Vernon C. Gibson
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British chemist
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Vernon C. Gibsonchemistry Degrees
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Chemistry
Vernon C. Gibson's Degrees
- PhD Chemistry University of Oxford
- Masters Chemical Engineering Imperial College London
Why Is Vernon C. Gibson Influential?
(Suggest an Edit or Addition)According to Wikipedia, Vernon Charles Gibson is a British scientist who served as Chief Scientific Adviser at the Ministry of Defence between 2012 and 2016. He was reappointed to the MoD CSA role in May 2023. He is visiting professor at Imperial College London and the University of Oxford, Honorary Professor at the University of Manchester. He delivered the Royal United Services Institute Prince Philip Lecture on Military Education in Nov 2023.
Vernon C. Gibson's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Advances in non-metallocene olefin polymerization catalysis. (2003) (1848)
- The Search for New-Generation Olefin Polymerization Catalysts: Life beyond Metallocenes. (1999) (1332)
- IRON AND COBALT ETHYLENE POLYMERIZATION CATALYSTS BEARING 2,6-BIS(IMINO)PYRIDYL LIGANDS : SYNTHESIS, STRUCTURES, AND POLYMERIZATION STUDIES (1999) (825)
- Novel olefin polymerization catalysts based on iron and cobalt (1998) (763)
- Bis(imino)pyridines: surprisingly reactive ligands and a gateway to new families of catalysts. (2007) (653)
- Remarkable stereocontrol in the polymerization of racemic lactide using aluminum initiators supported by tetradentate aminophenoxide ligands. (2004) (440)
- The syntheses and catalytic applications of unsymmetrical ferrocene ligands. (2004) (399)
- Living Ring-Opening Metathesis Polymerization of 2,3-Difunctionalized- Norbornadienes by Mo(CH-t-Bu)(N-2,6-C(6)H(3)-i-Pr(2)(O-t-Bu)(2) (1990) (251)
- Palladium(II) complexes containing mono-, bi- and tridentate carbene ligands. Synthesis, characterisation and application as catalysts in CC coupling reactions (2001) (238)
- Redox control within single-site polymerization catalysts. (2006) (233)
- Iron catalyzed polyethylene chain growth on zinc: a study of the factors delineating chain transfer versus catalyzed chain growth in zinc and related metal alkyl systems. (2004) (205)
- Study of ligand substituent effects on the rate and stereoselectivity of lactide polymerization using aluminum salen-type initiators (2006) (203)
- Polyethylene chain growth on zinc catalyzed by olefin polymerization catalysts: a comparative investigation of highly active catalyst systems across the transition series. (2005) (189)
- Synthetic, structural, mechanistic, and computational studies on single-site beta-diketiminate tin(II) initiators for the polymerization of rac-lactide. (2006) (181)
- A computational analysis of the ring-opening polymerization of rac-lactide initiated by single-site beta-diketiminate metal complexes: defining the mechanistic pathway and the origin of stereocontrol. (2005) (164)
- Bis(carbene)pyridine Complexes of the Early to Middle Transition Metals: Survey of Ethylene Oligomerization and Polymerization Capability (2004) (148)
- Magnesium and zinc complexes of a potentially tridentate β-diketiminate ligand (2004) (147)
- Iron‐Catalyzed Polyethylene Chain Growth on Zinc: Linear α‐Olefins with a Poisson Distribution (2002) (143)
- Discovery and optimization of new chromium catalysts for ethylene oligomerization and polymerization aided by high-throughput screening. (2005) (130)
- Iron and cobalt ethylene polymerization catalysts: variations on the central donor. (2003) (129)
- The role of bulky substituents in the polymerization of ethylene using late transition metal catalysts: a comparative study of nickel and iron catalyst systems (2003) (123)
- Design of highly active iron-based catalysts for atom transfer radical polymerization: tridentate salicylaldiminato ligands affording near ideal Nernstian behavior. (2003) (120)
- Experimental evidence for large ring metallacycle intermediates in polyethylene chain growth using homogeneous chromium catalysts. (2005) (116)
- Polymerization of functionalized norbornenes employing Mo(CH-t-Bu)(NAr)(O-t-Bu)2 as the initiator (1990) (113)
- Cationic 2,6-bis(imino)pyridine iron and cobalt complexes: synthesis, structures, ethylene polymerisation and ethylene/polar monomer co-polymerisation studies (2002) (112)
- A well defined tin(II) initiator for the living polymerisation of lactide (2001) (104)
- Selective Dimerization/Oligomerization of α-Olefins by Cobalt Bis(imino)pyridine Catalysts Stabilized by Trifluoromethyl Substituents: Group 9 Metal Catalysts with Productivities Matching Those of Iron Systems (2005) (104)
- Cationic alkyl aluminium ethylene polymerization catalysts based on monoanionic N,N,N-pyridyliminoamide ligands (1998) (104)
- Bis(imino)pyridyl iron and cobalt complexes: the effect of nitrogen substituents on ethylene oligomerisation and polymerisation (2001) (100)
- Four-coordinate iron complexes bearing alpha-diimine ligands: efficient catalysts for atom transfer radical polymerisation (ATRP). (2002) (98)
- Titanium-salen complexes as initiators for the ring opening polymerisation of rac-lactide. (2006) (97)
- Discovery of a new family of chromium ethylene polymerisation catalysts using high throughput screening methodology. (2002) (97)
- The nature of the active species in bis(imino)pyridyl cobalt ethylene polymerisation catalysts. (2001) (97)
