Wolfgang Kaim
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German chemist
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Chemistry
Wolfgang Kaim's Degrees
- PhD Chemistry University of Marburg
Why Is Wolfgang Kaim Influential?
(Suggest an Edit or Addition)According to Wikipedia, Wolfgang Kaim is a German chemist who held the chair of coordination chemistry at the University of Stuttgart. He is co-author of the internationally recognized book, Bioinorganic Chemistry which was awarded with the Literature Award of the German Chemical Industry.
Wolfgang Kaim's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Non-innocent ligands in bioinorganic chemistry—An overview (2010) (421)
- Manifestations of noninnocent ligand behavior. (2011) (397)
- Copper—A “Modern” Bioelement (1996) (396)
- Ligand-directed molecular architectures: self-assembly of two-dimensional rectangular metallacycles and three-dimensional trigonal or tetragonal prisms. (2003) (375)
- Spectroelectrochemistry: the best of two worlds. (2009) (302)
- The transition metal coordination chemistry of anion radicals (1987) (267)
- Unconventional mixed-valent complexes of ruthenium and osmium. (2007) (266)
- Exploration of mixed-valence chemistry: inventing new analogues of the Creutz-Taube ion. (2000) (236)
- The coordination chemistry of TCNE, TCNQ and related polynitrileπ acceptors (1994) (228)
- Bioinorganic Chemistry: Inorganic Elements in the Chemistry of Life: An Introduction and Guide (1994) (226)
- The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands (2012) (224)
- The coordination chemistry of 1,2,4,5-tetrazines (2002) (212)
- ESR of homo- and heteroleptic mono- and dinuclear tris(.alpha.-diimine)ruthenium radical complexes (1990) (196)
- Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen (2013) (193)
- Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: structures and mechanism of formation. (2002) (181)
- Separating innocence and non-innocence of ligands and metals in complexes [(L)Ru(acac)2](n) (n = -1, 0, +1; L = o-iminoquinone or o-iminothioquinone). (2003) (165)
- Energy level tailoring in ruthenium(II) polyazine complexes based on calculated and experimental ligand properties (1989) (135)
- Concepts for metal complex chromophores absorbing in the near infrared (2011) (135)
- Electronic structure of the "molecular light switch" bis(bipyridine)dipyrido[3,2-a:2',3'-c]phenazineruthenium(2+). Cyclic voltammetric, UV/visible and EPR/ENDOR study of multiply reduced complexes and ligands (1993) (131)
- Mixed valency in ruthenium complexes—Coordinative aspects (2007) (131)
- Four bridging bis chelate ligands with very low lying .pi.* orbitals. MO perturbation calculations, electrochemistry, and spectroscopy of mononuclear and binuclear group 6 metal tetracarbonyl complexes (1987) (129)
- Complexes with 2,2â²-azobispyridine and related 'S-frame' bridging ligands containing the azo function (2001) (126)
- When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O (1995) (117)
- The δ in 18 + δ Electron Complexes: Importance of the Metal/Ligand Interface for the Substitutional Reactivity of “Re(0)” Complexes (α-diimine-)ReI(CO)3(X) (1996) (115)
- What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers (1988) (115)
- Stable binuclear o- and p-semiquinone complexes of [Ru(bpy)2]2+. Radical ion versus mixed-valence dimer formulation (1989) (106)
- Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: a case of non-innocence in organometallic chemistry. (2008) (102)
- Coordination characteristics of four isomeric .alpha.-diimine ligands. .pi. Molecular orbital perturbation calculations for the bidiazines and their correlation with the properties of group 6 metal carbonyl complexes (1986) (101)
- Sensitive Valence Tautomer Equilibrium of Paramagnetic Complexes [(L)Cun+(Qn−)] (n=1 or 2; Q=Quinones) Related to Amine Oxidase Enzymes (1999) (100)
- Mixed-valent metals bridged by a radical ligand: fact or fiction based on structure-oxidation state correlations. (2008) (98)
- The chemistry and biochemistry of the copper–radical interaction (2003) (97)
- Intramolecular valence and spin interaction in meso and rac diastereomers of a p-quinonoid-bridged diruthenium complex. (2008) (97)
- Unkonventionelle gemischtvalente Komplexe des Rutheniums und Osmiums (2007) (95)
- Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates (1991) (93)
- Coordination compounds of pteridine, alloxazine and flavin ligands: structures and properties (1999) (90)
- Divinylphenylene bridged diruthenium complexes bearing Ru(CO)Cl(PiPr3)2 entities (2006) (90)
- C4 cumulene and the corresponding air-stable radical cation and dication. (2014) (90)
- Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands (2010) (89)
- Bor‐organische Redoxsysteme (1989) (88)
- Three-spin system with a twist: a bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center. (2005) (87)
- p‐Phenylenediboranes: Mirror Images of p‐Phenylenediamines? (1984) (86)
- Kupfer – ein “modernes” Bioelement (1996) (83)
- Boron atoms as spin carriers in two- and three-dimensional systems. (2009) (83)
- Theoretical and experimental evidence for a new kind of spin-coupled singlet species: isomeric mixed-valent complexes bridged by a radical anion ligand. (2005) (83)
- The nature of reduced and excited states of .pi.-electron-deficient complexes between tricarbonylhalorhenium and diimine ligands (1990) (81)
- cyclo‐P5 as Complex Ligand—the Phosphorus Analogue of the Cyclopentadienyl Ligand (1986) (78)
- The Versatile Chemistry of 1,4‐Diazines: Organic, Inorganic and Biochemical Aspects (1983) (75)
- Valence-state analysis through spectroelectrochemistry in a series of quinonoid-bridged diruthenium complexes [(acac)(2)Ru(mu-L)Ru(acac)(2)](n) (n=+2, +1, 0, -1, -2). (2008) (74)
- Chemical and Electrochemical Generation of Hydride-Forming Catalytic Intermediates (bpy)M(CnRn): M = Rh, Ir (n = 5); M = Ru, Os (n = 6). Coordinatively Unsaturated Ground State Models of MLCT Excited States? (1994) (74)
- An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5) (1993) (74)
- Charge Delocalization in a Heterobimetallic Ferrocene−(Vinyl)Ru(CO)Cl(PiPr3)2 System††Dedicated to Prof. Dr. Helmut Werner on the occasion of his 75th birthday (2009) (74)
- Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO) (1990) (73)
- 2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [{(bpy)2Ru}2(mu-H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(mu-H2L)]m (m=2-,-,0,+,2+). (2005) (71)
- Valence-state alternatives in diastereoisomeric complexes [(acac)2Ru(mu-QL)Ru(acac)2]n (QL2- = 1,4-dioxido-9,10-anthraquinone,n = +2, +1, 0, -1, -2). (2008) (71)
- Tripeldecker‐Sandwichkomplexe mit cyclo‐P6‐Mitteldeck (1988) (69)
- The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical: Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction (1999) (68)
- 2-(Dimethylamino)ethaneselenolates of palladium(II): synthesis, structure, spectroscopy and transformation into palladium selenide (2001) (66)
- Tetranuclear pentaammineruthenium complexes bridged by {pi}-conjugated tetracyano ligands related to TCNE: Syntheses and spectroscopy of different oxidation states (1995) (66)
- EPR study of paramagnetic rhenium(I) complexes (bpy>>·>>–>>)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction† (1997) (65)
- Axial Shielding of 5d8 and 5d7 Metal Centers in Dimesitylplatinum Complexes with Unsaturated Chelate Ligands: Spectroscopic and Spectroelectrochemical Studies of Four Different Oxidation States (1995) (62)
- Vom Ionenpaar zum Radikalkomplex: Koordinationsverbindungen des reduzierten 2,2′‐Bipyridins mit Organometall‐Kationen (1981) (61)
- Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through pi/pi interaction in an isolated complex. (2008) (61)
- Electron transfer to complex ligands. Radical anions and organomagnesium radical complexes of 2,2'-bipyridines and 1,10-phenanthrolines (1982) (61)
- New ruthenium nitrosyl complexes with tris(1-pyrazolyl)methane (tpm) and 2,2'-bipyridine (bpy) coligands. Structure, spectroscopy, and electrophilic and nucleophilic reactivities of bound nitrosyl. (2006) (60)
- Complex reduction chemistry of (abpy)PtCl2, abpy = 2,2'-azobispyridine: formation of cyclic [(micro,eta2:eta1-abpy)PtCl]2(2+) with a new coordination mode for abpy and a near-infrared ligand-to-ligand intervalence charge transfer absorption of the one-electron reduced state. (2004) (59)
- Complex series [Ru(tpy)(dpk)(X)]n+ (tpy = 2,2':6',2''-terpyridine; dpk = 2,2'-dipyridyl ketone; X = Cl-, CH3CN, NO2(-), NO+, NO*, NO-): substitution and electron transfer, structure, and spectroscopy. (2005) (59)
- Variable Reduction Sequences for Axial (L) and Chelate Ligands (NwedgeN) in Rhenium(I) Complexes [(NwedgeN)Re(CO)(3)(L)](n)(). (1998) (59)
- The semiquinone-ruthenium combination as a remarkably invariant feature in the redox and substitution series [Ru(Q)(n)(acac)(3-n)](m), n = 1-3; m = (-2), -1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone. (2009) (58)
- Electronic structure of catalytic intermediates for production of H2: (C5Me5)Ir(bpy) and its conjugated acid (1992) (58)
- EPR characteristics of the [(NC)(5)M(NO)](3-) ions (M = Fe, Ru, Os). Experimental and DFT study establishing NO* as a ligand. (2001) (57)
- Radical-forming electron-transfer reactions involving main-group organometallics (1985) (57)
- Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2 (M = Mo, W; R = iPr, Cy) in Their Complexes with H2, THF, and Three .pi.-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States (1995) (56)
- Formation, reactivity, and photorelease of metal bound nitrosyl in [Ru(trpy)(L)(NO)](n+) (trpy = 2,2':6',2''-terpyridine, L = 2-phenylimidazo[4,5-f]1,10-phenanthroline). (2008) (56)
- Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes. (2013) (56)
- Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. (2014) (56)
- Electronic Structure of π-Conjugated Redox Systems with Borane/Borataalkene End Groups (1996) (55)
- Dialan-Radikalanionen [R2Al-AlR2].− (1993) (55)
- Dicopper(I) complexes with reduced states of 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine: crystal structures and spectroscopic properties of the free ligand, a radical species, and a complex of the 1,4-dihydro form. (2001) (55)
- Spectroscopic and electrochemical properties of the isomeric bidiazine complexes [(C5Me5)CiRh(bdz)]+ and (C5Me5)Rh(bdz) and their relevance to the catalysis of the 2 H+ → H2 reaction by 2,2′-bipyridine analogues (1991) (54)
- Enhanced hydroxyl radical production by dihydroxybenzene-driven Fenton reactions: implications for wood biodegradation (2007) (54)
- Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine. (2005) (54)
- Metal-induced reductive ring opening of 1,2,4,5-tetrazines: three resulting coordination alternatives, including the new non-innocent 1,2-diiminohydrazido(2-) bridging ligand system. (2006) (54)
- What determines the solvatochromism of metal-to-ligand charge transfer transitions? A demonstration involving 17 tungsten carbonyl complexes (1987) (54)
- Application of a structure/oxidation-state correlation to complexes of bridging azo ligands. (2012) (53)
- Electrochemistry and spectroelectrochemistry (EPR, UV-visible-near-IR) of platinum(II) 2,2'-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L) (1992) (53)
- Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand (2011) (53)
- Electronic structure alternatives in nitrosylruthenium complexes. (2010) (53)
- Exceptionally variable solvatochromism of centrosymmetric octacarbonyldimolybdenum(0) complexes. Rules to estimate the solvent sensitivity of charge-transfer absorption energies (1986) (52)
- Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes. (2015) (52)
- Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn (1990) (52)
- CpIr(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six-pi-Electron Metallaheteroaromatic Compound? (1996) (51)
- Copper complexes with non-innocent ligands: probing CuII/catecholato-CuI/o-semiquinonato redox isomer equilibria with EPR spectroscopy (2002) (50)
- Electrochemical, spectroscopic and EPR study of transition metal complexes of dipyrido[3,2- a :2′,3′- c ]phenazine (1999) (50)
- The First Structural Characterization of an Azoaromatic Radical Anion Stabilized by Dicopper(I) Coordination. (1998) (50)
- Semireduced bridging ligands containing -N―N- multiple bond coordination sites. ESR study of binuclear group 6 metal carbonyl complexes (1986) (49)
- Charge-transfer and electron-transfer properties of d6 metal complexes with .mu.-pyrazine. Mononuclear and binuclear manganese(I) compounds (1986) (49)
- Molecular and electronic structure of cyclo[10]thiophene in various oxidation states: polaron pair vs. bipolaron (2011) (49)
- cyclo-P5 als Komplexligand-das Phosphor-Analogon des Cyclopentadienylliganden†‡ (1986) (49)
- Electron-transfer catalyzed substitution in carbonyl complexes. Part 5. Electron-transfer autocatalytic formation, intramolecular charge transfer, and qualitatively different solvatochromism of .sigma. and .pi. transition-metal carbonyl complexes with polynitrile ligands (1989) (49)
- Structures and spectroelectrochemistry (UV–vis, IR, EPR) of complexes [(OC)3ClRe]n(abpy), n=1, 2; abpy=2,2′-azobispyridine (2000) (48)
- Structural basis for unusually long wavelength charge transfer transitions in complexes [MCl(ECH(2)CH(2)NMe(2))(PR(3))] (E = Te, Se; M = Pt, Pd): experimental results and TD-DFT calculations. (2002) (48)
- A series of metal complexes with the non-innocent N,N'-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure. (2008) (48)
- Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C5R5)Fe(CO)2] (R CHMe2) (1996) (47)
- Das tetraalkyldigallan-radikalanion [R2Ga−GaR2]− [R CH(SiMe3)2] mit langer einelektron-π-bindung (1995) (47)
- A five-center redox system: molecular coupling of two noninnocent imino-o-benzoquinonato-ruthenium functions through a pi acceptor bridge. (2009) (47)
- Self-assembly of heterobimetallic neutral macrocycles incorporating ferrocene spacer groups: spectroelectrochemical analysis of the double two-electron oxidation of a molecular rectangle. (2005) (46)
- Radikalionen, XIX: Einelektronen‐Oxidationen (H3C)3SiCH2‐substituierter Benzole in der Gasphase und in Lösung (1978) (46)
- Effects of cyclic 8π-electron conjugation in reductively silylated nitrogen heterocycles (1983) (46)
- An odd-electron complex [Ru(k)(NO(m))(Q(n))(terpy)]2+ with two prototypical non-innocent ligands. (2009) (46)
- Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation . (2004) (46)
- Redox properties of ruthenium nitrosyl porphyrin complexes with different axial ligation: structural, spectroelectrochemical (IR, UV-visible, and EPR), and theoretical studies. (2008) (46)
- EPR and absorption spectra of singly reduced mono- and dinuclear diorganoplatinum complexes of heterocyclic .alpha.-diimines (1992) (45)
- Can geometry control the coordination behaviour of 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone? A study towards its origin (2011) (45)
- Changeover in a multimodal copper(ii) catenate as monitored by EPRspectroscopy (1997) (45)
- Electron transfer and chloride ligand dissociation in complexes [(C5Me5)ClM(bpy)]+/[(C5Me5)M(bpy)]n (M=Co, Rh, Ir;n = 2+, +, 0, −): A combined electrochemical and spectroscopic investigation (1996) (45)
- Stabilization of a cobalt-cobalt bond by two cyclic alkyl amino carbenes. (2014) (45)
- Establishing the NO oxidation state in complexes [Cl(5)(NO)M](n-), M = Ru or Ir, through experiments and DFT calculations. (2004) (44)
- Singlet diradical complexes of ruthenium and osmium: geometrical and electronic structures and their unexpected changes on oxidation. (2008) (44)
- Epr evidence for related electronic structures of α-diimine complexes with [Ru(bpy) 2 ] 2+ and re(CO) 3 (halide) fragments (1987) (44)
- Formation of racemate and mesocate complexes from an achiral tripodal ligand containing three benzimidazole groups. (2003) (43)
- Acidic iridium hydrides: implications for aerobic and Oppenauer oxidation of alcohols. (2006) (43)
- Sensitive oxidation state ambivalence in unsymmetrical three-center (M/Q/M) systems [(acac)2 Ru(mu-Q)Ru(acac)2](n), Q = 1,10-phenanthroline-5,6-dione or 1,10-phenanthroline-5,6-diimine (n = +, 0, -, 2-). (2005) (43)
- A new coordination mode of the photometric reagent glyoxalbis(2-hydroxyanil) (H2gbha): bis-bidentate bridging by gbha2- in the redox series [(mu-gbha)[Ru(acac)2]2]n (n = -2, -1, 0, +1, +2), including a radical-bridged diruthenium(III) and a Ru(III)/Ru(IV) intermediate. (2005) (43)
- Copper(I)‐Assisted Formation of an “Organic” Sandwich Structure: Structural Prerequisites for Luminescence of the Dinuclear Complexes [(μ‐Bipyrimidine){Cu(PR3)2}2]X2 (1989) (42)
- The triruthenium complex [[(acac)2Ru(II)]3(L)] containing a conjugated diquinoxaline[2,3-a:2',3'-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation. (2004) (42)
- Correlated coordination and redox activity of a hemilabile noninnocent ligand in nickel complexes. (2014) (42)
- Synthesis, electrochemistry and emission spectroscopy in fluid solution of four isomeric (α-diimine)Re(CO)3Hal complexes (1989) (41)
- Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1′-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent” Intermediates† (2010) (41)
- Reactivity of "GaI" toward N-substituted 1,4-diazabuta-1,3-dienes: Synthesis and characterization of gallium heterocycles containing paramagnetic diazabutadiene monoanions (2002) (41)
- Structure and Spectroelectrochemical Response of Arene–Ruthenium and Arene–Osmium Complexes with Potentially Hemilabile Noninnocent Ligands (2014) (41)
- Reductive approach to mixed valency (n = 1-) in the pyrazine ligand-bridged [(acac)2Ru(μ-L(2-))Ru(acac)2](n) (L(2-) = 2,5-pyrazine-dicarboxylate) through experiment and theory. (2011) (41)
- Metal-induced tautomerization of p- to o-quinone compounds: experimental evidence from CuI and ReI complexes of azophenine and DFT studies. (2004) (41)
- Pentaisopropylcyclopentadienyl: singlet anion, doublet radical, and triplet cation of a carbocyclic .pi. system (1993) (41)
- Radical ions. 37. Ionization and one-electron oxidation of electron-rich silylalkyl olefins (1980) (40)
- A Coordination-Induced 1,4→1,2-Quinonediimine Isomerization. (1998) (40)
- Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation (1992) (40)
- Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin (2008) (40)
- p-Phenylendiamine Spiegelbild der p-Phenylendiamine? (1984) (39)
- A Stable Neutral Radical in the Coordination Sphere of Aluminum. (2017) (39)
- The redox series [M(bpy)2(q)]n+, M = Ru or Os, Q = 3,5-di-tert-butyl-n-phenyl-1,2-benzoquinonemonoimine. Isolation and a complete X and W band EPR study of the semiquinone states (n = 1). (2005) (39)
- Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands† (2000) (39)
- Towards new organometallic wires: tetraruthenium complexes bridged by phenylenevinylene and vinylpyridine ligands. (2007) (39)
- Koordinationschemie reduzierter N‐Heterocyclen. Zweikernige Pentacarbonyl‐Komplexe des Molybdäns und Wolframs mit paramagnetischen Brückenliganden (1982) (39)
- Mixed valency of a 5d element: The osmium example (2013) (39)
- Metalla-supramolecular rectangles as electron reservoirs for multielectron reduction and oxidation. (2002) (39)
- Singlet diradical complexes of chromium, molybdenum, and tungsten with azo anion radical ligands from M(CO)6 precursors. (2007) (39)
- Long-range electronic coupling in various oxidation states of a C4-linked tris(beta-diketonato)ruthenium dimer. (2003) (38)
- Structural Variety and Multiple Isomerism in 1-(Dimethylamino)propyl-2- chalcogenolate and 2-(Dimethylamino)propyl-1-chalcogenolate Complexes of Palladium(II) and Platinum(II): Synthesis, Spectroscopy and Structures (2004) (38)
- A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO) 3 (Hal), Hal=F, Cl, Br, I; abpy=2,2′-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms (2004) (38)
- Pulled Molecular Strings and Stacked Molecular Decks: Chelate‐Ring Formation vs. Metal–Metal Bridging in Dicopper(I) Complexes of 2,2′‐Bipyrimidine with Diphosphine Ligands of Variable Polymethylene Chain Length (1996) (38)
- Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex [(η5-C5Me5)ClRh(μ-bptz)Re(CO)3Cl](PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine (2001) (38)
- Theoretische und experimentelle Hinweise auf einen neuen Typ spingekoppelter Singulett‐Spezies: isomere gemischtvalente Komplexe mit verbrückendem Radikalanion‐Liganden (2005) (38)
- Gas-Phase Structure of the Monomeric Alkylgallium(I) Compound Ga[C(SiMe3)3] and the Electrochemical Behavior of Ga4[C(SiMe3)3]4and In4[C(SiMe3)3]4with EPR Evidence for a Ga4R4Radical Anion (1996) (38)
- The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands (2003) (37)
- The metal-NO interaction in the redox systems [Cl5Os(NO)]n-, n = 1-3, and cis-[(bpy)2ClOs(NO)]2+/+: calculations, structural, electrochemical, and spectroscopic results. (2006) (37)
- Tellurium(0) as a ligand: synthesis and characterization of 2-pyridyltellurolates of platinum(II) and structures of [Pt{2-Te-3-(R)C5H3N}2Te(PR'3)] (R = H or Me). (2010) (37)
- Mixed valence aspects of diruthenium complexes [((L)ClRu)2(mu-tppz)]n+ incorporating 2-(2-pyridyl)azoles (L) as ancillary functions and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (Tppz) as bis-tridentate bridging ligand. (2004) (37)
- On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds [RkPt(μ-L)PtRk]n, k = 2 or 4† (1998) (37)
- The Fe(III)/Fe(II) vs Fe(2)(2.5) Formulation in Mixed-Valent Species [(NC)(4)Fe(BL)Fe(CN)(4)](3)(-), BL = 2,2'-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always Matter. (1999) (37)
- Extremely Long‐Wavelength Charge‐Transfer Absorptions of Binuclear Complexes with Azo‐Modified 2,2′‐Bipyridyl Ligands (1985) (37)
- Ligand-controlled oxidation state ambivalence in copper–quinone complexes. Replacement of N-donor by S-donor ligands favours the copper(I)–semiquinone over the copper(II)–catecholate form (1994) (37)
- Molecule-bridged mixed-valent intermediates involving the Ru I oxidation state. (2004) (37)
- Oxidation state analysis of a four-component redox series [Os(pap)2(Q)]n involving two different non-innocent ligands on a redox-active transition metal. (2011) (37)
- Redox reactivity of bis(1,4,7-triazacyclononane)iron(II/III) complexes in alkaline solution and characterization of a deprotonated species: amidoiron(III) vs aminyliron(II) ground-state formulation. EPR, kinetic, pulse radiolysis, and laser photolysis study (1988) (36)
