Tomislav Rovis

Tomislav Rovis's AcademicInfluence.com Rankings

Tomislav Rovis

Chemistry

#2586

World Rank

#3515

Historical Rank

Organic Chemistry

#384

World Rank

#454

Historical Rank

chemistry Degrees

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Chemistry

Tomislav Rovis's Degrees

PhD Chemistry University of Zagreb
Masters Chemistry University of Zagreb
Bachelors Chemistry University of Zagreb

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Tomislav Rovis's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. (2015) (1205)
Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C–H Activation (2012) (584)
Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. (2010) (481)
Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. (2012) (397)
A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation. (2013) (392)
Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer. (2018) (386)
Novel Actions of Estrogen Receptor-β on Anxiety-Related Behaviors (2005) (376)
Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds (2016) (342)
A highly enantioselective catalytic intramolecular Stetter reaction. (2002) (334)
Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. (2012) (312)
Photoredox Catalysis Using Infrared Light via Triplet Fusion Upconversion (2018) (291)
Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. (2004) (288)
Nickel-catalyzed reductive carboxylation of styrenes using CO2. (2008) (280)
Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. (2007) (278)
Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. (2011) (277)
Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters. (2013) (266)
More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. (2008) (264)
N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. (2011) (241)
Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. (2004) (225)
Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators (2014) (218)
Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. (2006) (217)
Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes. (2009) (215)
An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. (2005) (204)
Novel actions of estrogen receptor-beta on anxiety-related behaviors. (2005) (197)
Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. (2009) (195)
Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization. (2018) (194)
Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. (2005) (192)
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. (2008) (189)
Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity. (2012) (189)
A highly enantio- and diastereoselective catalytic intramolecular Stetter reaction. (2005) (177)
Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. (2009) (175)
Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives. (2011) (173)
An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade. (2012) (164)
An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis. (2011) (157)
A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters. (2004) (154)
Rh-Catalyzed Intermolecular Syn-Carboamination of Alkenes via a Transient Directing Group (2015) (145)
Development of Chiral Bicyclic Triazolium Salt Organic Catalysts : The Importance of the N-Aryl Substituent (2008) (139)
Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. (2013) (139)
Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. (2011) (137)
N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. (2012) (135)
Highly enantioselective syntheses of homopropargylic alcohols and dihydrofurans catalyzed by a bis(oxazolinyl)pyridine-scandium triflate complex. (2001) (130)
Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study. (2017) (124)
C2-SYMMETRIC CU(II) COMPLEXES AS CHIRAL LEWIS ACIDS. CATALYTIC ENANTIOSELECTIVE MICHAEL ADDITION OF SILYLKETENE ACETALS TO ALKYLIDENE MALONATES (1999) (121)
Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters (2000) (119)
Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets. (2009) (115)
Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis. (2017) (115)
Enantioselective N-Heterocyclic Carbene-Catalyzed β-Hydroxylation of Enals Using Nitroarenes: An Atom Transfer Reaction That Proceeds via Single Electron Transfer (2014) (114)
