Yitzhak Apeloig

Q: What Schools Are Affiliated With Yitzhak Apeloig

Yitzhak Apeloig is affiliated with the following schools: University of California, Berkeley, Tohoku University, Weizmann Institute of Science, Victoria University of Wellington, Technion – Israel Institute of Technology, Hebrew University of Jerusalem, University of Tsukuba, Ben-Gurion University of the Negev

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Yitzhak Apeloig

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Organic Chemistry

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Chemistry

Yitzhak Apeloig's Degrees

PhD Chemistry University of California, Berkeley
Bachelors Chemistry Technion – Israel Institute of Technology

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Yitzhak Apeloig's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

The chemistry of organic silicon compounds (1989) (2089)
Stabilization of planar tetracoordinate carbon (1976) (319)
On the Question of Stability, Conjugation, and “Aromaticity” in Imidazol-2-ylidenes and Their Silicon Analogs† (1996) (250)
A theoretical survey of unsaturated or multiply bonded and divalent silicon compounds. Comparison with carbon analogs (1986) (205)
Mechanism of the Acid-Catalyzed Si−O Bond Cleavage in Siloxanes and Siloxanols. A Theoretical Study (2002) (143)
Bonding and coupling of C1 fragments on metal surfaces (1988) (141)
A theoretical survey of singly bonded silicon compounds. Comparison of the structures and bond energies of silyl and methyl derivatives (1986) (133)
DILITHIUM DERIVATIVE OF TETRAPHENYLSILOLE : AN ETA 1-ETA 5 DILITHIUM STRUCTURE (1995) (106)
Reversible Transformation between a Diaminosilylene and a Novel Disilene (1999) (90)
Why Is Methylene a Ground State Triplet while Silylene Is a Ground State Singlet (2003) (89)
Substituent Effects on the Carbon-Silicon Double Bond. Monosubstituted Silenes (1984) (83)
The Dianion of Tetraphenylgermole is Aromatic (1996) (82)
Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. (2010) (81)
Substituent effects on the geometries and energies of the silicon-silicon double bond (1990) (80)
Novel Stable Silenes via a Sila-Peterson-type Reaction. Molecular Structure and Reactivity (1996) (77)
Chemical Shift Tensors and NICS Calculations for Stable Silylenes (1998) (66)
Synthesis, molecular structure, and reactivity of the isolable silylenoid with a tricoordinate silicon. (2006) (66)
(tBu2MeSi)2Sn=Sn(SiMetBu2)2: a distannene with a >Sn=Sn< double bond that is stable both in the solid state and in solution. (2006) (64)
Dimers of diaminosilylenes: doubly bonded or bridged? The dimers of (i-Pr(2)N)(2)Si:. (2001) (63)
On the mechanism of (C,H3,O).cntdot.loss from inoized methyl acetate. An ab initio molecular orbital study (1987) (62)
Theory Predicts Triplet Ground-State Organic Silylenes (1999) (60)
Novel route to carbon-silicon double bonds via a Peterson-type reaction (1992) (57)
Molecular orbital theory of the electronic structure of molecules. 33. The effect of .alpha.-electropositive substituents on the stabilities of carbenium ions (1977) (57)
Trisilaallene and the Relative Stability of Si3H4 Isomers. (2006) (57)
One-pot zinc-promoted asymmetric alkynylation/brook-type rearrangement/ene-allene cyclization: highly selective formation of three new bonds and two stereocenters in acyclic systems. (2013) (57)
The Search for an Isolable Silyl Cation Must Continue (1993) (56)
Mechanism of keto Å enol tautomerism of ionized vinyl alcohol versus acetaldehyde and their dissociation to C2H3O+ and H·. An ab initio molecular orbital study (1984) (55)
Molecular orbital theory of the electronic structure of molecules. 35. .beta.-Substituent effects on the stabilities of ethyl and vinyl cations. Comparison with isoelectronic methyl boranes. The relative importance of hyperconjugative and inductive effects (1977) (51)
Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond. (2006) (51)
Are carbenium ions stabilized or destabilized by .alpha.-silyl substitution? The solvolysis of 2-(trimethylsilyl)-2-adamantyl p-nitrobenzoate (1985) (50)
Theoretical Aspects of Organosilicon Compounds (2004) (50)
Radical reactions of a stable N-heterocyclic silylene: EPR study and DFT calculation. (2004) (49)
Structure and conformation of heterocycles. 16. Probing the anomeric effect. Trimethylsilyloxy and tert-butoxy substituents in 1,4-dioxane derivatives: theory vs. experiment (1987) (49)
The importance of hyperconjugation in nucleophilic vinylic substitution (1979) (48)
