Victor Snieckus
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Why Is Victor Snieckus Influential?
(Suggest an Edit or Addition)According to Wikipedia, Victor Snieckus was a synthetic organic chemist and professor emeritus at Queen's University in Kingston, Ontario. He was known for his influential research on directed ortho metalation. Early life and education Snieckus was born in Kaunas, Lithuania in 1937. His family lived in Germany during World War II and in 1948 immigrated to Alberta, Canada. Snieckus received his bachelor's degree in chemistry from University of Alberta in 1959, his master's degree from University of California, Berkeley in 1961, and his PhD from the University of Oregon in 1965 under the supervision of Virgil Boekelheide. He spent a year as a postdoctoral scholar at the National Research Council of Canada.
Victor Snieckus's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Palladium-catalyzed cross-coupling: a historical contextual perspective to the 2010 Nobel Prize. (2012) (1969)
- Directed ortho metalation. Tertiary amide and O-carbamate directors in synthetic strategies for polysubstituted aromatics (1990) (1604)
- Beyond thermodynamic acidity: a perspective on the complex-induced proximity effect (CIPE) in deprotonation reactions. (2004) (520)
- Intramolecular Ene Reactions in Organic Synthesis (1978) (311)
- Directed lithiation of aromatic tertiary amides: an evolving synthetic methodology for polysubstituted aromatics (1982) (264)
- Suzuki-Miyaura cross-coupling of aryl carbamates and sulfamates: experimental and computational studies. (2011) (241)
- Studies of a Ring-Cleaving Dioxygenase Illuminate the Role of Cholesterol Metabolism in the Pathogenesis of Mycobacterium tuberculosis (2009) (202)
- Direct and Highly Enantioselective Synthesis of Ferrocenes with Planar Chirality by (−)-Sparteine-Mediated Lithiation (1996) (166)
- Nickel(0)-catalyzed cross coupling of aryl O-carbamates and aryl triflates with Grignard reagents. Directed ortho metalation-aligned synthetic methods for polysubstituted aromatics via a 1,2-dipole equivalent (1992) (143)
- Directed ortho metalation approach to C-7-substituted indoles. Suzuki-Miyaura cross coupling and the synthesis of pyrrolophenanthridone alkaloids. (2003) (140)
- Sequential directed ortho metalation-boronic acid cross-coupling reactions. A general regiospecific route to oxygenated dibenzo[b,d]pyran-6-ones related to ellagic acid (1991) (138)
- Directed Metalation of Pi-Deficient Azaaromatics: Strategies of Functionalization of Pyridines, Quinolines, and Diazines (1992) (128)
- Expedient route to 3- and 3,3′-substituted 1,1′-bi-2-naphthols by directed ortho metalation and suzuki cross coupling methods (1992) (124)
- Impacts of structural photomodification on the toxicity of environmental contaminants: anthracene photooxidation products. (1999) (119)
- Intramolecular .alpha.-amidoyl-to-aryl 1,5-hydrogen atom transfer reactions. Heteroannulation and .alpha.-nitrogen functionalization by radical translocation (1990) (117)
- The directed ortho lithiation of O-aryl carbamates. An anionic equivalent of the Fries rearrangement (1983) (117)
- Directed ortho metalation of N,N-diethylbenzamides. Silicon protection of ortho sites and the o-methyl group (1989) (111)
- Directed ortho metalation methodology. The N,N-dialkyl aryl O-sulfamate as a new directed metalation group and cross-coupling partner for Grignard reagents. (2005) (111)
- The directed ortho metalation—cross coupling symbiosis. Regioselective methodologies for biaryls and heterobiaryls. Deployment in aromatic and heteroaromatic natural product synthesis (2002) (101)
- Identification and analysis of a bottleneck in PCB biodegradation (2002) (93)
- Synthetic connections to the aromatic directed metalation reaction. Functionalized aryl boronic acids by ipso borodesilylation. General syntheses of unsymmetrical biphenyls and m-terphenyls (1987) (86)
- Toxicity of hydroxylated alkyl-phenanthrenes to the early life stages of Japanese medaka (Oryzias latipes). (2012) (86)
- Combined directed ortho and remote metalation-Suzuki cross-coupling strategies. Efficient synthesis of heteroaryl-fused benzopyranones from biaryl O-carbamates. (2009) (85)
- Tandem directed metalation reactions. Short syntheses of polycyclic aromatic hydrocarbons and ellipticine alkaloids (1980) (84)
- The Directed ortho Metalation Reaction – A Point of Departure for New Synthetic Aromatic Chemistry (2004) (83)
- Iridium-catalyzed C-H activation versus directed ortho metalation: complementary borylation of aromatics and heteroaromatics. (2010) (81)
- Connections to the died ortho metalation strategy. Pd(0)-catalyzed cross coupling of aryl boronic acids with aryl triflatest☆ (1990) (81)
- Synthetic connections to the aromatic directed metalationreaction. Unsymmetrical biaryls by palladium-catalyzed cross coupling of directed metalation-derived arylboronic acids with aryl halides (1985) (81)
- Directed ortho metalation-boronation and Suzuki-Miyaura cross coupling of pyridine derivatives: a one-pot protocol to substituted azabiaryls. (2007) (80)
- A practical in situ generation of the Schwartz reagent. Reduction of tertiary amides to aldehydes and hydrozirconation. (2014) (79)
