Zvi. Rappoport

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Zvi. Rappoport

Chemistry

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Organic Chemistry

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#259

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Chemistry

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Zvi. Rappoport's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

The chemistry of organic silicon compounds (1989) (2089)
The Chemistry of the quinonoid compounds (1974) (694)
The Chemistry of Organic Selenium and Tellurium Compounds (1994) (589)
The chemistry of phenols (2003) (525)
The chemistry of the cyclopropyl group (1995) (378)
The chemistry of the cyano group (1970) (378)
The Chemistry of sulphones and sulphoxides (1988) (244)
The chemistry of enamines (1994) (243)
The Chemistry of Organic Germanium, Tin and Lead Compounds (1995) (227)
The Chemistry of Anilines (2007) (227)
The chemistry of peroxides (2006) (217)
The Chemistry of enols (1990) (215)
The chemistry of hydroxylamines, oximes and hydroxamic acids (2009) (203)
The Chemistry of Sulphonic Acids, Esters and their Derivatives (1991) (189)
CRC Handbook of Tables for Organic Compound Identification (1967) (152)
Crown ethers and analogs (1989) (149)
Organic Selenium and Tellurium Compounds (1986) (1986) (122)
The Chemistry of Organozinc Compounds (2006) (117)
The chemistry of dienes and polyenes (1997) (113)
The Chemistry of halides, pseudo-halides, and azides (1995) (107)
The chemistry of α-haloketones, α-haloaldehydes and α-haloimines (1988) (105)
The Chemistry of Organomagnesium Compounds (2008) (104)
The Cyano Group (1970) (1970) (99)
Synthesis of Carboxylic Acids, Esters and Their Derivatives (1991) (95)
Nucleophilic Vinylic Substitution (1969) (95)
Nucleophilic vinylic substitution. A single- or a multi-step process? (1981) (94)
The chemistry of organolithium compounds (2004) (87)
The Chemistry of alkanes and cycloalkanes (1992) (87)
The rapid steps in nucleophilic vinylic addition-elimination substitution. Recent developments (1992) (87)
The chemistry of cyclobutanes (2005) (86)
The Chemistry of enones (1989) (84)
Allylic Oxidation of Olefins by Palladium Acetate1 (1966) (77)
Sulphones and Sulphoxides (1988) (1988) (70)
The Chemistry of sulphur-containing functional groups (1993) (70)
The rich mechanistic world of nucleophilic vinylic (SNV) substitution (1986) (69)
The Silicon-heteroatom bond (1991) (65)
Sterically crowded stable simple enols (1988) (65)
The chemistry of organic derivatives of gold and silver (1999) (61)
Effect of Substituents on the Structure of the Vinyl Radical: Calculations and Experiments (1997) (59)
Recent advances in our mechanistic understanding of S(N)V reactions. (2009) (57)
The Chemistry of Organocopper Compounds (1994) (54)
The importance of hyperconjugation in nucleophilic vinylic substitution (1979) (48)
Unequivocal S(RN)1 route of vinyl halides with a multitude of competing pathways: reactivity and structure of the vinyl radical intermediate. (2003) (46)
Allylic oxidation of olefins by mercuric acetate (1972) (46)
Synthesis of lactones and lactams (2010) (45)
Differentiating between large isomers and derivation of structural information by ion mobility spectrometry/mass spectrometry techniques (1988) (43)
860. Nucleophilic attacks on carbon–carbon double bonds. Part V. The reaction of dimethylaniline with tetracyanoethylene: π- and σ-complexes in electrophilic aromatic and nucleophilic vinylic substitutions (1963) (43)
Azide-water competition in solvolysis reactions. A revisit of the reactivity-selectivity relationship (1983) (39)
Vinylic cations form solvolysis. I. Trianisylvinyl halide system (1969) (36)
Threshold Rotational Mechanisms and Enantiomerization Barriers of Polyarylvinyl Propellers (1997) (36)
Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: experimental and computational evidence for the formation of stable .alpha.-arylvinyl cations both by direct means and by spontaneous exothermic isomerization of unstable isomeric ions (1981) (34)
Enols of Carboxylic Acid Amides with β-Electron-Withdrawing Substituents (2000) (33)
Application of the structural correlation method to ring-flip processes in benzophenones (1990) (32)
Solvent-induced changes in the selectivity of solvolyses in aqueous alcohols and related mixtures (1992) (31)
Kinetics of the Reactions of Methoxybenzylidene Meldrum's Acid with Thiolate Ions, Alkoxide Ions, OH-, and Water in Aqueous DMSO. Detection and Kinetic Characterization of the SNV Intermediate (1998) (31)
Sulphonic Acids, Esters and their Derivatives (1991) (1991) (31)
Stable simple enols. 11. Equilibrium constants for the 1-alkyl-2,2-dimesitylethenol/1-alkyl-2,2-dimesitylethanone systems in hexane. The predominance of steric effects on Kenol values (1985) (29)
KINETICS OF THE REACTIONS OF BETA -METHOXY-ALPHA -NITROSILBENE WITH METHOXYAMINE AND N-METHYLMETHOXYAMINE. DIRECT OBSERVATION OF THE INTERMEDIATE IN N UCLEOPHILIC VINYLIC SUBSTITUTION (1995) (29)
Solvolysis in 2,2,2-trifluoroethanol-water and 2,2,2-trifluoroethanol-ethanol mixtures. Selectivity of the intermediates and N values (1980) (29)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 29. ROLE OF HYPERCONJUGATION IN DETERMINING THE STEREOCHEMISTRY OF NUCLEOPHILIC EPOXIDATION AND CYCLOPROPANATION OF ELECTROPHILIC OLEFINS (1983) (27)
Solvolysis of .alpha.-arylvinyl derivatives (1976) (27)
Stable simple enols. III: Static and dynamic NMR behavior of crowded triarylethenols and related compounds. Three-ring flip as the threshold mechanism for enantiomerization of crowded triarylvinyl propellers (1984) (27)
Stable simple enols. 5. Solvent dependence of the conformation of the OH group in 2,2-dimesitylethenol and several 1,2,2-triarylethenols (1984) (27)
Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HCC(OH)X (X = OH, NH2, NMe2, OMe, OCHO, F, Cl, Br) (1998) (25)
Cyclobutene-1,2-diones. A Theoretical and Spectroscopic Study. (1996) (25)
71. Nucleophilic attacks on carbon–carbon double bonds. Part II. Cleavage of arylmethylenemalononitriles by water in 95% ethanol (1962) (25)
Stable simple enols. 9. Solid state structures and conformations of several simple enols and their keto tautomers (1985) (25)
Alkyl- and silyl-substitutent effects on Keto-enol equilibria and the structures of simple aliphatic enols. A theoretical ab initio study (1990) (25)
Generation and Detection of a Relatively Persistent Carboxylic Acid Enol2,2-Bis(2‘,4‘,6‘-triisopropylphenyl)ethene-1,1-diol (1996) (24)
Nucleophilic attacks on carbon-carbon double bonds. 31. Complete and partial stereoconversion in vinylic substitution of (E)- and (Z)-.beta.-chloro-.alpha.-phenylcinnamaldehydes and (E)-2-iodo-1,2-diphenyl-1-nitroethylene by nucleophiles (1985) (23)
Stable simple enols. Polar and resonance substituent effects of .alpha.-aryl groups on keto .dblharw. enol equilibria of stable enols (1987) (23)
Vinyl cations from solvolysis (1970) (22)
Nucleophilic attacks on carbon-carbon double bonds. 28. Complete and partial stereoconversion in the substitution of methyl (E)- and (Z)-.beta.-chloro-.alpha.-cyano-p-nitrocinnamates by nucleophiles (1982) (21)
