Werner Uhl
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Computer Science
Werner Uhl's Degrees
- PhD Computer Science Stanford University
- Masters Computer Science University of California, Berkeley
- Bachelors Computer Science University of California, Berkeley
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(Suggest an Edit or Addition)Werner Uhl's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Geminal phosphorus/aluminum-based frustrated lewis pairs: C−H versus C≡C activation and CO2 fixation. (2011) (254)
- Acyl-und Alkylidenphosphane, XV 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1/ Acyl- and Alkylidenephosphines, XV 2,2-Dimethylpropvlidynephosphine, a Stable Compound with a Phosphorus Atom of Coordination Number 1 (1981) (193)
- Tetrakis[bis(trimethylsilyl)methyl]dialan(4), eine Verbindung mit Aluminium—Aluminium-Bindung (1988) (147)
- Synthese und Molekülstruktur des Tetrakis[bis(trimethylsilyl)methyl]digallans(4) mit GalliumGallium-Bindung (1989) (141)
- Reaction of a P/Al-based frustrated Lewis pair with ammonia, borane, and amine-boranes: adduct formation and catalytic dehydrogenation. (2013) (123)
- [Ga4{C(SiMe3)3}4] with a Tetrahedral Ga4 Skeleton (1992) (117)
- Dimeric aluminum-phosphorus compounds as masked frustrated Lewis pairs for small molecule activation. (2012) (114)
- Tetrakis[bis(trimethylsilyl)methyl]diindan(4) mit IndiumIndium-Bindung (1989) (111)
- Organoelement compounds with Al-Al, Ga-Ga, and In-In bonds (1993) (107)
- Die Reaktion des tert.Butyl-lithiums mit Aluminiumtribromid. Molekülstrukturen von [HAl(CMe3)2]3 und [LiHAl(CMe3)3]2 (1989) (96)
- A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2. (2016) (96)
- A phosphorus/aluminum-based frustrated Lewis pair as an ion pair receptor: alkali metal hydride adducts and phase-transfer catalysis. (2012) (89)
- Hydroalumination and hydrogallation of alkynes: New insights into the course of well-known reactions (2008) (81)
- [Ga4{C(SiMe3)3}4] mit tetraedrischem Ga4‐Gerüst (1992) (78)
- K2[Al12iBu12], a Compound with Al12 Icosahedra (1991) (75)
- Solvensfreies Tris(trimethylsilyl)methyllithium (1991) (71)
- Synthesis and Structure of [Ni{Ga−C(SiMe3)3}4] and Quantum-Chemical Verification of Strong π Back-Bonding in the Model Compounds [Ni(EMe)4] (E = B, Al, Ga, In, Tl) (1999) (70)
- In4{C(SiMe3)3}4 mit In4-tetraeder und In4Se4{C(SiMe3)3}4 mit In4Se4-heterocubanstruktur (1995) (67)
- Die Reaktionen eines P/Al‐basierten frustrierten Lewis‐Paars mit Ammoniak, Boran und Aminboranen: Adduktbildung und katalytische Wasserstoffeliminierung (2013) (64)
- Reactivity of dimeric P/Al-based Lewis pairs toward carbon dioxide and tert-butyl isocyanate (2013) (64)
- Acyl‐ und Alkylidenphosphane. XVI. (Dimethylaminomethyliden)‐ und (Diphenylmethyliden)phosphane (1981) (63)
- Generation of Weakly Bound Al–N Lewis Pairs by Hydroalumination of Ynamines and the Activation of Small Molecules: Phenylethyne and Dicyclohexylcarbodiimide (2012) (60)
- Al/P-Based Frustrated Lewis Pairs: Limitations of Their Synthesis by Hydroalumination and Formation of Dialkylaluminum Hydride Adducts (2014) (59)
- The reactivity of organoelement compounds with aluminium—aluminium, gallium—gallium and indium—indium bonds (1997) (59)
- Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus-aluminum ligand to gold. (2014) (58)
- Einfache Synthese von Alkylaluminium- und Alkylgalliumhydriden – Kristallstrukturen von [(Me3C)2GaH]3 und den neuartigen Sesquihydriden [(Me3C)2EH]2[EH2CMe3]2 (E = Al, Ga) (2001) (58)
- Dialan-Radikalanionen [R2Al-AlR2].− (1993) (55)
- Acyl‐ und Alkylidenphosphane. XII [1]. Synthese und Eigenschaften des 2,2‐Dimethylpropionylphosphans und einiger Derivate (1981) (55)
- cis/trans Isomerism of hydroalumination and hydrogallation products-reflections on stability and rearrangement mechanism. (2008) (53)
- Elementorganische Verbindungen mit AI‐AI‐, Ga‐Ga‐ und In‐In‐Bindung (1993) (53)
- SYSTEMATIC EXPERIMENTAL AND QUANTUM CHEMICAL INVESTIGATION INTO THE STRUCTURES, THE STABILITY, AND THE SPECTROSCOPIC PROPERTIES OF ALKYLINDIUM(I) COMP OUNDS: TETRAMERIC IN4C(SIMERR')34 VERSUS MONOMERIC INC(SIMERR')3 DERIVATIVE S (1998) (51)
- Reactions of an Al–P-Based Frustrated Lewis Pair with Carbonyl Compounds: Dynamic Coordination of Benzaldehyde, Activation of Benzoyl Chloride, and Al–C Bond Cleavage with Benzamide (2013) (51)
- Organoelement Compounds Possessing AlAl, GaGa, InIn, and TlTl Single Bonds (2004) (50)
- K2[Al12iBu12] mit Al12‐Ikosaeder (1991) (50)
- TlI[C(SiMe3)3]—An Alkylthallium(I) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State (1997) (48)
- Synthesis and molecular structure of a bis[di(alkyl)alanyl]methane; R2ALCH2AIR2 [R = CH(SiMe3)2] (1990) (48)
- Ni[In{C(SiMe3 )3 }4 ]: An Organometallic Nickel-Indium Compound Analogous to [Ni(CO)4 ]. (1998) (48)
- Das tetraalkyldigallan-radikalanion [R2Ga−GaR2]− [R CH(SiMe3)2] mit langer einelektron-π-bindung (1995) (47)
- Hydrogallation of Trimethylsilylethynylbenzenes: Generation of Potential Di- and Tripodal Chelating Lewis Acids (2007) (46)
- Tetraalkylhydrido‐und Tetraalkylmethyldialuminat(5) mit Aluminium – Aluminium‐Bindung: [R2Al – AlXR2]− {RCH(SiMe3)2; XH, Me} (1993) (44)
- A facile high-yield synthesis of the tetrahedral gallium(I) compounds Ga4[C(SiMe2R)3]4—crystal structure of Ga4[C(SiMe2Et)3]4 (1998) (44)
- Dative Au→Al interactions: crystallographic characterization and computational analysis. (2015) (42)
- Main-group-metal clusters stabilized by N-heterocyclic carbenes. (2009) (41)
- A persistent alkylaluminum peroxide: surprising stability of a molecule with strong reducing and oxidizing functions in close proximity. (2008) (41)
- Organogallium(II) compounds bearing chelating ligands, bridging versus terminal co-ordination of gallium–gallium single bonds (2000) (40)
- Two Different Structural Motifs Observed for Dimeric Dialkylaluminum and Dialkylgallium Alkynides [R2E-C≡C-C6H5]2† (2004) (39)
- Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands† (2000) (39)
- A METHYLENE BRIDGED DIALUMINIUM COMPOUND AS A CHELATING LEWIS ACID-COMPLEXATION OF AZIDE AND ACETATE ANIONS BY R2AL-CH2-ALR2 R = CH(SIME3)2 (1999) (39)
- Umsetzung von Isothiocyanaten und Isonitrilen mit R2Al–AlR2 [R = CH(SiMe3)2]; ein‐ und zweifache Insertion von Isonitril in die Aluminium‐Aluminium‐Bindung (1994) (38)
- [Ni{InC(SiMe3)3}4] – eine zu [Ni(CO)4] analoge metallorganische Nickel‐Indium‐Verbindung (1998) (38)