A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System. (2017) (112)
Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes. (2012) (110)
Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes (2014) (110)
N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. (2010) (109)
Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. (2008) (107)
Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon−Heteroatom Bond Forming Process (2000) (107)
Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins. (2019) (104)
Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes (2010) (103)
Direct α-alkylation of primary aliphatic amines enabled by CO2 and electrostatics (2018) (98)
Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. (2012) (95)
Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines. (2012) (95)
Enantioselective rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes: application to the total synthesis of (+)-lasubine II. (2006) (89)
Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. (2008) (87)
Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones. (2011) (84)
Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation. (2015) (82)
Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. (2009) (82)
Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals. (2015) (79)
Photoredox-Catalyzed Site-Selective α-C(sp3 )-H Alkylation of Primary Amine Derivatives. (2019) (77)
Decarbonylative cross-coupling of cyclic anhydrides: introducing stereochemistry at an sp3 carbon in the cross-coupling event. (2003) (76)
Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides. (2017) (76)
Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. (2011) (75)
Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. (2013) (74)
Rh(I)–Bisphosphine-Catalyzed Asymmetric, Intermolecular Hydroheteroarylation of α-Substituted Acrylate Derivatives (2014) (72)
Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. (2011) (72)
Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones (2014) (70)
Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. (2009) (70)
A Sakurai-Prins-Ritter sequence for the three-component diastereoselective synthesis of 4-amino tetrahydropyrans. (2006) (70)
Enantioselective cross-coupling of anhydrides with organozinc reagents: the controlled formation of carbon-carbon bonds through the nucleophilic interception of metalacycles. (2008) (69)
Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity (1995) (69)
Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme. (2019) (69)
Copper Catalyzed C(sp3)-H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer. (2021) (68)
Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. (2006) (67)
Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams. (2018) (67)
General Strategy toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline (1997) (67)
Chiral copper (ii) complexes as Lewis acids for catalyzed cycloaddition, carbonyl addition, and conjugate addition reactions (1999) (65)
Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. (2009) (61)
A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides. (2002) (60)
Rhodium(III)-Catalyzed Allylic C(sp(3))-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles. (2015) (60)
The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis. (2008) (59)
Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles. (2018) (58)
Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides. (2008) (58)
Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. (2009) (57)
Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents. (2005) (57)
A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes (1997) (56)
Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates. (2009) (56)
Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. (2007) (55)
Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline (1999) (55)
Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition. (2016) (54)
Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes. (2008) (54)
Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis. (2019) (53)
Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis. (2021) (52)
Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles (2001) (51)
Organometallic chemistry: C-H carboxylation takes gold. (2010) (51)
Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. (2007) (49)
Rhodium(III)-Catalyzed C–H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes (2013) (48)
Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction (2006) (47)
Stable Carbenes: From ‘Laboratory Curiosities’ to Catalysis Mainstays (2013) (47)
Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis. (2020) (46)
A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. (2013) (46)
Pyridine synthesis by [4 + 2] cycloadditions of 1-azadienes: hetero-Diels Alder and transition metal-catalysed approaches (2014) (46)
Regioselective Alkylative Cross-Coupling of Remote Unactivated C(sp3)-H Bonds. (2019) (45)
Development of a Platform for Near-Infrared Photoredox Catalysis (2020) (44)
Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer. (2019) (44)
Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. (2007) (43)
Stereoretentive O-to-C rearrangement of vinyl acetals: solvent cage effects as a stereocontrol element. (2002) (43)
Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II) (2018) (42)
A site-selective amination catalyst discriminates between nearly identical C–H bonds of unsymmetrical disubstituted alkenes (2019) (42)
Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization. (2018) (42)
A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. (2004) (39)
Asymmetric NHC-catalyzed synthesis of α-fluoroamides from readily accessible α-fluoroenals. (2013) (39)
Carbene catalysts. (2010) (39)
The Catalytic Asymmetric Intramolecular Stetter Reaction. (2009) (38)
Towards the total synthesis of FD-838: modular enantioselective assembly of the core. (2008) (38)
Iron-Catalyzed Photoinduced LMCT: a 1° C-H Abstraction Enables Skeletal Rearrangements and C(sp3)-H Alkylation. (2021) (36)
A concise synthesis of eupomatilones 4, 6, and 7 by rhodium-catalyzed enantioselective desymmetrization of cyclic meso anhydrides with organozinc reagents generated in situ. (2007) (36)
The effect of pre-existing stereocenters in the intramolecular asymmetric Stetter reaction (2005) (36)
Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation. (2006) (36)
Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates. (2011) (35)
Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols. (2019) (34)
Organocatalytic hydroacylation of unactivated alkenes. (2011) (33)
Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones. (2009) (32)
Recent Advances in Catalytic Asymmetric Desymmetrization Reactions (2006) (32)
Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols (1998) (32)
Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes. (2019) (31)
Rhodium(III)-Catalyzed C–H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate (2015) (30)
Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes. (2005) (30)
Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects. (2017) (29)
Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. (2008) (29)
Zn-catalyzed enantio- and diastereoselective formal [4 + 2] cycloaddition involving two electron-deficient partners: asymmetric synthesis of piperidines from 1-azadienes and nitro-alkenes. (2015) (29)
N-Heterocyclic Carbene and Chiral Brønsted Acid Cooperative Catalysis for a Highly Enantioselective [4+2] Annulation (2016) (27)
Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. (2009) (27)
Phosphoramidite-rhodium complexes as catalysts for the asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes (2010) (27)
Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers. (2005) (25)
External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light (2018) (25)
A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether. (2013) (23)
Photoredox-Catalyzed Deaminative Alkylation via C-N Bond Activation of Primary Amines. (2020) (23)
Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core. (2013) (22)
Stereospecific Polymerization of Chiral Oxazolidinone-Functionalized Alkenes (2010) (22)
Photoredox-Catalyzed Alkenylation of Benzylsulfonium Salts. (2019) (20)
