Viktoria Däschlein-Gessner
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(Suggest an Edit or Addition)According to Wikipedia, Viktoria Däschlein-Gessner is a German chemist who is the Chair of Inorganic Chemistry II at Ruhr University Bochum. Her research considers organometallic chemistry and catalysis. She has developed ylidic ligands to stabilise reactive main group compounds.
Viktoria Däschlein-Gessner's Published Works
Published Works
- Structure formation principles and reactivity of organolithium compounds. (2009) (190)
- Transition metal borylene complexes. (2013) (163)
- Total synthesis and absolute configuration of the guaiane sesquiterpene englerin A. (2009) (106)
- Ylide‐Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis (2018) (67)
- Remote sensing of in-use heavy-duty diesel trucks. (2006) (64)
- Synthesis of P-stereogenic compounds via kinetic deprotonation and dynamic thermodynamic resolution of phosphine sulfides: opposite sense of induction using (-)-sparteine. (2010) (63)
- Lithiation of TMEDA and its higher homologous TEEDA: understanding observed alpha- and beta-deprotonation. (2008) (61)
- The Bonding Situation in Metalated Ylides (2017) (60)
- A Highly Active Ylide-Functionalized Phosphine for Palladium-Catalyzed Aminations of Aryl Chlorides. (2019) (57)
- Synthesis and bonding in carbene complexes of an unsymmetrical dilithio methandiide: a combined experimental and theoretical study. (2013) (55)
- Crystal structures of the chiral diamine (R,R)-TMCDA with the commonly used alkyllithium bases methyllithium, iso-propyllithium, and sec-butyllithium. (2007) (50)
- From the alkyllithium aggregate [{(nBuLi)2.PMDTA}2] to lithiated PMDTA. (2007) (49)
- Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation. (2011) (49)
- Crystal structures of n-BuLi adducts with (R,R)-TMCDA and the consequences for the deprotonation of benzene. (2008) (49)
- Chiral 2-endo-substituted 9-oxabispidines: novel ligands for enantioselective copper(II)-catalyzed Henry reactions. (2009) (47)
- Stability and reactivity control of carbenoids: recent advances and perspectives. (2016) (44)
- Selective vinyl C-H lithiation of cis-stilbenes. (2009) (42)
- Selective dehydrocoupling of phosphines by lithium chloride carbenoids. (2014) (37)
- From MonomerictBuLi(R,R)-TMCDA to a-Lithiated (R,R)-TMCDA (2007) (37)
- Bridging the Gap between Bisylides and Methandiides: Isolation, Reactivity, and Electronic Structure of an Yldiide. (2015) (37)
- Tetrahedral versus planar four-coordinate carbon: a sulfonyl-substituted methandiide. (2012) (35)
- Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization. (2013) (35)
- Cooperative bond activation reactions with carbene complexes. (2018) (35)
- Substitution effects on the formation of T-shaped palladium carbene and thioketone complexes from Li/Cl carbenoids. (2014) (34)
- Isopropyllithium diamine adducts: from a non symmetric aggregate to monomeric i-PrLi.(1R,2R)-N,N,N',N'-tetraethylcyclohexane-1,2-diamine. (2008) (33)
- Formation of a Palladium Thioketone Complex from a Thiophosphinoyl Stabilized Li/Cl Carbenoid (2011) (33)
- Methandiide as a non-innocent ligand in carbene complexes: from the electronic structure to bond activation reactions and cooperative catalysis. (2014) (32)
- Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties (2017) (32)
- Synthesis and Electronic Structure of Carbene Complexes Based on a Sulfonyl-Substituted Dilithio Methandiide (2014) (30)
- On the structure and ambiphilicity of a sulfonyl substituted α-chloro lithium base. (2014) (29)
- Mechanistic insight into stereoselective carbolithiation. (2011) (29)