The Synthesis and Molecular Structure of the First Two-Coordinate, Dinuclear σ-Bonded Mercury(I) RHgHgR Compound. (1999) (47)
Dual character of arduengo carbene-radical adducts: addition versus coordination product. (2007) (47)
HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds. (1999) (47)
A SOLID-STATE 1NMR AND THEORETICAL STUDY OF THE CHEMICAL BONDING IN DISILENES (1997) (45)
Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation (1983) (45)
Cyclopropabenzene. Geometry, electronic structure, strain, reactivity, and the question of bond fixation. A theoretical study (1986) (44)
The First Persistent β‐Silyl‐Substituted Vinyl Cation (1991) (43)
Nonsolvated, aggregated 1,1-dilithiosilane and the derived silyl radicals. (2005) (43)
Evidence for the Dominant Role of Secondary Orbital Interactions in Determining the Stereochemistry of the Diels-Alder Reaction: The Case of Cyclopropene (1995) (42)
Importance of electronic geminal interactions in solvolysis reactions. Application to the determination of the .alpha.-silyl effect on carbonium ion stability (1993) (40)
Remote inductive effects in the solvolysis of secondary and tertiary 2-norbornyl derivatives. Evidence for nonclassical stabilization of the 2-norbornyl cation (1988) (38)
Do Silylenes Always Dimerize to Disilenes? Novel Silylene Dimers with Unusual Structures (1995) (35)
A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity. (2016) (35)
Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: experimental and computational evidence for the formation of stable .alpha.-arylvinyl cations both by direct means and by spontaneous exothermic isomerization of unstable isomeric ions (1981) (34)
The first demonstration of solvolytic generation of a simple silicenium ion (R3Si+). Access via 1,2-methyl migration (1987) (34)
Ab Initio and DFT Study of the 29Si NMR Chemical Shifts in RSi⋮SiR (2005) (34)
Stabilization of the phenyl cation by hyperconjugation (1985) (33)
Das erste persistente β‐Silyl‐substituierte Vinyl‐Kation (1991) (33)
The anomeric effect at silicon (1988) (33)
Ab Initio Study of Silyloxonium Ions (1997) (32)
An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity. (2018) (31)
Observation of a thermally accessible triplet state resulting from rotation around a main-group π bond. (2015) (30)
Triple Bonds to Silicon. Relative Stabilities and Energy Barriers Separating Silanitriles and Silaisonitriles. An ab Initio Study (1995) (30)
How to design linear allenic-type trisilaallenes and trigermaallenes. (2004) (30)
The synthesis and isolation of a metal-substituted bis-silene. (2008) (30)
The cyclic structure of monomeric dilithioacetylene (1976) (29)
The Synthesis of the First Compound with Li‐Si‐Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical (2002) (29)
On the Question of Cyclopropylidene Intermediates in Cyclopropene-to-Allene Rearrangements − Tetrakis(trimethylsilyl)cyclopropene, 3-Alkenyl-1,2,3-tris(trimethylsilyl)cyclopropenes, and Related Model Compounds (2001) (28)
A novel route to the trisilacyclobutane moiety. A possible silene-disilene reaction (1993) (28)
Formation of three new bonds and two stereocenters in acyclic systems by zinc-mediated enantioselective alkynylation of acylsilanes, Brook rearrangement, and ene-allene carbocyclization reactions. (2014) (28)
A New Method for the Synthesis of Branched Polysilane Anions (1997) (28)
Silynes (RC≡SiR') and Disilynes (RSi≡SiR'): Why Are Less Bonds Worth Energetically More? (2001) (28)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 29. ROLE OF HYPERCONJUGATION IN DETERMINING THE STEREOCHEMISTRY OF NUCLEOPHILIC EPOXIDATION AND CYCLOPROPANATION OF ELECTROPHILIC OLEFINS (1983) (27)
Geometries and Energies of Dilithioethylene Isomers and of Vinyl Lithium. An Ab Initio Study (1980) (26)
MECHANISM OF CARBON DIOXIDE ELIMINATION FROM IONIZED METHYL HALOACETATES IN THE GAS PHASE. FORMATION OF CH3XCH2+.CNTDOT. AND CH3XCHX+.CNTDOT. (X = CL, BR) HALONIUM RADICAL IONS (1983) (25)
Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HCC(OH)X (X = OH, NH2, NMe2, OMe, OCHO, F, Cl, Br) (1998) (25)
Alkyl- and silyl-substitutent effects on Keto-enol equilibria and the structures of simple aliphatic enols. A theoretical ab initio study (1990) (25)
Alkylated LixSiyOz Coating for Stabilization of Li-rich Layered Oxide Cathodes (2020) (24)
Chemical shielding tensors for a silicon-carbon double bond. (2001) (24)