Development of optimized drug-like small molecule inhibitors of the SARS-CoV-2 3CL protease for treatment of COVID-19 (2022) (20)
Direct Regio- and Diastereoselective Synthesis of δ-Lactams from Acrylamides and Unactivated Alkenes Initiated by RhIII -Catalyzed C-H Activation. (2020) (19)
A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources. (2019) (19)
Metal catalyzed hydrometalations and their applications in synthesis (1998) (19)
Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents. (2007) (18)
Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction. (2013) (17)
Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon. (2015) (17)
Inhibitors of Coronavirus 3CL Proteases Protect Cells from Protease-Mediated Cytotoxicity (2021) (16)
Use of acid fluorides increases the scope of the reductive acylation of esters. (2004) (16)
Rhodium‐Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C—H/N—H Activation. (2011) (16)
1,3-Polyol arrays via the stereoselective rearrangement of vinyl acetals (2003) (16)
Structural and Mechanistic Investigations in Asymmetric Copper(I) and Copper(II) Catalyzed Reactions (2002) (15)
Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring. (2006) (15)
A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans. (2006) (15)
Rh(III)-Catalyzed Three-Component Syn-Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones. (2021) (14)
A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. (2008) (13)
Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition. (2013) (13)
Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides (2009) (13)
Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. (2014) (13)
A Late-Stage Strategy for the Functionalization of Triazolium-Based NHC Catalysts (2014) (13)
Exploiting Acyl and Enol Azolium Intermediates via N-Heterocyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes. (2012) (13)
Nickel‐Catalyzed Reductive Carboxylation of Styrenes Using CO2. (2009) (12)
Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis. (2015) (12)
Site-Selective α-C-H Functionalization of Trialkylamines via Reversible Hydrogen Atom Transfer Catalysis. (2021) (12)
Stereoselective Synthesis of Dioxolanes and Oxazolidines via a Desymmetrization Acetalization/Michael Cascade (2014) (11)
Organic chemistry: Natural polarity inverted (2015) (11)
Preparation of Chiral and Achiral Triazolium Salts: Carbene Precursors with Demonstrated Synthetic Utility (2011) (11)
Rhodium-Catalyzed syn-Carboamination of Alkenes via a Transient Directing Group. (2016) (11)
Complementary Diastereoselective Reduction of Cyclic γ-Keto Acids: Efficient Access to Trisubsituted γ-Lactones (2005) (11)
A diastereoselective intermolecular heck reaction of 1,3-dioxepins. (2007) (10)
Conversion of α‐Haloaldehydes into Acylating Agents by an Internal Redox Reaction Catalyzed by Nucleophilic Carbenes. (2004) (9)
Enantioselective Protonation of Catalytically Generated Chiral Enolates as an Approach to the Synthesis of α-Chloroesters. (2006) (9)
A simplified cell-based assay to identify coronavirus 3CL protease inhibitors (2020) (9)
Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines. (2021) (9)
Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction (2003) (9)
Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes (2019) (9)
Targeted activation in localized protein environments via deep red photoredox catalysis (2021) (8)
A Coupling of Benzamides and Donor/Acceptor Diazo Compounds to Form γ‐Lactams via Rh(III)‐Catalyzed C—H Activation. (2013) (8)
SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes (2013) (8)
Diastereoselective Three-Component 3,4-Amino Oxygenation of 1,3-Dienes Catalyzed by a Cationic Heptamethylindenyl Rhodium(III) Complex. (2021) (8)
Late-Stage N-Me Selective Arylation of Trialkylamines Enabled by Ni/Photoredox Dual Catalysis. (2021) (8)
Asymmetric Organocatalysis 1 (2012) (8)
Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: a direct fluoroacylation of 1,3-dienes (2014) (8)
Iron-Catalyzed C(sp3)–H Alkylation through Ligand-to-Metal Charge Transfer (2021) (8)