Substituted 2-methylene-1,3-oxazolidines, -1,3-thiazolidines, -1,3-benzothiazines, -1,3-oxazines, and substituted imidazopyrimidinediones from Cl(CH2)nNCO and Cl(CH2)nNCS and active methylene compounds. (2006) (21)
262. Nucleophilic attacks on carbon–carbon double bonds. Part VIII. The reaction of N-methylaniline with tetracyanoethylene in chloroform (1964) (21)
Nucleophilic attacks on carbon-carbon double bonds. Part 39. Nucleophile and nucleofuge effects, catalysis and stereochemistry in vinylic substitution of electrophilic nitro olefins (1989) (21)
Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions (1990) (21)
Enols of substituted cyanomalonamides. (2007) (20)
Nucleophilic attacks on carbon-carbon double bonds. 26. Stereoconvergence in nucleophilic vinylic substitution of an activated nitro olefin (1980) (20)
Triphenylethenethiol. Structure, Equilibria with the Thioketone, Solvation, and Association with DMSO† (1996) (20)
The Syntheses of sulphones, sulphoxides and cyclic sulphides (1994) (20)
Vinylic cations from solvolysis. II. Stereochemistry of the SN1 reaction of 1,2-dianisyl-2-phenylvinyl halides (1969) (20)
Vinylic cations from solvolysis. Part XIII. SN1 and electrophilic addition–elimination routes in the solvolysis of α-bromo- and α-chloro-4-methoxystyrenes (1973) (19)
Stable simple enols. 23. Solid-state structures of 1-alkyl-2,2-dimesitylethenols. Application of the principle of structural correlation to ring-flip processes in 1,1-diarylvinyl systems (1989) (19)
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Cyanamide in 50 DMSO−50 Water. Failure to Detect the SNV Intermediate (1999) (19)
Stable simple enols. Part 19. Steric effects and threshold rotational mechanisms in 1-substituted 2,2-dimesitylethenols (1989) (19)
A comprehensive picture of the one-electron oxidation chemistry of enols, enolates and α-carbonyl radicals: oxidation potentials and characterization of radical intermediates (2009) (19)
OBSERVATION OF AN AMIDE ENOL OF BIS(2,4,6-TRIISOPROPYLPHENYL)ACETIC ACID (1996) (19)
Vinylic cations from solvolysis. XVIII. Unusual solvent effects and external ion return in the solvolysis of several vinylic compounds in aqueous trifluoroethanol (1974) (19)
Vinylic cations from solvolysis. Part 36. Vinylation of aromatic substrates with solvolytically generated trisubstituted vinyl cations (1982) (18)
Comprar The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids | William N. Zelman | 9780470512616 | Wiley (2008) (18)
Solvent Effects on Anchimerically Assisted Solvolyses. II. Solvent Effects in Solvolyses of threo-2-Aryl-1-methylpropyl p-Toluenesulfonates (1995) (18)
Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution (1989) (17)
Thermochemistry and unimolecular reactions of ionized 1,2-dimesityl-2-phenylethanone and 2,2-dimesityl-1-phenylethanone and their enols and enol acetates in the gas phase (1981) (17)
Nucleophilic attacks on carbon–carbon double bonds. Part XXII. Base catalysis, leaving group effects, and solvent effects in several nucleophilic vinylic substitutions by amines (1975) (17)
Nucleophilic attacks on carbon–carbon double bonds. Part XII. Addition of amines to electrophilic olefins and reactivity order of the activating groups (1970) (17)
Metal acetate promoted reactions of .sigma.- and .pi.-allylic organometallics (1972) (16)
Enols of amides. The effect of fluorine substituents in the ester groups of dicarboalkoxyanilidomethanes on the enol/amide and E-enol/Z-enol ratios. A multinuclei NMR study. (2001) (16)
The effective ‘size’ of the tris(trimethylsilyl)silyl group in several molecular environments (1994) (16)
Competition of Mechanisms in Nucleophilic Substitution of Vinyl Halides. An Unequivocal Example of the Vinylic SRN1 Route1 (1994) (16)
Sulphur-Containing Functional Groups (1993) (1993) (16)
861. Nucleophilic attacks on carbon–carbon double bonds. Part VI. Amine-catalysed cis–trans-isomerisation of ethyl α-cyano-β-O-methoxyphenylacrylate through a zwitterionic carbanion in benzene (1963) (16)
Vinylic cations from solvolysis. X. SN1 and nucleophilic addition-elimination routes for 9-(.alpha.-haloarylidene)fluorenes (1972) (15)
Nucleophilic attacks on carbon–carbon double bonds. Part XX. Reaction of active methylene compounds with electrophilic olefins. Formation of substituted 2-amino-4-cyano-4H-pyrans (1974) (15)
Nucleophilic attacks on carbon-carbon double bonds. 33. Approaching the retention region from the stereoconvergence region in nucleophilic substitution of (E)- and (Z)-methyl p-substituted .alpha.-formyl- and .alpha.-(tert-butoxycarbonyl)-.beta.-halocinnamates (1986) (15)
Equilibria of simple thioenol/thiocarbonyl pairs. Comparison with the oxygen analogs and with the parent selenium and tellurium systems. A theoretical study (2000) (15)
Nucleophilic attacks on carbon-carbon double bonds. 25. Reactions of monoamines and diamines with 1,1-dicyano-2-p-dimethylaminophenyl-2-trifluoroethoxyethylene (1979) (15)
Vinylic cations from solvolysis. XXII. High stereoselectivity in the synthesis of and ion pair return in the solvolysis of (E)-.alpha.-bromo-.beta.-deuterio-p-methoxystyrene (1974) (15)
Stable simple enols. 8. Synthesis and keto .dblharw. enol equilibria of the elusive 2,2-dimesitylethanal and 1,2,2-trimesitylethanone. Conformations of 1,2,2-trimesitylethanone and 1,2,2-trimesitylethanol (1985) (15)
The first solid enols of anhydrides. Structure, properties, and enol/anhydride equilibria(1). (2007) (15)
Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions. (2008) (15)
The first .alpha.-silicon-substituted simple enol. The stabilizing effect of the silyl substituent (1987) (14)
Vinylic cations from solvolysis. XX. Ion pairs and free ions in the solvolysis and isomerization of 1,2-dianisyl-2-phenylvinyl halides and mesylates. Use of cis-trans isomerization as a mechanistic tool (1975) (14)
Nucleophilic Vinylic Substitution (SNV) of Activated Alkoxymethylene Derivatives with 6‐Aminoquinoxaline (2005) (14)
Highly specific reciprocal methyl/hydrogen transfer reactions preceding some unimolecular dissociations of crowded enol cation radicals in the gas phase as examples for conformationally controlled processes (1984) (14)
The CF3CH2O- Adducts of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene and .beta.-Methoxy-.alpha.-nitrostilbene, and the MeO- Adducts of .beta.-Methoxy-.alpha.-nitrostilbene. Kinetics of Competition between Protonation and Acid Catalyzed Alkoxide Ion Departure (1995) (14)
Hydrogen bonding in calix[n]arenes. A preliminary 17O NMR study (1996) (13)
Does the Threshold Enantiomerization Route of Crowded Tetraarylethenes Involve Double Bond Rotation (1995) (13)
Competition of Mechanisms in the Photochemical Cleavage of the C−X Bond of Aryl-Substituted Vinyl Halides (1998) (13)
Stable simple enols. Resolution of chiral 1-[9'-(2'-fluoroanthryl)]-2,2-dimesitylethenol. A different racemization mechanism for the enol and its acetate. (2003) (13)
Nucleophilic reactions at vinylic center. 27. Vinylic substitution of 1,2-dibromo-1,2-difluoroethylene and tribromofluoroethylene. An intramolecular kBr/kF element effect and apparent inversion of configuration in SNV reactions (1993) (13)
