Xi‐yan Lu
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Chemistry
Xi‐yan Lu's Degrees
- PhD Chemistry University of California, Berkeley
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(Suggest an Edit or Addition)Xi‐yan Lu's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Phosphine-Catalyzed Cycloaddition of 2,3-Butadienoates or 2-Butynoates with Electron-Deficient Olefins. A Novel [3 + 2] Annulation Approach to Cyclopentenes (1995) (444)
- A novel [3+2] cycloaddition approach to nitrogen heterocycles via phosphine-catalyzed reactions of 2,3-butadienoates or 2-butynoates and dimethyl acetylenedicarboxylate with imines : A convenient synthesis of pentabromopseudilin (1998) (249)
- Rhodium(III)-catalyzed redox-neutral coupling of N-phenoxyacetamides and alkynes with tunable selectivity. (2013) (243)
- Phosphine-catalyzed [3+2] cycloaddition reaction of methyl 2,3-butadienoate and N-tosylimines. A novel approach to nitrogen heterocycles (1997) (176)
- A catalytic carbon-phosphorus ylide reaction: phosphane-catalyzed annulation of allylic compounds with electron-deficient alkenes. (2003) (164)
- A phosphine-catalyzed [3+6] annulation reaction of modified allylic compounds and tropone. (2005) (139)
- Synthetic methodology using tertiary phosphines as nucleophilic catalysts (2005) (137)
- Rhodium(III)-catalyzed C-H olefination for the synthesis of ortho-alkenyl phenols using an oxidizing directing group. (2013) (135)
- A phosphine-catalyzed [3+2] cycloaddition strategy leading to the first total synthesis of (-)-hinesol. (2003) (133)
- A phosphine-catalyzed [3 + 2] annulation reaction of modified allylic compounds and N-tosylimines. (2008) (122)
- Cationic palladium(II)-catalyzed addition of arylboronic acids to nitriles. One-step synthesis of benzofurans from phenoxyacetonitriles. (2006) (121)
- Highly regioselective construction of spirocycles via phosphine-catalyzed [3 + 2]-cycloaddition. (2002) (117)
- Pd(II)-Bipyridine Catalyzed Conjugate Addition of Arylboronic Acid to α,β-Unsaturated Carbonyl Compounds (2005) (108)
- Phosphine-catalyzed [4 + 3] annulation for the synthesis of highly functionalized bicyclo[3.2.2]nonadienes. (2009) (104)
- A novel regio- and stereospecific hydrohalogenation reaction of 2-propynoic acid and its derivatives (1992) (102)
- PdII-catalyzed cyclization of alkynes containing aldehyde, ketone, or nitrile groups initiated by the acetoxypalladation of alkynes. (2002) (99)
- Tandem reactions to construct heterocycles via phosphine-catalyzed umpolung addition and intramolecular conjugate addition. (2002) (97)
- Highly Enantioselective Palladium(II)-Catalyzed Cyclization of (Z)-4‘-Acetoxy-2‘-butenyl 2-Alkynoates: An Efficient Synthesis of Optically Active γ-Butyrolactones (2000) (97)
- Alkaloids-catalyzed regio- and enantioselective allylic nucleophilic substitution of tert-butyl carbonate of the Morita–Baylis–Hillman products (2004) (96)
- Cationic palladium complex catalyzed highly enantioselective intramolecular addition of arylboronic acids to ketones. A convenient synthesis of optically active cycloalkanols. (2006) (95)
- Umpolung addition reaction of nucleophiles to 2,3- butadienoates catalyzed by a phosphine (1995) (93)
- Cationic Pd(II)/bipyridine-catalyzed conjugate addition of arylboronic acids to beta,beta-disubstituted enones: construction of quaternary carbon centers. (2010) (91)
- A highly regio- and stereo-selective [3+2] annulation of allylic compounds and 2-substituted 1,1-dicyanoalkenes through a catalytic carbon–phosphorus ylide reaction (2007) (88)
- A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium (2004) (88)
- Cationic Pd(II)/bipyridine-catalyzed addition of arylboronic acids to arylaldehydes. One-pot synthesis of unsymmetrical triarylmethanes. (2007) (87)
- Role of Halide Ions in Divalent Palladium-Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon−Palladium Bond (2001) (86)
- Phosphine-catalyzed [3+2] cycloaddition reactions of substituted 2-alkynoates or 2,3-allenoates with electron-deficient olefins and imines (1999) (86)
- An unexpected phosphine-catalyzed [3 + 2] annulation. Synthesis of highly functionalized cyclopentenes. (2008) (84)
- Highly efficient construction of benzene ring in carbazoles by palladium-catalyzed endo-mode oxidative cyclization of 3-(3'-alkenyl)indoles. (2006) (83)
- Palladium(II)-catalyzed addition of arylboronic acid to nitriles (2006) (77)
- Palladium(II)-catalyzed enyne coupling reaction initiated by acetoxypalladation of alkynes and quenched by protonolysis of the carbon-palladium bond. (2005) (76)
- Diastereoselective synthesis of arylglycine derivatives by cationic palladium(II)-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters. (2007) (73)
- Stereoselective synthesis of .alpha.-chloromethylene-.gamma.-butyrolactone derivatives from acyclic allylic 2-alkynoates (1993) (71)
- Divalent palladium catalyzed stereoselective synthesis of (1991) (71)