- Proof of innocence for the quintessential noninnocent ligand TCNQ in its tetranuclear complex with four [fac-Re(CO)3(bpy)]+ groups: unusually different reactivity of the TCNX ligands (TCNX = TCNE, TCNQ, TCNB). (2003) (36)
- Bis(acetylacetonato)ruthenium complexes of noninnocent 1,2-dioxolene ligands: qualitatively different bonding in relation to monoimino and diimino analogues. (2011) (36)
- Asymmetrical diruthenium complex bridged by a redox-active ligand. (2012) (36)
- Reversible and site-specific reduction of the ligand sides in a molecular rectangle with up to eight electrons. (2000) (36)
- Boratome als Spinträger in zwei‐ und dreidimensionalen Systemen (2009) (36)
- Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes. (2016) (36)
- Sensitivity of the valence structure in diruthenium complexes as a function of terminal and bridging ligands. (2014) (36)
- Cooperation of metals with electroactive ligands of biochemical relevance: Beyond metalloporphyrins (2004) (36)
- Multifrequency EPR study and density functional g-tensor calculations of persistent organorhenium radical complexes. (2002) (35)
- Mono- and binuclear tri- and tetracarbonyl complexes of chromium(0), molybdenum(0), and tungsten(0) with the 2,2'-bipyrimidine radical anion (1984) (35)
- Interaction of frontier orbitals of group 15 and group 16 methides with the frontier orbitals of benzene (1985) (35)
- Ancillary ligand control of electronic structure in o-benzoquinonediimine-ruthenium complex redox series: structures, electron paramagnetic resonance (EPR), and ultraviolet-visible-near-infrared (UV-vis-NIR) spectroelectrochemistry. (2015) (35)
- The closo-Cluster Triad: B9X9, [B9X9]· –, and [B9X9]2– with Tricapped Trigonal Prisms (X = Cl, Br, I). Syntheses, Crystal and Electronic Structures (1999) (34)
- Iron versus ruthenium oxidation in 1,1′-bis(diphenylphosphino)ferrocene–ruthenium(II) complexes: EPR and spectroelectrochemical evidence (2000) (34)
- The mpz(+)/mpz(*) Pair as Organic Analogue of the NO(+)/NO(*) Ligand Redox System (mpz = N-Methylpyrazinium). A Combined Electrochemical and Spectroscopic Study (UV/Vis/NIR, IR, EPR) of Complexes [(mpz)M(CN)(5)](2)(-)(/3)(-) (M = Fe, Ru, Os). (1997) (34)
- Metal—metal interaction in ligand-bridged dimolybdenum(0,0) and -(I,0) complexes with very small frontier orbital gaps: electrochemistry and spectroscopic properties of three neighboring oxidation states☆ (1995) (34)
- Experimental and DFT evidence for the fractional non-innocence of a β-diketonate ligand. (2012) (34)
- Do Cp(CO)2Mn Fragments Stabilize Radicals (1985) (33)
- Dreispinsystem mit neuer Wendung: ein Bis(semichinonato)kupfer‐Komplex mit nichtplanarer Konfiguration am Kupfer(II)‐Zentrum (2005) (33)
- Elektrotransfer-katalysierte Substitution in Carbonyl-Komplexen (1989) (33)
- Synthesis and mixed valence aspects of [{(L)ClRu}2(μ-tppz)]n+ incorporating 2,2′-dipyridylamine (L) as ancillary and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) as bridging ligand (2003) (33)
- The 1,4-diazabutadiene/1,2-enediamido non-innocent ligand system in the formation of iridaheteroaromatic compounds: Spectroelectrochemistry and electronic structure (2010) (33)
- Tetranuclear Mixed‐Valence Manganese Complexes with Reduced TCNE or TCNQ as η4 Bridging Ligands (1987) (33)
- Different orbital occupation by an added single electron in 1,10-phenanthroline and its 3,4,7,8-tetramethyl derivative. Evidence from electron paramagnetic resonance spectroscopy of the anion radicals and of their dimesitylplatinum(II) complexes. X-Ray molecular structure of dimesityl(1,10-phenanthr (1995) (33)
- Tri(supersilyl)dialanyl (tBu3Si)3Al2• and Tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3• − New Stable Radicals of a Group 13 Element from Thermolysis of (tBu3Si)4Al2 (2000) (33)
- Reactions of New Organoplatinum(II) and -(IV) Complexes of 1,4-Diaza-1,3-butadienes with Light and Electrons. Emission vs Photochemistry and the Electronic Structures of Ground, Reduced, Oxidized, and Low-Lying Charge-Transfer Excited States† (1998) (33)
- 2,2'-Azobis(pyridine) (abpy) as a multiply reducible tetradentate ligand. EPR evidence for the configurational dependence of intramolecular electron transfer in the stereoisomeric tris-chelate ruthenium complexes [Ru(abpy)n(bpy)3-n]m (n = 2, 3; m = 2+ to 3-) (1993) (33)
- Solar cell sensitizer models [Ru(bpy-R)2(NCS)2] probed by spectroelectrochemistry. (2012) (33)
- Novel organosilicon radical cations. One-electron oxidation of permethylcyclopolysilanes (1979) (33)
- Ambident Behavior of the “New Vitamin” Methoxatin (Cofactor PQQ) towards Metals: Coordinative Stabilization of the Pyrrolide Form and the Semiquinone Form (1990) (32)
- EPR Insensitivity of the Metal‐Nitrosyl Spin‐Bearing Moiety in Complexes [LnRuII‐NO·]k (2004) (32)
- Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes (1987) (32)
- Substituenteneffekte und Störung von π-Systemen, XXXVI. Me3C-, Me3Si-, Me3Ge-, Me3Sn- und Me3Pb-substituierte Benzol- und Naphthalin-Derivate und ihre Radikalanionen (1980) (32)
- Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands. (2014) (32)
- Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12](2-/*-): experiment and theory. (2010) (32)
- [(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. (2004) (31)
- 3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR. (2005) (31)
- Stable radicals from commonly used precursors trichlorosilane and diphenylchlorophosphine. (2015) (31)
- 3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2 · H2O (E = S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2 (2006) (31)
- π* Molecular Orbital Crossing a2(χ)/b1(ψ) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)4 Complexes (M = Cr, Mo, W) (1996) (31)
- Tris(tri‐tert‐butylsilyl)digallanyl (tBu3Si)3Ga2: A New Type of Compound for a Heavy Group 13 Element (1997) (31)
- Rhenium(I) coordinated lumazine and pterin derivatives: structure and spectroelectrochemistry of reversibly reducible (6-ATML)Re(CO)3Cl (6-ATML=6-acetyl-1,3,7-trimethyllumazine) (2001) (31)
- Interacting metal and ligand based open shell systems: Challenges for experiment and theory (2017) (31)
- Radical ions : XXVII. Radical ions of tetrakis(trimethylsilyl)butatriene (1979) (30)
- The stable diiron(2.5) complex ion [(NC)(5)Fe(mu-tz)Fe(CN)5](5-), tz = 1,2,4,5-tetrazine, and its neighboring oxidation states. (2001) (30)
- Bis(1,4-di-tert-butyl-1,4-diazabutadiene)gallium is not a gallium(II) compound (1991) (30)
- Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2'-Azobispyridine): Stabilization of the Radical Intermediate and of the Os^0Os^I^I State (2005) (30)
- Uncommon cis configuration of a metal-metal bridging noninnocent Nindigo ligand. (2014) (30)
- What a difference ancillary thienyl makes: unexpected additional stabilization of the diruthenium(III,II) but not the diosmium(III,II) mixed-valent state in tetrazine ligand-bridged complexes. (2003) (30)
- Sensitivity of a strained C-C single bond to charge transfer: redox activity in mononuclear and dinuclear ruthenium complexes of bis(arylimino)acenaphthene (BIAN) ligands. (2014) (30)
- Charge and electron transfer from metal-to-carbon bonds of main group organometallics MRn (M = Al, Ga, Zn) to aromatic N-heterocycles: colored precursor compounds and radical complex formation (1994) (29)
- Synthesis, structure, and electronic properties of RuN6 dinuclear Ru-Hbpp complexes. (2012) (29)
- Organoboron substituent effects in EPR/ENDOR spectroscopy. Radical ions with B–C and B–N bonds (1992) (29)
- ESR and ENDOR study of three isomeric bidiazine anion radicals and of their Group 6 metal carbonyl complexes. Coordinative effects on the spin distribution (1986) (29)
- A diruthenium complex of a "Nindigo" ligand. (2013) (29)
- Reduced and excited states of (bpym)[PtCl(2)](n)() (bpym = 2,2'-bipyrimidine; n = 1, 2): experiments and DFT calculations. (2002) (29)
- Radical ions : XXVIII. Tris(trimethylsilylmethyl)aminium, N(CH2Si(CH3)3)3: A stable fluxional aminium radical cation☆ (1979) (29)
- Vierkernige gemischtvalente Mangankomplexe mit reduziertem TCNE oder TCNQ als η4‐Brückenliganden (1987) (29)
- Electronic structure and catalytic aspects of [Ru(tpm)(bqdi)(Cl/H2O)]n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimine. (2013) (29)
- Sensitivity of the chromium-chromium quadrupole bond to axial interactions in dichromium(II) compounds (1980) (29)
- Charged, but found "not guilty": innocence of the suspect bridging ligands [RO(O)CNNC(O)OR]2- = L2- in [(acac)2Ru(μ-L)Ru(acac)2]n, n = +,0,-,2-. (2012) (29)
- Metal vs ligand reduction in complexes of dipyrido[3,2-a:2',3'-c]phenazine and related ligands with [(C5Me5)ClM]+ (M = Rh or Ir): evidence for potential rather than orbital control in the reductive cleavage of the metal-chloride bond. (2004) (29)
- Heterocycles with 7 and 8π electrons. Models for flavin and pteridine intermediates and candidates for novel inorganic rings (1988) (28)
- Identifying intermediates of sequential electron and hydrogen loss from a dicarbonylcobalt hydride complex. (2013) (28)
- Inorganic hybrid analogs of Thiele's and Chichibabin's hydrocarbons. Spectroscopy, electrochemistry, and structure (1993) (28)
- Ruthenium(II) coordination to a model for the topasemiquinone cofactor of amine oxidases. Resolution of 1H and 99,101Ru EPR hyperfine structure (1993) (28)
- Spectroelectrochemistry of aromatic ligands and their derivatives (1991) (28)
- Dithiocarbamates of gallium(III) and indium(III): syntheses, spectroscopy, and structures (2002) (28)
- Chemical and electrochemical reduction of pentacarbonyl(4-cyanopyridine) complexes of chromium(0), molybdenum(0), and tungsten(0) (1984) (28)
- Farbige Komplexe: das Charge‐Transfer‐Phänomen (1987) (28)
- The “Antiaromaticity” of l,4‐Dihydropyrazines (1981) (28)
- Stabilization of biochemically interesting intermediates by metal coordination. VI: Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals (1989) (28)
- Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations. (2005) (28)
- Stabilization of {RuNO}6 and {RuNO}7 States in [RuII(trpy)(bik)(NO)]n+ {trpy = 2,2′:6′,2″-terpyridine, bik = 2,2′-bis(1-methylimidazolyl) ketone} – Formation, Reactivity, and Photorelease of Metal-Bound Nitrosyl (2009) (28)
- Thermal and light induced electron transfer reactions of main group metal hydrides and organometallics (1994) (28)
- Four-center oxidation state combinations and near-infrared absorption in [Ru(pap)(Q)2]n (Q = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-phenylazopyridine). (2013) (27)
- A Fully Characterized Complex Ion with Unreduced TCNQ as Fourfold Bridging Ligand: [(μ4 -TCNQ){fac-Re(CO)3 (bpy)}4 ]4+ . (2001) (27)
- First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex (2003) (27)
- Metal vs ligand reduction in complexes of 1,3-dimethylalloxazine (DMA) with copper(I), ruthenium(II), and tungsten(VI). Crystal structures of (DMA)WO2Cl2 and (bis(1-methylimidazol-2-yl)ketone)WO2Cl2. (2000) (27)
- Nano and dendritic structured carboranes and metallacarboranes: From materials to cancer therapy (2009) (27)
- Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A2Ru(mu-L)RuA2]n, A = 2,4-pentanedionato or 2-phenylazopyridine, L(2-) = 2,5-bis(2-oxidophenyl)pyrazine. (2007) (27)
- Platinum(II) Complexes of 2-(Dimethylamino)ethylselenolate − Donor−Acceptor Inter-Ligand Interactions as Evident from Experimental and TD-DFT Computational Analysis (2001) (27)
