Warren Roper
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New Zealand chemist
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Chemistry
Warren Roper 's Degrees
- Bachelors Chemistry University of Auckland
- Masters Chemistry University of New Zealand
- PhD Chemistry Victoria University of Wellington
Why Is Warren Roper Influential?
(Suggest an Edit or Addition)According to Wikipedia, Warren Richard Roper FRS FRSNZ FNZIC is a New Zealand chemist and Emeritus Professor at the University of Auckland. Roper was educated at Nelson College from 1952 to 1956, and was dux in his final year. He then studied chemistry at the University of Canterbury, and undertook his PhD under the supervision of CJ Wilkins. He completed his PhD in 1963, and spent three years undertaking postdoctoral research at the University of North Carolina in the United States before returning to New Zealand. At that point Roper was appointed as lecturer at the University of Auckland, where he remained until his retirement .
Warren Roper 's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Transition Metal−Boryl Compounds: Synthesis, Reactivity, and Structure (1998) (409)
- Transition-metal dihalocarbene complexes (1988) (161)
- Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh3)2] (1982) (141)
- Platinum group metals in the formation of metal–carbon multiple bonds (1986) (113)
- Oxidative-Addition Reactions of d8 Complexes (1969) (102)
- Organometallic models for possible Fischer-Tropsch intermediates. Synthesis, structure, and reactions of a formaldehyde complex of osmium (1979) (100)
- A mononuclear, low-valent, electron-rich osmium methylene complex (1983) (97)
- Preparation and Oxidative Addition Reactions of a Monomeric Ruthenium(0) Complex (1965) (93)
- Carbene and Carbyne Complexes of Ruthenium, Osmium, and Iridium (1986) (91)
- Activation of 2-propyn-1-ol derivatives by (arene)ruthenium(II) complexes: new route to (alkenylcarbene)- and (polyenylcarbene)-metal complexes (1992) (86)
- An osmium-carbyne complex (1980) (75)
- STEPWISE REDUCTION OF THE THIOCARBONYL LIGAND- HYDRIDE TRANSFER TO CS- THIOFORMYL, THIOFORMALDEHYDE, METHYLTHIOLATO, SECONDARY CARBENE, FORMYL AND IMINOFORMYL COMPLEXES OF OSMIUM (1978) (70)
- Tethered Boryl and Base-Stabilized Borylene Osmium Complexes from the Reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-Aminopyridine (2002) (67)
- An Osmabenzofuran from Reaction between Os(PhC⋮CPh)(CS)(PPh3)2 and Methyl Propiolate and the C-Protonation of this Compound to Form a Tethered Osmabenzene (2006) (62)
- Carbonyl, thiocarbonyl, selenocarbonyl, and tellurocarbonyl complexes derived from a dichlorocarbene complex of osmium (1980) (57)
- Stable Cationic and Neutral Ruthenabenzenes (2009) (56)
- Cationic cyclic carbene complexes of iridium(III), nickel(II), palladium(II), and platinum(II) (1974) (56)
- A Stable Iridabenzene Formed from an Iridacyclopentadiene Where the Additional Ring-Carbon Atom Is Derived from a Thiocarbonyl Ligand (2008) (54)
- Regioselective Mono-, Di-, and Trifunctionalization of Iridabenzofurans through Electrophilic Substitution Reactions (2011) (52)
- Synthesis and Oxidative Addition Reactions of a Phosphine Carbonyl Complex of Osmium(0)1 (1966) (44)
- Carbene complexes of iridium, rhodium, manganese, chromium, and iron containing thiazolidinylidene and pyridinylidene ligands (1974) (44)
- Anisotropic Electron Transport in Compounds Containing Polymeric Metal-Metal Bonds1 (1966) (43)
- Iridium(III) S-Sulfinates. Preparation of an Iridium(III) Aryl (1966) (42)
- Thermal Rearrangement of Osmabenzenes to Osmium Cyclopentadienyl Complexes (2010) (40)
- Pentacoordinate iridium(I) and rhodium(I) complexes derived from metal carbonyl anions (1968) (40)
- Synthesis, structure and reactions of a dihapto-formaldehyde complex, Os(η2-CH2O)(CO)2(PPh3)2 (1982) (40)
- Reaction between the thiocarbonyl complex, Os(CS)(CO)(PPh3)3, and propyne: crystal structure of a new sulfur-substituted osmabenzene (2001) (39)
- Reactions of cis and trans Bcat, Aryl Osmium Complexes (cat = 1,2-O2C6H4). Bis(Bcat) Complexes of Osmium and Ruthenium and a Structural Comparison of cis and trans Isomers of Os(Bcat)I(CO)2(PPh3)2 (2000) (39)
