Ei-ichi Negishi
#1,811
Most Influential Person Now
Japanese chemist
Ei-ichi Negishi's AcademicInfluence.com Rankings
Ei-ichi Negishichemistry Degrees
Chemistry
#28
World Rank
#84
Historical Rank
#14
USA Rank
Organic Chemistry
#29
World Rank
#44
Historical Rank
#16
USA Rank
Download Badge
Chemistry
Ei-ichi Negishi's Degrees
- PhD Organic Chemistry University of Pennsylvania
- Masters Organic Chemistry University of Tokyo
- Bachelors Organic Chemistry University of Tokyo
Why Is Ei-ichi Negishi Influential?
(Suggest an Edit or Addition)According to Wikipedia, Ei-ichi Negishi was a Japanese chemist who was best known for his discovery of the Negishi coupling. He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. He was awarded the 2010 Nobel Prize in Chemistry "for palladium catalyzed cross couplings in organic synthesis" jointly with Richard F. Heck and Akira Suzuki.
Ei-ichi Negishi's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Handbook of organopalladium chemistry for organic synthesis (2002) (2035)
- Palladium-catalyzed alkynylation. (2003) (955)
- Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation (1982) (767)
- Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides (1977) (577)
- Magical power of transition metals: past, present, and future (Nobel Lecture). (2011) (534)
- Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes☆ (1986) (407)
- Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides (1977) (362)
- Recent advances in efficient and selective synthesis of di-, tri-, and tetrasubstituted alkenes via Pd-catalyzed alkenylation-carbonyl olefination synergy. (2008) (337)
- Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation (1989) (310)
- A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides (1976) (261)
- Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest (1994) (255)
- Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes (1980) (245)
- Organometallics in organic synthesis (1980) (241)
- Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins (1978) (223)
- Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism (1987) (210)
- Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins (1978) (207)
- Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis (2007) (202)
- Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses (1981) (186)
- Palladium-catalyzed acylation of organozincs and other organometallics as a convenient route to ketones☆ (1983) (184)
- Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes (1985) (179)
- Regio- and stereoselective synthesis of ?-alkylidenebutenolides and related compounds (1997) (165)
- Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes (1985) (136)
- A convenient and genuine equivalent to HZrCp2Cl generated in situ from ZrCp2Cl2-DIBAL-H. (2006) (127)
- Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization (1987) (126)
- Selective carbon-carbon bond formation via transition metal catalysis. 4. A novel approach to cross-coupling exemplified by the nickel-catalyzed reaction of alkenylzirconium derivatives with aryl halides (1977) (124)
- Clean and convenient procedure for converting primary alkyl iodides and .alpha.,.omega.-diiodoalkanes into the corresponding alkyllithium derivatives by treatment with tert-butyllithium (1990) (124)
- Remarkably pair- and regioselective carbon-carbon bond-forming reaction of zirconacyclopentane derivatives with Grignard reagents (1991) (124)
- A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes (1981) (123)
- Facile cleavage of the CβCβ′ bond of zirconacyclopentenes. Convenient method for selectively coupling alkynes with alkynes, nitriles, and aldehydes (1993) (123)
- Palladium-Catalyzed Cyclization of .omega.-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation (1995) (119)
- Metal-promoted cyclization. 25. Palladium-catalyzed cascade carbometalation of alkynes and alkenes as an efficient route to cyclic and polycyclic structures (1989) (117)
- Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism (1996) (116)
- Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation (1996) (115)
- Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" way. (2010) (112)
- Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations. (1998) (111)
- Conversion of methyl ketones into terminal acetylenes and (E)-trisubstituted olefins of terpenoid origin (1980) (111)
- Organozirconium Compounds in Organic Synthesis (1988) (107)
- Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes (1981) (106)
- ZIRCONIUM-CATALYZED ENANTIOSELECTIVE METHYLALUMINATION OF MONOSUBSTITUTED ALKENES (1995) (105)
- Novel stereoselective alkenyl–aryl coupling via nickel-catalysed reaction of alkenylanes with aryl halides (1976) (104)
- Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes (1989) (102)
- Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes (1983) (100)
- Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials (2014) (98)
- A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10). (2002) (97)
- Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes (1996) (90)
- ONE-STEP CONSTRUCTION OF FUSED TRICYCLIC AND TETRACYCLIC STRUCTURES FROM ACYCLIC PRECURSORS VIA CYCLIC CARBOPALLADATION (1990) (89)
- Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents. (2004) (89)
- A quarter of a century of explorations in organozirconium chemistry. (2005) (88)
- Metal-promoted cyclization. 28. Regioselective and diastereoselective alkyl-alkene and alkene-alkene coupling promoted by zirconocene and hafnocene (1989) (84)
- Clean inversion of configuration in the Pd-catalyzed cross-coupling of 2-bromo-1,3-dienes. (2003) (83)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling (1982) (82)
- A palladium-catalyzed stereospecific substitution reaction of homoallylzincs with .beta.-bromo-substituted .alpha.,.beta.-unsaturated carbonyl derivatives. A highly selective synthesis of mokupalide (1980) (82)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling (1982) (82)
- A genealogy of Pd-catalyzed cross-coupling (2002) (81)
- Zipper-mode cascade carbometallation for construction of polycyclic structures (1992) (81)
- Metal-promoted cyclization. 26. Palladium-catalyzed cyclization of benzyl halides and related electrophiles containing alkenes and alkynes as a novel route to carbocycles (1989) (80)
- Zirconium-catalyzed, highly regioselective hydrosilation reaction of alkenes and X-ray structures of silyl(hydrido)zirconocene derivatives (1991) (79)
- Apparent endo-mode cyclic carbopalladation with inversion of alkene configuration via exo-mode cyclization-cyclopropanation rearrangement (1992) (78)
- All-catalytic, efficient, and asymmetric synthesis of alpha,omega-diheterofunctional reduced polypropionates via "one-pot" Zr-catalyzed asymmetric carboalumination-Pd-catalyzed cross-coupling tandem process. (2005) (77)
- Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-.beta.-Iodoenones and Related Derivatives Producing .gamma.-Lactones and .gamma.-Lactams (1995) (76)
- Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with .alpha.- or .gamma.-haloorganolithium reagents (1989) (75)
- Selective carbon-carbon bond formation via transition-metal catalysis. 33. Palladium-catalyzed cross-coupling reaction of .alpha.-heterosubstituted alkenylmetals. A stereoselective route to heterosubstituted dienes suitable for the Diels-Alder reaction (1983) (74)
- Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling. (2009) (74)
- Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the sonogashira alkynylation. (2003) (72)
- Anti-Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non-Chelation-Controlled Syn-Carbometalation and Chelation-Controlled Isomerization† (1997) (72)
- An efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric CC bond formation. (2004) (72)
- Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade (1994) (71)
- Cyclic cascade carbopalladation reactions as a route to benzene and fulvene derivatives (1992) (70)
- Widely applicable Pd-catalyzed trans-selective monoalkylation of unactivated 1,1-dichloro-1-alkenes and Pd-catalyzed second substitution for the selective synthesis of E or Z trisubstituted alkenes. (2006) (70)
- Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives (1985) (70)
- An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes (1996) (69)
- Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β‘ Carbon−Carbon Bond Cleavage of Zirconacyclopentenes (1998) (68)
- 1,1-Dimetalloalkenes containing aluminum as well as titanium or zirconium. Their structures and use as novel alkenylidene and alkenyl transfer agents (1981) (66)
- A novel zirconium-catalyzed hydroalumination of olefins (1980) (66)
- Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol. (2006) (66)
- Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones (1982) (64)
- Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3 (2002) (64)
- Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism (1988) (64)
- Metal-promoted cyclization. 17. A novel bicyclization methodology via cyclialkylation of .omega.-halo-1-metallo-1-alkynes containing aluminum and zinc (1988) (64)
- A highly stereo- , regio- , and chemoselective synthesis of conjugated dienes by the palladium-catalyzed reaction of ()-1-alkenylzirconium derivatives with alkenyl halides (1978) (63)
- Strictly regio-controlled method for α-alkenylation of cyclic ketones via palladium-catalyzed cross coupling (1991) (62)
- Highly Efficient and Selective Procedures for the Synthesis of γ-Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E (1997) (61)
- A novel, selective, and efficient route to carotenoids and related natural products via Zr-catalyzed carboalumination and Pd- and Zn-catalyzed cross coupling. (2001) (61)
- A method for the preparation of terminal and internal conjugated diynes via palladium-catalyzed cross-coupling (1984) (60)
- Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations (1997) (60)
- Stereo- and regioselective routes to allylic silanes☆ (1982) (60)
- A highly efficient and selective synthesis of lissoclinolide featuring hydrogen transfer hydrozirconation,trans-selective Pd-catalyzed cross coupling of alkenylzirconiums with 1,1-dibromoalkenes and Ag-catalyzed lactonization providing(Z)-γ-alkylidenebutenolides (1999) (60)
- Highly selective synthesis of allylated arenes and diarylmethanes via palladium-catalyzed cross coupling involving benzylic derivatives (1981) (59)
- Palladium-Catalyzed Cyclization of 1-Iodo-Substituted 1,4-, 1,5-, and 1,6-Dienes as Well as of 5-Iodo-1,5-dienes in the Presence of Carbon Monoxide (1996) (58)
- Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols (1994) (58)
- Highly selective synthesis of vitamin A and its derivatives. Critical comparison of some known palladium-catalyzed alkenyl-alkenyl coupling reactions (1991) (57)
- Efficient and selective synthesis of siphonarienolone and related reduced polypropionates via Zr-catalyzed asymmetric carboalumination. (2004) (57)
- An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain. (2004) (56)
- Zirconium-promoted bicyclization of enynes. Effects of enyne structure (1987) (56)
- Palladium-catalyzed cross-coupling reaction of alkynylzincs with benzylic electrophiles (2005) (56)
- Effects of organometals on the palladium-catalyzed tandem carbopalladation-cross coupling for preparing stereodefined exocyclic alkenes (1990) (56)
- Highly stereo- and regiocontrolled cyclopentannulation via allylphosphonate conjugate addition and hydroboration-oxidation-elimination. Synthesis of pentalenic acid with virtually complete stereo- and regiocontrol (1991) (56)
- Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2. (2003) (55)
- A convenient and asymmetric protocol for the synthesis of natural products containing chiral alkyl chains via Zr-catalyzed asymmetric carboalumination of alkenes. Synthesis of phytol and vitamins E and K. (2001) (55)
- anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles (1982) (55)
- Palladium-catalyzed or -promoted reductive carbon−carbon coupling. Effects of phosphines and carbon ligands (1987) (54)
- ‘Bis(triphenylphosphine)palladium:’ its generation, characterization, and reactions (1986) (54)
- Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes (1994) (53)
- An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-lodobromoethylene as a novel two-carbon synthon. (2000) (52)
- A highly stereoselective and general synthesis of conjugated trans,trans-dienes and trans-alkyl ketones via hydroboration (1973) (52)
- Novel silicon-promoted cycloalkylation of alkenylmetal derivatives (1983) (52)
- Mechanism of the zirconium-catalyzed carboalumination of alkynes. Evidence for direct carboalumination (1981) (51)
- Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives (1982) (51)
- Zirconium-catalyzed carboalumination of alkynes and enynes as a route to aluminacycles and their conversion to cyclic organic compounds (1998) (51)
- A general and convenient procedure for the preparation of zirconocene complexes of alkenes and conjugated dienes (1991) (51)
- Highly stereoselective and general synthesis of (z)-3-methyl-2-alken-1-ols via palladium-catalyzed cross coupling of (z)-3-iodo-2-buten-1-ol with organozincs and other organometals (1993) (50)
- Intermolecular alkyl-transfer reaction of tetraorganoborate anions with acyl halides. Novel method for moderating the carbanion reactivity (1975) (50)
- A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols (1986) (49)
- Principle of Activation of Electrophiles by Electrophiles through Dimeric Association—Two Are Better than One (1999) (48)
- Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO (1997) (48)
- Novel zirconocene-promoted carbon-carbon bond formation via a 1,2-migration reaction of alkynylzirconium derivatives (1991) (47)
- Complete reversal of regiochemistry in cyclic acylpalladation. Novel synthesis of quinones. (1986) (47)
- Fully reagent-controlled asymmetric synthesis of (-)-spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). (2007) (47)
- Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group☆ (1981) (47)
- Palladium-catalyzed carbonylative cyclization via trapping of acylpalladium derivatives with internal enolates. Its scope and factors affecting the C-to-O ratio (1994) (46)
- Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes. (2006) (45)
- A Selective Synthesis of (E)-2-Methyl-1-alkenyl Iodides via Zirconium-Catalyzed Carboalumination (1979) (45)
- Diastereoselective zirconocene-promoted bicyclization-carbonylation of allylically methyl-substituted enynes. Synthesis of (+)-iridomyrmecin (1992) (45)
- Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions (1987) (45)
- Thexylborane-A Highly Versatile Reagent for Organic Synthesis via Hydroboration (1974) (45)
- The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetals (1986) (45)
- Stereoselective synthesis of conjugated trans-enynes readily convertible into conjugated cis,trans-dienes and its application to the synthesis of the pheromone bombykol (1974) (44)
- Highly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol. (2011) (43)
- Use of InCl(3) as a cocatalyst and a Cl(2)Pd(DPEphos)-P(2-furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes. (2004) (43)
- Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals (2003) (43)
- A mild and selective synthesis of cyclopropene and cyclopropane derivatives via cycliallylation of alkenyllithiums (1985) (43)
- Carbonylative cyclization via intramolecular trapping of acylmetal derivatives by carbon nucleophiles catalyzed by late transition metals (1989) (43)
- Highly stereoselective total synthesis of fully hydroxy-protected mycolactones A and B and their stereoisomerization upon deprotection. (2011) (43)
- Convenient method for the tertiary alkyl-alkynyl coupling via organoalanes (1975) (42)
- Efficient synthesis of carbobicyclic and carbopolycyclic compounds via intramolecular carbopalladation catalyzed by palladium-phosphine complexes (1988) (42)
- Zirconium-catalyzed allylalumination and benzylalumination of alkynes (1984) (42)
- New four-carbon-atom homologation involving the free-radical chain reaction of 1,3-butadiene monoxide with organoboranes. Synthesis of 4-alkyl-2-buten-1-ols from olefins via hydroboration (1971) (42)
- Efficient and selective synthesis of 6,7-Dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs. (2004) (41)
- A New Protocol for the Enantioselective Synthesis of Methyl‐Substituted Alkanols and Their Derivatives through a Hydroalumination/Zirconium‐Catalyzed Alkylalumination Tandem Process (2002) (41)
- Strictly Regiocontrolled α-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd-Catalyzed Coupling of Cyclic α-Iodoenones with Organozincs. (2000) (41)
- Boraheterocycles via cyclic hydroboration (1977) (40)
- Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes (1984) (40)
- A strictly "pair"-selective synthesis of conjugated diynes via Pd-catalyzed cross coupling of 1,3-diynylzincs: a superior alternative to the Cadiot-Chodkiewicz reaction. (2000) (40)
- A convenient synthesis of unsymmetrical bibenzyls homoallylarenes, and homopropargylarenes via palladium-catalyzed cross coupling☆ (1983) (40)
- Metal promoted cyclization. 5. Mechanistic duality in cyclialkylation of alkenylmetal derivatives (1984) (40)
- Highly selective synthesis of conjugated dienoic and trienoic esters via alkyne elementometalation–Pd-catalyzed cross-coupling (2011) (40)
- Novel 1,2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with .alpha.-haloorganolithiums (1988) (39)