- Bis(carbene)pyridine complexes of Cr(III): exceptionally active catalysts for the oligomerization of ethylene. (2003) (94)
- Chromium(III) complexes bearing N,N-chelate ligands as ethene polymerization catalysts (1998) (93)
- Distinguishing Chain Growth Mechanisms in Metal-catalyzed Olefin Oligomerization and Polymerization Systems: C2H4/C2D4 Co-oligomerization/Polymerization Experiments Using Chromium, Iron, and Cobalt Catalysts (2009) (89)
- The nature of the active site in bis(imino)pyridine iron ethylene polymerisation catalysts (2002) (88)
- Unprecedented reversible migration of amide to schiff base ligands attached to tin: latent single-site initiators for lactide polymerization. (2004) (87)
- Correlation of metal spin state with catalytic reactivity: polymerizations mediated by alpha-diimine-iron complexes. (2006) (85)
- Anionic iron(II) alkoxides as initiators for the controlled ring‐opening polymerization of lactide (2003) (85)
- Hydrido methylidene, hydrido vinylidene, hydrido oxo, and hydrido formaldehyde derivatives of bis(pentamethylcyclopentadienyl)tantalum (1986) (84)
- Polymerization of Methyl Methacrylate Using Four-Coordinate (α-Diimine)iron Catalysts: Atom Transfer Radical Polymerization vs Catalytic Chain Transfer (2003) (84)
- A well-defined iron(II) alkoxide initiator for the controlled polymerisation of lactide (2002) (83)
- Controlled polymerization of lactides at ambient temperature using [5‐Cl‐salen]AlOMe (1999) (82)
- Synthesis and characterisation of neutral and cationic alkyl aluminium complexes bearing N,O-Schiff base chelates with pendant donor arms (2002) (81)
- Iron complexes bearing iminopyridine and aminopyridine ligands as catalysts for atom transfer radical polymerisation (2003) (81)
- Novel Mono-alkyl Magnesium Complexes Stabilized by a Bulky β-Diketiminate Ligand: Structural Characterization of a Coordinatively Unsaturated Trigonal System (2000) (76)
- Imine Versus Amine Donors in Iron‐Based Ethylene Polymerisation Catalysts (2001) (74)
- Mono- versus bis-chelate formation in triazenide and amidinate complexes of magnesium and zinc. (2007) (74)
- Low coordinate magnesium chemistry supported by a bulky β-diketiminate ligand (2003) (74)
- A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands (2000) (72)
- α-Diimine, Diamine, and Diphosphine Iron Catalysts for the Controlled Radical Polymerization of Styrene and Acrylate Monomers (2007) (72)
- A novel titanium–oxygen ladder structure supported by calix[4]arene ligands, characterised by synchrotron crystallography (1998) (71)
- The effect of the central donor in bis(benzimidazole)-based cobalt catalysts for the selective cis-1,4-polymerisation of butadiene. (2010) (69)
- An unprecedented alpha-olefin distribution arising from a homogeneous ethylene oligomerization catalyst. (2006) (67)
- Five-coordinate iron(II) complexes bearing tridentate nitrogen donor ligands as catalysts for atom transfer radical polymerisation (2004) (65)
- Ferrocene-Substituted Bis(imino)pyridine Iron and Cobalt Complexes: Toward Redox-Active Catalysts for the Polymerization of Ethylene (2006) (64)
- Half-sandwich imido complexes of niobium and tantalum (1992) (63)
- The surprisingly beneficial effect of soft donors on the performance of early transition metal olefin polymerisation catalysts. (2004) (63)
- Synthesis and reactivity of 1,8-bis(imino)carbazolide complexes of iron, cobalt and manganese (2003) (63)
- The effect of imine -carbon substituents in bis(imino)pyridine-based ethylene polymerisation catalysts across the transition series (2012) (63)
- Synthesis, Structures and Ethylene Polymerisation Behaviour of Low Valent β-Diketiminato Chromium Complexes (2001) (63)
- Chemical intercalation of magnesium into solid hosts (1991) (63)
- Investigations into the Mechanism of Activation and Initiation of Ethylene Polymerization by Bis(imino)pyridine Cobalt Catalysts: Synthesis, Structures, and Deuterium Labeling Studies (2005) (60)
- Iron-Based and Cobalt-Based Olefin Polymerisation Catalysts (2009) (60)
- rac-Lactide polymerization using aluminum complexes bearing tetradentate phenoxy-amine ligands (2007) (59)
- Transition metal imido catalysts for ethylene polymerisation (1999) (59)
- Rapid Entry into Mono-, Bi-, and Tricyclic β-Lactam Arrays via Alkene Metathesis (1998) (59)
- New homogeneous ethylene polymerization catalysts derived from transition metal imido precursors (1994) (59)
- The reversible amination of tin(II)-ligated imines: latent initiators for the polymerization of rac-lactide. (2008) (58)
- 1,3-Butadiene Polymerization by Bis(benzimidazolyl)amine Metal Complexes : Remarkable Microstructural Control and a Protocol for In-Reactor Blending of trans-1,4-, cis-1,4-, and cis-1,4-co-1,2-Vinylpolybutadiene (2009) (58)
- Organometallic Intermediates in the Controlled Radical Polymerization of Styrene by α-Diimine Iron Catalysts (2007) (58)
- Pyridine N-alkylation by lithium, magnesium, and zinc alkyl reagents: synthetic, structural, and mechanistic studies on the bis(imino)pyridine system. (2005) (58)
- High activity ethylene polymerisation catalysts based on chelating diamide ligands (1998) (58)
- Correlation of metal spin-state in alpha-diimine iron catalysts with polymerization mechanism (2007) (58)
- Synthesis and characterisation of neutral dialkylaluminium complexes stabilised by salicylaldiminato ligands, and their conversion to monoalkylaluminium cations (2001) (56)