- Structure, Bonding, and Reactivity of Room-Temperature-Stable Lithium Chloride Carbenoids (2014) (28)
- Carbene Complexes Based on Dilithium Methandiides: Carbene Complexes Based on Dilithium Methandiides (2015) (27)
- A precoordination complex of 1,2,3-trimethyl-1,3,5-triazacyclohexane with tert-butyllithium as key intermediate in its methylene group deprotonation. (2008) (25)
- Using Ylide Functionalization to Stabilize Boron Cations (2017) (23)
- Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature (2020) (22)
- Ylide-Functionalized Phosphine (YPhos)-Palladium Catalysts: Selective Monoarylation of Alkyl Ketones with Aryl Chlorides. (2019) (22)
- Synthesis and stability of Li/Cl carbenoids based on bis(iminophosphoryl)methanes. (2014) (21)
- Alkali Metal Carbenoids: A Case of Higher Stability of the Heavier Congeners. (2016) (20)
- Lithiation of Diamine Ligands to Chiral Building Blocks: Syntheses, Selectivities, and Lithiated Intermediates (2010) (19)
- Isolation of a Diylide‐Stabilized Stannylene and Germylene: Enhanced Donor Strength through Coplanar Lone Pair Alignment (2019) (19)
- Preparation and Isolation of a Chiral Methandiide and Its Application as Cooperative Ligand in Bond Activation. (2016) (19)
- Metal-Ligand Cooperativity in a Methandiide-Derived Iridium Carbene Complex. (2016) (18)
- Understanding Structure Formation in Organolithium Compounds: An Experimental and Quantum-Chemical Approach† (2013) (18)
- Unraveling the High Activity of Ylide-Functionalized Phosphines in Palladium-Catalyzed Amination Reactions: A Comparative Study with CyJohnPhos and PtBu3 (2019) (18)
- Cooperative P–H Bond Activation with Ruthenium and Iridium Carbene Complexes (2016) (18)
- Si-H activation by means of metal ligand cooperation in a methandiide derived carbene complex. (2015) (17)
- Preparation of "Si-centered" chiral silanes by direct alpha-lithiation of methylsilanes. (2010) (17)
- Unexpected direct dilithiation of a prochiral phosphine borane. (2010) (17)
- Simple is best : Diamine zinc complexes as unexpected catalysts in lactide polymerisation (2013) (16)
- Catalytic Transfer Hydrogenation with a Methandiide-Based Carbene Complex: An Experimental and Computational Study. (2015) (16)
- Coupling of Reformatsky Reagents with Aryl Chlorides Enabled by Ylide‐Functionalized Phosphine Ligands (2021) (16)
- Versatile Modes of Cooperative B-H Bond Activation Reactions in Ruthenium-Carbene Complexes: Addition, Ring-Opening and Insertion. (2018) (16)
- Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis (2018) (15)
- Efficient Pd‐Catalyzed Direct Coupling of Aryl Chlorides with Alkyllithium Reagents (2020) (14)
- Au⋅⋅⋅H−C Hydrogen Bonds as Design Principle in Gold(I) Catalysis (2021) (14)
- Modern Ylide Chemistry: Applications in Ligand Design, Organic and Catalytic Transformations (2018) (14)
- Modern Ylide Chemistry: Applications in Ligand Design, Organic and Catalytic Transformations (2018) (14)
- Cooperative Bond Activation Reactions with Ruthenium Carbene Complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene): Ru═C and N–Si Bond Reactivity (2018) (12)
- Taming Metal/Fluorine Carbenoids. (2017) (11)
- Isolation of the Metalated Ylides [Ph3P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation (2019) (11)
- α‐Lithiated (R,R)‐TMCDA as an Efficient Building Block for the Preparation of Chiral N,N,O Ligands by Asymmetric 1,2‐Addition (2010) (11)
- Selective [2+2] Cycloaddition Reactions of Isocyanates and Thioisocyanates across the M=C Bond in a Ruthenium Carbene Complex (2015) (10)