- Pd(II)-catalyzed one-step construction of cycloalkane-fused indoles and its application in formal synthesis of (±)-aspidospermidine. (2014) (70)
- Control of the β-Hydride Elimination Making Palladium-Catalyzed Coupling Reactions more Diversified (2005) (70)
- Effect of Halide Ligands on the Reactivity of Carbon−Palladium Bonds: Implications for Designing Catalytic Reactions (2000) (70)
- Phosphine-catalyzed [3+3] annulation reaction of modified tert-butyl allylic carbonates and substituted alkylidenemalononitriles (2009) (66)
- Palladium(II)-catalyzed synthesis of functionalized indenes from o-alkynylbenzylidene ketones. (2011) (66)
- Phosphine-catalyzed one-pot synthesis of cyclopentenes from electron-deficient allene, malononitrile and aromatic aldehydes (2006) (65)
- Regiocontrolled Coupling of Aromatic and Vinylic Amides with α-Allenols To Form γ-Lactams via Rhodium(III)-Catalyzed C-H Activation. (2016) (63)
- Reactivity and stereocheemistry of β-Heteroatom elimination. A detailed study through a palladium-catalyzed cyclization reaction model (1995) (62)
- Cationic Pd(II)-catalyzed enantioselective cyclization of aroylmethyl 2-alkynoates initiated by carbopalladation of alkynes with arylboronic acids. (2007) (62)
- Palladium(II)-Catalyzed Asymmetric Synthesis of (Z)-α-Alkylidene-γ-butyrolactams from (Z)-N-Allylic 2-Alkynamides. Total Synthesis of (−)-Isocynometrine (2006) (61)
- Iridium pentahydride complex catalyzed dehydrogenation of alcohols in the absence of a hydrogen acceptor (1987) (60)
- Palladium(II)-Catalyzed Three-Component Coupling Reaction Initiated by Acetoxypalladation of Alkynes: An Efficient Route to γ,δ-Unsaturated Carbonyls (2002) (59)
- Cationic Pd(II)-catalyzed tandem reaction of 2-arylethynylanilines and aldehydes: an efficient synthesis of substituted 3-hydroxymethyl indoles. (2010) (58)
- A Palladium(II)-Catalyzed Construction of .alpha.-Methylene-.gamma.-butyrolactones in Optically Active Form. Total Synthesis of (-)-Methylenolactocin (1995) (57)
- Palladium(II)-catalyzed tandem intramolecular aminopalladation of alkynylanilines and conjugate addition for synthesis of 2,3-disubstituted indole derivatives (2006) (56)
- Palladium-catalyzed allylic alkylation of carbonucleophiles witl allylic borates or allylic alcohols and boron oxide under neutral conditions (1988) (56)
- Reinvestigation on the catalytic isomerisation of carbon–carbon triple bonds (1993) (55)
- Cascade Synthesis of 3-Alkylidene Dihydrobenzofuran Derivatives via Rhodium(III)-Catalyzed Redox-Neutral C-H Functionalization/Cyclization. (2015) (53)
- Control of chemoselectivity by counteranions of cationic palladium complexes: a convenient enantioselective synthesis of dihydrocoumarins. (2010) (52)
- Highly stereoselective isomerization of ynones to conjugated dienones catalyzed by transition metal complexes (1989) (50)
- Synthesis of indoles via palladium-catalyzed C–H activation of N-aryl amides followed by coupling with alkynes (2011) (49)
- Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis. (2005) (49)
- Cationic palladium(II)-catalyzed highly enantioselective [3+2] annulation of 2-acylarylboronic acids with substituted alkynes. (2007) (48)
- A novel stereoselective synthesis of conjugated dienones (1988) (47)
- Rhodium(III)‐Catalyzed Redox‐Neutral CH Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives (2015) (47)
- Palladium(II)/2,2′-bipyridine-catalyzed addition of arylboronic acids to N-tosyl-arylaldimines (2009) (47)
- Enantioselective Synthesis of Tetrahydropyrano[3,4-b]indoles: Palladium(II)-Catalyzed Aminopalladation/1,4-Addition Sequence. (2017) (46)
- Cationic palladium(II)-catalyzed highly enantioselective tandem reactions of ortho-boronate-substituted cinnamic ketones and internal alkynes: a convenient synthesis of optically active indenes. (2009) (46)
- Palladium and arsenic (III) oxide-catalyzed allylic alkylation by allylic alcohols under neutral conditions (1987) (45)
- Novel palladium-catalyzed acyloxylation/cyclization of 2-(3'-alkenyl)indoles. (2009) (45)
- Palladium(II)-Catalyzed Synthesis of α-Alkylidene-γ-butyrolactams from N-Allylic 2-Alkynamides. Total Synthesis of (±)-Isocynodine and (±)-Isocynometrine (2001) (43)
- Palladium(II)‐Catalyzed One‐Pot Enantioselective Synthesis of Arylglycine Derivatives from Ethyl Glyoxylate, p‐Toluenesulfonyl Isocyanate and Arylboronic Acids (2008) (43)
- Cupric Halide-Mediated Intramolecular Halocyclization of N-Electron-Withdrawing Group-Substituted 2-Alkynylanilines for the Synthesis of 3-Haloindoles (2009) (41)
- Palladium-Templated Regio- and Stereoselective Cyclization of 2'-Alkenyl 2-Alkynoates and Its Synthetic Applications (1995) (41)
- Isomerization of propargylic alcohols catalyzed by an iridium complex (1989) (40)
- Cationic palladium complex catalyzed diastereo- and enantioselective tandem annulation of 2-formylarylboronic acids with allenoates. (2009) (40)