- CRYSTAL STRUCTURE OF OS(BCAT)CL(CO)(PPH3)2 AND THE SYNTHESES AND STRUCTURAL STUDIES OF DERIVED CATIONIC AND NEUTRAL OSMIUM BORYL COMPLEXES (1998) (36)
- The Nature of the Metal—Silicon Bond in [M(SiR3)H3(PPh3)3] (M = Ru, Os) And the Crystal Structure of [Os{Si(N-pyrrolyl)3}H3(PPh3)3] (1997) (36)
- Direct nitration of aryl groups σ-bound to ruthenium(II) (1994) (35)
- Cationic cyclic carbene or carbon-bonded ylide complexes of iridium(III) and platinum(II) (1973) (35)
- Tethered osmium boryl complexes from the reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-hydroxypyridine (2002) (35)
- Reactions of osmium coordinated formaldehyde. Synthesis of complexes of selenoformaldehyde and telluroformaldehyde (1983) (35)
- The diosmium tetrahydroxydisiloxane, [OsCl(CO)(PPh3)2Si(OH)2]2O from the coordinatively unsaturated trihydroxysilyl complex, Os(Si[OH]3)Cl(CO)(PPh3)2 (1992) (34)
- Bromination and nitration reactions of metallated (Ru and Os) multiaromatic ligands and crystal structures of selected products (2000) (34)
- Oxidation state control of the reactivity of a transition metal–carbon double bond. Synthesis, X-ray crystal structure, and reactions of the zerovalent difluorocarbene complex [Ru(CF2)(CO)2(PPh3)2] (1983) (32)
- Syntheses and structures of the chalcocarbonyl complexes OsCl2(CO)(CE)(PPh3)2 (E = S, Se, Te) (1988) (32)
- The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2 (1999) (32)
- First Metallabenzenes and now a Stable Metallabenzyne. (2001) (31)
- Trifluoromethyl, difluorocarbene and tetrafluoroethylene complexes of iridium and the crystal structures of IrI(CH3)(CF3)(CO)(PPh3)2, Ir(CF3)(C2F4)(CO)(PPh3)2 and Ir(CF3)(CF2)(CO)(PPh3)2 (1990) (31)
- Hydrogen transfer from HCl to the nitrosyl ligand. Examples of co-ordinated HNO, NHOH-, and NH2OH (1970) (31)
- Coordinatively unsaturated σ-aryl complexes of ruthenium(II) and osmium(II) (1990) (30)
- Difluorocarbene complexes of ruthenium derived from trifluoromethyl compounds. RuCl2(CF2)(CO)(PPh3)2, RuCl2(CFNMe2)(CO)(PPh3)2, RuCl2(CFOMe)(CO)(PPh3)2 and the structure of Ru(CF3)(HgCF3)(CO)2(PPh3)2 (1982) (30)
- Ru(CO)2(PPh3)3 and Os(CO)2(PPh3)3. An ethylene complex of ruthenium and a dioxygen complex of osmium (1972) (30)
- Five and six CO-ordinate σ-aryl derivatives of Ru(II) and Os(II) and the equilibrium RuRX(CO)2 (PPh3)2⇄ Ru[C(O)R]X(CO) (PPh3)2 (1977) (30)
- Synthesis of transition metal—heterocyclic carbene complexes. Oxazol-2-ylidene and oxazolidin-2-ylidene complexes of osmium(II) derived from coordinated tosylmethylisocyanide (1975) (29)
- Dinitrosyl complexes of rutheninm and osmium and their reaction with oxygen (1970) (29)
- Preparation of octahedral hydrido-aquo-ruthenium(II) complexes, and structural characterisation of hydridoaquodicarbonylbis(triphenylphosphine)-ruthenium(II) tetrafluoroborate (1981) (29)
- Synthesis and some reactions of a terminal carbyne complex of osmium. Crystal structures of Os(CR)Cl(CO)(PPh3)2 and Os(C[AgCl]R)Cl(CO)(PPh3)2 (1986) (29)
- Preparation and reactivity of some .eta.2-S2 and .eta.2-Se2 complexes of osmium and the x-ray crystal structure of Os(.eta.2-Se2)(CO)2(PPh3)2 (1979) (29)
- An Osmium Containing Benzene Analog, Os(CSCHCHCHCH)(CO)(Pph3)2, Carbonyl(5‐Thioxo‐1, 3‐Pentadiene‐1, 5‐Diyl‐C1, C5, S)‐Bis(Triphenylphosphine)Osmium, and its Precursors (2007) (28)
- Quaternization of the Bridgehead Nitrogen in Silatranylosmium(II) Complexes and Reestablishment of the Transannular N−Si Bond following Migratory Insertion of the Silatranyl Ligand (1998) (28)
- Synthesis and Structures of cis- and trans-[Os(Bcat)(aryl)(CO)2 (PPh3 )2 ]: Compounds of Relevance to the Metal-Catalyzed Hydroboration Reaction and the Metal-Mediated Borylation of Arenes. (1999) (28)
- Terminal phosphido complexes of ruthenium(II) and osmium(II): synthesis, reactivity, and crystal structures of Os(PHPh)Cl(CO)2(PPh3)2 and Os{PH(OMe)Ph}(CO)2(PPh3)2 (1986) (27)
- Compounds with ruthenium-silicon and osmium-silicon bonds (1990) (27)
- Coordinated carbon monoselenide and carbon diselenide. preparation and structure of the mixed carbonyl—selenocarbonyl complex, RuCl2(CO)(CSe)(PPh3)2 (1975) (26)
- A 2-iridafuran from reaction between a 1-iridaindene and methyl propiolate (2006) (25)