- One-Pot Ugi/Aza-Michael Synthesis of Highly Substituted 2,5-Diketopiperazines with Anti-Proliferative Properties (2012) (10)
- Lithium Chloride Carbenoids in Bond Activation Reactions (2015) (10)
- Ylide-Functionalization via Metalated Ylides: Synthesis and Structural Properties. (2019) (9)
- Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity (2016) (9)
- Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload. (2011) (9)
- Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos) (2020) (9)
- Formation of specific configurations at stereogenic nitrogen centers upon their coordination to zinc and mercury. (2012) (8)
- Synthesis and Characterization of a Sulfonyl- and Iminophosphoryl-Functionalized Methanide and Methandiide (2016) (8)
- [{(C7H7LiO)6(thf)2(μ-diglyme-κO,κO′)}Li2O]: a μ6-O2– Ion Encapsulating Aryllithium Compound† (2007) (8)
- Mono- and diylide-substituted phosphines (YPhos): impact of the ligand properties on the catalytic activity in gold(i)-catalysed hydroaminations (2019) (7)
- Theoretical and spectroscopic studies on the conformational equilibrium of 9-oxabispidines in solution (2011) (7)
- Formation of Extended 1D and 2D Coordination Polymers in Tetrathioether Complexes of Mercury(II) and Copper(I): Crystal Structures of [{{Ge(CH2SPh)4}HgBr2}n] and [{{Ge(CH2SPh)4}(Cu2l2}}n] (2009) (6)
- Preparation of aminomethyl functionalised silanes via an α-lithiated amine: from their synthesis, stability and crystal structures to stereochemical issues. (2012) (6)
- Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition (2019) (6)
- Ylide-Substituted Phosphines: A Platform of Strong Donor Ligands for Gold Catalysis and Palladium-Catalyzed Coupling Reactions. (2022) (6)
- Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy3P‐C‐SO2Tol]M (M = Li, Na, K) (2020) (5)
- (S)-1,2-Dimethyl-1,1,2-triphenyl-2-(4-piperidiniomethyl)disilane chloride (2008) (5)
- Alkali Metal Chlorine and Bromine Carbenoids: Their Thermal Stability and Structural Properties. (2017) (5)
- A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2. (2020) (5)
- Reactivity and Applications of α-Metalated Ylides (2017) (5)
- Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds (2020) (5)
- Synthesis of Low‐Valent Dinuclear Group 14 Compounds with Element–Element Bonds by Transylidation (2020) (4)
- Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PCcarbeneS Pincer Ligand (2019) (4)
- Synthesis and solid-state structures of gold(I) complexes of diphosphines (2016) (4)
- Remote Sensing of in Use Heavy Duty Diesel Vehicles (2006) (3)
- Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: from inactive to ppm-level catalysis† (2021) (3)
- (1R,2R)-N,N′-Dimethylcyclohexane-1,2-diamine (2008) (3)
- Diphenyl[2-(phenylsulfonyl)propan-2-yl]-λ5-phosphanethione (2012) (3)
- Structure Formation Principles and Reactivity of Organolithium Compounds (2009) (3)
- Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes (2020) (3)
- Single‐Site and Cooperative Bond Activation Reactions with Ylide‐Functionalized Tetrylenes: A Computational Study (2021) (2)
- Diphenyl[(phenylsulfanyl)methyl]-λ5-phosphanethione (2014) (2)
- Transition metal–free ketene formation from carbon monoxide through isolable ketenyl anions (2022) (2)
- Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone: Angle Dependence of the Donor Strength (2021) (2)
- Ylide‐Stabilized Phosphenium Cations: Impact of the Substitution Pattern on the Coordination Chemistry (2021) (2)
- 2-[(2-Hydroxy-2,2-diphenylethyl)(methyl)amino]-N,N-dimethylethanaminium bromide (2009) (2)
- Carbene Complexes Based on Dilithium Methandiides (2015) (2)