A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation–Ring-Expansion Approach to Substituted Azepanes (2017) (7)
Pyridine Synthesis from Oximes and Alkynes via Rhodium(III) Catalysis: Cp* and Cpt Provide Complementary Selectivity. (2012) (7)
Formation of Quaternary Stereocenters (2011) (7)
Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation (2019) (6)
Oxidatively Initiated NHC‐Catalyzed Enantioselective Synthesis of 3,4‐Disubstituted Cyclopentanones from Enals. (2016) (6)
Enantioselective N-Heterocyclic Carbene-Catalyzed β-Hydroxylation of Enals Using Nitroarenes: An Atom Transfer Reaction that Proceeds via Single Electron Transfer. (2015) (6)
Expedient Access to 2,3‐Dihydropyridines from Unsaturated Oximes by Rh(III)‐Catalyzed C—H Activation. (2016) (6)
International Union of Pure and Applied Chemistry (2020) (6)
Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. (2014) (5)
Sterically and Electronically Tuned Cp Ligands for Rhodium(III)-Catalyzed Carbon-Hydrogen Bond Functionalization (2019) (5)
Rhodium‐Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon—Heteroatom Bond Forming Process. (2000) (5)
A Rapid Total Synthesis of (±)-Sylvone (2008) (5)
Rh(III)‐Catalyzed Cyclopropanation Initiated by C—H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N‐Enoxyphthalimides and Alkenes. (2015) (5)
Enantioselective Synthesis of Indolizidines Bearing Quaternary Substituted Stereocenters via Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes. (2008) (5)
Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones. (2015) (4)
N-Heterocyclic-Carbene-Catalyzed Asymmetric Oxidative Hetero-Diels—Alder Reactions with Simple Aliphatic Aldehydes. (2013) (4)
Enantioselective Rhodium-CatalyzedAlkylative Desymmetrization of 3,5-Dimethylglutaric Anhydride (2009) (4)
Rhodium(III)‐Catalyzed Allylic C(sp3)—H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles. (2016) (3)
Enantioselective Rhodium‐Catalyzed [4 + 2 + 2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings. (2010) (3)
N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Protio and α-Deuterio α-Chloro and α-Fluoro Carboxylic Acids. (2010) (3)
Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents. (2022) (3)
Tuning the Electrochemical and Photophysical Properties of Osmium-Based Photoredox Catalysts (2022) (3)
Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis Edited by Jens Christoffers and Angelika Baro (Universität Stuttgart). Wiley-VCH Verlag GmbH & Co. KGA: Weinheim. 2005. xxiv + 336 pp. $170. ISBN 3-527-31107-6. (2006) (3)
Total Synthesis of Indolizidine Alkaloid (‐)‐209D: Overriding Substrate Bias in the Asymmetric Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition. (2009) (3)
A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes. (1998) (3)
Rh(III)‐Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β‐Unsaturated Oxime Esters. (2013) (3)
Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones (2018) (3)
Enantioselective Formation of Quaternary Stereocenters Using the Catalytic Intramolecular Stetter Reaction. (2007) (3)
More than Bystanders: The Effect of Olefins on Transition‐Metal‐Catalyzed Cross‐Coupling Reactions. (2008) (2)
Rhodium‐Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles. (2001) (2)
Correction: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones (2016) (2)
Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkynes and Alkenyl Isocyanates (2009) (2)
The [1,3] O-to-C Rearrangement: Opportunities for Stereoselective Synthesis (2008) (2)
Rhodium-Catalyzed Desymmetrization of meso-Glutaric Anhydrides to Access Enantioenriched anti,anti-Polypropionates (2017) (2)
Asymmetric Benzoin and Stetter Reactions (2011) (2)
Hydroalumination of Carbon—Carbon Double Bonds (2000) (2)
Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators. (2014) (2)
A Palladium‐Catalyzed Enantioselective Alkylative Desymmetrization of meso‐Succinic Anhydrides. (2004) (2)
Highly Enantioselective Syntheses of Homopropargylic Alcohols and Dihydrofurans Catalyzed by a Bis(oxazolinyl)pyridine—Scandium Triflate Complex. (2002) (2)
Reactions of Aliphatic Aldehydes (2012) (2)
Spin-Forbidden Excitation Enables Infrared Photoredox Catalysis (2020) (2)
