William Summer Johnson
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Chemistry
William Summer Johnson's Degrees
- PhD Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
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(Suggest an Edit or Addition)William Summer Johnson's Published Works
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Published Works
- Simple stereoselective version of the Claisen rearrangement leading to trans-trisubstituted olefinic bonds. Synthesis of squalene (1970) (516)
- Notes - Osmium Tetroxide-Catalyzed Periodate Oxidation of Olefinic Bonds (1956) (504)
- Nonenzymic biogenetic-like olefinic cyclizations (1968) (154)
- Asymmetric synthesis via acetal templates. 3. On the stereochemistry observed in the cyclization of chiral acetals of polyolefinic aldehydes; formation of optically active homoallylic alcohols (1983) (144)
- Affinity chromatography : a practical approach (1985) (139)
- The Proton Magnetic Resonance Spectra of Some α-Acetoxy Ketones (1961) (136)
- Biomimetic polyene cyclizations. (1976) (122)
- Acetylenic bond participation in biogenetic-like olefinic cyclizations. II. Synthesis of dl-progesterone. (1971) (97)
- A highly stereoselective synthesis of trans-trisubstituted olefinic bonds (1968) (96)
- The Energy Difference between the Chair and Boat Forms of Cyclohexane. The Twist Conformation of Cyclohexane (1961) (95)
- Methylation of Alcohols with Diazomethane (1958) (85)
- Biomimetic polyene cyclizations (1976) (83)
- An improved reagent for the o-alkyl cleavage of methyl esters by nucleophilic displacement (1970) (75)
- A Plan for Distinguishing between Some Five- and Six-membered Ring Ketones (1945) (66)
- Asymmetric synthesis via chiral acetal templates. 7. Further studies on the cyanation reaction. The use of acetals derived from diols with one chiral center (1984) (66)
- MORBIDITY AND MORTALITY IN PSEUDOPOLYCYTHÆMIA (1975) (63)
- Fifty years of research (1991) (62)
- Asymmetric synthesis via acetal templates. 4. Reactions with silylacetylenic compounds. Formation of chiral propargylic alcohols (1983) (60)
- The fluorine atom as a cation-stabilizing auxiliary in biomimetic polyene cyclizations. IV: Total synthesis of dl-β-amyrin (1993) (59)
- Cation-stabilizing auxiliaries: a new concept in biomimetic polyene cyclization (1987) (59)
- Cyclization Studies in the Quinoline Series. A New Synthesis of 4-Aminoquinolines (1949) (55)
- A stereospecific total synthesis of estrone via a cationic olefinic cyclization. (1973) (54)
- Reduction of Steroidal Enamines (1963) (53)
- The First Examples of Nonenzymic, Biomimetic Polyene Pentacyclizations. Total Synthesis of the Pentacyclic Triterpenoid Sophoradiol (1994) (52)
- A new synthesis of fused ring structure related to the steroids; the 17-equilenones; a total synthesis of equilenin. (1947) (51)
- Asymmetric synthesis via acetal templates. 12. Highly diastereoselective coupling reactions with a ketene acetal. An efficient, asymmetric synthesis of R-(+)-α-lipoic acid☆ (1985) (51)
- Ring-A α-Acetoxy Ketones in the Cholestane Series (1961) (50)
- Biomimetic polyene cyclizations. Asymmetric induction in the cyclization of a dienic acetal (1976) (49)
- A highly stereoselective synthesis of the racemic juvenile hormone (1968) (48)
- Inhibition of 2,3-oxidosqualene cyclases. (1992) (48)
- Asymmetric synthesis via acetal templates. 5. Reactions with cyanotrimethylsilane. Enantioselective preparation of cyanohydrins and derivatives (1983) (46)
- Nonenzymic biogenetic-like olefinic cyclizations. Stereospecific cyclization of dienic acetals (1973) (45)
- Rate enhancement of biomimetic polyene cyclizations by a cation-stabilizing auxiliary (1987) (44)
- Asymmetric induction of an olefinic acetal cyclization (1968) (44)
- The Total Synthesis of Estrone and Three Stereoisomers Including Lumiestrone (1952) (44)
- Asymmetric total synthesis of 11.alpha.-hydroxyprogesterone via a biomimetic polyene cyclization (1977) (43)
- Asymmetric synthesis via acetal templates. 15. The preparation of enantiomerically pure mevinolin analogs (1988) (43)
