Richard R. Schrock
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American chemist
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Richard R. Schrockchemistry Degrees
Chemistry
#15
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#62
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#9
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Inorganic Chemistry
#3
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#3
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#2
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Chemistry
Richard R. Schrock's Degrees
- Bachelors Chemistry University of California, Riverside
Why Is Richard R. Schrock Influential?
(Suggest an Edit or Addition)According to Wikipedia, Richard Royce Schrock is an American chemist and Nobel laureate recognized for his contributions to the olefin metathesis reaction used in organic chemistry. Education Born in Berne, Indiana, Schrock went to Mission Bay High School in San Diego, California. He holds a B.A. from the University of California, Riverside and a Ph.D. from Harvard University under the direction of John A. Osborn .
Richard R. Schrock's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center (2003) (905)
- Beyond fossil fuel–driven nitrogen transformations (2018) (894)
- Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts. (2003) (878)
- Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins (1990) (720)
- Multiple metal-carbon bonds for catalytic metathesis reactions (Nobel Lecture). (2006) (675)
- High oxidation state multiple metal-carbon bonds. (2002) (533)
- Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes (1990) (506)
- Catalytic reduction of dinitrogen to ammonia at a single molybdenum center (2005) (420)
- Preparation and properties of some cationic complexes of rhodium(I) and rhodium(III) (1971) (333)
- Alkylidene complexes of niobium and tantalum (1979) (317)
- Recent advances in high oxidation state Mo and W imido alkylidene chemistry. (2009) (304)
- Catalytic Z-selective olefin cross-metathesis for natural product synthesis (2011) (290)
- Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins (1976) (282)
- .pi.-Bonded complexes of the tetraphenylborate ion with rhodium(I) and iridium(I) (1970) (265)
- Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment. (2008) (255)
- Living Ring-Opening Metathesis Polymerization of 2,3-Difunctionalized- Norbornadienes by Mo(CH-t-Bu)(N-2,6-C(6)H(3)-i-Pr(2)(O-t-Bu)(2) (1990) (251)
- Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction (1974) (236)
- Coordinatively unsaturated cationic complexes of rhodium(I), iridium(I), palladium(II), and platinum(II). Generation, synthetic utility, and some catalytic studies (1971) (224)
- Preparation and reactivity of several alkylidene complexes of the type W(CHR')(N-2,6-C6H3-iso-Pr2)(OR)2 and related tungstacyclobutane complexes. Controlling metathesis activity through the choice of alkoxide ligand (1988) (214)
- Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis (2008) (210)
- Multiple metal-carbon bonds. 8. Preparation, characterization, and mechanism of formation of the tantalum and niobium neopentylidene complexes, M(CH2CMe3)3(CHCMe3) (1978) (210)
- Catalytic asymmetric olefin metathesis. (2001) (208)
- Recent Advances in the Syntheses and Applications of Molybdenum and Tungsten Alkylidene and Alkylidyne Catalysts for the Metathesis of Alkenes and Alkynes (2007) (204)
- Synthesis of Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligand, [((t-Bu-d6)N-o-C6H4)2O]2- ([NON]2-) and the Living Polymerization of 1-Hexene by Activated [NON]ZrMe2 (1997) (200)
- Catalytic hydrogenation using cationic rhodium complexes. II. The selective hydrogenation of alkynes to cis olefins (1976) (199)
- .sigma.-Alkyl and -aryl complexes of the group 4-7 transition metals (1976) (193)
- Metathesis of acetylenes by tungsten(VI)-alkylidyne complexes (1981) (192)
- Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex. (2009) (190)
- Olefin Metathesis by Molybdenum Imido Alkylidene Catalysts (1999) (188)
- Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex. (2002) (185)
- Living ring-opening metathesis polymerization of 2,3-difunctionalized 7-oxanorbornenes and 7-oxanorbornadienes by Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(O-tert-Bu)2 and Mo(CHCMe2R)(NC6H3-iso-Pr2-2,6)(OCMe2CF3)2 (1991) (184)
- Multiple metal carbon bonds. 35. A general route to tri-tert-butoxytungsten alkylidyne complexes. Scission of acetylenes by ditungsten hexa-tert-butoxide (1985) (178)
- High-oxidation-state molybdenum and tungsten alkylidyne complexes (1986) (178)
- Further studies of imido alkylidene complexes of tungsten, well-characterized olefin metathesis catalysts with controllable activity (1990) (178)
- Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis (2011) (178)
- Conjugation length dependence of Raman scattering in a series of linear polyenes: Implications for polyacetylene (1991) (173)
- Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes. (2009) (171)
- Highly Z-selective metathesis homocoupling of terminal olefins. (2009) (164)
- Living Cyclopolymerization of 1,6-Heptadiyne Derivatives Using Well-Defined Alkylidene Complexes: Polymerization Mechanism, Polymer Structure, and Polymer Properties (1994) (162)
- Ring-opening polymerization of norbornene by a living tungsten alkylidene complex (1987) (161)
- Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes. (2005) (157)
- Multiple metal-carbon bonds. 43. Well-characterized, highly active, Lewis acid free olefin metathesis catalysts (1986) (156)
- Metathesis of tungsten-tungsten triple bonds with acetylenes and nitriles to give alkylidyne and nitrido complexes (1982) (154)
- Transition Metal Complexes That Contain a Triamidoamine Ligand (1997) (152)
- Synthesis of stereoregular polymers through ring-opening metathesis polymerization. (2014) (147)
- Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen−Mo Complex (1998) (146)
- Multiple metal-carbon bonds. 16. Tungsten-oxo alkylidene complexes as olefins metathesis catalysts and the crystal structure of W(O)(CHCMe3(PEt3)Cl2 (1980) (144)
- Synthesis of palladium and platinum nanoclusters within microphase-separated diblock copolymers (1992) (143)
- Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen. (2004) (142)
- First isolable transition metal methylene complex and analogs. Characterization, mode of decomposition, and some simple reactions (1975) (142)
- Saturation of Cubic Optical Nonlinearity in Long-Chain Polyene Oligomers (1994) (139)
- Catalytic hydrogenation using cationic rhodium complexes. 3. The selective hydrogenation of dienes to monoenes (1976) (138)
- THE ALKOXIDE LIGAND IN OLEFIN AND ACETYLENE METATHESIS REACTIONS (1995) (136)
- Ligand variation in alkylidene complexes of the type Mo(CHR)(NR′)(OR″)2 (1993) (135)
- Tungsten(VI) neopentylidyne complexes (1982) (132)
- Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. (2009) (132)
- Multiple metal-carbon bonds. 7. Preparation and characterization of Ta(.eta.5-C5H5)2(CH2)(CH3), a study of its decomposition, and some simple reactions (1978) (128)
- Recent advances in olefin metathesis by molybdenum and tungsten imido alkylidene complexes (2004) (127)
- Preparation and characterization of active niobium, tantalum and tungsten metathesis catalysts (1980) (126)
- Synthesis of chiral molybdenum ROMP initiators and all-cis highly tactic poly(2,3-(R)2norbornadiene) (R = CF3 or CO2Me) (1993) (126)
- Well-characterized olefin metathesis catalysts that contain molybdenum (1987) (123)
- Synthesis and reactions of molybdenum triamidoamine complexes containing hexaisopropylterphenyl substituents. (2003) (122)
- Multiple metal-carbon bonds. 5. The reaction of niobium and tantalum neopentylidene complexes with the carbonyl function (1976) (121)
- Rotational Isomers of Mo(VI) Alkylidene Complexes and Cis/Trans Polymer Structure: Investigations in Ring-Opening Metathesis Polymerization (1993) (118)
- Surface versus molecular siloxy ligands in well-defined olefin metathesis catalysts: [{(RO)3SiO}Mo(=NAr)(=CHtBu)(CH2tBu)]. (2006) (118)
- Preparation of trialkoxymolybdenum(VI) alkylidyne complexes, their reactions with acetylenes, and the X-ray structure of Mo[C3(CMe3)2][OCH(CF3)2]2(C5H5N)21 (1985) (117)
- Synthesis of stereoregular ROMP polymers using molybdenum and tungsten imido alkylidene initiators. (2011) (117)
- A well-defined, silica-supported tungsten imido alkylidene olefin metathesis catalyst (2006) (116)
- Synthesis of silver and gold nanoclusters within microphase-separated diblock copolymers (1992) (115)
- Polymerization of functionalized norbornenes employing Mo(CH-t-Bu)(NAr)(O-t-Bu)2 as the initiator (1990) (113)
- Multiple metal-carbon bonds. 12. Tungsten and molybdenum neopentylidyne and some tungsten neopentylidene complexes (1978) (113)
- Simple, high yield syntheses of molybdenum(VI) bis(imido) complexes of the type Mo(NR)2Cl2(1,2-dimethoxyethane) (1992) (111)
- Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(IV) nitride. (2012) (110)
- Phosphinidenetantalum(V) Complexes of the Type [(N3N)TaPR] as Phospha‐Wittig Reagents (1993) (110)
- Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis (2016) (109)
- Synthesis of cis,syndiotactic ROMP polymers containing alternating enantiomers. (2011) (108)
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing Metathesis (1998) (108)
- Polymerization of Enantiomerically Pure 2,3-Dicarboalkoxynorbornadienes and 5,6-Disubstituted Norbornenes by Well-Characterized Molybdenum Ring-Opening Metathesis Polymerization Initiators. Direct Determination of Tacticity in Cis, Highly Tactic and Trans, Highly Tactic Polymers (1994) (107)
- Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes. (2017) (107)
- Preparation and catalytic properties of some cationic iridium(III) and rhodium(III) dihydrido complexes (1969) (106)
- Preparation of tert-butyl-capped polyenes containing up to 15 double bonds (1989) (106)
- Preparation and characterization of tantalum(III) olefin complexes and tantalum(V) metallacyclopentane complexes made from acyclic .alpha. olefins (1979) (102)
- CHIRAL MO-BINOL COMPLEXES : ACTIVITY, SYNTHESIS, AND STRUCTURE. EFFICIENT ENANTIOSELECTIVE SIX-MEMBERED RING SYNTHESIS THROUGH CATALYTIC METATHESIS (1999) (101)
- Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum. (2009) (101)
- Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes. (2011) (100)
- 31. Tetragtdrfuran Complexes of Selected Early Transition Metals. (2007) (100)
- Living cyclopolymerization of diethyl dipropargylmalonate by Mo(CH-t-Bu)(NAr)[OCMe(CF3)2]2 in dimethoxyethane (1992) (97)
- On the trail of metathesis catalysts (1986) (97)
- Preparation and reactions of tantalum alkylidene complexes containing bulky phenoxide or thiolate ligands. Controlling ring-opening metathesis polymerization activity and mechanism through choice of anionic ligand (1988) (96)
- Fabrication of Quantum Dot/Polymer Composites: Phosphine-Functionalized Block Copolymers as Passivating Hosts for Cadmium Selenide Nanoclusters (1997) (95)
- Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A. (2013) (94)
- Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis. (2013) (92)
- Preparation and characterization of M(CH3)5 (M = Nb or Ta) and Ta(CH2C6H5)5 and evidence for decomposition by α-hydrogen atom abstraction (1976) (91)
- Molybdenum chloride catalysts for Z-selective olefin metathesis reactions (2017) (91)
- Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by MonoAryloxidePyrrolide (MAP) Catalysts. (2010) (90)
- Reduction of dinitrogen (2006) (90)
- High oxidation state alkylidene and alkylidyne complexes. (2005) (88)
- Living Polymerization of (o-(Trimethylsilyl)phenyl)acetylene by Molybdenum Imido Alkylidene Complexes (1996) (87)
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis (2000) (87)
- A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis. (2001) (87)