- Combined directed ortho and remote metalation-cross-coupling strategies. General method for benzo[a]carbazoles and the synthesis of an unnamed indolo[2,3-a]carbazole alkaloid. (2004) (78)
- Connecting Directed Ortho Metalation and Olefin Metathesis Strategies. Benzene-Fused Multiring-Sized Oxygen Heterocycles. First Syntheses of Radulanin A and Helianane (1998) (76)
- Remote directed metalation of biaryl o-carbamates. Ring to ring carbamoyl transfer route to biaryls, dibenzo[b,d]pyranones, and the natural fluorenone dengibsin (1992) (71)
- Combined directed remote metalation-transition metal catalyzed cross coupling strategies: the total synthesis of the aglycones of the gilvocarcins V, M, and E and arnottin I. (2009) (70)
- Synthetic Connections to the aromatic directed metalation reaction. Radical-induced cyclization to substituted benzofurans, benzopyrans, and furopyridines (1985) (69)
- Heterocycles via ortho-Lithiated Benzamides (1980) (67)
- Beyond directed ortho metalation: Ru-catalyzed CAr-O activation/cross-coupling reaction by amide chelation. (2014) (64)
- Advances in Carbanion Chemistry (1996) (63)
- Catabolism of the Last Two Steroid Rings in Mycobacterium tuberculosis and Other Bacteria (2017) (63)
- Directed ortho metalation-based methodology. Halo-, nitroso-, and boro-induced ipso-desilylation. Link to an in situ Suzuki reaction. (2005) (62)
- .alpha.-Metalated tertiary enol carbamates. New acyl anion equivalents (1990) (62)
- (−)‐Sparteine‐Mediated Directed ortho‐Metalation of N‐Cumyl‐N‐ethylferrocenecarboxamide. Versatile Routes to Functionalized Planar Chiral Ferrocenecarboxamides, Amines, Esters and Phosphines (2003) (60)
- Remote aromatic metalation. An anionic Friedel-Crafts equivalent for the regioselective synthesis of condensed fluorenones from biaryl and m-teraryl 2-amides (1991) (59)
- Quantitative structure-activity relationships for chronic toxicity of alkyl-chrysenes and alkyl-benz[a]anthracenes to Japanese medaka embryos (Oryzias latipes). (2015) (58)
- Combined Metalation-Palladium-Catalyzed Cross Coupling Strategies. A Formal Synthesis of the Marine Alkaloid Amphimedine (1995) (58)
- Copper-catalyzed cross-coupling interrupted by an opportunistic Smiles rearrangement: an efficient domino approach to dibenzoxazepinones. (2012) (57)
- Phytochemistry and Antibacterial Activity of Senna alata Flower (2001) (56)
- N-Cumyl Benzamide, Sulfonamide, and Aryl O-Carbamate Directed Metalation Groups. Mild Hydrolytic Lability for Facile Manipulation of Directed Ortho Metalation Derived Aromatics (1999) (56)
- Ortho-metalated aryl tert-butyl sulfones. Comparison with other directing groups and new methodology for polysubstituted aromatics (1989) (55)
- Concise syntheses of the amaryllidaceae alkaloids ungerimine and hippadine via the suzuki aryl-aryl cross coupling reaction (1990) (55)
- Growth inhibitory effect of naphthofuran and naphthofuranquinone derivatives on Trypanosoma cruzi epimastigotes (1995) (54)
- The directed metalation connection to aryl-aryl cross coupling.Regiospecific synthesis of phenanthridines, phenanthridinones and the biphenyl alkaloid ismine (1988) (54)
- Ortho-lithiated tertiary benzamides. Magnesium transmetalation and synthesis of phthalides and isocoumarins including mellein and kigelin (1984) (53)
- Photoisomerization of 1-iminopyridinium ylides to 1(1H), 2-diazepines (1970) (53)
- Directed ortho metalation - mediated F+ introduction. Regiospecific synthesis of fluorinated aromatics (1994) (52)
- Palladium-catalyzed direct heck arylation of dual pi-deficient/pi-excessive heteroaromatics. Synthesis of C-5 arylated imidazo[1,5-a]pyrazines. (2008) (52)
- Combined Directed Ortho-, Remote-Metalation and Cross-Coupling Strategies. Concise Syntheses of the Kinamycin Biosynthetic Grid Antibiotics Phenanthroviridin Aglycon and Kinobscurinone. (1997) (51)
- Asymmetric total synthesis of (-)-panacene and correction of its relative configuration. (2006) (51)
- The Directed ortho Metallation-Cross- Coupling Fusion: Development and Application in Synthesis (2013) (51)
- Anionic N-fries rearrangement of N-carbamoyl diarylamines to anthranilamides. Methodology and application to acridone and pyranoacridone alkaloids. (2006) (50)
- The directed ortho metalation connection to aryl-aryl cross coupling.A general regiospecific synthesis of phenanthrols (1988) (50)
- Radioimmunoassay of melatonin in rat serum. (1981) (50)
- Anionic aromatic ring annelation of o-allyl benzamides. Regiospecific synthesis of naphthols and naphthoquinones (1986) (50)
- Selective ortho and benzylic functionalization of secondary and tertiary p-tolylsulfonamides. Ipso-bromo desilylation and Suzuki cross-coupling reactions. (2001) (48)
- The tert-BUTYL sulfoxide directed ortho metalation group. New synthetic methodology for substituted aromatics and pyridines and comparisons with others metalation directors (1992) (47)
- The Suzuki-Miyaura cross coupling reactions on solid support. Link to solution phase directed ortho metalation. The Leznoff acetal linker approach to biaryl and heterobiaryl aldehydes (1998) (47)