Stabilization of perpendicular olefins. The structures and rotational barriers of singlet and triplet 1,1-dilithioethylenes (1976) (24)
Different electronic structure of phosphonyl radical adducts of N-heterocyclic carbenes, silylenes and germylenes: EPR spectroscopic study and DFT calculations (2010) (23)
Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules. (2019) (23)
A Combined Experimental and Theoretical Study of the Kinetics and Mechanism of the Addition of Alcohols to Electronically Stabilized Silenes: A New Mechanism for the Addition of Alcohols to the SiC Bond (2006) (23)
The structure and energy of SiH+5. comparisons with CH+5 and BH5 (1983) (23)
Mechanistic aspects of gas-phase hydrogen-atom transfer from methane to [CO](·+) and [SiO](·+) : why do they differ? (2013) (23)
Activation of pentafluorophenylsilanes by weak Lewis bases in reaction with iminium cations. (2006) (22)
The Mechanism of Addition of Phenols to Tetramesityldisilene. Evidence for Both Nucleophilic and Electrophilic Rate-Determining Steps (1996) (22)
THERMAL AND PHOTOCHEMICAL 2+2 CYCLOREVERSION OF A 1,2-DISILACYCLOBUTANE AND A 1,2-DIGERMACYCLOBUTANE (1998) (22)
Isolation and Characterization, Including by X-ray Crystallography, of Contact and Solvent-Separated Ion Pairs of Silenyl Lithium Species. (2016) (22)
Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene. (2017) (21)
SYNTHESIS AND X-RAY MOLECULAR STRUCTURE OF THE FIRST STABLE ORGANIC RADICAL LACKING RESONANCE STABILIZATION (1999) (21)
.alpha.-Silicon-substituted vinyl cations. A theoretical ab initio investigation (1982) (21)
The direct synthesis of a silene-organometallic complex. (2004) (21)
Rearrangement vs. dissociation of gaseous silicon-containing cations: a combined experimental–theoretical approach (1987) (21)
Arrhenius Parameters for the Addition of Phenols to the Silicon-Silicon Double Bond of Tetramesityldisilene † (1998) (21)
ELECTRONIC SPECTRA OF ETHYNYL- AND VINYLSILYLENES : EXPERIMENT AND THEORY (1994) (21)
Preparation of a silanone through oxygen atom transfer to a stable cyclic silylene. (2015) (21)
The stabilities of α-oxy and α-thio carbenium ions: the importance of the ground-state energies of the neutral precursors (1988) (21)
Synthesis and the electronic spectra of the first ß-ketoacylsilanes and their lithium enolates: new insights into hyperconjugation in acylsilanes and their enolates (1995) (20)
Heavier congeners of CO and CO2 as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te) (2016) (20)
Vinylic cations from solvolysis. II. Stereochemistry of the SN1 reaction of 1,2-dianisyl-2-phenylvinyl halides (1969) (20)
Isolation of silenolates (R3Si)2Si=C(OLi)Ad with a doubly bonded silicon atom. (2010) (19)
Theoretical Aspects of Compounds Containing Si, Ge, Sn and Pb (2003) (19)
Polysilyl radicals: EPR study of the formation and decomposition of star polysilanes (2000) (19)
Addition of Nucleophiles to Silenes. A Theoretical Study of the Effect of Substituents on Their Kinetic Stability (2002) (19)
Preparation and regioselective metalation of bis(trimethylsilyl)methyl-substituted aryl derivatives. (2014) (18)
Radical activation of Si-H bonds by organozinc and silylzinc reagents: synthesis of geminal dizinciosilanes and zinciolithiosilanes. (2012) (18)
Molecular orbital theory of the electronic structure of molecules. 36. A theoretical study of several .alpha.-substituted vinyl cations (1977) (18)
Experimental evidence for novel hydrogen/methyl exchange processes preceding the unimolecular dissociation of silicon-containing cations in the gas phase (1990) (18)
The stereochemistry of diels-alder reactions of cyclopropenes☆ (1987) (18)
Studies in the cycloproparene series: a theoretical and experimental study of the cyclopropabenzynes (1986) (18)
Does Hydride Ion Transfer from Silanes to Carbenium Ions Proceed Via a Rate-Determining Formation of a Silicenium Ion or Via a Rate-Determining Electron Transfer? An Ab Initio Quantum Mechanical Study and a Curve-Crossing Analysis (1993) (17)
Isolable photoreactive polysilyl radicals. (2009) (17)
Reactivities of methylenetriangulanes and spirocyclopropanated bicyclopropylidenes toward bromine. Relative stabilities of spirocyclopropanated versus methyl-substituted bromonium ions. (2002) (17)
Synthesis of silenyllithiums Li(R'3Si)Si═C(SiR3)(1-Ad) via transient silyne-silylidene intermediates. (2012) (17)
Catalytic and Photochemical Cyclopropanation of Alkenes with Methyl Diazo(trialkylsilyl)acetates: Steric Effects and Thermodynamic Stabilities of Cyclopropanes (2001) (17)