- 2,5-Bis(1-phenyliminoethyl)pyrazine (bpip): a conjugated metal–metal bridging acceptor ligand and its homodinuclear complexes with low-valent metal centres (1999) (27)
- Electrochemistry, electron spin resonance, optical spectroscope, and reactivity of organometallic platinum(II) complexes containing strongly π-accepting aromatic α-diimine ligands (1992) (26)
- 9-Oxidophenalenone: a noninnocent β-diketonate ligand? (2012) (26)
- Electronic and molecular structure of 2,2'-bipyrimidine-bridged bis (organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediate (1997) (26)
- Heterohexanuclear (Cu3Fe3) complexes of substituted hexaazatrinaphthylene (HATN) ligands: twofold BF4(-) association in the solid and stepwise oxidation (3e) or reduction (2e) to spectroelectrochemically characterized species. (2009) (26)
- On the Gallanyls R*3Ga2· and R*4Ga3· As Well As Gallanides R*3Ga2− and R*4Ga3− (R* = SitBu3) − Syntheses, Characterization, Structures (2001) (26)
- Molecular and electronic structure of electron-transfer active main-group organometallics (1989) (26)
- Structure, biological and electrochemical studies of transition metal complexes from N,S,N′ donor ligand 8-(2-pyridinylmethylthio)quinoline (2010) (26)
- A Stable Bis(chelate) Analogue of the Creutz‐Taube Ion (1988) (26)
- Multiple Isomerism (cis / trans; syn / anti) in [(dmso)~2Pt(aryl)~2] Complexes: A Combined Structural, Spectroscopic, and Theoretical Investigation (2005) (25)
- Paramagnetism of Tetranuclear Complexes between TCNX Ligands (TCNE, TCNQ, TCNB) and Four Pentaammineruthenium or Dicarbonyl(pentamethylcyclopentadienyl)manganese Fragments. (1997) (25)
- Ligand‐Mediated Coupling of Organometallic Reaction Centers (1997) (25)
- Paramagnetic copper(I) dimers (1987) (25)
- Electronic coupling of two [Cp*ClM]+/[Cp*M] reaction centers via π conjugated bridging ligands: similarities and differences between rhodium and iridium analogues☆ (1999) (25)
- [(η5-C5Me5)2 Ti2P6], a Distorted Dimetallaphosphacubane† (1987) (25)
- Radical ions. 36. Structural changes accompanying the one-electron oxidation of hydrazine and its silyl derivatives (1980) (25)
- A Tale of Two Complexes, [PtMen(RNCHCHNR)] (n = 2 and n = 4, R = Cyclohexyl): Why do PtII and PtIV Complexes Exhibit Virtually Identical Redox Behavior and Colors? (1995) (25)
- Thiolato-bridged “Linear” trinuclear platinum complexes [Pt3(μ-SR)4(dppm)2]2+ (2004) (25)
- The coordination potential of indigo, anthraquinone and related redox-active dyes (2019) (25)
- Probing mixed valence in a new tppz-bridged diruthenium(III,II) complex {(mu-tppz)[Ru(bik)Cl]2}3+ (tppz=2,3,5,6-tetrakis(2-pyridyl)pyrazine, bik=2,2'-bis(1-methylimidazolyl)ketone): EPR silence, intervalence absorption, and nu(CO) line broadening. (2007) (24)
- Detection of electron paramagnetic resonance signals from three different isotope combinations 63Cu/63Cu, 63Cu/65Cu and 65Cu/65Cu in stable dicopper(I) radical complexes (1991) (24)
- First observation of resolved ESR hyperfine structure for a reduced ruthenium(II) polyazine complex (1985) (24)
- SINGLE ELECTRON TRANSFER REACTION OF ALUMINUM HYDRIDE WITH NITROGEN-CONTAINING HETEROCYCLES. ESR CHARACTERIZATION OF THE RADICAL PRODUCTS (1984) (24)
- d6‐Metal Complexes of 4,4′‐Bipyrimidine, an Ambident Ligand with High π‐Acceptor Ability (1985) (24)
- Synthesis and characterization of 3-dimethylaminopropyl selenolate complexes of palladium(II) and platinum(II) (2003) (24)
- Radikalionen, XX: Die hyperkonjugative Stabilisierung von p-Xylol-Radikalkationen durch (H3C)3Si-Substituenten (1978) (24)
- Ga9 (CMe3 )9 , an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds En Rn (E=B-In). (2001) (24)
- Azo compounds as electron acceptor or radical ligands in transition metal species: spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2'-azobis(5-chloropyrimidine) (2003) (24)
- Redox-rich spin-spin-coupled semiquinoneruthenium dimers with intense near-IR absorption. (2011) (24)
- Spectroelectrochemical Characterization of the Two-Step Redox System {(μ-pz)[Os(CN)5]2}n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz−Taube System (1998) (24)
- Widely differing stabilities of molecule-bridged cyanodiiron(III, II) species in non-aqueous solvents (1999) (24)
- Spectroelectrochemical evidence for the nitrosyl redox siblings NO+, NO*, and NO- coordinated to a strongly electron-accepting Fe(II) porphyrin: DFT calculations suggest the presence of high-spin states after reduction of the Fe(II)-NO- complex. (2011) (24)
- Binuclear radical complexes of molybdenum and tungsten tetracarbonyls with bridging N-heterocycles and group VA ligands. ESR evidence for a cis configuration (1984) (24)
- Valence structures of the diastereomeric complexes meso- and rac-[Ru(2)(acac)(4)(mu-Q)](n) (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane. (2009) (24)
- Ruthenium(IV)–Bis(methallyl) Complexes as UV‐Latent Initiators for Ring‐Opening Metathesis Polymerization (2012) (23)
- The valence-localized decacyanodiruthenium(III,II) analogue of the Creutz–Taube ion. Completing the full d5/d6 triad [(NC)5M(μ-pz)M(CN)5]5−, M=Fe,Ru,Os; pz=pyrazine (2000) (23)
- Structural Flexibility of the Hydrogen-Free Acceptor Ligand Octachloro-1,10-phenanthroline in Its Complexes with d10 Metal Ions (1997) (23)
- Kopplung zwischen Polypyridinruthenium(II)‐ und Methylviologen‐Einheiten in π‐konjugierten Hybridsystemen (1990) (23)
- Correlation between solvatochromism and back-bonding in four isomeric (α-diimine)M(CO)4 complexes, M = Cr, Mo, W (1986) (23)
- Ruthenium–Triazene Complexes as Latent Catalysts for UV‐Induced ROMP (2013) (23)
- Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complex. (2012) (23)
- Multistep redox sequences of azopyridyl (L) bridged reaction centres in stable radical complex ions {(μ-L)[MCl(η5-C5Me5)]2}˙+, M = Rh or Ir: spectroelectrochemistry and high-frequency EPR spectroscopy (2003) (23)
- Radical ions : XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution (1977) (23)
- RuII(α-diimine) or RuIII(α-diimine·–)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State† (2014) (23)
- MONO- AND BINUCLEAR TRI- AND TETRACARBONYL COMPLEXES OF CHROMIUM(0), MOLYBDENUM(0), AND TUNGSTEN(0) WITH THE 2,2′-BIPYRIMIDINE RADICAL ANION (1985) (23)
- Mono- and bi-nuclear pentacarbonyl complexes of chromium, molybdenum and tungsten with the anion radicals of 2,1,3-benzoxadiazole, 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole (1984) (23)
- Stabilization of a two-coordinate mononuclear cobalt(0) compound. (2014) (22)
- Kupfer(I)‐induzierte Bildung einer „organischen”︁ Sandwich‐Struktur – strukturelle Voraussetzungen für eine Lumineszenz von Zweikernkomplexen [(μ‐Bipyrimidin) {Cu(PR3)2}2]X2 (1989) (22)
- Electronic structure of heterodinuclear complexes (bpy)2RuII-(μ-bpym)MLn; bpy=2,2′-bipyridine; bpym=2,2′-bipyrimidine; MLn=+Cu(PPh3)2, Mo(CO)4, Re(CO)3Cl (1991) (22)
- Radikalionen, XXIII: R2P‐ und R2N‐substituierte Benzole: Die Ladungsverteilung in ihren Kationen, Anionen und Trianionen (1978) (22)
- Äußerst langwellige Charge‐Transfer‐Absorptionen von zweikernigen Komplexen mit azomodifizierten 2,2′‐Bipyridyl‐Liganden (1985) (22)
- Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. (2017) (22)
- Zur strukturellen Flexibilität der "antiaromatischen" 1,4-Dihydropyrazine : Kristall- und Molekülstrukturen metallorganischer Derivate (1985) (22)
- The Dinuclear CuA Center in Cytochrome c Oxidase and N2O Reductase—A Metal–Metal Bond in Biology? (1995) (22)
- Interconversion of structurally characterised complexes [PdCl(Se ̂N)] 2 and [Pd(Se ̂N) 2 ] 6 with the hemi-labile ligand Se ̂N=Me 2 NCH 2 CH 2 CH 2 Se − (2004) (22)
- 2,2'-Dipyridylketone (dpk) as ancillary acceptor and reporter ligand in complexes [(dpk)(Cl)Ru(mu-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. (2006) (22)
- 1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes. (2016) (22)
- Complexes of folic acid, lumiflavin and riboflavin with bis(2, 2′-bipyridine)ruthenium(II). Facilitated formation of flavosemiquinone complexes and substantial decrease of pKa(NH) (1992) (22)
- Crucial role of Cu-S bonding for structural changes accompanying the reversible CuI/CuII transition in an unrestrained Cu(N[symbol: see text]S)2 coordination arrangement. An experimental and DFT study. (2000) (22)
- Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(II) and platinum(II): synthesis, spectroscopy, photochemistry and structures (2003) (22)
- Neutral spin-delocalized mixed-valence manganese(I)-manganese(II) dimers bridged by alkoxide, imidazolate, or malonodinitrile anions (1986) (22)
- Electron-transfer-induced isomerization .eta.2(C:C) .fwdarw. .eta.1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-) (1992) (22)
- Strukturänderungen während der Oxidation B‐, C‐, Si‐ oder P‐substituierter Hydrazine (1978) (21)
- A first radical cation chelate ligand: electron paramagnetic resonance spectra of singly reduced 3,3′-diazamethylviologen, DAMV˙+ and the rhenium(I) complex [(DAMV˙+)Re +(CO)3(PPh3)]2+ (1990) (21)
- Elektronische Stabilisierung durch 7‐π‐Elektronen‐Konjugation in Heterocyclen Kristall‐ und Molekülstruktur eines inerten monocyclischen Radikalkations (1988) (21)
- Carboxylate tolerance of the redox-active platform [Ru(mu-tppz)Ru](n), where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine, in the electron-transfer series [(L)ClRu(mu-tppz)RuCl(L)](n), n = 2+, +, 0, -, 2-, with 2-picolinato, quinaldato, and 8-quinolinecarboxylato ligands (L(-)). (2010) (21)
- Spectroscopy of mixed valent states in dinuclear ions and metalloproteins (1993) (21)
- Unexpected paramagnetism of mono- and polynuclear 18 valence electron metal carbonyl complexes [(CnRn)(CO)2M]k(L), M = chromium, manganese; k = 1, 2, 4. Implications for photoreactivity (1992) (21)
- Metallaviolenes. An ESR study (1983) (21)
- Qualitatively different reactivities of hydride reagents toward [(α-diimine)(η5-C5Me5)ClIr]+ cations: Substitution, electron transfer (reduction), or stepwise hydrogenation (2002) (21)
- Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes. (2015) (21)
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- Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox‐Active o‐Amidophenolate Ligand (LN,O,S)2– with Coordinating Thioether Appendix (2012) (21)
- Isomeric Diruthenium Complexes Bridged by Deprotonated Indigo in cis and trans Configuration. (2018) (21)
- Stabilisierung biochemisch interessanter Zwischenstufen durch Metallkoordination. IV. Rhenium(I)‐Komplexe von Flavin‐ und Pterin‐analogen N/O‐Chelatliganden (1989) (20)
- Spectroelectrochemistry and DFT analysis of a new {RuNO}n redox system with multifrequency EPR suggesting conformational isomerism in the {RuNO}7 state. (2007) (20)
- Valence delocalisation in a strongly coupled (Kc = 1014) molecule-bridged cyanodiiron(III,II) species (1998) (20)
- FIRST EXPERIMENTAL STRUCTURE OF A 1:1 METAL COMPLEX WITH A PQQ COFACTOR DERIVATIVE OUTSIDE DEHYDROGENASE ENZYMES (1999) (20)
- ‘Inverse cryptate’ structure of an exceptionally stable dicopper(I) semiquinonoid intermediate (1993) (20)
- Geometrical and electronic structures of dinuclear complex ions {(mu-bpym)[Cu(EAr3)2]2}2+ with intramolecular "organic sandwich" formation (E = P or As; Ar = Aryl; bpym = 2,2'-bipyrimidine). (2005) (20)
- Crystalline heterocyclic radical cation salts as stable intermediates of new redox-mediating systems (1988) (20)