- Gas-Phase Structure of the Monomeric Alkylgallium(I) Compound Ga[C(SiMe3)3] and the Electrochemical Behavior of Ga4[C(SiMe3)3]4and In4[C(SiMe3)3]4with EPR Evidence for a Ga4R4Radical Anion (1996) (38)
- Hydrogallation of alkynes: Syntheses of carbon-gallium cages possessing heteroadamantane structures (2002) (37)
- A P-H Functionalized Al/P Frustrated Lewis Pair: Substrate Activation and Selective Hydrogen Transfer. (2016) (37)
- A Methylene‐Bridged Dialuminium Compound as a Chelating Lewis Acid: Complexation of Nitrite and Nitrate Anions by R2Al–CH2–AlR2[R = CH(SiMe3)2]☆ (1998) (36)
- Die Zersetzungsreaktion des Dialan-Radikalanions [R2Al-AlR2]·− in DME: I. Kristallstrukturen von R2Al(Me)OC2H4OMeK(DME) und R2Al(OC2H4OMe)2K (R CH(SiMe3) 2) (1994) (36)
- Bis[bis(trimethylsilyl)methyl]galliumbromid und monomeres {Bis[bis(trimethylsilyl)methyl]gallium}[tris(trimethylsilyl)silyl]tellurid [(Me3Si)2CH]2Ga–TeSi(SiMe3)3 (1992) (35)
- Activation of isocyanates and carbon dioxide by a monomeric aluminium hydrazide as an active Lewis pair. (2013) (35)
- Pentacarba-arachno-tridecaalane (AlMe)8 (CCH2 Ph)5 H with an Al8 C5 Skeleton-The First Polyhedral Carbaalane. (1999) (35)
- Facile Modulation of FLP Properties: A Phosphinylvinyl Grignard Reagent and Ga/P- and In/P2 -Based Frustrated Lewis Pairs. (2017) (34)
- Synthese und Kristallstruktur von Li2[(Me3SiCH2)3Al ? CH2 ? Al(CH2SiMe3)3] — ein Addukt des Dilithiomethans CH2Li2? (1991) (34)
- Acyl‐ und Alkylidenphosphane. X. Synthese des Phenyl‐bis(trimethylsilylsulfano)methyliden phosphans (1980) (34)
- Umsetzungen von Ga2Br4 · 2 Dioxan mit (Trimethylsilyl)methyllithium und Neopentyllithium – Synthese und Kristallstruktur von Lithiumtetraalkylgallanaten(III) mit Li–C–Ga-Brücke (1991) (33)
- Lithiumdibenzoylphosphid·1,2‐Dimethoxyethan, ein neues 2‐Phospha‐1,3‐dionat (1980) (33)
- The insertion of alkylgallium(I) groups [Ga–C(SiMe3)3] into P–P bonds of P4: formation of a P4(GaR)3 cage (1999) (33)
- Synthesen und Kristallstrukturen von Dialkylgalliumhydriden — dimere versus trimere FormeleinheitenProfessor Joachim Strähle zum 65. Geburtstag gewidmet (2002) (33)
- Synthese und Molekülstruktur des (N,N′ ‐Dimethylpiperazin)lithium‐(μ‐hydrido)(tert‐butyl)bis[bis(trimethylsilyl)methyl]alanats mit intramolekularer Wechselwirkung zwischen Lithium und CHσ‐Bindungen (1991) (33)
- μ-Hydroxo organo aluminium and gallium compounds (1996) (33)
- The decomposition reaction of the dialene radical anion [R2Al&.;−AlR2]− in DME(II): crystal strctures of the aluminum glycolates [R2Al(OCH2)2]K(DME) and R2Al(OCH)2)2 Al(R)(OCH2)2AlR2 (R = CH(SiMe3)2) (1996) (33)
- C≡C Triple Bond Activation by Heterocyclic Aluminum Phosphinides (2010) (32)
- Die reaktion des tetrakis[bis(trimethylsilyl)methyl]dialans(4) mit Schwefelkohlenstoff: Molekülstrukturen mit AlSAl- und AlCS2Al-Fragment (1993) (32)
- Reactions of the Alkylindium(I) Compound In4[C(SiMe3)3]4 with Sulfur and Tellurium: Syntheses of In4S4[C(SiMe3)3]4 and In4Te4[C(SiMe3)3]4 with Indium Chalcogen Heterocubane Structures (1996) (32)
- An aluminum-nitrogen based Lewis pair as an effective catalyst for the oligomerization of cyanamides: formation of acyclic C-N oligomers instead of thermodynamically favored cyclic aromatic trimers. (2013) (31)
- Pentacarba-arachno-tridecaalan (AlMe)8(CCH2Ph)5H mit Al8C5-Gerüst – das erste polyedrische Carbaalan (1999) (31)
- Reaction of Ni2Cp2(mu-CO)2 with the alkylgallium(I) and alkylindium(I) compounds E4[C(SiMe3)3]4 (E = Ga, In). Insertion of E-R groups into the Ni-Ni bond versus replacement of CO by the isolobal E-R ligands. (2001) (31)
- Di(µ-acetato)dialkyldigallium as starting compound for the facile syntheses of digallium derivatives containing bridged or terminally co-ordinated Ga–Ga single bonds (1999) (31)
- Syntheses of polyaluminium compounds by hydroalumination reactions, chelating Lewis acids possessing two and four coordinatively unsaturated aluminium atoms (2002) (31)
- Reaktionen von R2AlAlR2 (R CH(SiMe3)2) mit Trimethylsilylazid — Insertion in die AlAl‐Bindung und Abbau zum trimeren Dialkylaluminiumazid (1995) (31)
- Gallium‒Gallium Bonds as Key Building Blocks for the Formation of Large Organometallic Macrocycles, on the Way to a Mesoporous Molecule (2004) (30)
- Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation (2008) (30)
- THE FORMATION OF MACROCYCLIC COMPOUNDS CONTAINING TWO GA-GA BONDS BY THE REACTION OF TETRAALKYLDIGALLANE(4) R2GA-GAR2 R = CH(SIME3)2 WITH DICARBOXYLIC ACIDS (1998) (30)
- SYNTHESIS AND REACTIVITY TETRAHEDRAL CLUSTERS CONTAINING OF THE MONOVALENT ELEMENTS ALUMINIUM, GALLIUM, INDIUM, AND THALLIUM (1998) (30)
- Hydroalumination and Hydrogallation of 1,2-Bis(trimethylsilylethynyl)benzene: Formation of Molecular Capsules and C−C Bond Activation (2010) (30)
- The reactions of dialkylgallium hydrides with tert-butylethynylbenzenes--a systematic investigation into the course of hydrogallation reactions. (2007) (30)
- Reactions of Tetrakis[bis(trimethylsilyl)methyl]digallane(4) with Carboxylic Acids — Substituent Exchange and Bridging of the GaGa bond by two Carboxylato Groups† (1996) (29)
- Pt[In–C(SiMe3)3]4 – eine zu Pt(CO)4 analoge Verbindung mit einem durch vier InR‐Liganden ideal tetraedrisch koordinierten Platinatom (2000) (29)
- New Carbaalanes − (AlMe)8(CCH2Me)5(C≡C−Me) and the THF Adduct (AlMe)8(CCH2Me)5H·2THF (2001) (29)
- Die Reaktionen von R2AlAlR2 und R2InInR2 mit Benzoesäure – Synthese und Kristallstruktur von R2Al(μ-H)(μ-O2CC6H5)AlR2 und RIn(μ-O2CC6H5)4InR [R CH(SiMe3)2]† (1997) (29)
- Alkylindium subhalides derived from the tetrahedral indium(I) cluster compound [In4[C(SiMe3)3]4]. (2001) (29)
- Trialkylhydridoalanate RxR′3-xAlH⊖ [R = CMe3; R′ = CH(SiMe3)2] (1992) (29)
- Hydrogallation of alkynes with H-GaCl2: formation of organoelement dichlorogallium compounds potentially applicable as chelating Lewis acids. (2008) (29)
- Twofold hydrogallation of C triple bonds c triple bonds by H-GaCl(2)-synthesis of chelating Lewis acids and their application in adduct formation. (2008) (29)
- Two New Carbaalanes: Compounds with an Al7C5 and a [B11H11]2− Analogous Al7C4 Cluster (2000) (29)
- Synthese und Molekülstruktur eines 1‐Sila‐3‐alanatetans (1989) (28)
- The hydroalumination of diethynes with di(tert-butyl)aluminium hydride: a facile method for the synthesis of organometallic dialuminium compounds (2000) (28)
- Umsetzungen der Dielementverbindungen R2E-ER2 [E = Ga, In; R = CH(SiMe3)2] mit Lithium-phenylethinid - Bildung von Addukten unter Erhalt der E-E-Bindungen (2000) (27)