- Reactions of the dichloroboryl complex of osmium, Os(BCl2)Cl(CO)(PPh3)2, with water, alcohols, and amines: Crystal structures of Os[B(OH)2]Cl(CO)(PPh3)2, Os[B(OEt)2]Cl(CO)(PPh3)2, and Os[BN(CH3)C6H4N(CH3)]Cl(CO)(PPh3)2 (2003) (25)
- Dihapto-acyl derivatives of ruthenium(II). Preparation and structure of Ru[η2-C(O)CH3] I(CO)(PPh3)2 and Ru[η2-C(O)p-tolyl]I(C0) (PPh3) 2 (1979) (24)
- 2,2'-Dipyridyl Adducts of the Group VB Trihalides and Their Ionization (1964) (24)
- Migratory-insertion reactions involving the thiocarbonyl ligand. dihapto-thioacyl complexes from the rearrangement of arylthiocarbonyl complexes of osmium(II). Structure of Os(η2-CSR)(η1-O2CCF3)(CO)(PPh3)2 (1983) (24)
- The tris(triphenylphosphine)osmium zerovalent complexes Os(CO)2(PPh3)3, .Os(CO)(CNR)(PPh3)3, Os(CO)(CS)(PPh3)3, Os(CS)(cNR)(PPh3)3 and derived compounds (1982) (24)
- A 2-iridathiophene from reaction between IrCl(CS)(PPh3)2 and Hg(CHCHPh)2 (2005) (24)
- 680. Bipyridyl and terpyridyl complexes from halides of Group IVB elements (1965) (23)
- Stepwise Conversion of an Osmium Trimethylstannyl Complex to a Triiodostannyl Complex and Nucleophilic Substitution Reactions at the Tin−Iodine Bonds (2000) (23)
- Oxidative additions to nitrosyltris(triphenylphosphine)iridium(-I). Five-co-ordinate methyl–nitrosyl and hydrido–nitrosyl derivatives of iridium(I) (1970) (23)
- Preparation and properties of nitrosyl complexes of ruthenium(0) (1970) (22)
- Oxidation of alcohol to co-ordinated carboxylate with a dioxygen complex of ruthenium. Examples of reversible hydrogen transfer to an isocyanide ligand (1972) (22)
- Members of the series IrX(CO)(PPh3)2 with various anionic ligands and their dioxygen complexes (1973) (22)
- Nucleophilic substitution reactions at the Si–Cl bonds of the dichloro(methyl)silyl ligand in five- and six-coordinate complexes of ruthenium(II) and osmium(II) (2004) (22)
- Stable terminal methylene complexes of osmium(II) and ruthenium(II). The unexpected preferential migration of aσ-aryl ligand to carbon monoxide rather than to methylene (1988) (22)
- Oxidative addition of Group 14 hydrides to osmium(O), osmium(II) and ruthenium(O) complexes. Crystal structures of Os(SiEt3)H(CO )2 (PPh3) 2 and Os(Ge[p-tolyl]3) H(CO) 2(PPh3) 2 (1993) (21)
- Tethered silyl complexes from nucleophilic substitution reactions at the Si–Cl bond of the chloro(diphenyl)silyl ligand in Ru(SiClPh2)(κ2-S2CNMe2)(CO)(PPh3)2 (2004) (21)
- The interaction of an osmium-carbon triple bond with copper(I), silver(I) and gold(I) to give mixed dimetallocyclopropene species and the structures of Os(AgCl) (CR) Cl(CO) (PPh3)2 (1980) (20)
- Examination of Metal−Silicon Bonding through Structural and Theoretical Studies of an Isostructural Set of Five-Coordinate Silyl Complexes, Os(SiR3)Cl(CO)(PPh3)2 (R = F, Cl, OH, Me) (1997) (20)
- Migration of a hydride ligand to a difluorocarbene ligand bound to rhodium. The synthesis and crystal structure of RhCl2(CF2H)(PPh3)2 (1990) (20)
- Thiocarbonyl, h2;-dithiomethyl ester, and dithiocarbene complexes derived from carbon disulphide complexes of ruthenium and osmium (1975) (20)
- Syntheses and reactions of the carbyne complexes, M(CR)Cl(CO)(PPh3)2 (M=Ru, Os; R=1-naphthyl, 2-naphthyl). The crystal structures of [Os(C-1-naphthyl)(CO)2(PPh3)2]ClO4, Os(CH-2-naphthyl)Cl2(CO)(PPh3)2, and Os(2-naphthyl)Cl(CO)2(PPh3)2 (1998) (20)
- Reactions of a dichlorocarbene-ruthenium complex, RuCl2(CCl2)(CO)(PPh3)2 (1982) (20)
- Migratory-insertion reactions of osmium(II) ehtyl complexes derived from an osmium(O) ethylene complex (1981) (20)
- The synthesis of nitrosyl-thiocarbonyl complexes of osmium (1986) (19)
- Alkoxide-ion attack at the nitrosyl group of [IrCl3(NO)(PPh3)2]+ to give alkyl nitrite complexes of iridium(III) (1972) (19)
- Silatranyl, hydride complexes of osmium(II) and osmium(IV): crystal structure of Os(Si{OCH2CH2}3N)H3(PPh3)3 (2000) (19)
- Coordinatively unsaturated stannyl complexes of ruthenium(II) via a new synthetic route involving vinylstannanes: molecular structure of Ru(SnMe3)Cl(CO)(PPh3)2 (1993) (19)
- Exchange of boryl ligand substituents in Os[B(OEt)2]Cl(CO)(PPh3)2 (2004) (19)