- Asymmetric synthesis via acetal templates. 13. Preparation of aldol compounds from butane-1,3-diol acetals (1987) (41)
- A new approach to steroid total synthesis. A nonenzymic biogenetic-like olefinic cyclization involving the stereospecific formation of five asymmetric centers (1968) (40)
- The Nature of the Intermediary Ketols in the Robinson Annelation Reaction1 (1960) (40)
- The synthesis of the optically active form of the C-18 Cecropia juvenile hormone. (1971) (39)
- Acetylenic bond participation in biomimetic polyene cyclizations. Model studies directed toward the synthesis of 20-keto steroids. Synthesis of dl-progesterone and dl-.DELTA.4-androstene-3,17-dione (1978) (39)
- Introduction of the Angular Methyl Group. III. The Alkoxymethylene Blocking Group1 (1947) (39)
- Cyclization Studies in the Benzoquinoline Series (1944) (39)
- Asymmetric synthesis via acetal templates. 6. A stereoselective approach to a key intermediate for the preparation of vitamin D metabolites (1984) (39)
- Further developments in the nonenzymic biogenetic-like steroid synthesis. (1970) (38)
- Olefinic ketal Claisen reaction. Facile route to juvenile hormone (1970) (38)
- Propargylsilane function as a terminator of biomimetic polyene cyclizations leading to steroids (1980) (37)
- Asymmetric synthesis via acetal templates. 9. Further studies of the allylation reaction. Preparation of (−)-dihydromyoporone (1984) (37)
- Studies Relating to the Formation and Reactions of Glycidic Esters (1953) (37)
- Cation-stabilizing auxiliaries in polyene cyclizations. 5. The fluorine atom as a cation-stabilizing auxiliary in biomimetic polyene cyclizations. 2. Asymmetric synthesis of a steroid (1993) (37)
- Steroid Total Synthesis—Hydrochrysene Approach. VII.1 Metal-in-Ammonia Reduction of the Aromatic Nucleus. dl-Epiandrosterone and the Lumi Epimer (1956) (36)
- 14-Isoestrone Methyl Ether and its Identity with Totally Synthetic Material (1957) (35)
- Acetylenic bond participation in biogenetic-like olefinic cyclizations. I. Formation of five-membered rings in model systems (1971) (34)
- A HIGHLY STEREOSELECTIVE ROUTE TO CALCITRIOL LACTONE (1985) (34)
- The Synthesis of Ketones from Di-t-butyl Malonates (1952) (34)
- Cationic Cyclizations Involving Olefinic Bonds. II.1 Solvolysis of 5-Hexenyl and trans-5,9-Decadienyl p-Nitrobenzenesulfonates (1964) (34)
- Selective recognition of the m5CpG dinucleotide sequence in DNA by mitomycin C for alkylation and cross-linking. (1995) (33)
- Asymmetric synthesis via chiral acetal templates. 8. Reactions with organometallic reagents (1985) (33)
- Cyanide poisoning successfully treated without 'therapeutic methemoglobin levels'. (1989) (33)
- The Action of Lead Tetraacetate on an Enol Acetate. The Epimeric 16-Acetoxy Derivatives of Epiandrosterone Acetate, their Interconversion and Rearrangement (1957) (33)
- Derivatives of 5-Methoxyhydrindene and 6-Methoxytetralin. Synthesis of β-(2-Carboxy-5-methoxyphenyl)-propionic Acid1 (1944) (33)
- Improved asymmetric total synthesis of corticoids via biomimetic polyene cyclization methodology (1981) (33)
- 1,2-Dihydroquinoline (1952) (33)
- Cation-stabilizing auxiliaries in polyene cyclizations. 6. The fluorine atom as a cation-stabilizing auxiliary in biomimetic polyene cyclizations. 3. Use to effect regiospecific control (1993) (33)
- Configuration of the Estrones. Total Synthesis of the Remaining Stereoisomers (1958) (33)
- Cation-stabilizing auxiliaries in polyene cyclizations. 4. The fluorine atom as a cation-stabilizing auxiliary in biomimetic polyene cyclizations. 1. Background and exploratory experiments (1993) (32)
- Novel synthesis of longifolene (1975) (32)
- Asymmetric Synthesis via Acetal Templates. 14.1 Preparation of Enantiomerically Pure (3S,4S)- and (3S,4R)-Statine Derivatives (1987) (32)
- Ring Closure of the 2-Benzoylaminocyclohexanols. The Mechanism of Oxazoline Formation (1950) (32)
- Stereospecific tricyclization of a polyolefinic acetal. (1966) (30)
- The Acid-catalyzed Reaction of Diazomethane with Some α,β-Unsaturated Ketones (1962) (30)