- Beyond directed ortho metalation: ruthenium-catalyzed amide-directed C(Ar)-N activation/C-C coupling reaction of anthranilamides with organoboronates. (2014) (46)
- General route to anthraquinone natural products via directed metalation of N,N-diethylbenzamides (1979) (46)
- Phenylboronic Acid-Mediated Synthesis of 2H-Chromenes (1998) (45)
- Synthetic connections to the aromatic directed metalation reaction. Iterative ortho metalation-cross coupling tactics for the construction of polyphenyls (1987) (45)
- Identification of novel dynamin‐related protein 1 (Drp1) GTPase inhibitors: Therapeutic potential of Drpitor1 and Drpitor1a in cancer and cardiac ischemia‐reperfusion injury (2020) (45)
- Ortho-lithiated tertiary benzamides. Chain extension via o-toluamide anion and general synthesis of isocoumarins including hydrangenol and phyllodulcin (1984) (44)
- Tandem conjugate addition-α-alkylation of unsaturated amides. Synthetic methodology. (1980) (44)
- The tertiary sulfonamide as a latent directed-metalation group: Ni0-catalyzed reductive cleavage and cross-coupling reactions of aryl sulfonamides with grignard reagents. (2004) (44)
- Fluorinated vinyl carbamates and carbamoyloxy allylsilanes. α-Metalation, organolithium addition-elimination, and fluoride. Mediated electrophilic reactivity patterns (1993) (43)
- Directed ortho metalation of n,n-diethyl benzamides. Methodology and regiospecific synthesis of useful contiguously tri- and tetra-substituted oxygenated aromatics, phthalides and phthalic anhydrides (1992) (42)
- Directed metalation of tertiary benzamides. Ortho N-aryl amination and synthesis of acridones (1982) (42)
- Carbanionic Friedel-Crafts equivalents. regioselective directed ortho and remote metalation-C-N cross coupling routes to acridones and dibenzo[b,f]azepinones. (2008) (41)
- Directed ortho metalation - cross coupling links. Carbamoyl rendition of the baker-venkataraman rearrangement. Regiospecific route to substituted 4-hydroxycoumarins (1998) (41)
- Directed ortho metalation of O-pyridyl carbamates. Regiospecific entries into polysubstituted pyridines (1985) (41)
- ortho-Anisylsulfonyl as a protecting group for secondary amines: mild Ni0-catalyzed hydrodesulfonylation. (2004) (41)
- Rapid route to 3,4-substituted indoles via a directed ortho metalation-retro-Mannich sequence. (2002) (40)
- The Directed Ortho Metallation (DoM)–Cross‐Coupling Nexus. Synthetic Methodology for the Formation of Aryl–Aryl and Aryl–Heteroatom–Aryl Bonds (2008) (40)
- Intramolecular Anionic Friedel-Crafts Equivalents. A General Regiospecific Route to Substituted and Naturally Occurring Xanthen-9-ones (1997) (39)
- Combined directed ortho metalation-halogen dance (HD) synthetic strategies. HD-anionic ortho fries rearrangement and double HD sequences. (2010) (39)
- (-)-Sparteine-mediated metalation of ferrocenesulfonates. The first case of double asymmetric induction of ferrocene planar chirality. (2002) (39)
- Directed ortho metalation-cross coupling strategies. N-cumyl arylsulfonamides. Facile deprotection and expedient route to 7- and 4,7-substituted saccharins. (2007) (38)
- α′,α′-disilylated tertiary benzamides as dual ortho- and α′-carbanion synthons: Amide Peterson olefination routes to N-benzoyl enamines, isoquinolines, and dibenzazocines (1989) (38)
- Directed ortho metalation - suzuki cross coupling connections. Convenient regiospecific routes to functionalized m- and p-teraryls and m-quinquearyls (1992) (37)
- Short synthesis of azafluorenone alkaloids using transition metal-catalyzed cross coupling tactics (1988) (37)
- The directed ortho metalation - palladium catalyzed cross coupling connection. A general regiospecific route to 9-phenanthrols and phenanthrenes. Exploratory further metalation (2000) (36)
- Anionic Indole N-carbamoyl N --> C translocation. A directed remote metalation route to 2-Aryl- and 2-heteroarylindoles. synthesis of benz[a]carbazoles and Indeno[1,2-b]indoles. (2008) (36)
- Directed ortho metallation of tertiary aromatic amides (1983) (35)
- THE RELATIONSHIP BETWEEN GLUCOSINOLATE CONTENT OF CRUCIFEROUS PLANTS AND OVIPOSITION PREFERENCES OF HYLEMYA BRASSICAE (DIPTERA: ANTHOMYIIDAE) (1976) (35)
- Synthetic strategies based on aromatic metalation - cross coupling links. A concise formal synthesis of the azaphenanthrene alkaloid eupolauramine (1991) (35)
- Metalated unsaturated amides. Regio- and stereoselective .gamma.-alkylation (1981) (34)
- Directed ortho metalation reactions. Convergent synthesis of "angular" anthracyclinones ochromycinone and X-14881 C (1987) (34)
- On the mechanism of the directed ortho and remote metalation reactions of N,N-dialkylbiphenyl 2-carboxamides. (2010) (34)
- A Mixed Naphthyl-Phenyl Phosphine Ligand Motif for Suzuki, Heck, and Hydrodehalogenation Reactions (2006) (34)
- BENZENOID RING FUNCTIONALIZATION OF INDOLES AND TRYPTOPHOLS VIA COMBINED DIRECTED ORTHO METALATION-CROSS COUPLING METHODOLOGY (1995) (34)
- Combined directed metalation - cross coupling strategies. Total synthesis of the aglycones of gilvocarcin V, M and E (1997) (33)
- Efficient directed ortho metalation-based route to cytotoxic furanonaphthoquinone natural products (1987) (33)
- Directed metalation of tertiary benzamides. Silicon protection of ortho sites and ortho methyl groups (1983) (33)