- Synthesis of benzofurans via ruthenium-catalyzed redox-neutral C–H functionalization and reaction with alkynes under mild conditions (2014) (39)
- Efficient Preparation of Functionalized (E,Z) Dienes Using Acetylene as the Building Block (1998) (37)
- Palladium(II)-catalyzed intramolecular addition of arylboronic acids to ketones (2008) (37)
- Samarium diiodide initiated addition reaction of fluoroalkyl iodides to olefins (1988) (37)
- Enyne Coupling as the Potent Methodology for the Synthesis of Bioactive Molecules (1998) (36)
- Palladium(II)-catalyzed highly regio- and diastereoselective cyclization of difunctional allylic N-tosylcarbamates. A convenient synthesis of optically active 4-vinyl-2-oxazolidinones and total synthesis of 1,4-dideoxy-1,4-imino-L-xylitol. (2002) (36)
- A facile highly regio-and stereoselelctive preparation of N-tosyl allylic amines from allylic alcohols and tosyl isocyanate via palladium(II)-catalyzed aminopalladation-β-heteroatom elimination (2000) (36)
- Cationic Palladium‐Catalyzed [5+2] Annulation: Synthesis of 1‐Benzoxepines from 2‐Aroylmethoxyarylboronic Acids (2007) (35)
- An organometallic analogue of the Wittig reaction. A one-pot reaction for CC bond formation catalyzed by a molybdenum complex (1989) (34)
- Palladium(II)-catalyzed tandem annulation reaction of o-alkynylbenzoates with methyl vinyl ketone for the synthesis of isocoumarins (2013) (34)
- A novel deoxygenation–isomerization reaction of 4-hydroxy-2-ynoic esters and γ-hydroxy-α,β-ynones (1993) (34)
- Cationic Pd(II)-catalyzed highly enantioselective arylative cyclization of alkyne-tethered enals or enones initiated by carbopalladation of alkynes with arylboronic acids. (2012) (34)
- Palladium catalyzed annulation reaction using a bifunctional allylic alkylating agent (1988) (34)
- A novel stereospecific hydrohalogenation reaction of propiolates and propiolic acid (1990) (33)
- Controlling factors on the stereochemistry of palladium(II)-catalyzed cyclization of 1'-alkyl-4'-chloro-2'-alkenyl 2-alkynoates (1993) (33)
- Studies on samarium diiodide initiated addition reaction of fluoroalkyl iodides to alkynes and its mechanism (1990) (33)
- Palladium–bipyridine catalyzed conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds in aqueous media (2006) (32)
- A convenient stereoselective synthesis of conjugated (2Z)- EN-4-Ynoic and (2Z,4Z)-and (2Z,4E)-dienoic acid derivatives from propiolic acid derivatives (1992) (32)
- Selective ene-yne coupling-Functionalization: A new strategy in constructing heterocycles (1995) (31)
- Efficient Synthesis of 9‐Tosylaminofluorene Derivatives by Boron Trifluoride Etherate‐Catalyzed Aza‐Friedel–Crafts Reaction of in situ Generated N‐Tosylbenzaldimines (2011) (30)
- Palladium-catalyzed intramolecular alkyne-α,β-unsaturated carbonyl coupling. A formal synthesis of (+)-pilocarpine (1997) (30)
- A novel regio- and stereo-specific hydroacetoxylation reaction of 2-alkynoic acid derivatives (1992) (29)
- Palladium-Catalyzed Reaction of Aryl Polyfluoroalkanesulfonates with O,O-Dialkyl Phosphonates (1987) (29)
- Efficient synthesis of heterocyle-fused β-naphthylamines via intramolecular addition to a cyano group initiated by nucleopalladation of alkynes. (2014) (29)
- A simple route to α,β-unsaturated aldehydes from prop-2-ynols (1989) (28)
- Synthesis of Cyclohexane-Fused Isocoumarins via Cationic Palladium(II)-Catalyzed Cascade Cyclization Reaction of Alkyne-Tethered Carbonyl Compounds Initiated by Intramolecular Oxypalladation of Ester-Substituted Aryl Alkynes. (2016) (28)
- Umpolung in allylic phosphonates. Regioselective reaction of acetoxy allylic phosphonates with nucleophiles catalyzed by palladium(0) complex (1987) (28)
- The use of iminopyridines as efficient ligands in the palladium(II)-catalyzed cyclization of (Z)-4′-acetoxy-2′-butenyl 2-alkynoates (2007) (27)
- Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2′-ynyl- oxy)benzonitriles or 2-(Alk-2′-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-Dihydroquinoline Derivatives (2012) (27)
- Cationic Pd(II)-Catalyzed Cyclization of N-Tosyl-aniline Tethered Allenyl Aldehydes with Arylboronic Acids: Diastereo- and Enantioselective Synthesis of Tetrahydroquinoline Derivatives. (2015) (27)
- Atom-Economic Synthesis of Pentaleno[2,1-b]indoles via Tandem Cyclization of Alkynones Initiated by Aminopalladation. (2017) (26)
- Palladium(II)-catalyzed coupling of allenoic acids and α,β-unsaturated carbonyl compounds through tandem intramolecular oxypalladation and conjugate addition reactions (2003) (25)
- Cationic Pd(II)-catalyzed reductive cyclization of alkyne-tethered ketones or aldehydes using ethanol as hydrogen source. (2013) (24)
- Molecular oxygen promoted oxidative cleavage of carbon-palladium bonds — catalytic cyclization of allylic 2-alkynoates to α-alkylidine-γ-butyrolactones by a PdII complex (1996) (24)