- Selenol nitrosation and Se-nitrososelenol homolysis: a reaction path with possible biochemical implications. (2004) (20)
- "Guilty" verdict--evidence for the noninnocence of cyanide. (2011) (20)
- Synthesis and characterisation of the persistent radical [BCl2(bipy)]*. (2010) (20)
- Axiale abschirmung des quadratisch-planar konfigurierten platin(II) in strukturell charakterisiertem (bpy)PtMes2: Lumineszenz und elektrochemisch reversible Bildung von Platin(III) (1992) (20)
- Isoelektronische Radikalionen und Redoxsysteme (1980) (20)
- Low-valent cobalt complexes with three different pi acceptor ligands: experimental and DFT studies of the reduced and the low-lying excited states of (R-DAB)Co(NO)(CO), R-DAB = substituted 1,4-diaza-1,4-butadiene. (2003) (20)
- Kantenverknüpfung zweier Metallchelat-Fünfringe: Strukturen und Magnetismus von Mo0-, CuI- und CoII- Komplexen mit dem „S-Frame”-Liganden Azo-2,2′-pyridin† (1991) (20)
- Isomeric Diruthenium Complexes of a Heterocyclic and Quinonoid Bridging Ligand: Valence and Spin Alternatives for the Metal/Ligand/Metal Arrangement. (2016) (20)
- Characterization of the mixed-valent intermediate (n = 3) of the complex series {(μ, η3 :η3-L)[(Ru(terpy)]2}n+ with the unsaturated bridging ligand N, N'-bis (α-picolinoyl)hydrazido(2-) = l2- (2004) (20)
- SYNTHESE UND CHARAKTERISIERUNG DES STABILEN DICARBONYL(CYCLOPENTADIENYL)EISEN-RADIKALS (C5R5)FE(CO)2. (R = CHME2) (1996) (20)
- The d0, d1 and d2 Configuration in Known and Unknown Tetrathiometal Compounds MS4n- (M=Mo,Tc,Ru; W,Re,Os), A Quantum Chemical Study. (1999) (20)
- Structure and reactivity of paramagnetic cyclopentadienyl cobalt complexes with bulky alkyl substituents (1999) (20)
- Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands (2007) (20)
- Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals. (2017) (19)
- The reaction of heterocyclic anion radicals with group VI carbonyls. ESR characterization of paramagnetic binuclear complexes (1981) (19)
- Reinvestigation of the visible absorption bands of the 2,2′-bipyrimidine complexes W(CO)4(bpym) and (μ-bpym)[M(CO)4]2 (M=Mo, W) with resonance Raman spectroscopy; the emission spectrum of (μ-bpym)[Mo(CO)4]2 (1993) (19)
- Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear {(μ4-TCNX)[Ru(NH3)5]4}8+, TCNX = TCNE and TCNQ, from DFT calculations (2009) (19)
- Electronic, charge and magnetic interactions in three-centre systems (2015) (19)
- Selbstorganisation trigonal‐prismatischer Metallakäfige mit eingeschlossenen BF4−‐ oder CuI32−‐Gast‐Ionen: Strukturen und Bildungsmechanismen (2002) (19)
- Tetrakis[bis(difluorophosphino)methylamine]dichlorodimolybdenum. A new type of compound with a metal-metal triple bond (1980) (19)
- Resolving the Two-Electron Process for the Couple [(C5Me5)M(N∧N)Cl]+/[(C5Me5)M(N∧N)] (M = Rh, Ir) into Two One-Electron Steps Using the 2,2‘-Azobis(pyridine) N∧N Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MIIIntermediates (2003) (19)
- Analysis of Redox Series of Unsymmetrical 1,4-Diamido-9,10-anthraquinone-Bridged Diruthenium Compounds. (2016) (19)
- Mixed-valent and radical states of complexes [(bpy)2M(μ-abpy)M′(bpy)2]n+, M,M′ = Ru or Os, abpy = 2,2′-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes (2006) (19)
- Some reactions of the octahalodirhenate(III) ions. 11. Two new quadruply bonded dirhenium amidinato-bridged complexes (1980) (19)
- Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors. (2017) (19)
- High-frequency (245 GHz) and X-band EPR study of stable dicopper radical complexes (1999) (19)
- A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistry (2008) (19)
- Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. (2015) (19)
- Coordination Alternatives in Dinuclear Bis(pyridin‐2‐ylalkyl)benzylaminecopper(II) Complexes with OH–, RO–, F–, or Cl– Bridges: Experimental Structures and DFT Preferences (2007) (19)
- Tetranuclear osmium complexes of tetracyanoquinodimethane [TCNQ, 2,2′-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile)] and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism† (1997) (18)
- Design and evaluation of conjugated bridging .pi. systems. Molecular orbital characterization and electrochemical determination of the pentacarbonyltungsten binding site in two new ambidentate ligands (1990) (18)
- Geometrical and electronic structures of the acetyl complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M=Mn,Re (2000) (18)
- [(η5‐C5Me5)2Ti2P6], ein verzerrtes Dimetallaphosphacuban (1987) (18)
- 3, 6‐Bis(2‐pyrazinyl)‐1, 2, 4, 5‐tetrazin: Ein neuer mehrfunktioneller Ligand und sein syn, fac‐konfigurierter Bis(tricarbonylchlororhenium)‐Komplex (2003) (18)
- d6‐Metallkomplexe von 4,4′‐Bipyrimidin, einem ambidenten Liganden mit hohem π‐Acceptorvermögen (1985) (18)
- Radical ions, 41. Durosemiquinone and its BF Analogue – Detection of 1,4‐Diborine as an Unexpected Elimination Product (1980) (18)
- Electron paramagnetic resonance and spectroscopic characteristics of electrogenerated mixed-valent systems [(eta 5-C5Me5)M(mu-L)M(eta 5-C5Me5)]+ (M = Rh, Ir; L = 2,5-diiminopyrazines) in relation to the radicals [(eta 5-C5Me5)ClM(mu-L)MCl(eta 5-C5Me5)]+ and [(eta 5-C5Me5)M(mu-L)MCl(eta 5-C5Me5)]2+. (2000) (18)
- Complexes of the imine/thioether mixed-donor ligand 8-methylthioquinoline with d6-configurated transition metal centers: synthesis, structures and comparison with complexes of 1-methyl-2-(methylthiomethyl)-1H-benzimidazole (2004) (18)
- Structural Changes during the Oxidation of B‐, C‐, Si‐, and P‐Substituted Hydrazines (1978) (18)
- Weitreichende elektronische Kopplung in unterschiedlichen Oxidationszuständen eines C4‐verknüpften Tris(β‐diketonato)ruthenium‐Dimers (2003) (18)
- Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion (1999) (18)
- High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge. (2004) (18)
- Structure, EPR and UV–VIS and IR spectroelectrochemistry of reversibly reducible compounds [(C5Me5)IrCl(L)](PF6), L = 1,3-dimethyllumazine or 1,3-dimethylalloxazine (1996) (18)
- Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR (1986) (18)
- Erste strukturelle Charakterisierung eines azoaromatischen Radikalanions, stabilisiert durch Dikupfer(I)‐Koordination (1998) (18)
- Elektrontransfer-katalysierte carbonyl-substitution: I. Synthese und spektroskopie von phosphantricarbonylmetall-komplexen der bidiazine (1988) (18)
- Ambidentes Verhalten des „neuen Vitamins”︁ Methoxatin (Cofaktor PQQ) gegenüber Metallen: Koordinative Stabilisierung der Pyrrolid‐ und der Semichinon‐Form (1990) (18)
- Filling gaps in the series of noninnocent hetero-1,3-diene chelate ligands: ruthenium complexes of redox-active α-azocarbonyl and α-azothiocarbonyl ligands RNNC(R')E, E = O or S. (2012) (18)
- Koordinationsambivalenz und elektronenstruktur ein- und zweikerniger methylcyclopentadienyldicarbonylmangan-komplexe der cyanpyridine und terephthalsäuredinitrile (1987) (17)
- Discovering more non-innocence: triazenido versus triazenyl radical ligand function, and a comment on [NO2]n as a "suspect" ligand. (2013) (17)
- Zur ”Antiaromatizität„ von 1,4-Dihydropyrazinen† (1981) (17)
- Redox Induced Configurational Isomerization of Bisphosphine-Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes. (2017) (17)
- Aluminiumorganische radikalkomplexe von N-heterozyklen (1981) (17)
- A Ligand-Bridged Heterotetranuclear (Fe2Cu2) Redox System with Fc/Fc+ and Radical Ion Intermediates (2013) (17)
- Aggregation control of copper(I) thiolates through substituent size and ancillary chelate ligands: closely related mono-, di-, tri- and tetranuclear complexes (2001) (17)
- Synthesis and Crystal Structure of the First Polymeric Cesium Compound of a Carborane Ligand System (1998) (17)
- Organometallic iridium(III) and rhenium(I) complexes with lumazine, alloxazine and pterin derivatives (1999) (17)
- Effect of metal exchange (Os vs. Ru) and co-ligand variation (Cl(-)vs. acac(-)) on the oxidation state distribution in complexes of an o-phenylenediamido(2(-))/o-quinonediimine redox system. (2009) (17)
- Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): synthesis, spectroscopy and structures (2003) (17)
- A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical. (2018) (17)
- Carbene supported dimer of heavier ketenimine analogue with p and si atoms. (2015) (17)
- Paramagnetic Cluster Ions [B(6)Hal(n)()Hal'(6)(-)(n)()](*)(-) (Hal, Hal' = Cl, Br, I). EPR Evidence for Radical Stabilization through Electronic Effects of the Halogen Substituents. (1998) (17)
- Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(μ-tppz)Ru(L)Cl]+, L = β-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. (2012) (17)
- Coordination of a Hemilabile N,N,S Donor Ligand in the Redox System [CuL2]+/2+, L = 2‐Pyridyl‐N‐(2′‐alkylthiophenyl)methyleneimine (2011) (17)
- Ein- und zweikernige Bis(2,2′-bipyridyl)ruthenium-Komplexe mit N,O-Modelliganden für Dehydrogenase-Cofaktoren / Mono- and Binuclear Bis(2,2′-bipyridine)ruthenium Complexes with N,O-Ligands Modelling Dehydrogenase Cofactors (1987) (17)
- Odd Electron on Nitrogen: A Metal-Stabilized Aminyl Radical (2005) (16)
- Iron(II) versus osmium(II) oxidation in 1,1′-bis(diorganophosphino)ferrocene–osmium(II) complexes (2001) (16)
- Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate Ligand R,R-QuinoxP (2008) (16)
- Spectroelectrochemistry of the Multistep Redox System {(μ-bpym)[Ru(NH3)4]2}n+,n= 2−6, in a Nonaqueous Medium (1998) (16)
- Stufenweise und chemisch reversible Reduktion von Zweikernkomplexen {(μ-bmtz)[MCl(η6-Cym)]2}[PF6]2 (M = Ru, Os; bmtz = 3,6-Bis(2′-pyrimidyl)1,2,4,5-tetrazin) mit bis zu sechs Elektronen (2001) (16)
- Organometallic platinum(II) complexes of methyl-substituted phenanthrolines (2002) (16)
- The intricate paramagnetic state of [Os(Q)2(bpy)]+, Q = 4,6-di-tert-butyl-o-iminobenzoquinone. (2012) (16)
- Tetranuclear complexes of [Fe(CO)2(C5H5)]+ with TCNX ligands (TCNX=TCNE, TCNQ, TCNB): intramolecular electron transfer alternatives in compounds (mu4-TCNX)[MLn]4. (2007) (16)
- Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 20. Synthetic and Structural Studies on Sandwich Ln(III) Carborane Clusters. II (Ln(III) = Sm, Gd, Dy, Ho, Er) (1996) (16)
- N(2) (.3-): filling a gap in the N(2) (n-) series. (2009) (16)
- Homologous chromium, molybdenum, and tungsten derivatives of 6-chloro-2-hydroxypyridine. Inductive effects on the metal-metal bond length (1980) (16)
- Ga9(CMe3)9, ein wichtiger neuer Baustein in der Strukturchemie der Alkylelement(i)-Verbindungen EnRn (E=B–In) (2001) (16)
- Einelektronenübertragung: Abschied von Elektronenpaar‐Mechanismen? (1984) (16)
- Chelate rings of different sizes with non-innocent ligands. (2019) (16)
- Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1,4-bis(2-phenolato)-1,4-diazabutadiene. (2007) (15)
- Elektronenübertragung durch Grignard‐Reagentien: Direkter Nachweis von Organomagnesium‐Radikalkomplexen (1982) (15)
- Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II) (2005) (15)
- Reversibly reducible cis-dichloroplatinum(II) and cis-dichloropalladium(II) complexes of bis(1-methylimidazol-2-yl)glyoxal. (2007) (15)
- Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 21. Syntheses, Structures, EPR Spectra, and Reactivities of Bent-Sandwich and Half-Sandwich Titanacarboranes. Full Analysis of Spin−Spin Coupling in Two Structurally Characterized Titanium(III)−Carborane Dimers (1997) (15)