Enantioselective Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes: Application to the Total Synthesis of (+)‐Lasubine II. (2007) (2)
Overcoming Photochemical Limitations in Metallaphotoredox Catalysis: Red-Light-Driven C-N Cross-Coupling. (2022) (2)
Stereoelectronic Basis for the Kinetic Resolution of N‐Heterocycles with Chiral Acylating Reagents. (2014) (2)
Ligand Differentiated Complementary Rh‐Catalyst Systems for the Enantioselective Desymmetrization of meso‐Cyclic Anhydrides. (2009) (1)
Catalytic Asymmetric α‐Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N‐Heterocyclic Carbene and Photoredox Catalysis. (2012) (1)
Rhodium-Catalyzed Enantioselective Desymmetrization (2007) (1)
Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Pentenyl Isocyanate and 4-Ethynylanisole: Preparation and Use of Taddolpyrrolidine Phosphoramidite. (2014) (1)
6.12 Benzoin and Stetter Reactions (2012) (1)
An Asymmetric Synthesis of 1,2,4-Trioxane Anticancer Agents via Desymmetrization of Peroxyquinols Through a Broensted Acid Catalysis Cascade. (2013) (1)
Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity. (1995) (1)
Complementary Diastereoselective Reduction of Cyclic γ‐Keto Acids: Efficient Access to Trisubstituted γ‐Lactones. (2005) (1)
Rh-Catalyzed Cycloadditions of Unsymmetrical Alkynes withIsocyanates (2009) (1)
Cluster Preface: Catalysis Using Sustainable Metals – Part II (2015) (1)
Cluster Preface: Catalytic Aerobic Oxidations (2017) (1)
Fluorine-Substitution Effect in Intermolecular Stetter Reactions (2009) (1)
Asymmetric Intramolecular Stetter Reaction of Aryl Aldehydes (2011) (1)
General Strategy Toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline. (1997) (1)
Chiral Copper(II) Complexes as Lewis Acids for Catalyzed Cycloaddition, Carbonyl Addition, and Conjugate Addition Reactions (2000) (1)
Rh(III)-Catalyzed Intra- and Intermolecular 3,4-Difunctionalization of 1,3-Dienes via Rh(III)-π-Allyl Amidation with 1,4,2-Dioxazolones (2022) (1)
Modular Synthesis of Unnatural Peptides via Rh(III)-Catalyzed Diastereoselective Three-Component Carboamidation Reaction. (2022) (1)
Photoinduced Nickel-Catalyzed Selective N-Demethylation of Trialkylamines Using C(sp2)-Bromides as HAT Reagents. (2023) (1)
The Catalytic Alkylative Desymmetrization of Anhydrides in a Formal Synthesis of Ionomycin (2018) (1)
Beyond Reppe: Building Substituted Arenes by [2 + 2 + 2] Cycloadditions of Alkynes (2009) (1)
An Improved Catalyst Architecture for Rhodium(III)‐Catalyzed C—H Activation and Its Application to Pyridone Synthesis. (2011) (1)
Desymmetrization of meso-Anhydrides with Organozinc Reagents (2007) (1)
Organocatalytic Hydroacylation of Unactivated Alkenes (2011) (1)
Homodimerization of Aryl Aldehydes Catalyzed by N-Heterocyclic Carbenes (2011) (0)
6 Proton-Coupled Electron Transfer (2019) (0)
The Comprehensive e-Book of Named Organic Reactions and Their Mechanisms (2005) (0)
Tuning through-space interactions via the secondary coordination sphere of an artificial metalloenzyme leads to enhanced Rh(iii)-catalysis (2022) (0)
Multicomponent Cycloaddition Approaches in the Catalytic Asymmetric Synthesis of Alkaloid Targets (2010) (0)
Reactions of Glyoxamides with Alkylidenemalonates (2011) (0)
Stereoselective reactions of carbonyl and imino groups (2011) (0)
Carbene-Catalyzed Stetter Reactions (2013) (0)
Asymmetric Intramolecular Benzoin Reactions (2011) (0)
Correction (2013) (0)
Reactions of Hetaryl Aldehydes with Nitroalkenes (2011) (0)
Regioselective Lewis Acid Mediated [1,3] Rearrangement of Allylvinyl Ethers. (2005) (0)
Asymmetric Intramolecular Stetter Reaction of Aliphatic Aldehydes (2011) (0)
Rh(I)—Bisphosphine-Catalyzed Asymmetric, Intermolecular Hydroheteroarylation of α-Substituted Acrylate Derivatives. (2015) (0)
Dynamic crosslinking compatibilizes immiscible mixed plastics (2023) (0)
Desymmetrization of Cyclohexadienones (2011) (0)
Correction to "Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study". (2020) (0)
Reactions of Aldehydes with Methyl 2-(Acetylamino)acrylate (2012) (0)
Nickel-Catalyzed Regioselective Olefin-Directed Cross-Coupling Reaction (2008) (0)