- Tailored copolymers via coupled anionic and ring opening metathesis polymerization. Synthesis and polymerization of bicyclo[2.2.1]hept-5-ene-2,3-trans-bis(polystyrylcarboxylate)s (1994) (55)
- Tert-butylamidinate tin(ii) complexes: high activity, single-site initiators for the controlled production of polylactide. (2007) (55)
- Group 4 Metal Olefin Polymerization Catalysts Stabilized by Bidentate O,P Ligands (2008) (53)
- Pendant arm Schiff base complexes of aluminium as ethylene polymerisation catalysts (1999) (53)
- Functionalized polyolefin synthesis using [P,O]Ni catalysts. (2001) (51)
- Shuttling Polyolefins to a New Materials Dimension (2006) (51)
- A remarkable ancillary ligand effect in living ring-opening metathesis polymerisation (1992) (50)
- Highly active ethylene polymerisation catalysts based on iron: an ab initio study (1999) (50)
- Synthesis of 1,1‘-Ferrocenediyl Salicylaldimine Ligands and Their Application in Titanium-Initiated Lactide Polymerization (2007) (49)
- On the polymerization of methyl methacrylate by group 4 metallocenes (2000) (49)
- Chromium ethylene polymerisation catalysts bearing reduced Schiff-base N,O-chelate ligands (1999) (47)
- Synthetic, spectroscopic and olefin oligomerisation studies on nickel and palladium complexes containing ferrocene substituted nitrogen donor ligands (2003) (47)
- The use of silylethers and silylthioethers in syntheses of oxohalide and thiohalide compounds of molybdenum and tungsten (1990) (46)
- Aluminum alkyl-mediated route to novel N,N,O-chelates for five-coordinate Iron(II) chloride complexes: Synthesis, structures, and ethylene polymerization studies (2007) (45)
- Advances in Non-metallocene Olefin Polymerization Catalysis (2003) (45)
- Electronic effects in oxo transfer reactions catalysed by salan molybdenum(VI) cis-dioxo complexes. (2009) (45)
- Synthesis and structural characterisation of aluminium imino-amide and pyridyl-amide complexes: bulky monoanionic N,N chelate ligands via methyl group transfer1Dedicated to Professor Ken Wade on the occasion of his 65th birthday in recognition of his outstanding contributions to inorganic chemistry. (1998) (45)
- Chromium complexes bearing pyrrolide-imine N,N-chelate ligands: synthesis, structures and ethylene polymerisation behaviour (2002) (44)
- Ethylene polymerisation by a copper catalyst bearing α-diimine ligands (2002) (44)
- Living ring-opening metathesis polymerisation of amino ester functionalised norbornenes (1998) (43)
- Novel µ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts (1997) (43)
- Combining hard and soft donors in early-transition-metal olefin polymerization catalysts. (2006) (43)
- Thio-Pybox and Thio-Phebox complexes of chromium, iron, cobalt and nickel and their application in ethylene and butadiene polymerisation catalysis. (2012) (43)
- Bis(benzimidazole)amine vanadium catalysts for olefin polymerisation and co-polymerisation: thermally robust, single-site catalysts activated by simple alkylaluminium reagents. (2004) (42)
- New, improved syntheses of the group 6 oxyhalides, W(O)Cl4, W(O)2Cl2 and Mo(O)2Cl2 (1988) (42)
- Synthesis and reactivity of permethyltantalocene derivatives processing .eta.3-allyl, .eta.2-butadiene, .eta.2-methylallene, and .eta.1-alkenylidene ligands. Model studies for the role of surface vinylidenes in the Fischer-Tropsch hydrocarbon-chain-lengthening process (1991) (42)
- Well-defined ethylene polymerisation catalysts derived from bis(imido) chromium(VI) precursors (1995) (41)
- Iron-based ethylene polymerization catalysts supported by bis(imino)pyridine ligands: Derivatization via deprotonation/alkylation at the ketimine methyl position (2007) (40)
- Asymmetric allylboration and ring closing alkene metathesis: a novel strategy for the synthesis of glycosphingolipids. (2000) (40)
- Polystyrene supports for vanadium ethylene polymerisation catalysts (1998) (40)
- Synthesis of End-Functionalized Polynorbornenes and Polynorbornanes via Metathesis: Novel Macromonomers for Polycondensation Reactions (2000) (39)
- The effect of bulky substituents on the olefin polymerisation behaviour of nickel catalysts bearing [P,O] chelate ligands (2001) (39)
- Experimental and Computational Study of β-H Transfer between Cobalt(I) Alkyl Complexes and 1-Alkenes (2004) (39)
- Dramatic effect of heteroatom backbone substituents on the ethylene polymerization behavior of bis(imino)pyridine iron catalysts. (2004) (38)
- Calix[6] and [8]arene complexes of vanadium (2001) (37)
- Ruthenium initiated ring opening metathesis polymerisation of amino-acid and -ester functionalised norbornenes and a highly selective chain-end functionalisation reaction using molecular oxygen (2001) (37)
- Trimethylphosphine as a reactive solvent: synthesis, crystal structures, and reactions of [Ta(PMe3)3(η2-CH2PMe2)(η2-CHPMe2)] and [W(PMe3)4(η2-CH2PMe2)H] and related studies (1985) (37)
- Novel Aluminum-Containing Ring Systems: An Octanuclear Structural Analogue of a Calix[4]pyrrole. (1999) (37)
- Dalton perspectives. Structural and bonding patterns in tetrahedral and pseudo-tetrahedral transition-metal complexes containing π-donor ligands (1994) (36)
- Synthesis and reactivity of the first stable chromium(VI) alkylidene complexes (1996) (36)
- Bent-sandwich derivatives of tantalum bearing one or two pentamethylcyclopentadienyl ligands (1986) (36)