- Cationic palladium-catalyzed [5 + 2] annulation of 2-acylmethoxyarylboronic acids and allenoates: synthesis of 1-benzoxepine derivatives. (2011) (24)
- A new methodology to key intermediates for synthesizing polyene compounds (1990) (24)
- Studies on [PdH]- and [PdCl]-Catalyzed Intramolecular Cyclization: The Search for a Better Solution to Selective Enyne Coupling (1996) (23)
- Pd(II)-catalyzed annulation of N-benzyl-N-aroylmethyl-2-alkynamides with arylboronic acids: an efficient synthesis of highly substituted α-alkylidene-β-hydroxy-γ-lactams (2010) (23)
- Structural factors affecting the selectivities in the palladium (II) catalyzed cyclization of N-alkenyl-2-alkynamides (1996) (23)
- Synthesis of Indole-Substituted Indanones via Palladium(II)-Catalyzed Tandem Reaction of ortho-Electron-Deficient Alkynyl-Substituted Aryl Aldehydes with Indoles. (2016) (22)
- Unexpected results in the reaction of active methylene compounds with phenylsulfonyl-1,2-propadiene triggered by triphenylphosphine (2004) (22)
- Differentiation of the reactivities of carbon-carbon multiple bonds in one molecule. Highly chemo- and stereo-selective hydrohalogenation of allyl or propargyl propiolates (1990) (21)
- A palladium-catalyzed construction of enantiomerically pure α-methylene-γ-butyrolactones. Enantiospecific synthesis of both enantiomers of methylenolactocin (1995) (20)
- Catalytic tandem addition route to γ,δ-unsaturated carbonyls (1996) (20)
- Observations on the unusual stereochemistry of the oxidative cleavage of palladium–carbon bonds (1995) (20)
- Palladium(II)-catalyzed coupling reactions of alkynes and allylic compounds initiated by intramolecular carbopalladation of alkynes (2002) (20)
- Facile synthesis of 2,5-disubstituted furans via palladium complex and perfluorinated resinsulfonic acid catalysed isomerization–dehydration of alkynediols (1993) (20)
- Palladium(0)-catalyzed tandem cyclization of N-(2′,4′-dienyl)alkynamides to α-alkylidene-γ-lactams (1999) (20)
- Palladium-catalyzed reaction of nucleophiles with diacetates of allylic 1,1-diols (1984) (20)
- One-pot synthesis of tetrahydrofuran derivatives via a divalent palladium-catalyzed three-component coupling (2003) (19)
- A convenient stereoselective synthesis of fluorinated α-alkylidene-γ-butyrolactone derivatives (1994) (19)
- Facile Cu(OTf)2-catalyzed preparation of 9-tosylaminofluorene derivatives from o-arylated N-tosylbenzaldimines (2011) (18)
- Nickel chlorides catalyzed rearrangement of allylic phosphites (1986) (18)
- Pd(OAc)2‐Catalyzed Tandem Reactions for the Synthesis of Indol‐3‐yl Substituted 1H‐Isochromenes and 1,2‐Dihydroisoquinolines (2011) (18)
- Palladium(II)-catalyzed oxidative annulation of alkenylindoles with alkynes initiated by C–H activation (2014) (17)
- Palladium-catalyzed synthesis of allylic and benzylic sulfides from the corresponding dithiocarbonates (1987) (16)
- Facile synthesis of (2E,4E)-dienoic esters via stereoselective isomerization of 2-ynoic esters (1989) (16)
- Novel palladium catalayzed synthesis of pyran derivatives (1987) (16)
- A convenient synthesis of 3-iodohomoallylic alcohols and the further transformation to α,β-unsaturated γ-lactones (1997) (16)
- Palladium catalyzed cyclization-carbonylation of allylic 2-alkynoates: Facile synthesis of α-alkylidene-γ-butyrolactone β-acetic acid derivatives (1994) (16)
- A Convenient Stereoselective Synthesis of 1,3-Dienylphosphonates and 1-En-3-ynylphosphonates and Their Phosphine Oxide Analogs (1995) (16)
- Cationic Pd(II)-catalyzed arylative cyclization of N-(2-formylaryl)alkynamides: An efficient route to 2-quinolinones (2017) (15)
- Umpolung in allylic phosphonates. Regio- and stereo-selective synthesis of (E)-γ-amino-α,β-unsaturated phosphonates by palladium-catalysed reaction of allylic acetoxy phosphonates (1987) (15)
- Cationic Palladium Complex‐Catalyzed Diastereoselective Tandem Annulation of 2‐Iminoarylboronic Acids with Substituted Alkynes: Enantioselective Synthesis of Aminoindene Derivatives by Double Asymmetric Induction (2011) (15)
- Nickel(0)-catalyzed Reaction of O,O-Dialkyl Phosphonates with Allyl Acetates or Carbonates. A Novel Method of Preparing Allyl Phosphonates (1986) (15)
- Prop-2-ynylic carbonates as a1,a2 synthons in palladium catalysed annulation reactions with bifunctional nucleophiles (1992) (14)
- Stereoselective synthesis of perfluoroalkylated (E,E)-dienes from perfluoroalkylated alkynes. the synthesis of fluorinated analogs of lepidoptera pheromones (1995) (14)
- Stereoselective synthesis of conjugated polyenones from diynones (1991) (14)
- Highly enantioselective hydrogenation of exocyclic double bond of N-tosyloxazolidinones catalyzed by a neutral rhodium complex and its synthetic applications (2006) (14)
- Synthesis of 2-Quinolinones through Palladium(II) Acetate Catalyzed Cyclization of N-(2-Formylaryl)alkynamides (2015) (14)
- Palladium(II)-Catalyzed Redox-Neutral Cyclizations of Alkynes Containing Alkenyl or Electrophilic Functional Groups: A Convenient Synthesis of Carbocycles and Heterocycles (2018) (13)