- Highly stereo- and regioselective synthesis of (Z)-trisubstituted alkenes via 1-bromo-1-alkyne hydroboration-migratory insertion-Zn-promoted iodinolysis and Pd-catalyzed organozinc cross-coupling. (2007) (39)
- Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes (1978) (37)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Aluminum, and Zirconium: The Negishi Coupling (2005) (37)
- 1,4- and 1,5-Diketones via palladium-catalyzed allylation of potassium enoxyborates (1983) (37)
- Synthesis of enol esters and enol lactones via palladium-catalyzed carbonyiation of ary land alkenyl halides (1990) (37)
- Selective carbon-carbon bond formation via transition metal catalysis. 31. Controlled carbometalation. 15. Zirconium-promoted carbozincation of alkynes (1983) (37)
- Novel head-to-tail alkyl-alkene or alkene-alkene coupling via zirconium-catalyzed reaction of alkylmagnesium derivatives with monosubstituted alkenes (1992) (36)
- Tetrahydrofuran-promoted aryl-alkyl coupling involving organolithium reagents (1974) (36)
- Novel and selective α-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of α,β-unsaturated carbonyl derivatives containing α-halogen or α-metal groups ☆ (1999) (36)
- Highly regioselective generation of “thermodynamic” enolates and their direct characterization by NMR☆ (1983) (36)
- Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl- gamma-butyrolactone. (2006) (36)
- Synthesis of benzofurans, tetrahydrobenzopyrans, and related cyclic ethers via cyclic carbopalladation (1989) (36)
- Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes (1990) (36)
- Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes (1994) (36)
- Facile reaction of B-alkylboracyclanes with .alpha.,.beta.-unsaturated carbonyl derivatives. Extension of the 1,4-addition reaction via organoboranes to highly branched secondary and tertiary alkyl groups (1971) (36)
- Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes. (2016) (35)
- Palladium-catalyzed allylation of lithium 3-alkenyl-1-cyclopentenolates-triethylborane and its application to a selective synthesis of methyl (z)-jasmonate1 (1985) (35)
- Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). (2008) (35)
- A convenient procedure for hydrozirconation of alkynes with iso-BuZrCp2Cl generated in situ by treatment of Cp2ZrCl2 with tert-butylmagnesium chloride (1991) (35)
- Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates (1983) (35)
- Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling. (2006) (34)
- CATALYTIC GENERATION AND TRAPPING OF ACYLMETALS CONTAINING NI AND CU WITH ENOLATES (1998) (33)
- Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation (1988) (33)
- Palladium-Catalyzed Cross-Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs† (2005) (33)
- One-pot conversion of alkynes and alkenes into one-carbon homologated aldehydes via hydrozirconation-isocyanide insertion-hydrolysis (1988) (33)
- Carbonylation of the organoboranes from the cyclic hydroboration of dienes with thexylborane. Simple procedure for the conversion of dienes into cyclic ketones (1967) (32)
- A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium-Catalyzed Carboalumination of Terminal Alkynes (1980) (32)
- Titanium-Catalyzed Cascade Carboalumination of Dienes and Trienes (1994) (32)
- A highly efficient chemo- , regio- , and stereoselective synthesis of (7E, 9Z)-dodecadien-1-yl acetate, a sex pheromone of lobesia botrana, via a functionalized organoborate (1977) (32)
- Palladium-catalyzed reaction of organoalanes and organozincs with .alpha.,.beta.-unsaturated acetals and orthoesters as conjugate addition equivalents (1985) (32)
- A Highly Efficient, Selective, and General Method for the Synthesis of Conjugated (all-E)-Oligoenes of the (CHCH)n Type via Iterative Hydrozirconation−Palladium-Catalyzed Cross-Coupling (2002) (32)
- Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation (1988) (31)
- Zirconium-promoted Bicyclization of Enynes (1985) (31)
- Highly efficient asymmetric synthesis of fluvirucinine A1 via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-lipase-catalyzed acetylation tandem process. (2008) (31)
- Highly stereoselective syntheses of conjugated ,- and ,-dienes, -enynes and -1,2,3-butatriened via alkenylborane derivatives (1991) (30)
- A stereoselective synthesis of cis-alkenylboranes (1975) (30)
- A selective procedure for α-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B (1996) (30)
- Zirconocene–Alkene Complexes. An X-Ray Structure and a Novel Preparative Method (1989) (30)
- Hydroboration. XXXII. Cyclic hydroboration of dienes with thexylborane (1972) (29)
- Palladium-catalyzed carbonylative cyclization of o-allylbenzyl halides to produce benzo-annulated enol lactones and/or bicyclo[3.3.0]hept-3-en-6-ones. An efficient route to U-68,215 (1991) (28)
- Hydroboration. XXXVII. Structural study of the hydroboration of olefins with thexylborane in the molar ratio of 1:1. Convenient synthesis of thexylmonoalkylboranes and their ready conversion to monoalkylboranes (1975) (28)
- Selective synthesis of benzene derivatives via palladium-catalyzed cascade carbometallation of alkynes (1993) (28)
- Synthesis of α-iodo-α,β-unsaturated ketones by the reaction of α-silyl-α,β-unsaturated ketones with ICl or IClAlCl3 (1999) (28)
- Synthesis of cyclopentanol derivatives via palladium-catalyzed cyclic allylmetallation-dehydrometallation (1989) (28)
- Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes (1984) (28)
- Pd-catalyzed selective tandem arylation–alkylation of 1,1-dihalo-1-alkenes with aryl- and alkylzinc derivatives to produce α-alkyl-substituted styrene derivatives (2003) (28)
- A novel intermolecular transfer reaction of alkenyltrialkylborates with aqueous bases and its application to the protonolysis of alkenylboron derivatives (1976) (28)
- A selective and convenient synthesis of β, β-dialkyl-substituted alkenylbroanes and alkenylzirconiums via carboalumination of alkynes1 (1982) (27)
- Carbonylation of perhydro-9b-boraphenalene to form perhydro-9b-phenalenol. New general synthesis of polycyclic derivatives (1967) (27)
- Palladium-catalyzed highly diastereoselective cyclic carbopalladation-carbonylative esterification tandem reaction of iododienes and iodoarylalkenes. (1999) (27)
- Catalytic Hydrogenation of Alkenes Using Zirconocene–Alkene Complexes (1991) (27)
- Metallic conductivity and ferromagnetic interaction of iron(III) d spins in the needle crystals of (ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)(2).FeBr(4) salt. (2002) (27)
- Efficient and diastereoselective synthesis of (+)-Goniobutenolide A via palladium-catalyzed ene-yne cross coupling-lactonization cascade (1996) (27)
- Carbonylation of thexyldialkylboranes. New general synthesis of ketones (1967) (27)
- Vinylic organoboranes. 6. A general synthesis of (E)-disubstituted-alkenes or ketones via the (E)-(1-substituted-1-alkenyl)boronic esters (1986) (27)
- Conversion of non-conjugated dienes into conjugated diene-zirconocenes via multipositional regioisomerization (1993) (26)
- Hydroboration. XXXV. Cyclic hydroboration of 2,4-dimethyl-1,4-pentadiene and 2,5-dimethyl-1,5-hexadiene. Simple synthesis of bis(3,5-dimethyl)borinane and bis(3,6-dimethyl)borepane and their application to the 1,4-addition reaction of organoboranes (1973) (26)
- Palladium-catalyzed cyclic acylmetalation of allylic electrophiles as a route to cyclopentenone derivatives (1988) (26)
- Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling. (2008) (25)
- Stereoselective synthesis of partially substituted 1,2,3-butatriene derivatives via hydroboration (1974) (25)
- Selective skeletal rearrangement by carbon–carbon bond activation (1990) (25)
- Carbon-carbon bond formation by the reaction of organolithiums with α-lithiated cyclic enol ethers. Stereoselective synthesis of β- and γ-hydroxy DI- and tri-substituted alkenes (1991) (25)
- Stereoselective synthesis of exocyclic alkenes via zirconium-promoted alkyl-diene coupling (1989) (25)
- Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA). (2010) (25)
- Direct synthesis of heteroarylethynes via palladium-catalyzed coupling of heteroaryl halides with ethynylzinc halides. Its application to an efficient synthesis of a thiophenelactone from Chamaemelum nobile L (1997) (25)
- Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr−Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives (2000) (25)
- 1,4-Pentenyne as a five-carbon synthon for efficient and selective syntheses of natural products containing 2,4-dimethyl-1-penten-1,5-ylidene and related moieties by means of Zr-catalyzed carboalumination of alkynes and alkenes. (2008) (25)
- Inhibition of reductive elimination of diorganopalladium species by formation of tetraorganopalladates (1987) (24)
- A highly selective method for α-alkylation of ketones via potassium enoxytrialkylborates (1979) (24)
- Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes: ZACA–Lipase-Catalyzed Acetylation Synergy (2007) (24)
- A new protocol for the enantioselective synthesis of methyl-substituted alkanols and their derivatives through a hydroalumination/ zirconium-catalyzed alkylalumination tandem process. (2002) (24)
- Enantioselective two-dimensional high-performance liquid chromatographic determination of N-methyl-D-aspartic acid and its analogues in mammals and bivalves. (2012) (24)
- Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization (1995) (23)
- Zirconium catalyzed CC bond formation reaction of conjugated diynes with EtMgBr (1993) (23)
- Carbozincation of Enynes Catalyzed by Titanium(IV) Alkoxides and Alkylmagnesium Derivatives (1998) (23)
- Palladium‐Catalyzed Carbonylative Cyclization Cascades with Iododienes and ‐trienes (1996) (23)
- A GENERAL ONE-CARBON HOMOLOGATION OF ORGANOBORANES VIA ALPHA-THIOORGANOBORATE ANIONS (1975) (23)
- Arylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of ≥98% IsomericPurity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes. (2010) (23)
- A novel copper-containing hydride species and its application to the reduction of organic substances (1974) (22)
- Nickel- or palladium-catalyzed cross coupling. 28. A selective synthesis of a mixture of C-15 epimers of (.+-.)-11-deoxyprostaglandin E2 methyl ester (1985) (22)
- Highly stereoselective and efficient synthesis of ω-heterofunctional di- and trienoic esters for Horner–Wadsworth–Emmons reaction via alkyne hydrozirconation and Pd-catalyzed alkenylation (2009) (22)
- Highly Chemo-, Regio-, and Stereoselective Carbon−Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5-Dienes and 1,5-Enynes (1999) (22)
- Widely applicable synthesis of enantiomerically pure tertiary alkyl-containing 1-alkanols by zirconium-catalyzed asymmetric carboalumination of alkenes and palladium- or copper-catalyzed cross-coupling. (2013) (22)
- Hydroboration. XXXI. Cyclic hydroboration of dienes with borane in tetrahydrofuran in the molar ratio of 1:1 (1972) (22)
- Highly Selective Methods for α-Alkenylation and α-Arylation of Ketones via Palladium- or Nickel-Catalyzed Cross Coupling (1987) (22)
- Strictly pair -selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations (2003) (22)
- Efficient and selective syntheses of (all-E)- and (6E,10Z)-2'-O-methylmyxalamides D via Pd-catalyzed alkenylation--carbonyl olefination synergy. (2008) (21)
- Factors Affecting the Unusual Reactivity Order in the β-Hydrogen Abstraction of Dialkylzirconocenes (1992) (21)
- Zirconium-catalyzed and zirconium-promoted cyclization reactions of non-conjugated dienes with alkylmagnesium halides to give cycloalkylmethylmagnesium derivatives☆ (1998) (21)
- Carbon-carbon bond formation via opening of epoxysilanes with organometals containing lithium and copper (1989) (21)
- Highly stereoselective synthesis of exocyclic alkenes via cyclialkylation (1987) (21)
- Synthesis and Reactivity of Zirconocene Derivatives (2003) (21)
- Hydroboration. XXXIII. Cyclic hydroboration of 1,4-pentadiene with borane in tetrahydrofuran. Thermal behavior of the organoborane derivatives and a simple synthesis of bisborinane and .beta.-alkylborinanes (1972) (21)
- Termination of carbopalladation of alkynes via carbonylative amidation producing lactams (1995) (21)
- Preparation of a hafnocene–ethylene complex from bis(η5-cyclopentadienyl)hafnacyclopentane and its characterization (1989) (20)
- Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation (2001) (20)
- Novel stereoselective synthesis of (E)- and (Z)-.alpha.,.beta.-unsaturated carboxylic esters via hydroboration (1974) (20)
- Stereoselective Synthesis of Exocyclic Alkenes by Cu‐Catalyzed Allylmagnesiation, Pd‐Catalyzed Alkylation, and Ru‐Catalyzed Ring‐Closing Metathesis: Highly Stereoselective Synthesis of (Z)‐ and (E)‐γ‐Bisabolenes (2001) (20)
- Hydroboration. 70. The polycyclic hydroboration of acyclic and cyclic trienes with borane in tetrahydrofuran and triethylamine-borane. Reexamination of the stereochemistry of isomeric perhydro-9b-boraphenalenes (1985) (19)
- Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes (1990) (19)
- Conversion of linear trienes into bicyclic boranes via hydroboration-isomerization and their carbonylation. A simple synthesis of angularly substituted bicyclic alcohols (1969) (19)
- An efficient and selective synthesis of nakienone A involving a novel protocol for α-alkenylation of ketones via palladium-catalyzed alkenyl-alkenyl coupling (1997) (19)
- Reaction of B-methoxydialkylboranes with lithium aluminum hydride in the presence of olefins. A new and general synthesis of acyclic and cyclic mixed trialkylboranes and their conversion into the corresponding trialkylcarbinols via carbonylation-oxidation (1970) (18)
- Zirconium-catalyzed asymmetric carboalumination (ZACA reaction) of 1,4-dienes (2006) (18)
- Molecular tuning of the closed shell C-H···F-C hydrogen bond. (2013) (18)
- Cyclic carbopalladation of alkynes terminated by carbonylative amidation (1996) (18)
- An intramolecular Michael reaction involving borate complexes. A novel synthesis of -hydroxycarboxylic acids. (1973) (18)
- Bisborolane. Highly elusive bisboracyclane (1971) (17)
- Stereoselective synthesis of β-hydroxy substituted trans-alkenes by the reaction of trans-alkenyltrialkylaluminates with epoxides (1976) (17)
- Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin (1998) (17)
- Metal-promoted cyclization. 3. Highly selective synthesis of .alpha.-alkylidenetetrahydrofurans and .gamma.-alkylidenebutyrolactones via intramolecular opening of epoxysilanes (1983) (17)
- Titanium-catalyzed cascade carboalumination of 2-alkyl-substituted dienes and related trienes (1996) (17)
- Highly Enantiospecific Borylation for Chiral α-Amino Tertiary Boronic Esters. (2018) (17)
- Facile and reversible displacement of η-C5H5 from Zr by organolithiums; formation of (η5-cyclopentadienyl) trialkylzirconiums and their reactions eith electrophiles and alkenes (1996) (16)
- AlCl3-Promoted Facile E-to-Z Isomerization Route to (Z)-2-Methyl-1-buten-1,4-ylidene Synthons for Highly Efficient and Selective (Z)-Isoprenoid Synthesis. (2009) (16)
- Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid. (2015) (16)
- A stereoselective synthesis of disubstituted trans-alkenes by the reaction of trans-alkenyl trialkylaluminates with alkyl halides and sulfonates (1976) (16)
- Development of a Method for the Synthesis of a-Substituted a,b-Unsaturated Lactones Based on Stille-Type Pd-catalyzed Carbonylation of (Z)-w-Iodoalkenols. An Efficient and Selective Synthesis of (+)-Hamabiwa-lactone B (2000) (16)
- Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes (2005) (16)
- Carbometalation Reactions of Diphenylacetylene and Other Alkynes with Methylalanes and Titanocene Derivatives (1997) (16)
- Highly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes. (2010) (16)
- Hydrogen Transfer Hydrozirconation of Alkenes with iBuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, and Pd (1999) (15)
- Organoboranes. IX. Structure of the organoboranes formed in the reaction of 1,3-butadiene and diborane in the stoichiometric ratio. An unusual thermal isomerization of these organoboranes (1970) (15)
- Metal-promoted cyclization: VI. Palladium-catalyzed cyclization via intramolecular allylation of alkenylmetals (1985) (15)
- Isolation and characterization of the ethylene-bridged zirconocene complex (Cp2ZrMe)2(CH2CH2) (1994) (15)
- Selective carbon-carbon bond formation via transition metal catalysis. 23. Highly selective and convenient method for the synthesis of 1,5-enynes and 1,5-dienes by the reaction of 1,3-dilithiopropargyl phenyl sulfide with allylic halides (1981) (14)
- Palladium‐Catalyzed Alkenylation by the Negishi Coupling (2006) (14)
- A novel highly enantio- and diastereoselective synthesis of vitamin E side-chain (2015) (14)
- Specific heat studies for ?-(BEDT-TSF) 2FeCl 4 (2003) (14)
- Hydroboration. XXXVIII. Structural study of the hydroboration of olefins with thexylmonoalkylboranes. Convenient route to thexyldialkylboranes, mixed dialkylboranes, and mixed trialkylboranes (1975) (14)
- The cyclic hydroboration of dienes. A simple convenient route to heterocyclic organoboranes (1972) (14)
- Highly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)–Cu- or Pd-catalyzed cross-coupling (2014) (14)
- Zr-promoted ‘pair’-selective and regioselective synthesis of penta-substituted benzene derivatives (2004) (13)
- A General Multi-Carbon Homologation of Olefins via Hydroboration-Carbonylation (1972) (13)
- Nondissociative mechanism for decomposition of dialkylzirconocenes to produce alkene–zirconocene–phosphine complexes (1990) (13)