- The configuration of cevine (1959) (30)
- Introduction of the Angular Methyl Group. The Preparation of cis- and trans-9-Methyldecalone-11 (1943) (29)
- Synthesis of veratramine (1967) (28)
- Energy Relationships of Fused Ring Systems (1953) (28)
- Steroid Total Synthesis--Hydrochrysene Approach. XV.1 Total Synthesis of Aldosterone (1963) (28)
- Stereochemical Control of the Angular Methylation of Fused Ring Ketones (1962) (27)
- Steroid Total Synthesis—Hydrochrysene Approach. X.1 Total Synthesis of Testosterone (1956) (27)
- Olefinic Cyclizations. VIII.1 The Butenylmethylcyclohexenol System (1965) (27)
- Further Studies on the Energy Difference between the Chair and Twist Forms of Cyclohexane (1963) (27)
- Total Synthesis of Racemic Conessine (1962) (27)
- The Fluorine Atom as a Cation-Stabilizing Auxiliary in Biomimetic Polyene Cyclizations: Total Synthesis of dl-Dammarenediol1 (1999) (26)
- Cyclization Studies in the Benzoquinoline and Naphthoquinoline Series. II (1947) (26)
- Nonenzymic, biogenetic-like cyclization of a tetraenic acetal to produce the D-homosteroid nucleus (1974) (26)
- Epoxide-initiated cationic polyene cyclisations (1993) (26)
- Vinyl fluoride function as a terminator of biomimetic polyene cyclizations leading to steroids (1980) (26)
- Δ2,6-Hexalin-1,5-dione (1963) (24)
- Cationic Cyclizations Involving Olefinic Bonds. IV.1 The Butenylcyclohexenol System (1964) (24)
- 4-(p-Hydroxyphenyl)-cyclohexanecarboxylic Acid and Derivatives (1946) (24)
- Decalin-1,5-dione (1951) (23)
- The Acid-Catalyzed Decarboxylation of Cinnamic Acids (1949) (23)
- Extension of the Modified Stobbe Condensation. Acid-Catalyzed Decomposition of the Products and a Lacto—Enoic Tautomerism1 (1947) (23)
- Direct formation of the steroid nucleus by a nonenzymic biogenetic-like cyclization. Preparation of the cyclization substrate. (1973) (23)
- Termination of biomimetic cyclizations by the allylsilane function. Formation of the steroid nucleus in one step from an acyclic polyenic chain (1983) (23)
- Olefinic cyclizations. XI. Allylic cation promoted olefinic cyclizations. The stereospecific formation of a tricyclic system and the total synthesis of dl-fichtelite (1968) (23)
- Direct formation of the steroid nucleus by a biomimetic cyclization (1980) (23)
- Neutrophil pyruvate kinase deficiency with recurrent staphylococcal infections: first reported case. (1976) (22)
- Ranitidine and bradycardia. (1988) (22)
- Letter: A stereospecific total synthesis of racemic 11alpha-hydroxyprogesterone via a biomimetic polyene cyclization. (1976) (22)
- 45. A stereoselective total synthesis of œstrone, and related studies (1962) (21)
- Steroid Total Synthesis—Hydrochrysene Approach. V.1 Introduction of Oxygen at the 11-Position (1956) (21)
- THE ENERGY DIFFERENCE BETWEEN THE BOAT AND CHAIR FORMS OF CYCLOHEXANE (1960) (21)
- Olefinic Cyclizations. VII. Formolysis of cis- and trans-5,9-Decadienyl p-Nitrobenzenesulfonate and of Some Isomeric Monocyclic Esters*,1,2 (1965) (21)
- The Stobbe Condensation with 2-Acetylnaphthalene. A Synthesis of 2,4-Dimethylphenanthrene (1945) (20)
- New Structural and Stereochemical Aspects of the Cyclization of Olefinic Acetals (1967) (20)
- A Total Synthesis of Estrone and 14-Isoestrone (1957) (20)
- BIOMIMETIC POLYENE CYCLIZATIONS. PARTICIPATION OF THE (TRIMETHYLSILYL)ACETYLENIC GROUP AND THE TOTAL SYNTHESIS OF THE D-HOMOSTEROID SYSTEM (1980) (20)
- Morbidity and mortality in pseudopolycythaemia. (1975) (20)
- Comprehensive organic chemistry volume 5 (Biological compounds): Edited by E. Haslam (1979) (20)
- Formation of vinyl halides from vinyl cations generated by acetylenic participation in biomimetic polyene cyclizations (1981) (19)
- Revision of the configuration of veratramine and jervine (1967) (19)
- The nonenzymic, biogenetic-like cyclization of a tetraenic acetal (1968) (19)
- The Hydroborating Properties of Sodium Borohydride and Acetic Acid (1963) (19)
- The Stobbe Condensation with Sodium Hydride1 (1948) (19)
- Ring E degradation in the veratramine series (1964) (18)