- [Ga9(CMe3)9]*--a persistent cluster radical anion, boron-analogous chemistry with the heavier homologue gallium. (2003) (15)
- Configuration-dependent electron hopping between equivalent ligands in isomeric ruthenium(II) complexes (1996) (15)
- The "supershort" chromium-to-chromium quadruple bond: its occurrence in a tetracarboxamidatodichromium(II) compound (1979) (15)
- Metallorganische Komplexkationen [(ηn-CnR′n M(RN=CH-CH=NR)Cl]+ von 1,4-Diazabutadienen (M = Os und n = 6 oder M = Rh, Ir und n = 5, R = 2,6-Dialkylphenyl). Strukturen und Reduktion zu den Neutralverbindungen [(ηn-CnR′n)M(RN-CH=CH-NR)] (2001) (15)
- Reduction reactivity of catecholamines and their ability to promote a Fenton reaction (2016) (15)
- Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac = acetylacetonate, bpy = 2,2′-bipyridine): syntheses, structures, spectra and redox properties (2005) (15)
- UV-vis-NIR and EPR characterisation of the redox series [MQ(3)](2+,+,0,-,2-), M = Ru or Os, and Q = o-quinone derivative. (2012) (15)
- N,N'-DISILYLATED 1,4-DIHYDROPYRAZINES: ORGANOSILYL SUBSTITUTION REACTIONS,STRUCTURAL EFFECTS OF STERIC HINDRANCE, AND ELECTRON EXCHANGE WITH C60 (1995) (15)
- Isoelectronic Radical Ions and Redox Systems (1980) (15)
- Copper(I) and copper(II) complexes of the bidentate imidazole/thioether ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole (1999) (15)
- Radical ions. 22. Radical anion and radical trianion of 1,4-bis(dimethylphosphino)benzene (1978) (15)
- Koordinationsverbindungen des reduzierten Pyrazins mit Alkylderivaten von Bor, Aluminium, Gallium und Indium / Coordination Complexes of Reduced Pyrazine and Alkyl Derivatives of Boron, Aluminum, Gallium, and Indium (1981) (15)
- Die vielseitige Chemie der 1,4-Diazine: Organische, anorganische und biochemische Aspekte (2006) (15)
- Complexes of [Re(CO)3Cl] with different oxidation states of the polyfunctional bmtz/H2bmtz ligand system (bmtz=3,6-bis(2-pyrimidyl)-1,2,4,5-tetrazine) (2004) (14)
- The molecular geometry of the elusive 1,4-dihydropyrazine. An MNDO study (1984) (14)
- Mixed-ligand copper complexes with 8-methylthioquinoline and triphenylphosphane or the o-semiquinone/catecholate redox system (2005) (14)
- Tetranuclear complexes {(μ4-TCNX)[Cu(Me3TACN)]4}(BF4)4 with TCNX=TCNE, TCNQ or TCNB (1,2,4,5-tetracyanobenzene) and Me3TACN=1,4,7-trimethyl-1,4,7-triazacyclononane (2001) (14)
- Electorn Transfer by Grignard Reagents: Direct Evidence for Organomagnesium Radical Complexes (1982) (14)
- Electron distribution in the Cr(CO)4(bpy)>·>>–>> (bpy = 2,2′-bipyridine) radical anion as revealed by EPR spectroscopy and IR spectroelectrochemistry of 13CO-enriched species (1998) (14)
- A tetranuclear organorhenium(i) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4 (-). (2008) (14)
- Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes. (2019) (14)
- Dichlorogold(III) complexes of bis(1-methyl-2-imidazolyl)ketone and related ligands: Geometrical and electronic structures (2006) (14)
- Oxotungsten(V) and (VI) complexes of 1,3-dimethyllumazine as models for the tungstopterin cofactor (1994) (14)
- EPR EVIDENCE FOR LOW-LYING MLCT STATES IN TETRACYANOIRON AND -RUTHENIUM COMPLEXES WITH STRONGLY PI -ACCEPTING CHELATE LIGANDS. COMPARISON WITH ISOELEC TRONIC TETRACARBONYLMETAL SPECIES (1995) (14)
- All-trans-[ClRu(II)(py)4(NC)Ru(II)(py)4(CN)Ru(II)(py)4(NO)](PF6)4: a redox-active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motif. (2009) (14)
- Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer. (2017) (14)
- A SYSTEMATIC SYNTHETIC APPROACH TO A NOVEL, MIXED 2,3-C2B4- AND 2,4-C2B4-ERBIUM(III) CARBORANE BENT-SANDWICH COMPLEX (1995) (14)
- Tetrathiorhenate(VI), ReS42–. Spectroelectrochemical characterization (UV–VIS–IR) of a small new d1 system and of its tetrakis(2,2′-bipyridine)diruthenium(II) complex (EPR) (1992) (14)
- Interaction of two equivalent electron transfer/atom transfer centers via 2,2′-bipyrimidine as bridging ligand (1998) (14)
- Isoelektronische Radikalionen aus Einelektronenübertragungsreaktionen: Direkter Nachweis beständiger, solvensgetrennter Radikalanion/Radikalkation-Paare† (1984) (14)
- Ein stabiles neutrales Radikal in der Koordinationssphäre des Aluminiums (2017) (14)
- π‐Rückbindung und Stabilität der Oxidationsstufen in Tetracarbonyldicyclopentadienyl(μ‐pyrazin)‐dimangan(I)‐Komplexen (1984) (14)
- Elektrochemische und spektroskopische Charakterisierung von N,N′‐Dialkylchinoxalinium‐Redoxsystemen (1991) (14)
- π-Back Bonding and Stability of the Oxidation States in Tetracarbonyldicyclopentadienyl-(μ-pyrazine)dimanganese(I) Complexes† (1984) (13)
- A study of the reduced states of four isomeric bidiazines (diaza-2,2′-bipyridines) by UV–VIS/NIR-spectroelectrochemistry (1992) (13)
- Electron transfer reactions of (C5R5)2(CO)2Ti (R=H or Me) with TCNE or TCNQ: Spectroelectrochemical assignment of metal and ligand oxidation states in [(C5Me5)2(CO)Ti(TCNX)]2−/−/o/+ (2003) (13)
- Oxidation and reduction response of α-diimine complexes with tricarbonylrhenium halides and pseudohalides (2014) (13)
- Specific solvatochromism of the prototypical olefin complexes (.eta.2-TCNE)M(CO)5 (M = chromium, tungsten) resulting from n and .pi. donation of aprotic solvents toward the .pi.-acceptor ligand (1991) (13)
- Bis(homoleptische) vs. heteroleptische Kupfer(I)‐Komplexe: Elektrosynthese, Spektroskopie und Kristallstruktur von {[Cu(BIK)2]+}2{[Cu4(SR)6]2−} · 3(CH3CN) · (RSH); BIK = Bis(N‐methylimidazol‐2‐yl)keton, R = o‐Tolyl (1996) (13)
- Multinuclear NMR study of some organoplatinum complexes containing multifunctional azines as chelating ligands (2004) (13)
- Ein vollständig charakterisiertes Komplexion mit nichtreduziertem TCNQ als vierfach verbrückendem Liganden: [(μ4‐TCNQ){fac‐Re(CO)3(bpy)}4]4+ (2001) (13)
- Radical Cations of Tetrasilyl‐Substituted Hydrazines (1976) (13)
- Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation (2011) (13)
- Elektronenreiche Heterocyclen mit Thiophosphinamid‐, Carboxamid‐, O‐Silylurethan‐ und O‐Silylisoharnstoff‐Funktionalität. Synthese, Spektren, chemische und elektrochemische Reaktivität (1989) (13)
- (α-Diimine)tricarbonylhalorhenium complexes: the oxidation side. (2012) (13)
- Synthesis and characterization of a triphenyl-substituted radical and an unprecedented formation of a carbene-functionalized quinodimethane. (2014) (13)
- Reversible radical complex formation of an organometallic diplatinum(IV) compound (2007) (13)
- cis-Dicarbonylbis(tributylphosphan)molybdän-Komplexe der vier isomeren bidiazine (1988) (13)
- Die konjugative Verbrückung metallorganischer Reaktionszentren in Heterozweikernkomplexen [(OC)3ClRe(μ-L)MCl(C5Me5)]+, M = Rh oder Ir - Spektroskopische Konsequenzen reduktiver Aktivierung† (2004) (13)
- A structurally characterised redox pair involving an indigo radical: indigo based redox activity in complexes with one or two [Ru(bpy)2] fragments. (2017) (13)
- 3,3′-Bipyridazine: the ‘second-best’ bidiazine ligand for M(CO)4 fragments (M = Cr, Mo, W) (1986) (13)
- Electrochemical oxidation of [Cr(CO)4(tmp)] to the low-spin Cr(I) species [Cr(CO)4(tmp)]+ (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): an IR, UV–Vis, and EPR spectroelectrochemical and DFT computational study of the accompanying changes in molecular and electronic structure (2001) (13)
- Non-innocence of 1,4-dicyanamidobenzene bridging ligands in dinuclear ruthenium complexes. (2013) (13)
- LIGANDENGESTUTZTE KOPPLUNG METALLORGANISCHER REAKTIONSZENTREN (1997) (13)
- Electronic structure of a heterotetranuclear Cu12FeII2 complex bridged by π-accepting 2,2′-bipyrimidine. Close-lying but orthogonal frontier orbitals (1990) (13)
- A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes {(μ4-TCNX)[Ru(NH3)5]4}8+ (TCNX=TCNE, TCNQ) (1993) (13)
- Copper(I) complexes with N,O-donor Schiff base ligands related to intermediate forms of the TPQ cofactor in amine oxidases (2000) (13)
- Conjugation length dependent ground and excited state electronic behavior in oligothienyl ru complexes. (2006) (13)
- 2,3-Bis(1-methylimidazol-2-yl)quinoxaline (bmiq), a new ligand with decoupled electron transfer and metal coordination sites: the very different redox behaviour of isoelectronic complexes with [PtCl2] and [AuCl2]+. (2011) (13)
- Das ungeradzahlig elektronenkonfigurierte Komplexion [Ruk(NOm)(Qn)(terpy)]2+ mit zwei idealtypischen “nicht‐unschuldigen” Liganden (2009) (13)
- GROUND STATE ELECTRON TRANSFER BETWEEN TCNE AND ONE OR MORE 16-ELECTRON SPECIES CONTAINING VANADIUM, OSMIUM, RUTHENIUM OR COBALT (1996) (13)
- The New Tetrafunctional π Acceptor Ligand 3,6-Bis(2′-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of its 1,4-Dihydro Form (1995) (13)
- Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2). (2008) (13)
- A TETRAKIS(AMIDINATO)DICHROMIUM COMPLEX WITH A “SUPERSHORT” CHROMIUM-CHROMIUM QUADRUPLE BOND (1980) (13)
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- Tetraacetanilidodichromium and -dimolybdenum: another supershort chromium-chromium bond and an unexpected structural difference (1979) (12)
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- Replacement of 2,2‘-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for [(N∧N)IrCl(C5Me5)]+ Complexes but the Hypsochromic Shift for (N∧N)Ir(C5Me5)? (2003) (12)
- The complex (μ,η2:η2-L)[AuCl2]2, L2−=N,N′-bis(α-picolinoyl)hydrazido(2−), as obtained directly or through ring-opening reaction of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (2004) (12)
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- 2‐Heteroatom‐1,3‐diazole und Chinoxalin als π‐Acceptor‐Brückenliganden für M(CO)5‐Fragmente (M = Cr, Mo, W) Synthese, Elektrochemie, Absorptions‐ und Emissions‐Spektroskopie (1989) (11)
- Mixed-valency with cyanides as terminal ligands: Diruthenium(III,II) complexes with the 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine bridge and variable co-ligands (CN− vs. bpy or NH3) (2010) (11)
- Mechanism and product characterization from the electroreduction of heterodinuclear complexes [(C5Me5)ClM(μ-L)Re(CO)3X](PF6), M=Rh or Ir, L=2,2′-azobispyridine or 2,2′-azobis(5-chloropyrimidine), X=halide (2004) (11)
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- Bidirectional non-innocence of the β-diketonato ligand 9-oxidophenalenone (L-) in [Ru([9]aneS3)(L)(dmso)]n, [9]aneS3 = 1,4,7-trithiacyclononane. (2014) (11)
- Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties (2008) (11)
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- Eine weitere Unschuldsvermutung widerlegt: Triazenido‐ versus Triazenylradikal‐Ligandenfunktion sowie eine Anmerkung zu [NO2]n als “suspektem” Liganden (2013) (11)
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- Syntheses, Structures, and Properties of the Complexes [Ag(N∧S)n](X), N∧S = 1‐Methyl‐2‐(alkylthiomethyl)‐1H‐benzimidazoles, X = PF6 (n = 2) or PO2F2 (n = 1) (2000) (10)
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- UV-vis, IR and EPR spectroelectrochemical study of the EC redox transition [(PR3)n(CO)3(R′-pz)M]+/0; M = Mo, W; R′-pz = N-alkylpyrazinium; R = isopropyl, cyclohexyl; n = 1 or 2 (1996) (9)
- Lewis basicity of a chlorine atom bound to an aliphatic carbon atom as sensed by a quadruple chromium-chromium bond. Structures of M2[(2,6-xylyl)NC(CH3)O]4.2CH2Cl2, M = chromium, molybdenum (1980) (9)