- HYDROBORATION PART 34, THE CYCLIC HYDROBORATION OF 1,5-HEXADIEN WITH BORANE IN TETRAHYDROFURAN AND 9-BORABICYCLO(3.3.1)NONANE, A NEW CONVENIENT ROUTE TO THE BOREPANE RING SYSTEM UTILIZING 9-BORABICYCLO(3.3.1)NONANE (1973) (13)
- Palladium‐Catalyzed Heterogeneous Hydrogenation (2003) (12)
- Anti-hydroalumination of Homo- and bishomopropargyl alcohols (1997) (12)
- Facile opening of the borolane ring with borane. A simple entry into 1,2-tetramethylenediboranes (1970) (12)
- By Oxidative Addition (2003) (12)
- Palladium‐Catalyzed Aryl–Aryl Coupling (2003) (12)
- Design and synthesis of a novel pre-column derivatization reagent with a 6-methoxy-4-quinolone moiety for fluorescence and tandem mass spectrometric detection and its application to chiral amino acid analysis. (2015) (12)
- Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carboncarbon bond formation (2002) (11)
- A novel regiospecific aryl ketone synthesis by the reaction of arylborate anions with acyl chlorides (1975) (11)
- Dielectric ordering and colossal magnetodielectricity in the antiferromagnetic insulating state of l-ÑBEDT-TSFÖ2FeCl4 (2005) (11)
- Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes (2003) (11)
- Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents (1977) (11)
- Intermolecular trapping of acylpalladium and related acylmetal derivatives with active C–H compounds (1999) (11)
- Scope of the reaction of organoboranes with organolithiums as a method of preparation of lithium organoborates. Stability of lithium organoborates (1979) (11)
- An efficient synthesis of juvabione and todomatuic acid via hydroboration-carbonylation (1976) (11)
- On the regiochemistry of cyclialkylation of regiodefined 4-halo-1-alkenylmetals producing cyclobutenes (1997) (11)
- Zirconium-catalyzed methylalumination of heterosubstituted arylethynes. Factors affecting the regio-, stereo-, and chemoselectivities. (2007) (10)
- A simple synthesis of bisborinane and its applicability in hydroboration for the preparation ofB-alkylborinanes (1971) (10)
- Syntheses of Chiral Heterocyclic Compounds via Zirconium-Catalyzed Asymmetric Carboalumination of Alkynes (ZACA Reaction) (2014) (10)
- Remarkably facile and selective dehydroboration of tetramethylethylene from thexylmonoalkylboranes under the influence of triethylamine. Novel, convenient synthesis of monoalkylboranes as triethylaminates (1972) (10)
- Historical Background of Organopalladium Chemistry (2003) (10)
- Organoboranes. XII. Hydroboration of 1,3-butadiene with borane in tetrahydrofuran in a ratio equal to or smaller than 1:1. Interconversion between .beta.-alkylborolanes and 1,2-tetramethylenediboranes (1971) (10)
- The Reaction of Organoboranes Containing a Tertiary Alkyl Group with Carbon Monoxide. A New Approach to the Synthesis of Highly Branched Trialkylcarbinols (1972) (9)
- Novel borate anion-assisted cyclization. Facile rearrangement of 1-cyclopropylidenealkylboranes to homopropargylboranes (1977) (9)
- Organoboranes and organoborate anions. New classes of electrophiles and nucleophiles in organic synthesis (1975) (9)
- A selective synthesis of alkenylmercuric chlorides via alkenylalanes (1982) (9)
- Palladium‐Catalyzed Cross‐Coupling Involving Alkylmetals or Alkyl Electrophiles: Palladium‐Catalyzed Cross‐Coupling Involving Saturated Alkylmetals (2003) (9)
- General one-carbon homologation of organoboranes via .alpha.-thioorganoborate anions (1975) (9)
- A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes (2001) (9)
- Palladium‐Catalyzed Conjugate Substitution (2003) (9)
- Novel synthesis of an ω-alkynylorganometallic reagent via triple bond isomerization with potassium 3-aminopropylamide: ω-(9-borabicyclo[3.3.1]nonan-9-yl)alkl-1-ynes (1977) (9)
- A simple synthesis of bis(3,5-dimethyl)borinane and bis(3,6-dimethyl)borepane as new valuable reagents via cyclic hydroboration (1971) (8)
- Formation of Carbon ? Carbon and Carbon ? Heteroatom Bonds via Organoboranes and Organoborates (2004) (8)
- ZACA Reaction: Zr-Catalyzed Asymmetric Carboalumination of Alkenes (2010) (8)
- Enantioselective synthesis of chiral isotopomers of 1-alkanols by a ZACA-Cu-catalyzed cross-coupling protocol. (2014) (8)
- Novel and regioselective aromatic double substitution involving borate anions and a regio- and stereo-selective route to dihydroaromatic derivatives (1975) (8)
- Hydroboration. XXXIV. Cyclic hydroboration of 1,5-hexadiene with borane in tetrahydrofuran and 9-borabicyclo[3.3.1]nonane. New convenient route to the borepane ring system utilizing 9-borabicyclo[3.3.1]nonane (1973) (8)
- Pd(0) and Pd(II) Complexes Containing Phosphorus and Other Group 15 Atom Ligands (2003) (8)
- Antiferromagnetic resonance in λ-(BEDT-TSF) 2 FeCl 4 (2003) (8)
- SELECTIVE CARBON‐CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 30. A SELECTIVE AND CONVENIENT SYNTHESIS OF β,β‐DIALKYL‐SUBSTITUTED ALKENYLBORANES AND ALKENYLZIRCONIUMS VIA CARBOALUMINATION OF ALKYNES (1983) (8)
- Palladium‐Catalyzed Cross‐Coupling between Allyl, Benzyl, or Propargyl Groups and Unsaturated Groups (2003) (8)
- Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism. (1996) (7)
- Transition Metal Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis (2007) (7)
- PALLADIUM- OR NICKEL-CATALYZED CROSS COUPLING INVOLVING PROXIMALLY HETEROFUNCTIONAL REAGENTS (1983) (7)
- Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture) (2011) (7)
- Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation (2007) (7)
- Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter by Zirconium-Catalyzed Double Carboalumination. (2017) (7)
- A novel synthesis of cyclopentenones and cyclohexenones via cycliacylation of lithioalkenylcarboxamides (1986) (7)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Magnesium, Aluminum, and Zirconium (2007) (7)
- Establishment of a Two-Dimensional HPLC-MS/MS Method Combined with DCl/D 2 O Hydrolysis for the Determination of Trace Amounts of D-Amino Acid Residues in Proteins (2015) (7)
- Negishi Coupling—Expedient Formation of Biphenyls on the Periphery of Inorganic/Organometallic Diruthenium Species (2007) (7)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling Reactions with Organozincs and Related Organometals (2009) (6)
- By π-Complexation (2003) (6)
- Cyclization reactions of ω-tosyloxy-1-alkynyl- and ω-tosyloxy-1-alkenylborates and their ω-halo analogues† (1992) (6)
- Preparation of secondary alcohols by reaction of trialkylboranes with bis(phenylthio)methyl-lithium (1976) (6)
- Palladium- or Nickel-Catalyzed Cross-Coupling with Organometals Containing Zinc, Magnesium, Aluminum, and Zirconium (1998) (6)
- Synthesis of Natural Products via Palladium-Catalyzed Cross-Coupling (2003) (6)
- Ferromagnetic ordering in a new nickel polyborate NiB12O14(OH)10. (2006) (6)
- Catalysis in Organic Synthesis : edited by W.H. Jones Academic Press, New York, 1980, ix + 314 pages, $ 29.50. (1980) (5)
- NMR determination of n-butyllithium (1979) (5)
- Clean and Convenient Procedure for Converting Primary Alkyl Iodides and α,ω-Diiodoalkanes into the Corresponding Alkyllithium Derivatives by Treatment with tert-Butyllithium. (1991) (5)
- An Efficient and General Method for the Synthesis of α,ω‐Difunctional Reduced Polypropionates by Zr‐Catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Side Chain (I). (2004) (5)
- Enantiomerically pure zirconium and hafnium complexes containing a chiral cyclopentadiene derivative prepared from (−)-β-pinene (1997) (5)
- Controlled Carbometalation. Part 20. Carbometalation Reaction of Alkynes with Organoalane‐Zirconocene Derivatives as a Route to Stereo‐ and Regiodefined Trisubstituted Alkenes. (2002) (5)
- An unusually facile dehydroboration of triorganoboranes formed by treatment of alkenyltrialkylborates with hydrochloric acid (1976) (5)
- Cross coupling reactions in organic synthesis themed issue (2011) (5)
- Palladium-Catalyzed Carbon—Carbon Cross-Coupling. Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals (2003) (5)
- Zirconium-Catalyzed Enantioselective Methylalumination of Monosubstituted Alkenes. (1996) (5)
- Catalysis with d-Block Transition Metals for Green Organic Synthesis and a Sustainable World (2011) (5)
- An Efficient and Stereoselective Synthesis of Xerulin via Pd-Catalyzed Cross Coupling and Lactonization Featuring (E)-Iodobromoethylene as a Novel Two-Carbon Synthon. (2000) (5)
- Regio- and Stereoselective Synthesis of γ-Alkylidenebutenolides and Related Compounds. (1997) (5)
- A tribute to Herbert C. Brown (1992) (4)
- Organic Syntheses Using Zirconium Compounds-Recent Developments (1989) (4)
- Catalytic and Selective Conversion of (Z)‐2‐En‐4‐ynoic Acids to Either 2H‐Pyran‐2‐ones in the Presence of ZnBr2 or (Z)‐5‐Alkylidenefuran‐2(5H)‐ones in the Presence of Ag2CO3. (2002) (4)
- Molecularly Tuning the Radicaloid N-H···O═C Hydrogen Bond. (2016) (4)