Substitution of β-Halostyrenes by MeS- (1998) (13)
Syntheses of Sulphones, Sulphoxides and Cyclic Sulphides (1995) (1995) (13)
Nucleophilic attacks on carbon-carbon double bonds. 34. Intramolecular elements effect in competitive expulsion of two halide nucleofuges as a tool for investigating the rapid step of nucleophilic vinylic substitution (1987) (12)
Vinylic cations from solvolysis. XVII. Unusual solvent effect and common ion rate depression in aqueous trifluoroethanol (1974) (12)
REVERSIBILITY OF KETENE HYDRATION (1995) (12)
Reactions of substituted (methylthio)benzylidene Meldrum's acids with secondary alicyclic amines in aqueous DMSO. Evidence for rate-limiting proton transfer. (2004) (12)
Methyl vs. methylene condensation of aromatic aldehydes with 1,1,1-trifluoroacetylacetone (1985) (12)
Stable simple enols. Part 21. Solvent and .alpha.- and .beta.-substituent effects on the association with hydrogen bond accepting solvents and the hydroxyl conformation of stable simple enols (1989) (12)
Alkanes and Cycloalkanes (1992) (1992) (12)
STABLE SIMPLE ENOLS. 3. STATIC AND DYNAMIC NMR BEHAVIOR OF CROWDED TRIARYLETHENOLS AND RELATED COMPOUNDS. THREE-RING FLIP AS THE THRESHOLD MECHANISM FOR ENANTIOMERIZATION OF CROWDED TRIARYLVINYL PROPELLERS (1984) (12)
Limitations of ultra-violet spectroscopy for the study of the reversible hydration of carbonyl compounds (1967) (11)
On the coexistence of the “reactivity-selectivity” and the “constant selectivity” relationships in reactions of carbonium ions with nucleophiles (1979) (11)
Nucleophilic attacks on carbon-carbon double bonds. 36. Stereochemistry of substitution of good nucleofuges at the stereoconvergence region as a tool for investigating the rapid step of nucleophilic vinylic substitution (1988) (11)
GAS PHASE BASICITIES OF PHENYLACETYLENES. INTRINSIC RESONANCE DEMAND OF THE 1-PHENYLVINYL CATION (1996) (11)
Nucleophilic attacks on carbon-carbon double bonds. Part 35. Methyl trideuteriomethyl (E)-(.alpha.-bromoarylidene)malonates. Simple stereochemical probes in nucleophilic vinylic substitution near the retention/stereoconvergence borderline (1987) (11)
Studies of substituent effects by carbon‐13 NMR spectroscopy. V —Ethyl (E)‐(α‐cyano)cinnamates, (E)‐(α‐cyano)cinnamamides and ethyl (α‐ethoxycarbonyl)cinnamates (1986) (11)
DETECTION AND KINETIC CHARACTERIZATION OF SNV INTERMEDIATES. REACTIONS OF THIOMETHOXYBENZYLIDENE MELDRUM'S ACID WITH THIOLATE IONS, ALKOXIDE IONS, OH- , AND WATER IN AQUEOUS DMSO (1999) (11)
Bis(dimesitylmethylene)-1,3-dithietane, -1,2,4-trithiane, and -1,2,4,5-tetrathiane. Conformation and DNMR Study. Observable Dimesityl Thioketene. (1996) (11)
Nucleophilicity and ionizing power in binary solvent mixtures (1977) (11)
Stable simple enols. 24. Unusual kinetic stability of enols to ketonization: 1,2-dimesityl-3-methylbut-1-en-1-ol and related .beta.-alkyl-.alpha.,.beta.-dimesitylethenols (1990) (11)
Kinetics of reactions of hydroxide ion and water with .beta.-X-substituted .alpha.-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution (1991) (11)
Nucleophilic attacks on carbon–carbon double bonds. Part XVIII. Reaction of 2-dicyanomethyleneindane-1,3-dione with anilines in acetonitrile (1973) (11)
A Search for Unambiguous Vinylic SRN1 Reactions (2002) (10)
Hydrolysis of α-Alkyl-α-(methylthio)methylene Meldrum's Acids. A Kinetic and Computational Investigation of Steric Effects (2006) (10)
Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .be (1994) (10)
Planar tetracoordinate carbon in a transition state (1978) (10)
70. Nucleophilic attacks on carbon–carbon double bonds. Part I. General considerations: arylmethylene transfer and cyclodimerisation (1962) (10)
Isolation of a ketene imine from the decomposition of a vinyl azide (1988) (10)
Degenerate .beta.-aryl rearrangements in photochemically generated triarylvinyl cations (1984) (10)
Enols of amides activated by the 2,2,2-trichloroethoxycarbonyl group. (2004) (10)
Stereochemistry of the Vinylic S(RN)1 Reaction of Triarylvinyl Halides. The Structure of the Intermediate alpha-Arylvinyl Radical. (1996) (10)
72. Nucleophilic attacks on carbon–carbon double bonds. Part III. Base-catalysed hydrolysis of activated carbon–carbon double bonds in 95% ethanol (1962) (10)
PHOTOCYCLIZATION OF 2,4,6,2',4',6'-HEXAALKYLBENZILS (1995) (10)
Stable simple enols. 33. Effect of tetra-m-bromo and tetra-m-methyl buttressing on the ground-state structures, rotational barriers, and keto .dblharw. enol equilibria of 2,2-dimesityl-1-R-ethenols (1993) (10)
263. Nucleophilic attacks on carbon–carbon double bonds. Part IX. The primary (equilibrium) step. The reaction of tri-n-butylphosphine with arylmethylenemalononitriles in methanol (1964) (10)
Observable Enols of Anhydrides: Claimed Literature Systems, Calculations, and Predictions (2001) (10)
Hexamethyldisilane as a source of both trimethylsilyl and pentamethyldisilyl anions. Formation of a substituted pentamethyldisilyl stable enol (1990) (10)
A two-ring flip as the threshold enantiomerization route for a triarylvinyl propeller. 1D and 2D NMR and static and dynamic stereochemistry of trimesitylethylene (1986) (10)
Vinylic cations from solvolysis. III. Solvolysis of triarylvinyl arylsulfonates in aqueous acetone (1970) (10)
A rich array of reactions of Cyanomonothiocarbonylmalonamides RNHCSCH(CN)CONHR' and their Thioenols RNHC(SH)=C(CN)CONHR'1. (2008) (9)
Unraveling structure-reactivity relationships in SNV reactions: kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)-1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl beta-methylthio-alpha-nitrocinnamate with OH- and thiolate ions in aqueous DMSO (2001) (9)
Vinylic cations from solvolysis. 42. Cyclization on methyl, capture by solvent, and degenerate rearrangement of the trimesitylvinyl cation (1986) (9)
Multiple buttressing interactions : enantiomerization barrier of tetrakis(pentamethylphenyl)ethene (1994) (9)
Crown Ethers and Analogs: Updates from the Chemistry of the Functional Groups (1989) (9)
Calculated pKEnol Values for β,β-Diarylacetic Acids and β,β-Diarylacetaldehydes. Effect of Steric Bulk of Substituents on the Relative Stability of Enols of Carboxylic Acids and Aldehydes (2000) (9)
Two dimers derived from the 2,4,6-tri-tert-butylphenyl radical, formed during reactions of the aryllithium or the Grignard reagent with carbonyl compounds (1991) (9)
Kinetics of reactions of amines with .alpha.-nitro-.beta.-substituted-stilbenes in 50% dimethyl sulfoxide-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions (1990) (9)
Crystal Structure of 1,2-Diphenyl-5,7-di-tert-butylspiro[2.5]octa-1,4,7-trien-6-one, a Possible Model for Diphenylvinylidenephenonium Ions (1999) (9)
Stable simple enols. 31. Substituted xanthenylidene enols. The importance of .beta.-Ar-C:C conjugation in the stabilization of aryl-substituted enols (1992) (9)
Dipole moments and electronic absorption spectra of aryltricyanoethylenes (1970) (9)
Stable simple enols. 10. 500-MHz proton NMR of trimesitylethenol and deuterated analogs: complete signal assignments and direct determination of equilibrium steric isotope effects from the NMR integrals of the isotopomeric enols (1985) (9)
Resolution and enantiomerization barrier of tetramesitylethylene (1992) (9)