- Composite thin films of CdSe nanocrystals and a surface passivating/electron transporting block copolymer: Correlations between film microstructure by transmission electron microscopy and electroluminescence (1999) (87)
- Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations. (2008) (86)
- Fabrication of Quantum Dot-Polymer Composites: Semiconductor Nanoclusters in Dual-Function Polymer Matrices with Electron-Transporting and Cluster-Passivating Properties (1997) (86)
- Structure of bis(cyclopentadienyl)methylmethylenetantalum and the estimated barrier to rotation about the tantalum-methylene bond (1975) (85)
- Synthesis of five- and six-coordinate alkylidene complexes of the type Mo(CHR)(NAr)[OCMe(CF3)2]2Sx and their use as living ROMP initiators or Wittig reagents (1993) (85)
- Multiple metal-carbon bonds. 13. Preparation and characterization of monocyclopentadienyl mononeopentylidene complexes of niobium and tantalum including the first details of an .alpha.-abstraction process (1979) (84)
- Reaction of tungsten(VI) alkylidyne complexes with acetylenes to give tungstenacyclobutadiene and cyclopentadienyl complexes (1982) (83)
- Synthesis of Terminal Vanadium(V) Imido, Oxo, Sulfido, Selenido, and Tellurido Complexes by Imido Group or Chalcogenide Atom Transfer to Trigonal Monopyramidal V[N3N] (N3N = [(Me3SiNCH2CH2)3N]3-) (1994) (83)
- Preparation of Biscarboxylato Imido Alkylidene Complexes of Molybdenum and Cyclopolymerization of Diethyldipropargylmalonate To Give a Polyene Containing only Six-Membered Rings (1996) (83)
- Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts. (2011) (82)
- Synthesis of single silver nanoclusters within spherical microdomains in block copolymer films (1992) (82)
- Rhodium catalysts for the homogeneous hydrogenation of ketones (1970) (81)
- Multiple metal-carbon bonds. 34. Metathesis of acetylenes by molybdenum(VI) alkylidyne complexes (1984) (81)
- Isolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures. (2011) (80)
- Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2- ([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2- ([CyNON]2-) (1999) (80)
- Preparation of sugar-coated homopolymers and multiblock ROMP copolymers (1996) (79)
- Kinetically controlled E-selective catalytic olefin metathesis (2016) (79)
- Synthesis of zinc sulfide and cadmium sulfide within ROMP block copolymer microdomains (1992) (78)
- Tantalum carbyne complex (1975) (78)
- Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis. (2009) (78)
- Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes. (2012) (78)
- Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis. (2005) (78)
- Planar 20-electron osmium imido complexes. A linear imido ligand does not necessarily donate its lone pair of electrons to the metal (1990) (78)
- Synthesis of Polyenes That Contain Metallocenes via the Living Polymerization of Ethynylferrocene and Ethynylruthenocene (1995) (77)
- Synthetic and Mechanistic Investigations of Trimethylsilyl-Substituted Triamidoamine Complexes of Tantalum That Contain Metal−Ligand Multiple Bonds (1996) (77)
- Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. (2006) (76)
- Transition metal–carbon multiple bonds (2001) (76)
- Efficient catalytic enantioselective synthesis of unsaturated amines: preparation of small- and medium-ring cyclic amines through mo-catalyzed asymmetric ring-closing metathesis in the absence of solvent. (2002) (75)
- Osmium imido complexes: synthesis, reactivity, and SCF-X.alpha.-SW electronic structure (1991) (75)
- Synthesis of group 4 complexes that contain the diamidoamine ligands, [(2,4,6-Me{sub 3}C{sub 6}H{sub 2}NCH{sub 2}CH{sub 2}){sub 2}NR]{sup 2{minus}} ([Mes{sub 2}N{sub 2}NR]{sup 2{minus}}; R = H or CH{sub 3}), and polymerization of 1-hexene by activated [Mes{sub 2}N{sub 2}NR]ZrMe{sub 2} complexes (1999) (75)
- Formation of cyclopentadienyl complexes from tungstenacyclobutadiene complexes and the x-ray crystal structure of an .eta.3-cyclopropenyl complex, W[C(CMe3)C(Me)C(Me)](Me2NCH2CH2NMe2)Cl3 (1984) (75)
- Catalytic asymmetric ring-opening metathesis/cross metathesis (AROM/CM) reactions. Mechanism and application to enantioselective synthesis of functionalized cyclopentanes. (2001) (75)
- High-oxidation-state pentamethylcyclopentadienyl tungsten hydrazine and hydrazido complexes and cleavage of the nitrogen-nitrogen bond (1993) (74)
- Highly active, stable, and selective well-defined silica supported mo imido olefin metathesis catalysts. (2007) (73)
- Small PbS clusters prepared via ROMP block copolymer technology (1990) (73)
- Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum (1994) (72)
- Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts. (2006) (71)
- Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst (2008) (70)
- MONOADDUCTS OF IMIDO ALKYLIDENE COMPLEXES, SYN AND ANTI ROTAMERS, AND ALKYLIDENE LIGAND ROTATION (1991) (70)
- Synthesis of zinc sulfide clusters and zinc particles within microphase-separated domains of organometallic block copolymers (1993) (70)
- Efficient enantioselective synthesis of piperidines through catalytic asymmetric ring-opening/cross-metathesis reactions. (2007) (70)
- Multiple metal-carbon bonds. 34. Why terminal alkynes cannot be metathesized. Preparation and crystal structure of a deprotonated tungstacyclobutadiene complex, W(.eta.5-C5H5)[C3(CMe3)2]Cl (1983) (70)
- Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis. (2013) (69)
- Selective dimerization of monosubstituted .alpha.-olefins by tantalacyclopentane catalysts (1980) (69)
- Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes. (2009) (69)
- Synthesis of side-chain liquid crystal polymers by living ring-opening metathesis polymerization. 3. Influence of molecular weight, interconnecting unit, and substituent on the mesomorphic behavior of polymers with laterally attached mesogens (1992) (68)
- Multiple metal-carbon bonds. 19. How niobium and tantalum complexes of the type M(CHCMe3)(PR3)2Cl3 can be modified to give olefin metathesis catalysts (1981) (67)
- A well-defined rhenium(VII) olefin metathesis catalyst (1990) (67)
- Multiple metal-carbon bonds. 27. Preparation of tungsten(VI) phenylimido alkyl and alkylidene complexes (1982) (67)
- Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N] (1992) (66)
- Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations. (2003) (66)
- Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR')(OR'')(pyrrolyl): enyne metathesis with high oxidation state catalysts. (2007) (66)
- Rate of interconversion of syn and anti rotamers of Mo(CHCMe2Ph)(NAr)(OR)2 and relative reactivity toward 2,3-bis(trifluoromethyl)norbornadiene (1992) (66)
- Olefin Metathesis by Well-Defined Complexes of Molybdenum and Tungsten (1998) (66)
- Acetylene metathesis by tungsten(VI) alkylidyne complexes (1982) (66)
- Catalytic reduction of dinitrogen under mild conditions. (2003) (66)
- Dramatic improvements of well-defined silica supported Mo-based olefin metathesis catalysts by tuning the N-containing ligands. (2007) (65)
- Synthesis and characterization of tungsten oxo neopentylidene complexes (1982) (64)
- Multiple metal-carbon bonds. 32. Rhenium(VII) neopentylidene and neopentylidyne complexes and the x-ray structure of Re(CCMe3)(CHCMe3)(C5H5N)2 (1983) (64)
- Ring Opening Metathesis Polymerization with Binaphtholate or Biphenolate Complexes of Molybdenum (1996) (64)
- SYNTHESIS OF STAR BLOCK COPOLYMERS BY CONTROLLED RING-OPENING METATHESIS POLYMERIZATION (1991) (64)
- Mo-catalyzed asymmetric olefin metathesis in target-oriented synthesis: enantioselective synthesis of (+)-africanol. (2004) (64)
- A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst. (2013) (63)
- Z-selective metathesis homocoupling of 1,3-dienes by molybdenum and tungsten monoaryloxide pyrrolide (MAP) complexes. (2012) (63)
- Synthesis of Side Chain Liquid Crystal Polymers by Living Ring Opening Metathesis Polymerization. 1. Influence of Molecular Weight, Polydispersity, and Flexible Spacer Length (n=2-8) on the Thermotropic behavior of the Resulting Polymers (1992) (63)
- Trigonal-Monopyramidal MIII Complexes of the Type [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N)† (1992) (62)
- Fundamental studies of tungsten alkylidene imido monoalkoxidepyrrolide complexes. (2009) (62)
- The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis (2002) (62)
- Alkyne metathesis by molybdenum and tungsten alkylidyne complexes. (2013) (62)
- Living polymerization of 2-butyne using a well-characterized tantalum catalyst (1989) (61)
- Synthesis and characterization of rhenium(VII) alkylidene alkylidyne complexes of the type Re(CR')(CHR')(OR)2 and related species (1992) (61)
- Preparation of organoimido and .mu.-dinitrogen complexes of tantalum and niobium from neopentylidene complexes (1982) (61)
- Enantioselective synthesis of medium-ring heterocycles, tertiary ethers, and tertiary alcohols by Mo-catalyzed ring-closing metathesis. (2002) (61)
- Synthesis of Molybdenum Imido Alkylidene Complexes That Contain 3,3‘-Dialkyl-5,5‘,6,6‘-tetramethyl-1,1‘-biphenyl-2,2‘-diolates (Alkyl = t-Bu, Adamantyl). Catalysts for Enantioselective Olefin Metathesis Reactions (2000) (61)
- Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates. (2007) (61)
- Multiple metal-carbon bonds. 41. Wittig-like reactions of tungsten alkylidyne complexes (1986) (61)
- Exploring Factors That Determine Cis/Trans Structure and Tacticity in Polymers Prepared by Ring-Opening Metathesis Polymerizations with Initiators of the Type syn- and anti-Mo(NAr)(CHCMe2Ph)(OR)2. Observation of a Temperature-Dependent Cis/Trans Ratio (1995) (61)
- Controlled ring-opening metathesis polymerization by molybdenum and tungsten alkylidene complexes (1988) (61)
- Multiple metal-carbon bonds. 9. Preparation and characterization of several alkylidene complexes, M(.eta.5-C5H5)2(alkylidene)X (M = tantalum or niobium), and the x-ray structure of Ta(.eta.5-C5H5)2(CHC6H5)(CH2C6H5). An investigation of alkylidene ligand rotation (1978) (60)
- The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry (2014) (60)
- Metallacyclopentane to metallacyclobutane ring contraction (1979) (60)
- Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles. (2002) (59)
- Enantioselective synthesis of cyclic secondary amines through Mo-catalyzed asymmetric ring-closing metathesis (ARCM). (2003) (59)
- Reaction of neopentylidene complexes of the type M(CH-t-Bu)(N-2,6-C6H3-i-Pr2)(OR)2 (M = W, Mo) with methyl acrylate and N,N-dimethylacrylamide to give metallacyclobutane complexes (1989) (58)
- Triamidoamine Complexes of Molybdenum and Tungsten That Contain Metal−E (E = N, P, and As) Single, Double, or Triple Bonds (1997) (58)
- Monomeric Molybdenum and Tungsten Complexes That Contain a Metal–Phosphorus Triple Bond (1995) (58)
- Synthesis of Group 4 Organometallic Complexes That Contain the Bis(borylamide) Ligand [Mes2BNCH2CH2NBMes2]2- (1996) (57)
- Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles. (2007) (57)
- Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2- and an Evaluation of Activated Versions for the Polymerization of 1-Hexene (1999) (56)
- Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis (2009) (56)
- Ring-opening polymerization of norbornene by a tantalum catalyst: a living polymerization (1987) (56)
- Living Polymerization of (o-(Trimethylsilyl)phenyl)acetylene Using "Small Alkoxide" Molybdenum(VI) Initiators (1994) (55)
- Multiple metal-carbon bonds. 15. Octahedral alkylidene complexes of niobium and tantalum by ligand-promoted .alpha. abstraction (1980) (55)
- Preparation and reactivity of tungsten(VI) metallacyclobutane complexes. Square pyramids versus trigonal bipyramids (1990) (55)
- Rapid selective dimerization of ethylene to 1-butene by a tantalum catalyst and a new mechanism for ethylene oligomerization (1979) (55)