- Convenient synthesis of diene-zirconocenes and regioselective partial reduction of the more highly substituted double bonds of conjugated dienes via complexation with zirconocenes and protonolysis (1993) (4)
- Crystal Structures, and Electrical Conducting and Magnetic Properties in the Plate Crystals of (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·MX4 (M=Fe, Ga, X=Br; M=Fe, X=C1) Salts (2002) (4)
- Reaction of the cyclic organoboranes from dienes with methyl vinyl ketone. A convenient synthesis of ω-hydroxy-ketones from dienes via hydroboration (1969) (4)
- HIGHLY GENERAL STEREO-, REGIO-, AND CHEMO-SELECTIVE SYNTHESIS OF TERMINAL AND INTERNAL CONJUGATED ENYNES BY THE PALLADIUM-CATALYZED REACTION OF ALKYNYLZINC REAGENTS WITH ALKENYL HALIDES (1978) (4)
- A general method for the synthesis of E and/or Z oligoisoprenoids based on Pd-catalyzed homoallyl-alkenyl and homopropargyl-alkenyl cross coupling and Zr-catalyzed carboalumination (2000) (4)
- (−)‐Dichlorobis[(1,2,3,3a,7a‐η)‐1‐[(1S,‐2S,5R)‐5‐methyl‐2‐(1‐methylethyl)]cyclohexyl‐1H‐inden‐1‐yl]zirconium and Its (+)‐(1R,2R,5S)‐Isomer (2003) (4)
- Remarkably “Pair”‐Selective and Regioselective Carbon‐Carbon Bond Forming Reaction of Zirconacyclopentane Derivatives with Grignard Reagents. (1991) (4)
- Crystal structures and conducting/magnetic properties in two different crystals of (ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·MBr4 (M = Fe, Ga) (2003) (4)
- Magnetic susceptibility and electrical resistivity of a mesoporous carbon CMK-1 (2003) (4)
- Pd‐Catalyzed Cross‐Coupling with Organometals Containing Zn, Al, Zr, and so on – The Negishi Coupling and Its Recent Advances (2013) (4)
- Diastereoselective, Enantioselective, and Regioselective Carboalumination Reactions Catalyzed by Zirconocene Derivatives (2006) (4)
- Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation—Carbonyl Olefination Synergy (2009) (4)
- A HIGHLY EFFICIENT CHEMO-, REGIO-, AND STEREOSELECTIVE SYNTHESIS OF (7E,9Z)-DODECADIEN-1-YL ACETATE, A SEX PHEROMONE OF LOBESIA BOTRANA, VIA A FUNCTIONALIZED ORGANOBORATE (1977) (3)
- Reaction of Zirconocene Dichloride with Alkyllithiums or Alkyl Grignard Reagents as a Convenient Method for Generating of "Zirconocene" Equivalent and Its Use in Zirconium-Promoted Cyclization of Alkenes, Alkynes, Dienes, Enynes, and (1986) (3)
- Catalytic enantioselective synthesis of chiral organic compounds of ultra-high purity of >99% ee (2015) (3)
- Palladium‐Catalyzed Isomerization of Alkenes, Alkynes, and Related Compounds Without Skeletal Rearrangements (2003) (3)
- Reaction of Alkynes with Organometallic Reagents (1997) (3)
- Chemo- and Stereoselective Dearomative Coupling of Indoles and Bielectrophilic β-Imino Boronic Esters via Imine-Induced 1,2-Boronate Migration. (2021) (3)
- Applications of Thexylmonoalkylboranes to the Stereoselective Synthesis of trans Disubstituted Olefins (2002) (3)
- (E)-2-PHENYL-1-PROPENYLDIMETHYLALUMINUM (1986) (3)
- Highly Satisfactory Alkynylation of Alkenyl Halides via Pd‐Catalyzed Cross‐Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation. (2003) (3)
- General Discussion of the Methods of Synthesis and In Situ Generation of Organopalladium Compounds (2003) (3)
- NOVEL STEREOSELECTIVE ALKENYL-ARYL COUPLING VIA NICKEL-CATALYZED REACTION OF ALKENYLALANES WITH ARYL HALIDES (1976) (3)
- Palladium‐Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1‐Disubstituted Alkenes Terminated by Carbonylative Reactions (2003) (3)
- Palladium‐Catalyzed Alkenyl–Aryl, Aryl–Alkenyl, and Alkenyl–Alkenyl Coupling Reactions (2003) (3)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 23. HIGHLY SELECTIVE AND CONVENIENT METHOD FOR THE SYNTHESIS OF 1,5-ENYNES AND 1,5-DIENES BY THE REACTION OF 1,3-DILITHIOPROPARGYL PHENYL SULFIDE WITH ALLYLIC HALI (1982) (3)
- A Strictly “Pair”‐Selective Synthesis of Conjugated Diynes via Pd‐Catalyzed Cross Coupling of 1,3‐Diynylzincs: A Superior Alternative to the Cadiot‐Chodkiewicz Reaction. (2001) (3)
- Highly Stereo- and Regioselective Synthesis of (Z)-Trisubstituted Alkenes via 1-Bromo-1-alkyne Hydroboration—Migratory Insertion—Zn-Promoted Iodinolysis and Pd-Catalyzed Organozinc Cross-Coupling. (2008) (3)
- Synthesis of Biaryls via Palladium‐Catalyzed Cross‐Coupling: 2‐Methyl‐4′‐Nitrobiphenyl (2003) (3)
- Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations (2010) (3)
- One‐Step Construction of Fused Tricyclic and Tetracyclic Structures from Acyclic Precursors via Cyclic Carbopalladation. (1991) (3)
- Palladium-Catalyzed Cyclization of ω-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation. (1995) (3)
- Widely Applicable Pd‐Catalyzed trans‐Selective Monoalkylation of Unactivated 1,1‐Dichloro‐1‐alkenes and Pd‐Catalyzed Second Substitution for the Selective Synthesis of (E)‐ or (Z)‐Trisubstituted Alkenes. (2006) (3)
- Palladium‐Catalyzed Cyclization of 1‐Iodo‐Substituted 1,4‐, 1,5‐, and 1,6‐Dienes as well as of 5‐Iodo‐1,5‐dienes in the Presence of Carbon Monoxide. (1996) (2)
- Palladium‐Catalyzed Cross‐Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs. (2005) (2)
- Alkyne Elementometalation—Pd-Catalyzed Cross-Coupling. Toward Synthesis of All Conceivable Types of Acyclic Alkenes in High Yields, Efficiently, Selectively, Economically, and Safely: “Green” Way. (2010) (2)
- Palladium-Catalyzed Cross-Coupling Substitution (2003) (2)
- Zirconium‐Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes (2016) (2)
- Direct Synthesis of Terminal Alkynes via Pd‐Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations. (1998) (2)
- A STEREOSELCTIVE SYNTHESIS OF CIS-ALKENYLBORANES (1975) (2)
- By β-Hydrogen Abstraction (2003) (2)
- Zirconium-Catalyzed, Highly Regioselective Hydrosilation Reaction of Alkenes and X-Ray Structures of Silyl(hydrido)zirconocene Derivatives. (1992) (2)
- Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions. (1987) (2)
- General discussions, organometallics of main group metals in organic synthesis (1980) (2)
- Facile Cleavage of the Cβ‐Cβ′ Bond of Zirconacyclopentenes. Convenient Method for Selectively Coupling Alkynes with Alkynes, Nitriles, and Aldehydes. (1993) (2)
- A general stereospecific annelation for the synthesis of trans-fused polycyclic ketones via hydroboration–carbonylation (1968) (2)
- Metal‐Promoted Cyclization. Part 18. Novel Cyclialkylation Reactions of (ω‐Halo‐1‐alkenyl)metal Derivatives. Synthetic Scope and Mechanism. (1988) (2)
- Palladium‐Catalyzed Synthesis of 1,4‐Dienes by Allylation of Alkenylalanes:α‐Farnesene (2003) (2)
- One-Step Homologation for the Catalytic Asymmetric Synthesis of Deoxypropionates. (2017) (2)
- 2.19 – Vinyl- and Arylmetals (1995) (2)
- A STEREOSELECTIVE SYNTHESIS OF PARTIALLY SUBSTITUTED 1,2,3-BUTATRIENE DERIVATIVES VIA HYDROBORATION (1974) (2)
- Highly Efficient and Selective Procedures for the Synthesis of γ- Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver-Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E (1997) (2)
- Search for highly efficient, stereoselective, and practical synthesis of complex organic compounds of medicinal importance as exemplified by the synthesis of the C21-C37 fragment of amphotericin B. (2013) (2)
- Palladium‐Catalyzed Alkynylation with Alkynylmetals and Alkynyl Electrophiles (2003) (2)
- Palladium‐Catalyzed Cross‐Coupling Reaction of Alkynylzincs with Benzylic Electrophiles. (2005) (2)
- Asymmetric Reactions and Processes in Chemistry (1982) (2)
- Zirconium-Catalyzed Carboalumination of Alkynes and Enynes as a Route to Aluminacycles and Their Conversion to Cyclic Organic Compounds. (1998) (2)
- ZACA-Lipase-Catalyzed Acetylation Synergy (2007) (2)
- Chemistry of Organo‐Boron Compounds. Part 60. Highly Stereoselective Syntheses of Conjugated E,E‐ and E,Z‐Dienes, E‐Enynes and E‐1,2,3‐Butatrienes via Alkenylborane Derivatives. (1991) (2)
- Palladium- and Nickel-Catalyzed Reactions of Organozinc Compounds (1999) (2)
- anti‐Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non‐Chelation‐Controlled syn‐Carbometalation and Chelation‐Controlled Isomerization. (1997) (2)
- NMR evidence for antiferromagnetic spin fluctuations in superconducting λ-(BETS)2GaCl4 (2003) (2)
- Palladium‐Catalyzed Hydrometallation (2003) (2)
- Cyclic Cascade Carbopalladation Reactions as a Route to Benzene and Fulvene Derivatives. (1992) (1)
- Apparent Endo-Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo-Mode Cyclization-Cyclopropanation-Rearrangement. (1993) (1)
- Novel Zirconocene-Promoted Carbon-Carbon Bond Formation via a 1,2- Migration Reaction of Alkynylzirconium Derivatives. (1991) (1)
- Antiferromagnetic resonance in ?-(BEDT-TSF) 2FeCl 4 (2003) (1)
- ONE‐STEP CONVERSION OF TERMINAL ACETYLENES INTO TERMINALLY FUNCTIONALIZED (E)‐3‐METHYL‐2‐ALKENES VIA ZIRCONIUM‐CATALYZED CARBOALUMINATION. A SIMPLE AND SELECTIVE ROUTE TO TERPENOIDS (1978) (1)