- The synthesis of N-norbornenyl-amino acids and esters: Monomers for the preparation of well defined polymers (1995) (36)
- The synthesis, coordination chemistry and ethylene polymerisation activity of ferrocenediyl nitrogen-substituted ligands and their metal complexes (2005) (35)
- Bidentate salicylaldiminato tin(II) complexes and their use as lactide polymerisation initiators. (2009) (35)
- Dielectric and pyroelectric properties of poly[2,3-bis(trifluoromethyl)norbornadiene] (1995) (35)
- Synthesis and structures of bimetallic and polymeric zinc coordination compounds supported by salicylaldiminato and anilido-aldimine ligands. (2007) (34)
- η2-Benzyne and η1-benzylidene complexes of niobium with ancillary imido ligands (1992) (33)
- Bis(imino)carbazolide Complexes of Rhodium: Highly Nucleophilic Ligands Exerting a Dramatic Accelerating Effect on MeI Oxidative Addition (2004) (33)
- Thymine functionalised polymers via living ring-opening metathesis polymerisation (1997) (31)
- Four coordinate bis(imido) alkene complexes of molybdenum(IV): relatives of the zirconocene family (1992) (31)
- Zirconium Complexes Containing Tetradentate O,P,P,O Ligands: Ethylene and Propylene Polymerization Studies (2008) (30)
- Well-defined graft copolymers via coupled living anionic and living ring opening metathesis polymerisation (1997) (30)
- Synthesis of penicillin derived polymers utilising ring-openingmetathesis polymerisation methodology (1997) (30)
- A New and Highly Efficient Grubbs Initiator for Ring-Opening Metathesis Polymerization (1999) (30)
- Bis(imino)pyridine cobalt alkyl complexes and their reactivity towards ethylene: a model system for beta-hydrogen chain transfer. (2002) (30)
- Amino acid derived homochiral polymers via ring-opening metathesis polymerisation (1994) (29)
- A new route to chiral bis-tertiary phosphine ligands: synthesis, resolution, and crystal structure of trans-bis-1,2-(diphenylphosphino)-cyclopentane and the nickel adduct NiBr2[trans-1,2-(PPh2)2C5H8] (1983) (28)
- A well-defined magnesium enolate initiator for the living and highly syndioselective polymerisation of methylmethacrylate. (2002) (28)
- Highly functionalised monocyclic and bicyclic β-lactamsvia alkene metathesis (1997) (28)
- Synthesis, characterisation and catalytic activity of metal complexes of neutral, unsymmetrical P/S ferrocenediyl ligands (2002) (28)
- A tripartite asymmetric allylboration — Silicon tethered alkene ring closing metathesis — in situ ring opening protocol for the regiospecific generation of functionalized (E)-disubstituted homoallylic alcohols (1999) (28)
- Iron-Catalyzed Polyethylene Chain Growth on Zinc: Linear α-Olefins with a Poisson Distribution This work was supported by BP plc. Dr. Gary Audley and Dr. Jane Boyle are thanked for GPC and NMR measurements, respectively. (2002) (28)
- Bimolecular termination in living ring opening metathesis polymerization (1992) (27)
- A versatile route to well-defined molybdenum metathesis catalysts via mixed imido precursors: the molecular structure of [Mo(N-2,6-Pri2C6H3)(N-But)(CH2CMe3)2] (1994) (27)
- The synthesis and ring-opening metathesis polymerization of peptide functionalized norbornenes (1999) (27)
- Living and highly stereoregular ring-opening polymerization of 5,6-difunctionalized norbornadienes by a well-characterized molybdenum catalyst (1989) (27)
- Group 4 metal complexes bearing new tridentate (NNO) ligands: Benzyl migration and formation of unusual C–C coupled products (2009) (27)
- Can alkali-metal ions influence the coordination and reactivity ofcalix[4]arenes at transition-metal centres? (1997) (27)
- Four coordinate molybdenum alkene and alkyne complexes bearing ancillary imido ligands (1995) (26)
- Highly active titanium-based olefin polymerization catalysts supported by bidentate phenoxyamide ligands. (2006) (26)
- From monomeric to polymeric manganese complexes bearing bis(imino)pyridine and related ligands (2003) (26)
- Co-condensation of molybdenum atoms with the bulky tertiary diphosphine 1,2-bis(di-isopropylphosphino)ethane: the molecular structure of [MoH4(Pri2PCH2CH2PPri2)2] (1988) (26)
- Synthesis, crystal structures and some reactions of zero-valent tris[bis-1,2-(dimethylphosphino)ethane]derivatives of chromium, molybdenum, tungsten, vanadium, niobium and tantalum (1984) (26)
- Bent versus linear imido ligands in five-co-ordinate molybdenum complexes (1996) (25)
- Synthesis, Coordination Chemistry, and Catalytic Application of a Novel Unsymmetrical P/O Ferrocenediyl Ligand (2004) (25)
- Enyne metathesis for the facile synthesis of highly functionalisednovel bicyclic β-lactams (1997) (25)
- Coordination complexes bearing potentially tetradentate phenoxyamine ligands. (2006) (25)
- Chain-transfer agents for living ROMP [Ring-Opening Metathesis Polymerization] reactions of norbornene (1990) (25)
- Bis(imino)phenoxide complexes of aluminium. (2004) (24)
- Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes Bearing Bis(imino)pyridine Ligands (2010) (24)
- Nucleophilic attack at pyridine nitrogen and its use to access a novel mono-anionic ligand for iron-based ethylene polymerisation catalysts. (2002) (24)
- Convenient, high yield syntheses of [Nb(O)Cl3], [Nb(O)Cl3(CH3CN)2] and [NB(O)Cl3(THF)2]. Formation and decomposition of intermediate alkoxo (and siloxo) derivatives of general formula [NbCl4(OR)]2 (R = Me, Et, SiMe3) (1988) (24)
- Novel metal imido calixarene complexes (1995) (23)