- An Al/P-based frustrated Lewis pair as an efficient ambiphilic ligand: coordination of boron trihalides, rearrangement, and formation of HBX₂ complexes (X = Br, I). (2014) (27)
- Tetrahedral homonuclear organoelement clusters and subhalides of aluminium, gallium and indium (2004) (27)
- Ga2Br2R2 und Ga3I2R3 [R = C(SiMe3)3] — zwei neue elementorganische Galliumsubhalogenide mit einer bzw. zwei Ga‐Ga‐Bindungen (2004) (26)
- C-H bond activation by hyperconjugation with Al-C bonds and by chelating coordination of the hydride ion. (2007) (26)
- Acyl‐ und Alkylidenphosphane. XIII [1]. Molekül‐ und Kristallstruktur des 2,4‐Di(tert.butyl)‐2,4‐bis‐(trimethylsiloxy)‐1,3‐diphosphetans (1981) (26)
- Influence of the Lewis Acidity of Gallium Atoms on the Reactivity of a Frustrated Lewis Pair: Experimental and Theoretical Studies (2018) (26)
- In3I2[C(SiMe3)3]3: Synthesis of a Diiodotrialkyltriindane(5) Containing Two In−In Single Bonds (2001) (26)
- Zwei neue Carbaalane: Verbindungen mit Al7C5‐ und zu [B11H11]2− isovalenzelektronischem Al7C4‐Cluster (2000) (26)
- Treatment of Terminal Alkynes R–C≡C–H with Dialkylaluminum Hydrides: Hydroalumination versus Deprotonation (2009) (26)
- Hydrogallierungsreaktionen mit den Monoalkinen H5C6‐C≡C‐SiMe3 und H5C6‐C≡C‐CMe3 – cis/trans‐Isomerie und Substituentenaustausch (2008) (25)
- Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C–H Bond Activation with H–C≡C–Ph and Pentafluorobenzene (2016) (25)
- Ga2I2[C(SiMe3)3]2– an organogallium(II) halide containing a Ga–Ga single bond (2003) (25)
- Hydroalumination and Hydrogallation Reactions with Tri(ethynyl)silanes – Generation of Compounds with up to Three Coordinatively Unsaturated Aluminium Atoms (2012) (25)
- Fe2(CO)6[In−C(SiMe3)3]3 with a Trigonal-Bipyramidal Fe2In3 Cluster† (1997) (25)
- SYNTHESIS OF AN ALUMINATACYCLOPROPENE DERIVATIVE WITH AN ALC2 HETEROCYCLE AND AN EXOCYCLIC ALR2 SUBSTITUENT : EVIDENCE FOR A NONCLASSICAL BONDING SITU ATION (1999) (25)
- New Insight into Hydrogallation Reactions: Facile Synthesis of a Gallium-Bridged [3,3,3]-Cyclophane (2005) (25)
- Tetrakis[bis(trimethylsilyl)methyl]dialuminoxane with a Linear AlOAl Group†‡ (1995) (25)
- Chalcogen Capture by an Al/P-Based Frustrated Lewis Pair: Formation of Al-E-P Bridges and Intermolecular Tellurium–Tellurium Interactions (2015) (24)
- New Aspects of Hydrogallation Reactions with Alkynes: Simple Addition versus Formation of Cyclophanes (2006) (24)
- 1‐Sila‐3‐alumina‐4‐aluminatacyclopentan mit Al–Al‐Bindung und C2Al2Si‐Heterocyclus (1993) (24)
- Reactions of β-diketiminatoaluminum hydrides with tert-butyl hydrogenperoxide – Facile formation of dialuminoxanes containing Al–O–Al groups (2009) (24)
- Ga9 (CMe3 )9 , an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds En Rn (E=B-In). (2001) (24)
- A Carbon-Bridged Digallium Compound as a Chelating Lewis Acid: Complexation of Thiophenolate and Benzoate Anions by H5C6−CH2−C(SiMe3)[Ga(CH2tBu)2]2 (2008) (24)
- Facile Synthesis of an Unsaturated Spiro Germane by Hydroalumination and Intramolecular 1,1-Carbalumination† (2010) (24)
- Hydroalumination of a chlorotrialkynylsilane: spontaneous stepwise 1,3-dyotropic rearrangement via an intermediate silyl cation. (2014) (23)
- Functional group chemistry at intramolecular frustrated Lewis pairs: substituent exchange at the Lewis acid site with 9-BBN. (2013) (23)
- The influence of halogen substituents on the course of hydrogallation and hydroalumination reactions. (2009) (23)
- Synthesis and Crystal Structure of a Monomeric Tetraalkyldigallium Telluride with a Bent Ga-Te-Ga Group (1995) (23)
- Dialkylaluminum hydrazides derived from free hydrazine N2H4. Molecular Structures of [(MeC)2AlN2H3]2 and [(MeC)2Al]4(N2H2)2. (2001) (23)
- THE INSERTION OF CHALCOGEN ATOMS INTO AL-AL AND GA-GA BONDS : MONOMERIC COMPOUNDS WITH AL-SE-AL, GA-S-GA AND GA-SE-GA GROUPS (1996) (23)
- Aluminium Atoms at High Connectivity Sites in Polyhedral Polyborane Analogous Clusters: From Aluminaboranes to Carbaalanes (2000) (23)
- Reducing Ga-H and Ga-C bonds in close proximity to oxidizing peroxo groups: conflicting properties in single molecules. (2009) (23)
- Unexpected Formation of Ga4C2H4 Heteroadamantane Cages by the Reaction of Carbon-Bridged Bis(dichlorogallium) Compounds with tert-Butyllithium (2011) (23)
- Hydroalumination of bis(alkynyl)germanes and -silanes: Generation of a chelating Lewis-acid and observation of a dismutation reaction (2011) (22)
- Cooperative Ge–N Bond Activation in Hydrogallation Products of Alkynyl(diethylamino)germanes (Et2N)nGe(C≡CtBu)4–n (2013) (22)
- A heterocyclic organogallium peroxide with two dialkylgallium groups bridged by a peroxide dianion. (2009) (22)
- Hydroalumination of Bis(alkynyl)silanes: Generation of Chelating Lewis Acids, Their Application in the Coordination of Chloride Ions and a 1,1-Carbalumination Reaction (2012) (22)
- Novel Al-based FLP systems. (2013) (22)
- Die Reaktion des [(Me3Si)2CH]2Al ? CH2 ? Al [CH(SiMe3)2]2 mit Neopentyllithium: Bildung des {[(Me3Si)2CH]2Al ? CH2 ? Al [CH(SiMe3)2]2CH2CMe3}⊖ [Li(TMEDA)2]⊕ (1993) (22)
- Sterically Constrained Bicyclic Phosphines: A Class of Fascinating Compounds Suitable for Application in Small Molecule Activation and Coordination Chemistry. (2018) (22)
- Reactions of an Aluminium/Phosphorus Frustrated Lewis Pair (FLP) with α,β-Unsaturated Carbonyl Compounds: FLPs as Efficient Two-Electron Reductants with the Formation of Enolates, a cis-Enediolate, and an Allene. (2018) (21)
- Hydroalumination of dialkynylgermanes—synthesis of alkenyl–alkynylgermanes with intramolecular aluminium–carbon interactions (2010) (21)
- Different Reactivity Patterns in the Reactions of the Homologous Trimethylelement Compounds EMe3 (E = Al, Ga, In) with Methylhydrazine (2008) (21)
- N,N,N′,N′-Tetramethylethylendiamin-di(tert-butyl)aluminium-Kationen — Molekülstruktur des [(Me3C)2Al · TMEDA]⊕[(Me3C)2AlBr2]⊖ (1992) (21)
- N-Acyl- and N-Sulfonylformamidines from Cyanamides and Carbodiimides by Hydroalumination and Subsequent Treatment with Electrophiles (2013) (21)
- Molecular self-assembly controlled by gallium–gallium single bonds—facile syntheses of macrocyclic octagallium compounds (2002) (21)
- tert-Butylaluminum Bis[1,2-bis(trimethylsilyl)hydrazide]: The First Alkylaluminum Dihydrazide (2000) (21)
- Surprising Stability of an Al/P‐Based Frustrated Lewis‐Pair Towards Protolysis: HX Adducts (X = F, Cl) with Intramolecular H···X Hydrogen Bonds (2015) (21)
- Hauptgruppenmetallcluster stabilisiert durch N‐heterocyclische Carbene (2009) (20)