- The N-tert-butylcarbamoyl directed metalation group for the regiospecific synthesis of 2-substituted pyrroles and indoles (1991) (33)
- Combinational O-aryl carbamate and benzamide directed ortho metalation reactions. Synthesis of ochratoxin A and ochratoxin B (1985) (32)
- ortho and remote metalation – cross coupling strategies. Total synthesis of the naturally occurring fluorenone dengibsinin and the azafluoranthene alkaloid imeluteine (1994) (31)
- Beyond Directed ortho Metalation: Ruthenium-Catalyzed Amide-Directed CAr-OMe Activation/Cross-Coupling Reaction of Naphthamides with Aryl Boronates. (2015) (31)
- In situ anionic shielding for regioselective metalation: directed peri and iterative metalation routes to polyfunctionalized 7-azaindoles. (2012) (31)
- The directed ortho metalation - Cross-coupling symbiosis in heteroaromatic synthesis (1999) (30)
- Directed ortho-metalation-cross-coupling strategies. One-pot Suzuki reaction to biaryl and heterobiaryl sulfonamides. (2011) (30)
- Dilithiated synthons of tertiary benzamides, phthalamides, and 0,0′-aryl dicarbamates (1985) (29)
- The directed ortho metalation reaction. Methodology, applications, synthetic links, and a non-aromatic ramification (1990) (29)
- The directed ortho metalation–transition metal–catalyzed reaction symbiosis in heteroaromatic synthesis (1999) (29)
- The Stille cross coupling reactions on solid support. Link to solution phase directed ortho metalation. An ester linker approach to styryl, biaryl and heterobiaryl car☐ylic acids (1998) (29)
- Directed ortho metalation strategies. Effective regioselective routes to 1,2-, 2,3-, and 1,2,3-substituted naphthalenes. (2014) (29)
- THE DI-T-BUTYLPHOSPHINYL DIRECTED ORTHO METALATION GROUP. SYNTHESIS OF HINDERED DIALKYLARYLPHOSPHINES (1998) (28)
- (–)-Sparteine-mediated stereoselective directed ortho metalation of ferrocene diamides (2006) (28)
- Synthetic Connections to the Directed ortho Methalation Reaction. 3,4-Pyridynes from 4-Trialkylsilyl-3-pyridyl Triflates (1992) (27)
- 1,2-Diazepines: a new vista in heterocyclic chemistry (1981) (27)
- 3,3'-dipyridyl BINOL ligands. Synthesis and application in enantioselective addition of Et2Zn to aldehydes. (2007) (27)
- 1,3-Asymmetric Induction via 1,5-Hydrogen Atom Translocation Reactions. Highly Enantioselective Synthesis of β-Substituted β-Amino Acids (1996) (27)
- The Wittig Reaction of Indole-2-methyltriphenylphosphonium Iodide with 4-Piperidone Derivatives and Aromatic Aldehydes (1973) (27)
- 4,6-Dimethoxy-3,7-dimethylcoumarin from Colchicum decaisnei. Total synthesis by carbamoyl Baker-venkataraman rearrangement and structural revision to isoeugenetin methyl ether (1998) (27)
- Reaction of 1-acetyl-3-piperidionindole with acetylenic esters (1971) (27)
- Carbanion‐Mediated Heterocyclizations: Regiospecific, General Route to Dibenzo‐ [b,e]phosphininones by Synthetic Anionic Equivalents of Friedel–Crafts Reactions and Remote Fries Rearrangement (1996) (26)
- α-Aryl O-vinyl carbamates. Tandem carbolithiation — α-alkylation and -[1,2]-Wittig rearrangement reactions (1996) (26)
- Synthetic strategies based on aromatic metalation - cross coupling links. regiospecific synthesis of the phenanthrene natural product gymnopusin (1991) (26)
- Sequential directed ortho metalation reactions. A synthesis ofanthramycin. (1984) (26)
- Regiospecific Syntheses of All Isomeric Nitrofluorenones and Nitrofluorenes by Transition Metal Catalyzed Cross-Coupling Reactions (1989) (26)
- Synthesis of pyrethroid via epoxy amide cyclization (1984) (26)
- Directed ortho-metalation and Suzuki–Miyaura cross-coupling connections: regiospecific synthesis of all isomeric chlorodihydroxybiphenyls for microbial degradation studies of PCBs (1999) (25)
- Reductive cleavage of aryl O-carbamates to phenols by the Schwartz reagent. Expedient link to the directed ortho metalation strategy. (2013) (25)
- Directed lithiation of N,N-diethylbenzamides. Regiospecific synthesis of contiguously tri- and tetra-substituted alkoxybenzenes (1978) (25)
- CH Activation by Amide Chelation Control: Ruthenium‐ Catalyzed Direct Synthesis of 2‐Aryl‐3‐furanamides (2014) (24)
- Directed ortho metalation-cross coupling connections. Nickel(0)-catalyzed cross coupling of aryl triflates with organozinc reagents (1994) (24)
- Condensation of laterally lithiated o-methyl and o-ethyl benzamides with imines mediated by (-)-sparteine. Enantioselective synthesis of tetrahydroisoquinolin-1-ones. (2001) (24)
- The Wittig Synthesis and Photocyclodehydrogenation of 3-(2-Aryl)Vinylindole Derivatives (1974) (23)
- “New Trends in Cross-Coupling: Theory and Applications” (2016) (23)
- Inhibition of benzo[a]pyrene dihydrodiol epoxide mutagenicity by synthetic analogues of ellagic acid. (1990) (23)
- Activated Cyclopropanes: A Remarkable Breadth of Recent Chemistry (2014) (23)
- Directed metalation of tertiary benzamides.: Short syntheses of hydrangenol and phyllodulcin (1982) (22)
- 3,5-Dilithiated tertiary thiophene 2-carboxamide. Regioselective entries into diversely substituted thiophenes (1985) (22)
- Directed ortho metalation of O-aryl and O-pyridyl thiocarbamates. A versatile synthetic method for substituted phenol into thiophenol conversion (1992) (22)