- Nonenzymic biogenetic-like cyclizations. Synthesis and cyclization of 4-(trans, trans-7,12-dimethyl-3,7-11-tridecatrienyl)-3-methyl-2-cyclohexen-1-ol and of its allylic isomer (1974) (18)
- Biomimetic polyene cyclizations. Cationic cyclization of a substrate having an internal acetylenic bond. Synthesis of euphol and tirucallol (1990) (18)
- Chiral Acetal-Initiated Asymmetric Pentacyclization. Enantioselective Synthesis of 18.alpha.(H)-Oleananes (1994) (18)
- The Mechanism of the Stobbe Condensation (1950) (17)
- A new method of producing fused ring structures related to the steroids; a synthesis of equilenin. (1945) (17)
- BIOMIMETIC POLYENE CYCLIZATIONS. PARTICIPATION OF THE PHENYLACETYLENIC GROUP AS A TERMINATOR AND THE FORMATION OF C/D CIS STEROIDAL PRODUCTS (1979) (17)
- 2-Methyl-2-cyclohexenone (1953) (17)
- Syntheses in the 1,2-Benzanthracene and Chrysene Series (1939) (17)
- A New Synthesis of Chloroquine (1952) (17)
- Concerning the mechanism of a nonenzymic biogenetic-like olefinic cyclization. (1973) (17)
- Cation-stabilizing auxiliaries in polyene cyclization. 3. Chiral acetal induced asymmetric polyene tetracyclization assisted by a cation-stabilizing auxiliary (1989) (16)
- The Stobbe Condensation with Tetralone-1. A Synthesis of 3'-Keto-3,4-dihydro-1,2-cyclopentenonaphthalene1 (1945) (16)
- Steroid Total Synthesis—Hydrochrysene Approach. III.1 Reduction of the Olefinic Bonds and of the Carbonyl Group in 1-Methoxy-8-keto-10a-methyl-5,6,8,9,10,10a,11,12-octahydrochrysene (1956) (16)
- Steroid Total Synthesis—Hydrochrysene Approach. IV.1 1-Methoxy-6a-hydroxy-8-keto-10a-methyl-5,6,6a,7,8,9,10,10a,11,12- decahydrochrysene and Reduction Products (1956) (16)
- TOTAL SYNTHESIS OF EPIANDROSTERONE (1953) (16)
- The Stobbe Condensation with Cyclohexanone (1948) (16)
- Letter: Biomimetic polyene cyclizations. Asymmetric induction by a chiral center remote from the initiating cationic center. 11alpha-methylprogesterone. (1976) (16)
- Olefinic cyclizations. IX. Further observations on the butenylcyclohexenol system (1967) (16)
- TOTAL SYNTHESIS OF ALDOSTERONE (1958) (16)
- Steroid Total Synthesis—Hydrochrysene Approach. VIII.1 dl-3β,11β-Dihydroxyandrostane-17-one (1956) (16)
- Intramolecular Acylation. II.1 The Inverse Friedel--Crafts Method (1949) (15)
- Total synthesis of dl-spironolactone and dl-19-norspironolactone by biomimetic polyene cyclization methodology (1982) (15)
- Some Observations on Friedel-Crafts Reactions Involving Unsaturated Ketones. 9-Keto-4b,5,6,7,8,8a,9,10-octahydrophenanthrene (1946) (15)
- THE TOTAL SYNTHESIS OF ESTRONE AND THE REMAINING STEREOISOMERS (1950) (15)
- Application of the chloro ketal Claisen reaction to the total synthesis of squalene. (1970) (15)
- A Record of Cleaning Symbiosis Involving Gobiosoma sp. and a Large Caribbean Octopus (1982) (15)
- An efficient, stereospecific polyolefinic cyclization. Total synthesis of dl-fichtelite. (1966) (14)
- Nonenzymic biogenetic-like olefinic cyclizations. Cyclization of 1-methyl-6-(trans, trans-7,11-dimethyl-3,7,11-dodecatrienyl)-2-cyclohexen-1-ol (1974) (14)
- Acetylenic bond participation in biogenetic-like olefinic cyclizations. Wagner-Meerwein rearrangement of a linear to a bent vinyl cation (1972) (14)
- 1,3-Diaxial Hydrogen Bonding and the Intramolecular Assistance of Solvolysis (1960) (14)
- PARTICIPATION OF THE STYRENE GROUP AS A TERMINATOR OF BIOMIMETIC POLYENE CYCLIZATIONS. FORMATION OF THE TRANS-8-METHYLHYDRINDAN RING SYSTEM (1976) (14)
- An approach to taxodione involving biomimetic polyene cyclization methodology (1982) (13)
- Reactions Involving Ester-Exchange (1945) (13)
- Nonenzymic biogenetic-like olefinic cyclizations. Cyclization of 4-(trans-3,7-octadienyl)-3-methyl-2-cyclohexen-1-ol and 4-(trans, trans-7-methyl-3,7,11-dodecatrienyl)-3-methyl-2-cyclohexen-1-ol (1974) (13)
- Synthesis of 6-Hydroxy-3,4-benzpyrene and 8-Isopropyl-1,2-benzanthracene from 9,10-Dihydrophenanthrene (1940) (13)
- Corticoid synthesis via vinylic fluoride-terminated biomimetic polyene cyclizations (1982) (13)