- Metallacyclobutadiene complexes from ligand combination of cs and acetylene on osmium (1983) (19)
- Rearrangement of σ-aryl-thiocarbonyl complexes to dihapto-thioacyl complexes. (1978) (19)
- Synthesis, structure, and reactions of a bimetallacyclic carbene complex of ruthenium, Br2(CO)[C(C6H4PPh2)2] (1990) (18)
- Alkoxide attack at carbonyl and hydrosulphide attack at isocyanide in the mixed carbonyl-isocyanide cation [OsCl(CO)2(CNR)(PPh3)2]+. A new synthesis of π-bound isothiocyanate (RNCS) complexes (1976) (18)
- Phosphine (PH3) complexes of ruthenium, osmium and iridium as precursors of terminal phosphido (PH2) complexes and the crystal structure of [Os(μ2-PH2) Cl(CO) (PPh3)2]2 · (C2H2Cl4)4 (1988) (18)
- Neutral, cationic, and dicatinic ruthenium(II) complexes of the secondary carbenes CHNH(p-C6H4CH3) and CHN(CH3)(p-C6H4CH3) (1974) (17)
- Isocyanide complexes of zerovalent ruthenium. Proton addition to a transition-metal base offering alternative base sites (1971) (17)
- Thioformyl and formyl complexes of osmium(II) (1977) (17)
- Migratory insertion of silyl and thiocarbonyl ligands on ruthenium and osmium to give the .eta.2-silathioacyl complexes M(.eta.2-C[S]SiMe2X)Cl(CO)(PPh3)2 (M = Ru, Os; X = Cl, OEt) (1992) (17)
- Dioxygen complexes of ruthenium as homogeneous catalysts for the oxidation of triphenylphosphine (1972) (17)
- Synthesis of monomercurated N-protected pyrroles and the use of these compounds as pyrrolyl group transfer reagents to ruthenium and osmium. Crystal structures of (2-C4H3NC[O]CH3)HgCl, (2-C4H3NC[O]CH3)2 Hg and (1995) (16)
- Four-co-ordinate iridium(I) cations and the ligand dependence of oxygen uptake: the crystal structure of [Ir(PPh2CH3)4]BF4 (1971) (16)
- Sulfene-transition metal complexes from SO2 addition to terminal methylene complexes of osmium(0) and iridium(I). Structure of )Cl(NO)(PPh3)2 (1984) (15)
- Metallacyclic complexes with ortho-silylated triphenylphosphine ligands, LnOs(κ2(Si,P)-SiMe2C6H4PPh2), derived from thermal reactions of the coordinatively unsaturated trimethylsilyl, methyl complex, Os(SiMe3)(Me)(CO)(PPh3)2 (2005) (15)
- Synthesis of low-valent thiocarbonyl complexes 1,2-elimination of methylthiol from -metal-hydrido-dithiomethylester complexes. Os(cs)(CO)2(PPh3)2 and IrCl(CS)(PPh3)2. (1976) (15)
- Octahedral carbyneosmium(II) complexes (1983) (15)
- The iridium(I) cation, [Ir(CO)(CH3CN)(PPh3)2]+ and its substitution reactions (1973) (15)
- Geometrical isomerism arising from C,S- or C,Se- coordination of carbon selenide sulphide and the conversion of a thiocarbonyl ligand to a selenocarbonyl ligand (1980) (15)
- A four-membered osmium metallocycle from inter-ligand reaction between thiocarboxamido- and thiocarbonyl ligands. Structure of NMeptolyl)H(CO) (PPh3)2. (1977) (15)
- A terminal methylene complex of iridium(I), Ir(=CH2)I(CO)(PPh3)2, and rearrangement to an ortho-metallated phosphorus ylide complex, Ir(CH2PPh2C6H4)HI(CO)(PPh3) (1984) (15)
- Similarities and Contrasts Between Silyl and Stannyl Derivatives of Ruthenium and Osmium (2006) (14)
- Acylphosphido and η2-phosphaalkenyl complexes of osmium (1988) (14)
- Selenocarbonyl complexes of iridium(I) and iridium(III). Synthesis and reactions of IrCl(CSe)(PPh3)2 (1983) (14)
- Trifluoromethyl and mixed hydrido trifluoromethyl complexes of iridium(III) as potential precursors of an iridium(I) trifluoromethyl complex (1986) (14)
- Synthesis and reactions of Ru(CH2)Cl(NO)(PPh3)2, a stable terminal methylene complex and the crystal structure of Ru(CH2PPh3)(η2-C2F4)Cl(NO)(PPh3) (1991) (14)
- A dihapto-iminoacyl derivative of ruthenium(II). Synthesis and structure of RU[η2-C(NR)R]Cl(CO)(PPh3)2 (1978) (14)
- Terminal methylene complexes of ruthenium(II) and osmium(II) and intramolecular methylene and acyl ligand combination to form metallaoxetenes: the crystal structures of [OsCl(η2-C[O]-o-tolyl)(CH2)(PPh3)2] and [Ru(C[Ph]OCH2)(CN-p-tolyl)2(PPh3)2]ClO4 (1987) (14)
- Synthesis of Metal-Metal Bonds via Iridium and Rhodium Anions1 (1966) (14)
- Hydrido-complexes of osmium(II) by protonation of tricarbonylbis(triphenylphosphine)osmium(0) (1969) (13)
- The geometry of nitrosyl ligands. Preparation, reactions, and X-ray structure determination of [Os(NO)(CO)2(PPh3)2]+ (1972) (13)