- Low polydispersity homopolymers and block copolymers by ring opening of 5,6-dicarbomethoxynorbornene (1987) (55)
- Kinetically E-Selective Macrocyclic Ring-Closing Metathesis (2016) (55)
- Synthesis of Tungsten Oxo Alkylidene Complexes (2012) (54)
- Synthesis of molybdenum complexes that contain "hybrid" triamidoamine ligands, [(hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and studies relevant to catalytic reduction of dinitrogen. (2006) (54)
- Pentamethyl complexes of niobium and tantalum (1974) (54)
- Synthesis of amphiphilic star block copolymers using ring-opening metathesis polymerization (1992) (54)
- Nonlinear optical analysis of a series of triblock copolymers containing model polyenes: the dependence of hyperpolarizability on conjugation length (1993) (54)
- Well-Defined Redox-Active Polymers and Block Copolymers Prepared by Living Ring-Opening Metathesis Polymerization (1992) (54)
- Synthesis and reactions of tungsten(IV) bis(imido) complexes: relatives of bent metallocenes (1990) (54)
- Stereospecific Ring-Opening Metathesis Polymerization (ROMP) of endo-Dicyclopentadiene by Molybdenum and Tungsten Catalysts (2015) (54)
- Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1 (2014) (53)
- Multiple metal carbon bonds. Part 29. Facile conversion of tungsten(VI) neopentylidyne complexes into oxo and imido neopentylidene complexes and the crystal structure of W(CCMe3)(PHPh)(PEt3)2Cl2 (1982) (53)
- Synthesis of Molybdenum Complexes That Contain Silylated Triamidoamine Ligands. A .mu.-Dinitrogen Complex, Methyl and Acetylide Complexes, and Coupling of Acetylides (1994) (53)
- Unusual 31P Chemical Shielding Tensors in Terminal Phosphido Complexes Containing a Phosphorus−Metal Triple Bond (1996) (53)
- Supported chiral Mo-based complexes as efficient catalysts for enantioselective olefin metathesis. (2004) (53)
- Preparation of polycyclooctyne by ring-opening polymerization employing d0 tungsten and molybdenum alkylidyne complexes (1989) (52)
- PREPARATION OF OCTACHLORODITUNGSTATE(4-) AND SEVERAL OF ITS DERIVATIVES (1983) (52)
- Multiple metalcarbon bonds (1979) (52)
- Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis (2017) (52)
- Fundamental Studies of Molybdenum and Tungsten Methylidene and Metallacyclobutane Complexes (2010) (52)
- A New Type of Blue-Light-Emitting Electroluminescent Polymer (1995) (52)
- A Comparison of Cationic Zirconium Methyl and Isobutyl Initiators that Contain an Arylated Diamido-Pyridine Ligand for Polymerization of 1-Hexene. Elucidation of a Dramatic “Initiator Effect” (2000) (52)
- Synthesis of d2 complexes that contain tungsten [W(NAr)2] and rhenium [Re(NAr)2] cores, SCF-X.alpha.-SW calculations, and a discussion of the MCp2/M'(NR)2 isolobal relationship (1993) (52)
- Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide. (2014) (51)
- CH Bond Activation in Cations of the Type {[(2,4,6-Me3C6H2NCH2CH2)2NMe]ZrR}+ and a Simple Solution that Yields a Catalyst for the Living Polymerization of 1-Hexene (2001) (51)
- Catalysis by Transition Metals: Metal-Carbon Double and Triple Bonds (1983) (51)
- Cleavage of the nitrogen-nitrogen bond in a high oxidation state tungsten or molybdenum hydrazine complex and the catalytic reduction of hydrazine (1991) (51)
- Selective olefin dimerization via tantallocyclopentane complexes (1978) (51)
- The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes. (2009) (51)
- Well-defined silica-supported Mo-alkylidene catalyst precursors containing one or substituent: methods of preparation and structure-reactivity relationship in alkene metathesis. (2009) (51)
- Recent advances in the chemistry and applications of high oxidation state alkylidene complexes (1994) (51)
- Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis. (2006) (50)
- Z-selective ring-opening metathesis polymerization of 3-substituted cyclooctenes by monoaryloxide pyrrolide imido alkylidene (MAP) catalysts of molybdenum and Tungsten (2013) (50)
- Stable polarons in polyacetylene oligomers: optical spectra of long polyene radical cations (1992) (50)
- Electroluminescence from New Polynorbornenes That Contain Blue-Light-Emitting and Charge-Transport Side Chains (1997) (50)
- Reduction of molybdenum imido-alkylidene complexes in the presence of olefins to give molybdenum(IV) complexes (1991) (50)
- Multiple metal-carbon bonds. 26. .alpha.-Hydride elimination from methylene and neopentylidene ligands. Preparation and protonation of tungsten(IV) methylidyne and neopentylidyne complexes (1982) (50)
- Direct polymerization of acetylene to give living polyenes (1989) (50)
- Rational Design of Highly Active “Hybrid” Phosphine–Phosphinite Pincer Iridium Catalysts for Alkane Metathesis (2013) (49)
- Stereospecific Ring-Opening Metathesis Polymerization (ROMP) of Norbornene and Tetracyclododecene by Mo and W Initiators (2015) (49)
- Simple routes to mono(.eta.5-pentamethylcyclopentadienyl) complexes of molybdenum(V) and tungsten(V) (1985) (49)
- A MOLECULE CONTAINING THE OWOWO UNIT. SYNTHESIS, STRUCTURE AND SPECTROSCOPY OF HEXANEOPENTYLDITUNGSTEN TRIOXIDE (1985) (49)
- Living Ring-Opening Metathesis Polymerization of Cyclopropenes (2006) (49)
- Five-Coordinate Rearrangements of Metallacyclobutane Intermediates during Ring-Opening Metathesis Polymerization of 2,3-Dicarboalkoxynorbornenes by Molybdenum and Tungsten Monoalkoxide Pyrrolide Initiators (2012) (49)
- Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene. (2016) (49)
- Multiple metal-carbon bonds. 17. Preparation of monocyclopentadienyl benzylidene complexes of tantalum and the crystal structure of Ta(.eta.5-C5Me5)(CHPh)(CH2Ph)2 (1980) (49)
- Preparation and characterization of two high oxidation state molybdenum dinitrogen complexes: [MoCp*Me3]2(.mu.-N2) and [MoCp*Me3](.mu.-N2)[WCp'Me3] (1990) (48)
- An enantiomerically pure adamantylimido molybdenum alkylidene complex. An effective new catalyst for enantioselective olefin metathesis. (2003) (48)
- Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis (2014) (48)
- Low-temperature neutron diffraction studies of C-H-metal interactions in two tantalum-neopentylidene complexes: (Ta(CHCMe/sub 3/)(PMe/sub 3/)Cl/sub 3/)/sub 2/ (T = 110 K) and the first alkylidene/olefin complex, Ta(eta/sup 5/-C/sub 5/Me/sub 5/)(CHCMe/sub 3/)(eta/sup 2/-C/sub 2/H/sub 4/)(PMe/sub 3/) (1981) (48)
- SYNTHESIS OF MONOMERIC NIOBIUM- AND TANTALUM-BENZYNE COMPLEXES AND THE MOLECULAR STRUCTURE OF TA(η5-C5ME5)(C6H4)ME2 (1979) (47)
- Multiple metal-carbon bonds. 10. Thermally stable tantalum alkylidyne complexes and the crystal structure of Ta(.eta.5-C5Me5)(CPh)(PMe3)2Cl (1978) (47)
- Preparation of polyacetylene chains in low-polydispersity diblock and triblock copolymers (1988) (47)
- Sulfonation and Epoxidation of Substituted Polynorbornenes and Construction of Light-Emitting Devices (1999) (47)
- Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis. (2013) (47)
- Metathetical reactions of rhenium(VII) alkylidene-alkylidyne complexes of the type Re(CR')(CHR')[OCMe(CF3)2]2 (R' = CMe3 or CMe2Ph) with terminal and internal olefins (1993) (47)
- Multiple metal-carbon bonds. 33. Some reactions of tungsten methylidyne complexes and the crystal structure of [W2(CPMe3)2(PMe3)4Cl4][AlCl4]2 (1984) (47)
- Synthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen. (2010) (46)
- Derivatization of Dinitrogen by Molybdenum in Triamidoamine Complexes (1998) (46)
- Multiple metal-carbon bonds. 6. The reaction of niobium and tantalum neopentylidene complexes with simple olefins: a route to metallocyclopentanes (1977) (46)
- Preparation of Well-Defined, Metathetically Active Oxo Alkylidene Complexes of Tungsten (1996) (45)
- Neutral and Cationic Group 4 Complexes Containing Bis(borylamide) Ligands, [R2BNCH2CH2NBR2]2- (R = 2,4,6-i-Pr3C6H2, M = Zr; R = Cyclohexyl, M = Ti, Zr, Hf) (1998) (45)
- Synthesis of side chain liquid crystal polymers by living ring-opening metathesis polymerization. 4. Synthesis of AB block copolymers containing amorphous and side chain liquid crystal blocks (1993) (45)
- Soluble, Highly Conjugated Polyenes via the Molybdenum-Catalyzed Copolymerization of Acetylene and Diethyl Dipropargylmalonate (1996) (45)
- RHENIUM(VII) MONOIMIDO ALKYLIDYNE COMPLEXES. THE IMPORTANCE OF FACE SELECTIVITY IN THE METATHESIS OF ACETYLENES VIA RHENACYCLOBUTADIENE INTERMEDIATES (1991) (45)
- Synthesis of triamidoamine ligands of the type (ArylNHCH(2)CH(2))(3)N and molybdenum and tungsten complexes that contain an [ArylNCH(2)CH(2))(3)N]3- ligand. (2001) (45)
- Synthesis and characterization of diblock copolymer films containing self-assembled polyacetylene structures (1991) (45)
- Alkylidene hydride complexes of tantalum and the polymerization of ethylene by diiodotris(trimethylphosphine)hydroneopentylidenetantalum [Ta(CHCMe3)(H)(PMe3)3I2] (1983) (44)
- Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum. (2009) (44)
- Preparation and reactions of [ZrCl3(PR3)2]2 (R = ethyl, propyl, butyl) and the x-ray structure of [ZrCl3(PBu3)2]2 (1981) (44)
- Catalytic Z-selective cross-metathesis with secondary silyl- and benzyl-protected allylic ethers: mechanistic aspects and applications to natural product synthesis. (2013) (44)
- Tantalum imido complexes (1980) (44)
- Third-order microscopic nonlinearities of very long chain polyenes: saturation phenomena and conformational effects (1999) (44)
- Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)). (2010) (44)
- Synthesis and Decomposition of Alkyl Complexes of Molybdenum(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand. Direct Detection of α-Elimination Processes That Are More than Six Orders of Magnitude Faster than β-Elimination Processes (1997) (43)
- Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia. (2010) (43)
- Preparation and Activation of Complexes of the Type [((mesityl)NCH2CH2)2NX]ZrMe2 (X = H, Me) with [Ph3C][B(C6F5)4] or [PhNMe2H][B(C6F5)4] (2000) (43)
- Evaluation of cyclopentene-based chain-transfer agents for living ring-opening metathesis polymerization (1989) (42)
- Surface attachment of well-defined redox-active polymers and block polymers via terminal functional groups (1993) (42)
- Synthesis of [(HIPTNCH2CH2)3N]V compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of vanadium for the reduction of dinitrogen to ammonia. (2006) (42)
- High oxidation state monopentamethylcyclopentadienyltungsten methyl complexes including the first d0 complex containing a highly distorted methylene ligand, W(.eta.5-C5Me5)(CH3)3(CH2) (1987) (42)
- Synthesis, structure, and electrochemical studies of molybdenum and tungsten dinitrogen, diazenido, and hydrazido complexes that contain aryl-substituted triamidoamine ligands. (2001) (42)
- Cationic hafnium alkyl complexes that are stable toward beta-hydride elimination below 10 degrees C and active as initiators for the living polymerization of 1-hexene. (2001) (42)
- Living polymerization of 1-hexene by cationic zirconium and hafnium complexes that contain a diamido/donor ligand of the type [H3CC(2-C5H4N)(CH2NMesityl)2]2-. A comparison of methyl and isobutyl initiators (2003) (42)
- Recent advances in the chemistry of d0 alkylidene and metallacyclobutane complexes (2007) (41)
- Multiple metal-carbon bonds. 11. bisneopentylidene complexes of niobium and tantalum (1978) (41)
- Synthesis of tungsten complexes that contain hexaisopropylterphenyl-substituted triamidoamine ligands, and reactions relevant to the reduction of dinitrogen to ammonia (2005) (41)
- Interconversion of ZnF2 and ZnS nanoclusters within spherical microdomains in block copolymer films (1993) (41)
- Bulky aryloxide ligand stabilizes a heterogeneous metathesis catalyst. (2014) (41)
- Synthesis and reactivity of a series of analogous rhenium tris(imido), bis(imido) alkyne, and imido bis(alkyne) complexes (1993) (41)
- Multiple metal-carbon bonds. 37. Preparation of di-tert-butoxytungsten(VI) alkylidene complexes by protonation of tri-tert-butoxytungsten(VI) alkylidyne complexes (1985) (41)
