENE. A SILASEMIBULLVALENE (1983) (0)
- Theoretical structure characterization of polydiethynylsilane - a new nonlinear optical material (1992) (0)
- Synthesis and Structure of a Tetrasilacyclohexyne. (2010) (0)
- Carbon-13 in Organic Chemistry, Vol. 3 in series in Organic Chemistry, : E. Buncel and C.C. Lee (Eds.), Elsevier Scientific Publishing Co., Amsterdam, 1977,xvi + 288 pp., price Dfl.1490. (US $60.95) (1978) (0)
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