- Organotransition metal substituted primary phosphines : osmium phosphido (PH2) complexes (1990) (13)
- Synthesis and molecular structure of the first monomeric (thiohydroxy)stannyl ruthenium complex, Ru(SnMe2SH)I(CO)(CN[p-tolyl])(PPh3)2 (1993) (13)
- Synthetic routes to terminal phosphido complexes of Group VIII (8) metals: neutral and cationic complexes of phenyl- and diphenylphosphine (1986) (13)
- Cyclometallated complexes of ruthenium and osmium containing the o-C6H4PPh2 ligand (2000) (13)
- Electrophilic addition of an osminim-bound chloromethylene ligand to the benzene ring of a triphenylphosphine ligand. Synthesis of metallacyclic and metallabicyclic complexes. X-Ray structures of [OsCl(CO)2(o-PPh2C6H4CHCl)(PPh3)] and [OsCl(CO)2(o-PPh2C6H4CHC6H4PPh2-o)] (1984) (13)
- Combined decarboxylation of the formato ligand and reductive elimination of hydrido and aryl groups in the synthesis of ruthenium(0) complexes. Methylation of ruthenium(0) with formaldehyde (1982) (13)
- Synthesis, structure, and reactions of IrCl3(CCl2)(PPh3)2, A compound with an iridium-carbon double bond (LnIrCCl2) (1982) (13)
- Seven-coordinate dioxygen complexes from dioxygen addition to five-coordinate σ-phenyl, isocyanide-containing derivatives of ruthenium(II) and osmium(II). Crystal structures of OS(η2-O2)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2 and Os(η2-SO4)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2 (1996) (13)
- Co-ordinated thioformaldehyde monomer. Synthesis and Reactions of [Os(η2-CH2S)(CO)2(PPh3)2] (1977) (13)
- Tris(N-pyrrolyl)phosphine complexes of osmium(II) and osmium(0) (2002) (13)
- Tetrafluoroethyl complexes of iridium(III) derived from a tetrafluoroethylene complex of iridium(I). A study of α-fluoride abstraction and determination of the structure of IrCl2(CF2CF2Cl)(CO)(PPh3)2 (1994) (12)
- Syntheses and structures of dimethylamino-bridged bis(silylene)ruthenium and -osmium complexes (2002) (12)
- Acid−Base Control of a Migratory Insertion Reaction: p-Aminophenyl Derivatives of Ruthenium(II) and the Crystal Structure of Ru(η2-C[O]C6H4NH2-4)Cl(CO)(PPh3)2 (1997) (12)
- 405. Iodides of osmium and rhenium (1962) (12)
- Hydrogen reduction of co-ordinated carbon monosulphide in [IrH(CS)(PPh3)3] to the methanethiolato-ligand and an iridium thioformyl compound [Ir(CHS)Cl2(CO)(PPh3)2] (1977) (12)
- Preparation and structure of the secondary carbene complex RuI2[CHN(CH3)(p-CH3C6H4)](CO)(CN-p-CH3C6H4)(PPh3) (1974) (12)
- A fluorochlorocarbene complex of osmium, OsCl2(CFCI)(CO)(PPh3)2 and the structure of a fluoroalkoxycarbene complex of ruthenium, RuCl2(CFOCH2CMe3)(CO)(PPh3)2 (1984) (12)
- Structure of a η2-dithiomethylester-ruthenium(II) complex and further reactions of a η1-dithiomethylester-ruthenium (II) complex (1977) (11)
- An unusual vinylidene complex from hydride addition to the aromatic ring of the tolyl—carbyne ligand in a cationic osmium carbyne complex (1980) (11)
- Metallacyclic complexes with ortho-stannylated triphenylphosphine ligands, LnOs(κ2(Sn,P)-SnMe2C6H4PPh2), derived from thermal reactions of the five-coordinate complex, Os(SnMe3)Cl(CO)(PPh3)2 (2005) (11)
- Synthesis of 2-pyrrolyl complexes of ruthenium and osmium via hydrolysis of a chloro(pyrrolyl)carbene ligand or via transmetalation reactions using (2-pyrrolyl)mercuric chloride (1994) (11)
- Neutral and cationic dithiocarbonyl complexes of osmium(II) (1977) (11)
- Synthesis and structure of osmium and ruthenium complexes containing tetrafluoroethylene and maleic anhydride as ligands (1990) (11)
- Further stable models for catalytic intermediates. cis-Hydrido(acetyl)-, cis-hydrido(methyl)-, and cis-hydrido(hydridoxymethyl)-osmium(II) complexes (1980) (11)
- Electron diffraction investigation of the molecular structure of N-methylaminotrimethylsilane (1962) (11)
- Syntheses and reactions of coordinatively unsaturated silyl, aryl osmium(II) complexes and the crystal structures of Os[Si(OEt)3]R(CO)(PPh3)2 and Os[Si(OEt)3]R(CO)2(PPh3)2 (R=phenyl or o-tolyl) (2001) (10)
- Synthesis and structure of an ortho-metallated ketazine complex of osmium, OsH(CO)2[(C6H3-p-Me)(p-tolyl)CNNC(p-tolyl)2](PPh3) (1990) (10)