- Synthesis of a class of complexes containing tungsten-tungsten quadruple bonds (1980) (40)
- Synthesis of Group 4 Complexes That Contain the Tridentate Diamido/Donor Ligands [(ArylNCH2CH2)2O]2- and Zirconium Complexes That Contain [(ArylNCH2CH2)2S]2- and an Evaluation of Their Activity for the Polymerization of 1-Hexene (1998) (40)
- Multiple metal-carbon bonds. 42. Formation of tungstenacyclobutadiene complexes containing a proton in the ring and their conversion to deprotio tungstenacyclobutadiene complexes (1986) (40)
- Trigonal-bipyramidal and square-pyramidal tungstacyclobutane intermediates are both present in systems in which olefins are metathesized by complexes of the type W(CHR')(N-2,6-C6H3-iso-Pr2)(OR)2 (1989) (40)
- New Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3‘-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands (2002) (40)
- Zirconium and Hafnium Complexes that Contain the Electron-Withdrawing Diamido/Donor Ligands [(2,6-X2C6H3NCH2)2C(2-C5H4N)(CH3)]2- (X = Cl or F). An Evaluation of the Role of Ortho Halides in 1-Hexene Polymerization (2003) (40)
- Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin) (2010) (39)
- Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen. (2009) (39)
- Modular Mo-based catalysts for efficient asymmetric olefin metathesis. Catalytic enantioselective synthesis of cyclic ethers and acetals (2000) (39)
- Stereospecific ring-opening metathesis polymerization of norbornadienes employing tungsten oxo alkylidene initiators. (2014) (39)
- Synthesis of Zirconium Complexes Containing the Tridentate Diamido Ligands [(t-Bu-d6-N-o-C6H4)2S]2- and [(i-PrN-o-C6H4)2S]2- (1999) (39)
- Investigations of reactions between chiral molybdenum imido alkylidene complexes and ethylene: Observation of unsolvated base-free methylene complexes, metalacyclobutane and metalacyclopentane complexes, and molybdenum(IV) olefin complexes (2004) (39)
- Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction evidence for an activated carbon-hydrogen bond in an electron-deficient tantalum-neopentylidene complex (1979) (39)
- Tantalum complexes containing diimido bridging dinitrogen ligands (1980) (39)
- Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex (1994) (39)
- Synthesis and Side Chain Liquid Crystal Polymers by Living Ring Opening Metathesis Polymerization. 5. Influence of Mesogenic Group and Interconnecting Group on the Thermotropic Behavior of the Resulting Polymers (1993) (39)
- Coupling of terminal olefins by molybdenum(VI) imido alkylidene complexes (1994) (38)
- .alpha.-Elimination Can Be Faster than .beta.-Elimination in d2 Alkyl Complexes of Molybdenum and Tungsten That Contain the Trimethylsilyl-Substituted Triamidoamine Ligand (1995) (38)
- Formation of High-Oxidation-State Metal–Carbon Double Bonds (2017) (38)
- Formation of dimers that contain unbridged W(IV)/W(IV) double bonds. (2004) (38)
- Multiple metal-carbon bonds. 20. Tungsten methylidyne complexes (1981) (38)
- A One-Pot Tandem Olefin Isomerization/Metathesis-Coupling (ISOMET) Reaction (2014) (37)
- Aqueous tungsten(VI) alkyl chemistry (1983) (37)
- Heterobimetallic Dinitrogen Complexes That Contain the {[N3N]Mo−NN}- Ligand (1999) (37)
- E- and Z-, Di-, and trisubstituted alkenyl nitriles through catalytic cross-metathesis (2019) (37)
- Tungsten Oxo Alkylidene Complexes as Initiators for the Stereoregular Polymerization of 2,3-Dicarbomethoxynorbornadiene (2014) (36)
- .alpha.-Hydride vs. .beta.-hydride elimination. An example of an equilibrium between two tautomers (1982) (36)
- Preparation of rhenium(VII) monoimido alkylidyne complexes and metathesis of acetylenes via rhenacyclobutadiene intermediates (1988) (36)
- Multiple metal-carbon bonds. 36. Metathesis of molybdenum-molybdenum triple bonds with acetylenes to give alkylidyne complexes (1984) (36)
- “Fixation” of Dinitrogen by Molybdenum and the Formation of a Trigonal Planar Iron−Tris[molybdenum(dinitrogen)] Complex (1997) (36)
- Thiolato dinitrogen (or hydrazido(4-)) complexes, [Ta(SAr)3(THF)]2(.mu.-N2) (Ar = 2,6-C6H3-iso-Pr2, 2,4,6-C6H2-iso-Pr3), and phenoxide analogs. A structural comparison of [Ta(S-2,6-C6H3-iso-Pr2)3(THF)]2(.mu.-N2), and [Ta(O-2,6-C6H3-iso-Pr2)3(THF)]2(.mu.-N2) (1988) (36)
- Evaluation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts for Asymmetric Olefin Metathesis Reactions that Contain 3,3‘-Diphenyl- or 3,3‘-Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of Unsubstituted Molybdacyclobutane Complexes (2001) (35)
- Synthesis and reactivity of two monomeric tungsten(IV) phenoxide complexes (1988) (35)
- Synthesis and Decomposition of Alkyl Complexes of Tungsten(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand (1997) (35)
- Facile Synthesis of a Tungsten Alkylidyne Catalyst for Alkyne Metathesis (2007) (35)
- Optical spectroscopy of long polyenes (2004) (35)
- Preparation and isolation of polyenes containing up to 15 double bonds (1988) (35)
- A study of high-oxidation-state complexes of the type [W(.eta.5-C5Me5)Me2X]2(.mu.-N2), including x-ray structures of [W(.eta.5-C5Me5)Me2(OC6F5)]2(.mu.-N2) and [W(.eta.5-C5Me5)Me2(S-2,4,6-C6H2Me3)]2(.mu.-N2) (1990) (34)
- Reaction of carbon monoxide with (.eta.5-pentamethylcyclopentadienyl)tetramethyltantalum. Intramolecular reductive coupling of carbon monoxide via an ".eta.2-acetone" intermediate (1979) (34)
- .alpha.-Hydride elimination: the first observable equilibriums between alkylidene complexes and alkylidyne hydride complexes (1982) (33)
- Preparation of tantalum .mu.-dinitrogen complexes from molecular nitrogen and reduced tantalum complexes (1982) (33)
- Ring-opening polymerization of cyclooctyne (1987) (33)
- Multiple metal-carbon bonds. 25. Preparation and structure of tungsten neopentylidene hydride, neopentylidene carbonyl, and neopentylidene ethylene complexes (1982) (33)
- Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes (2008) (33)
- SYNTHESIS OF NORBORNENES CONTAINING TIN(II), TIN(IV), LEAD(II), AND ZINC(II) AND THEIR POLYMERIZATION TO GIVE MICROPHASE-SEPARATED BLOCK COPOLYMERS (1991) (33)
- An electrochemical investigation of intermediates and processes involved in the catalytic reduction of dinitrogen by [HIPTN3N]Mo (HIPTN3N = (3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2)3N). (2012) (33)
- Electronic Structure of Mo(VI) Alkylidene Complexes and an Examination of Reactive Intermediates Using the SCF-X.alpha.-SW Method (1994) (33)
- B(C6F5)3 Activation of Oxo Tungsten Complexes That Are Relevant to Olefin Metathesis (2013) (33)
- Ultrafast excited state relaxation in long-chain polyenes (2010) (33)
- TRIGONAL-BIPYRAMIDAL BIS(NEOPENTYLIDENE), NEOPENTYLIDENE/ETHYLENE, AND BIS(ETHYLENE) COMPLEXES OF TANTALUM AND HOW THEY REACT WITH ETHYLENE. A CATALYST FOR RAPIDLY DIMERIZING ETHYLENE TO 1-BUTENE (1981) (32)
- Dimers that Contain Unbridged W(IV)/W(IV) Double Bonds (2006) (32)
- Ring Opening Metathesis Polymerization (1992) (32)
- Synthesis of PbS nanoclusters within microphase-separated diblock copolymer films (1994) (32)
- Polymerization of ethylene by an alkylidene hydride catalyst (1982) (31)
- Reduction of carbon monoxide by binuclear tantalum hydride complexes (1983) (31)
- Catalytic reduction of dinitrogen to ammonia at well-defined single metal sites (2005) (31)
- Understanding the reactivity of [WNAr(CH2tBu)2(CHtBu)] (Ar = 2,6-iPrC6H3) with silica partially dehydroxylated at low temperatures through a combined use of molecular and surface organometallic chemistry (2006) (31)
- Protonation of the dinitrogen-reduction catalyst [HIPTN3N]Mo(III) investigated by ENDOR spectroscopy. (2011) (31)
- Coupling of methylidyne and carbonyl ligands on tungsten. Crystal structure of W(.eta.2-HC.tplbond.COAlCl3)(CO)(PMe3)3Cl (1982) (31)
- Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes. (2011) (31)
- Reactions of M(N-2,6-i-Pr2C6H3)(CHR)(CH2R‘)2 (M = Mo, W) Complexes with Alcohols To Give Olefin Metathesis Catalysts of the Type M(N-2,6-i-Pr2C6H3)(CHR)(CH2R‘)(OR‘ ‘) (2006) (31)
- Multiple Metal–Carbon Bonds for Catalytic Metathesis Reactions (Nobel Lecture 2005)† (2007) (30)
- Enantioselective synthesis of cyclic allylboronates by Mo-catalyzed asymmetric ring-closing metathesis (ARCM). A one-pot protocol for net catalytic enantioselective cross metathesis (2004) (30)
- Tantalacyclopentane complexes and their role in the catalytic dimerization of olefins (1980) (30)
- Metathesis of acetylenes by (fluoroalkoxy)tungstenacyclobutadiene complexes and the crystal structure of W(C3Et3)[OCH(CF3)2]3. A higher order mechanism for acetylene metathesis (1984) (30)
- Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex. (2018) (30)
- ALKYL, ALKYLIDENE, AND ALKYLIDYNE COMPLEXES OF OSMIUM(VI) (1995) (30)
- NMR detection of living intermediates prepared from activated [NON]ZrMe2 ([NON]2−=[(t-Bu-d6-N-o-C6H4)2O]2−) and olefins (1998) (30)
- Multiple metal-carbon bonds. 40. Reaction of Mo(CCMe3)[OCH(CF3)2]3(dimethoxyethane) with tert-butylacetylene, an aborted acetylene polymerization (1985) (29)
- Proof of Tacticity of Stereoregular ROMP Polymers through Post Polymerization Modification (2015) (29)
- Cationic Zirconium Complexes that Contain Mesityl-Substituted Diamido/Donor Ligands. Decomposition via CH Activation and Its Influence on 1-Hexene Polymerization (2001) (29)
- A TUNGSTEN T-SHAPED METHYLENE COMPLEX AND RELATED METHYLIDYNE HYDRIDE COMPLEXES (1981) (29)
- Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes. (2013) (29)
- Synthesis and ROMP Chemistry of Decafluoroterphenoxide Molybdenum Imido Alkylidene and Ethylene Complexes (2013) (29)
- Preparation and structure of tetraphenylarsonium tricyclooctatetraeneniobium, [As(C6H5)4][Nb(C8H8)3] (1975) (29)
- Synthesis of an iron(IV) cyanide complex that contains the triamido amine ligand [(tert-BuMe2SiNCH2CH2)3N]3- (1994) (29)
- Cationic Molybdenum Imido Alkylidene Complexes (2008) (29)
- Diamagnetic (pentamethylcyclopentadienyl)tungsten complexes containing unsubstituted, monomethyl- or 1,1-dimethylhydrazine or -hydrazido ligands (1992) (29)
- Synthesis and characterization of a series of (pentamethylcyclopentadienyl)tungsten(V) and -(VI) amino, amido, imido, and bridging nitrido complexes and molybdenum analogs (1991) (29)
- Alkyl and Alkylidene Complexes of Tantalum That Contain a Triethylsilyl-Substituted Triamido−Amine Ligand (1996) (29)
- Synthesis of Zirconium Complexes That Contain the Diamidophosphine Ligands [(Me3SiNCH2CH2)2PPh]2- or [(RNSiMe2CH2)2PPh]2- (R = t-Bu or 2,6-Me2C6H3) (1999) (29)
- Morphology of diblock copolymers of norbornene and organometallic derivatives of norbornene (1991) (28)
- Cis, Isotactic Selective ROMP of Norbornenes Fused with N-Arylpyrrolidines. Double Stranded Polynorbornene-Based Ladderphanes with Z-Double Bonds (2012) (28)
- SPONTANEOUS LOSS OF MOLECULAR HYDROGEN FROM TUNGSTEN(IV) ALKYL COMPLEXES TO GIVE ALKYLIDYNE COMPLEXES (1994) (28)
- SYNTHESIS OF ARYL-SUBSTITUTED TRIAMIDOAMINE LIGANDS AND MOLYBDENUM(IV) COMPLEXES THAT CONTAIN THEM (1998) (28)
- Synthesis and reactivity of [Re(N-2,6-C6H3-iso-Pr2)3]- and the x-ray structure of Hg[Re(N-2,6-C6H3-iso-Pr2)3]2 (1991) (28)
- Attempts to prepare alkylidene zirconium complexes by α-hydrogen atom abstraction (1981) (28)
- Nitrogen reduction: Molybdenum does it again. (2011) (28)
- New functional polymers prepared by ring-opening metathesis polymerization. Study of the quenching of luminescence of pyrene end groups by ferrocene or phenothiazine centers in the polymers (1993) (28)
- ALKYL, ALKYLIDENE, AND ALKYLIDYNE COMPLEXES OF RHENIUM (1995) (28)
- Tantalum-neopentylidene hydride and tantalum-neopentylidyne hydride complexes (1980) (28)
- Dramatic enhancement of the alkene metathesis activity of Mo imido alkylidene complexes upon replacement of one tBuO by a surface siloxy ligand. (2008) (28)
- Reaction of Phosphoranes with Mo(N-2,6-i-Pr2C6H3)(CHCMe3)(OCMe(CF3)2)2: Synthesis and Reactivity of an Anionic Imido Alkylidyne Complex (2006) (28)