Theoretical study of heavier group 14 analogues of allene (2002) (17)
Novel Aggregation Motif of gem-Dilithiosilanes: Coaggregation of Two R2SiLi2 Molecules with Two RLi Molecules (2006) (16)
Ab Initio Study on the Unimolecular Decomposition Mechanisms and Spectroscopic Properties of CH3OF (1995) (16)
Theoretical prediction of vertical transition energies of diaminosilylenes and aminosubstituted disilenes (2001) (16)
The effect of substituents on the first transition in the visible spectra of silanediyls (silylenes) (1985) (16)
The effective ‘size’ of the tris(trimethylsilyl)silyl group in several molecular environments (1994) (16)
Were reactions of triplet silylenes observed? (2013) (16)
Solvent-Dependent Stereoselectivity in the Addition of p-CH3OC6H4OH to (E)-1,2-Di-tert-butyl-1,2-dimesityldisilene. Evidence for Rotation around the Si−Si Bond in the Zwitterionic Intermediate (1998) (16)
Silabutadienes. Internal rotations and pi-conjugation. A density functional theory study. (2008) (16)
Equilibria of simple thioenol/thiocarbonyl pairs. Comparison with the oxygen analogs and with the parent selenium and tellurium systems. A theoretical study (2000) (15)
A reliable and inexpensive method for calculating ionization potentials and electron affinities of radicals and molecules (1993) (15)
Vinylic cations from solvolysis. XXII. High stereoselectivity in the synthesis of and ion pair return in the solvolysis of (E)-.alpha.-bromo-.beta.-deuterio-p-methoxystyrene (1974) (15)
Mercury-Substituted Silyl Radical Intermediates in Formation and Fragmentation of Geminal Dimercury Silyl Compounds† (2005) (15)
Simple carbenium ions with electropositive α-substituents (1982) (15)
Polycyclic Arene Episulfides. Attempted Synthesis, Molecular Orbital Calculations and Comparison with Arene Oxides (1998) (15)
A novel synthesis of a germene and of a 1,2-digermacyclobutane via a Peterson-type reaction (1995) (15)
Electronic Structure of Bis(silyl)carbon-, Bis(silyl)silicon-, and Bis(silyl)germanium-Centered Radicals (R3Si)2XE• (E = C, Si, Ge; X = H, Re(CO)5, F): EPR and DFT Studies† (2010) (15)
Theoretical study of the isomeric cyclopropylidenemethyl and 1-cyclobutenyl cations, unusually stable vinyl cations (1980) (15)
Molecular Structures of Fulvalenes Derived from Methylidenecycloproparenes: X-ray Structure Determinations and ab Initio Calculations (1998) (15)
Vinylic cations from solvolysis. XX. Ion pairs and free ions in the solvolysis and isomerization of 1,2-dianisyl-2-phenylvinyl halides and mesylates. Use of cis-trans isomerization as a mechanistic tool (1975) (14)
The first .alpha.-silicon-substituted simple enol. The stabilizing effect of the silyl substituent (1987) (14)
Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl-Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles. (2015) (14)
Reversal of Stereoselectivity in the Reduction of gem-Dichlorides by Tributyltin Hydride and Tris(trimethylsilyl)silane. Synthetic and Mechanistic Implications (1994) (14)
Synthesis, isolation, and characterization of 1,1-diGrignard and 1,1-dizincio silanes. (2010) (14)
Bimolecular substitution at carbon in neopentyl-like silylcarbinyl sulfonates (1982) (14)
The Syntheses and Molecular Structure of a Branched Oligosilyl Anion with a Record of Nine Silicon Atoms and of the First Branched Oligosilyl Dianion (2000) (13)
Silylene dimers: highly fluxional molecules with unusual structures (1990) (13)
Ionization Energies of Linear and Cyclic Polysilanes. Application of the Green's Function Method Coupled with Semiempirical Molecular Orbital Calculations (1996) (13)
A theoretical investigation of a-substituted silicenium ions. (1977) (12)
The .PI. and .SIGMA.N electronic states of the succinimidyl radical. Can nitrogen-centered radicals have .SIGMA.N ground states? An ab initio study (1980) (12)
A single crystal molecular structure determination and theoretical calculations on alkynyl carboxylate esters (1990) (12)
Ionization energies of triazines and tetrazines. Application of Green's function method coupled with semiempirical molecular orbital calculations (1991) (12)
Relative Stabilities of Spirocyclopropanated Cyclopropyl Cations (2003) (12)
Ionization Potentials of Silenes (R‘2SiCR2). Experiment and Theory (2002) (11)
On the possible formation of Si=O, Si=S, and Si=Se double bonds via the reaction of silylenes with oxirane, thiirane, and selenirane, respectively. An ab initio theoretical study (2000) (11)