- Construction of α-alkylidene-γ-butyrolactones from acyclic ester precursors (1994) (13)
- Allylic carbon-phosphorus bond formation catalyzed by nickel complexes (1987) (13)
- Novel reactions catalyzed by iridium pentahydride complex (1988) (12)
- A new three-carbon homologating agent for synthesis of α- keto aldehydes (1991) (12)
- Palladium(II)-Catalyzed Asymmetric Tandem Cyclization of 2-Aminoaryl Alkynones: An Approach to Chiral 1,2,3,4-Tetrahydro-β-carbolines. (2018) (12)
- Allylic geminal diacetates as a a1,a3 synthon. A convenient synthesis of bicyclo[3.3.1]nonan-9-one derivatives (1986) (12)
- A facile and stereoselective synthesis of dienediones and 6-oxo-2,4-dienoic esters (1992) (11)
- Effect of ligands on the divalent palladium- catalyzed carbon-carbon coupling reactions. Highly enantioselective synthesis of optically active g-butyrolactones (2001) (11)
- Selective cconversion of pinane into β-pinene catalyzed by an iridium pentahydride complex (1987) (11)
- Hydrogen transfer reaction of allylic alcohols catalyzed by a molybdenum complex (1983) (10)
- Total synthesis of both enantiomers of melodorinol. Redetermination of their absolute configurations. (1997) (10)
- Convenient and Stereoselective Synthesis of (E,E,E)-Trienones (1992) (10)
- Palladium(II)-Catalyzed Reductive Cyclization of N-Tosyl-Tethered 1,7-Enynes: Enantioselective Synthesis of 1,2,3,4-Tetrahydroquinolines. (2019) (9)
- Umpolung reactivity of allylic phosphonates. A simple route to 3‐aminoalkane‐ and 3‐amino‐1‐alkenylphosphonates (phosphinates and phosphine oxides) (1992) (9)
- Template effect of Pd(II) in the synthesis of differently substituted enantiopure γ-butyrolactones and its synthetic applications (1995) (9)
- Stereoselective synthesis of cis-fused bicyclic α -(Z)-chloroalkylidene-γ-butyrolactone derivatives via the cascade carbopalladation cyclization reaction (1993) (9)
- A novel regio‐ and stereo‐specific hydrohalogenation reaction of 2‐alkynoic acids and their derivatives (2010) (9)
- Role of halide ions in palladium(II) catalyzed nucleophile alkyne-α,β-unsaturated carbonyl coupling reactions (2000) (8)
- Regio- and Stereoselective Synthesis of Symmetrical and Unsymmetrical 1,3-Diphosphoryl(Phosphonyl, Phosphinyl) Substituted (E)-Propenes (1989) (8)
- Effective activation of allylic etherrs by boron oxide in palladium catalyzed allylic alkylation (1989) (8)
- Reaction of allylic arsenites with low valent transition metal complexes (1986) (8)
- Palladium(0) catalyzed reactions of propargylic carbonates and dialkyl cycloalkanone‐α,α‐dicarboxylates (2010) (8)
- Palladium dihalide catalysed stereoselective synthesis of α-(Z)-halomethylene-γ-butyrolactone derivatives (1990) (8)
- An Efficient Synthesis of (±)-Isohinokinin from the Acyclic Ester Precursor (1993) (7)
- Samarium di-iodide initiated addition of polyhalogenomethanes to olefins (1990) (7)
- Palladium-catalyzed reduction of acyl chlorides with tributylgermanium hydride (1989) (7)
- Cationic Pd(II)-catalyzed arylative cyclization of 1,6-enynes with arylboronic acids (2017) (7)
- PALLADIUM(0) CATALYZED ISOMERIZATION OF ALKYNYLDIETHYL PHOSPHONATE AND ALKYNYLDIPHENYL PHOSPHINE OXIDE (1995) (6)
- Cationic Pd( ii )-catalyzed cyclization of N -tosyl-aniline tethered alkynyl ketones initiated by hydropalladation of alkynes: a facile way to 1,2-dihydro or 1,2,3,4-tetrahydroquinoline derivatives (2015) (6)
- An efficient diastereoselective synthesis of chiral ferrocenyl aldehydes (1998) (5)
- Stereoselective synthesis of enantiopure β, γ-disubstituted α-alkylideneγ-butyrolactones via A palladium(II) catalyzed cyclization (1995) (5)
- A Convenient Synthesis of 3-(1,3-Alkadienyl)-2-cycloalken-1-ones (1990) (5)
- Novel synthesis of 3-chloromethylidene-2-ethoxy-1,2λ5-oxaphospholan-2-ones catalysed by palladium(II) (1995) (5)
- Studies on The Reaction of CIS-MoO2(S2CNEt2)2 with Compounds of Group V Elements (1982) (4)
- Enantioselective Synthesis of Tetrahydropyrano[3,4‐b]indoles: Palladium(II)‐Catalyzed Aminopalladation/1,4‐Addition Sequence (2017) (4)
- Role of Halide Ions in Divalent Palladium‐Mediated Reactions: Competition Between β‐Heteroatom Elimination and β‐Hydride Elimination of a Carbon—Palladium Bond. (2001) (4)
- Cationic Palladium(II)-CatalyzedSynthesis of 2-Substituted 3-Hydroxymethylbenzo[b]furans (2011) (3)
- Palladium—Bipyridine Catalyzed Conjugate Addition of Arylboronic Acids to α,β‐Unsaturated Carbonyl Compounds in Aqueous Media. (2007) (3)
- Stereospecific Synthesis of Ethyl (Z)-3-Bromo-2-Propenoate (2003) (3)
- Synthesis of Substituted Piperidines via Cationic Palladium(II)-Catalyzed Reductive Coupling of N-Tosyl-Tethered Alkynones (2017) (3)
- Rhodium(III)‐Catalyzed Redox‐Neutral Coupling of N‐Phenoxyacetamides and Alkynes with Tunable Selectivity. (2013) (3)