- ‘One-Pot’ Zr-Catalyzed Asymmetric Carboalumination-Pd Cross-Coupling (2005) (1)
- Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-β-Iodoenones and Related Derivatives Producing γ-Lactones and γ-Lactams. (1995) (1)
- Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr—Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives. (2000) (1)
- Strictly Regiocontrolled α‐Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd‐Catalyzed Coupling of Cyclic α‐Iodoenones with Organozincs. (2001) (1)
- Titanium‐Catalyzed Cascade Carboalumination of 2‐Alkyl‐Substituted Dienes and Related Trienes. (1996) (1)
- Conversion of Methyl Ketones into Terminal Alkynes: (E)‐Buten‐3‐ynyl‐2,6,6‐trimethyl‐1‐cyclohexene (2003) (1)
- An Odyssey from Stoichiometric Carbotitanation of Alkynes to Zirconium‐ Catalyzed Enantioselective Carboalumination of Alkenes (1997) (1)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds: Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds Other than Enolates (2003) (1)
- Direct Synthesis of Heteroarylethynes via Palladium-Catalyzed Coupling of Heteroaryl Halides with Ethynylzinc Halides. Its Application to an Efficient Synthesis of a Thiophenelactone from Chamaemelum nobile L. (1998) (1)
- Low frequency dielectric properties in a ferromagnetic semiconductor (ED-TTFVO)${_{2}}$FeBr${_{4}}$ with permanent electric dipoles (2004) (1)
- Palladium‐Catalyzed Carbon Skeletal Rearrangements: Palladium‐Catalyzed Carbon Skeletal Rearrangements Other than [3,3] Rearrangements (2003) (1)
- Palladium Complexes Containing Halogen and Oxygen Ligands (2003) (1)
- Highly Efficient Asymmetric Synthesis of Fluvirucinine A1 via Zr‐Catalyzed Asymmetric Carboalumination of Alkenes (ZACA)—Lipase‐Catalyzed Acetylation Tandem Process. (2008) (1)
- Reviews and Accounts on Organopalladium Chemistry (as of September 1999) (2003) (1)
- Convenient Preparative Method of α,β‐Disubstituted Cyclopentenone by Zirconium Promoted Intermolecular Coupling of an Alkyne, EtMgBr (or Ethylene) and CO. (1997) (1)
- Nonlinear electrical trnasport in ?-(BEDT-TSF) 2FeCl 4 under magnetic field (2003) (1)
- Palladium‐Catalyzed Cross‐Coupling between Allyl‐, Benzyl‐, or Propargylmetals and Allyl, Benzyl, or Propargyl Electrophiles (2003) (1)
- Use of InCl3 as a Cocatalyst and a Cl2Pd(DPEphos)—P(2-Furyl)3 Catalyst System for One-Pot Hydrometalation—Cross-Coupling and Carbometalation—Cross-Coupling Tandem Processes. (2004) (1)
- Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes. (1992) (1)
- Carbozincation of Enynes Catalyzed by Titanium(IV) Alkoxides and Alkylmagnesium Derivatives. (1998) (1)
- Palladium‐Catalyzed Cross‐Coupling Involving Alkylmetals or Alkyl Electrophiles: Reactions between Homoallyl‐, Homopropargyl‐, or Homobenzylmetals and Alkenyl or Aryl Electrophiles (2003) (1)
- Catalytic Generation and Trapping of Acylmetals Containing Ni and Cu with Enolates. (1998) (1)
- Intramolecular Acylpalladation: Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds (2003) (1)
- Synthesis of Natural Products via Nucleophilic Attack on π‐Ligands of Palladium–Alkene, Palladium–Alkyne, and Related π‐Complexes (2003) (1)
- The Tsuji–Trost Reaction and Related Carbon–Carbon Bond Formation Reactions: Palladium‐Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, Aldehydes, and Other Carbonyl Compounds (2003) (1)
- Synthesis of Five-Membered Heterocycles (2003) (1)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 25. STEREO- AND REGIOSELECTIVE ROUTES TO ALLYLIC SILANES (1982) (1)
- Other Palladium‐Catalyzed or ‐Promoted Oxidation Reactions via 1,2‐ or 1,4‐Elimination (2003) (1)
- Reactions of Acylpalladium Derivatives with Enolates and Related Amphiphilic Reagents (2003) (1)
- Multiple Mechanistic Pathways for Zirconium‐Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C‐H Activation. (1997) (1)
- Organometallic Complexes of Zirconium and Hafnium (2004) (1)
- Other Miscellaneous Palladium‐Catalyzed or ‐Promoted Oxidation Reactions (2003) (1)
- Scientific Contributions of Professor Herbert C. Brown (1978) (1)
- A profile of Professor Richard F. Heck (1999) (1)
- Highly Efficient and Selective Synthesis of Conjugated Triynes and Higher Oligoynes of Biological and Materials Chemical Interest via Palladium‐Catalyzed Alkynyl—Alkenyl Coupling. (2007) (1)
- Efficient and Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed Asymmetric Carboalumination and Pd-Catalyzed Cross-Coupling of Organozincs (2004) (1)
- Highly Enantiospecific Borylation for Chiral α‐Amino Tertiary Boronic Esters (2018) (1)
- AN INTRAMOLECULAR MICHAEL REACTION INVOLVING BORATE COMPLEXES, A NOVEL SYNTHESIS OF BETA-HYDROXYCARBOXYLIC ACIDS (1973) (1)
- WATER-DROPPING AERODYNAMICS FOR FIRE-FIGHTING AMPHIBIAN (2010) (1)
- Palladium-Catalyzed Cross-Coupling of Alkynylzincs with Allylic Electrophiles: An Efficient and Selective Synthesis of Stereo- and Regio-Defined 1,4-Enynes. (2005) (1)
- THEXYLBORANE - A HIGHLY VERSATILE REAGENT FOR ORGANIC SYNTHESIS VIA HYDROBORATION (1974) (1)
- ORGANOBORANE HETEROCYCLES VIA CYCLIC HYDROBORATION OF DIENES (1976) (1)
- Zirconium‐Catalyzed C‐C Bond Formation Reaction of Conjugated Diynes with EtMgBr. (1994) (1)
- Palladium‐Catalyzed Carbonylative Cyclization of o‐Allylbenzyl Halides to Produce Benzo‐Annulated Enol Lactones and/or Bicyclo(3.3.0)hept‐3‐ en‐6‐ones. An Efficient Route to U‐68,215. (1992) (1)
- By Reductive Carbonylation (2003) (1)
- Stereoselective Synthesis of Exocyclic Alkenes by Cu‐Catalyzed Allylmagnesiation, Pd‐Catalyzed Alkylation, and Ru‐Catalyzed Ring‐Closing Metathesis: Highly Stereoselective Synthesis of (Z)‐(V) and (E)‐(IX)‐γ‐Bisabolenes. (2002) (0)
- Metal-Promoted Cyclization. Part 29. Carbonylative Cyclization via Intramolecular Trapping of Acylmetal Derivatives by Carbon Nucleophiles Catalyzed by Late Transition Metals. (1990) (0)
- Zirconocene-Alkene Complexes: Their Formation, Structure, and Reactions (1993) (0)
- Zirconocene-Promoted Stereoselective Bicyclization of 1,6- and 1,7-Dienes to Produce trans-Zirconabicyclo(3.3.0)octanes and cis-Zirconabicyclo(4.3.0)nonanes. (1990) (0)
- Palladium-Catalyzed Carbon Skeletal Rearrangements Other than [3,3] Rearrangements (2003) (0)
- Formation of Oxo-, Thioxo-, or Phosphinidenezirconium Complexes (2003) (0)
- Formation of Trichloro(η-cyclopentadienyl)zirconium from Thallium(I) Methylcyclopentadienide and Zirconium(IV) Chloride–Bis(tetrahydrofuran) Complex (2003) (0)
- CONTROLLED CARBOMETALATION. 4. A SELECTIVE SYNTHESIS OF (E)-2-METHYL-1-ALKENYL IODIDES VIA ZIRCONIUM-CATALYZED CARBOALUMINATION (1979) (0)
- METAL-PROMOTED CYCLIZATION. VI. PALLADIUM-CATALYZED CYCLIZATION VIA INTRAMOLECULAR ALLYLATION OF ALKENYLMETALS (1985) (0)
- Highly Selective Methods for α‐Alkenylation and α‐Arylation of Ketones via Palladium‐ or Nickel‐Catalyzed Cross Coupling. (1988) (0)
- C—C Bond Formation via Stoichiometric Transmetalation (2003) (0)
- Development of a Method for the Synthesis of α‐Substituted α,β‐Unsaturated Lactones Based on Stille‐Type Pd‐Catalyzed Carbonylation of (Z)‐ω‐Iodoalkenols. An Efficient and Selective Synthesis of (+)‐Hamabiwalactone B. (2000) (0)
- Compounds of Groups 7-3 (Mn..., Cr..., V..., Ti..., Sc..., La..., Ac...) (2003) (0)
- Reactions of Zirconocene–Conjugated Diene Complexes with π-Compounds (2003) (0)
- Highly Selective Synthesis of Vitamin A and Its Derivatives. Critical Comparison of Some Known Palladium‐Catalyzed Alkenyl‐Alkenyl Coupling Reactions. (1992) (0)
- Metal-Promoted Cyclization. Part 22. Synthesis of Benzofurans, Tetrahydrobenzopyrans, and Related Cyclic Ethers via Cyclic Carbopalladation. (1989) (0)
- A Highly Efficient and Selective Synthesis of Lissoclinolide Featuring Hydrogen Transfer Hydrozirconation, trans-Selective Pd-Catalyzed Cross Coupling of Alkenylzirconiums with 1,1-Dibromoalkenes and Ag-Catalyzed Lactonization Providing (Z)-γ-Alkylidenebutenolides. (1999) (0)
- Highly Stereoselective and General Synthesis of Z‐3‐Methyl‐2‐alken‐1‐ ols via Palladium‐Catalyzed Cross Coupling of Z‐3‐Iodo‐2‐buten‐1‐ol with Organozincs and Other Organometals. (2010) (0)
- Synthesis of Bis(η-cyclopentadienyl)metal(IV) "Ate" Complexes (2003) (0)
- Formation of Carbon-Carbon and Carbon- Heteroatom Bonds via Organoboranes and Organoborates (1986) (0)
- Carbon-Carbon Bond Formation via Opening of Epoxysilanes with Organometals Containing Lithium and Copper. (1989) (0)
- Formation of Tris(η-cyclopentadienyl)metal Complexes (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 33. PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF α-HETEROSUBSTITUTED ALKENYLMETALS. A STEREOSELECTIVE ROUTE TO HETEROSUBSTITUTED DIENES SUITABLE FOR THE DIELS-AL (1983) (0)