- Ein P‐H‐funktionalisiertes Al/P‐basiertes frustriertes Lewis‐Paar: Substrataktivierung und selektiver Wasserstofftransfer (2016) (20)
- Einfache Bildung eines beständigen Butadien‐2‐yl‐Kations: Stabilisierung durch Hyperkonjugation mit einer Al‐C‐Bindung (2006) (20)
- Structure and reactivity of an Al/P-based frustrated Lewis pair bearing relatively small substituents at aluminium (2017) (20)
- The Reactions of R2Ga−GaR2 and R2In−InR2 [R = CH(SiMe3)2] with Protic Reagents: Substituent Exchange versus Cleavage of the Element−Element Bond (1998) (20)
- Alkynide and acetonitrile activation by strained AlPC2 heterocycles. (2012) (20)
- Lithium Dibenzoylphosphide · 1,2‐Dimethoxyethane—A New 2‐Phospha‐1,3‐dionate (1980) (20)
- Octacarbonylbis {μ-(tris(trimethylsilyl)methyl]indany l} dimanganese with Two Monoalkyl Indium Groups Bridging the Mn–Mn Bond (1995) (20)
- Hydroaluminierungsreaktionen mit dem sperrigen Dialkylaluminiumhydrid [(Me3Si)2HC]2Al-H - Unterdrückung von Folgereaktionen† (2005) (20)
- 1,4-Di(isopropyl)-1,4-diazabutadien als Abfangreagenz für monomere Bruchstücke des Tetragalliumclusters Ga4[C(SiMe3)3]4 – Bildung eines ungesättigten GaN2C2-Heterocyclus und eines Oxidationsprodukts mit Ga-O-O-Ga-Gruppe† (2005) (20)
- The Reaction of Diazomethane Derivatives with the Dielement Compounds R2Al–AlR2 and R2Ga–GaR2 [R = CH(SiMe3)2] – Insertion versus Fragmentation (1999) (20)
- Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis (2017) (19)
- Synthesis of aluminum hydrazides by hydroalumination of 2,3-diazabutadienes--formation of an Al4(N2)3 cage compound and an Al3(N2)3 macrocyclic ligand. (2001) (19)
- An E4O4 heterocubane structure with a trivalent element of group 13 realized in In4O4[C(SiMe3)3]4 (1998) (19)
- TlI[C(SiMe3)3] – eine Alkylthallium(I)‐Verbindung mit einem verzerrten Tetraeder aus Tl‐Atomen im Festkörper (1997) (19)
- Synthesis and structure of an alkylgallium bridged [1,1]ferrocenophane (2001) (19)
- Gallium-gallium bonds as efficient templates for the generation of a large cage containing twelve gallium atoms. (2010) (19)
- Twofold Insertion of Isocyanides into the GaGa Bond of Tetrakis[bis(trimethylsilyl)methyl]digallane(4) (1996) (19)
- Monomere versus dimere Dialkylaluminiumalkinide R2Al‐C≡C‐R′ – dreifach koordinierte Aluminiumatome gebunden an C≡C‐Dreifachbindungen (2008) (18)
- Verbrückende Koordination von Gallium–Gallium‐Bindungen durch Chelatliganden – Grenzen der Beständigkeit von Digallium‐Verbindungen (2000) (18)
- Verbrückende und terminale Koordination von Ga–Ga‐Bindungen durch die Chelatliganden Imidotetraphenyldiphosphinat bzw. ‐dithiodiphosphinat (1999) (18)
- Reactivity of Organoelement Subhalides of Gallium and Indium — Ga−Ga and In−In Bonds Bridged by Carboxylato Ligands (2004) (18)
- UNTERSUCHUNGEN ZUR CARBENINSERTION IN AL-AL-, GA-GA- UND IN-IN-BINDUNGEN (1998) (18)
- Die Reaktion des [(Me3Si)2CH]2AlCH2Al [CH(SiMe3)2]2 mit LiCH(PMe2)2; Bildung eines fünfgliedrigen Al2C2P-Heterozyklus (1994) (18)
- Die Bildung von Gallium‐Chalkogen‐Heterokubanstrukturen durch Umsetzung der Alkylgallium(I)‐Verbindung Ga4[C(SiMe3)3]4 mit Schwefel, Selen und Tellur (1998) (18)
- Facile formation of a persistent butadien-2-yl cation stabilized by hyperconjugation with an Al-C bond. (2006) (18)
- Aluminium Hydrazides: Dimeric Bis(tert‐butyl)aluminium Hydrazides withSix‐Membered Al2N4 and Five‐Membered Al2N3 Heterocycles (2000) (17)
- Synthese und Kristallstruktur eines μ‐Methylen‐μ‐hydrido‐dialanats [R2Al(μ‐CH2)(μ‐H)AlR2]− (R = CH(SiMe3)2) (1994) (17)
- μ-Methylen-bis[chlor-bis(trimethylsilyl)methylalan] {(Me3Si)2CH(Cl)AlCH2Al(Cl)CH(SiMe3)2} mit einer Heteroadamantanstruktur (1991) (17)
- Facile Synthesis of Aluminum-Bridged [3,3,3]Cyclophanes by Hydroalumination (2007) (17)
- Investigations into the Reactivity of Organoelement Gallium and Indium Subhalides – Syntheses of Digallium and Diindium Acetylacetonates (2005) (17)
- Clusters of the Heavier Group 13 Elements (2005) (17)
- Reaction of the Alkylindium(I) Compound In4[C(SiMe3)3]4 with Octacarbonyldicobalt: Bridging of the CoCo Bond by one or two InC(SiMe3)3 Groups† (1996) (17)
- A Sterically Constrained Tricyclic PC3 Phosphine: Coordination Behavior and Insertion of Chalcogen Atoms into P-C Bonds. (2018) (17)
- Reactions of Tetraalkyldiindane(4), R2In−InR2 (R = CH(SiMe3)2), with tert-Butyl and Phenyl Isonitriles. Formation of Adducts with Retention of the In−In Bond† (1998) (17)
- Formation of the Digallium Compound [(C5C6)2N3](R)Ga–Ga(R)[N3(C6H5)2] with Two Bis(trimethylsilyl)methyl Groups and Two Terminal Chelating Diphenyltriazenido Ligands (1997) (17)
- Tetrakis[bis(trimethylsilyl)methyl]dialuminoxan mit linearer Al‐O‐Al‐Gruppe (1995) (16)
- Insertion von Rhodizonsäure in die Gallium-Gallium- bzw. Indium-Indium-Bindungen von Digallan(4)- bzw. Diindan(4)-Verbindungen† (2002) (16)
- Hydroaluminierung von Silicium-zentrierten Dialkinen – Synthese gemischt-substituierter Alkenyl-alkinylsilane (2010) (16)
- Synthese eines funktionalen Aluminiumalkinids, Me3C‐C≡C‐AlBr2, und dessen Reaktionen mit der sperrigen Lithiumverbindung LiCH(SiMe3)2 (2006) (16)
- The hydrogallation of CN double bonds — reactions of GaH3·NMe2Et with tetramethyl-2,3-diazabutadiene (2001) (16)
- Ga9(CMe3)9, ein wichtiger neuer Baustein in der Strukturchemie der Alkylelement(i)-Verbindungen EnRn (E=B–In) (2001) (16)
- P–H Functionalized Al/P-Based Frustrated Lewis Pairs in Dipolar Activation and Hydrophosphination: Reactions with CO2 and SO2 (2019) (16)
- Vinylgallium and alkyllithium compounds: transmetalation and generation of oligolithium cages. (2011) (16)
- Organometallic Iron Indium Derivatives Prepared by the Reaction of Carbonyliron Compounds with the Alkylindium(I) Derivative In4[C(SiMe3)3]4† (1997) (16)
- Di(tert-butyl)aluminum, -gallium and -indium β-diketonates and β-diketiminates, reactions with oxygen and formation of an unprecedented peroxo-rich hexaperoxotriindium compound (2018) (15)
- Hydroalumination versus Deprotonation of Alkynes with Sterically Demanding Substituents (2013) (15)
- Acyl‐ und Alkylidenphosphane. XXIX. Molekül‐ und Kristallstruktur des Orthorhombischen (Diphenylmethyliden)mesitylphosphans (1986) (15)
- Oligonuclear gallium nitrogen cage compounds: molecular intermediates on the way from gallium hydrazides to gallium nitride. (2011) (15)
- Die Reaktion des Digalliumsubiodids R(I)Ga-Ga(I)R [R = C(SiMe3)3] mit Lithium-diphenylphosphanid – radikalische Öffnung der Ga-Ga-Bindung† (2006) (15)
- [Ga9(CMe3)9]*--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. (2003) (15)