- Directed Metalation-Suzuki-Miyaura Cross-Coupling Strategies: Regioselective Synthesis of Hydroxylated 1-Methyl-phenanthrenes. (2015) (22)
- α′-Silylated tertiary benzamides as dual ortho- and α′-carbanion synthons. Carbodesilylative routes to isoquinoline and dibenzoquinolizidine derivatives (1989) (22)
- Concerning the structures of alkali-metal-mediated ortho zincation of benzamides and phenyl o-carbamate (2011) (21)
- α-Zinc >O-vinyl carbamates as anionic Friedel-Crafts equivalents. Cross coupling reactions with aryl and heteroaryl halides and triflates (1996) (21)
- Carbamoyl translocations by an anionic ortho-fries and cumulenolate alpha-acylation pathway: regioselective synthesis of polysubstituted chromone 3- and 8-carboxamides. (2008) (21)
- Directed aromatic functionalization (2011) (21)
- Reaction of diazomethane with 2-methyl-6,7-methylenedioxy-3,4-dihydro-isoquinolinium perchlorate (1971) (21)
- Combined directed ortho metalation-cross coupling strategies. Design for natural product synthesis (1994) (21)
- Directed ortho metalation reactions. Synthesis of the naturally-occurring benz[a]anthraquinones X-14881 C and ochromycinone (1985) (21)
- Substitution of hydroxybiaryls via directed ortho-lithiation of N-silylated O-aryl N-isopropylcarbamates. (2005) (21)
- Alkylation of α,β-unsaturated amides via metalated and dimetalated intermediates (1978) (20)
- Stereoselective Synthesis of Planar Chiral Ferrocenes (2010) (20)
- Regiospecific synthesis of alkylphenanthrenes using a combined directed ortho and remote metalation SuzukiMiyaura cross coupling strategy (2004) (20)
- Regioselective synthetic processes based on the aromatic metalation strategy (1990) (20)
- Anionic Homologous Fries Rearrangement of O-(2-Methylaryl)carbamates. A Regiospecific Route to Benzo[b]furan-2(3H)-ones including an Unnamed Metabolite from Helenium Species (1997) (20)
- Silicon in benzamide directed ortho metalation. Formation and reactions of benzamide benzynes (1984) (19)
- A convergent route to phthalideisoquinoline alkaloids via directed metalation of tertiary benzamides (1979) (19)
- Indole N-alkylation of tryptamines via dianion and phthalimido intermediates. New potential indolealkylamine haptens (1978) (19)
- Directed ortho-Metalation of N,N-Dialkyl O-Aryl Carbamates. Methodology, Anionic ortho Fries Rearrangement, and Lateral Metalation (2017) (19)
- A new synthesis of a stemmadenine model (1975) (19)
- Silicon in benzamide directed ortho metalation reactions. Carbo- and bromo-desilylations and synthesis of naturally-occurring anthraquinones (1984) (19)
- Tandem conjugate addition-α-alkylation of unsaturated amides. Synthesis of 1-aryltetralin lignans (1981) (19)
- Chemical synthesis : gnosis to prognosis (1996) (19)
- Directed Metalation of Diaryl Sulfone 2-Amides and 2-O-Carbamates. Regiospecific General Route to Thioxanthen-9-one 10,10-Dioxides via Anionic Friedel-Crafts and Remote Fries Rearrangement Equivalents (1994) (18)
- Directed ortho metalation-induced epoxy cyclialkylation. Regiospecific 5-exo-tet and 6-exo-tet routes to benzofurans and -pyrans (1984) (18)
- Ester-directed Ru-catalyzed C-O activation/C-C coupling reaction of ortho-methoxy naphthoates with organoboroneopentylates. (2016) (18)
- Anionic O → α- and β-Vinyl Carbamoyl Translocation of 2-(O-Carbamoyl) Stilbenes† (2004) (18)
- Directed metalation of N,N-diethylbenzamides. Silylated benzamides for the synthesis of naturally occurring peri-methylanthraquinones and peri-methyl polycyclic aromatic hydrocarbons (1989) (18)
- N,N-Diethyl O-Carbamate: Directed Metalation Group and Orthogonal Suzuki—Miyaura Cross-Coupling Partner. (2010) (17)
- Synthetic connections to the aromatic directed metalation reaction. A modified von niementowski quinoline synthesis from anthranilamides (1986) (17)
- Directed ortho metalation of silyloxybenzamides. Anion induced 0 → C silicon rearrangement (1983) (17)
- Intramolecular Anionic Friedel-Crafts Equivalents. An Expeditious Synthesis of 4H-1,2-Benzothiazin-4-one 1,1-Dioxides from N-Arylsulfonylated Amino Acids (1997) (17)
- Selected Catalytic Decompositions of Indole-2-diazoketone (1971) (17)
- The 2-(trimethylsilyl)ethoxymethoxy (OSEM) directed ortho metalation group. New regiospecific synthetic routes to substituted benzenes and pyridines (1990) (17)
- Insight into the Mechanism and Stereochemistry of the Transformations of Alkyltitanium Ate‐Complexes. An Enhanced Enantioselectivity in the Cyclopropanation of the Carboxylic Esters with Titanacyclopropane Reagents (2014) (17)
- Directed ortho metalation reactions. Expedient synthesis of 3,3′-disubstituted 1,1′-bi-(2-phenols) (BIPOLS) (1994) (16)
- Directed ortho metalation - cross coupling connections. Remote lateral metalation - cyclization of 2-imino-2′-methyl biaryls to 9-aminophenanthrenes. A synthesis of the alkaloid piperolactam C (1998) (16)
- Sodium Borohydride Reduction of 1-Acyl-1,2(1H)-Diazepines and their Iron Tricarbonyl Complexes. Some Reactions of 2,3-Dihydro-1,2(1H)-Diazepines (1975) (16)
- Adding a Structural Context to the Deprotometalation and Trans-Metal Trapping Chemistry of Phenyl-Substituted Benzotriazole. (2015) (16)