Handbook Tables For Organic Compound Identification, Third Edition (1966) (9)
Intramolecular Geminal and Vicinal Element Effects in Substitution of Simple Bromo(chloro)alkenes by Methoxide and Thiolate Ions. An Example of a Single Step Substitution? (1997) (9)
Non-linearity and non-additivity of substituent effects in solvolysis of 1,1-diphenylethyl p-nitrobenzoates (2002) (9)
Kinetics and mechanism of reactions of substituted (methylthio)benzylidene Meldrum's acids with primary amines in aqueous DMSO (2006) (9)
Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile (1993) (9)
VINYLIC CATIONS FROM SOLVOLYSIS PART 18, UNUSUAL SOLVENT EFFECTS AND EXTERNAL ION RETURN IN THE SOLVOLYSIS OF SEVERAL VINYLIC COMPOUNDS IN AQUEOUS TRIFLUOROAETHANOL (1974) (9)
Vinylic cations from solvolysis. IX. Trifluoroacetolysis of 1-anisyl-2-methylpropen-1-yl arylsulfonates (1971) (9)
VINYLIC CATIONS FROM SOLVOLYSIS. 27. SOLVOLYSIS OF AN OPTICALLY ACTIVE VINYL BROMIDE (1979) (9)
Comparison of the Strengths of Dicyano-Methylene and Oxygen Acids (1970) (9)
Acidities of Stable Simple Enols and Bond Dissociation Enthalpies of Their H−O Bonds in DMSO (1997) (9)
Nucleophilic attacks on carbon–carbon double bonds. Part XVI. Some relative reactivities of the leaving groups (kBr/kCl, kOMs/kCl, and kOBs/kOTs) in vinylic substitutions (1972) (9)
Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid. (1999) (9)
Substituent Effects in the 1,1-Diphenylcarbenium Systems : Hydration and Bromination of 1,1-Diphenylethylenes (2003) (8)
The Quinonoid Compounds: Vol. 1 (1988) (1988) (8)
Stable enols of amides ArNHC(OH)=C(CN)CO(2)R. E/Z enols, equilibria with the amides, solvent effects, and hydrogen bonding. (2003) (8)
Nucleophilic attacks on carbon-nitrogen double bonds. 3. Diversity of mechanisms for the substitution of diarylimidoyl chlorides by amines in acetonitrile (1976) (8)
Acyl-oxygen cleavage in the alkaline hydrolysis of activated vinyl esters (1982) (8)
Nucleophilic attacks on carbon–carbon double bonds. Part XV. Further evidence for base-catalysis in the reaction of 1,1-dicyano-2-p-dimethylaminophenyl-2-fluoroethylene with substituted anilines in acetonitrile (1972) (8)
TRIFLATE/MESYLATE RATIOS AND COMPETING C-O AND S-O BOND CLEAVAGES IN NUCLEOPHILIC VINYLIC SUBSTITUTION (1996) (8)
Amine catalysis in the vinylic substitution of α-methylthio-α-arylmethylene Meldrum's acids and its absence in the substitution of methyl β-iodo-α-nitrocinnamate by amines (2001) (8)
Stable simple enols. 17. Linear free energy relationship between keto .dblharw. enol equilibrium constants of stable .beta.,.beta.-dimesityl and unstable .beta.,.beta.-unsubstituted .alpha.-substituted enols (1987) (8)
Nucleophilic attacks on carbon–carbon double bonds (2010) (8)
Gas-phase acidities of disubstituted methanes and of enols of carboxamides substituted by electron-withdrawing groups. (2004) (8)
Solvent Effects on Anchimerically Assisted Solvolyses. III. Solvent Effects on the Solvolyses of (1-Arylcycloalkyl)methyl p-Toluenesulfonates (1996) (8)
Vinylic cations from solvolysis. XIX. Low tosylate-bromide reactivity ratios in vinylic solvolyses. Do kOTs/kBr ratios measure the polarity of the solvolytic transition state (1974) (8)
Allylic oxidation of allylbenzene by mercuric acetate (1970) (8)
Oxa-ene reaction of enols of amides with 4-phenyl-1,2,4-triazoline-3,5-dione. (2008) (8)
N‐Isopropyl enols of carboxylic acid amides (2003) (8)
Solvent Effects on the Solvolysis of Benzyl Tosylates. Behavior of Derivatives with Electron-Donating Substituents (1995) (8)
Vinylic cations from solvolysis. V. Common ion rate depression and stability of some vinyl cations in acetolysis (1970) (8)
Triple-Bonded Functional Groups: Vol. 1 (1983) (1983) (7)
The gas-phase ion chemistry of an enol/aldehyde pair: 2,2-dimesitylethenol and 2,2-dimesitylethanal (1986) (7)
Vinylic cations from solvolysis. Part XI. Solvolysis of triarylvinyl arenesulphonates and bromides (1972) (7)
Conformations of vicinal-triketones. A theoretical and 17O NMR approach (2001) (7)
Tables for identification of organic compounds (1964) (7)
Stable simple enols. Self-catalyzed E/Z-isomerization of the sterically crowded 2-(m-methoxymesityl)-1,2-dimesitylethenol. (2003) (7)
Vinylic cations from solvolysis. XXI. Solvent effects on the external ion return and the internal return in several vinylic solvolyses (1975) (7)
Solvolysis of p,p'-dichlorobenzhydryl chloride in ethanol-2,2,2-trifluoroethanol mixtures (1978) (7)
Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions (1980) (7)
Vinylic cations from solvolysis. 26. Solvolysis of 9-(.alpha.-chlorovinyl)anthracene and selectivity of the derived ion (1978) (7)
The gas-phase ion chemistry of crowded, triaryl-substituted keto/enol pairs (1986) (7)
17O NMR studies of diaryl α‐diketones. The case of 2,2′,4,4′,6,6′‐hexa‐tert‐butylbenzil (1995) (7)
Nucleophilic attacks on carbon–carbon double bonds. Part X. Nucleophile-catalysed cis–trans isomerisation of cis-4-nitrochalcone and of diethyl maleate in 95% ethanol (1966) (7)
Isomeric solid enols on ring- and amide-carbonyls of substituted 2-carbanilido-1,3-indandiones. (2007) (7)
Vinylic cations from solvolysis. Part XV. β-Phenyl and β-p-methoxyphenyl rearrangement during the solvolysis of 2,2-diaryl-1-phenylvinyl bromides (1973) (7)
Nucleophilic attacks on carbon–carbon double bonds. Part XVII. Base-catalysis in the displacement of vinylic ethoxy-, fluoro-, and cyano-leaving groups by amines (1973) (7)
Solvent effects on the solvolysis of 1-(p-methoxyphenyl)-2-methylpropen-1-yl tosylate (1992) (7)
Reactions of enols of amides with diazomethane. (2002) (7)
Calculated amide/enol of amide energy differences for several interesting amide systems (2000) (7)
Nucleophilic attacks on carbon–carbon double bonds. Part XIII. Vinylic substitution of 1,1-dicyano-2-p-dimethylaminophenyl-2-halogenoethylenes by aromatic amines in acetonitrile (1971) (6)
The 1-N-(methoxycarbonyl-2-phenylethyl)imino-2,2,2-trifluoroethanephosphonate systems are not stable enols of carboxylic esters (2003) (6)
The acid dissociation constant of triphenylethenethiol, a simple thioenol, and that of its oxygen-enol analog (1998) (6)
SRN1 Photostimulated Reaction of Triphenylvinyl Bromide with Carbanions in DMSO (1996) (6)
Hindered rotation in several diarylamidines (1972) (6)
Vinylic cations from solvolysis. 30. Bromide exchange as a reactivity-selectivity probe in vinylic solvolysis (1980) (6)
Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes (1973) (6)
Vinylic cations from solvolysis. Part XII. Solvolysis of cis- and trans-α-bromo- and-αβ-dibromo-4,4′-dimethoxystilbenes (1972) (6)
Fluoride Ion as a Catalyst for Michael Additions to Nitro-Alkenes (1975) (6)
Spectroscopic and kinetic evidence for an accumulating intermediate in an SNV reaction with amine nucleophiles. Reaction of methyl beta-methylthio-alpha-nitrocinnamate with piperidine and morpholine. (2007) (6)
Stable simple enols. 6. A shift in the threshold mechanism of correlated rotation in 2,2-dimesitylethenols from a one- to a two-ring flip (1984) (6)
Nucleophilicity in Reactions at a Vinylic Carbon (1987) (6)
Chemistry on stamps (chemophilately) (1992) (6)