- Aluminiumhydrazide. Bildung eines dimeren Di(tert‐butyl)aluminiumhydrazids mit viergliedrigem Al2N2‐Heterozyklus und Umsetzung eines Dialkylaluminiumchlorids mit Dilithium‐bis(trimethylsilyl)hydrazid (2000) (15)
- [In3Br3{C(SiMe3)3}3][Li(THF)3] mit einer Kette aus drei Indiumatomen — ein bemerkenswertes Nebenprodukt aus der Synthese des Tetraindiumclusters In4[C(SiMe3)3]4 (2002) (15)
- New aluminum and gallium complexes of β-diketiminato and β-ketiminato ligands (2017) (15)
- In4S[C(SiMe3)3]4, eine indiumorganische Verbindung mit einem zu Pentahydro-closo-pentaborat(2−) isovalenzelektronischen In4S-Gerüst† (1997) (15)
- Formation of a gallium triphosphorus heterocycle by reaction of the alkylgallium(I) compound Ga4[C(SiMe3)3]4 with tri(tert-butyl)cyclotriphosphane (2000) (15)
- Die Hydroaluminierung von 1,1,4,4‐Tetramethyl‐2,3‐diazabutadien mit Dialkylaluminiumhydriden – Synthese von Dialkylaluminiumhydrazoniden (2001) (15)
- Hydrometallation of amino-trialkynylsilanes--intramolecular M-N interactions (M = Al, Ga) and potential activation of Si-N bonds. (2014) (14)
- A Unique Chlorine–Methyl Exchange Reaction upon Treatment of Dichloroorganogallium Compounds, RGaCl2, with the Bulky Alkyllithium Derivative LiC(SiMe3)3 (2011) (14)
- Adducts of organogallium chlorides with hydrazines and the formation of dimeric dialkylgallium hydrazides possessing different ring sizes (2005) (14)
- Strongly oxidizing and reducing functions combined in a single compound: an alkyl gallium peroxide possessing a nine-membered (GaR)3(O2)3 heterocycle. (2008) (14)
- Alkenyl-Alkynylgermanes Functionalised by Lewis Acids: Intramolecular Aluminium– and Gallium–Alkyne Interactions and Potential Ge–C Bond Activation (2014) (14)
- Reactions of Al/P, Ga/P and P–H functionalized frustrated Lewis pairs with azides and a diazomethane – formation of adducts and capture of nitrenes (2017) (14)
- Acyl‐ und Alkylidenphosphane. XXVIII. Synthese und Struktur von 1,3‐Dibenzyl‐ und 1,3‐Diethyl‐2,4‐bis(phenylimino)‐1,3‐diphosphetan (1986) (14)
- Aluminum, gallium, and indium hydrazides and the generation of oligonuclear element-nitrogen cages: molecular intermediates on the way to element nitrides. (2011) (14)
- Tris(trimethylsilyl)phosphine and lithium bis(trimethylsilyl)phosphide · bis-(tetrahydrofuran) (2007) (14)
- 1,2- and 1,3-diphosphetanes from alkylidenephosphines (1983) (14)
- Hydrazin-Addukte mit Dialkylindiumchloriden — Überraschende strukturelle Vielfalt bei einfachen Verbindungen† (2003) (14)
- Umsetzungen des Tetrakis[bis(trimethylsilyl)methyl]dialans(4) mit Methylisothiocyanat und Phenylisocyanat – Insertion in die Al ? Al‐Bindung bzw. Fragmentierung (1996) (14)
- Reactions of Carbaalanes with HBF4 and HCl: A μ3-Bridging Fluorine Atom in (AlEt)7(CCHPh)2(CCH2Ph)3(μ3-F) versus a Terminal Chlorine Atom in (AlMe)7(AlCl)(CCH2Ph)5H (2001) (14)
- Synthese und Kristallstruktur des trimeren [(Me3Si)2CH]2Al ? CN (1995) (14)
- The insertion of chalcogen atoms into the InIn bond of tetrakis[bis(trimethylsilyl)methyl]diindane(4): monomeric compounds with InSIn, InSeIn, and InTeIn groups (1996) (14)
- The unique decomposition behavior of the dimeric dialkylaluminum hydrazide [(Me3C)2Al-N(H)-N(H)-Me]2-butane versus ammonia elimination. (2009) (14)
- Die Umsetzung von Dialkylaluminiumchloriden mit Bis(trimethylsilyl)hydrazin: Bildung von Addukten R2AlCl · NH2NHSiMe3 mit dem thermisch unbeständigen Trimethylsilylhydrazin (1999) (13)
- Formal Oxidation State +2: Metal–Metal Bonded Versus Mononuclear Derivatives (2011) (13)
- Aluminium Hydrazides: Reactions of tert‐Butylaluminium Chlorides with Dilithium Bis(trimethylsilyl)hydrazide – Formation of Iminoalanes and their Hydrazido Adducts (1999) (13)
- Bridging and Terminal Arrangement of Alkylperoxo Groups in Organoindium Peroxides (2009) (13)
- Reactions of a Ga/P-Based Frustrated Lewis Pair with HX (X = F – I), Heterocumulenes R–NCY (Y = O, S) and Chalcogens–Adduct Formation and Surprising Stability towards Protolysis (2017) (13)
- Die Reaktion des Tri(isobutyl)alans mit Kalium : eine Neuuntersuchung ; Kristallstruktur des Kalium[tetra(isobutyl)alanats] (1992) (13)
- Gallium-Gallium Single Bonds Terminally Coordinated by Tropolonato Ligands (2002) (13)
- In4S[C(SiMe3)3]4: An Organoindium Compound with an In4S Core Isovalence Electronic to Pentahydro‐closo‐pentaborate(2–) (1997) (12)
- Unexpected formation of gallium–gallium single bonds by irradiation of the hydride [(Me3C)2GaH]3 (2001) (12)
- Al/P- and Ga/P-Based Frustrated Lewis Pairs and Electronically Unsaturated Substrates: Ring Cleavage and Ring Closure, C-C and C-N Bond Formation. (2019) (12)
- Synthesis and molecular structures of dialkylselenonium methylide complexes of indium tribromide (2005) (12)
- Cooperative Ge-N Bond activation in aluminium-functionalised aminogermanes and spontaneous imine elimination via an intermediate germyl cation. (2015) (12)
- Dimethylindium hydrazides [Me2In-NH-NHR]2 (R = CMe3, C6H5) (2006) (12)
- Monomeres [(Me3Si)2CH]2Al-Te-Al[CH(SiMe3)2]2 mit gewinkelter Al-Te-Al-Gruppe / Monomeric [(Me3Si)2CH]2Al-Te-Al[CH(SiMe3)2] 2 with a Bent Al-Te-Al Group (1994) (12)
- Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C-C Bonds. (2017) (12)
- Bis[dichlor-bis(trimethylsilyl)methylalan] : Synthese und Molekülstruktur (1990) (12)
- Ein Al‐N‐basiertes Lewis‐Paar als effektiver Katalysator für die Oligomerisierung von Cyanamiden – Bildung von acyclischen C‐N‐Oligomeren anstelle von thermodynamisch begünstigten cyclischen Trimeren (2013) (12)
- A P-H functionalized Al/P-based frustrated Lewis pair - hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of P[double bond, length as m-dash]C double bond formation. (2018) (11)
- On the reactions of the tetraindium cluster In4[C(SiMe3)3]4: Insertion of the monomeric fragments InC(SiMe3)3 into chalcogen–chalcogen bonds (2009) (11)
- Crystalline Complexes of Pyr12O1TFSI-Based Ionic Liquid Electrolytes (2015) (11)
- Stark oxidierende und reduzierende Funktionen vereint in einer Verbindung – ein Alkylgalliumperoxid mit neungliedrigem (GaR)3(O2)3-Heterocyclus† (2008) (11)
- Investigations into the reactivity of organoelement gallium subhalides : Syntheses of bifunctional digallium carboxylate iodides possessing bridged Ga-Ga bonds and terminal iodine atoms (2006) (11)
- Dehydrochlorination of Carboxylic Acid Chlorides by an Aluminum/Phosphorus‐Based Frustrated Lewis Pair and the Formation of Ketene Adducts (2015) (11)