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl- and Amino-Substituted Metallated Ylide. (2021) (1)
- Computer-Driven Development of Ylide Functionalized Phosphines for Palladium-Catalyzed Hiyama Couplings. (2022) (1)
- Carbenoid‐Mediated Formation and Activation of Element‐Element and Element–Hydrogen Bonds (2020) (1)
- Carbon Dioxide Catalyzed Cyclometallation of a Carbene Complex: Synthesis and Mechanism (2019) (1)
- (2,2-Dichlorovinyl)ferrocene (2009) (1)
- Selective B(C6F5)3-Catalyzed Reactions of α-Diazoesters with Heterocycles and Alkenes (2020) (1)
- Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide (2021) (1)
- Palladium-Catalyzed Arylation of Hydantoins with Aryl Chlorides Enabled by Ylide-Functionalized Phosphines (YPhos) (2023) (0)
- Quantum Chemistry The Bonding Situation in Metalated Ylides (2017) (0)
- Tritiation gets selective (2022) (0)
- Formation of exceptional monomeric YPhos–PdCl2 complexes with high activities in coupling reactions (2022) (0)
- Coordination Chemistry of Methandiides and Related Ligands (2021) (0)
- Regioselective Deprotonation of cis-Stilbenes (2009) (0)
- CCDC 794673: Experimental Crystal Structure Determination (2010) (0)
- The Complex‐Induced Proximity Effect in Organolithium Chemistry and Its Importance in the Lithiation of Tertiary Amines (2010) (0)
- Methandiide as a Non‐innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis. (2015) (0)
- From monomeric tBuLi(R,R)-TMCDA to alpha-lithiated (R,R)-TMCDA. (2007) (0)
- Cover Feature: Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature (Chem. Eur. J. 19/2020) (2020) (0)
- Transition Metal Borylene Complexes (2013) (0)
- Inside Back Cover: Alkali Metal Carbenoids: A Case of Higher Stability of the Heavier Congeners (Angew. Chem. Int. Ed. 27/2016) (2016) (0)
- From Stable PH‐Ylides to α‐Carbanionic Phosphines as Ligands for Zwitterionic Catalysts (2022) (0)
- Tuning Ruthenium Carbene Complexes for Selective P−H Activation through Metal‐Ligand Cooperation (2021) (0)
- Cover Picture: Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis (Angew. Chem. Int. Ed. 39/2018) (2018) (0)
- Synthesis, structure and thermal stability of a crown ether complexed K/Cl carbenoid (2017) (0)
- Synthesis of Sterically Encumbered Di- and Triarylamines by Palladium-Catalysed C-N Coupling Reactions at Mild Reaction Conditions (2022) (0)
- Carbene Complexes Based on Dilithium Methandiides (Eur. J. Inorg. Chem. 11/2015) (2015) (0)
- Stability and Reactivity Control of Carbenoids: Recent Advances and Perspectives (2016) (0)
- Carbene complex formation versus cyclometallation from a phosphoryl-tethered methanide ruthenium complex (2020) (0)
- Front Cover: Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide (ChemistryOpen 11/2021) (2021) (0)
- Titelbild: Ylide-Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis (Angew. Chem. 39/2018) (2018) (0)
- Back Cover: Taming Metal/Fluorine Carbenoids (Chem. Eur. J. 11/2017) (2017) (0)
- Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PCylideN pincer ligand (2023) (0)
- Selective Vinyl C—H Lithiation of cis‐Stilbenes. (2009) (0)
- Reaction of lithium hexamethyldisilazide (LiHMDS) with water at ultracold conditions. (2022) (0)
- Solvation Effects on the Structure and Stability of Alkali Metal Carbenoids (2020) (0)
- Innenrücktitelbild: Alkali Metal Carbenoids: A Case of Higher Stability of the Heavier Congeners (Angew. Chem. 27/2016) (2016) (0)
- Synthesis of Engerlin A (2010) (0)
- Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and Csp3–H Activation (2020) (0)
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