The role of hydride migration in the mechanism of alcohol elimination from protonated ethers upon chemical ionization (2003) (11)
Stabilization of silicenium ions by second row π-donor substituents.An ab initio study. (1981) (11)
The Diamond Within a Silicon Analog of Cyclobutadiene (2011) (11)
Branched Star-Type Polysilyllithium Compounds: The Effects of β-Silyl Substitution and of Complexation on Their Molecular Structure. (2001) (11)
Determination of the Solution Acidity of Tris(trimethylsilyl)silane (2002) (11)
Remote inductive effects on secondary and tertiary 2-norbornyl solvolysis rates (1981) (10)
Direct evidence for anchimeric assistance in alcohol elimination fromgas-phase MH+ ions of 1,4-dialkoxycyclohexanes under chemicalionisation. Experiment and theory (1997) (10)
Negative fluorine hyperconjugation. A theoretical re-examination (1981) (10)
Synthesis of the first long-lived bis-silene (2003) (10)
Spectroscopic studies of the role of silyl radicals in photolysis of polysilanes (2003) (10)
Convenient Synthesis of Deuterosilanes by Direct H/D Exchange Mediated by Easily Accessible Pt(0) Complexes (2017) (10)
Tris(trimethylsilyl)cyclopropenylium Cation: The First X-ray Structure Analysis of an α-Silyl-Substituted Carbocation† (1996) (10)
Theoretical Study of Ladder Polysilanes (2007) (10)
Tetrafluorocyclodisilazanes: synthesis, crystal structure, and molecular orbital ab initio calculations (1995) (10)
The Trichlorovinylsilane/tert-Butyllithium ReagentsA Source for Transient Silenes? (2001) (9)
Possible strategies toward the elusive tetraaminodisilene. (2002) (9)
Thermal transformation of a 1,2-disilacyclobutane to a trisilacyclobutane (2002) (9)
Are disilacyclopropylidenes and their carbenoids good precursors for the unknown 1,3-disilaallenes? (2001) (9)
BIMOLECULAR SUBSTITUTION AT CARBON IN NEOPENTYL‐LIKE SILYLCARBINYL SULFONATES (1983) (8)
[{(tBu2Me)2Si}3Li4]2-: An aggregated dianion of a 1,1-dilithiosilane with a unique structural motif. (2006) (8)
Single-Crystal Molecular Structure Determinations and Theoretical Calculations on Alkynyl Sulfonate and Carboxylate Esters (1991) (8)
Radical reactions of a stable N-heterocyclic germylene: EPR study and DFT calculation. (2004) (8)
Radical polymerization of the silene (Me3Si)2Si=CR2 by hydrogen transfer from a trimethylsilyl group. (2009) (8)
[CH3COH]˙+, the central intermediate in the isomerization–dissociation reactions of ionized vinyl alcohol (1983) (8)
Generation and Characterization of the First Persistent Platinum(I)-Centered Radical. (2018) (8)
Vinylic cations from solvolysis. XIX. Low tosylate-bromide reactivity ratios in vinylic solvolyses. Do kOTs/kBr ratios measure the polarity of the solvolytic transition state (1974) (8)
Dication ethers, R+-O-R+, conjugated cations with remarkably low rotation barriers. Theoretical investigation (1981) (8)
Silicon-Centered Radicals (2017) (7)
Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions (1980) (7)
Vinylic cations from solvolysis. XXI. Solvent effects on the external ion return and the internal return in several vinylic solvolyses (1975) (7)
Theoretical Aspects and Quantum Mechanical Calculations of Silaaromatic Compounds (1999) (6)
Substituent Effects on the Geometries and Energies of the Si=Si Double Bond (1991) (6)
The quest for a stable silyne, RSi ≡ CR′. The effect of bulky substituents [1] (2002) (6)
The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors (2004) (6)
Exocyclic Alkylidene Carbenes - An ab initio Theoretical Study. (1980) (6)
Activation of Homolytic Si-Zn and Si-Hg Bond Cleavage, Mediated by a Pt(0) Complex, via Novel Pt-Zn and Pt-Hg Compounds. (2015) (6)
α-Sila-Dipeptides: Synthesis and Characterization. (2018) (6)
Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes (1973) (6)
Transformation of Organosilicon-Loaded Alumina Gel to Homogeneous Alumino- silicates: A Solid-State NMR Study (2001) (5)
Novel stable ion/dipole complexes of HF and HCl with halocarbenes (1984) (5)
Synthesis by Si-H bond lithiation of novel half-pincer and pincer silyllithium compounds and their molecular structures (2017) (5)
The Raman, Ultraviolet, and Infrared Spectra and the JSiC NMR Coupling Constant of the Stable Silene (t-BuMe2Si)(Me3Si)Si2-Ad. Manifestations of the SiC Double Bond (2002) (5)
Diarylmethylenecyclopropabenzenes in cycloaddition (1993) (5)
A theoretical investigation of substituted alkylidene carbenes (1978) (5)
Conjugation, Resonance, and Stability in N-Heterocyclic Silylenes and in Phosphorus Ylide Substituted Silylenes (2012) (5)