- New unsymmetrical thioether- and thiolate-substituted ferrocenediyl ligands and their metal complexes (2003) (23)
- Structural and spectroscopic evidence for multiple {alpha}-agostic interactions in dialkyl complexes of niobium (1993) (23)
- The synthesis and metal coordination chemistry of new 1,1′-N-substituted ferrocenediyl ligands derived from 1,1′-diaminoferrocene (2001) (23)
- Alkene metathesis in the synthesis of novel β-lactams (1996) (23)
- Metathesis Polymerization: ROMPing towards new materials (1994) (23)
- Group 4 catalysts for ethene polymerization containing tetradentate salicylaldiminato ligands. (2006) (22)
- Ligands as “Compass Needles”: How Orientations of Alkene, Alkyne, and Alkylidene Ligands Reveal π‐Bonding Features in Tetrahedral Transition Metal Complexes (1994) (22)
- Bis(arylimido) complexes of chromium(VI) (1995) (22)
- Group 6 transition metal complexes containing the σ-bonded 2,4,6-tris(trifluoromethyl) phenyl (“fluoromes”) ligand (1997) (22)
- Multivalent cation intercalation (1992) (21)
- Silicon-containing macrocycles and polymers via metathesis: x-ray crystal structures of cis,cis- and trans,trans-1,1,6,6-tetraphenyl-1,6-disilacyclodeca-3,8-diene (1993) (21)
- Transition-metal catalysed metathesis of phosphorus–phosphorus double bonds (1995) (21)
- Bis(imido) molybdenum(IV) complexes containing η2-diphosphene ligands (1996) (21)
- Reactions of (.eta.-C5Me5)Ta(PMe3)(H)2(.eta.2-CHPMe2) and nature of the .eta.2-CHPMe2 ligand (1991) (21)
- Molybdenum(VI) complexes containing differing cis multiply-bonded ligands: Some structural consequences of competing π-donor groups (1996) (21)
- Half-sandwich imido complexes of niobium bearing alkyne, benzyne and benzylidene ligands: relatives of the zirconocene family (1998) (20)
- The Synthesis and Metal Coordination Chemistry of a Novel Phosphine- and Thiolate-Substituted Ferrocenediyl Ligand (2002) (20)
- Synthesis, characterisation and reactivity of the molybdenum(VI) dimethyl complex [Mo(NR)2Me2] (R = 2,6-Pri2C6H3) (1999) (20)
- Synthesis and structural characterization of some novel metalloboroxides bearing boron-bound mesityl and fluoromesityl substituents: the molecular structure of the first metallaboroxane complex (1997) (19)
- New unsymmetrical thioether- and thiolate-substituted ferrocene ligands and an unusual bridged-Pd dimer complex (2000) (19)
- Metathesis polymerization of 1,7,7-trimethylbicyclo [2.2.1] hept-2-ene using a well defined molybdenum initiator (1994) (19)
- Half-sandwich niobium(III) nitrene (Imido) complexes containing carbonyl, alkene and acetylene ligands (1992) (18)
- Synthesis, Characterization, and Metal Complexation of Unsymmetrical 1,1‘-Bis(organylthiolato)ferrocenes (2004) (18)
- Novel bis(imido) complexes of molybdenum(VI): precursors to new alkene metathesis catalysts (1994) (18)
- Imido ligand reactivity in four-co-ordinate bis(imido) complexes of molybdenum(VI) (1992) (18)
- Chain-end functionalization of living polymers formed by the ring-opening metathesis polymerization of norbornene (1991) (18)
- Novel tungsten calix[8]arene complexes. (2002) (17)
- SYNTHESIS AND CHARACTERISATION OF MOLYBDENUM COMPLEXES BEARING HIGHLY FUNCTIONALISED IMIDO SUBSTITUENTS (1997) (17)
- Dialkylaluminium complexes derived from 1,8-diphenyl-3,6-dimethylcarbazole: a new sterically hindered monodentate ligand system (2003) (17)
- Cross metathesis of the amino acid homoallylglycine (1997) (17)
- Interaction of trialkylaluminum reagents with metal-bound ethylene and carbon monoxide. The molecular structure of (.eta.5-C5Me5)2Ta(H)(C2H4.cntdot.AlEt3) (1988) (17)
- Pentamethylcyclopentadienyl—rhodium and —iridium complexes: Part 35. Hydrogenation catalysts based on [(RhC5Me5)2(OH)3]+ and the border between homogeneous and heterogeneous systems (1982) (17)
- The Synthesis and Structure of the Yellow and Green Forms of [Nb(O)Cl3(PMe3)3] and the Orange and Green Forms of [Nb(S)Cl3(PMe3)3]; Examples of Perfectly Matched Bond‐Stretch Isomers? (1991) (16)
- Synthesis and properties of stereoregular fluoro‐polymers via ring‐opening metathesis polymerization of fluorinated norbornenes and norbornadienes. An overview and progress report (1993) (16)
- Novel unsymmetrical P/O substituted ferrocene ligands and the first structurally characterised hydroxyferrocene derivative. (2004) (16)
- Pentamethylcyclopentadienyl niobium(III) nitrene complexes containing phosphine, carbonyl, olefin and acetylene ligands (1992) (15)
- Vanadium complexes containing the 2,4,6-tris(trifluoromethyl)phenyl (‘fluoromes’) ligand (1996) (15)
- Low valent chromium complexes bearing N,O-chelating pyridyl-enolate ligands [OC(But)(2-CHN5H3Me-x)]− (x = 3–6) (2003) (15)
- Competitive ligand CH bond activations: ring- and phosphine-metallated forms of (C5Me5)Ta(PMe3)2 (1991) (15)
- Synthesis and crystal structures of chromium and molybdenum complexes containing the 2,4,6-tris(trifluoromethyl)phenyl ligand (2001) (15)
- Hang-gliding with Ferrocenes: Unusual Coordination Chemistry of 1,1‘-Bis(mesitylthio)ferrocene (2000) (15)
- Nickel(II) α-diimine catalysts for the atom transfer radical polymerization of styrene (2006) (15)
- Fluorinated homopolymers and block co-polymers via living ring-opening metathesis polymerisation (1994) (15)
- Edge-shared, bioctahedral, bismuth phosphine complexes (1992) (14)
- Pentamethylcyclopentadienyl tungsten complexes containing imido,hydrazido and amino acid derived N–O chelateligands (1997) (14)