Enols and thioenols of substituted cyanomonothiocarbonylmalonamides: structures, enolization vs. thioenolization, equilibria and conformations. (2008) (6)
Effect of halogen and of a para substituent on the solid-state conformation of several crowded electrophilic vinyl halides (1986) (6)
Reactions of the Relatively Persistent Carboxylic Acid Enol2,2-Ditipylethene-1,1-diol. The Reversibility of Ketene Hydration1 (1996) (6)
The Quinonoid Compounds: Vol. 2 (1988) (1988) (6)
Nucleophilic attacks on carbon–carbon double bonds. Part XXIII. Substitution of β-chloro-α-phenylacrylonitriles (1975) (6)
Comprar The Chemistry of Organomagnesium Compounds | Prof Zvi Rappoport | 9780470057193 | Wiley (2008) (5)
N‐ Vs. C‐ Tricyanovinylation of Ring‐Substituted Dimethylanilines. The Spectral Properties of the Products. (1968) (5)
Specific reciprocal methyl/hydrogen transfer reactions and hydrogen exchange processes between aryl rings in crowded ketone cation radicals (1985) (5)
332. The kinetics and mechanism of the decomposition of Michael adducts: an example of the E1cB elimination (1962) (5)
Vinylic cations from solvolysis. 33. Solvolysis of E- and Z-1-anisyl-2-(p-nitrophenyl) propen-1-yl chlorides (1980) (5)
The first example of isomeric solid amide and its enol. (2006) (5)
Enols of 2‐nitro‐ and related 2‐substituted malonamides (2009) (5)
Structure of the intermediate in the 4-tricyanovinylation of 2,6-dimethylaniline (1969) (5)
261. Nucleophilic attacks on carbon–carbon double bonds. Part VII. The “element effect” in tricyanovinylation. The reaction of tricyanovinyl chloride with NN-dialkylanilines (1964) (5)
73. Nucleophilic attacks on carbon–carbon double bonds. Part IV. cis–trans-Isomerisation of ethyl α-cyano-β-o-methoxyphenylacrylate by various nucleophiles (1962) (5)
The ultraviolet spectra of O-(2,4-dinitrophenyl)oximes and 2,4-dinitrophenylhydrazones: transmission of electronic effects through O and NH groups (1967) (5)
Ionization energies of 1-R-2,2-dimesitylethenols, 1,2-dimesityl-2-phenylethenol, and some of their keto tautomers (1986) (5)
Association of .alpha.-alkyl-.beta.,.beta.-dimesitylethenols with hydrogen-bond-accepting solvents (1988) (5)
Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021) (2022) (5)
On the selectivity-selectivity relationship in the solvolysis reactions of alkyl halides (1982) (4)
1,10-, 1,4-, and 1,2-Eliminations and 1,5- and 1,7-rearrangements in the reactions of substituted 9-anisylidene-9,10-dihydroanthracenes and anthrones in acetic acid (1979) (4)
Oxygen‐17 and carbon‐13 NMR studies of diarylketenes (1995) (4)
Thiocyanate Ion Promoted E ⇌ Z Isomerization of a‐Bromo‐β,β‐Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS− (1989) (4)
Reactions of 1,1-diarylethylenes with selenium compounds (1971) (4)
Vinylic cations from solvolysis. 24. Degenerate .beta.-aryl rearrangements during the solvolysis of 1,2-dianisyl-2-phenylvinyl bromides and trianisylvinyl bromide. Free vinyl cations as intermediates (1976) (4)
Thioenols and thioamides substituted by two β‐EWGs. Comparison with analogous amides and enols (2008) (4)
The effect of steric crowding on the structures of solvolytically reactive arylvinyl systems (1985) (4)
Dialkoxyphosphinyl-substituted enols of carboxamides. (2007) (4)
Conformations and Threshold Rotational Mechanisms of the (Z)-1,2-Diarylethene Moiety: A Structural Correlation Study. (1999) (4)
Stereoelectronic Effects in the Nucleophilic Addition to the sp-Hybridized Carbon of a Ketene and Vinyl Cation: When Is a Mesityl Effectively Smaller than a Phenyl Ring?1 (1996) (4)
Static and Dynamic Stereochemistry and Solvation of 2,2-Ditipylethenols(1). (1997) (4)
Crystal and molecular structures of dimesitylketene and bis(3,5‐dibromo‐2,4,6‐trimethylphenyl)ketene. Intrinsic torsional angles and buttressing effects in 1,1‐dimesitylvinyl propellers (1989) (4)
Vinylic cations from solvolysis. XIV. Anisyl rearrangement in the acetolysis of β,β-dianisyl-α-phenylvinyl bromide (1973) (4)
On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides (1982) (4)
Nucleophilic attacks on carbon–carbon double bonds. Part XIV. Low-element effects and amine catalysis in the substitution of 1,1-dicyano-2-p-dimethylaminophenyl-2-halogenoethylenes by anilines in alcohols (1971) (4)
Solvolysis of 1‐p‐Methoxyphenyl‐2‐Methylpropen‐1‐Yl Trifluoroacetate and 3,5‐Dinitrobenzoate (1974) (4)
Nucleophilic attacks on carbon-carbon double bonds. Part 38. Chloride ion exchange and E .dblharw. Z isomerization of an electrophilic vinyl chloride (1989) (4)
Vinylic cations from solvolysis. VIII. Solvolysis of cis and trans α-bromo-p,p'-dimethoxystilbenes. (1970) (4)
Vinylic cations from solvolysis. XXIII. Degenerate .beta.-anisyl rearrangement during the solvolysis of 2-anisyl-1,2-diphenylvinyl bromides. Free ions as intermediates (1976) (4)
Calculated double-bond stabilization by bromine and chlorine. Relevance to the kBr/kCl element effect (1991) (4)
Recent Advances in Our Mechanistic Understanding of SNV Reactions (2010) (4)
Relative stability of crowded isomeric enols: 2‐Mesityl‐2‐phenylethenols and their methyl ethers (1993) (3)
Four Enantiomerization Routes of 1,2,2-Trimesitylvinyl Acetate. Enantioselective Liquid Chromatography of (E)- and (Z)-2-m-Methoxymesityl-1,2-dimesitylvinyl Acetates. (1999) (3)
Nucleophilic attacks on carbon–carbon double bonds. Part 24. Nucleophilic substitution of (E)- and (Z)-3-chloro-2-phenylpropenonitriles; comments on the work of Le Guillanton and Cariou (1977) (3)
The chemistry of organomanganese compounds (2011) (3)
Sensitivity to the activating group in E1CB eliminations (1971) (3)
Nuclear magnetic resonance and mass spectra of benzoselenopheno-[2,3-b]benzoselenophens (1970) (3)
The chemistry of dienes and polyenes; Volume 2 (2000) (3)
Vinylic cations from solvolysis. 28. Solvent dependency of the solvolytic site of 9-(.alpha.-bromoanisylidene)-10-hydroxy-9,10-dihydroanthracene (1979) (3)
Residual Enantiomerism and Chromatographic Resolution of a 1,1,2‐Triarylalkene (1989) (3)
Formation of .alpha.-[bis(dimethylamino)phosphoryl]-substituted stable enols and N,N-dialkyl diarylacetamides from diarylketenes and methyllithium in hexamethyl phosphoric triamide (1991) (3)
Electronic effects in polyarylvinyl propellers. Solid state structures and dynamic behaviour in solution of several crowded enol derivatives (1998) (3)
Vinylic cations from solvolysis. IV. Absence of β-aryl participation in the solvolysis of triarylvinyl halides (1970) (3)
The Rapid Steps in Nucleophilic Vinylic “Addition‐Elimination” Substitution. Recent Developments (1993) (3)
Stable Simple Enols. Part 12. Molecular Mechanics Structure and Dipole Moment of (Z)-1,2-Dimesityl-2-phenylethenol. (1986) (3)
Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HC=C(OH)X (X: OH, NH2, NMe2, OMe, OCHO, F, Cl, Br). (1999) (3)
Vinylic cations from solvolysis. 25. Ion pairs in the solvolysis, isomerization, and rearrangement of .alpha.-arylvinyl halides in pivalic acid (1976) (3)
17O and13C NMR spectra of stable simple enols (1995) (3)
The ultraviolet spectra of nitrophenylhydrazones in neutral solution; substituent and solvent effects (1968) (3)