- γ-Silylated α,β-unsaturated amides. Formation by [1,5] silicon migration from O-silylated vinyl ketene aminals and fluoride- and Lewis acid-mediated aldol condensations (1986) (16)
- Ortho-amination of lithiated tertiary benzamides. Short route to polysubstituted anthranilamides (1984) (16)
- Optimization in organic synthesis (1999) (16)
- Synthesis of 2-Substituted Dihydropyran 3-O-Carbamates via Combined Metalation−Suzuki−Miyaura Cross-Coupling Reactions (1998) (16)
- Combined directed ortho Metalation/Suzuki-Miyaura cross-coupling strategies. Regiospecific synthesis of chlorodihydroxybiphenyls and polychlorinated biphenyls. (2007) (16)
- Radiolabeling of monoclonal antibody B43.13 with rhenium-188 for immunoradiotherapy. (1997) (16)
- Re-evaluation of the effect of ellagic acid on dimethylnitrosamine mutagenicity. (1989) (15)
- Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones. (2019) (15)
- Stereoselective Lateral Functionalization of Monosubstituted [2.2]Paracyclophanes by Directed ortho‐Metalation−Homologous Anionic Fries Rearrangement (2001) (15)
- Directed ortho Metalation Reactions of Aryl O-Carbamates; A Regiospecific Synthesis of 2,2-Disubstituted 2H-1-Benzopyrans (2001) (15)
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- Synthesis of Perimidines and 1,5-Benzodiazepines (2013) (0)
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- Silver-Catalyzed Synthesis of Trifluoromethylated Heterocycles (2017) (0)
- Aza-Annulation by C–H Arene Amination with O-Sulfonylhydroxyamines (2016) (0)
- Azetidines, Pyrrolidines, and Indolines via C(sp3)–H and C(sp2)–H Bond Amination (2012) (0)
- Preparation of 2,5-Dihydroazepines from Dienyltriazoles by [4+3] Cycloaddition (2015) (0)
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- Michael Addition–Reductive Lactamization Route to 5-Alkyl-5-aryl-γ-lactams (2014) (0)
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- [3+2]-Cycloaddition Route to Imidazoles and Imidazolines (2019) (0)
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- Auto-Oxidation–Povarov Annulation Approach to Quinolines (2015) (0)
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- Metal-Free Synthesis of Perfluorinated Oxindoles (2015) (0)
- Cobalt-Catalyzed Synthesis of Benzoindol-2-ones from Naphthylamides (2019) (0)
- Di‐(1‐isopropyl‐3‐methylbut‐2‐enyl)borane (i‐PP2B) (2008) (0)
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- A Cloke–Wilson Rearrangement Approach to Fused Bromofurans (2013) (0)
- Phenanthridinones via Benzyne Intermediates Using Palladium Catalysis (2014) (0)
- Modular Rhodium-Catalyzed Synthesis of Quinolines from Anthranils and Acrylic Acids (2020) (0)
- Prins Reaction–Pinacol Rearrangement Route to Oxaspiro[4.5]decan-1-one (2015) (0)
- Ruthenium-Catalyzed Remote C–H Activation of Purines (2018) (0)
- Synthesis of Spiroxindoles by Enantioselective [3+2] Annulation (2015) (0)
- Photocatalytic Synthesis of 8- to 11-Membered Lactams by C–C Bond Cleavage (2018) (0)
- Synthesis of Alkene Carbonates through Carbon Dioxide Fixation Using Perfluorinated Triol Catalysts (2020) (0)
- Modular Synthesis of Unsymmetrically Polysubstituted and Fused Pyridines (2012) (0)
- Photoredox-Promoted Anti-Markovnikov Hydroamination of Nonactivated Olefins (2017) (0)
- Stereoselective Synthesis of Cyclic Ethers by Reductive Cyclization of Alkynols (2018) (0)
- 2-Aryl-3-fluoro-5-silylthiophenes via a [2,3]-Sigmatropic Rearrangement (2013) (0)
- Synthesis of Trifluoromethylated Pyrido[2,3-d]pyrimidinediones (2017) (0)
- Gold-Catalyzed Cyclizations Leading to Indenoazepines and Strained Bicycles (2012) (0)
- Cobalt(III)-Catalyzed Synthesis of Isoquinolinones and Pyridinones by Annulative Vinylene Transfer (2020) (0)
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- Synthesis of Imidazo[1,5-a]pyrazin-8(7H)-ones (2017) (0)
- 1,2,4-Triazines by the Reaction of N-Tosylhydrazones with Aziridines (2017) (0)
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- Synthesis of 3H-Pyrrolo[2,3-c]quinolin-4(5H)-ones Using ToSMIC Derivatives (2014) (0)
- One-Pot ortho-Borylation and Subsequent Cross-Coupling-Reaction (2011) (0)
- Indoloquinolizines from a One-Pot, 12-Step, Three-Component Cascade Reaction (2012) (0)
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- Synthesis of N-Heterocycles via Rhodium(III)-Catalyzed C–H Activation (2014) (0)
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- Rhodium-Catalyzed Synthesis of Furo[2,3-b]pyran-6-ones (2014) (0)
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- β-Lactams from N-Allylamines Using Palladium Catalysis (2014) (0)
- 7-Azaindoles via Rhodium(III)-Catalyzed C–H Activation–Annulative Coupling (2015) (0)
- Palladium-Catalyzed Synthesis of Phenanthridinones by Dual C–H Activation (2016) (0)
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- Synthesis of Heterocyclic Triquinanes via Sequential Radical Cyclizations (2013) (0)
- Organocatalytic Synthesis of Enantioenriched Five- and Six-Membered Cyclic Ureas (2019) (0)
- One-Pot Synthesis of 1,2-Disubstituted Benzimidazoles (2017) (0)
- Organocatalytic Approaches to Highly Functionalized Piperidines (2016) (0)