- Syn/anti rotamer interconversion as the rate-determining initiation step in ring-opening metathesis polymerisations using well-defined molybdenum alkylidene complexes (1994) (14)
- Intermetal exchange of oxo, imido and alkylidene ligands (1992) (14)
- Isocyanate versus isothiocyanate insertion into alkoxo and imido ligands (1994) (14)
- Novel silicon-containing hydrocarbon rings and polymers via metathesis: X-ray crystal structure of cis,cis-1,1,6,6-tetraphenyl-1,6-disilacyclodeca-3,8-diene (1991) (14)
- Trimethylphosphine as a reactive solvent: synthesis and crystal structure of Ta(PMe3)3(η2-CH2–PMe2)(η2-CH–PMe2) and synthesis of related molybdenum and tungsten compounds (1983) (14)
- Synthesis, X-ray structure and reactivity of the half-sandwich imido complex (η-C5H5)NbCl2(NCH3) (1989) (13)
- Titanium and zirconium complexes bearing (S,S′)-ferrocenyldithiolate ligands (1999) (13)
- An unusual double CH activation of coordinated trimethylphosphine. Synthesis, molecular structure and reactivity of (C5Me5)Ta(PMe3)(H)2(η2-CHPMe2) (1987) (13)
- Bridged bis(imido)molybdenum complexes: isolobal analogues of ansa-zirconocenes and bizirconocenes (1996) (13)
- Ring‐opening metathesis polymerization of syn‐ and anti‐7‐methylbicyclo[2.2.1]hept‐2‐ene initiated by Mo(CHCMe3)(NC6H3‐2,6‐i‐Pr2)(OCMe3)2 (1992) (13)
- Synthesis and characterisation of 2,6-diisopropylphenylimido complexes of chromium in oxidation states IV–VI (1999) (13)
- Benefits of the Chelate Effect: Preparation of an Unsymmetrical ansa-Bis(imido)molybdenum Complex Containing a Seven-Membered Chelate Ring. (1998) (13)
- The use of hexamethyldisilthiane in the synthesis of transition metal thiohaides (1989) (13)
- Formation and Unexpected Catalytic Reactivity of Organoaluminum Boryloxides (2001) (12)
- Synthesis and structure of bis(methylaluminium · HCCH3) p-tert-butylcalix[4]arene (1997) (12)
- Copolymerization of amino acid and amino ester functionalized norbornenes via living ring-opening metathesis polymerization (2008) (12)
- Niobium η-cyclopentadienyl compounds with imido and amido ligands derived from tert-butylamine (2000) (12)
- Aluminium-containing ring systems and N-heterocycle formation via nitrile insertions into Al–N bonds (2001) (11)
- A double intramolecular ring metalation: formation, spectroscopic characterization, and molecular structure of (C5Me3(CH2)2)Ta(H)2(PMe3)2 (1989) (11)
- Zirconocene-like reactivity of half-sandwich tantalum imido complexes: new C–C coupling reagents (1995) (11)
- SUPRAMOLECULAR METALLOCALIXARENE CHEMISTRY : LINKING METALLOCALIXARENES THROUGH IMIDO BRIDGES (1998) (11)
- Dalton perspectives. Bond stretch isomerism: fact or artifact? (1992) (11)
- Synthesis of stereoblock copolymers via ligand exchange in living stereoselective ring opening metathesis polymerisation of 2,3-bis(trifluoromethyl)bicyclo[2.2.1]hepta-2,5-diene (1996) (10)
- Coordination chemistry with phosphine and phosphine oxide-substituted hydroxyferrocenes. (2010) (10)
- Four-versus five-co-ordinate bis(imido) alkene complexes of molybdenum: the contrasting effects of tert-butyl- and 2,6-diisopropylphenyl-imido substituents (1995) (10)
- A novel ligand family based on bulky metallocalix[4 and 8]arene substituents (2002) (10)
- Sodium intercalation into WO2Cl2 (1990) (9)
- Half-sandwich chalcogenido complexes of niobium(V) (1992) (9)
- The Disordered Structure of WO2Cl2: A Powder Diffraction Study (1993) (9)
- Synthesis and characterisation of half-sandwich tantalum compounds in oxidation states (I)–(V): tertiary phosphine, acetylene, butadiene, carbonyl, and oxo derivatives. X-Ray crystal structures of [Ta(C5Me5)Cl3(PMe3)] and [Ta(C5Me5)Cl2(CO)2(PMe3)] (1990) (9)
- Ethylene polymerization under mild conditions using simple aluminum alkyls and chloro activators (2007) (9)
- Synthesis and X-ray structural characterization of the seven-coordinate niobium oxo complex, [Nb(O)Cl3(PMe3)3]; the first tertiary phosphine adduct of Nb(O)Cl3 (1988) (9)
- Iron-Catalyzed Polyethylene Chain Growth on Zinc : Linear-Olefins with a Poisson Distribution * * (2002) (9)
- Half-sandwich pentamethylcyclopentadienyl oxo and alkoxo complexes of tantalum. Synthesis and characterisation of (η-C5Me5)Ta(O)Cl2 (1989) (9)
- Niobium and tantalum methyl complexes containing imido and cyclopentadienyl ligands. Crystal structure of [Nb(μ-C5H5)(NtBu)(Me)(Cl)] (1993) (9)
- Bis(adamantylimido) Complexes of Chromium (VI) (1998) (8)
- Molybdenum and tungsten mono-isodiazene complexes with alkyl ligands as ring-opening metathesis polymerisation procatalysts. Crystal and molecular structures of [Mo(CH2CMe2Ph)3(NNPh2)(OC6F5)], [W(CH2SiMe3)3(NNPh2)(OC6F5)] and [WCl2(NNPh2)(OC6F5)2(thf)] (1999) (8)
- Pairwise ligand exchange reactions in tetrahedral and pseudo-tetrahedral transition metal complexes (2003) (8)
- Tandem asymmetric allylboration–alkene metathesis: a novel strategy for the synthesis of trans-disubstituted homoallylic alcohols (1996) (8)
- 9.1 – Metal Complexes as Catalysts for Polymerization Reactions (2003) (8)
- Reactions of (η5-C5Me5)Ta(PMe3)(H)2(η2 CHPMe2) with heterocumulenes and the interconversion of tautomeric formamido complexes of tantalum (1994) (8)
- Alkoxide, phenoxide and hydrido-phenoxide compounds of tantalum bearing the pentamethylcyclopentadienyl ligand (1993) (7)
- (η-C5Me5)Ta(CH2CH2CMe3)2(η2-CHPMe2): a stable sixteen electron long-chain di-alkyl compound of tantalum (1990) (7)