- [Os(η2-PHS)(CO)2(PPh3)2], a Stable η2-Thioxophosphane(HPS)-Metal Complex† (1988) (10)
- Preparation and crystal structure of dichloro(chloromercury)(nitrosyl)bis(triphenylphosphine)osmium(II) (1970) (10)
- Tritium exchange using homogeneous hydrogenation catalysts: I. Chlorotris(triphenylphosphine)rhodium(l) as a hydrogen-exchange catalyst (1967) (10)
- Phenyl derivatives of mercury functionalised in the 2-position with either a formyl or a vinyl group. Crystal structures of Hg[C6H4(CHO)-2]Cl and Hg[C6H4(CHCH2)-2]2 (2001) (10)
- Thiocarbonyl complexes of ruthenium(II). Synthesis of RuCl2(CS)(H2O)(PPh3)2 and RuHCl(CS)(PPh3)3 (1983) (10)
- Syntheses, reactions, and structures of osmium(II) stannyl complexes with the simple stannyl ligands SnH3, SnH2Me, and SnHMe2 (2007) (9)
- Coupling versus substitution of coordinated ethylene with iminooxosulfanes: crystal structure of [Os{CH2CH2S(NSO2C6H4Me-4)O}Cl(NO)(PPh3)2] (1989) (9)
- Catalytic oxidation of triphenylphosphine using a ruthenium–oxygen complex (1970) (9)
- Reversible methyl group migration between osmium and tin in reactions of osmium trimethylstannyl complexes (1999) (9)
- Cyclic transition-metal carbene complexes from ring-closing reactions on the π-bound substrates CS2 and CSe2. 1,3-Dithiolan-2-ylidene and 1,3-diselenolan-2-ylidene complexes of ruthenium(II) and osmium(II) (1976) (9)
- An α-diazoalkylosmium complex as carbyne-complex precursor. Synthesis and X-ray crystal structure of [OsCl(I)(NO)(PPh2C6H4CHCO2Et)(PPh3)], the product of an intramolecular carbyne insertion reaction (1984) (9)
- Oxidative addition reactions of an iridium nitrosyl compound (1969) (9)
- Synthesis and reactivity of coordinatively unsaturated osmium and ruthenium stannyl complexes (1995) (8)
- Reactions of coordinated phosphorus trichloride, phenylphosphonus dichloride, 1-phenyl-3,4- dimethylphosphole and mesitylphosphine in osmium(II) complexes (1991) (8)
- Four- and five-co-ordinate nitrosyl complexes of iridium(I) (1973) (8)
- [Os(η2‐PHS)(CO)2(PPh3)2], ein stabiler η2‐Thioxophosphan(HPS)‐Metallkomplex (1988) (8)
- Crystal structure of the maleic anhydride complex Ru(η2-C4H2O3)(CO)(CN-p-tolyl)(PPh3)2 (1989) (7)
- Selective Substitution of One of the Substituents on Germanium in Coordinatively Unsaturated Ruthenium Germyl Complexes (2012) (7)
- Synthesis of an osmium(II) complex with the PIPh ligand and a possible terminal phenylphosphinidene complex intermediate from iodide abstraction (1984) (7)
- Syntheses and structural studies of five- and six-coordinate o-halophenyl derivatives of ruthenium(II) and osmium(II) (2000) (7)
- On the supposed iridium–gold compound Cl2(CO)(PPh3)2Ir·Au(PPh3) (1970) (7)
- Osmium complexes containing either chelating or non-chelating 8-quinolyl ligands (1997) (6)
- Dioxygen oxidation of a carbonyl ligand to form a chelating peroxycarbonyl ligand: synthesis, structure, and reactions of Cl(NO)(PPh3)2 (2004) (6)
- A cyclic osmastannyl complex, Os(κ2(Sn,P)-SnMe2C6H4PPh2)(κ2-S2CNMe2)(CO)(PPh3) derived from the osmastannol complex, Os(SnMe2OH)(κ2-S2CNMe2)(CO)(PPh3)2 (2005) (6)
- Synthesis and structure of Os(η2-3,3-diphenylcyclopropene)Cl(NO)(PPh3)2 and the ring-opening reactions of the π-bound cyclopropene with acids (2006) (6)
- Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(CC10H8)(CO)2(PPh3)2 (1998) (6)
- [IrCl(NO)(PPh3)2]+: a nitrosyl analogue of IrCl(CO)(PPh3)2 (1969) (6)
- The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]☆ (1991) (6)
- Carbonylchlorido(1-methylsulfanylpenta-1,3-dien-1-yl-5-ylidene)bis(triphenylphosphane)osmium(II) (2009) (6)
- C–H Activation of 3,3-diphenylcyclopropene in the reaction with Os(CO)2(PPh3)3: 3,3-diphenylcyclopropenyl, 2,2-diphenylcyclopropyl, and 3-phenylindenyl complexes of osmium(II) (2006) (6)
- Photochemistry of Osmium-Carbyne Complexes (1983) (6)
- Transition Metal—Boryl Compounds: Synthesis, Reactivity, and Structure (1999) (5)
- Some transesterification reactions of [Ir(CO2Me)(CO)2(PPh3)2] (1974) (5)
- Reactions of functionalised aryl groups σ-bound to ruthenium(II) (1996) (5)
- A stable 6-metallated 1-azafulvene: synthesis and reactions of Ru(C[C4H3N]SCNMe2S)(η2-S2CNMe2)(CO)(PPh3) and crystal structure of [Ru{C(SCNMe2S)(2-pyrrolyl)}(η2-S2CNMe2)(CO)(PPh3)]+ (1990) (5)