- Preparation and characterization of two unsubstituted hydrazido(1-) complexes, W(.eta.5-C5Me5)Me4(.eta.2-NHNH2) and [W(.eta.5-C5Me5)Me3(.eta.2NHNH2)]+[SO3CF3]- (1988) (27)
- Synthesis of group 4 complexes that contain the tridentate diamido ligands [(ArNCH2CH2)2O]2– (Ar = C6H3-Me2-2,6 or C6H3Pri2-2,6) (1998) (27)
- Multiple metal-carbon bonds. 39. Preparation of molybdenum and tungsten neopentylidyne complexes of the type M(CCMe3)(O2CR)3, their reactions with acetylenes, and the x-ray structure of the .eta.3-cyclopropenyl complex W[C3(CMe3)Et2](O2CCH3)3 (1986) (27)
- A Solid-State NMR Study of Tungsten Methyl Group Dynamics in [W(η5-C5Me5)Me4][PF6] (1996) (27)
- Molybdenum alkylidyne complexes that contain a 3,3′-di-t-butyl-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2,2′-diolate ([Biphen]2−) ligand (2003) (27)
- Living and highly stereoregular ring-opening polymerization of 5,6-difunctionalized norbornadienes by a well-characterized molybdenum catalyst (1989) (27)
- Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy. (2010) (27)
- Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands (1996) (27)
- Reactivity of co-ordinated ligands. Part XVIII. Cationic ruthenium(II) and osmium(II) complexes by electrophilic attack on a π-allyl ligand (1974) (27)
- Synthesis and reactions of monomeric hydrazine and hydrazido complexes that contain the Cp*MoMe3 core (1993) (27)
- Preparation of bis and tris(arylimido) complexes of rhenium(VII), including bis(arylimido) neopentylidene complexes, candidates as olefin metathesis catalysts (1988) (27)
- Cyclooctatetraene complexes of niobium and tantalum and the structure of Nb(.eta.4-C8H8)[.eta.5-C8H8(C6H5)][(CH3)2AsC6H4As(CH3)2] (1976) (26)
- Synthesis of alkyne complexes of the type Ta(.eta.5-C5Me5)(alkyne)Cl2 and crystal structure of (.eta.5-pentamethylcyclopentadienyl)(diphenylacetylene)dichlorotantalum (1981) (26)
- Preparation of anionic tungsten(VI) alkyl complexes containing oxo or sulfido ligands and the X-ray structure of [N(C2H5)4]{WO2[OC(CH3)2C(CH3)2O][CH2C(CH3)3]} (1985) (26)
- Molybdenum, Tungsten, and Rhenium d2 Complexes That Contain the [(C6F5NCH2CH2)2NMe]2- Ligand (2000) (26)
- Synthesis and crystallographic characterization of a dinuclear 1,2-hydrazido(2-) complex of tungsten(VI), [W(.eta.5-C5Me4(CMe3))(CCMe3)I]2(.mu.-N2H2).CH2Cl2 (1984) (26)
- Multiple metal-carbon bonds. 30. Rhenium(VII) neopentylidene and neopentylidyne complexes (1982) (26)
- Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Alkylidene Complexes That Contain a 2,6-Dimesitylphenylimido Ligand (2013) (26)
- Synthesis and kinetics of decomposition of tungsten(VI) and molybdenum(VI) 2-oxametallacyclobutane complexes and the x-ray structure of trans-Mo[CH(tert-Bu)CH(C6F5)O](NAr)(O-tert-Bu)2 (1991) (26)
- Kinetic Investigation of the Polymerization of 1-Hexene by the {[t-BuNON]ZrMe}[B(C6F5)4] Initiator (2001) (25)
- Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R2-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene (2013) (25)
- Energetics and dynamics of the low-lying electronic states of constrained polyenes: implications for infinite polyenes. (2013) (25)
- Synthesis of molybdenum alkylidene complexes that contain the 2,6-dimesitylphenylimido ligand. (2011) (25)
- Investigations of polymerizations and metathesis reactions. 6. Metathesis-like reaction of a tungsten alkylidyne complex with cyclohexyl isocyanate (1986) (25)
- Preparation of an unsubstituted hydrazido(1−) complex and an authentic high oxidation state ditungsten dinitrogen complex (1985) (25)
- The synthesis and structures of tantalum complexes that contain a triamido or a diamidoamine ligand (1998) (25)
- The Discovery and Development of High Oxidation State Mo and W Imido Alkylidene Complexes for Alkene Metathesis (2008) (25)
- Synthesis and Characterization of ABA Triblock Copolymers Containing Smectic C* Liquid Crystal Side Chains via Ring-Opening Metathesis Polymerization Using a Bimetallic Molybdenum Initiator (2006) (25)
- Reactions of Mo(NAr)(CH-t-Bu)(CH2-t-Bu)2 with Alcohols To Give Metathesis Catalysts of the Type Mo(NAr)(CH-t-Bu)(CH2-t-Bu)(OR) (2004) (25)
- A high yield route to rhenium(VII) bis(imido) neopentylidene complexes (1987) (25)
- Niobium and tantalum mesityl complexes and the role of the mesityl ligand in α- and γ-hydrogen abstraction reactions (1979) (25)
- Multiple metal-carbon bonds. 44. Isolation and characterization of the first simple tantalacyclobutane complexes (1986) (25)
- Synthesis of Zirconium Complexes That Contain a Tridentate Diamido Ligand (1998) (25)
- Preparation, structure, and coordination chemistry of molybdenum(IV) tetrathiolates, Mo[S-2,4,6-C6H2(CHMe2)3]4 (1985) (25)
- Chain-transfer agents for living ROMP [Ring-Opening Metathesis Polymerization] reactions of norbornene (1990) (25)
- Stereospecific Ring-Opening Metathesis Polymerization of 3-Methyl-3-phenylcylopropene by Molybdenum Alkylidene Initiators (2008) (25)
- Zirconium Complexes That Contain a Diamido O-Donor Ligand with a Restricted Geometry (1999) (24)
- Synthesis of Molybdenum(VI) Monoimido Alkyl and Alkylidene Complexes (2005) (24)
- Alkyne Complexes of Tungsten(IV) (1983) (24)
- Rhenium(VII) monoimido alkylidene complexes: synthesis, structure, and Lewis-acid-cocatalyzed olefin metathesis (1991) (24)
- PREPARATION OF RUTHENIUM(0) AND OSMIUM(0) CYCLOOCTATETRAENE COMPLEXES (1973) (24)
- Traceless Protection for More Broadly Applicable Olefin Metathesis. (2019) (24)
- Tungsten and Molybdenum Alkyl or Aryl Complexes That Contain the [(C6F5NCH2CH2)3N]3- Ligand (1998) (24)
- Pentafluorophenylimido Alkylidene Complexes of Molybdenum and Tungsten (2012) (24)
- Synthesis of alternating trans-AB copolymers through ring-opening metathesis polymerization initiated by molybdenum alkylidenes. (2015) (24)
- Ring-Opening Metathesis Polymerization of (+) and (+ or -)-endo,exo-5,6- Dimethylbicyclo(2.2.1)hept-2-ene by Mo(CH-t-Bu)(N-2,6-C6H3-i-Pr2)(OR)2 (1994) (23)
- Synthesis of a TREN in which the aryl substituents are part of a 45 atom macrocycle. (2013) (23)
- Preparation of discrete polyenes and norbornene-polyene block copolymers using Mo(CH-t-Bu)(NAr)(O-t-Bu)2 as the initiator (1991) (23)
- Syntheses of Molybdenum Oxo Benzylidene Complexes. (2018) (23)
- Preparation of ditungsten hexakis(2,6-dimethylphenoxide) and its reaction with acetylenes to give tungstenacyclobutadiene complexes (1986) (22)
- Synthesis of oligoenes that contain up to 15 double bonds from 1,6-heptadiynes. (2006) (22)
- Synthesis of [(HIPTNCH 2 CH 2 ) 3 N]Crk Compounds (HIPT = 3,5-(2,4,6-!-Pr 3 C 6 H 2 ) 2 C 6 H 3 ) and an Evaluation of Chromium for the Reduction of Dinitrogen to Ammonia (2006) (22)
- Olefin metathesis reactions initiated by d2 molybdenum or tungsten complexes (2005) (22)
- Synthesis of High Oxidation State Bimetallic Alkylidene Complexes for Controlled ROMP Synthesis of Triblock Copolymers (2005) (22)
- Synthesis of Methylidene Complexes that Contain a 2,6-Dimesitylphenylimido Ligand and Ethenolysis of 2,3-Dicarbomethoxynorbornadiene (2013) (22)
- High oxidation state coordination chemistry with triamidoamine tungsten and molybdenum complexes (1997) (21)
- Bimetallic hydrazido(3- and 4-) and nitrido complexes of tungsten containing the W(.eta.5-C5Me5)Me3 core (1991) (21)
- Synthesis of cadmium pentamethylcyclopentadienyl complexes (1991) (21)
- Cationic imido alkylidene complexes of molybdenum supported by β-diketonate and β-diketiminate ligands (2006) (21)
- Preparation and some chemistry of a molecule containing a .mu.-.eta.2,.eta.2-NHNH2- and a .mu.-.eta.1,.eta.1-NH2NH2 ligand bound between two tungsten(VI) centers (1984) (21)
- Heterobimetallic complexes connected by peralkylated cyclopentadienyl rings (1987) (21)
- Synthesis of ABA triblock copolymers via ring opening metathesis polymerization using a bimetallic initiator : Influence of a flexible spacer in the side chain liquid crystalline block (2006) (21)
- Blue electroluminesence from a novel polymer structure (1994) (21)
- Stereoselective Ring-Opening Metathesis Polymerization (ROMP) of Methyl-N-(1-phenylethyl)-2-azabicyclo[2.2.1]hept-5-ene-3-carboxylate by Molybdenum and Tungsten Initiators (2015) (20)
- Potential dependence of the conductivity of polyacetylene: finite potential windows of high conductivity (1991) (20)
- Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile. (2016) (20)
- Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes (2008) (20)
- Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride As the Acid (2012) (20)
- Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes. (2012) (20)
- Reversible 3 + 2 cycloaddition of ethylene to the C:Re.tplbond.C unit in rhenium complexes of the type Re(.tplbond.CCMe3)(:CHR')(OR)2 (1993) (20)
- Synthesis and Structures of Zirconium and Hafnium Alkyl Complexes That Contain [H3CC(2-C5H4N)(CH2NAr)2]2- ([ArNpy]2-; Ar = Mesityl, Triisopropylphenyl) Ligands (2002) (20)
- Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands (2014) (20)
- Synthesis of yttrium complexes that contain the [NON]{sup 2-} ligand, [(t-Bu-d{sub 6}-N-o-C{sub 6}H{sub 4}){sub 2}O]{sup 2-} (1998) (19)
- Trigonal-monopyramidale MIII-Komplexe des Typs [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N) (1992) (19)
- Synthesis and Structure of a Trigonal Monopyramidal Vanadium(III) Complex, [(C6F5NCH2CH2)3N]V, and the Vanadium(IV) Product of Its Oxidation, {[(C6F5NCH2CH2)2N(CH2CH2NHC6F5)]V(O)}2 (1997) (19)
- Tungsten and molybdenum alkylidyne complexes containing bulky thiolate ligands (1988) (19)
- FORCE CONSTANTS OF MOLYBDENUM- AND TUNGSTEN-PNICTOGEN TRIPLE BONDS (1996) (19)
- Synthesis of [(Me3SiNCH2CH2)3N]3- and [(C6F5NCH2CH2)3N]3- Complexes of Molybdenum and Tungsten That Contain CO, Isocyanides, or Ethylene (2000) (19)
- Synthesis of palladium nanoclusters within spherical microdomains in films made from block copolymer/homopolymer blends (1993) (19)
- Synthesis of molybdenum and tantalum complexes that contain diamido/donor ligands of the type [(3,5-Cl2C6H3NCH2CH2)2NMe]2- or [(3,5-Cl2C6H3NCH2)2C(2-C5H4N)(CH3)]2- (2001) (19)
- Bimetallic complexes containing the bis(tetramethylcyclopentadienyl)ethane ligand (1989) (19)
- Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra. (2006) (18)
- Operationally simple, efficient, and diastereoselective synthesis of cis-2,6-disubstituted-4-methylene tetrahydropyrans catalyzed by triflic acid. (2006) (18)
- Evaluation of Zirconium and Hafnium Complexes that Contain the Electron-Withdrawing Diamido/Donor Ligand [(2,6-Cl2C6H3NCH2CH2)2NCH3)]2- for the Polymerization of 1-Hexene (2005) (18)
- The preparation of NbH5(Me2PCH2CH2Me2)2 and NbHL2(Me2PCH2CH2PMe2)2 (L = CO or C2H4) (1976) (18)
- Recent advances in the chemistry of well-defined olefin and acetylene metathesis catalysts (1985) (18)
- Chain-end functionalization of living polymers formed by the ring-opening metathesis polymerization of norbornene (1991) (18)
- Carboxylate-based molybdenum alkylidene catalysts: Synthesis, characterization, and use as initiators for 1,6-heptadiyne cyclopolymerizations (2008) (18)
- PREPARATION OF A “STABILIZED FORMYL” COMPLEX FROM CARBON MONOXIDE AND HYDROGEN AND THE CRYSTAL STRUCTURE OF A DERIVATIVE IN WHICH THE CARBON‐OXYGEN BOND HAS BEEN CLEAVED (1980) (18)
- EPR study of the low-spin [d(3); S =(1)/(2)], Jahn-Teller-active, dinitrogen complex of a molybdenum trisamidoamine. (2007) (18)
- Formation of Alternating trans-A-alt-B Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Imido Alkylidene Complexes (2015) (18)
- Preparation and Characterization of Molybdenum( IV)-Alkyne Complexes Containing Bulky Aryloxide or Arenethiolate Ligands (1987) (18)
- Synthesis and structure of a tungsten(IV) .eta.2-dimethyldiazene complex in which the diazene ligand behaves as a four-electron donor (1992) (18)