- The Stobbe Condensation with 1-Keto-2-methyl-7-methoxy-1,2,3,4-tetrahydrophenanthrene. A New Synthesis of Equilenin1 (1950) (13)
- The tetramethylallyl cation as a surrogate for the epoxide function as an initiator of biomimetic polyene pentacyclizations. Total synthesis of sophoradiol (1994) (13)
- Total Synthesis of dl-18-Norestrone1 (1962) (13)
- Direct formation of the steroid nucleus by a nonenzymic biogenetic-like cyclization. Cyclization and proof of structure and configuration of products. (1973) (13)
- Synthetic Applications of the Abnormal Reimer-Tiemann Reaction (1959) (13)
- Participation of the allylsilane group as a terminator of biomimetic polyene cyclizations to form steroid-like products (1979) (13)
- STEREOSELECTIVE INDUCTION OF BIOMIMETIC POLYENE CYCLIZATIONS BY REMOTE CHIRAL CENTERS. EFFECT OF A PRO-C-7 SUBSTITUENT IN A SUBSTRATE LEADING TO STEROIDAL PRODUCTS (1982) (13)
- Production of a Fused-Ring System by an Intramolecular Michael Condensation (1962) (12)
- The Course of the Mannich Reaction with Isopropyl Methyl Ketone. Preparation of Isopropyl Vinyl Ketone (1962) (12)
- An application of the trost reaction to the stereoselective synthesis of trans-tetrasubstituted fluoroalkenes (1992) (12)
- Steroid Total Synthesis—Hydrochrysene Approach. VI.1 Catalytic Hydrogenation of the Aromatic Nucleus. Synthesis of dl-3β-Acetoxy-14-iso-etioallohomobilianic Acid (1956) (12)
- Orientation isomers of the mitomycin C interstrand cross-link in non-self-complementary DNA. Differential effect of the two isomers on restriction endonuclease cleavage at a nearby site. (1993) (12)
- Steroid Total Synthesis—Hydrochrysene Approach. II.1 1-Methoxy-8-keto-10a-methyl-5,6,8,9,10,10a,11,12-octahydrochrysene (1956) (11)
- A fifty-year love affair with organic chemistry (1998) (11)
- Some Observations on the Steroid Ring-D-Fission C-Aromatization Reaction (1966) (11)
- Olefinic Cyclizations. VI. Formolysis of Some Branched-Chain Alkenyl p-Nitrobenzenesulfonates (1964) (11)
- Steroid Total Synthesis—Hydrochrysene Approach. I. General Plan and Summary of Major Objectives (1956) (11)
- The Cyclization of β-p-Methoxyphenylpropionic Acid (1945) (11)
- Introduction of the Angular Methyl Group. II.1cis- and trans-8-Methylhydrindanone-12 (1944) (11)
- Acetylenic bond participation in biogenetic-like olefinic cyclizations in nitroalkane solvents. A facile total synthesis of dl-testosterone benzoate. (1973) (11)
- Total synthesis of the racemic form of the second juvenile hormone (methyl 12-homojuvenate) from the cecropia silk moth. (1969) (11)
- The synthesis of conessine from the corresponding 3-keto-Δ4-unsaturated system (1961) (10)
- A NEW TOTAL SYNTHESIS OF ESTRONE (1951) (10)
- Tetrahydroacenaphthene and the Mills--Nixon Effect (1949) (10)
- Biomimetic polyene cyclizations. Participation of the methylacetylenic terminator and nitroalkanes. A synthesis of testosterone (1980) (10)
- The Dimer of 2-Methylenecyclohexanone (1953) (10)
- 2,2-Dimethoxypropane, a rapid dehydrating agent for scanning electron microscopy (1976) (10)
- Biomimetic polyene cyclizations. Total synthesis of dl-19-nor-4-pregnen-20-one. Asymmetric induction by the initiating center (1980) (10)
- Biomimetic polyene cyclizations. Trapping of the resultant carbocation by an internal nucleophile (1979) (9)
- Acetylenic bond participation in biomimetic polyene cyclizations. Preliminary model studies (1978) (9)
- Nonenzymic, biogenetic-like cyclization of a trienic acetal (1971) (9)
- STEREOCHEMICAL CONTROL OF ANGULAR METHYLATION. A STEREOSELECTIVE TOTAL SYNTHESIS OF A 9,11-DEHYDROSTEROID (1957) (8)
- The Stobbe Condensation with 1-Keto-1,2,3,4-tetrahydrophenanthrene. A Synthesis of 3'-Keto-3,4-dihydro-1,2-cyclopentenophenanthrene1 (1945) (8)
- The carboalkoxyallylsilane terminator for biomimetic polyene cyclizations. A route to 21-hydroxyprogesterone types (1986) (8)
- A three-step synthesis of fichtelite from abietic acid (1967) (8)
- A biogenetically patterned concept for the laboratory synthesis of cyclic compounds (1960) (8)