- Triphenylphosphoniodithiocarboxylato-SS′-carbonylbis(triphenylphosphine)-iridium(I) tetrafluoroborate: X-ray structure of an apparent η-CS2 complex of iridium (1976) (5)
- A chelate methldisulphido-ligand from methylation of co-ordinated disulphur. Structure of [Os(η2-S2Me) (CO)2 (PPh3)2]ClO4 (1977) (5)
- Osmadisiloxane and osmastannasiloxane complexes derived from silanolate complexes of osmium(II) (2005) (5)
- An unusual nitrosyl-diazoalkane coupling reaction. Synthesis, structure and reactivity of the aldoxime-dinitrogen complex, OsCl2(N2)[N(OH)CHCO2Et](PPh3)2 (1984) (5)
- Four isomers from the oxidative addition of Me3SnH to Os(CO)2(PPh3)3 and the crystal structure of Os(SnMeI2)I(CO)2(PPh3)2, in which the pairs of CO and PPh3 ligands are mutually trans (2004) (5)
- Synthesis and structure of a P-metallated phospha-alkene, [Os(PC[O]CF3)(CO)2(PPh3)2] (1985) (5)
- Tetrafluoroethyl complexes derived from insertion of the tetrafluoroethylene ligand into an iridium-hydride bond (1990) (4)
- Compounds containing 3-metallated pyrrole (1996) (4)
- The X-ray structure of Os(CS)(PhC≡CPh)(PPh3)2, a complex containing a four-electron donor acetylene ligand (1990) (4)
- Catecholate spanning a metal-carbon double bond. Synthesis and crystal structure of -(2-N-methylpyrrolyl)]I(CO)(PPh3)2 (1990) (4)
- Syntheses, reactions, and structures of osmium(II) distannyl complexes, LnOs–SnMe2SnR3 (R = Me, Ph), from reaction between LnOs–SnClMe2 and either LiSnMe3 or KSnPh3 (2006) (4)
- Osmium nitrosyl complexes with osmium-tin bonds crystal structure of Os[Sn(p-tolyl)3](NO)(CO)2(PPh3) (1997) (4)
- Hydrido-thiocarbonyl complexes as precursors of low-valent thiocarbonyl complexes (1977) (4)
- Iridium(III) metallacycles from electrophilic addition of dichlorocarbene ligands to triphenylphosphine ligands and the crystal structures of IrCl2(o-PPh2C6H4CO)(CO)(PPh3) and (1985) (4)
- Reactivity patterns associated with pyramidal and planar phosphido-ligand geometries; synthesis and structure of [Os(PHPh)Cl(CO)2(PPh3)2] and of [Os{PH(OMe)Ph}(CO)2(PPh3)2] (1984) (3)
- Oxygen adducts from nitrosyl derivatives of zerovalent ruthenium (1968) (3)
- Carbyne Complexes of Ruthenium and Osmium (1993) (3)
- Stable, Terminal Methylene (=CH2) Complexes of Ruthenium, Osmium and Iridium (1989) (3)
- The structurally characterised silyl complexes, Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 and Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2, which have remarkably unreactive Si–Cl bonds (2006) (3)
- Transition metal complexes of the dipyrromethylidene (dipyrrol-2-ylmethylene) ligand, LnM[=C(C4H4N)2], from reaction between ruthenium- and osmium-bound dichlorocarbene and pyrrole: structures of [RuCl2{=CCl(C4H4N)}(CO)(PPh3)2] and [RuCl{=C(C4H3N)(C4H4N)}(CO)(PPh3)2] (1988) (3)
- Trifluoromethyl Complexes of Osmium(II) by Halogen Oxidation of an Osmium(0) Difluorocarbene Compound and the Structures of Os(CF3)Cl2(NO)(PPh3)2 and Os(CF3)Cl0.666I1.333(NO)(PPh3)2 (1986) (3)
- Cationic complexes containing ruthenium–mercury and osmium–mercury bonds (1966) (2)
- O-bonded and S-bonded sulphinate complexes of iridium(I) and iridium(III). Ligand isomerisation accompanying change in co-ordination number (1971) (2)
- Boryl complexes of ruthenium and osmium (2000) (1)
- Dimethyl 7a-carbonyl-2-methoxy-7a,7a-bis(triphenylphosphino)-7a-ruthena-1-benzofuran-4,7-dicarboxylate (2008) (1)
- Synthesis of Ruthenium Carbene Complexes (2008) (1)
- Coordinatively unsaturated σ-aryl iridium(III) complexes containing iridiummercury bonds (1991) (1)
- PREPARATION AND REACTIVITY OF SOME η2-S2 AND η2-SE2 COMPLEXES OF OSMIUM AND THE X-RAY CRYSTAL STRUCTURE OF OS(η2-SE2)(CO)2(PPH3)2 (1980) (1)
- Reactions of coordinated tetrafluoroethylene with halogens. Synthesis of σ-bonded halotetrafluoroethyl complexes of ruthenium(II) and osmium(II) and the structure of OsI(C2F4I) (CO)2(PPh3)2 (1994) (1)
- Metallabenzenes and Fused‐Ring Metallabenzenes of Osmium, Ruthenium and Iridium: Syntheses, Properties and Reactions (2017) (1)
- (Os(η2-PHS)(CO)2(PPh3)2), a Stable η2-Thioxophosphine (H-P=S) Metal Complex. (1988) (1)
- CCDC 627310: Experimental Crystal Structure Determination (2007) (0)