- Die Reaktion von Tetraalkyldialuminium(4)-, -digallium(4)- und -diindium(4)-Verbindungen mit 3-Chlorperbenzoesäure: Bildung von μ-Carboxylato-O,O′-μ-hydroxo-dielement-Derivaten (1997) (11)
- An organogallium subfluoride and subhydroxide: three Ga-Ga bonds in single molecules. (2009) (11)
- K{μ-Cl2Al[CH(SiMe3)2]2} – Kristallstruktur eines eindimensional über K – Cl-Brücken koordinationspolymeren Alanats / K{µ-Cl2Al[CH(SiMe3)2]2} – Crystal Structure of an Alanate Featuring a Onedimensional Coordination Polymer with K–Cl Bridges (1990) (11)
- Reactivity of a Monomeric Aluminium Hydrazide towards Isocyanates and Isothiocyanates: Active Lewis Pair Behaviour versus Classical Insertion Reactions (2016) (11)
- [Tl3Cp2][CpMo(CO)3] – ein Salz mit dem neuartigen Kation [Tl3Cp2]+. Neuuntersuchung der Struktur von MCp (M = In, Tl) (1999) (11)
- Germacyclobutenes: generation by 1,1-carbalumination or 1,1-carbagallation and their photophysical properties. (2015) (11)
- From tert-Butylhydrazine Adducts of AlR3 (R = Me, CMe3) to Oligonuclear AlN Cage Compounds – Evidence for a Hydrazine Twist Across an Al3 Triangle (2011) (11)
- Synthesis of a GaN cage compound with a hydrazinetetraide fragment, [N-N]4-, stabilised by six gallium atoms. (2010) (11)
- Hydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P-N bond activation, a transient phosphaallene, a zwitterionic AlP2C2 heterocycle and a masked Al/P-based frustrated Lewis pair. (2016) (11)
- Molecular Structures of Dimeric and Trimeric Dineopentylaluminum Hydride and Trimeric Diphenylaluminum Hydride (2014) (10)
- Einfache Modulierung von FLP-Eigenschaften: ein Phosphanylvinyl-Grignard-Reagenz und Ga/P- oder In/P2-basierte frustrierte Lewis-Paare (2017) (10)
- Reactions of Hydrazines with AlH3·NMe2Et – Formation of Aluminum‐Nitrogen Heterocycles (2009) (10)
- Hydrometallation (M = Al, Ga) of Silicon- and Germanium-centred Oligoalkynes (2014) (10)
- Persistent Alkylgallium Peroxides - Synthesis of the Cage Compound Na4[(Ga-R)3(O2)3(O)]2(Et2O)(DABCO) [R = CH(SiMe3)2] (2009) (10)
- Replacement of CO ligands by the isolobal gallium(I) compound GaR [R = C(SiMe3)3], formation of the transition metal gallium compounds Mn2(CO)8(μ-GaR)2 and Fe3(CO)9(μ-CO)(μ-GaR)2 (2000) (10)
- Phenylhydrazinverbindungen mit Aluminium und Gallium – von Addukten über zyklische Hydrazide zu Käfigen (2009) (10)
- Sterically encumbered lithium dialkynidoalanates Li[R 2 Al([sbnd]C[tbnd]C[sbnd]R') 2 ] [R = CH(SiMe 3 ) 2 ] (2006) (10)
- Aluminum and Gallium Hydrazides (2003) (10)
- Reaktionen der Digalliumverbindung R2Ga–GaR2 [R = CH(SiMe3)2] mit Wasser und Carbonsäuren – Synthese von μ‐Hydroxo‐μ‐carboxylatodigallium‐Verbindungen unter Erhalt der Ga–Ga‐Bindungen (2010) (9)
- Diazomethane Derivatives Bearing Dialkylaluminium or DialkylgalliumSubstituents – The Isomeric Diazomethane and Nitrile Imine Structures Realized by the Different Coordination Behavior of Aluminium and Gallium (1999) (9)
- Hydroalumination and hydrogallation of an aryl-chloro-dialkynylsilane: Si–Cl bond activation by intramolecular Al–Cl and Ga–Cl interactions (2016) (9)
- Die Insertion von Sauerstoffatomen in Ga–Ga‐ und In–In‐Bindungen – Bildung von monomeren Verbindungen R2E–O–ER2 [R = CH(SiMe3)2] mit stark aufgeweiteten E–O–E‐Winkeln (1999) (9)
- Gallium–Gallium Bonds Bridged by Functionalized Carboxylato Ligands (2010) (9)
- Synthesis of a large functional cage compound based on four Ga-Ga single bonds and its application as an oligoacceptor: on the way to bio-organogallium hybrid molecules. (2011) (9)
- 3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms. (2019) (9)
- Gallium–Gallium Bonds As Effective Templates for the Generation of Macrocycles and Supramolecular Entities (2012) (9)
- Benzil Derivatives as Trapping Reagents for the Monomeric Alkylindium(i) Compound in–c(SiMe3)3 (1997) (9)
- Reaction of an Al/P-based frustrated Lewis pair with benzophenone: formation of adducts and aluminium alcoholates via β-hydride elimination (2016) (8)
- Heterozyklische Verbindungen mit fünfgliedrigen ESi4‐Ringen (E = Ga, In) (2007) (8)
- Hydrometallation of amino-dialkynylgermanes – a gallium hydride oligomer and intramolecular Lewis acid-base interactions (2015) (8)
- A Dimeric Gallium Hydrazide as an Active Lewis Pair – Complexation and Activation of Me2GaH and Various Heterocumulenes (2017) (8)
- The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges (2003) (8)
- Dialkyl‐[5]trovacenylethinylaluminium‐ und –gallium Verbindungen {[5]Trovacenyl = (η7‐C7H7)V(η5‐C5H4‐)} ‐ Zur Frage magnetischer Austauschwechselwirkung über Trenngruppen mit Elektronenmangel‐Bindungssegmenten‡ (2009) (8)
- Reactivity of a P-H Functionalized Al/P-Based Frustrated Lewis Pair - Hydrophosphination versus Classic Adduct Formation (2017) (8)
- (2,2-Dimethylpropylidyne)phosphine (1990) (7)
- Ein gespanntes tricyclisches PC3‐Phosphan – Koordinationschemie und Insertion von Chalkogenatomen in P‐C‐Bindungen (2018) (7)
- [Ga9(CMe3)9].− – ein beständiges Clusterradikalanion; Bor-analoge Chemie mit dem schweren Homologen Gallium† (2003) (7)
- Functionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation. (2016) (7)
- Aluminium Functionalized Germanes: Intramolecular Activation of Ge-H Bonds, Formation of a Dihydrogen Bond and Facile Hydrogermylation of Unsaturated Substrates (2019) (7)
- Hydroalumination of Oligoalkynylgermanes and ‐digermanes – Reactions with Heterocumulenes by Al–C or Ge–C Bond Activation and Formation of a Hexazenedialuminum Complex (2018) (7)
- Aluminum and Gallium Hydrazides Derived from N-Aminopyrrole and N-Aminopiperidine (2006) (7)
- Thermolyse sterisch überladener Alanate; Synthese zweier neuer 1-Sila-3-alanata-cyclobutan-Derivate mit AlC2Si-Heterozyklus (1995) (7)
- Supramolecular Chemistry Based on Frustrated Lewis Pairs - Reactions of an Al/P FLP with Potassium Formate and Cesium Fluoride (2018) (7)
- Alkynyl functionalized Al/P-based frustrated Lewis pairs - aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-P=C=C(H)-(t)Bu]. (2015) (6)
- The missing link in the coordination chemistry of hydrazines--a hydrazinetriide [N-N(Me)](3-) anion coordinated to five Al atoms. (2012) (6)
- Hydrazine Adducts of Tri(tert-butyl)aluminum, -gallium and -indium – a Systematic Approach (2008) (6)
- cis/trans Isomers of Dimeric Dialkylaluminum and Dialkylgallium Hydrazides (2008) (6)
- Das Anion [R2Al-AlR2Br]- (R = CH(SiMe3)2) mit Aluminium-Aluminium- und terminaler Aluminium-Brom-Bindung / The Anion [R2Al-AlR2Br]- (R = CH(SiMe3)2) with an Aluminium -Aluminium and a Terminal Aluminium -Bromine Bond (1994) (6)