Extraordinary large stabilization of the phenyl cation by hyperconjugation with strained bonds. Experimental confirmation of a theoretical prediction (1989) (5)
Propellanes. LXII. The endo- and exo-adducts of 11-cyano-1,6-methano[10] annulene with 4-methyl-1,2,4-triazoline-3,5-dione†‡ (1981) (5)
Additions and Corrections - α-Silicon-Substituted Vinyl Cations. A Theoretical ab Initio Investigation. (1983) (5)
The Reactions of Carbon Monoxide with Silyl and Silenyl Lithium. Synthesis and Isolation of the First Stable Bis-Silyl Ketyl Radical and 1-Silaallenolate Lithium. (2019) (5)
The effect of steric crowding on the structures of solvolytically reactive arylvinyl systems (1985) (4)
Thiocyanate Ion Promoted E ⇌ Z Isomerization of a‐Bromo‐β,β‐Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS− (1989) (4)
1,10-, 1,4-, and 1,2-Eliminations and 1,5- and 1,7-rearrangements in the reactions of substituted 9-anisylidene-9,10-dihydroanthracenes and anthrones in acetic acid (1979) (4)
Generation and Characterization of the First Persistent Platinum(I)‐Centered Radical (2018) (4)
Propellanes. Part LXXXI. Why are tetrakis[organoboranediylbis(oxy)]cyclobutanes formed without a trace of the isomeric tetrakis‐dioxabora[3.3.2]propellanes? (1985) (4)
The Lise Meitner‐Minerva Center for Computational Quantum Chemistry: 18 Years of Israeli‐German Collaboration (2015) (4)
Destabilized vinyl cations. An MO study of the influence of electron-withdrawing substituents (1994) (4)
Main group chemistry: Small silicon oxides isolated. (2015) (3)
Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HC=C(OH)X (X: OH, NH2, NMe2, OMe, OCHO, F, Cl, Br). (1999) (3)
A Novel High Yield Synthesis of an Octastannacubane and a Bis(silyl) Stannylene via Reductive Elimination of a Silane. (2020) (3)
Bonding and Coupling of C1 Fragments on Metal Surfaces. (1988) (3)
The 1‐Phenyl‐1‐(trimethylsilyl)ethyl Cation: An NMR Spectroscopic and Computational Study of the α‐Silyl Effect in Benzyl Cations (2012) (3)
On the experimental–theoretical discrepancy regarding the silicon–carbon double bond length (1984) (3)
Generation and EPR Spectroscopy of the First Silenyl Radicals, R2 C=Si. -R: Experiment and Theory. (2019) (3)
Vinylic cations from solvolysis. IV. Absence of β-aryl participation in the solvolysis of triarylvinyl halides (1970) (3)
Studies in the cycloproparene series: Cycloaddition reactions of diarylmethylidenecycloproparenes (2001) (3)
α-SILICON-SUBSTITUTED VINYL CATIONS. A THEORETICAL AB INITIO INVESTIGATION (1982) (3)
Cyclopropabenzenes and Alkylidenecyclopropabenzenes a Synergistic Relation between Theory and Experiment (1989) (3)
α‐Sila‐Dipeptides: Synthesis and Characterization (2018) (3)
Stereoselectivity of Alkylidenecarbene Addition to Olefins. Part 2. Effect of Orbital Polarization in the Alkenes (1986) (2)
Silylenes, Stable and Unstable (2008) (2)
Generation and EPR Spectroscopy of the First Silenyl Radicals, R 2 C=Si . −R: Experiment and Theory (2019) (2)
Persistent and Stable Silyl Radicals (2012) (2)
Vinylic cations from solvolysis. VI. Cis-trans isomerization as a tool for studying vinyl cation formation (1970) (2)
Theoretical Survey of Unsaturated or Multiply Bonded and Divalent Silicon Compounds. (1986) (1)
Novel Route to C=Si Double Bonds via a Peterson-Type Reaction. (2010) (1)
MOLECULAR ORBITAL THEORY OF THE ELECTRONIC STRUCTURE OF MOLECULES. 36. A THEORETICAL STUDY OF SEVERAL α‐SUBSTITUTED VINYL CATIONS (1978) (1)
Calculated p K Enol Values for Enols of Carboxylic Acid Derivatives (1998) (1)
Isolation of Silenolates (R 3 Si) 2 Si=C(OLi)Ad with a Doubly Bonded (2010) (1)
Synthesis of Silyl Aluminum Reagents: Relevance Toward Atomic Layer Deposition of Metal Silicides and the Serendipitous Synthesis of a Novel Al-Hydride Cluster. (2020) (1)
Transformation of Organosilicon‐Loaded Alumina Gel to Homogeneous Aluminosilicates: A Solid‐State NMR Study. (2001) (1)
Mechanism of the Thermal Z⇌E Isomerization of a Stable Silene. Experiment and Theory. (2019) (1)
A combined experimental and theoretical study of the kinetics and mechanism of the addition of alcohols to electronically stabilized silenes: a new mechanism for the addition of alcohols to the Si=C bond. (2006) (1)
Theory and Calculations for Vinyl Cations (1998) (1)
Silylenes and Multiple Bonds to Silicon: Synergism between Theory and Experiment (2008) (1)
Exo/emdo soltolysis rate ratios in constrained 2-norbornyl systems (1981) (1)