- Synthesis of Molybdenum Imido Alkylidene Complexes Containing N,N‘-Disubstituted 2,2‘-Bisamido-1,1‘-binaphthyl Ligands (2000) (18)
- Synthesis, Characterization, and Activation of Zirconium and Hafnium Dialkyl Complexes that Contain a C2-Symmetric Diaminobinaphthyl Dipyridine Ligand (2005) (18)
- High oxidation-state compounds containing hydrazine and hydrazido ligands bound to a W(N-2,6-C6H3-iso-Pr2)[2,6-NC5H3(CH2NTosyl)2] core (1991) (17)
- Synthesis of Molybdenum Imido Alkylidene Complexes and Some Reactions Involving Acyclic Olefins. (1990) (17)
- Homo- and heterobimetallic complexes connected by peralkylated cyclopentadienyl rings having a two-carbon bridge between them (1985) (17)
- Synthesis and optical spectroscopy of oligo(1,6-heptadiynes) with a single basic structure prepared through adamantylimido-based molybdenum Wittig and metathesis chemistry. (2009) (16)
- Two rhenium complexes that contain an unsupported metal-metal double bond in the presence of potentially bridging ligands (1991) (16)
- Molybdenum and Tungsten Alkylidene and Metallacyclobutane Complexes That Contain a Dianionic Biphenolate Pincer Ligand (2016) (16)
- Some Reactions Involving [W(N-2,6-Me2C6H3)(OCMe2CF3)2]2, a Symmetric d2/d2 Dimer that Contains No Bridging Ligands (2008) (16)
- Synthesis of osmium(VI) neopentyl, neopentylidene, and neopentylidyne complexes (1993) (16)
- Synthesis of Molybdenum Imido Alkylidene Complexes That Contain Siloxides (2007) (16)
- Thick Optical‐Quality Films of Substituted Polyacetylenes with Large, Ultrafast Third‐Order Nonlinearities and Application to Image Correlation (2008) (16)
- Tris(pyrrolyl-α-methyl)amines that Sterically Protect a Trigonal Metal Site (2007) (16)
- Preparation of Tungsten‐Based Olefin Metathesis Catalysts Supported on Alumina (2011) (16)
- Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand (2015) (16)
- Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes (2016) (16)
- X-ray crystallographic studies on octahedral oxo alkylidene complexes of tungsten(VI): W(O)(CHCMe3)(PMe3)2Cl2 and W(O)(CHCMe3)(PEt3)2Cl2 (1981) (16)
- Some Organometallic Chemistry of Molybdenum Complexes that Contain the (HIPTN3N) 3- Triamidoamine Ligand, {(3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2)3N} 3- (2005) (16)
- Catalytic homologation of vinyltributylstannane to allyltributylstannane by Mo(IV) complexes in the presence of ethylene. (2004) (16)
- Linear optical properties of a series of linear polyenes: implications for polyacetylene (1992) (16)
- Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain a tert-Butylimido Ligand (2015) (15)
- Preparation and characterization of tungsten phenoxo W(OR)4Cl2 complexes (R = pentafluorophenyl, 2,6-dichlorophenyl) and some of their reduction products, including an x-ray study of W(O-2,6-C6H3Cl2)4Cl(Et2O) (1989) (15)
- Crystal structure of bis(.eta.5-cyclopentadienyl)chloro(neopentylidene)tantalum, Ta(.eta.5-C5H5)2(CHCMe3)Cl, a molecule containing a twisted neopentylidene ligand with a highly obtuse Ta-C(.alpha.)-C(.beta.) angle (1978) (15)
- Conformational disorder in long polyenes (2001) (15)
- Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes. (2010) (15)
- Synthesis of monomeric niobium- and tantalum-benzyne complexes and the molecular structure of Ta(η2-C5Me5)(C6H 4)Me2 [34] (1979) (15)
- Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2. (2017) (15)
- Monomeric tungsten(IV) phenoxide and thiolate complexes (1985) (15)
- Synthesis of cis,syndiotactic-A-alt-B Copolymers from Enantiomerically Pure Endo-2-Substituted-5,6-Norbornenes. (2017) (15)
- Binuclear tantalum hydride complexes (1982) (15)
- Alkylation of dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)). (2009) (14)
- Silica-Supported Molybdenum-Oxo alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis. (2019) (14)
- The Discovery and Development of High Oxidation State Alkylidyne Complexes for Alkyne Metathesis (2008) (14)
- Reactions of [(Me3SiNCH2CH2)3N]WH with dihydrogen, olefins, acetylenes, carbon monoxide, n-butylisocyanide and azobenzene (1997) (14)
- High oxidation state dinitrogen complexes. Synthesis and crystal structure of [W(C6H5C.tplbond.CC6H5)(CH3OCH2CH2OCH3)Cl2]2(.mu.-N2).0.5CH3OCH2CH2OCH3 (1984) (14)
- Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions. (2016) (13)
- Alkylidyne Complexes of Molybdenum and Tungsten That Contain the [(3,4,5-C6H2F3NCH2CH2)2NMe]2- Ligand (2001) (13)
- Synthesis of Group 4 [(RN-o-C6H4)2O]2− complexes where R is SiMe3 or 0.5 Me2SiCH2CH2SiMe2 (1999) (13)
- A tungstenVI nitride having a W2(mu-N)2 core. (2008) (13)
- Synthesis and characterization of Mo(nor)4 (nor=1-norbornyl) (1988) (13)
- Synthesis of Rhenium(V) 2,4,6-Trimethylbenzylidyne Complexes by Abstracting "O2-" from an Acyl with Triflic Anhydride (1994) (13)
- A DFT study of the role of water in the rhodium-catalyzed hydrogenation of acetone. (2016) (13)
- Tantallabicycloalkane complexes and their use as catalysts for the cyclization of α,ω-dienes (1980) (13)
- 2, 2‐Dimethylpropylidyne Tungsten(VI) Complexes and Precursors for their Syntheses (2007) (13)
- Molybdenum Imido Alkylidene Complexes that Contain a β-Diketiminate Ligand (2007) (13)
- Transition metal complexes containing functionalized organoimido and phosphaneiminato ligands (2003) (12)
- Structural characterization of the nonachloroditungsten(II, III) ion (1983) (12)
- Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine. (2017) (12)
- Potential Group IV olefin polymerization catalysts that contain a diamido ligand substituted with hexaisopropylterphenyl groups (2006) (12)
- Synthesis and Nonlinear Optical Characterization of Spin-Coated Films of Triblock Copolymers Containing Durham Polyacetylene (1995) (12)
- X-ray study of Ta(CHCMe sub 3 )(S-2,4,6-C sub 6 H sub 2 -i-Pr sub 3 ) sub 3 (SEt sub 2 ) suggests why it is inactive for metathesis of ordinary olefins (1990) (12)
- Stereochemical Control Yields Mucin Mimetic Polymers (2021) (12)
- Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2- (2004) (11)
- Formation of a tetrahedral WC3 framework from a cyclic WC3(tungstenacyclobutadiene) system via attack on tungsten by nitrogen-doner ligands: X-ray study of W[C3Me2(But)][Me2N(CH2)2NMe2]Cl3 (1984) (11)
- Reduction of nitriles by a binuclear tantalum hydride complex. Structural study of [(.eta.5-C5Me4Et)TaCl2](.mu.-.eta.1-N,.eta.2-C,N-NCHMe)(.mu.-Cl)(.mu.-H)[.eta.5-C5Me4Et)TaCl] (1982) (11)
- Syntheses of Variations of Stereogenic-at-Metal Imido Alkylidene Complexes of Molybdenum (2012) (11)
- MULTIPLE METAL-CARBON BONDS. 6. THE REACTION OF NIOBIUM AND TANTALUM NEOPENTYLIDENE COMPLEXES WITH SIMPLE OLEFINS- A ROUTE TO METALLOCYCLOPENTANES (1977) (11)
- Molybdenum Monoaryloxide Pyrrolide Alkylidene Complexes That Contain Mono-ortho-substituted Phenyl Imido Ligands (2012) (11)
- New Enantiomerically Pure Alkylimido Mo-Based Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts. (2007) (11)
- Labile, reactive bis(imido)rhenium(V) complexes (1991) (11)
- Preparation of complexes of the forms WCp*(OR)3Cl, WCp*(OR)4, and WCp*(X)(.eta.2-alkyne)2 (X = OR, Cl) (1992) (11)
- Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2−, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3− (2006) (11)
- Synthesis and nonlinear optical analysis of triblock copolymers containing discrete polyenes (1994) (10)
- Synthesis of Triamidoamine Complexes of Niobium. (1996) (10)
- Synthesis, Characterization, and Polymerization Behavior of Zirconium and Hafnium Complexes that Contain Asymmetric Diamido-N-Donor Ligands (2004) (10)
- Imido/Oxo Exchange between Osmium and Tantalum as a Route to Os(NAr)2R2 and OsO(NAr)R2 Complexes (NAr = N-2,6-i-Pr2C6H3; R = CH2CMe3, CH2CMe2Ph, CH2SiMe3) and Attempts To Induce .alpha.-Hydrogen Abstraction To Give Alkylidene Complexes (1995) (10)
- Molybdenum and Tungsten Alkylidene Complexes That Contain a 2-Pyridyl-Substituted Phenoxide Ligand (2016) (10)
- Metathesis by Molybdenum and Tungsten Catalysts. (2015) (10)
- Synthesis of the ruthenium imido complexes, [Ru(?-C6H6)(N-2,6-R2C6H3)]2(R = Pri or Me), and the crystal structure of [Ru(?-C6H6)(N-2,6-Pri 2C6H3)]2 (1991) (10)
- Recent Advances in the Chemistry of “d0” Alkylidene and Metallacyclobutane Complexes (1993) (10)
- MULTIPLE METAL-CARBON BONDS FOR CATALYTIC METATHESIS REACTIONS (2007) (10)
- Synthesis of [(HIPTNCH2CH2)3N]Cr Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of chromium for the reduction of dinitrogen to ammonia. (2006) (10)
- MULTIPLE METAL-CARBON BONDS. PART 19. HOW NIOBIUM AND TANTALUM COMPLEXES OF THE TYPE M(CHCME3)(PR3)2CL3 CAN BE MODIFIED TO GIVE OLEFIN METATHESIS CATALYSTS (1981) (10)
- Rhenium(III) and Rhenium(V) Complexes That Contain the (C6F5NCH2CH2)3N Ligand (1996) (10)
- EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]MoVL Complexes (L = N-, NH). (2017) (10)
- Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand (2014) (10)
- Metathesis of acetylenes by triphenoxytungstenacyclobutadiene complexes and the crystal structure of W(C3Et3) [O-2,6-C6H3(i-Pr)2]3 (1984) (10)
- Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts. (2006) (9)
- Preparation of (Nb(eta/sup 5/-C/sub 5/Me/sub 5/)Cl/sub 2/)/sub 2/ and Nb(eta/sup 5/-C/sub 5/Me/sub 5/)(3-hexyne)Cl/sub 2/ (1984) (9)
- Living Ring‐Opening Metathesis Polymerization of 2,3‐Difunctionalized 7‐Oxanorbornenes and 7‐Oxanorbornadienes by Mo(CHCMe2R)(N‐2,6‐C6H3‐ iPr2)(O‐t‐Bu)2 and Mo(CHCMe2R)(N‐2,6‐C6H3‐iPr2)(OCMe2CF3)2. (1991) (9)
- Effect of chain length on the conductivity of polyacetylene. Potential dependence of the conductivity of a series of polyenes prepared by a living polymerization method (1992) (9)
- Exchange of oxo ligands in osmium tetroxide with imido ligands in bis(arylimido)bis(tert-butoxo)molybdenum complexes, Mo(NAr)2(O-tert-Bu)2. A facile route to Os(NAr)2O2 and Os(NAr)3O and osmium(IV) complexes of the type Os(NAr)2L2 (NAr = N-2,6-C6H3-iso-Pr2; L = a phosphine) (1993) (9)
- Multiple Metal-Carbon Bonds in Catalysis (1983) (9)
- 13C NMR spectra of tactic and atactic hydrogenated ring‐opened polymers of enantiomeric and racemic endo,exo‐5,6‐dimethylnorbornene (1998) (9)
- Molybdenum Complexes that Contain a Calix[6]azacryptand Ligand as Catalysts for Reduction of N2 to Ammonia. (2018) (8)
- Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum (2010) (8)
- Initiators of the Type Mo(NAr)(CHR')(OR")~2 for the Controlled Polymerization of Diethyldipropargylmalonate (2006) (8)
- Synthesis of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN. (2018) (8)
- Alkylidene Complexes of the Earlier Transition Metals (1986) (8)
- Preparation of tungsten(V) alkyl complexes and hydride complexes of the type [W(.eta.5-C5Me4-tert-Bu)Hx]y (1983) (8)
- Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes (2020) (8)
- A kinetic study of the thermal decomposition of pentabenzyltantalum (1978) (8)
- High Oxidation State Multiple Metal—Carbon Bonds (2002) (8)
- α -Hydrogen migration reactions in tungsten(VI) cyclopentadienyl alkylidyne complexes (1998) (7)
- High Oxidation State Molybdenum and Tungsten Alkene and Alkyne Metathesis Catalysts: Where We Are and Where We Want to Go (2007) (7)
- High‐Oxidation State Molybdenum and Tungsten Complexes Relevant to Olefin Metathesis (2015) (7)
- Oxidative reactions of the Mo(IV) dialkyl complex [{(3-CF3C6H4NCH2CH2)2NMe}Mo(CH2SiMe3)2]. (2007) (7)
- Synthesis of Oligo(1,6-heptadiynes) with a Single Structure and Terminal Methylene Groups Using Molybdenum-Based Wittig and Metathesis Chemistry. 1. 2,6-Dimethylphenylimido Systems (2008) (7)
- Linear Optical Properties of a Series of Polyacetylene Oligomers (1990) (7)
- Monomeric Tungsten(IV) Phenoxide and Thiolate Complexes. (1986) (7)
- No End in Sight for Further Uses of Metathesis Chemistry, or for Further Development (2002) (7)
- The synthesis of trans-(Me3CO)3WCCHCHCW(OCMe3)3, cis,cis-(Me3CO)3WCCHCHCCCHCHCW(OCMe3)3, and related metal-capped ene-ynes, and evaluation of them as catalysts for preparing polydiacetylenes (1988) (7)