Stable simple enols. 2. Correlated rotation in two .beta..beta.-dimesityl-.alpha.-arylethenols. A probable example of a three-ring flip (1981) (3)
The chemistry of organogold compounds (2014) (3)
Conformational dependence of substituent effects in the solvolyses of the 1,1-diphenyl-2,2,2-trifluoroethyl system (2002) (3)
A rearranged acetylene from an E1 solvolysis of a substituted α-trimethylsilylvinyl system (1991) (2)
Low temperature enol–enol association of stable 2,2‐diarylethenols (1994) (2)
Table of Contents of Volume 1 (2005) (2)
Stereoelectronic effect in the capture reaction of the 1,2-dimesityl-2-phenylvinyl radical (1999) (2)
The kBr/kCl element effect for nucleophilic vinylic substitution of the highly reactive tricyanovinyl-X system by substituted anilines (1984) (2)
The migratory aptitudes of some aryl groops in triarylvinyl cations (1980) (2)
Effect of substituents on the competition between several mechanisms of nucleophilic vinylic substitution (1995) (2)
Nucleophilic attacks on carbon–carbon double bonds. Part XXI. Substitution of (E)-α-chloro-β-nitrostyrene by anilines in acetonitrile (1975) (2)
Nucleophilic Dechlorocarbomethoxylation of (E)-Methyl β-Chloro-α-methyl-β-(3-bromo- 2,4,6-trimethylphenyl)acrylate (1996) (2)
Mapping the Enantiomerization Routes of Triarylvinyl Propellers. Barriers to the Three-Ring Flip and the Three Different Two-Ring Flips of m-Methoxy-Substituted Trimesitylvinyl Isopropyl Ethers (1994) (2)
E1cB eliminations. Part V. Two types of E1cB reaction in the amine-catalysed elimination of HCN from 2,6-dimethyl-4-(ααββ-tetracyanoethyl)aniline in chloroform (1971) (2)
Aryl exchange via reversible Friedel-Crafts reaction in the synthesis of a diarylacetic acid (1988) (2)
Nucleophilic Substitution of Methyl β-Chloro-(3-bromo-2,4,6-trimethyl)cinnamate (1997) (2)
Nucleophilic attacks on carbon–nitrogen double bonds. Part 4. Substitution of N-arylbenzimidoyl cyanides by amines in acetonitrile and by alkoxides in alcohols (1977) (2)
1 – INTRODUCTION AND HISTORICAL BACKGROUND (1979) (2)
CRYSTAL STRUCTURE OF THE SOLID STATE PHOTOREACTIVE 2,2',4,4',6,6'-HEXAISOPROPYLBENZIL (1995) (2)
2,2',4,4',6-PENTA-TERT-BUTYLBENZIL : AN UNEXPECTED PRODUCT IN THE ATTEMPTED COUPLING OF TRI-TERT-BUTYLBENZOYL CHLORIDE WITH MAGNESIUM-MAGNESIUM IODIDE (1997) (2)
Vinylic cations from solvolysis. VI. Cis-trans isomerization as a tool for studying vinyl cation formation (1970) (2)
Internal rotation in 2,2-dimesityl-1-trimethylsilylethenol (1991) (2)
Nature of the cationoid intermediates in the solvolytic rearrangement of 2,2-dianisyl-1-arylvinyl bromides in 2,2,2-trifluoroethanol and acetic acid (1982) (2)
The chemistry of [alpha]-haloketones, [alpha]-haloaldehydes, and [alpha]-haloimines (1988) (2)
140. Carbonyl–methylene condensations. Part XIII. Acid-catalysed condensation of ethyl cyanoacetate with aromatic aldehydes (1962) (2)
Sites of successive bromination of the ambident nucleophiles 2-methoxy-, 2,4-dimethoxy- and 2,4,6-trimethoxy-benzylidenefluorenes and 2,2-dimesityl-1-tert-butylethenol (1993) (2)
E1cB eliminations. Substituent and solvent effects on the E1cB elimination of the second type from 2-aryl-1,1,2-tricyanopropanes (1972) (2)
Acidities and pKEnol values of stable simple enols in the gas phase (2000) (2)
Isolable and relatively stable simple enols (2010) (2)
Intramolecular cyclization of bis(2,4,6-trialkylphenyl) ketenes to isochromenes (1997) (2)
Revisit of the leaving group (LG)/halogen exchange in 1,2‐dimesityl‐2‐phenylvinyl–LG systems: a caveat about ‘mistaken identity’ by X‐ray diffraction (2001) (2)
Vinylic cations from solvolysis. 39. Solvolysis of 9-[.alpha.-bromo- and .alpha.-(tosyloxy)-p-methoxybenzylidene]xanthenes (1984) (2)
Kinetics of Reactions of Thiolate Ions with α-Nitro β-Substituted Stilbenes in 50% Me2SO-50% Water. Observation of the Intermediate in Nucleophilic Vinylic Substitution Reactions. (1990) (2)
E1cB and E2cB mechanisms in the elimination of trifluoroethoxide ion from α,α-dinitro-β,β-diphenyl-β-(trifluoroethoxy)ethanide anion and the non-reactivity of the β-cyano-α,α-dinitro-β,β-diphenylethanide anion (1975) (2)
Cyclopropyl Group Volume 1 and Volume 2 (1987) (1987) (2)
Contribution of activity coefficients to the nucleophilicity of solvent components in solvent mixtures. Influence of added acetone on selectivity values, kE/kW, in ethanol–water mixtures (1990) (2)
Restricted rotation and torsional isomerism in tamoxifen derivatives (1989) (1)
A very slow ElcB elimination under extreme ElcB conditions (1972) (1)
Substitution of 9-(α-bromo-α-arylmethylene)fluorenes by thiolate ions in aqueous acetonitrile (1997) (1)
Reactions of α-isobutyl-α-(methylthio)methylene Meldrum's acid with primary amines in aqueous DMSO (2006) (1)
SOLVOLYSIS OF α-ARYLVINYL DERIVATIVES (1976) (1)
Vinylic Cations from Solvolysis. Part 40. On the Distribution of Products in the De- generate Rearrangement of Doubly Labeled Triarylvinyl Cations. (1984) (1)
Rearrangement studies with 14C. XLIV. Ion-pairs and dissociated ions in the solvolysis of triphenyl[2-14C]vinyl and trianisyl[2-14C]vinyl bromides in 70% acetic acid – 30% water (1980) (1)
Unequivocal SRN1 Route of Vinyl Halides with a Multitude of Competing Pathways: Reactivity and Structure of the Vinyl Radical Intermediate. (2003) (1)
Acidities of Stable Simple Enols and Bond Dissociation Enthalpies of Their H‐O Bonds in DMSO. (1997) (1)
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution (1989) (1)
Intramolecular Rotations in 2,2-Dimesityl-1-(9-anthryl)- and -1-(9-triptycyl)vinyl Acetates (1994) (1)
Trityl cation as a leaving group in electrophilic vinylic substitution (1972) (1)
THERMOCHEMISTRY AND UNIMOLECULAR REACTIONS OF IONIZED 1,2‐DIMESITYL‐2‐PHENYLETHANONE AND 2,2‐DIMESITYL‐1‐PHENYLETHANONE AND THEIR ENOLS AND ENOL ACETATES IN THE GAS PHASE (1981) (1)
THE RELEVANCE OF BASE CATALYSIS IN AROMATIC NUCLEOPHILIC SUBSTITUTION TO C-X BOND CLEAVAGE (1974) (1)
Solvent‐Induced Changes in the Selectivity of Solvolyses in Aqueous Alcohols and Related Mixtures (1993) (1)
Studies on reaction kinetics and on 82Br exchange in the solvolysis of triphenylvinyl bromide or trianisylvinyl bromide in 70% HOAc – 30% H2O (1982) (1)
An Z to E Isomerization of an Electrophilic Vinyl Azide by 15 N3-. A Probe for Internal Rotation Processes in the CarbanionicIntermediate of Nucleophilic Vinylic Substitution. (1994) (1)
TENTH INTERNATIONAL CONFERENCE ON PHYSICAL ORGANIC CHEMISTRY : SLECTED PAPERS, HAIFA, ISRAEL, 6-10 AUGUST 1990 (1991) (1)
STABLE SIMPLE ENOLS. 8. SYNTHESIS AND KETO ⇌ ENOL EQUILIBRIA OF THE ELUSIVE 2,2-DIMESITYLETHANAL AND 1,2,2-TRIMESITYLETHANONE. CONFORMATIONS OF 1,2,2-TRIMESITYLETHANONE AND 1,2,2-TRIMESITYLETHANOL (1985) (1)
DEGENERATE β-ARYL REARRANGEMENTS IN PHOTOCHEMICALLY GENERATED TRIARYLVINYL CATIONS (1985) (1)
Application of the Structural Correlation Method to Ring-Flip Processes in Benzophenones. (1991) (1)
The Chemistry of Enols. Isolable and Relatively Stable Simple Enols (1991) (1)
Structural Sensitivity of 1,2-Aryl Rearrangements in Triarylvinyl Cations: Bridged Transition States vs Bridged Intermediates and Inversion vs Helicity Retention (1998) (1)
The low KEnol values of β-sulfonyl-substituted amides (2015) (1)