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- Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centres Bridged by 2,2'-Bipyrimidine (2001) (8)
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- Synthesis and crystal structure of a novel, TMEDA-stabilized closo-cobalt(II) carborane : an intermediate for anionic, commo-cobalt(III) carborane complexes (1993) (8)
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- Notizen. Radikalionen, XVIII: Existieren beständige Radikalkationen von Phosphinen? (1978) (8)
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- A tetrakis(amidinato)dichromium complex with a "supershort" chromium-chromium quadruple bond (1979) (8)
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- Radical anion of 1,4-diborabenzene (1980) (8)
- ESR Spectroscopy of Inorganic and Organometallic Radicals (2008) (8)
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- Coordination chemistry of Π-electron deficient ligands. Binuclear tungsten pentacarbonyl complexes of the weakly basic 2.1.3-benzochalcogenadiazoles (1985) (7)
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- Insertion von CO2, COS and CS2 in die NSi-Bindung des extrem elektronenreichen 1,4-Bis(trimethylsilyl) -1,4-dihydropyrazins und Bildung eines neuen poly(N,S-) heterocyclischen Systems durch mehrfache Cycloaddition (1995) (7)
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- TeS2.−‐Radikalanionen in CuBrCu1.2TeS2 (1998) (7)
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- Silver(I), Copper(I) and Copper(II) Complex of the New N,Se‐Chelate Ligand 2‐Phenylselenomethyl‐1H‐benzimidazole: Electrochemistry and Structure (2009) (6)
- Molekül- und Kristallstrukturen zweier einkerniger Ruthenium(II)-Komplexe mit dem starken π·Akzeptorliganden 2,2'-Azobis(pyridin) (abpy): [mer-Ru(abpy)3](PF6)2 und Ru(abpy)2Cl2 (ctc-Isomer) / Molecular and Crystal Structures of Two Mononuclear Ruthenium(II) Complexes with the Strongly π Accepting Li (1995) (6)
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- VALENCE DELOCALIZATION DESPITE WEAK METAL-METAL COUPLING IN A BIS(ORGANOOSMIUM(III,II)) COMPLEX WITH A PYRAZINE BRIDGE (1998) (6)
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- Kupferkomplexe des neuen Chelatliganden 1-Methyl-2-(2-thiophenolato)-1H-benzimidazol (mtpb) und dessen Oxidationsprodukten† (2005) (5)
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- Metallorganische 5d6-Übergangsmetallkomplexe von zwei 1-Methyl-(2-alkylthiomethyl)-1H-benzimidazol-Liganden: Strukturen und elektrochemische OxidationProfessor Joachim Strähle zum 65. Geburtstag gewidmet (2002) (5)
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- (ACETATO)TRIS(N,N′-DIPHENYLACETAMIDINATO)DIMOLYBDENUM AND BIS(ACETATO)BIS(N,N′-BIS(2,6-XYLYL)ACETAMIDINATO)DIMOLYBDENUM TETRAKIS(TETRAHYDROFURANATE). TWO NEW MIXED-LIGAND QUADRUPLY BONDED DIMOLYBDENUM COMPOUNDS (1981) (5)
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- Koordinationschemie reduzierter N-Heterozyklen. Komplexe des Pyrazin-Radikalanions mit Phenylmetallkationen +MPh von Beryllium, Magnesium und Zink / Coordination Chemistry of Reduced N-Heterocycles. Complexes of Pyrazine Anion Radical with Phenyl Metal Cations +MPh of Beryllium, Magnesium and Zinc (1981) (4)
- Bindungscharakteristik der H2-koordinierenden Fragmente W(CO)3(PR3)2. Aussergewöhnliche optische und elektrochemische Eigenschaften zweikerniger Pyrazinkomplexe (1990) (4)
- Cobalt Carbonyl Hydrides with 1,1′-Diphosphinylferrocene Ligands - Structural and Electrochemical Diversity: Cobalt Carbonyl Hydrides with 1,1′-Diphosphinylferrocene Ligands - Structural and Electrochemical Diversity (2017) (4)
- The Coordination Chemistry of TCNE, TCNQ, and Related Polynitrile π‐ Acceptors (1994) (4)
- Heterokuban‐Cluster‐Verbindungen (NEt4){Y=M[(μ3‐S)Re(CO)3]3(μ3‐E)} (M = W oder Mo, Y = O oder S, E = S oder Se): Strukturen, Spektroskopie und Elektrochemie (2001) (4)
- Fused N-Heterocyclic-Bridged Isomeric Diruthenium Complexes [(acac)2Ru(μ-DIPQD)Ru(acac)2]n, n = +2, + 1, 0, -1, -2. (2020) (4)
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- Axially coordinated tetrakis[N-2,6-dimethyphenyl)lacetamido]dimolybdenum(II) compounds. Structures of Mo2[(xylyl)NC(CH3)O]4.L (L = NC5H4CH3) (1982) (4)
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- Variable noninnocence of substituted azobis(phenylcyanamido)diruthenium complexes. (2015) (3)
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- Charge Delocalization in a Heterobimetallic Ferrocene-( Vinyl ) Ru ( CO )-Cl ( P i Pr 3 ) 2 System † (2009) (3)
- (Acetato)tris(N,N'-diphenylacetamidinato)dimolybdenum and bis(acetato)bis[N,N'-bis(2,6-xylyl)acetamidinato]dimolybdenum tetrakis(tetrahydrofuranate). Two new mixed-ligand quadruply bonded dimolybdenum compounds (1981) (3)
- Intramolecular Charge Transfer in Ruthenium Complexes [Ru(acac) 2 (ciq)] with Ambidentate Camphoriminoquinone (ciq) Ligands (2021) (3)
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- Zur Reaktion aromatischer Phosphanderivate mit Elektronen, III [1, 2] Phosphan-Borane, -Alane und -Gallane / On the Reaction of Aromatic Phosphane Derivatives with Electrons, III [1, 2] Phosphane-Boranes, -Alanes, and -Gallanes (1985) (3)
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- RADICAL PRODUCTS IN SINGLE ELECTRON TRANSFER REACTIONS OF LITHIUM TRIETHYLHYDRIDOBORATE AS DETECTED BY ESR AND MULTINUCLEAR (PROTON, BORON-10, BORON-11, AND NITROGEN-14) ENDOR SPECTROSCOPY (1984) (2)
- Oxidation State Assignments in the Organoplatinum One‐Electron Redox Series [(N ^ N)PtMes 2 ] n , n = +,0, –,2‐ (2020) (2)
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- A Fully Characterized Complex Ion with Unreduced TCNQ as Fourfold Bridging Ligand: (2001) (0)
- Cobalamine, einschließlich Vitamin und Coenzym B12 (1995) (0)
- Tetrazine Chelate Ligands Bridging Two [Ru(acac)2] Fragments: Mixed Valency and Radical Complex Formation (2022) (0)
- Rhenium Tricarbonyl Complexes of Azodicarboxylate Ligands (2022) (0)
- Crystalline Heterocyclic Radical Cation Salts as Stable Intermediates of New Redox-Mediating Systems. (1989) (0)
- DIHYDROPYRAZINE. KRISTALL- UND MOLEKULSTRUKTUREN METALLORGANISCHER DERIVATE * (1985) (0)
- Book Review: Transition Metal Chemistry. By M. Gerloch and E.C. Constable (1996) (0)
- Exceptionally Variable Solvatochromism of Centrosymmetric Octacarbonyldimolybdenum(0) Complexes. Rules to Estimate the Solvent Sensitivity of Charge-Transfer Absorption Energies. (1987) (0)
- Deprotonated p-Phenylenediamines as Noninnocent Ligands. Metal-to-Ligand Spin Transfer in the Ground State and Ligand-to-Metal Charge Transfer in the Lowest Excited State of Low-Spin Manganese(II) Complexes. (1988) (0)
- Flavosemiquinone Model Systems. Part 3. Molecular and Crystal Structure of the Cation Radical Salt 1,4,6,7-Tetramethylquinoxalinium Triiodide. (1993) (0)
- The Stable Radical Cation of Tetrakis(dimethylamino)-p-benzoquinone. (1986) (0)
- Metalle im Zentrum der Photosynthese: Magnesium und Mangan (1991) (0)
- Fundgrube Anorganischer Chemie: Modern Inorganic Chemistry. Von W. L. Jolly. McGraw-Hill Book Company, New York 1983. 610 S., Abb., geb., ca. 105, 40 DM. ISBN 0-07-032760-2 (1984) (0)
- Oxidative Perhydroxylation of [closo‐B12H12]2‐ to the Stable Inorganic Cluster Redox System [B12(OH)12]2‐/·‐: Experiment and Theory. (2011) (0)
- Exploration of Mixed‐Valence Chemistry: Inventing New Analogues of the Creutz—Taube Ion (2001) (0)
- Copper(I)-Assisted Formation of an “Organic” Sandwich-Structure: Structural Prerequisites for Luminescence of the Dinuclear Complexes ((μ-Bipyrimidine)(Cu(PR3)2)2)X2. (1990) (0)
- The d0, d1 and d2 Configurations in Known and Unknown Tetrathiometal Compounds MS4n- (M: Mo, Tc, Ru; W, Re, Os). A Quantum Chemical Study. (2010) (0)
- Oxidative Perhydroxylation of [c[oso-b 12 H 12 ]2-to the Stable Inorganic Cluster Redox System [b 12 (oh)12]2-1.-: Experiment and Theory** (2011) (0)
- (Übergangs-)Metall-Metall-Mehrfachbindungen: Multiple Bonds between Metal Atoms. Von F. A. Cotton und R. A. Walton. Clarendon Press, Oxford, 2. Aufl., 1993. 787 S., Abb., Tab., geb. 70,-£. ISBN 0-19-855649-7. (1994) (0)
- Book Review: Photoinduced Electron Transfer. Parts A–D. Edited by M. A. Fox and M. Chanon (1990) (0)
- Aufnahme, Transport und Speicherung eines essentiellen Elements: Das Beispiel Eisen (1991) (0)
- “Guilty” Verdict — Evidence for the Noninnocence of Cyanide (2012) (0)
- Replacement of 2,2'-bipyridine by 1,4-diazabutadiene acceptor ligands: why the bathochromic shift for [(N empty set N)IrCl(C5Me5)]+ complexes but the hypsochromic shift for (N empty set N)Ir(C5Me5)? (2003) (0)
- Nickelhaltige Enzyme: Die steile Karriere eines lange übersehenen Biometalls (2005) (0)
- Cobalamine (Vitamin und Coenzym B 12 ) (1991) (0)
- Electron Transfer Reactivity of Organometallic Compounds Involving Radical-Forming Noninnocent Ligands (2016) (0)
- Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (Ai-WS4)[IrCl(C5Me5)]2 (2013) (0)
- Biologische Funktion der “frühen” Übergangsmetalle: Molybdän, Wolfram, Vanadium, Chrom (1991) (0)
- Tetranuclear Mixed-Valence Manganese Complexes with Reduced TCNE or TCNQ as η4-Bridging Ligands. (1987) (0)
- Structure, Spectroscopy and Magnetism of 1,4‐Dihydro‐1,4‐diazine Radical Cations: Exceptionally Stable Intermediates Related to Methylviologen and Flavosemiquinone Radicals (1994) (0)
- Bis ( 1-methylimidazol-2-yl ) quinoxaline ( bmiq ) , a new ligand with decoupled electron transfer and metal coordination sites : the very different redox behaviour of isoelectronic complexes with [ PtCl 2 ] and [ AuCl (2011) (0)
- Zur Reaktion aromatischer Phosphanderivate mit Elektronen. III: Phosphan-Borane, -Alane und -Gallane (1985) (0)
- CHEMICAL AND ELECTROCHEMICAL REDUCTION OF PENTACARBONYL(4-CYANOPYRIDINE) COMPLEXES OF CHROMIUM(0), MOLYBDENUM(0) AND TUNGSTEN(0) (1984) (0)
- Chemotherapie mit Verbindungen nicht-essentieller Elemente: Platin, Gold, Lithium (1991) (0)
- RADICAL IONS. PART X. ELECTRON-RICH ALKYL OLEFINS AND THEIR RADICAL CATIONS (1977) (0)
- Coordinative Aspects of Single Electron Exchange Between Main Group or Transition Metal Compounds and Unsaturated Organic Substrates (2010) (0)
- Charge-Transfer and Electron-Transfer Properties of d6 Metal Complexes with μ-Pyrazine. (1986) (0)
- THE REDUCTION OF TRIPHENYLPHOSPHINE DERIVATIVES TO THEIR RADICAL ANIONS AND TO THE RADICAL DIANION OF DIBENZOPHOSPHOLE (1983) (0)
- Elektronenreiche olefins. III: Bildung des ersten N, N'-persilylierten 1,4-Diaminoethens über eine 1,2,3 Triazolin (4)-Zurschenstufe mit 8 cyclisch konjugierten π-elektronen und 3 benachbarten N-Elektronenpaaren (1989) (0)
- ELECTRON TRANSFER BY GRIGNARD REAGENTS: DIRECT DETECTION OF ORGANOMAGNESIUM RADICAL COMPLEXES (1982) (0)
- Unconventional Mixed‐Valent Complexes of Ruthenium and Osmium (2007) (0)
- Struktur und Magnetismus stabiler Radikalkation-Salze: N,N'-Diethylchinoxalinium Tetraphenylborat im Vergleich mit Pyrazinium- und Phenazinium-Analogen (1989) (0)
- pi Molecular Orbital Crossing a(2)(chi)/b(1)(psi) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)(4) Complexes (M = Cr, Mo, W). (1996) (0)
- THE “SUPERSHORT” CHROMIUM-TO-CHROMIUM QUADRUPLE BOND: ITS OCCURRENCE IN A TETRACARBOXAMIDATODICHROMIUM(II) COMPOUND (1979) (0)