- Reactions of molybdenum and tungsten alkyl and aryl complexes that contain a triamidoamine ligand with carbon monoxide (2001) (7)
- SYNTHESIS OF (HEXAFLUORO-TERT-BUTYL)AMINE AND MOLYBDENUM(VI) (HEXAFLUORO-TERT-BUTYL)IMIDO COMPLEXES (1995) (7)
- Rate Constant Ratios During Nitrogen Dioxide Photolysis (1966) (6)
- Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class (2022) (6)
- Metathesis by Molybdenum and Tungsten Catalysts. (2015) (6)
- PREPARATION AND CHARACTERIZATION OF A COMPOUND CONTAINING THE OCTACHLORODITUNGSTATE (TUNGSTEN-TUNGSTEN QUADRUPLE BOND) ION, (W2CL8)4- (2002) (6)
- The detection of ethylketen and enol-crotonaldehyde in the vapour-phase photolysis of trans-crotonaldehyde (1968) (6)
- Cover Picture: Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts (Angew. Chem. Int. Ed. 38/2003) (2003) (6)
- MOLYBDENUM AND TUNGSTEN CP COMPLEXES THAT CONTAIN 2,2'-DIAMIDODIPHENYLAMIDO OR 2-AMIDO-2'-OXYDIPHENYLAMIDO LIGANDS (1998) (6)
- Oxo 2-Adamantylidene Complexes of Mo(VI) and W(VI) (2021) (6)
- Conversion of rhenium alkylidyne complexes that contain unsupported metal-metal double bonds into relatives that contain μ-alkylidyne ligands (1996) (6)
- High Oxidation State Alkylidyne Complexes (1990) (6)
- Synthesis and conversion kinetics of some new “Durham” polyacetylene precursors† (1994) (6)
- Synthesis of bifunctional imido alkylidene bispyrrolide complexes of molybdenum and their conversion into bifunctional imido alkylidene diolate complexes that can be employed as ROMP initiators. (2008) (5)
- High-oxidation-state rhenium Cp* complexes containing hydrazine, hydrazido, ammonia, and amido ligands (1991) (5)
- Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Cata-lysts [J. Am. Chem. Soc. 2007, 129, 1044−1045]. (2007) (5)
- Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen—Mo Complex. (1998) (5)
- AN ′ALKYLCARBENE′ COMPLEX OF TANTALUM BY INTRAMOLECULAR ALPHA-HYDROGEN ABSTRACTION (1974) (5)
- Multiple Metal - Carbon Bonds. Part 43. A Well-Characterized, Highly Active, Lewis Acid Free Olefin Metathesis Catalyst. (1986) (5)
- Rate of interconversion of syn and anti rotamers of Mo(CHCMe2Ph)(NAr)(OR)2 and relative reactivity toward 2,3-bis(trifluoromethyl)norbornadiene. [Erratum to document cited in CA117(13):131334u] (1992) (5)
- PREPARATION AND SOME CHEMISTRY OF A MOLECULE CONTAINING A .mu±eta.2,η2-NHNH2- AND A .mu±eta.1,η1-NH2NH2 LIGAND BOUND BETWEEN TWO TUNGSTEN(VI) CENTERS (1985) (4)
- Tungstacyclopentane Ring Contraction Yields Olefin Metathesis Catalysts. (2022) (4)
- 22. Catalytic Asymmetric Olefin Metathesis (2008) (4)
- Protonation Studies of Molybdenum(VI) Nitride Complexes That Contain the [2,6-(ArNCH2)2NC5H3]2- Ligand (Ar = 2,6-Diisopropylphenyl). (2019) (4)
- Preparation and Reactivity of Several Alkylidene Complexes of the Type W(CHR′)(N-2,6-C6H3-iPr2)(OR)2 and Related Tungstacyclobutane Complexes. Controlling Metathesis Activity Through the Choice of Alkoxide Ligand. (1988) (4)
- Electrochemistry of well-defined redox active block polymers prepared by ring-opening metathesis polymerization (1992) (4)
- Synthesis of Tungsten Oxo Alkylidene Biphenolate Complexes and Ring-Opening Metathesis Polymerization of Norbornenes and Norbornadienes (2019) (4)
- Ferrocenyl‐Functionalised Molybdenum Imido Complexes: An Approach to Redox‐Tunable Olefin Polymerisation Catalysts (2001) (4)
- Turkey must end violent response to protests. (2013) (4)
- PREPARATION OF AN UNSUBSTITUTED HYDRAZIDO(1-) COMPLEX AND AN AUTHENTIC HIGH OXIDATION STATE DITUNGSTEN DINITROGEN COMPLEX (1985) (4)
- E- and Z-Trisubstituted macrocyclic alkenes for natural product synthesis and skeletal editing (2022) (4)
- Structure of iodo(methylene)tetrakis(trimethylphosphine)tungsten trifluoromethanesulfonate, [WI(CH2){P(CH3)3}4][CF3SO3] (1984) (4)
- Molybdenum Disubstituted Alkylidene Complexes (2020) (4)
- Preparation and characterization of a compound containing the octachloroditungstate (tungsten-tungsten quadruple bond) ion, [W2Cl8]4- (1982) (3)
- Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand. (1988) (3)
- Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment (2008) (3)
- Recent advances in olefin metathesis chemistry (2009) (3)
- Boosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand σ Donation. (2021) (3)
- Synthesis of Side Chain Liquid Crystal Polymers by Living Ring Opening Metathesis Polymerization. 4. Synthesis of Amorphous and Side Chain Liquid Crystal AB Block Copolymers (1992) (3)
- Syntheses of Molybdenum(VI) Imido Alkylidene Complexes That Contain a Bidentate Dithiolate Ligand (2018) (3)
- PREPARATION AND CHARACTERIZATION OF TANTALUM(III) OLEFIN COMPLEXES AND TANTALUM(V) METALLACYCLOPENTANE COMPLEXES MADE FROM ACYCLIC α OLEFINS (2002) (3)
- Catalytic Reduction of Dinitrogen under Mild Conditions (2004) (3)
- Molybdenum tris(2,5-dimethylpyrrolide), a rare homoleptic molybdenum(III) monomer. (2008) (2)
- Metathesis of acetylenes by triphenoxytunstenacyclobutadiene complexes and the crystal structure of W(C3Et3)[O-2,6-C6H3(i-Pr)2]3 (1984) (2)
- Multiple MetalCarbon Bonds for Catalytic Metathesis Reactins (Nobel Lecture). (2006) (2)
- Synthesis of Cationic Molybdenum Imido 2-Adamantylidene Complexes from Bispyrrolides via Cationic Pyrrolenine Complexes (2021) (2)
- Ring Contraction of a Tungstacyclopentane Supported on Silica: Direct Conversion of Ethylene to Propylene. (2022) (2)
- Interconversion of Molybdenum or Tungsten d2 Styrene Complexes with d0 1-Phenethylidene Analogues. (2021) (2)
- Transformation of a Tungstenacyclobutadiene Complex into a Nonfluxional η3-Cyclopropenyl Complex by Addition of a Donor Ligand. The X-Ray Structure of W(η5-C5H5)[C3(CMe3)2Me](PMe3)Cl2. (1984) (2)
- In Memory of John Anthony Osborn (2001) (2)
- Highly Efficient Molybdenum‐Based Catalysts for Enantioselective Alkene Metathesis. (2009) (2)
- Evaluation of Several Molybdenum and Ruthenium Catalysts for the Metathesis Homocoupling of 3-Methyl-1-Butene (2017) (2)
- Rhenium(VII) Monoimido Alkylidyne Complexes. The Importance of Face Selectivity in the Metathesis of Acetylenes via Rhenacyclobutadiene Intermediates. (1991) (2)
- Synthesis of Molybdenum(VI) Neopentylidene Neopentylidyne Complexes (2019) (2)
- A Well-Defined Rhenium(VII) Olefin Metathesis Catalyst. (1990) (2)
- Ring-Opening Metathesis Polymerization by Molybdenum Imido Alkylidene Complexes (1998) (2)
- Some Chemistry of Tungsten(IV) Alkyne Complexes (1983) (2)
- Tandem Catalytic Asymmetric Ring‐Opening Metathesis/Ring‐Closing Metathesis. (2000) (2)
- Reducing Them Down To Charge Them Up: Low Temperature Catalyst Activation (2016) (2)
- Synthesis of Molybdenum Imido 2-Adamantylidene Complexes through α Hydrogen Abstraction (2020) (2)
- Enantioselective Synthesis of Cyclic Enol Ethers and All‐Carbon Quaternary Stereogenic Centers Through Catalytic Asymmetric Ring‐Closing Metathesis. (2006) (1)
- Further studies of imido alkylidene complexes of tungsten, well-characterized olefin metathesis catalysts with controllable activity [Erratum to document cited in CA113(17):152665k] (1990) (1)
- Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts (2011) (1)
- Preparation and Isolation of Polyenes Containing up to 15 Double Bonds. (1988) (1)
- Living Polymerization of Alkynes by Molybdenum Imido Alkylidene Complexes (1998) (1)
- Syntheses of Molybdenum and Tungsten Imido Alkylidene Complexes that Contain a Bidentate Oxo/Thiolato Ligand (2020) (1)
- Preparation of Macrocyclic (2014) (1)
- Accessed Terms of Use Detailed Terms (2010) (1)
- The Preparation and Reactivity of Several Alkylidene Complexes of the Type W(CHR′)(N-2,6-C6H3-iPr2)(OR)2 and Related Tungstacyclobutane Complexes: How the Choice of OR Ligand Controls Structure and Metathesis Activity (1989) (1)
- Catalytic Asymmetric Ring‐Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes. (2001) (1)
- Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers by Mo‐Catalyzed Olefin Metathesis. (2001) (1)
- Why terminal alkynes cannot be metathesized. Preparation and crystal structure of a deprotonated tungstenacyclobutadiene complex, W(η5-C5H5)[C3(CMe 3)2]Cl (1983) (1)
- What′s New in Olefin Metathesis Catalyzed by Molybdenum and Tungsten Complexes? (2012) (1)
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization Through Ring-Closing Metathesis. (1999) (1)
- Enantioselective Synthesis of Cyclic Secondary Amines Through Mo‐Catalyzed Asymmetric Ring‐Closing Metathesis (ARCM). (2004) (1)
- Olefin Metathesis by Well-Characterized Re(VII) Alkylidene/Alkylidyne Complexes (1993) (1)
- α-HYDRIDE ELIMINATION: THE FIRST OBSERVABLE EQUILIBRIUMS BETWEEN ALKYLIDENE COMPLEXES AND ALKYLIDYNE HYDRIDE COMPLEXES (1982) (1)
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis. (2000) (1)
- Correction to Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin) (2011) (1)
- High Oxidation State Monopentamethylcyclopentadienyl Tungsten Methyl Complexes Including the First d0 Complex Containing a Highly Distorted Methylene Ligand, W(η5-C5Me5)(CH3)3(CH2). (1987) (1)
- Preparation of Bis and Tris(arylimido) Complexes of Rhenium(VII), Including Bis(arylimido) Neopentylidene Complexes, Candidates as Olefin Metathesis Catalysts. (1989) (1)
- Some Reactions Involving [ W ( N-2 , 6-Me 2 C 6 H 3 ) ( OCMe 2 CF 3 ) 2 ] 2 , a Symmetric d 2 / d 2 Dimer that Contains No Bridging Ligands (2008) (1)
- Thiolato Dinitrogen (or Hydrazido(4-)) Complexes, (Ta(SAr)3(THF))2(μ-N2) (Ar: 2,6-C6H3-iPr2, 2,4,6-C6H2-iPr3), and Phenoxide Analogues. Structural Comparison of (Ta(S-2,6-C6H3-iPr2)3(THF))2(μ-N2) and (Ta(O-2,6-C6H3-iPr2)3(THF))2(μ-N2) (1988) (1)
- Enol Ethers as Substrates for Efficient Zand Enantioselective Ring-Opening / Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes : (2012) (1)
- A neutron diffraction study of bis(cyclopentadienyl)(methyl)(methylene)tantalum(V) at 15 K (1988) (1)
- Supported Chiral Mo‐Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis. (2005) (1)
- W‐oxo Adamantylidenes: Stable Molecular Precursors for Efficient Silica‐Supported Metathesis Catalysts (2022) (1)
- MULTIPLE METAL-CARBON BONDS. 16. TUNGSTEN-OXO ALKYLIDENE COMPLEXES AS OLEFINS S METATHESIS CATALYSTS AND THE CRYSTAL STRUCTURE OF W(O)(CHCME3(PET3)CL2 (1980) (1)
- Synthesis of Molybdenum Perfluorophenylimido 2-Adamantylidene Complexes (2021) (1)
- The Discovery and Development of High Oxidation State Alkylidene Complexes (2002) (1)
- Increasing Olefin Metathesis Activity of Silica‐supported Molybdenum Imido Adamantylidene Complexes through E Ligand σ‐Donation (2021) (1)
- Hydrazido(1-), 1,2-Hydrazido(2-), and Hydrazido(4-) Complexes of Tungsten(VI) (1984) (1)
- In Vitro and In Vivo Studies of Pharmacological Effects of Zerumbone on Human Malignant Melanoma (2013) (1)
- The Synthesis of ROMP Homopolymers and Multi-Block Copolymers Containing Sugars. (1995) (1)
- THE PREPARATION OF PENTAHYDRIDOBIS(1,2-ETHANEDIYLBIS(DIMETHYLPHOSPHINEL))NIOBIUM AND NBHL2(ME2PCH2CH2PME2)2 (L = CO, OR, C2H4) (1977) (0)
- Publisher Correction: Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class (2022) (0)
- Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Phenethylidene Complexes (2022) (0)
- Molybdenum, [(S)‐3,3′‐Bis(1,1‐dimethylethyl)‐5,5′, 6,6′‐tetramethyl[1,1′‐biphenyl]‐2,2′‐diolato(2−)‐κO,κO′]‐2‐methyl‐2‐phenylpropylidene)[tricyclo[3.3.1.1]decan‐1‐aminato(2−)] (2007) (0)
- CCDC 1034282: Experimental Crystal Structure Determination (2014) (0)
- Preparation and Characterization of W(OR)4Cl2 Complexes (R: Pentafluorophenyl, 2,6-Dichlorophenyl) and Some of Their Reduction Products, Including an X-Ray Study of W(O-2,6-C6H3Cl2)4Cl(Et2O). (1989) (0)
- Mo-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysts for Efficient Z-Selective Synthesis of a Macrocyclic Trisubstituted Alkene by Ring-Closing Metathesis (2013) (0)
- Nonlinear optical properties of model triblock polyene copolymers: effect of conjugation length (1993) (0)