- Biomimetic polyene cyclizations. Participation of the trimethylsilylacetylenic group as a terminator and the total synthesis of a D-homosteroid☆ (1978) (8)
- Entry into the podocarpane series through a biogenetic-like stereoselective olefin cyclization (1969) (8)
- 2,8-Dihydroxy-5,6,11,12-tetrahydrochrysene (1952) (8)
- 8-Methyl-1,2-benzanthracene (1939) (8)
- Application of the chloro ketal claisen reaction to the total synthesis of squalene. Experimental details. (1970) (7)
- BIOMIMETIC POLYENE CYCLIZATIONS. SYNTHESIS AND CYCLIZATION OF 1,3-DIMETHYL-2-(3-METHYL-TRANS-3,7-OCTADIENYL)CYCLOHEX-2-EN-1-OL (1977) (7)
- Steroid Total Synthesis—Hydrochrysene Approach. XIV.1 The Synthesis of dl-18-Norepiandrosterone and dl-18-Nortestosterone2 (1962) (7)
- The Stobbe Condensation with Ethyl γ-Anisoylbutyrate. A New Route to Some Estrone Intermediates (1950) (7)
- Studies on Opening the Rings of Cyclic Ketones (1945) (7)
- Recent studies on the synthesis of homocyclic systems (1963) (7)
- Cationic Cyclizations Involving Olefnic Bonds. III.1 On the Mechanism of Formation of trans-Fused Rings (1964) (7)
- The Stobbe Condensation with Methyl p-Tolyl Ketone. A Synthesis of Cadalene (1947) (7)
- Acetylenic bond participation in biogenetic-like olefinic cyclizations in nitroalkane solvents. Synthesis of the 17-hydroxy-5 beta-pregnan-20-one system. (1973) (7)
- The Stobbe Condensation with 6-Methoxy-2-propionylnaphthalene. A Synthesis of Bisdehydrodoisynolic Acid1 (1950) (7)
- Synthesis of dendrolasin (1969) (7)
- Studies in Decarboxylation and Lacto—Enoic Tautomerism. III.1 The Stobbe Condensation with p,p'-Dimethoxybenzophenone (1950) (6)
- A short stereoselective synthesis of some terpenes from the pheromonal secretion of the queen and monarch butterflies (1972) (6)
- Totally Synthetic Lumiestrone (1951) (6)
- The Condensation of 1-Methyl-2-acetylcyclohexene with 1-Decalone, and with 1,5-Decalindione (1950) (6)
- A Procedure for Acetate Pyrolysis. The Preparation of 2-Cyclohexenone (1962) (6)
- Studies in Decarboxylation and Lacto—Enoic Tautomerism. IV.1Paraconic Acids2 (1950) (6)
- A novel fragmentation reaction (1963) (6)
- The proton magnetic resonance spectra of the lα-deuterio-2-acetoxycholestane-3-ones. A contribution to the mechanism of dehydrohalogenation of α-halo ketones (1962) (6)
- The reaction of steroidal 4,6-dien-3-ones with cyanide (1963) (6)
- ON THE CONFIGURATION OF CEVINE (1956) (6)
- A new reaction of diazomethane with α,β-unsaturated ketones (1960) (5)
- 4-(p-Hydroxyphenyl)-hexahydroacetophenone and Homologs (1945) (5)
- A Synthesis of 1-Keto-1,2,3,4,9,10-hexahydrophenanthrene (1946) (5)
- The Condensation of 2-Acetylnaphthalene with Diethyl Succinate1 (1944) (5)
- THE TETRAACETYL-β-GLUCOSIDE OF DESOXYCORTICOSTERONE (1941) (4)
- The Unexpected Fate of an Attempted Steroid Synthesis (1962) (4)
- DIRECT FORMATION OF THE STEROID NUCLEUS BY A NONENZYMIC BIOGENETIC-LIKE CYCLIZATION, CYCLIZATION AND POOF OF STRUCTURE AND CONFIGURATION OF PRODUCTS (1973) (4)
- Structure of the Adduct of 3-Methyl-2-cyclohexenone and Ethyl Cyanoacetate. The Question of “Meta”- and “Para”-Bridged Rings (1953) (4)
- Potential Steroid Substitutes. I. Introductory Remarks. The Synthesis of Some Dioxoperhydroanthracenes (1959) (4)
- TOTAL SYNTHESIS OF TESTOSTERONE (1955) (4)
- Structure and Hydrogenation of Key Intermediates in the Equilenin Synthesis1,2 (1951) (4)
- Cation-Stabilizing Auxiliaries in Polyene Cyclizations. Part 7. The Fluorine Atom as a Cation-Stabilizing Auxiliary in Biomimetic Polyene Cyclizations. Part 4. Total Synthesis of dl-β-Amyrin. (1993) (4)
- A general synthesis of vinylic fluorides (1985) (4)
- Steroid Total Synthesis—Hydrochrysene Approach. IX.1 Preparation of Comparison Substances by Partial Synthesis (1956) (4)
- INTRODUCTION OF THE ANGULAR METHYL GROUP (1945) (4)
- Asymmetric total synthesis of 11alpha-hydroxyprogesterone via a briomimetic polyene cyclization. (1977) (4)
- The relative stability of stereoisomeric forms of fused ring systems (1951) (4)
- Steroid total synthesis—hydrochrysene approach—XVI (1966) (4)