Silole and Germole Dianions and their Dilithium Derivatives: Are they Aromatic? (2008) (1)
The Fascinating World of Low-Coordination Silicon Compounds: Theory and Experiment in Synergy (2006) (1)
Mechanism of the Thermal Z⇌E Isomerization of a Stable Silene; Experiment and Theory (2019) (1)
The selectivity of isopropylidenecarbene (1986) (1)
Ab Initio Study on the Unimolecular Decomposition Mechanisms and Spectroscopic Properties of CH30F (2001) (0)
VINYLIC CATIONS FROM SOLVOLYSIS, HIGH K(CIS)/K(TRANS)-REACTIVITY RATIO IN THE SOLVOLYSIS OF ALPHA-BROMO-BETA-TERT.-BUTYL-P-METHOXY-STYRENES (1973) (0)
PROPELLANES. PART LXXXI. WHY ARE TETRAKIS(ORGANOBORANEDIYLBIS(OXY))CYCLOBUTANES FORMED WITHOUT A TRACE OF THE ISOMERIC TETRAKISDIOXABORA(3.3.2)PROPELLANES (1985) (0)
DISSOCIATIVE IONIZATION OF ARYL-SUBSTITUTED VINYL BROMIDES IN THE GAS PHASE: EXPERIMENTAL AND COMPUTATIONAL EVIDENCE FOR THE FORMATION OF STABLE α-ARYLVINYL CATIONS BOTH BY DIRECT MEANS AND BY SPONTANEOUS EXOTHERMIC ISOMERIZATION OF U (1981) (0)
Synthesis, isolation and characterization of a stable lithium stannenolate. A keto or an enol tautomer? (2021) (0)
Polycyclic Arene Episulfides. Attempted Synthesis, Molecular Orbital Calculations and Comparison with Arene Oxides. (1999) (0)
The Chemistry of Enols. Theoretical Calculations (1991) (0)
Structure and Conformation of Heterocycles. Part 16. Probing the Anomeric Effect. Trimethylsilyloxy and tert-Butoxy Substituents in 1,4-Dioxane Derivatives: Theory vs. Experiment (1987) (0)
The Reactions of Carbon Monoxide with Silyl and Silenyl Lithium – Synthesis and Isolation of the First Stable Tetra‐Silyl Di‐Ketyl Biradical and 1‐Silaallenolate Lithium (2019) (0)
η2-Phosphasilene transition metal complexes – a novel building block for hetero-multimetallic complexes (2022) (0)
Correction to "An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity". (2019) (0)
Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 37. Thiocyanate Ion Promoted E ⇌ Z Isomerization of α-Bromo-β,β-Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS-. (1990) (0)
Theoretical Survey of Singly Bonded Silicon Compounds. Comparison of the Structures and Bond Energies of Silyl and Methyl Derivatives (1986) (0)
Cyclopropabenzene. Geometry, Electronic Structure, Strain, Reactivity, and the Question of Bond Fixation. (1986) (0)
The Schulich Faculty of Chemistry, Technion - Israel Institute of Technology (2020) (0)
A Reliable and Inexpensive Method for Calculating Ionization Potentials and Electron Affinities of Radicals and Molecules. (1993) (0)
Synthesis, Isolation, and Characterization of 1,1-DiGrignard and (2010) (0)
Mechanism of (C,H3,O)· Loss from Ionized Methyl Acetate. An ab initio MO Study (1987) (0)
The First α-Silicon-Substituted Simple Enol. The Stabilizing Effect of the Silyl Substituent. (1988) (0)
The Stabilities of α‐Oxy and α‐Thio Carbenium Ions: The Importance of the Ground‐State Energies of the Neutral Precursors (1988) (0)
First Demonstration of Solvolytic Generation of a Simple Silicenium Ion (R3Si+). Access via 1,2-Methyl Migration. (1987) (0)
Contents of volume 2 (1988) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 19, LOW TOSYLATE-BROMIDE REACTIVITY RATIOS IN VINYLIC SOLVOLYSES, DO K(OTS)/K(BR) RATIOS MEASURE THE POLARITY OF THE SOLVOLYTIC TRANSITION STATE (1974) (0)
Bonding and Coupling of C sub 1 Fragments on Metal Surfaces (1987) (0)
A Convenient Preparation of Organofluorosilanes. A Possible Involvement of Tetracoordinated Siliconium Ion Pairs (1992) (0)
Triple Bonds to Silicon: Substituted Silanitriles Versus Silaisonitriles — A Theoretical Study (2008) (0)
The Search for an Isolable Silyl Cation Must Continue. (1994) (0)
Foreword by the Guest Editors (1993) (0)
A High Yield Synthesis of an Octastannacubane and a Bis(silyl) Stannylene via Reductive Elimination of a Silane (2020) (0)
Diarylmethylenecyclopropabenzenes in Cycloaddition. (1994) (0)
The Stereochemistry of Diels-Alder Reactions of Cyclopropenes. (1988) (0)
Cover Feature: The Schulich Faculty of Chemistry, Technion - Israel Institute of Technology (Eur. J. Org. Chem. 21/2020) (2020) (0)
Remote Inductive Effects in the Solvolysis of Secondary and Tertiary 2-Norbornyl Derivatives. Evidence for Nonclassical Stabilization of the 2-Norbornyl Cation. (1988) (0)
Cycloproparene Series: A Theoretical and Experimental Study of the Cyclopropabenzynes. (1986) (0)
Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl‐Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles. (2015) (0)