- Synthesis of nucleic-acid base containing norbornene derivatives as monomers for ring-opening-metathesis-polymerization (2001) (7)
- Structure of the intercalate NaWO2Cl2 (1991) (7)
- Bis(isodiazene) and related complexes of molybdenum(VI). Syntheses and structures of [Mo(OTf)2(NNPh2)2(py)2], [MoCl(OTf)(NNPh2){NC5H3(CH2C(O)Ph2)2-2,6}], [{MoCl(NNPh2)2(µ-Cl)(NH2But)}2] and [MoTp′Cl(NNPh2)2] [OTf = O3SCF3, Tp′ = tris(3,5-dimethylpyrazolyl)hydroborate] (1999) (7)
- Ring opening metathesis polymerization of 2,3-diazanorborn-5-ene derivatives (1999) (7)
- Multiple α-agostic interactions in a metal–methyl complex: the neutron structure of [Mo(NC6H3Pri2-2,6)2Me2] (1998) (7)
- The effect of Brønsted acids on the stability of oxo-alkoxide and imido-alkoxide complexes of molybdenum (2002) (7)
- Four coordinate oxo-phenoxide compounds of niobium(V): Synthesis and characterization of [Nb(O)(O-2,6-R2C6H3)3], R Me (1), R tBu (2) (1992) (6)
- Distortional Isomerism in Oxomolybdenum Systems; the Evidence Re‐evaluated (1992) (6)
- Facile conversion of a cationic MoIV phosphinimato complex into an anionic nitrido-bridged dimer with a bis(trimethylphosphine)iminium counterion (1989) (6)
- Synthesis and X-ray crystal structures of hydridotris(3,5-dimethylpyrazolyl)borate (Tp′) molybdenum(VI) bis(imido) complexes (2004) (6)
- A novel tantalum butterfly oxo cluster (1990) (6)
- New S/O-substituted ferrocenediyl ligands and their metal complexes. (2006) (5)
- Synthesis, characterization and reactivity of the molybdenum(VI) complex [MoCl(NAr)2(CH2CMe2Ph)] (Ar=2,6-Pri2C6H3) (2004) (5)
- Selective catalytic dimerisation of ethylene to but-1-ene by [(η-C5Me5)Ta(PMe3)(H)(Br)(η2-CHPMe2)] (1990) (5)
- Surprises in enolate binding at high valent molybdenum (1998) (5)
- New coordination modes at molybdenum for 2-diphenylphosphinoaniline derived ligands. (2007) (5)
- Unexpected synthesis of a binuclear chromium(III) salt exhibiting NH…Cl hydrogen-bonding interactions (1995) (5)
- Synthesis, structural characterisation and reactivity of the d2 pseudo-metallocene complex Mo(N-2,6-iPr2C6H3)2(PMe3)2 (1993) (5)
- Facile synthesis of 2-arylpyrroles from 4-oxo-butanoic acids and their use in the preparation of bis(pyrrolyl)methanes (2006) (5)
- Synthesis and characterization of the paramagnetic niobium(III) complex [Nb(η-C5Me5)Cl2(PMe3)2] and its reaction with carbon monoxide (1992) (4)
- Iron-catalyzed polyethylene chain growth on zinc: linear alpha-olefins with a poisson distribution. (2002) (4)
- Bis[hydrazido(2-)] and related complexes ofmolybdenum(VI): towards alkene-metathesis catalysts based onhydrazido(2-) ligation (1997) (4)
- Tertiary phosphine adducts of [Nb(O)Cl3] (1993) (4)
- Carboxylate versus imidobenzoate bonding for anthranilic acid derivatives. Crystal structures of [W(η-C5Me5)Cl3(η2-O2CC6H4NH2-2)] and [ReCl(OEt)(PPh3)2(NC6H4CO2)] (2001) (4)
- Titanium complexes bearing bidentate benzimidazole-containing ligands and their behavior in ethylene polymerization (2008) (4)
- Niobium—phosphorus coupling constants (1994) (3)
- ‘Electronic bending’ of imido ligands and the effect on the coordination mode of a tridentate ancillary ligand (2007) (3)
- Dichloro(η5‐cyclopentadienyl)(phenylimido)vanadium(V) (1997) (3)
- Dibenzylbis(tert‐butylimido)molybdenum(VI), containing both η1‐ and η2‐benzyl ligands (1999) (3)
- Securing technology-critical metals for Britain (2021) (3)
- Magnesium and zinc complexes of a potentially tridentate beta-diketiminate ligand. (2004) (3)
- A novel polar polymer via romp (1996) (3)
- Structure of the intercalate Na1.5WO2Cl2 by powder neutron diffraction (1993) (3)
- Correlation of metal spin-state in alpha-diimine iron catalysts with polymerization mechanism. (2007) (2)
- Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(N(t)Bu)(CH2R)2 with pentafluorophenol. (2011) (2)
- A computational study on the ring-opening polymerization of lactide initiated by β-diketiminate metal alkoxides. 2: The origin of heterotactic stereocontrol (2004) (2)
- The role of Brønsted acid catalysis in inter-metal ligand exchange reactions (2001) (2)
- INOR 556-Correlation between metal spin state and catalytic reactivity: Polymerizations mediated by diimine iron complexes (2006) (2)
- A journey in metal-ligand multiple bond chemistry (2002) (2)
- Temperature dependence of sodium ion diffusion in NaxWO2Cl2 (1992) (2)
- Rapid Entry into Mono-, Bi-, and Tricyclic β-Lactam Arrays via Alkene Metathesis. (1999) (2)
- Stereoselective Acrylate Polymerization (2007) (2)
- A mild, phosphine-assisted synthesis of (η-C5Me5)Ta(CO)4. Isolation and crystal structure of intermediate (η-C5Me5)TaCl2(CO)2(PMe3) (1988) (2)
- Recent Developments in the Synthesis of Functionalised Polymers via Living Ring-Opening Metathesis Polymerization (1995) (2)
- Iron diimine complexes: Robust, low toxic catalysts for atom transfer radical polymerization (ATRP) (2004) (1)
- New, Improved Syntheses of the Group 6 Oxyhalides, W(O)Cl4, W(O)2Cl2, and Mo(O)2Cl2. (1988) (1)
- Hydrido Methylidene, Hydrido Vinylidene, Hydrido Oxo, and Hydrido Formaldehyde Derivatives of Bis(pentamethylcyclopentadienyl)tantalum. (1986) (1)
- Charm and Beauty Hadron Production at sqrt(s) ~ M_{z0} (1995) (1)
- The Search for New‐Generation Olefin Polymerization Catalysts: Life beyond Metallocenes (1999) (1)
- Enyne Metathesis for the Facile Synthesis of Highly Functionalized Novel Bicyclic β-Lactams. (1997) (1)