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- Multicomponent Diastereoselective Synthesis of Tetrahydropyridines in Aqueous Micelles (2016) (0)
- Synthesis of Fluorocoumarins by a Photoredox Reaction (2018) (0)
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- Photoredox Approach to Fluorinated Pyrrolo[1,2-a][1,5]benzodiazepines (2019) (0)
- Synthesis of Pyridazines and Their Fused Derivatives from 1,3-Diketones (2013) (0)
- Efficient Synthesis of 5-Nitro-7-azaindole on a Kilogram Scale (2015) (0)
- Oxazoline Synthesis by Using the XtalFluor-E Reagent (2020) (0)
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- Synthesis of 2-Trifluoromethylquinolines via a [2+3] Cycloaddition (2014) (0)
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- Tetrahydro-1,4-benzodiazepin-2-ones from Ugi MCR Intermediates (2012) (0)
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- Fused Heterocycles by an Amine-Catalyzed aza-Diels–Alder Reaction (2017) (0)
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- Synthesis of Chiral γ-Lactams through Pd(II)-Catalyzed Cascade Alkenylation/Aza-Wacker Cyclization (2020) (0)
- Palladium-Catalyzed Synthesis of Difluoroalkylated Phenanthridines (2016) (0)
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- A Pd-Catalyzed C–H Activation Route to Benzisoxazolones (2012) (0)
- Metal-Free Tandem Oxidative Acylation–Cyclization to Coumarins (2015) (0)
- Synthesis of Perfluoroalkyl Pyrroles and Thiophenes from Cyclopropanes (2014) (0)
- β-Enaminones in the Synthesis of Heterocycles (2017) (0)
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- Synthesis of 1-Benzyl- or 1-Benzoyliso-quinolines by Dehydrogenative Coupling (2016) (0)
- Palladium-Controlled Regioseletive Arylative Cyclization of Alkynols to Cyclic Ethers (2014) (0)
- Mild Regioselective Halogenation of Anilines, Anilides, and Indoles (2020) (0)
- Copper-Catalyzed Synthesis of Substituted 1,4-Oxathianes (2016) (0)
- Isoindoloquinazolinones by Palladium Catalysis (2014) (0)
- Dihydroisocoumarin Synthesis by C–H ortho-Alkylation of Benzoic Acids (2015) (0)
- Direct C-2 Pyridine C–H Olefination (2012) (0)
- Three-Component Synthesis of Fluorinated Pyrazoles (2015) (0)
- Synthesis of Trifluoromethylated Piperazines from Aziridines (2017) (0)
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- Photocatalytic Synthesis of (Trifluoromethyl)phenanthridines (2016) (0)
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- Au(I)-Catalyzed Synthesis of Indole- and Arene-Fused Hexahydroquinolizinones (2012) (0)
- Synthesis of 4-Alkyl-2,3-difluorobut-2-enolides by Cyclization (2014) (0)
- Regioselective Synthesis of CF2H-Containing Pyrazoles (2020) (0)
- Synthesis of Indolizines from 2-(Propargyloxy)pyridines and Methyl Ketones (2019) (0)
- Access to Functionalized Chromanes by Asymmetric [4+2]-Cycloaddition (2020) (0)
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- Synthesis of Oxazolones by a β-Selective Oxidative Heck Coupling (2014) (0)
- Combined Chemoenzymatic Sequence for the Synthesis of γ-Lactones (2020) (0)
- Biaryls from Anilines and Aryl Sulfoxides through Sigmatropic Rearrangement (2020) (0)
- 6-exo-dig Iodocyclization Route to Dihydro-1,3-oxazines (2019) (0)
- C(sp3)–H Functionalization of Aliphatic Acids through β-Lactonization (2020) (0)
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- Synthesis of Pyrrolopyridines from 3-Aminopyrrole (2016) (0)
- Synthesis of Fluoropyrrolidines by Using an Iodine/Hydrogen Fluoride Reagent (2017) (0)
- Gold-Catalyzed Synthesis of Furan-3-ones via [2,3]-Sigmatropic Rearrangement (2013) (0)
- Synthesis of 2,3-Disubstituted Pyridines by Transition-Metal-Free Amination (2017) (0)
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- [3+2] Cycloaddition Route to Imidazopyrrolo-Fused Isoxazoles (2016) (0)
- Asymmetric Paal–Knorr Pyrrole Synthesis (2017) (0)
- Catalyst-Controlled Regioselective C-5 Hetarene Olefination (2020) (0)
- Rh-Catalyzed De Novo Synthesis of Pyridines from Terminal Alkynes and Ketoximes (2012) (0)
- Synthesis of Quinolines from N-Alkyl Anilines and Olefins (2012) (0)
- Access to Quaternary Amino Acids via Dynamic Kinetic Resolution of Azlactones (2013) (0)
- Copper-Mediated Synthesis of Fused Cyclopropylpyrrolidines (2014) (0)
- PIDA-Mediated Intramolecular Oxidative Cyclization of Enamides to Oxazoles (2013) (0)
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- Nickel-Mediated C(sp2)–H Amination: Synthesis of Anthranilic Amides (2018) (0)
- Phosphonium Salts as Surrogates for Aromatic Carbon–Heteroatom Bond Formation (2018) (0)
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- Synthesis of 1,4-Thiazepin-5(4H)-ones without Transition Metals (2014) (0)
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- 2-Picolylamines and Imidazopyridines from Pyridotriazoles by Rh(II) Catalysis (2015) (0)
- Lewis Acid Catalyzed Synthesis of Azepines from Oxiranes and Alkynes (2016) (0)
- Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers (2014) (0)
- Synthesis of Benzodiazepines from Benzimidazolium Salts (2020) (0)
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- Synthesis of Isoxazolino Phenanthridines (2015) (0)