Rhodium‐Catalyzed Enantioselective Desymmetrization of meso‐3,5‐Dimethyl Glutaric Anhydride: A General Strategy to syn‐Deoxypolypropionate Synthons. (2007) (0)
Stereoselective Lewis Acid Mediated [1,3] Ring Contraction of 2,5‐Dihydrooxepins as a Route to Polysubstituted Cyclopentenes. (2005) (0)
Rhodium-Catalyzed Enantioselective Cycloaddition Route to Indolizidines (2008) (0)
Enantioselective Rhodium‐Catalyzed [4 + 2] Cycloaddition of α,β‐Unsaturated Imines and Isocyanates. (2011) (0)
Reactions of Hetaryl Aldehydes with Arylmethylenemalonates (2011) (0)
Book Review of Six-Membered Transition States in Organic Synthesis (2008) (0)
17th IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 17), Fort Collins, CO, USA, July 28–August 1, 2013 (2013) (0)
Diastereoselective Synthesis of Substituted 1,3-Dioxepins (2008) (0)
Reactions of Aryl Aldehydes (2012) (0)
Asymmetric Intermolecular Benzoin Reactions of Aryl Aldehydes (2011) (0)
Author Correction: Photoredox catalysis using infrared light via triplet fusion upconversion (2019) (0)
Enantioselective Rhodium‐Catalyzed Isomerization of 4‐Iminocrotonates: Asymmetric Synthesis of a Unique Chiral Synthon. (2015) (0)
2‐Phenyl‐6,10b‐dihydro‐4H,5aH‐5‐oxa‐3,10c‐diaza‐2‐azonia‐cyclopenta[c]fluorene tetrafluoroborate; 2‐Pentafluorophenyl‐6,10b‐dihydro‐4HM,5aH‐5‐oxa‐3,10c‐diaza‐2‐azoniacyclopenta[c]fluorene tetrafluoroborate; 6,7‐Dihydro‐2‐phenyl‐5‐(phenylmethyl)‐5H‐pyrrolo[2,1‐c]‐1,2,4‐triazolium chloride (2009) (0)
Aldehyde–Ketone Crossed Benzoin Reactions Catalyzed by N-Heterocyclic Carbenes (2011) (0)
Reactions of Aryl Aldehydes with 1,3-Diarylprop-2-en-1-ones (2011) (0)
Ni-Catalyzed Reductive Carboxylation of Styrenes Using CO2 (2009) (0)
Enantioselective Cross-Coupling of Anhydrides with Organozinc Reagents: The Controlled Formation of Carbon—Carbon Bonds Through the Nucleophilic Interception of Metalacycles (2008) (0)
Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition (2013) (0)
Carbene-Catalyzed Redox Amidations (2008) (0)
Preface: Modern Heterocycle Synthesis and Functionalization (2021) (0)
Photoredox-Catalyzed Alkenylation of Benzylsulfoniums (2019) (0)
Correction to “Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes” (2014) (0)
Phosphoramidite—Rhodium Complexes as Catalysts for the Asymmetric [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Alkynes (2011) (0)
Coupling of α-bromoamides and unactivated alkenes to form γ-lactams through EDA and photocatalysis (2023) (0)
Ionic Liquid Catalysts (2012) (0)
Predictable and Regioselective Insertion of Internal Unsymmetrical Alkynes in Rhodium‐Catalyzed Cycloadditions with Alkenyl Isocyanates. (2010) (0)
Organocatalytic Asymmetric Synthesis of a-Chloroesters (2006) (0)
The Catalytic Asymmetric Intramolecular Stetter Reaction (2008) (0)
Complementary diastereoselective reduction of cyclic gamma-keto acids: efficient access to trisubsituted gamma-lactones. (2005) (0)
A Hydroheteroarylation Route to 2-Substituted Benzoxazoles (2015) (0)
A Sakurai—Prins—Ritter Sequence for the Three‐Component Diastereoselective Synthesis of 4‐Amino Tetrahydropyrans. (2007) (0)
Correction to "Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals". (2015) (0)
Cluster Preface: Alkene Halofunctionalization (2018) (0)
Towards the Total Synthesis of FD‐838: Modular Enantioselective Assembly of the Core. (2008) (0)
Carbenium Cation Based Catalysts (2012) (0)
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes (2015) (0)
Rhodium‐Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Alkynes. (2006) (0)
Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline. (1999) (0)
Photoredox catalysis using infrared light via triplet fusion upconversion (2019) (0)
N-Heterocyclic Carbene and Broensted Acid Cooperative Catalysis: Asymmetric Synthesis of trans-γ-Lactams. (2012) (0)
1.13 Intramolecular Hydrogen-Atom Transfer (2021) (0)
Heterodimerization of Aryl Aldehydes by Enzyme Catalysis (2011) (0)
A Rapid Total Synthesis of (.+-.)-Sylvone. (2008) (0)
Indolizinone and Quinolizinone via Asymmetric [2+2+2] Cycloaddition (2006) (0)
Total synthesis of Ionomycin using anhydride desymmetrization techniques (2011) (0)
CCDC 154284: Experimental Crystal Structure Determination (2001) (0)
Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2‐Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters. (2001) (0)
Correction: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. (2015) (0)
Heterodimerization of Aryl Aldehydes Catalyzed by Metallophosphites (2011) (0)
Aldehyde–Imine Cross Coupling Catalyzed by N-Heterocyclic Carbenes (2011) (0)
6,7‐Dihydro‐2‐phenyl‐5‐(phenylmethyl)‐5H‐pyrrolo[2,1‐c]‐1,2,4‐triazolium Chloride (2007) (0)
Asymmetric Synthesis of α-Halo Carboxylic Acidsfrom α,α-Dihalo Aldehydes (2010) (0)
Asymmetric Intermolecular Acylation of α,β-Unsaturated Amides Catalyzed by Metallophosphites (2011) (0)
2,2-Dimethoxy-5,5-dimethyl-delta3-1,3,4-oxadiazoline (First Update) (2012) (0)
Asymmetric Synthesis of Hydrobenzofuranones via Enantioselective Stetter Reaction (2006) (0)
Secondary Amine/N-Heterocyclic Carbene CatalyzedCascade Sequence (2009) (0)
Asymmetric Intermolecular Stetter Reaction of Enals withNitroalkenes (2011) (0)
Catalysis with Stable Carbenes ( n ?→?π*) (2016) (0)
Metal and Nonmetal Catalysts for Carbon——Carbon Bond-Forming Reactions Leading to Desymmetrized 1,4-Dicarbonyl Compounds (2004) (0)
Enantioslective Rhodium Catalyzed Desymmetrization of meso-3,5-Dimethyl Glutaric Anhydride: A General Strategy to syn-Polyporpionate Synthons (2007) (0)
Catalysis Using Sustainable Metals – Part I (2014) (0)
Synthesis of Bicyclic Azocine Rings via Rh-Catalyzed [4+2+2] Cycloaddition (2009) (0)
Rhodium-Catalyzed [2+2+2] Cycloaddition of Carbodiimides (2008) (0)
Rhodium-Catalyzed Diastereoselective C–H Activation (2016) (0)
Red-Shifting Blue Light Photoredox Catalysis for Organic Synthesis: A Graphical Review (2023) (0)
Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction. (2004) (0)
The Catalytic Enantioselective Stetter Reaction (2021) (0)
Scope of the Nickel Catalyzed Asymmetric Reductive Ring Opening Reaction. Synthesis of Enantiomerically Enriched Cyclohexenols. (1998) (0)
Reactions of Hetaryl Aldehydes with Arylidenemalonates (2012) (0)
Author Correction: Photoredox catalysis using infrared light via triplet fusion upconversion (2019) (0)
Zn‐Catalyzed Enantio‐ and Diastereoselective Formal [4 + 2] Cycloaddition Involving Two Electron‐Deficient Partners: Asymmetric Synthesis of Piperidines from 1‐Azadienes and Nitro‐Alkenes. (2015) (0)
Rh-Catalyzed Asymmetric Cycloaddition of Imines and Isocyanates (2011) (0)
Hypervalent Silicon Catalysts (2012) (0)
Asymmetric Intermolecular Stetter Reactions Catalyzed by N-Heterocyclic Carbenes (2011) (0)
Stereoretentive O‐ to ‐C Rearrangement of Vinyl Acetals: Solvent Cage Effects as a Stereocontrol Element. (2002) (0)
Heterocycle Construction via Asymmetric Rhodium‐Catalyzed Cycloadditions (2013) (0)
Catalytic Asymmetric Cross Aza-Benzoin Reactions of Aliphatic Aldehydes with N -Boc Imines (2012) (0)
A Concise Synthesis of Eupomatilones 4, 6, and 7 by Rhodium‐Catalyzed Enantioselective Desymmetrization of Cyclic meso Anhydrides with Organozinc Reagents Generated in situ. (2007) (0)
Pyridine Synthesis by [4 + 2] Cycloadditions of 1-Azadienes: Hetero-Diels—Alder and Transition Metal-Catalyzed Approaches (2015) (0)
Deep Red to Near-Infrared Light-Controlled Ruthenium-Catalyzed Olefin Metathesis (2023) (0)
Development of Chiral Bicyclic Triazolium Salt Organic Catalysts: The Importance of the N‐Aryl Substituent (2008) (0)
Catalytic Asymmetric Cross‐Aza‐Benzoin Reactions of Aliphatic Aldehydes with N‐Boc‐Protected Imines. (2012) (0)
Tuning the Electrochemical and Photophysical Properties of Osmium Complexes for Application in Photoredox Catalysis (2021) (0)
Asymmetric Synthesis of a-Halo Carboxylic Acids from a,a-Dihalo Aldehydes (2010) (0)
Free Radicals: Fundamentals and Applications in Organic Synthesis 1 (2021) (0)
Enantio- and Diastereoselective Intermolecular Stetter Reaction of Glycoxamide and Alkylidene Ketoamides. (2009) (0)

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What Schools Are Affiliated With Tomislav Rovis?

Tomislav Rovis is affiliated with the following schools:

Cornell University
University of Toronto
Columbia University
University of Zagreb
Colorado State University
Harvard University