- Extremely Long-waved Charge-Transfer Absorptions of Binuclear Complexes with Azomodified 2,2′-Bipyridine Ligands. (1985) (0)
- Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox‐Active Amidinato Ligand (2020) (0)
- Biomineralisation: Kontrollierter Aufbau biologischer Hochleistungsmaterialien (1991) (0)
- CCDC 1504145: Experimental Crystal Structure Determination (2016) (0)
- Electronic Structure of 1,4-Dihydro-l,2,4,5-tetrazines and of Related 1,4-Dihydro-aromatic Compounds. (1986) (0)
- Copper ‐ A “Modern” Bioelement (1996) (0)
- Stable Binuclear o- and p-Semiquinone Complexes of (Ru(bpy)2)2+. Radical Ion versus Mixed Valence Dimer Formulation. (1989) (0)
- FROM ION PAIRS TO RADICAL COMPLEXES: COORDINATION COMPOUNDS OF REDUCED 2,2′-BIPYRIDINE WITH ORGANOMETALLIC CATIONS (1982) (0)
- RADICAL IONS, XXI. ESR INVESTIGATION OF TRIMETHYLSILYLMETHYL OR TRIMETHYLSILYL SUBSTITUTED RADICAL CATIONS OF ANTHRACENE, BIPHENYL, AN 9,10-DIHYDROANTHRACENE (1979) (0)
- Synthesis and characterization of 2-dimethylaminoethyl thiolate complexes of palladium(II) and platinum(II) (2003) (0)
- Historischer Überblick und aktuelle Bedeutung (1991) (0)
- Reaction of Aromatic Phosphanes with Electrons. Part 4. Significance of Low-Lying Orbitals at Phosphorus for the Mobility and Coordinative Characteristics of PR2 Substituents in Reduced p-Phenylenediphosphanes. (1990) (0)
- Metallaheterocumulenes. Part 6. An Isocyanide Radical as a Complex Ligand. (1987) (0)
- Benzo-1,3,2-diselenazolylium Salts - Synthesis and Reactivity. (1992) (0)
- Reactivity of Very Electron‐Rich Organosilyl Amines (2008) (0)
- Additions and Corrections - Radical Anion and Radical Trianion of 1,4-Bis(dimethyl-phosphino)benzene (1981) (0)
- Electronic Stabilization Through 7‐π Electron Conjugation in Heterocycles. Molecular and Crystal Structure of an Inert Monocyclic Radical Cation. (1989) (0)
- HETEROCYCLIC RADICAL ANIONS AS LIGANDS: AN UNEXPECTED COORDINATION CHANGE IN PENTACARBONYLMETAL COMPLEXES (1982) (0)
- Colored Complexes: The Charge Transfer Phenomenon (1988) (0)
- TeS2·⁻- Radikalanionen in CuBrCu1.2TeS (1998) (0)
- TETRACARBANILANILIDODICHROMIUM(II): A KEY TO THE UNDERSTANDING OF THE CHROMIUM-CHROMIUM QUADRUPLE BOND (1980) (0)
- CCDC 277356: Experimental Crystal Structure Determination (2006) (0)
- CCDC 271456: Experimental Crystal Structure Determination (2006) (0)
- CCDC 1504144: Experimental Crystal Structure Determination (2016) (0)
- The Dinuclear CuA Center in Cytochrome c Oxidase and N2O Reductase ‐ A Metal‐Metal Bond in Proteins (1995) (0)
- Stabilization of Biochemically Interesting Intermediates by Metal Coordination. Part 6. Charge Transfer in Complexes of 1,3-Dimethyllumazine with Low-Valent Metals. (1990) (0)
- Chemie der ungeraden Elektronenzahl Electron‐Transfer and Radical Processes in Transition‐Metal Chemistry. Von D. Astruc. VCH, Weinheim, 1995. 630 S., geb., 225,hyphen;DM. ISBN 1‐56081‐642‐2. (1996) (0)
- Thermal and Light Induced Electron Transfer Reactions of Main Group Metal Hydrides and Organometallics. (1994) (0)
- [Radical Ions .61. Dialkylamino-substituted Acetylenes and Allenes - Ionization, Oxidation and Alcl3-catalyzed Hydrogen Transfer] (1984) (0)
- RADICAL IONS, XVI. TETRAZENE AND ITS DERIVATIVES. 6. ONE-ELECTRON OXIDATION OF SILYL-SUBSTITUTED TETRAZENES AND PENTAZENES (1978) (0)
- Paramagnetic Copper(I) Dimers. (1987) (0)
- Biologische Bedeutung anorganischer Nichtmetall-Elemente (1991) (0)
- Synthesis, characterization and structure of tribromo(2-phenyl-1,8- naphthyridine)gold(III) (2011) (0)
- SUBSTITUENT EFFECTS AND PERTURBATION OF Π-SYSTEMS. XXXVI. TERT-BUTYL-, TRIMETHYLSILYL-, TRIMETHYLGERMYL-, TRIMETHYLSTANNYL- AND TRIMETHYLPLUMBYL-SUBSTITUTED BENZENE AND NAPHTHALENE DERIVATIVES AND THEIR ANION RADICALS (1981) (0)
- Elektronischer Olefine. I: Zusammenhang zwischen Struktur, Spektroskopie und Reaktivität von Tetrakis(trimethylsilylmethyl)ethen (1988) (0)
- RADICAL IONS. 48. RADICAL ANIONS AS INTERMEDIATES IN THE REDUCTIVE DESULFURIZATION OF TERTIARY PHOSPHINE SULFIDES (1982) (0)
- Synthesis , Structure , and Spectroscopic Properties of the New Lanthanum ( III ) Fluoride Oxomolybdate ( VI ) La 3 FMo 4 O 16 (2010) (0)
- Molecular and Electronic Structure of Electron-Transfer Active Main-Group Organometallics. (1989) (0)
- Interaction of Frontier Orbitals of Group 15 and Group 16 Methides with the Frontier Orbitals of Benzene (Elektronentransmissionsspektren von (I)--(IV)). (1986) (0)
- Moderne Anorganik‐ ein Versuch: „Anorganische Chemie”︁. Von D. F. Shriver, P. W. Atkins und C. H. Langford. VCH Verlagsgesellschaft, Weinheim 1992. 781 S., 368 Abb., 127 Tab., geb. DM 98,‐. ISBN 3‐527‐28105‐3. (1993) (0)
- Electron Transfer Catalyzed Substitution in Carbonyl Complexes. Part 5. Electron Transfer Autocatalytic Formation, Intramolecular Charge Transfer, and Qualitatively Different Solvatochromism of σ and π Transition-Metal Carbonyl Comple (1989) (0)
- Biomineralisation: Kontrollierte Konstruktion biologischer Hochleistungsmaterialien (1995) (0)
- Electron Rich Olefins. Part 3. Formation of the First N,N′-Persilylated 1,2-Diaminoethene via a 1,2,3-Triazoline(4)-Intermediate with 8 Cyclically Conjugated π Electrons and 3 Neighboring N Electron Pairs. (1989) (0)
- 3,3′-Bipyridazine: the "Second-best" Bidiazine Ligand for M(CO)4 Fragments (M: Cr, Mo, W). (1986) (0)
- PHOTOELECTRON SPECTRA AND MOLECULAR PROPERTIES. 75. RADICAL IONS, XIX. ONE-ELECTRON OXIDATIONS OF (TRIMETHYLSILYLMETHYL-SUBSTITUTED BENZENES IN THE GASEOUS PHASE AND IN SOLUTION (1979) (0)
- Der anorganische Naturstoff O2: Aufnahme, Transport und Speicherung (1991) (0)
- What Determines the Comproportionation Constant in Molecule-Bridged Mixed-Valence Complexes? Evidence for the Crucial Role of the Ligand LUMO in Four Ru(II)Ru(III) Dimers. (1988) (0)
- Biochemisches Verhalten anorganischer Radionuklide: Strahlenbelastung und medizinischer Nutzen (1991) (0)
- Synthesis, Characterization and Structure of Tribromo(2-phenyl- (2011) (0)
- New Sulfide-Bridged Heterocubanes [MVI(S)Re3I(CO)9 (μ3-S)4]-, M: Mo or W, with Transition Metals in Very Different Oxidation States. (2010) (0)
- A Stable Bis(chelate) Analogue of the Creutz‐Taube Ion. (1988) (0)
- ORGANOMETALLICALLY STABILIZED 1,4‐DIHYDROPYRAZINES: EXTREMELY ELECTRON‐RICH HETEROCYCLES (1981) (0)
- RADICAL IONS. PART 40. RADICAL ANION OF 1,4-DIBORABENZENE (1980) (0)
- Products from Multiple Insertion Reactions between Diisocyanates and Antiheteroaromatic 1,4‐Bis(trimethylsilyl)‐1,4‐Dihydropyrazine (2008) (0)
- Katalyse und Regulation bioenergetischer Prozesse durch die Erdalkalimetallionen Mg2+ und Ca2+ (1991) (0)
- Specific Insertion of OCS into the N‐Si Bond of an Extremely Electron‐Rich Molecule as Evident from the X‐Ray Crystal Structure (2008) (0)
- Synthesis, Structure, and Spectroscopic Properties of the New Lanthanum(III) Fluoride Oxomolybdate(VI) La3FMo4O16. (2010) (0)
- PHOTOELECTRON SPECTRA AND MOLECULAR PROPERTIES. 77. RADICAL IONS, XXIII. R2P 2P AND R2N SUBSTITUTED BENZENES: CHARGE DISTRIBUTION IN THEIR CATIONS, ANIONS, AND TRIANIONS (1979) (0)
- Organoboron Substituent Effects in EPR/ENDOR Spectroscopy. Radical Ions with B‐C and B‐N Bonds. (1992) (0)
- Generation and Characterization of Diphosphene and Triphosphene Radical Anions . Computational Studies on the Structure and Stability of P 3 H 3 (1997) (0)
- Coordinative diversity in mononuclear CuI and CuII complexes of O,N,S-ambidentate camphoriminoquinone ligands (2022) (0)
- Spectroelectrochemistry: The Best of Two Worlds (2010) (0)
- Synthesis, Characterization and Structure of Tribromo(2-phenyl- (2011) (0)
- 2‐Heteroatom‐1,3‐diazoles and Quinoxaline as Bridging π Acceptor Ligands for Metal Fragments M(CO)5 (M: Cr, Mo, W). Synthesis, Electrochemistry, Absorption and Emission Spectroscopy. (1989) (0)
- RADICAL IONS. 9. RADICAL CATIONS OF TETRASILYL-SUBSTITUTED HYDRAZINES (1977) (0)
- Boron Atoms as Spin Carriers in Two‐ and Three‐Dimensional Systems (2009) (0)
- Hans Bock (1928–2008) (2008) (0)
- RADICAL IONS. XXX. REDUCTION OF R3SIO SUBSTITUTED BENZENE DERIVATIVES (1980) (0)
- 1,4,7,10 - Tetraazacyclododecane Metal Complexes as Potent Promoters of Phosphodiester Hydrolysis under Physiologica (2008) (0)
- Π-BACKBONDING AND STABILITY OF OXIDATION STEPS IN TETRACARBONYLDICYCLOPENTADIENYL(μ-PYRAZINE)DIMANGANESE(I) COMPLEXES (1984) (0)
- QuantUIl 1 chell 1 ical interpretation of redox properties of rutheniUIl 1 conlplexes with vinyl and TCNX type non-innocent ligands (2011) (0)
- N2·3‐: Filling a Gap in the Nn‐2 Series (2010) (0)
- AXIALLY COORDINATED TETRAKIS(N-2,6-DIMETHYPHENYL)LACETAMIDO)DIMOLYBDENUM(II) COMPOUNDS. STRUCTURES OF MO2((XYLYL)NC(CH3)O)4.L (L = NC5H4CH3) (1982) (0)
- Stabilization of Biochemically Relevant Intermediates by Metal Coordination. Part 2. 5,8-Bis(trimethylsilyl)-5,8-dihydropteridine and Its Deaza Derivatives. (1989) (0)
- Excellent yield of a variety of silicon-boron radicals and their reactivity. (2022) (0)
- Electron-Rich Olefins. Part 4. Electron-Rich Compounds with Thiophosphinamide, Carboxamide, O-Silylurethane, and O-Silylisourea Functionality. Synthesis, Spectroscopy, Chemical, and Electrochemical Reactivity. (1989) (0)
- An Acyclic Diaminocarbene Complex of Platinum Formed by Desulfurization of 1,3‐Bis(3‐methylpyridin‐2‐yl)thiourea (2021) (0)
- COORDINATION CHEMISTRY OF Π-ELECTRON DEFICIENT LIGANDS. BINUCLEAR TUNGSTEN PENTACARBONYL COMPLEXES OF THE WEAKLY BASIC 2,1,3-BENZOCHALCOGENADIAZOLES (1985) (0)
- ( L = 3-amino-6-( 3 , 5-dimethylpyrazol-1-yl )-1 , 2 , 4 , 5-tetrazine , acac = acetylacetonate , bpy = 2 , 2 0-bipyridine ) : syntheses , structures , spectra and redox properties (2005) (0)
- ((η5‐C5Me5)2Ti2P6), a Distorted Dimetallaphospha Cubane. (1988) (0)
- A FIRST STABLE ORGANOMETALLIC ANALOGUE (0)
- Advanced Inorganic Chemistry. 5. Auflage. Von F. A. Cotton und G. Wilkinson. Wiley, Chichester 1988. XVII, 1455 S., geb. $ 44.95. – ISBN 0‐471‐84997‐9 (1989) (0)
- Coordination Characteristics of Four Isomeric α-Diimine Ligands. (1986) (0)
- 3.8 Complexes of group 7 (Mn, Tc, Re) (2006) (0)
- Mixed Valency vs Radical Bridge Formulation in Symmetrically and Asymmetrically Ligated Diruthenium Complexes (2022) (0)
- CHEMISTRY OF BORON. C. RADICAL IONS. XXXI. NMR AND ESR SPECTROSCOPIC INVESTIGATIONS ON FIVE- AND SIX-MEMBERED BORON-NITROGEN HETEROCYCLES (1979) (0)
- RADICAL IONS. 45. RADICAL ANIONS OF DIMETHYLPHOSPHINO-SUBSTITUTED BENZENES (1981) (0)
- RADICAL IONS. XI. ONE-ELECTRON OXIDATION OF ALKYLSILYL BENZENES IN THE GAS PHASE AND IN SOLUTION (1977) (0)
- Book Review: Perspectives in Co‐ordination Chemistry. Edited by A. F. Williams, C. Floriani, and A. E. Merbach (1993) (0)
- Charge-Transfer-Assisted Polynucleation Reactions. A Trinuclear Carbonyltungsten Complex of Ambident 4,4′-Bipyrimidine. (1988) (0)
- LEWIS BASICITY OF A CHLORINE ATOM BOUND TO AN ALIPHATIC CARBON ATOM AS SENSED BY A QUADRUPLE CHROMIUM-CHROMIUM BOND. STRUCTURES OF M2((2,6-XYLYL)NC(CH3)O)4.2CH2CL2, M = CHROMIUM, MOLYBDENUM (1980) (0)
- Analysis of Multiple Redox Sites in Complexes [M(C 5 Me 5 )(Q)(NO)] n , M=Ru or Os, Q= o ‐Quinones (2021) (0)
- Redox Reactivity of Bis(1,4,7-triazacyclononane)iron(II/III) Complexes in Alkaline Solution and Characterization of a Deprotonated Species: Amidoiron(III) vs Aminyliron(II) Ground-State Formulation. EPR, Kinetics, Pulse Radiolysis, an (1988) (0)
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