Mechanism of COS Elimination from Ionized Methyl Haloacetates in the Gas Phase. Formation of CH3XCH2+* and CH3XCHXf- (X = C1, Br) Halonium Radical Ions (1983) (0)
A Novel Route to the Trisilacyclobutane Moiety. A Possible Silene- Disilene Reaction. (2010) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 22, HIGH STEREOSELECTIVITY IN THE SYNTHESIS OF AND ION PAIR RETURN IN THE SOLVOLYSIS OF (E)-ALPHA-BROMO-BETA-DEUTERIO-P-METHOXYSTYRENE (1974) (0)
ARE CARBENIUM IONS STABILIZED OR DESTABILIZED BY α-SILYL SUBSTITUTION? THE SOLVOLYSIS OF 2-(TRIMETHYLSILYL)-2-ADAMANTYL P-NITROBENZOATE (1985) (0)
A Novel Synthesis of a Germene and of a 1,2-Digermacyclobutane via a Peterson-Type Reaction. (1996) (0)
PROPELLANES. LXII. THE ENDO- AND EXO-ADDUCTS OF 11-CYANO-1,6-METHANO(10)ANNULENE WITH 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE (1981) (0)
The First Persistent β‐Silyl‐Substituted Vinyl Cation. (1992) (0)
The Dianion of Tetraphenylgermole is Aromatic. (1996) (0)
A Single Crystal Molecular Structure Determination and Theoretical Calculations on Alkynyl Carboxylate Esters. (1990) (0)
In celebration of the 65th birthday of Professor Yitzhak Apeloig. (2009) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 20, ION PAIRS AND FREE IONS IN THE SOLVOLYSIS AND ISOMERIZATION OF 1,2-DIANISYL-2-PHENYLVINYL HALIDES AND MESYLATES, USE OF CIS-TRANS ISOMERIZATION AS A MECHANISTIC TOOL (1975) (0)
Front Cover: The Schulich Faculty of Chemistry, Technion - Israel Institute of Technology (Eur. J. Org. Chem. 21/2020) (2020) (0)
Multiple Bonding with Four-Coordinate Silicon ? Insights into the Nature of the Si d O and Si d S Double Bonds in Stable Silanoic Esters and Related Thioesters : A Combined NMR Spectroscopic and Computational Study (2010) (0)
Berichtigung: Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene (2020) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 21, SOLVENT EFFECTS ON THE EXTERNAL ION RETURN AND THE INTERNAL RETURN IN SEVERAL VINYLIC SOLVOLYSES (1975) (0)
Organosilicon Chemistry: A Synergistic Relation Between Theory and Experiment (1991) (0)
Molecular Structures of Fulvalenes Derived from Methylidenecycloproparenes: X‐Ray Structure Determinations and ab initio Calculations. (1999) (0)
Robert C. West (1928-2022): A Giant in Organosilicon Chemistry, Cosmopolitan, Mountain Climber and Pilot. (2023) (0)
A Combined Experimental and Theoretical Study of the Kinetics and Mechanism of the Addition of Alcohols to Electronically Stabilized Silenes : A New Mechanism for the Addition of Alcohols to the Si d C Bond (2006) (0)
Synthesis of Genuine Germenyl Lithiums and the First Persistent Germenyl Radicals (2022) (0)
Communications to the Editor First Demonstration of Solvolytic Generation of a Simple Silicenium Ion (R3Si+).t Access via 1,2-Methyl Migration' (1987) (0)
Catalytic and Photochemical Cyclopropanation of Alkenes with Methyl Diazo(trialkylsilyl)acetates: Steric Effects and Thermodynamic Stabilities of Cyclopropanes. (2002) (0)
EXO/ENDO SOLVOLYSIS RATE RATIOS IN CONSTRAINED 2-NORBORNYL SYSTEMS (1982) (0)
Corrigendum: Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene. (2020) (0)
Facile Synthesis of an Octagermacubane with Two Three-Coordinate Germanium(0) Atoms and its Unique Radical Anion. (2023) (0)
HCSiF and HCSiCl: The First Detection of Molecules with Formal CSi Triple Bonds. (1999) (0)
MO Theory of the Electronic Structure of Molecules. Part 35. β-Substituent Effects. on the Stabilities of Ethyl and Vinyl Cations. Comparison with Isoelectronic Methyl Boranes. The Relative Importance of Hyperconjugative and Inductive (1977) (0)
( tBu 2 MeSi ) 2 Sn d Sn ( SiMetBu 2 ) 2 : A Distannene with a > Sn d Sn < Double Bond That Is Stable Both in the Solid State and in Solution (0)
The Selectivity of Isopropylidenecarbene. (1987) (0)
Ionization Energies of Triazines and Tetrazines. Application of Green′ s Function Method Coupled with Semiempirical MO Calculations (1992) (0)
STABILIZATION OF SILICENIUM IONS BY SECOND ROW Π-DONOR SUBSTITUENTS. AN AB INITIO STUDY (1982) (0)

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What Schools Are Affiliated With Yitzhak Apeloig?

Yitzhak Apeloig is affiliated with the following schools:

University of California, Berkeley
Tohoku University
Weizmann Institute of Science
Victoria University of Wellington
Technion – Israel Institute of Technology
Hebrew University of Jerusalem
University of Tsukuba
Ben-Gurion University of the Negev