Calculated p K Enol Values for Enols of Carboxylic Acid Derivatives (1998) (1)
Halides, Pseudo-Halides and Azides: Vol. 1 (1983) (1983) (1)
VINYLIC CATIONS FROM SOLVOLYSIS PART 17, AN UNUSUAL SOLVENT EFFECT AND COMMON ION RATE DEPRESSION IN AQUEOUS TRIFLUOROETHANOL (1974) (1)
Stable Simple Enols. Part 19. Steric Effects and Threshold Rotational Mechanisms in 1‐Substituted 2,2‐Dimesitylethenols (1989) (1)
Effect of Halogen and of a Para Substituent on the Solid-State Conformation of Several Crowded Electrophilic Vinyl Halides. (1987) (1)
Vinylic cations from solvolysis. 41. Solvolytic rearrangements of 2,2-dianisyl-1-tolylvinyl bromide and (E)- and (Z)-1,2- dianisyl-2-tolylvinyl bromide (1984) (1)
Reaction of 1,1-diarylethylenes with tellurium halides (1971) (1)
Chaim Weizmann as a Scientist – From Berlin to the End of His Manchester Period (2015) (1)
Nucleophilic attacks on carbon-nitrogen double bonds. Part I. Substitution of diarylimidoyl chlorides with amines in benzene (1971) (1)
Thermal motion of tert-butyl groups III. tert-Butyl substituents in aromatic hydrocarbons, the view from the bottom of the well. (2010) (1)
Halides, Pseudo-Halides and Azides: Part 2 (1983) (1983) (1)
Enols of Carboxylic Acid Amides with β‐Electron‐Withdrawing Substituents. (2000) (1)
KETO ENOL EQUILIBRIA FOR AND OXIDATIVE CYCLIZATION TO BENZOFURANS OF 2,2-DITIPYL-1-R-ETHENOLS. COMPARISON WITH DIMESITYL ANALOGS (1999) (1)
Infrared Correlation Chart No. 1 (1966) (0)
Explanations and References to Table V (1966) (0)
Contents of Volume 1 (2000) (0)
VINYLIC CATIONS FROM SOLVOLYSIS. 28. SOLVENT DEPENDENCY OF THE SOLVOLYTIC SITE OF 9-(α-BROMOANISYLIDENE)-10-HYDROXY-9,10-DIHYDROANTHRACENE (1979) (0)
Sites of Successive Bromination of the Ambident Nucleophiles 2-Methoxy- , 2,4-Dimethoxy- and 2,4,6-Trimethoxy-benzylidenefluorenes and 2,2- Dimesityl-1-tert-butylethenol. (1993) (0)
Two Dimers Derived from the 2,4,6‐Tri‐tert‐butylphenyl Radical, Formed During Reactions of the Aryllithium or the Grignard Reagent with Carbonyl Compounds. (1991) (0)
STABLE SIMPLE ENOLS. 2. CORRELATED ROTATION IN TWO ββ-DIMESITYL-α-ARYLETHENOLS. A PROBABLE EXAMPLE OF A THREE-RING FLIP (1982) (0)
Kinetics of the Reaction of beta-Methoxy-alpha-nitrostilbene with Cyanamide in 50 DMSO-50 Water. Failure to Detect the S(N)V Intermediate. (1999) (0)
Explanations and References to Table XXI (1966) (0)
Stable Simple Enols. Part 21. Solvent and α- and β-Substituent Effects on the Association with Hydrogen Bond Accepting Solvents and the OH Conformation of Stable Simple Enols. (1989) (0)
Formation of α-(Bis(dimethylamino)phosphoryl)-Substituted Stable Enols and N,N-Dialkyldiarylacetamides from Diarylketenes and MeLi in HMPA. (1991) (0)
Methyl Trideuteriomethyl (E)-(α-Bromoarylidene)malonates: Simple Stereochemical Probes in Nucleophilic Vinylic Substitution near the Retention/Stereoconvergence Borderline. (1988) (0)
The First α-Silicon-Substituted Simple Enol. The Stabilizing Effect of the Silyl Substituent. (1988) (0)
Contents of volume 2 (1988) (0)
Rearrangement studies with 14C. XLVI. Isotopic scrambling studies on the acetolysis of trianisylvinyl bromide labeled with 13C and with 14C (1981) (0)
SOLVOLYSIS OF P,P′-DICHLOROBENZHYDRYL CHLORIDE IN ETHANOL-2,2,2-TRIFLUOROETHANOL MIXTURES (1979) (0)
Explanations and References to Table XV (1966) (0)
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Explanations and References to Table XIV (1966) (0)
Stable simple enols. Part 28. Representation of the strain in 2,2-dimesitylethenol and its 1-alkyl derivatives (1991) (0)
Stable Simple Enols. Part 33. Effect of Tetra‐m‐bromo and Tetra‐m‐ methyl Buttressing on the Ground‐State Structures, Rotational Barriers, and Keto ⇌ Enol Equilibria of 2,2‐Dimesityl‐1‐R‐ethenols. (1993) (0)
Explanations and References to Table XII (1966) (0)
The chemistry of dines and polyenes; Volume 1 (1997) (0)
NUCLEOPHILE ANGRIFFE AUF C=C-DOPPELBINDUNGEN 14. MITT. KLEINE ELEMENTEFFEKTE UND AMIN-KATALYSE BEI SUBSTITUTION VON 1,1-DICYAN-2-(P-DIMETHYLAMINO-PHENYL)-2-HALOGEN-AETHYLEN DURCH ANILINE IN ALKOHOLEN (1971) (0)
Bis(dimesitylmethylene)-1,3-dithietane, -1,2,4-trithiane, and -1,2,4,5- tetrathiane. Conformation and DNMR Study. Observable Dimesityl Thioketene. (1997) (0)
3) K. Friedrich in The Chernistry 0/ Functional Groups, Supp. C (Hrsg.: S. (1998) (0)
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Effect of Substituents on the Competition Between Several Mechanisms of Nucleophilic Vinylic Substitution. (1996) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 19, SIGMA, RHO ANALYSIS OF NUCLEOPHILIC REACTIONS ON ARYL-SUBSTITUTED ELECTROPHILIC OLEFINS (1974) (0)
VINYLIC CATIONS FROM SOLVOLYSIS. 24. DEGENERATE β-ARYL REARRANGEMENTS DURING THE SOLVOLYSIS OF 1,2-DIANISYL-2-PHENYLVINYL BROMIDES AND TRIANISYLVINYL BROMIDE. FREE VINYL CATIONS AS INTERMEDIATES (1976) (0)
Isolation of a Ketene Imine from the Decomposition of a Vinyl Azide. (1988) (0)
Triple-Bonded Functional Groups: Vol. 2 (1983) (1983) (0)
NUCLEOPHILIC ATTACKS ON CARBON‐CARBON DOUBLE BONDS PART 20, REACTION OF ACTIVE METHYLENE COMPOUNDS WITH ELECTROPHILIC OLEFINS, FORMATION OF SUBSTITUTED 2‐AMINO‐4‐CYANO‐4H‐PYRANS (1975) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 23, SUBSTITUTION OF BETA-CHLORO-ALPHA-PHENYLACRYLONITRILES (1975) (0)
Explanations and References to Table XIII (1966) (0)
Explanations and References to Table XXIX (1966) (0)
VINYLKATIONEN DURCH SOLVOLYSE (1970) (0)
Explanations and References to Table XXIV (1966) (0)
Stable Simple Enols. Part 15. Polar and Resonance Substituent Effects of α-Aryl Groups on Keto ⇌ Enol Equilibria of Stable Enols (1987) (0)
Explanations and References to Table XXIII (1966) (0)
Explanations and References to Table VIII (1966) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 22, HIGH STEREOSELECTIVITY IN THE SYNTHESIS OF AND ION PAIR RETURN IN THE SOLVOLYSIS OF (E)-ALPHA-BROMO-BETA-DEUTERIO-P-METHOXYSTYRENE (1974) (0)
Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 31. Complete and Partial Stereoconversion in Vinylic Substitution of (E)- and (Z)-β-Chloro-α-phenylcinnamaldehydes and (E)-2-Iodo-1,2-diphenyl-1-nitroethylene by Nueleophiles. (1986) (0)
Explanations and References to Table XX (1966) (0)
Nucleophilic Reactions at Vinylic Center. Part 27. Vinylic Substitution of 1,2‐Dibromo‐1,2‐difluoroethylene and Tribromofluoroethylene. An Intramolecular kBr/kF Element Effect and Apparent Inversion of Configuration in SNV Reactions. (1993) (0)
Stable Simple Enols. Part 23. Solid-State Structures of 1-Alkyl-2,2-dimesitylethenols. Application of the Principle of Structural Correlation to Ring-Flip Processes in 1,1-Diarylvinyl Systems. (1990) (0)
Foreword by the Guest Editor of this Issue (1985) (0)
Explanations and References to Table XVI (1966) (0)
Vinylic Cations from Solvolysis. Part 42. Cyclization on Methyl, Capture by Solvent and Degenerate Rearrangement of the Trimesitylvinyl Cation. (1986) (0)
Explanations and References to Table XXVI (1966) (0)
Stable Simple Enols. Part 25. Unusual Kinetic Stability of Enols to Ketonization: 1,2-Dimesityl-3-methylbut-1-en-1-ol and Related β-Alkyl-α,β-dimesitylethenols. (1990) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 18, REACTION OF 2-DICYANOMETHYLENEINDANE-1,3-DIONE WITH ANILINES IN ACETONITRILE (1973) (0)