- Heterocyclic Digallanates, Encapsulation of Lithium Cations in Organometallic Cages and C–H Bond Activation† (2015) (6)
- Dihalides of Sterically Constrained Tricyclic Phosphines, Lewis Acidity and Fluoride Affinity, Chloride Abstraction, and a Phosphonium Cation, Dimethylphosphorane (2020) (6)
- GROUP 13 CLUSTER CHEMISTRY: ORGANOGALLIUM AND -INDIUM SUBHALIDES AND RADICALS (2004) (6)
- Hydroalumination of Ketenimines and Subsequent Reactions with Heterocumulenes: Synthesis of Unsaturated Amide Derivatives and 1,3-Diimines. (2015) (6)
- Terminale und verbrückende Koordination von Indium‐Indium‐Bindungen – bemerkenswerte Polymorphie an der Verbindung In2R2[(OCC6H5)2CH]2 [R = C(SiMe3)3] (2007) (6)
- Synthese und Molekülstruktur zweier 1‐Sila‐3‐alanata‐cyclobutan‐Derivate mit AlC2Si‐Heterozyklus (1994) (6)
- Silicon-Halogen Bond Activation in Mixed Si/Al Compounds and an Approach to Intramolecular Stabilized Silylium Ions (2019) (5)
- Organoaluminum Compounds and Lewis Pairs (2016) (5)
- On the reactions of the tetraindiumcluster In4[C(SiMe3)3]4 with phenylselenium and phenyltellurium bromides (2007) (5)
- Treatment of a Methylene‐Bridged Dialuminium Compound with Lithium Alkanides and Alkynides ‐ Single vs. Twofold Terminal Coordination (2012) (5)
- Organoelement Compounds Possessing Al—Al, Ga—Ga, In—In, and Tl—Tl Single Bonds (2004) (5)
- Aspects of phosphaallene chemistry - heat induced formation of 1,2-dihydrophosphetes by intramolecular nucleophilic aromatic substitution and photochemical generation of tricyclic phosphiranes. (2020) (4)
- Supramolecular Chemistry Based on Gallium–Gallium Single Bonds – Formation of Large Heterocycles and Cages with up to Twelve Gallium Atoms (2015) (4)
- Die Insertion von Chalkogenatomen in die Gallium‐Gallium‐Bindung von Acetat‐verbrückten Digallanen (2003) (4)
- σ‐Bond Activation in Aluminium‐Functionalized Alkynylchlorogermanes: Facile Insertion of Isocyanate and Azide into Al–C and Ge–Cl Bonds (2016) (4)
- Cooperative activation of azides by an Al/N-based active Lewis pair – unexpected insertion of nitrogen atoms into C–Si bonds and formation of AlCN3 heterocycles (2019) (4)
- Formation of a [4.3.0]-Bicyclic Aluminum-Phosphorus Compound with Annulated C3P2 and Al2C2PH Heterocycles and a 3c-2e Al–H–Al Bond† (2013) (4)
- ACYL- AND ALKYLIDENEPHOSPHINES. XV. 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE, A STABLE COMPOUND WITH A PHOSPHORUS ATOM OF COORDINATION NUMBER 1 (1981) (4)
- Ga‐Ga Bonds as Key Building Blocks for the Formation of Supramolecular Entities ‐ Unusual Macrocyclic Tetra‐ and Octagallium Compounds (2017) (4)
- New Organogallium Peroxides (2009) (3)
- New Ga/N‐based Active Lewis Pairs, Trifunctional Ga–Ga Compounds, Reactions with Cyanamide and Dual Insertion of Isocyanate (2019) (3)
- A Geometrically Constrained Tricyclic Phosphine: Coordination, Ring Expansion by Insertion of CO into a P–C Bond, and Lewis Acid Initiated Formation of an Oligocyclic Molecule with a P2C22 backbone (2020) (3)
- Treatment of the Digallium Compound R2Ga–GaR2 [R = CH(SiMe3)2] with Functionalized Dicarboxylic Acids: Macrocycles, Hydrogen Bonding, and Sulfur–Sulfur Closed‐Shell Interactions (2014) (3)
- Carbaalanes - A New Class of Compounds Containing Clusters of Aluminum and Carbon Atoms (2003) (3)
- Reactions of the Tetraalkyldigallium Compound R2Ga–GaR2 [R = CH(SiMe3)2] with Acidic Reagents, Retention vs. Cleavage of the Ga–Ga Bond and Formation of Supramolecular Aggregates via Hydrogen Bonding (2011) (3)
- The Methylene-bridged Dialuminium Compound R2Al-CH2-AlR2 [R=CH(SiMe3)2] as an Effective Chelating Lewis Acid – Adducts with Halides, Perchlorate and Isopropylamide (2012) (3)
- Tetrakis(bis(trimethylsilyl)methyl)dialane(4), a Compound with an Aluminum-Aluminum Bond. (1989) (2)
- Reactions of Al‐N Based Active Lewis Pairs with Ketones and 1,2‐Diketones: Insertion into Al‐N Bonds, C‐C and C‐N Bond Formation and a Tricyclic Saturated Tetraaza Compound (2020) (2)
- Hydroalumination of Nitriles and Isonitriles (2004) (2)
- Chemoselective Hydroalumination of 1-Aza-but-1-en-3-ynes (C-Iminoalkynes): Formation of Propargylamines by Imine Reduction and of 5-Aluminazoles and 1-Aza-butadienes by Anti-Michael Attack (2018) (2)
- Treatment of Tetramethylpyrazole and 3,5-Diphenylpyrazole with Dialkylaluminum Hydrides - Hydroalumination versus Deprotonation (2010) (2)
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- Heteropolyalanes, ‐gallanes, ‐indanes and ‐thallanes (2005) (1)
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- Frustriert, aber äußerst nützlich (2013) (1)
- Alkylidenephosphines and diphosphetanes (1987) (1)
- Solid‐State Nuclear Magnetic Resonance Techniques for the Structural Characterization of Geminal Alane‐Phosphane Frustrated Lewis Pairs and Secondary Adducts (2021) (1)
- Anorganische Chemie 1996 (1997) (1)
- Über Onium‐Salze von Verbindungen mit semipolar gebundenem Sauerstoff (1956) (1)
- Gerd Becker (1940-2017). (2017) (1)
- Main-Group-Metal Clusters Stabilized by N-Heterocyclic Carbenes (2009) (1)
- Palliative Therapie maligner distaler Gallenwegsverschlüsse – endoskopisch versus offen (2016) (1)
- MCl2 Molecules (M = Zn, Cd, Hg) Coordinated by Trifunctional E/P2-Based FLPs (E = Ga, In): Chelating Coordination of the Metal Atoms and Activation of M–Cl Bonds by E–Cl Interactions (2020) (1)
- Sterically constrained tricyclic phosphine: redox behaviour, reductive and oxidative cleavage of P–C bonds, generation of a dilithium phosphaindole as a promising synthon in phosphine chemistry†‡ (2021) (1)
- Ga(9)(CMe(3))(9), an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds E(n)R(n) (E=B-In) This work was supported by Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. (2001) (1)
- Hydrosilylation and Hydrogermylation of CO 2 and CS 2 by Al and Ga Functionalized Silanes and Germanes – Cooperative Reactivity with Formation of Silyl Formates and Disilylacetals (2020) (1)
- Neutral clusters EnRR of the monovalent elements gallium and indium, recent results in synthesis and reactivity (2003) (1)
- New Reactivity Patterns in 3H‐Phosphaallene Chemistry [Aryl‐P=C=C(H)‐tBu]: Hydroboration of the C=C Bond, Deprotonation and Trimerisation (2020) (1)
- Anorganische Chemie 1998 (1999) (1)
- CCDC 909576: Experimental Crystal Structure Determination (2017) (0)
- Bis(dichloro‐bis(trimethylsilyl)methylalane) ‐ Synthesis and Molecular Structure. (1991) (0)
- Molekül- und Kristallstruktur des orthorhombischen (Diphenylmethyliden)mesitylphosphans (Acyl- und Alkylidenphosphane ; 29) (1986) (0)