- Erratum to: “Synthesis and X-ray crystal structures of hydridotris(3,5-dimethylpyrazolyl)borate (Tp′) molybdenum(VI) bis(imido) complexes” [Polyhedron 23 (2004) 189] (2004) (1)
- The Synthesis of N-Norbornenyl-Amino Acids and Esters: Monomers for the Preparation of Well Defined Polymers. (1995) (1)
- Bond stretch isomerism : fact or artifact ? (1992) (1)
- Platinum(II) complexes of some unsymmetrical diphosphenes. (2017) (1)
- Atom transfer vs. catalytic chain transfer polymerization using a-diimine iron catalysts: Influence of metal spin state on mechanism (2005) (1)
- Chemistry. Shuttling polyolefins to a new materials dimension. (2006) (1)
- Recent developments in the synthesis of stereoregular fluoropolymers (1994) (0)
- The synthesis and ROMP of heterocyclic monomers (1997) (0)
- A Tripartite Asymmetric Allylboration — Silicon Tethered Alkene Ring Closing Metathesis — in situ Ring Opening Protocol for the Regiospecific Generation of Functionalized (E)‐Disubstituted Homoallylic Alcohols. (1999) (0)
- Half-sandwich niobium imido and molybdenum bis(imido) complexes: metallocene analogues (1993) (0)
- Four Coordinate Bis(imido) Alkene Complexes of Molybdenum(IV): Relatives of the Zirconocene Family. (2010) (0)
- Discovery of new single-site chromium polymerization catalysts using high throughput screening. (2002) (0)
- The Syntheses and Catalytic Applications of Unsymmetrical Ferrocene Ligands (2004) (0)
- Synthesis of Penicillin Derived Polymers Utilizing Ring-Opening Metathesis Polymerization Methodology. (1997) (0)
- Ring‐opening polymerization: Mechanisms, catalysis, structure, utility. Edited by Daniel J. Brunelle, Carl Hanser Verlag, Munich 1993, 361 pp., hardcover, DM 188, US $ 114, ISBN 3‐446‐16293‐3 (1994) (0)
- The Use of Hexamethyldisilthiane in the Synthesis of Transition Metal Thiohalides. (1989) (0)
- Facile Synthesis of 2-Arylpyrroles from 4-Oxo-butanoic Acids and Their Use in the Preparation of Bis(pyrrolyl)methanes. (2006) (0)
- Aluminum compounds for the preparation of vinyl polymers (1999) (0)
- A computational study on the ring-opening polymerization of lactide initiated by β-diketiminate metal alkoxides. 1: The mechanism of chain propagation (2004) (0)
- Novel Silicon‐Containing Hydrocarbon Rings and Polymers via Metathesis: X‐Ray Crystal Structure of cis,cis‐1,1,6,6‐Tetraphenyl‐1,6‐ disilacyclodeca‐3,8‐diene. (1992) (0)
- HIGHLY FUNCTIONAL MONOCYCLIC AND BICYCLIC BETA -LACTAMS VIA ALKENE METATHESIS (1997) (0)
- Alkene Metathesis in the Synthesis of Novel β‐Lactams. (1997) (0)
- Synthesis and X-Ray Structural Characterization of the Seven-Coordinate Niobium Oxo Complex, (Nb(O)Cl3(PMe3)3); the First Tertiary Phosphine Adduct of Nb(O)Cl3. (1989) (0)
- Brooke L. Small and Maurice Brookhart, Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization (2017) (0)
- Four‐ versus Five‐co‐ordinate Bis(imido) Alkene Complexes of Molybdenum: The Contrasting Effects of tert‐Butyl‐ and 2,6‐ Diisopropylphenyl‐imido Substituents. (1996) (0)
- Tandem Asymmetric Allylboration-Alkene Metathesis: A Novel Strategy for the Synthesis of trans-Disubstituted Homoallylic Alcohols. (1997) (0)
- CCDC 248423: Experimental Crystal Structure Determination (2006) (0)
- The Use of Silylethers and Silylthioethers in Syntheses of Oxohalide and Thiohalide Compounds of Molybdenum and Tungsten. (1991) (0)
- Synthesis and Characterization of Half-Sandwich Tantalum Compounds in Oxidation States (I)-(V): Tertiary Phosphine, Acetylene, Butadiene, Carbonyl, and Oxo Derivatives. X-Ray Crystal Structures of (Ta(C5Me5) Cl3(PMe3)) and (Ta(C5Me5)Cl2(CO)2(PMe3)). (1991) (0)
- CCDC 216483: Experimental Crystal Structure Determination (2004) (0)
- INOR 355-Polymerization catalyst design based on metal spin state (2006) (0)
- Trimethylphosphine as a Reactive Solvent: Synthesis, Crystal Structures, and Reactions of [Ta(PMe3)3(η2-CH2PMe2)(η2-CHPMe2)] and [W(PMe3)4(η2-CH2PMe22)H] and Related Studies. (1986) (0)
- COMPRISINGA HAFNOCENE COMPONENT FOR THE PRODUCTION OF BIMODAL POLYOLEFINS IN A SINGLE REACTOR (2017) (0)
- Ligands as Compass Needles: How Orientations of Alkene, Alkyne, and Alkylidene Ligands Reveal π‐Bonding Features in Tetrahedral Transition Metal Complexes (1995) (0)
- Bis(μ-2-tert-butylphenylimido-1:2κ2 N:N)chlorido-2κCl-(diethyl ether-1κO)(2η5-pentamethylcyclopentadienyl)lithiumtantalum(V) (2011) (0)
- Cocondensation of Molybdenum Atoms with the Bulky Tertiary Diphosphine 1,2-Bis(diisopropylphosphino)ethane: The Molecular Structure of (MoH4(iPr2PCH2CH2PiPr2)2). (1988) (0)
- Cross Metathesis of the Amino Acid Homoallylglycine. (1997) (0)
- INOR 447-Computational studies on Iron diimine complexes: Understanding the role of metal spin state in catalytic polymerization (2006) (0)
- Spectroscopic studies on iron-based ethylene polymerization catalysts. (2001) (0)
- Bis(imino)pyridines: Surprisingly Reactive Ligands and a Gateway to New Families of Catalysts (2007) (0)
- Highly functionalised polymers via ring-opening metathesis polymerisation (1997) (0)
- INOR 352-Computational investigations into the mechanism of Iron diimine catalyzed polymerizations: Examining the catalyst and the role of metal spin state (2006) (0)
- Highly Functionalized Monocyclic and Bicyclic β‐Lactams via Alkene Metathesis. (1997) (0)
- Chemical Intercalation of Divalent Cations (1991) (0)
- Edge‐Shared, Bioctahedral, Bismuth Phosphine Complexes. (1992) (0)
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