- A Catalytic Carbon—Phosphorus Ylide Reaction: Phosphane‐Catalyzed Annulation of Allylic Compounds with Electron‐Deficient Alkenes. (2003) (2)
- Palladium‐Catalyzed Reaction via Halopalladation of π‐Compounds (2003) (2)
- Cationic Pd(II)/Bipyridine‐Catalyzed Conjugate Addition of Arylboronic Acids to β,β‐Disubstituted Enones: Construction of Quaternary Carbon Centers. (2010) (2)
- Rhodium(III)-Catalyzed C—H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group. (2013) (2)
- A Novel Regio- and Stereospecific Hydrohalogenation Reaction of 2- Propynoic Acid and Its Derivatives. (1992) (2)
- Palladium‐Catalyzed Allylic Alkylation of Carbonucleophiles with Allylic Borates or Allylic Alcohols and Boron Oxide Under Neutral Conditions. (1988) (1)
- Highly Stereoselective Isomerization of Ynones to Conjugated Dienones Catalyzed by Transition-Metal Complexes. (1989) (1)
- An Unexpected Reaction of Allylic Propynoate under Palladium(II) Catalysis (2010) (1)
- Phosphine-Catalyzed (3 + 2) Cycloaddition Reaction of Methyl 2,3- Butadienoate and N-Tosylimines. A Novel Approach to Nitrogen Heterocycles. (1997) (1)
- Novel methods for the deoxygenation of triphenylarsine oxide to triphenylarsine (1985) (1)
- Novel Palladium‐Catalyzed Acyloxylation/Cyclization of 2‐(3′‐Alkenyl)indoles. (2009) (1)
- Phosphine-Catalyzed Cycloaddition of 2,3-Butadienoates or 2-Butynoates with Electron-Deficient Olefins. A Novel (3 + 2) Annulation Approach to Cyclopentenes. (1995) (1)
- Iridium Pentahydride Complex Catalyzed Dehydrogenation of Alcohols in the Absence of a Hydrogen Acceptor. (1987) (1)
- A Novel Highly Regio‐ and Diastereoselective Haloamination of Alkenes Catalyzed by Divalent Palladium. (2004) (1)
- Pd(II)-Catalyzed Annulation of N-Benzyl-N-aroylmethyl-2-alkynamides with Arylboronic Acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-β-hydroxy-γ-lactams. (2011) (1)
- Cationic Pd(II)/Bipyridine‐Catalyzed Addition of Arylboronic Acids to Arylaldehydes. One‐Pot Synthesis of Unsymmetrical Triarylmethanes. (2008) (1)
- Rhodium(III)‐Catalyzed Redox‐Neutral C—H Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives. (2016) (1)
- Umpolung Addition Reaction of Nucleophiles to 2,3-Butadienoates Catalyzed by a Phosphine. (1995) (1)
- Palladium(II)-Catalyzed Redox-Neutral Cyclizations of Alkynes Containing Alkenyl or Electrophilic Functional Groups: A Convenient Synthesis of Carbocycles and Heterocycles (2018) (0)
- Palladium-Catalyzed Reaction of Aryl Polyfluoroalkanesulfonates with O,O-Dialkyl Phosphonates. (1988) (0)
- One‐Pot Synthesis of Tetrahydrofuran Derivatives via a Divalent Palladium‐Catalyzed Three‐Component Coupling. (2003) (0)
- Palladium(II)-catalyzed tandem cyclization of 2-ethynylaniline tethered cinnamyl acetate for the synthesis of indenoindoles. (2020) (0)
- A Simple Route to α,β‐Unsaturated Aldehydes from Prop‐2‐ynols. (1989) (0)
- Observations on the Unusual Stereochemistry of the Oxidative Cleavage of Palladium‐Carbon Bonds. (1995) (0)
- Highly Regioselective Construction of Spirocycles via Phosphine‐Catalyzed [3 + 2]‐Cycloaddition. (2003) (0)
- Palladium‐Templated Regio‐ and Stereoselective Cyclization of 2′‐ Alkenyl 2‐Alkynoates and Its Synthetic Applications. (1995) (0)
- Alkaloids‐Catalyzed Regio‐ and Enantioselective Allylic Nucleophilic Substitution of tert‐Butyl Carbonate of the Morita—Baylis—Hillman Products. (2004) (0)
- Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis (2001) (0)
- Selective Ene-Yne Coupling-Functionalization: A New Strategy in Constructing Heterocycles. (1995) (0)
- Palladium(II)‐Catalyzed Highly Regio‐ and Diastereoselective Cyclization of Difunctional Allylic N‐Tosylcarbamates. A Convenient Synthesis of Optically Active 4‐Vinyl‐2‐oxazolidinones and Total Synthesis of 1,4‐Dideoxy‐1,4‐imino‐L‐xylitol (XVI). (2002) (0)
- Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzed endo-Mode Oxidative Cyclization of 3-(3′-Alkenyl)indoles. (2006) (0)
- An Efficient Preparation of α-Alkylidene-β-formylmethyl-γ-lactams via Pd(II)-Catalyzed Intramolecular Alkyne-α,β-unsaturated Carbonyl Coupling. (2000) (0)
- Pd(II)-Catalyzed One-Step Construction of Cycloalkane-Fused Indoles and Its Application in Formal Synthesis of (.+-.)-Aspidospermidine (XIII). (2014) (0)
- Cycloisomerization of 1,6‐Enynes Using Acetate as a Nucleophile under Palladium(II) Catalysis. (2005) (0)
- A Convenient Synthesis of 3-Iodohomoallylic Alcohols and the Further Transformation to α,β-Unsaturated γ-Lactones. (1997) (0)
- Palladium(II)-Catalyzed Coupling of Allenoic Acids and α,β-Unsaturated Carbonyl Compounds Through Tandem Intramolecular Oxypalladation and Conjugate Addition Reactions. (2003) (0)
- Efficient Preparation of Functionalized (E,Z) Dienes Using Acetylene as the Building Block. (1998) (0)
- Palladium(II)‐Catalyzed Addition of Arylboronic Acid to Nitriles. (2007) (0)
- Studies on Samarium Diiodide Initiated Addition Reaction of Fluoroalkyl Iodides to Alkynes and Its Mechanism. (1990) (0)