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- Synthesis of Azolopyrimidines through Rhodium-Catalyzed C–H Functionalization (2018) (0)
- Palladium-Catalyzed Oxidative Annulation Route to Benzo[b]furans (2013) (0)
- Synthesis of Epoxides by a Darzens Reaction and Vicarious Nucleophilic Substitution (2017) (0)
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- Synthesis of Isoxazoles from 1,3-Dialkynes and Hydroxylamine (2012) (0)
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- Synthesis of 2‑Aminoquinolines from N‑Acyl‑o‑alkynylanilines (2018) (0)
- Substituted Oxindoles and Dibenzoazepinones through Aryne Insertion (2017) (0)
- Synthesis of Oxazol-2(3H)-ones and Fused Oxazolidones from Ynamides (2018) (0)
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- Potassium Carbonate-Catalyzed Synthesis of Highly Functionalized Indoles (2020) (0)
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- Tetrahydroquinolines by Sulfenoamination of Alkenes (2017) (0)
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- Safe and Efficient Synthesis of 4-Aminofurazan-3-Carboxylic Acid and its Ethyl Ester (2020) (0)
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- Oxepinocoumarins by Ring-Closing Metathesis (2019) (0)
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- Synthesis of Acylated Benzimidazoles with Copper Catalysts (2017) (0)
- Facile Access to Dihydrocoumarins through Catalytic Hydroarylation (2018) (0)
- Pyridazines via an Organophosphorus-Catalyzed Diaza-Wittig Reaction (2014) (0)
- Synthesis of 3-Carboxylated Indoles from 2-Ethynylanilines and CO2 (2012) (0)
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- Benzyne-Mediated Heteroannulation Route to Indolines and Carbazoles (2013) (0)
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- A C–H Bond Alkenylation/Aza-Michael Route to Benzoisothiazole 1-Oxides (2019) (0)
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- PB135 ORTHO-FURANONAPHTHOQUINONES : A SIMPLE ROUTE TO ANGULAR ANALOGS OF NATURAL PARA-FURANONAPHTHOQUINONES (1988) (0)
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- UMLAGERUNG VON 1-PHENYLIMINOPYRIDINIUM-YLIDEN IN 1,6-DIHYDROPYRIDAZIN-DERIVATE (1970) (0)
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- Conversion of N-Sulfonyl Triazoles into Triazole-Fused Isoindolines (2019) (0)
- Synthesis of Benzo[b]thiophenes by Sequential Cyclization Reactions (2015) (0)
- 1,3-Dipolar Cycloaddition to Access Spirocyclic Nitrochromene Derivatives (2019) (0)
- Rhodium(II)-Catalyzed Synthesis of Fused Azepine Derivatives (2015) (0)
- Reactions of a Fluorosulfuryl Cation Donor with Phenols or Amines (2018) (0)
- Multicomponent Synthesis of Thiazepines (2014) (0)
- Organocatalytic Enantioselective Synthesis of Functionalized Piperidines (2012) (0)
- Benzylic Lithiation of 1,3,4-Oxadiazoles in Batch and Continuous Flow (2019) (0)
- Synthesis of Butenolides from Functionalized Cyclopropenones (2020) (0)
- The Directed Metalation Connection to Aryl-Aryl Cross Coupling. Regiospecific Synthesis of Phenanthridines, Phenanthridinones, and the Biphenyl Alkaloid Ismine. (1989) (0)
- Synthesis of Phenanthridines from Diaryliodonium Salts and Nitriles (2014) (0)
- Synthesis of Fused Imidazobenzodiazepinones by Ugi Reaction (2015) (0)
- Intramolecular Aryl–Aryl Coupling of 2-Substituted N-Phenylbenzamides (2014) (0)
- A Scalable Route to N-Difluoromethylated Heterocycles (2020) (0)
- Mild Synthesis of 3H-Indoles and Benzazepinones from Nonactivated Anilines (2020) (0)
- Atom-Efficient Organolanthanide 1,2-Dearomatization of Pyridines (2015) (0)
- β-Phenethylamines and simple isoquinoline alkaloids (1971) (0)
- An Improved Procedure for a Pd-Catalyzed Amidation Approach to Imidazopyridines (2015) (0)
- SN2′/SNV Reactions in the Synthesis of 2-Fluoro-2-pyrrolines (2016) (0)
- Regioselective N-Methyl Carbon Lithiation of N-Boc-Methylalkylamines. Expedient Synthesis of Unsymmetrical Amines. (1994) (0)
- Diels–Alder Cycloaddition Approach to Indoles from Alkynol-Furans (2013) (0)
- Synthesis of Pyrrolidines, Pyrroles, and Carbazoles by Iridium Catalysis (2017) (0)
- Ortho-Metalation of Aromatic Compounds. Novel Methods and Applications in Organic Synthesis (1988) (0)
- Nickel-Catalyzed Asymmetric Synthesis of Axially Chiral Isoquinolones (2015) (0)
- Allylation–Radical Cyclization to Difluoromethylated Dihydrobenzoheteroles (2014) (0)
- Hypervalent Iodine Reagent for the Synthesis of 2-Substituted Indoles (2018) (0)
- THE SYNTHESIS OF 1,2-DIAZEPINES FROM THIAPYRYLIUM SALTS (1974) (0)
- Copper-Mediated Synthesis of 3-Chloro-4-iodoisoxazoles (2015) (0)
- Pyridine Synthesis by 6π-3-Azatriene Electrocyclization (2019) (0)
- Polycyclic Spiroindolines from Asymmetric Dearomatization of Indoles (2015) (0)
- Palladium-Mediated Synthesis of 3,4-Dihydroisoquinoline N-Oxides (2017) (0)
- Synthesis of Propellane, Azetidine, and Cyclobutane Amines (2016) (0)
- Sulfonated β-Cyclodextrin-Catalyzed Synthesis of Imidazopyridinamines (2016) (0)
- One-Pot Synthesis of Isoxazolines (2013) (0)
- Photocatalyzed Synthesis of Sulfonated Isoindolinones (2018) (0)
- Selective Synthesis of 3- or 5-Substituted Aminopyrazoles (2015) (0)
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