- Molekül- und Kristallstruktur des 2,4-Di{tert.butyl)-2,4-bis (trimethylsi loxy) -1 ,3-diphosphetans (1981) (0)
- Tetrakis(bis(trimethylsilyl)methyl)diindane(4) with Indium-Indium Bond. (1989) (0)
- Acyl- and Alkylidenephosphines. Part 28. Synthesis and Structure of 1,3-Dibenzyl and 1,3-Diethyl-2,4-bis(phenylimino)-1,3-diphosphetane. (1986) (0)
- Synthesis and Molecular Structure of a 1-Sila-3-alanatetane. (1990) (0)
- TRIMETHYLAMINOXIDADDUKTE AN TETRAKISBIS(TRIMETHYLSILYL)METHYLDIALUMINOXAN:R2AL-O-ALR2.ONME3 UND R2AL-O-ALR2.2ONME3 MIT GEWINKELTEN AL-O-AL-GRUPPEN (1995) (0)
- CCDC 840610: Experimental Crystal Structure Determination (2017) (0)
- Reactions of Tetrakis(bis(trimethylsilyl)methyl)dialane(4) with Methylisothiocyanate and Phenylisocyanate ‐ Insertion into the Al‐Al Bond and Fragmentation. (1996) (0)
- Oxy‐Borylenes as Photoreductants: Synthesis and Application in Dehalogenation and Detosylation Reactions (2022) (0)
- ACYL AND ALKYLIDENE PHOSPHINES. XII. SYNTHESIS AND PROPERTIES OF 2,2-DIMETHYLPROPIONYLPHOSPHINE AND OF SOME DERIVATIVES (1981) (0)
- Diphosphetanes from monomeric alkylidene phosphines (1981) (0)
- CCDC 292841: Experimental Crystal Structure Determination (2006) (0)
- Synthesis and Molecular Structure of a Bis(di(alkyl)alanyl)methane; R2Al-CH2-AlR2 (R: CH(SiMe3)2). (1990) (0)
- Acyl- and Alkylidenephosphines. Part 29. Molecular and Crystal Structure of Orthorhombic (Diphenylmethylidene)mesitylphosphine (1987) (0)
- Bis(bis(trimethylsilyl)methyl)gallium Bromide and Monomeric (Bis(bis( trimethylsilyl)methyl)gallium) (Tris(trimethylsilyl)silyl)telluride (( Me3Si)2CH)2Ga‐TeSi(SiMe3)3. (1992) (0)
- Tridentate Ligand with Three Carbanions as Donor Atoms: Formation of Dinuclear, Heptacyclic Complexes of Boron, Aluminum, or Gallium with B-C-B, Al-C-Al, or Ga-C-Ga Three-Center-Two-Electron Bonds. (2020) (0)
- PROGRAMMA MINI-SYMPOSIUM International Research Training Group "Generation of Supramolecular Functional Cavities-Container Molecules, Macrocycles and Related Compounds" (2008) (0)
- CCDC 840612: Experimental Crystal Structure Determination (2017) (0)
- N-Acyl- and N-Sulfonylformamidines from Cyanamides and Carbodiimides by Hydroalumination and Subsequent Treatment with Electrophiles. (2013) (0)
- CCDC 840609: Experimental Crystal Structure Determination (2017) (0)
- Solvent-Free Tris(trimethylsilyl)methyllithium. (1991) (0)
- Reactions of Ga2Br4×2 Dioxane with (Trimethylsilyl)methyllithium and Neopentyllithium ‐ Synthesis and Molecular Structure of Lithium Tetraalkylgallanates(III) with Li‐C‐Ga Bridges. (1991) (0)
- Organo‐Element Compounds with Al‐Al, Ga‐Ga, and In‐In Bonds (1994) (0)
- ACYL- AND ALKYLIDENEPHOSPHINES. XVI. (DIMETHYLAMINOMETHYLIDENE)- AND (DIPHENYLMETHYLIDENE)PHOSPHINES (1981) (0)
- Synthesis and Molecular Structure of Tetrakis(bis(trimethylsilyl)methyl)digallane(4) with a Ga-Ga Bond. (1989) (0)
- CCDC 118593: Experimental Crystal Structure Determination (1999) (0)
- Inorganic Chemistry 1999. Main Group Elements (2000) (0)
- ACYL- AND ALKYLIDENEPHOSPHINES. X. SYNTHESIS OF PHENYL(BIS(TRIMETHYLSILYLTHIO)METHYLIDENE)PHOSPHINE (1980) (0)
- Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules (2020) (0)
- CCDC 878408: Experimental Crystal Structure Determination (2013) (0)
- ACYL- AND ALKYLIDENE PHOSPHINES. 14. LITHIUM DIBENZOYLPHOSPHIDE-1,2-DIMETHOXYETHANE, A NEW 2-PHOSPHA-1,3-DIKETONATE (1980) (0)
- Frontispiece: Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis (2015) (0)
- CCDC 878407: Experimental Crystal Structure Determination (2013) (0)
- Organogallium(II) Compounds Bearing Chelating Ligands, Bridging versus Terminal Co‐ordination of Gallium—Gallium Single Bonds (2000) (0)
- Reaction of tert.-Butyllithium with Aluminumtribromide. Molecular Structures of (HAl(CMe3)2)3 and (LiHAl(CMe3)3)2. (1989) (0)
- Ga4(C(SiMe3)3)4) with a Tetrahedral Ga4 Skeleton. (1993) (0)
- Dialane Radical Anions (R2Al-AlR2).times± (1993) (0)
- Cyclopentadienyl-, Indenyl- and Fluorenyl-Functionalized N-Heterocyclic Carbene Metal Complexes: Synthesis and Catalytic Applications Cyclopentadienyl-NHC Iron Complexes for Solvent-Free Catalytic Hydrosilylation of Aldehydes and Ketones Hydroalumination (2012) (0)
- Synthese des Phenyl-bis(trimethylsilylsulfano }methyliden phosphans (1980) (0)
- ACYL AND ALKYLIDENE PHOSPHINES. XIII. MOLECULAR AND CRYSTAL STRUCTURE OF 2,4-DI(TERT-BUTYL)-2,4-BIS(TRIMETHYLSILOXY)-1,3-DIPHOSPHETANE (1981) (0)
- K2(Al12iBu12), a Compound with Al12 Icosahedra. (1991) (0)
- The Reactivity of Organoelement Compounds with Aluminum—Aluminum, Gallium—Gallium, and Indium—Indium Bonds (1998) (0)
- Synthesis and Molecular Structure of a Dimeric Organometallic Indiumsubfluoride (2014) (0)
- CCDC 840611: Experimental Crystal Structure Determination (2017) (0)
- Tetrahedral Homonuclear Organoelement Clusters and Subhalides of Aluminum, Gallium and Indium (2005) (0)
- The Insertion of Oxygen Atoms into Ga—Ga and In—In Bonds — Formation of the Monomeric Compounds R2E—O—ER2 [R = CH(SiMe3)2] with Strongly Enlarged Angles E—O—E (1999) (0)
- μ‐Methylene‐bis(chloro‐bis(trimethylsilyl)methylalane), (Me3Si)2CH( Cl)Al‐CH2‐Al(Cl)CH(SiMe3)2, with a Heteroadamantane Structure. (1991) (0)
- 2,2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1 (Acyl- und Alkylidenphosphane ; 15) (1981) (0)
- CCDC 1557573: Experimental Crystal Structure Determination (2018) (0)
- MONOMERES (ME3SI)2CH2AL-TE-ALCH(SIME3)22 MIT GEWINKELTER AL-TE-AL-GRUPPE (1994) (0)
- Anorganische Chemie 1997 (1998) (0)
- Bis(2,2-dimethylpropionyl)phosphan und Bis(2,2-dimethylpropionyl)phosphide (Acyl- und Alkylidenphosphane ; 20) (1982) (0)
- Coordination Chemistry of Aluminum. Herausgegeben von G. H. Robinson. VCH Verlagsgesellschaft, Weinheim/VCH Publishers, New York, 1993. XIII, 234 S., geb. 189.00 DM/115.00 $. ‐ ISBN 3‐527‐28 149‐5/1‐56081‐059‐9 (1994) (0)
- Synthese des Phenyl-bis(trimethylsilylsulfano)methyliden phosphans (Acyl- und Alkylidenphosphane ; 10) (1980) (0)
- Molekül- und Kristallstruktur des 2,4-Di(tert.butyl)-2,4-bis-(trimethylsiloxy)-1,3-diphosphetans (Acyl- und Alkylidenphosphane ; 13) (1981) (0)
- Synthese und Eigenschaften des 2,2-Dimethylpropionylphosphans und einiger Derivate (Acyl- und Alkylidenphosphane ; 12) (1981) (0)
- Synthese und Struktur von 1,3-Dibenzyl- und 1,3-Diethyl-2,4-bis(phenylimino)-1,3-diphosphetan (Acyl- und Alkylidenphosphane ; 28) (1986) (0)
- des 2,2-Dimethylpropionylphosphans und einiger Derivate (1981) (0)
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