- Palladium-Catalyzed Annulation Reaction Using a Bifunctional Allylic Alkylating Agent. (1989) (0)
- Pd(OAc)2-Catalyzed Tandem Reactions for the Synthesis of Indol-3-yl Substituted 1H-Isochromenes (III) and 1,2-Dihydroisoquinolines (V). (2012) (0)
- A Convenient Synthesis of γ-Z-Alkylidene Butenolides. (1994) (0)
- Allylic Geminal Diacetates as a a1,a3 Synthon. A Convenient Synthesis of Bicyclo[3.3.1]nonan-9-one Derivatives. (1986) (0)
- Palladium(II)/2,2′-bipyridine-Catalyzed Addition of Arylboronic Acids to N-Tosyl-Arylaldimines. (2009) (0)
- The Use of Iminopyridines as Efficient Ligands in the Palladium(II)-Catalyzed Cyclization of (Z)-4′-Acetoxy-2′-butenyl 2-Alkynoates. (2007) (0)
- Cupric Halide Mediated Intramolecular Halocyclization of N-Electron-Withdrawing Group-Substituted 2-Alkynylanilines for the Synthesis of 3-Haloindoles. (2010) (0)
- Phosphine‐Catalyzed [3 + 3] Annulation Reaction of Modified tert‐Butyl Allylic Carbonates and Substituted Alkylidenemalononitriles. (2009) (0)
- Cationic Palladium-Catalyzed [5 + 2] Annulation: Synthesis of 1-Benzoxepines from 2-Aroylmethoxyarylboronic Acids. (2008) (0)
- Convenient and Stereoselective Synthesis of E,E,E-Trienones. (1992) (0)
- Palladium(II)-Catalyzed Coupling Reactions of Alkynes and Allylic Compounds Initiated by Intramolecular Carbopalladation of Alkynes. (2002) (0)
- A Novel Stereospecific Hydrohalogenation Reaction of Propiolates and Propiolic Acid. (1991) (0)
- A Highly Regio- and Stereo-Selective [3 + 2] Annulation of Allylic Compounds and 2-Substituted 1,1-Dicyanoalkenes Through a Catalytic Carbon—Phosphorus Ylide Reaction. (2007) (0)
- Palladium(0)-Catalyzed Tandem Cyclization of N-(2′,4′-Dienyl)alkynamides to α-Alkylidene-γ-lactams. (2000) (0)
- A Convenient Stereoselective Synthesis of Conjugated 2Z-En-4-ynoic and 2Z,4Z- and 2Z,4E-Dienoic Acid Derivatives from Propiolic Acid Derivatives. (1992) (0)
- An Organometallic Analogue of the Wittig Reaction. A One-Pot Reaction for C=C Bond Formation Catalyzed by a Molybdenum Complex. (1990) (0)
- Facile Cu(OTf)2‐Catalyzed Preparation of 9‐Tosylaminofluorene Derivatives from o‐Arylated N‐Tosylbenzaldimines. (2011) (0)
- A Novel Stereoselective Synthesis of Conjugated Dienones. (1988) (0)
- Palladium(II)‐Catalyzed Tandem Annulation Reaction of o‐Alkynylbenzoates with Methyl Vinyl Ketone for the Synthesis of Isocoumarins. (2014) (0)
- Synthesis of Indole‐Substituted Indanones via Palladium(II)‐Catalyzed Tandem Reaction of ortho‐Electron‐Deficient Alkynyl‐Substituted Aryl Aldehydes with Indoles. (2016) (0)
- Palladium(II)‐Catalyzed Synthesis of Functionalized Indenes from o‐Alkynylbenzylidene Ketones. (2011) (0)
- Synthesis of Indoles via Palladium-Catalyzed C—H Activation of N-Aryl Amides Followed by Coupling with Alkynes. (2011) (0)
- A Convenient Synthesis of 3-(1,3-Alkadienyl)-2-cycloalken-1-ones. (1990) (0)
- Cationic Palladium-Catalyzed [5 + 2] Annulation of 2-Acylmethoxyboronic Acids and Allenoates: Synthesis of 1-Benzoxepine Derivatives. (2011) (0)
- Palladium(II)-catalyzed three-component coupling reaction initiated by acetoxypalladation of alkynes: an efficient route to gamma,delta-unsaturated carbonyls. (2002) (0)
- Cationic Palladium(II)‐Catalyzed Synthesis of 2‐Substituted 3‐Hydroxymethylbenzo[b]furans. (2012) (0)
- Palladium-Catalyzed Cyclization-Carbonylation of Allylic 2-Alkynoates: Facile Synthesis of α-Alkylidene-γ-butyrolactone β- Acetic Acid Derivatives. (2010) (0)
- A Palladium Catalyzed Construction of Enantiomerically Pure α- Methylene-γ-butyrolactones. Enantiospecific Synthesis of Both Enantiomers of Methylenolactocin. (1995) (0)
- Palladium(II)-catalyzed asymmetric synthesis of (Z)-alpha-alkylidene-gamma-butyrolactams from (Z)-N-allylic 2-Alkynamides. Total synthesis of (-)-isocynometrine. (2006) (0)
- Pd(II)-bipyridine catalyzed conjugate addition of arylboronic acid to alpha,beta-unsaturated carbonyl compounds. (2005) (0)
- Umpolung in Allylic Phosphonates. Regioselective Reaction of Acetoxy Allylic Phosphonates with Nucleophiles Catalyzed by Palladium(0) Complex. (1987) (0)
- Intramolecular 1,2‐Addition and 1,4‐Addition Reactions (2010) (0)
- Palladium(II)‐Catalyzed Asymmetric Synthesis of (Z)‐α‐Alkylidene‐γ‐butyrolactams from (Z)‐N‐Allylic 2‐Alkynamides. Total Synthesis of (‐)‐Isocynometrine. (2006) (0)
- Palladium(II)-Catalyzed Tandem Intramolecular Aminopalladation of Alkynylanilines and Conjugate Addition for Synthesis of 2,3-Disubstituted Indole Derivatives (III). (2007) (0)
- Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4′-Acetoxy-2′-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions. (2002) (0)
- Cascade Synthesis of 3-Alkylidene Dihydrobenzofuran Derivatives via Rhodium(III)-Catalyzed Redox-Neutral C—H Functionalization/Cyclization. (2016) (0)
- Highly Enantioselective Hydrogenation of Exocyclic Double Bond of N-Tosyloxazolidinones Catalyzed by a Neutral Rhodium Complex and Its Synthetic Applications. (2007) (0)