- A Stable 6-Metalated 1-Azafulvene: Synthesis and Reactions of Cyclic Ru(C(C4H3N)SCNMe2S)(η2-S2CNMe2)(CO)(PPh3) and Crystal Structure of Cyclic (Ru(=C(SCNMe2S)(2-pyrrolyl))(η2-S2CNMe2)(CO)(PPh3))+. (1990) (0)
- PREPARATION AND STRUCTURE OF THE SECONDARY CARBENE COMPLEX RUJ2(CHN(CH3)(P-CH3C6H4))(CO)(CN-P-CH3C6H4)(PPH3) (1975) (0)
- CYCLIC TRANSITION-METAL CARBENE COMPLEXES FROM RING-CLOSING REACTIONS ON THE Π-BOUND SUBSTRATES CARBON DISULFIDE AND CARBON DISELENIDE. 1,3-DITHIOLAN-2-YLIDENE AND 1,3-DISELENOLAN-2-YLIDENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II) (1976) (0)
- CCDC 231887: Experimental Crystal Structure Determination (2005) (0)
- Acceptor properties of halides of elements of groups IV and V (1963) (0)
- Variation of the M—Si bond length with silicon substituent in the complexes [M(SiX3Cl(CO)(PPh3)2)] (1993) (0)
- CCDC 288558: Experimental Crystal Structure Determination (2006) (0)
- CCDC 134378: Experimental Crystal Structure Determination (2000) (0)
- SYNTHESIS OF LOW-VALENT THIOCARBONYL COMPLEXES VIA 1,2-ELIMINATION OF METHYLTHIOL FROM CIS-METAL-HYDRIDO-DITHIO METHYL ESTER COMPLEXES. DICARBONYLTHIOCARBONYLBIS(TRIPHENYLPHOSPHINE)OSMIUM AND CHLOROTHIOCARBONYLBIS(TRIPHENYLPHOSPHINE)I (1977) (0)
- Oxidation of co-ordinated ligands via oxygen adducts of ruthenium and osmium: oxidation of CO to CO32– and no to NO3 (1968) (0)
- Catecholate spanning a metal-carbon double bond. Synthesis and crystal structure of Ru[=C(OC6H4O)-(2-N-methylpyrrolyl)]I(CO)(PPh2)2 (1990) (0)
- First Metallabenzenes and Now a Stable Metallabenzyne (2001) (0)
- NEUTRAL, CATIONIC, AND DICATIONIC RUTHENIUM(II) COMPLEXES OF THE SECONDARY CARBENES CHNH(P-C6H4CH3) AND CHN(CH3)(P-C6H4CH3) (1975) (0)
- Heteropolyvanadate of Phosphorus : Preparation and Structure (2001) (0)
- HYDROGEN REDUCTION OF COORDINATED CARBON MONOSULFIDE IN (IRH(CS)(PPH3)3) TO THE METHANETHIOLATO-LIGAND AND AN IRIDIUM THIOFORMYL COMPOUND (IR(CHS)CL2(CO)(PPH3)2) (1978) (0)
- Reactions of Coordinated Phosphorus Trichloride, Phenylphosphonous Dichloride, 1-Phenyl-3,4-dimethylphosphole and Mesitylphosphine in Osmium(II) Complexes. (1991) (0)
- COORDINATED THIOFORMALDEHYDE MONOMER. SYNTHESIS AND REACTIONS OF (OS(η2-CH2S)(CO)2(PPH3)2) (1978) (0)
- SOME TRANSESTERIFICATION REACTIONS OF (IR(CO2ME)(CO)2(PPH3)2) (1974) (0)
- THE IRIDIUM(I) CATION, (IR(CO)(CH3CN)(PPH3)2)(+) AND ITS SUBSTITUTION REACTIONS (1973) (0)
- Transition Metalminus signBoryl Compounds: Synthesis, Reactivity, and Structure. (1998) (0)
- COORDINATED CARBON MONOSELENIDE AND CARBON DISELENIDE, PREPARATION AND STRUCTURE OF THE MIXED CARBONYL-SELENO-CARBONYL COMPLEX, RUCL2(CO)(CSE)(PPH3)2 (1975) (0)
- CCDC 234040: Experimental Crystal Structure Determination (2005) (0)
- ALKOXIDE ATTACK AT CARBONYL AND HYDROSULFIDE ATTACK AT ISOCYANIDE IN THE MIXED CARBONYL-ISOCYANIDE CATION (OSCL(CO)2(CNR)(PPH3)2)+. A NEW SYNTHESIS OF Π-BOUND ISOTHIOCYANATE (RNCS) COMPLEXES (1976) (0)
- CCDC 231888: Experimental Crystal Structure Determination (2005) (0)
- THIOCARBONYL, H(2)-DITHIOMETHYL ESTER, AND DITHIOCARBENE COMPLEXES DERIVED FROM CARBON DISULPHIDE COMPLEXES OF RUTHENIUM AND OSMIUM (1975) (0)
- A FOUR-MEMBERED OSMIUM METALLOCYCLE FROM INTERLIGAND REACTION BETWEEN THIOCARBOXAMIDO AND THIOCARBONYL LIGANDS. STRUCTURE OF OS(CS2CNME-P-TOLYL)H(CO)(PPH3)2 (HAVING AN OS-CN BOND) (1978) (0)
- Hydride Transfer to Coordinated Carbon Monoxide and Related Ligands (1986) (0)
- SYNTHESIS OF TRANSITION METAL - HETEROCYCLIC CARBENE COMPLEXES. OXAZOL-2-YLIDENE AND OXAZOLIDIN-2-YLIDENE COMPLEXES OF OSMIUM(II) DERIVED FROM COORDINATED TOSYLMETHYLISOCYANIDE (1975) (0)
- CCDC 288557: Experimental Crystal Structure Determination (2006) (0)
- CCDC 627311: Experimental Crystal Structure Determination (2007) (0)
- CCDC 134385: Experimental Crystal Structure Determination (2000) (0)
- 3,3,6,6-Tetraphenyl-trans-tricyclo[3.1.0.02,4]hexane (2006) (0)
- Organo-Transition-Metal Substituted Primary Phosphines: Osmium Phosphido (PH2) Complexes (1990) (0)
- STRUCTURE OF A η2-(DITHIO METHYL ESTER)RUTHENIUM(II) COMPLEX AND FURTHER REACTIONS OF A η1-(DITHIO METHYL ESTER)RUTHENIUM(II) COMPLEX (1977) (0)
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