- The biomimetic cyclization of I,3-dimethyl-2-(trans-trans-7,II-dimethyl-3,7,II-dodecatrienyl)-2-cyclohexenol to give the d-homosteroid nucleus (I) (1975) (3)
- The Stobbe Condensation (2011) (3)
- 8-alpha, 9-beta-estrone methyl ether, the elusive boat C-ring isomer. (1968) (3)
- Cationic Cyclizations Involving Olefinic Bonds. V.1 Solvolysis of cis-5,9-Decadienyl p-Nitrobenzenesulfonate (1964) (3)
- Nonenzymic biogenetic-like olefinic cyclizations. (1967) (3)
- TOTAL SYNTHESIS OF AN 11-OXYGENATED STEROID (1954) (3)
- ACETYLENIC BOND PARTICIPATION IN BIOGENETIC-LIKE OLEFINIC CYCLIZATIONS IN NITROALKANE SOLVENTS, SYNTHESIS OF THE 17-HYDROXY-5BETA-PREGNAN-20-ONE SYSTEM (1973) (3)
- Biomimetic polyene cyclizations. The synthesis and cyclization of 2-(4-pentenyl)-2-cyclohexenol (1977) (3)
- The Fluorine Atom as a Cation‐Stabilizing Auxiliary in Biomimetic Polyene Cyclizations: Total Synthesis of dl‐Dammarenediol. (2000) (3)
- Steroid total synthesis--benzhydrindane approach preliminary survey (1961) (3)
- 18, 19-BIS-NOR-D-HOMOTESTOSTERONE (1954) (3)
- A novel ring contraction leading to the veratramine nucleus (1963) (3)
- On the C-9 configuration of veratramine and jervine (1963) (3)
- d1-18-Nortestosterone (1960) (3)
- Numerical corrections for Hall effect measurements in silicon containing Gaussian dopant distributions (1970) (3)
- The Stobbe Condensation with 1-Keto-2-methyl-1,2,3,4-tetrahydrophenanthrene. A New Approach to β-17-Equilenone (1949) (3)
- Cation‐Stabilizing Auxiliaries in Polyene Cyclizations. Part 6. Fluorine Atom as a Cation‐Stabilizing Auxiliary in Biomimetic Polyene Cyclizations. Part 3. Use to Effect Regiospecific Control. (1993) (2)
- BIS-DEHYDRODOISYNOLIC ACID (1948) (2)
- Di‐tert‐butyl Malonate (2003) (2)
- 18-NOR-D-HOMOANDROSTANE-3,17a-DIONE (1953) (2)
- AN EXPERIMENTAL METHOD FOR DETERMINING A-VALUES: THE METHYL GROUP. (1965) (2)
- An alternative synthesis of 17-acetyl- 5α-etiojerva-12,14,16- trien-3β-ol (1968) (2)
- A New Synthesis of the 6-Methoxy-17-equilenones and Some Stereochemical Considerations (1951) (2)
- β‐Carbethoxy‐γ,γ‐Diphenylvinylacetic Acid (2003) (2)
- The Formation of Cyclic Ketones by Intramolecular Acylation (2011) (2)
- 2‐Chloro‐2‐Methylcyclohexanone and 2‐Methyl‐2‐Cyclohexenone (2003) (2)
- ASYMMETRIC TOTAL SYNTHESIS OF 11α-HYDROXYPROGESTERONE VIA A BIOMIMETIC POLYENE CYCLIZATION (1978) (1)
- STUDY OF NONENZYMIC BIOGENETIC LIKE OLEFINIC CYCLIZATION, CYCLIZATION OF 4-(TRANS-3,7-OCTADIENYL)-3-METHYL-2-CYCLOHEXEN-1-OL AND 4-(TRANS,TRANS-7-METHYL-3,7,11-DODECATRIENYL)-3-METHYL-2-CYCLOHEXEN-1-OL (1974) (1)
- Comprehensive organic chemistry the synthesis and reactions of organic compounds: Volume 5 (Biological compounds; edited by E. Haslam, Sheffield) (1979) (1)
- Chiral Acetal-Initiated Asymmetric Pentacyclization. Enantioselective Synthesis of 18α(H)-Oleananes. (1995) (1)
- BIOMIMETIC POLYENE CYCLIZATIONS. ASYMMETRIC INDUCTION BY A CHIRAL CENTER REMOTE FROM THE INITIATING CATIONIC CENTER. 11α-METHYLPROGESTERONE (1976) (1)
- A STEREOSPECIFIC TOTAL SYNTHESIS OF RACEMIC 11α-HYDROXYPROGESTERONE VIA A BIOMIMETIC POLYENE CYCLIZATION (1976) (1)
- ASYMMETRIC SYNTHESIS VIA ACETAL TEMPLATES. 12. HIGHLY DIASTEREOSELECTIVE COUPLING REACTIONS WITH A KETENE ACETAL. AN EFFICIENT, ASYMMETRIC SYNTHESIS OF R-(+)-α-LIPOIC ACID (1985) (1)
- Cation-Stabilizing Auxiliaries: A New Concept in Biomimetic Polyene Cyclization. (1987) (1)
- BIOMIMETIC POLYENE CYCLIZATIONS. SYNTHESIS OF RACEMIC 19-NORPROGESTERONE (1979) (1)
- Total synthesis of dl-19-nor-16,17-dehydroprogesterone. (1969) (1)
- Cation-Stabilizing Auxiliaries in Polyene Cyclizations. Part 4. Fluorine Atom as a Cation-Stabilizing Auxiliary in Biomimetic Polyene Cyclizations. Part 1. Background and Exploratory Experiments. (1993) (0)
- First Examples of Nonenzymic, Biomimetic Polyene Pentacylizations. Total Synthesis of the Pentacyclic Triterpenoid Sophoradiol. (1994) (0)
- ASYMMETRIC SYNTHESIS VIA ACETAL TEMPLATES. 9. FURTHER STUDIES OF THE ALLYLATION REACTION. PREPARATION OF (-)-DIHYDROMYOPORONE (1985) (0)