- Transition Metal—Carbon Multiple Bonds. (2002) (0)
- Silica‐Supported Molybdenum Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis (2019) (0)
- Rotational isomers of Mo ( VI ) Alkylidene Complexes and Cis / Trans Polymer Structure : Investigations in Ring-C N 00014-92-J-1433 0 (0)
- Molybdenum-Catalyzed Z- and Enantioselective Ring-Opening/Cross-MetathesisReactions (2009) (0)
- living olefin polymerization (1998) (0)
- Synthesis of P-Stereogenic Centers Through Ring-Closing Metathesis (2009) (0)
- PREPARATION OF (NB(η5-C5ME5)CL2)2 AND NB(η5-C5ME5)(3-HEXYNE)CL2 (1984) (0)
- Formation of diazenido(3-) and hydrazido(4-)heterobimetallic complexes from the hydrazido(2-) complex Cp*WMe3(NNH2) and its derivatives (1989) (0)
- Dedication to the Special Volume for Dietmar Seyferth (2010) (0)
- A message from the new ChemComm chair. (2012) (0)
- Synthesis of 2,6-Hexa-Tert-Butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu₃C₆H₂)₂C₆H₃X, Where X = I, Li, OH, SH, N₃, or NH₂ (2017) (0)
- A TANTALUM CARBYNE COMPLEX (1975) (0)
- Multiple Metal-Carbon Bonds. Part 44. Isolation and Characterization of the First Simple Tantalacyclobutane Complexes. (1987) (0)
- Chemistry of Bimetallic Linked Cyclopentadienyl Complexes (2005) (0)
- Experimental and Theoretical EPR Study of Jahn−Teller-Active [HIPTN[subscript 3]N]MoL Complexes (L = N[subscript 2], CO, NH[subscript 3]) (2010) (0)
- Multiple Metal-Carbon Bonds. Part 40. Reaction of Mo(CCMe3[OCH(CF3)2]3(dimethoxyethane) with tert.-Butylacetylene, an Aborted Acetylene Polymerization. (1986) (0)
- Book Review: Dictionary of Organometallic Compounds (1986) (0)
- Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes". (2017) (0)
- SYNTHESIS OF ALKYNE COMPLEXES OF THE TYPE TA(η5-C5ME5)(ALKYNE)CL2 AND CRYSTAL STRUCTURE OF (η5-PENTAMETHYLCYCLOPENTADIENYL)(DIPHENYLACETYLENE)DICHLOROTANTALUM (1981) (0)
- Chainlengh dependence of cubic optical nonlinearities in polyene oligomers: saturation and scaling law (1994) (0)
- Metathesis Reactions Catalyzed by Well‐Characterized Transition Metal Alkylidene Complexes (1993) (0)
- Synthesis and Characterization of Mo(nor)4 (nor: 1-Norbornyl). (1988) (0)
- Preparation and Characterization of Molybdenum(IV)-Alkyne Complexes Containing Bulky Aryloxide or Arenethiolate Ligands. (1987) (0)
- Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts. (2003) (0)
- Synthesis of Linear (Z)‐α,β‐Unsaturated Esters by Catalytic Cross‐Metathesis. The Influence of Acetonitrile. (2016) (0)
- Synthesis of Molybdenum(VI) Tritylimido Alkylidene Complexes (2022) (0)
- Polymerization of Enantiomerically Pure 2,3-Dicarboalkoxy Norbornadienes and 5,6-Disubstituted Norbornenes by Well-Characterized Molybdenum ROMP catalysts (1993) (0)
- CCDC 622617: Experimental Crystal Structure Determination (2006) (0)
- through catalytic cross-metathesis. (2019) (0)
- The Catalytic Reduction of Dinitrogen Under Mild Conditions (2019) (0)
- CCDC 848335: Experimental Crystal Structure Determination (2012) (0)
- REACTION OF CARBON MONOXIDE WITH (η5-PENTAMETHYLCYCLOPENTADIENYL)TETRAMETHYLTANTALUM. INTRAMOLECULAR REDUCTIVE COUPLING OF CARBON MONOXIDE VIA AN “η2-ACETONE” INTERMEDIATE (1979) (0)
- Preparation and Characterization of Two High Oxidation State Molybdenum Dinitrogen Complexes: (MoCp*Me3)2(μ-N2) and (MoCp*Me3)(μ-N2)(WCp′Me3). (1990) (0)
- Comprehensive Organometallic Chemistry. The Synthesis, Reactions and Structures of Organometallic Compounds (1984) (0)
- Preparation of tert-butyl-capped polyenes containing up to 15 double bonds [Erratum to document cited in CA111(16):134867g] (1991) (0)
- The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry (2014) (0)
- LOW-TEMPERATURE NEUTRON DIFFRACTION STUDIES OF CARBON-HYDROGEN-METAL INTERACTIONS IN TWO TANTALUM-NEOPENTYLIDENE COMPLEXES: (TA(CHCME3)(PME3)CL3)2 (T = 110 K) AND THE FIRST ALKYLIDENE/OLEFIN COMPLEX, TA(η5-C5ME5)(CHCME3)(η2-C2H4)(PME3 (1981) (0)
- Q&A: A sustainable chemist (2013) (0)
- Multiple Metal-Carbon Bonds. Part 9. Preparation and Characterization of Several Alkylidene Complexes, M(η5-C5H5)2(alkylidene)X (M = Ta or Nb), and the X-Ray Structure of Ta(η5-C5H5)2(CHC6H5)(CH2C6H5). An Investigation of Alkylidene L (1978) (0)
- Bimetallic Complexes Containing the Bis(tetramethylcyclopentadienyl)ethane Ligand. (1989) (0)
- Molybdenum-Catalyzed Enantioselective Alkene Metathesis (2009) (0)
- Multiple Metal-Carbon Bonds in Catalysis (37 Literaturzitate). (1983) (0)
- Some reactions of tungsten methylidyne complexes and the crystal structure of [W2(CPMe3)2(PMe3)4Cl 4][AlCl4]2 (1984) (0)
- CCDC 139272: Experimental Crystal Structure Determination (2000) (0)
- Catalytic Z-Selective Olefin Cross-Metathesis (2011) (0)
- Synthesis and Reactions of Tungsten(IV) Bis(imido) Complexes: Relatives of Bent Metallocenes. (1990) (0)
- Controlled synthesis of polyenes by catalytic methods. Progress report, December 1, 1992--November 30, 1993 (1993) (0)
- Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C[subscript 1] (2014) (0)
- Preparation and characterization of some high oxidation state dinitrogen complexes of tungsten (1989) (0)
- Ru- and Mo-Catalyzed Asymmetric Synthesis of Pyrans and Piperidines (2007) (0)
- Recent Advances in the Chemistry and Applications of High Oxidation State Akylidene Complexes (1994) (0)
- Synthesis and Reactivity of Two Monomeric Tungsten(IV) Phenoxide Complexes. (1988) (0)
- Living polymerization with well-defined alkylidene catalysts (1995) (0)
- Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1 , 2-Citation Lam (2018) (0)
- Tris(pyrrolyl-alpha-methyl)amines that sterically protect a trigonal metal site. (2007) (0)
- Enantioselective Synthesis of Cyclic Amides and Amines Through Mo‐Catalyzed Asymmetric Ring‐Closing Metathesis. (2005) (0)
- CATALYTIC HYDROGENATION USING CATIONIC RHODIUM COMPLEXES. I. EVOLUTION OF THE E CATALYTIC SYSTEM AND THE HYDROGENATION OF OLEFINS (1976) (0)
- Controlled Synthesis of Polyenes by Catalytic Methods. Progress Report for the period December 1, 1989 - November 30, 1992 (1992) (0)
- Domino Asymmetric Ring-Opening/Cross Metathesis Reaction (2007) (0)
- A Study of High Oxidation State Complexes of the Type (W(η5-C5Me5)Me2X)2(μ-N2), Including X-Ray Structures of (W(η5-C5Me5)Me2(OC6F5))2(μ-N2) and (W(η5-C5Me5)Me2(S-2,4,6-C6H2Me3))2(μ-N2). (1990) (0)
- Catalytic Z‐Selective Cross‐Metathesis with Secondary Silyl‐ and Benzyl‐Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis. (2013) (0)
- ChemInform Abstract: LOW-TEMPERATURE NEUTRON DIFFRACTION STUDIES OF CARBON-HYDROGEN-METAL INTERACTIONS IN TWO TANTALUM-NEOPENTYLIDENE COMPLEXES: (TA(CHCME3)(PME3)CL3)2 (T = 110 K) AND THE FIRST ALKYLIDENE/OLEFIN COMPLEX, TA(η5-C5ME5)(CHCME3)(η2-C2H4)(PME3 (1981) (0)
- PREPARATION AND STRUCTURE OF TETRAPHENYLARSONIUM TRICYCLOOCTATETRAENENIOBIUM, (AS(C6H5)4)(NB(C8H8)3) (1976) (0)
- Fostering interdisciplinary biology (2012) (0)
- Reaction of Neopentylidene Complexes of the Type M(CH-tBu)(N-2,6-C6H3-iPr2)(OR)2 (M: W, Mo) with Methyl Acrylate and N,N-Dimethylacrylamide to Give Metallacyclobutane Complexes. (1989) (0)
- Nature supp info accepted version C (2011) (0)
- ChemInform Abstract: Catalytic Asymmetric Olefin Metathesis (2002) (0)
- Enantioselective Synthesis of Cyclic Allylboronates by Mo-Catalyzed Asymmetric Ring-Closing Metathesis (ARCM). A One-Pot Protocol for Net Catalytic Enantioselective Cross Metathesis. (2004) (0)
- A study of the effects of a wave gradient on intertidal zonation at Yaquina Head, Lincoln County, Oregon (1978) (0)
- High oxidation state dinitrogen complexes. Synthesis and crystal structure of [W(C6H5C≡CC6H5)(CH 3OCH2CH2OCH3)Cl2] 2(μ-N2)·0.5CH3OCH2CH 2OCH3 (1985) (0)
- Modular Mo‐Based Catalysts for Efficient Asymmetric Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Ethers and Acetals. (2001) (0)
- Rhenium(VII) neopentylidene and neopentylidyne complexes and the X-ray structure of Re(CCMe3)(CHCMe3)(C5H5N) 2I2 (1983) (0)
- Chemistry of bimetallic linked cyclopentadienyl complexes: Progress report, 1 December 1986--30 November 1989 (1986) (0)
- Preparation of a "stabilized formyl" complex from carbon monoxide and hydrogen and the crystal structure of a derivative in which the C-O bond has been cleaved [15] (1980) (0)
- Preparation and Characterization of Two Unsubstituted Hydrazido(1‐) Complexes, W(η5‐C5Me5)Me4(η2‐NHNH2) and (W(η5‐C5Me5)Me3(η2‐NHNH2))+(SO3CF3)‐. (1989) (0)
- Alkylation of Dinitrogen in [(HIPTNCH[subscript 2]CH[subscript 2])[subscript 3]N]Mo Complexes (HIPT = 3,5-(2,4,6-i-Pr[subscript 3]C[subscript 6]H[subscript 2])[subscript 2]C[subscript 6]H[subscript 3]) (2009) (0)
- Reduction of carbon monoxide. Past research summary (1981) (0)
- High Oxidation State Alkylidene and Alkylidyne Complexes (2005) (0)
- ENYNE METATHESIS REACTIONS IN THE SYNTHESIS OF SMALL RING HETEROCYCLES (2017) (0)
- Controlled synthesis of polyenes by catalytic methods. Progress report, December 1, 1989--November 30, 1992 (1992) (0)
- Controlled Polymerizations by Well - Defined Transition Metal Catalysts (1990) (0)
- The First Polymer‐Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis. (2002) (0)
- CCDC 869154: Experimental Crystal Structure Determination (2012) (0)
- Additions and Corrections - Metallacyclopentane to Metallacyaclobutabe Ring Contraction (1980) (0)
- Metathesis Homocoupling of Terminal Olefins (2010) (0)
- REACTIVITY OF CO‐ORDINATED LIGANDS PART 18, CATIONIC RUTHENIUM(II) AND OSMIUM(II) COMPLEXES BY ELECTROPHILIC ATTACK ON A PI‐ALLYL LIGAND (1974) (0)
- MULTIPLE METAL-CARBON BONDS. 10. THERMALLY STABLE TANTALUM ALKYLIDYNE COMPLEXES AND THE CRYSTAL STRUCTURE OF TA(η5-C5ME5)(CPH)(PME3)2CL (1978) (0)
- Dictionary of Organometallic Compounds (1986) (0)
- ALKYLIDENE HYDRIDE COMPLEXES OF TANTALUM AND THE POLYMERIZATION OF ETHYLENE BY DIIODOTRIS(TRIMETHYLPHOSPHINE)HYDRONEOPENTYLIDENETANTALUM (TA(CHCME3)(H)(PME3)3I2) (1983) (0)
- Multiple Metal-Carbon Bonds. Part 38. Preparation of Trialkoxymolybdenum(VI) Alkylidyne Complexes, Their Reactions with Acetylenes, and the X-Ray Structure of Mo[C3(CMe3)2][OCH(CF3)2]2(C5H5N)2. (1986) (0)
- Toward the realization of practicable materials for χ(3) based photonic applications (2006) (0)
- Living ROMP of Disubstituted Cyclopropenes (2006) (0)
- A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis This research was supported by the National Institutes of Health (GM-59426) and the National Science Foundation (CHE-9905806 to A. H. H. and CHE-9988766 to R. R. S.). (2001) (0)
- New Enantiomerically Pure Alkylimido Molybdenum-Based Alkylidene Complexes . Synthesis , Characterization , and Activity as Chiral Olefin Metathesis Catalysts (0)
- Alkyne Metathesis by Molybdenum and Tungsten Alkylidyne Complexes (2013) (0)
- Purification of Alkene Stereoisomers through Z-Selective Ethenolysis (2011) (0)
- Synthesis of (+)-Quebrachamine (2009) (0)
- Preparation of Rhenium(VII) Monoimido Alkylidyne Complexes and Metathesis of Acetylenes via Rhenacyclobutadiene Intermediates. (1988) (0)
- Controlled synthesis of polyenes by catalytic methods (1990) (0)
- Processible Polyacetylene-Based χ(3) Materials for Photonic Applications (2007) (0)
- Preparation, Structure, and Coordination Chemistry of Mo[S-2,4,6-C6H2(CHMe2)3]4. (1986) (0)
- Recent Advances in High Oxidation State Mo and W Imido Alkylidene Chemistry (2009) (0)
- Some prominent scientists who have worked on metathesis reactions (2006) (0)
- Crystal structure of bis(η5-cyclopentadienyl)-chloro(neopentylidene)tantalum, Ta(η5-C5H5)2(CHCMe 3)-Cl, a molecule containing a twisted neopentylidene ligand with a highly obtuse Ta-C(α)-C(β) angle [18] (1978) (0)
- Additions and Corrections - Preparation of Di-tert-butoxytungsten(VI) Alkylidene Complexes by Protonation of Tri-tert-butoxytungsten(VI) Alkylidyne Complexes (1986) (0)
- A Tungsten Oxo Alkylidene Supported on Sulfated Zirconium Oxide for Olefin Metathesis (2023) (0)
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