- A Phosphine-Catalyzed [3 + 2] Cycloaddition Strategy Leading to the First Total Synthesis of (-)-Hinesol (I). (2003) (0)
- Palladium(II)‐Catalyzed One‐Pot Enantioselective Synthesis of Arylglycine Derivatives from Ethyl Glyoxylate, p‐Toluenesulfonyl Isocyanate and Arylboronic Acids. (2008) (0)
- Template Effect of Pd(II) in the Synthesis of Differently Substituted Enantiopure γ‐Butyrolactones and Its Synthetic Applications. (1996) (0)
- Efficient Synthesis of 9-Tosylaminofluorene Derivatives by Boron Trifluoride Etherate-Catalyzed Aza-Friedel—Crafts Reaction of in situ Generated N-Tosylbenzaldimines. (2011) (0)
- Regio- and Stereoselective Synthesis of Symmetrical and Unsymmetrical 1,3-Diphosphoryl(Phosphonyl, Phosphinyl)-Substituted E-Propenes. (1990) (0)
- An Efficient Diastereoselective Synthesis of Chiral Ferrocenyl Aldehydes. (1999) (0)
- Efficient Synthesis of Heterocyle‐Fused β‐Naphthylamines via Intramolecular Addition to a Cyano Group Initiated by Nucleopalladation of Alkynes. (2015) (0)
- Cationic Pd(II)‐Catalyzed Cyclization of N‐Tosyl‐aniline Tethered Allenyl Aldehydes with Arylboronic Acids: Diastereo‐ and Enantioselective Synthesis of Tetrahydroquinoline Derivatives. (2015) (0)
- Palladium(II)‐Catalyzed Cyclization Reaction of 2‐(Alk‐2′‐ynyloxy)benzonitriles or 2‐(Alk‐2′‐ynylamino)benzonitriles: A Facile Way to 2H‐Chromene and 1,2‐Dihydroquinoline Derivatives. (2013) (0)
- Palladium(II)‐Catalyzed Oxidative Annulation of Alkenylindoles with Alkynes Initiated by C—H Activation. (2014) (0)
- Cationic Palladium(II)-Catalyzed Highly Enantioselective [3 + 2] Annulation of 2-Acylarylboronic Acids with Substituted Alkynes. (2008) (0)
- Palladium-Catalyzed Intramolecular Alkyne-α,β-Unsaturated Carbonyl Coupling. A Formal Synthesis of (+)-Pilocarpine. (1997) (0)
- Phosphine‐Catalyzed [3 + 2] Cycloaddition Reactions of Substituted 2‐Alkynoates or 2,3‐Allenoates with Electron‐Deficient Olefins and Imines. (1999) (0)
- A Convenient Stereoselective Synthesis of Fluorinated α‐ Alkylidene‐γ‐butyrolactone Derivatives. (1994) (0)
- Palladium-Catalyzed Reduction of Acyl Chlorides with Tributylgermanium Hydride. (1990) (0)
- Diastereoselective Synthesis of Arylglycine Derivatives by Cationic Palladium(II)‐Catalyzed Addition of Arylboronic Acids to N‐tert‐Butanesulfinyl Imino Esters. (2007) (0)
- Stereospecific Hydrohalogenation Reactions of Electron‐Deficient Alkynes (1999) (0)
- Cationic Pd(II)‐Catalyzed Reductive Cyclization of Alkyne‐Tethered Ketones or Aldehydes Using Ethanol as Hydrogen Source. (2013) (0)
- Brief Analysis on Profits Allocation of IOT Industry Chain (2011) (0)
- Palladium(II)‐Catalyzed Intramolecular Addition of Arylboronic Acids to Ketones. (2008) (0)
- Stereoselective Synthesis of Conjugated Polyenones from Diynones. (1992) (0)
- Stereoselective Synthesis of cis-Fused Bicyclic α-(Z)- Chloroalkylidene-γ-butyrolactone Derivatives via the Cascade Carbopalladation Cyclization Reaction. (1994) (0)
- Palladium(II)-Catalyzed Enyne Coupling Reaction Initiated by Acetoxypalladation of Alkynes and Quenched by Protonolysis of the Carbon—Palladium Bond. (2005) (0)
- Structural Factors Affecting the Selectivities in the Palladium(II)‐ Catalyzed Cyclization of N‐Alkenyl‐2‐alkynamides. (1996) (0)
- A Phosphine‐Catalyzed [3 + 6] Annulation Reaction of Modified Allylic Compounds and Tropone. (2005) (0)
- Studies on (PdH)‐ and (PdCl)‐Catalyzed Intramolecular Cyclization: The Search for a Better Solution to Selective Enyne Coupling (1996) (0)
- Pd(II)-Bipyridine Catalyzed Conjugate Additions of Arylboronic Acid to α,β-Unsaturated Carbonyl Compounds. (2006) (0)
- A New Methodology to Key Intermediates for Synthesizing Polyene Compounds. (1990) (0)
- Samarium Diiodide Initiated Addition Reaction of Fluoroalkyl Iodides (I) to Olefins (II), (IV), (VI). (1989) (0)
- Helping Chinese Enterprises be Successful in Global Markets (2007) (0)
- Highly Enantioselective Palladium(II)‐Catalyzed Cyclization of (Z)‐4′‐Acetoxy‐2′‐butenyl 2‐Alkynoates: An Efficient Synthesis of Optically Active γ‐Butyrolactones. (2000) (0)
- Palladium(II)‐Catalyzed Synthesis of α‐Alkylidene‐γ‐butyrolactams from N‐Allylic 2‐Alkynamides. Total Synthesis of (.+‐.)‐Isocynodine and (.+‐.)‐Isocynometrine. (2002) (0)
- A Catalytic Tandem Addition Route to γ,δ‐Unsaturated Carbonyls (2010) (0)
- Palladium-Catalyzed Synthesis of Allylic and Benzylic Sulfides from the Corresponding Dithiocarbonates. (1987) (0)
- Phosphine‐Catalyzed One‐Pot Synthesis of Cyclopentenes from Electron‐Deficient Allene, Malononitrile and Aromatic Aldehydes. (2006) (0)
- Palladium(II)‐Catalyzed Three‐Component Coupling Reaction Initiated by Acetoxypalladation of Alkynes: An Efficient Route to γ,δ‐Unsaturated Carbonyls. (2003) (0)
- A Novel Deoxygenation-Isomerization Reaction of 4-Hydroxy-2-ynoic Esters and γ-Hydroxy-α,β-ynones. (1993) (0)
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