Explanations and References to Table VI (1966) (0)
Explanations and References to Table XXVII (1966) (0)
Stable Simple Enols. Part 17. Linear Free Energy Relationship Between Keto ⇌ Enol Equilibrium Constants of Stable β,β-Dimesityl and Unstable β,β-Unsubstituted α-Substituted Enols. (1987) (0)
Additions and Corrections - Nucleophilic Attacks on Carbon-Nitrogen Double Bonds. 3. Diversity of Mechanisms for the Substitution of Diarylimidoyl Chlorides by Amines in Acetonitrile. (1977) (0)
Table I. Alkanes and Cycloalkanes (1966) (0)
Explanations and References to Table IX (1966) (0)
SOLVOLYSIS OF 1‐P‐METHOXYPHENYL‐2‐METHYLPROPEN‐1‐YL TRIFLUORACETATE AND 3,5‐DINITROBENZOATE (1975) (0)
2,2′,4,4′,6-Penta-tert-butylbenzil: An Unexpected Product in the Attempted Coupling of Tri-tert-butylbenzoyl Chloride with Magnesium—Magnesium Iodide. (1997) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 20, ION PAIRS AND FREE IONS IN THE SOLVOLYSIS AND ISOMERIZATION OF 1,2-DIANISYL-2-PHENYLVINYL HALIDES AND MESYLATES, USE OF CIS-TRANS ISOMERIZATION AS A MECHANISTIC TOOL (1975) (0)
Gas Phase Chemistry of Gold (2014) (0)
Triphenylethenethiol. Structure, Equilibria with the Thioketone, Solvation, and Association with DMSO. (1996) (0)
Explanations and References to Table IV (1966) (0)
Explanations and References to Table XXVIII (1966) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 22, BASE CATALYSIS, LEAVING GROUP EFFECTS, AND SOLVENT EFFECTS IN SEVERAL NUCLEOPHILIC VINYLIC SUBSTITUTIONS BY AMINES (1975) (0)
Additions and Corrections - Stable Simple Enols. 11. Equilibrium Constants for the 1-Alkyl-2,2-dimesitylethenol /1-Alkyl2,2-dimesitylethanone Systems in Hexane. The Predominance of Steric Effects on Kenol Values (1985) (0)
A Two-Ring Flip as the Threshold Enantiomerization Route for a Triarylvinyl Propeller. 1D and 2D NMR and Static and Dynamic Stereochemistryof Trimesitylethylene. (1987) (0)
E1CB AND E2CB MECHANISMS IN THE ELIMINATION OF TRIFLUOROETHOXIDE ION FROM ALPHA,ALPHA-DINITRO-BETA,BETA-DIPHENYL-BETA-(TRIFLUOROETHOXY)ETHANIDE ANION AND THE NON-REACTIVITY OF THE BETA-CYANO-ALPHA,ALPHA-DINITRO-BETA-,BETA-DIPHENYLETHA (1975) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 19, LOW TOSYLATE-BROMIDE REACTIVITY RATIOS IN VINYLIC SOLVOLYSES, DO K(OTS)/K(BR) RATIOS MEASURE THE POLARITY OF THE SOLVOLYTIC TRANSITION STATE (1974) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 21, SUBSTITUTION OF (E)-ALPHA-CHLORO-BETA-NITROSTYRENE BY ANILINES IN ACETONITRILE (1975) (0)
VINYLIC CATIONS FROM SOLVOLYSIS, HIGH K(CIS)/K(TRANS)-REACTIVITY RATIO IN THE SOLVOLYSIS OF ALPHA-BROMO-BETA-TERT.-BUTYL-P-METHOXY-STYRENES (1973) (0)
Explanations and References to Table II (1966) (0)
FLUORIDE ION AS A CATALYST FOR MICHAEL ADDITION TO NITRO‐ALKENES (1975) (0)
Nucleophilic Attacks on Carbon‐Carbon Double Bonds. Part 36. Stereochemistry of Substitution of Good Nucleofuges at the Stereoconvergence Region as a Tool for Investigating the Rapid Step of Nucleophilic Vinylic Substitution. (1988) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 21, SOLVENT EFFECTS ON THE EXTERNAL ION RETURN AND THE INTERNAL RETURN IN SEVERAL VINYLIC SOLVOLYSES (1975) (0)
Stable Simple Enols. Part 31. Substituted Xanthenylidene Enols. The Importance of β-Ar-C=C Conjugation in the Stabilization of Aryl- Substituted Enols (1992) (0)
Explanations and References to Table XI (1966) (0)
Explanations and References to Table XXII (1966) (0)
NUCLEOPHILIC ATTACKS ON CARBON-NITROGEN DOUBLE BONDS. PART 4. SUBSTITUTION OF N-ARYLBENZIMIDOYL CYANIDES BY AMINES IN ACETONITRILE AND BY ALKOXIDES IN ALCOHOLS (1977) (0)
Intramolecular Cyclization of Bis(2,4,6‐trialkylphenyl) Ketenes to Isochromenes. (1998) (0)
Far Infrared Vibrational Frequency Correlation Chart (1966) (0)
Reactions of substituted benzylidene Meldrum’s acids and methylthiobenzylidene Meldrum’s acids with OH–, CF3CH2O– And HOCH2CH2S– in 50% DMSO-50% water. π-Donor effects, soft acid-base interactions and transition state imbalances (2002) (0)
Explanations and References to Table III (1966) (0)
Hydrolysis of alpha-alkyl-alpha-(methylthio)methylene Meldrum's acids. A kinetic and computational investigation of steric effects. (2006) (0)
Comprar The Chemistry of Organo-Copper | Ian Fleming | 9780470772966 | Wiley (2009) (0)
VINYLIC CATIONS FROM SOLVOLYSIS PART 15, BETA-PHENYL AND BETA-P-METHOXYPHENYL REARRANGEMENT DURING THE SOLVOLYSIS OF 2,2-DIARYL-1-PHENYLVINYL BROMIDES (1973) (0)
Solvent Effects on Anchimerically Assisted Solvolyses. Part 3. Solvent Effects on the Solvolyses of (1-Arylcycloalkyl)methyl p- Toluenesulfonates. (1996) (0)
“Residual Enantiomerism” and Chromatographic Resolution of a 1,1,2-Triarylalkene (1989) (0)
NMR Investigation of the Reaction of 1,1‐Diarylethylenes with Seleninyl Chloride and Diselenium Dichloride (1971) (0)
Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 37. Thiocyanate Ion Promoted E ⇌ Z Isomerization of α-Bromo-β,β-Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS-. (1990) (0)
Explanations and References to Table X (1966) (0)
DISSOCIATIVE IONIZATION OF ARYL-SUBSTITUTED VINYL BROMIDES IN THE GAS PHASE: EXPERIMENTAL AND COMPUTATIONAL EVIDENCE FOR THE FORMATION OF STABLE α-ARYLVINYL CATIONS BOTH BY DIRECT MEANS AND BY SPONTANEOUS EXOTHERMIC ISOMERIZATION OF U (1981) (0)
Conformations of Vicinal‐Triketones (I). A Theoretical and 17O NMR Approach. (2001) (0)
Stable Aryl-Substituted Enols (2010) (0)
Explanations and References to Table XXV (1966) (0)
Explanations and References to Table XVII (1966) (0)
NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 24. NUCLEOPHILIC SUBSTITUTION OF (E)- AND (Z)-3-CHLORO-2-PHENYLPROPENONITRILES, COMMENTS ON THE WORK OF LE GUILLANTON AND CARIOU (1977) (0)
Nucleophilic Attacks on Carbon‐Carbon Double Bonds. Part 33. Approaching the Retention Region from the Stereoconvergence Region in Nucleophilic Substitution of (E)‐ and (Z)‐Methyl p‐Substituted α‐Formyland α‐(tert‐Butoxycarbonyl)‐β‐halocinnamates. (1987) (0)
Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 34. Intramolecular Element Effect in Competitive Expulsion of Two Halide Nucleofuges as a Tool for Investigating the Rapid Step of Nucleophilic Vinylic Substitution. (1988) (0)
Substituted 2‐Methylene‐1,3‐oxazolidines, ‐1,3‐thiazolidines, ‐1,3‐benzothiazines, ‐1,3‐oxazines, and Substituted Imidazopyrimidinediones from Cl(CH2)nNCO and Cl(CH2)nNCS and Active Methylene Compounds. (2007) (0)
Reactivity Trends in Condensed Benzothiophenes (1971) (0)
Explanations and References to Table XIX (1966) (0)
Explanations and References to Tavle VII (1966) (0)
Hexamethyldisilane as a Source of Both Trimethylsilyl and Pentamethyldisilyl Anions. Formation of a Substituted Pentamethyldisilyl Stable Enol. (1990) (0)
Explanations and References to Table XVIII (1966) (0)
Triflate/Mesylate Ratios and Competing C‐O and S‐O Bond Cleavages in Nucleophilic Vinylic Substitution. (1997) (0)
Aryl Exchange via Reversible Friedel-Crafts Reaction in the Synthesis of a Diarylacetic Acid. (1989) (0)

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