- The Carboalkoxyallylsilane Terminator for Biomimetic Polyene Cyclizations. A Route to 21-Hydroxyprogesterone Types. (1987) (0)
- ACETYLENIC BOND PARTICIPATION IN BIOGENETIC-LIKE OLEFINIC CYCLIZATIONS IN NITROALKANE SOLVENTS, A FACILE TOTAL SYNTHESIS OF DL-TESTOSTERONE BENZOATE (1973) (0)
- STUDY OF NOENZYMIC BIOGENETIC LIKE OLEFINIC CYCLIZATION, THE SYNTHESIS AND CYCLIZATION OF 4-(TRANS,TRANS-7,12-DIMETHYL-3,7,11-TRIDECATRIENYL)-3-METHYL-2-CYCLOHEXEN-1-OL AND ITS ALLYLIC ISOMER (1974) (0)
- DIRECT FORMATION OF THE STEROID NUCLEUS BY A NONENZYMIC BIOGENETIC-LIKE CYCLIZATION, PREPARATION OF THE CYCLIZATION SUBSTRATE (1973) (0)
- A NOVEL SYNTHESIS OF LINGIFOLENE (1975) (0)
- Epoxide‐Initiated Cationic Polyene Cyclizations. (1994) (0)
- Ethyl β,β‐Pentamethyleneglycidate (2003) (0)
- Ionization, electricity. A. Proof that ions exist (1966) (0)
- Chiral Acetal-Induced Asymmetric Polyene Tetracyclization Assisted by a Cation-Stabilizing Auxiliary. (1990) (0)
- Recent Develnpments in Biomimetic Polyene Cyclizations (36 Literaturangaben). (1982) (0)
- STUDY OF NONENZYMIC, BIOGENETIC LIKE OLEFINIC CYCLIZATION, CYCLIZATION OF 1-METHYL-6-(TRANS,TRANS-7,11-DIMETHYL-3,7,11-DODECATRIENYL)-2-CYCLOHEXEN-1-OL (1974) (0)
- ASYMMETRIC SYNTHESIS VIA ACETAL TEMPLATES. 3. ON THE STEREOCHEMISTRY OBSERVED D IN THE CYCLIZATION OF CHIRAL ACETALS OF POLYOLEFINIC ALDEHYDES; FORMATION OF OPTICALLY ACTIVE HOMOALLYLIC ALCOHOLS (1983) (0)
- Asymmetric Synthesis via Acetal Templates. Part 13. Preparation of Aldol Compounds from Butane-1,3-diol Acetals. (1987) (0)
- BIOMIMETIC POLYENE CYCLIZATIONS. PARTICIPATION OF THE TRIMETHYLSILYLACETYLENIC GROUP AS A TERMINATOR AND THE TOTAL SYNTHESIS OF A D-HOMOSTEROID (1978) (0)
- An Application of the Trost Reaction to the Stereoselective Synthesis of trans-Tetrasubstituted Fluoroalkenes. (1993) (0)
- Ethyl Orthocarbonate [Orthocarbonic acid, tetrahethyl ester] (1952) (0)
- 459. Unsaturated lactones and related substances. Part II. The synthesis of aldehydo-acids by the Rosenmund reaction (1950) (0)
- Asymmetric Synthesis via Acetal Templates. Part 15. The Preparation of Enantiomerically Pure Mevinolin Analogues. (1989) (0)
- Additions and Corrections - New Structural and Stereochemical Aspects of the Cyclization of Olefinic Acetals (1967) (0)
- BIOMIMETIC CYCLIZATIONS OF POLYENES (1976) (0)
- AN EXPERIMENTAL METHOD FOR DETERMINING A-VALUES: THE METHYL GRROUP* (0)
- Electricity and matter (1927) (0)
- ASYMMETRIC SYNTHESIS VIA ACETAL TEMPLATES. 6. A STEREOSELECTIVE APPROACH TO A A KEY INTERMEDIATE FOR THE PREPARATION OF VITAMIN D METABOLITES (1984) (0)
- Cation-Stabilizing Auxiliaries in Polyene Cyclizations. Part 5. Fluorine Atom as a Cation-Stabilizing Auxiliary in Biomimetic Polyene Cyclizations. Part 2. Asymmetric Synthesis of a Steroid. (1993) (0)
- Additions and Corrections. Syntheses in the 1,2-Benzathracene and Chrysene Series. (1939) (0)
- Cyclization of N-β-Cyanoethylanilines (1953) (0)
- Asymmetric Synthesis via Acetal Templates. Part 10. Aldol-Type Reactions. Preparation of a Nonactic Acid Intermediate. (1985) (0)
- Additions and Corrections-The Acid-Catalyzed Decarboxylation of Cinnamic Acids (1949) (0)
- Improvement of the Synthesis of Bisdehydrodoisynolic Acid1 (1950) (0)
- Biological compounds: Volume 5; edited by E. Haslam, Sheffield (1978) (0)
- Biomimetic polyene cyclizations. Synthesis of racemic 19‐norprogesterone (2010) (0)
- The synthesis and reactions of organic compounds: Chairman of the Editorial Board: Sir Derek Barton, FRS Deputy Chairman: W. David Ollis, FRS Volume 1 (Stereochemistry, Hydrocarbons, Halo Compounds, Oxygen Compounds; edited by J. F. Stoddart, Sheffield) (1979) (0)
- Rate Enhancement of Biomimetic Polyene Cyclizations by a Cation-Stabilizing Auxiliary. (1988) (0)
- Cholestanyl Methyl Ether (2003) (0)
- A STEREOSPEZIFIC TOTAL SYNTHESIS OF ESTRONE VIA A CATIONIC OLEFINIC CYCLIZATION (1974) (0)
- Asymmetric Synthesis via Acetal Templates. Part 14. Preparation of Enantiomerically Pure (3S,4S)‐ and (3S,4R)‐Statine Derivatives. (1988) (0)
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