- HYDROBORATION PART 35, CYCLIC HYDROBORATION OF 2,4-DIMETHYL-1,4-PENTADIENE AND 2,5-DIMETHYL-1,5-HEXADIENE, A SIMPLE SYNTHESIS OF BIS(3,5-DIMETHYL)BORINANE AND BIS(3,6-DIMETHYL)BOREPANE AND THEIR APPLICATION TO THE 1,4-ADDITION REACTIO (1973) (0)
- Stoichiometric Reactions of Nonconjugated Dienes with Zirconocene Derivatives. Further Delineation of the Scope of Bicyclization and Observation of Novel Multipositional Alkene Regioisomerization. (1995) (0)
- Bis(η-cyclopentadienyl)zirconium(II)-Catalyzed Hydrosilylation of Alkenes (2003) (0)
- Palladium‐Catalyzed trans‐Selective Alkynylation—Alkylation Tandem Process for the Synthesis of (E)‐3‐Alkyl‐1‐trialkylsilyl‐3‐alken‐1‐ynes. (2006) (0)
- Conversion of Non-Conjugated Dienes into Conjugated Diene-Zirconocenes via Multipositional Regioisomerization. (1993) (0)
- Stoichiometric Reactions of Bis(η-cyclopentadienyl)hydridozirconium(IV) and Bis(η-cyclopentadienyl)dihydridozirconium(IV) Complexes and Related Reagents (2003) (0)
- Hydroamination of Internal Alkynes Catalyzed by Zirconium–Nitrene Complexes (2003) (0)
- Strictly Regio‐ and Stereo‐Controlled α‐Alkenylation of Bicyclic Enone Derivatives via Palladium‐Catalyzed Cross Coupling and Its Application to a Formal Synthesis of (.+‐.)‐Carbacyclin. (1998) (0)
- Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes. (1995) (0)
- Some Newer Aspects of Organozirconium Chemistry of Relevance to Organic Synthesis: Zr‐Catalyzed Enantioselective Carbometalation (2001) (0)
- Acylpalladation and Related Addition Reactions—Intramolecular Acylpalladation: Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds (2003) (0)
- Catalytic Oligomerization of Terminal Alkynes (2003) (0)
- Reactions of (η-Cyclooctatetraene)zirconium Derivatives (2003) (0)
- Reactions Between Homoallyl‐, and Homopropargyl‐, or Homobenzyl and Alkenyl or Aryl Electrophiles (2003) (0)
- Palladium-catalyzed acetylene syntheses (1979) (0)
- Convenient and General Synthesis of 1‐Monoorganyl‐ and 1,2‐ Diorganylcyclobutenes via Cyclialkylation. (1997) (0)
- Metal–Bis(η-cyclopentadienyl) Derivatives of Oxidation States Two and Three (2003) (0)
- Zr-Catalyzed Carboalumination: A New Route to Tocotrienols (2011) (0)
- Metal-Promoted Cyclization. Part 26. Palladium-Catalyzed Cyclization of Benzyl Halides and Related Electrophiles Containing Alkenes and Alkynes as a Novel Route to Carbocycles. (1989) (0)
- Ring Expansion of Zirconacyclopentenes and Zirconacyclopentanes with Aldehydes (2003) (0)
- The Metal-Organic Approach to the Stereoselective Synthesis of Exocyclic Alkenes (1990) (0)
- HYDROBORATION PART 38, STRUCTURAL STUDY OF THE HYDROBORATION OF OLEFINS WITH THEXYLMONOALKYLBORANES, A CONVENIENT ROUTE TO THEXYLDIALKYLBORANES, MIXED DIALKYLBORANES, AND MIXED TRIALKYLBORANES (1975) (0)
- Stereoselective Cyclic Carbolithiation of Alkyne Derivatives. A Stereoselective Synthesis of Exocyclic Alkenes. (1990) (0)
- A NOVEL STEREOSELECTIVE SYNTHESIS OF (E)‐ AND (Z)‐ALPHA,BETA‐UNSATURATED CARBOXYLIC ESTERS VIA HYDROBORATION (2002) (0)
- Palladium-Catalyzed Cross-Coupling of Alkynylzincs with Allylic Electrophiles: An Efficient and Selective Synthesis of Stereo- and Regio-Defined 1,4-Enynes (2005) (0)
- Oxo-, Thioxo-, Selenoxo-, or Telluroxozirconium Complexes by the Oxidative Reaction of a Zirconium(II) Complex (2003) (0)
- Bis(η-cyclopentadienyl)monoorganometal Complexes (2003) (0)
- Metal-Promoted Cyclization. Part 20. Palladium-Catalyzed Cyclization of Alkenyl and Aryl Halides Containing α,β-Unsaturated Carbonyl Groups via Intramolecular Carbopalladation. (1989) (0)
- Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds (1996) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS; 15. CONTROLLED CARBOMETALLATION; 6. A SELECTIVE AND EFFICIENT SYNTHESIS OF (E)-4-METHYL-3-ALKEN-1-OLS VIA ZIRCONIUM-CATALYZED CARBOALUMINATION OF TERMINAL ALKYNES (1981) (0)
- Highly Stereoselective Synthesis of Exocyclic Alkenes via Cyclialkylation. (1988) (0)
- Hydrogen Transfer Hydrozirconation of Alkenes with iBuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, and Pd. (2010) (0)
- ACS PRF Funding Leads to Nobel Prize in Chemistry for Two 2010 Laureates (2010) (0)
- Zwitterionic Bis(η-cyclopentadienyl)zirconium(IV) Derivatives (2003) (0)
- Highly Satisfactory Procedures for the Pd‐Catalyzed Cross Coupling of Aryl Electrophiles with in situ Generated Alkynylzinc Derivatives. (2002) (0)
- Highly Chemo‐, Regio‐, and Stereoselective Carbon—Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5‐Dienes and 1,5‐Enynes. (2000) (0)
- NOVEL SYNTHESIS OF AN Ω-ALKYNYLORGANONMETALLIC REAGENT VIA TRIPLE BOND ISOMERIZATION WITH POTASSIUM 3-AMINOPROPYLAMIDE- Ω-(9-BORABICYCLO(3.3.1)NONAN-9-YL)ALKL-YNES (1977) (0)
- Termination of Carbopalladation of Alkynes via Carbonylative Amidation Producing Lactams. (1995) (0)
- C—C Bond Formation by the Reactions of Five-Membered Zirconacycles with Carbon Monoxide, Isocyanides, and Related Carbon Nucleophiles (2003) (0)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐hetero‐ Substituted Compounds Other than Enolates (2003) (0)
- Metal-Promoted Cyclization. Part 28. Regioselective and Diastereoselective Alkyl-Alkene and Alkene-Alkene Coupling Promoted by Zirconocene and Hafnocene. (1990) (0)
- Formation of Bis(η-cyclopentadienyl)zirconium Complexes with Allenes, Silenes, Imines, and Diphenyldiazene Derivatives (2003) (0)
- VIII. Organozirconium Chemistry (2013) (0)
- Bis(η-cyclopentadienyl)metal(IV) Complexes Containing Two Electronegative Heteroatom Groups (2003) (0)
- Use of Alkenes and Grignard Reagents (2012) (0)
- Synthesis of Enol Esters and Enol Lactones via Palladium-Catalyzed Carbonylation of Aryl and Alkenyl Halides. (1991) (0)
- (E)‐1‐Bromo‐4‐trimethylsilyl‐1‐buten‐3‐yne and (E)‐1‐Bromo‐4‐(tert‐butyldimethylsilyl)‐1‐buten‐3‐yne (2003) (0)
- Protonolysis, Deuterolysis, and Halogenolysis (2003) (0)
- Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade. (1995) (0)
- Metal σ-Complexes without π-Ligands of Oxidation State Four (2003) (0)
- Carbonyl Addition and Related Addition Reactions of σ-Organozirconium Complexes (2003) (0)
- Synthesis of Bis(η-cyclopentadienyl)dihalometal(IV) Complexes and Their Derivatives with Modified Cyclopentadienyl Ligands (2003) (0)
- By β,γ-C—C Bond Cleavage (2003) (0)
- By Reduction with Metals (2003) (0)
- Selective Synthesis of Benzene Derivatives via Palladium-Catalyzed Cascade Carbometalation of Alkynes. (1993) (0)
- Hydrozirconation and Hydrogen-Transfer Hydrozirconation (2003) (0)
- By Halogen or Alkyl Abstraction from Bis(η-cyclopentadienyl)organozirconium Complexes (2003) (0)
- A STEREOSELECTIVE SYNTHESIS OF DISUBSTITUTED TRANS-ALKENES BY THE REACTION OF TRANS-ALKENYLTRIALKYLALUMINATES WITH ALKYL HALIDES AND SULFONATES (1976) (0)
- Highly Stereoselective and Efficient Synthesis of ω‐Heterofunctional Di‐ and Trienoic Esters for Horner—Wadsworth—Emmons Reaction via Alkyne Hydrozirconation and Pd‐Catalyzed Alkenylation. (2009) (0)
- A Selective Procedure for α‐Alkenylation of Enones Involving Pd‐ Catalyzed Alkenyl‐Alkenyl Coupling and Its Application to a Convergent and Efficient Synthesis of Nakienone B. (1996) (0)
- Addition of Alkyl(chloro)bis(η-cyclopentadienyl)zirconium Complexes to Aldehydes (2003) (0)
- Novel Structures and Reaction Patterns in Organozirconium and Related Chemistry (1996) (0)
- Light metal hydrides and superconductivity (1991) (0)
- Effects of Organometals on the Palladium-Catalyzed Tandem Carbopalladation - Cross Coupling for Preparing Stereodefined Exocyclic Alkenes. (1991) (0)
- Five-Membered Metallocycle–Bis(η-cyclopentadienyl) Derivatives of Oxidation State Four (2003) (0)
- One-Electron Oxidation of Bis(η-cyclopentadienyl)diorganozirconium (2003) (0)
- Other Protocols for the Synthesis of Five-Membered Zirconacycles and Hafnacycles (2003) (0)
- Catalytic Reactions Involving Bis(η-cyclopentadienyl)hydridozirconium Derivatives (2003) (0)
- Aldol-Type Reactions of 1-Naphthol Catalyzed by Trichloro(η-cyclopentadienyl)zirconium Derivatives (2003) (0)
- Co-condensation of Metal Vapors with Arenes (2003) (0)
- Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes by Halogen Abstraction from Bis(η-cyclopentadienyl)halo(methyl)zirconium (2003) (0)
- Novel and Selective α-Substitution of Ketones and Other Carbonyl Compounds Based on Pd-Catalyzed Cross-Coupling of α,β-Unsaturated Carbonyl Derivatives Containing α-Halogen or α-Metal Groups (1999) (0)
- Back Cover: Widely Applicable Synthesis of Enantiomerically Pure Tertiary Alkyl-Containing 1-Alkanols by Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes and Palladium- or Copper-Catalyzed Cross-Coupling (Chem. Asian J. 8/2013) (2013) (0)
- Method for evaluating ultraviolet light protection effect, evaluation device, and computer-readable storage medium (2013) (0)
- Formation of Trichloromono(η-cyclopentadienyl)metal Derivatives from Metal(IV) Tetrachloride–Bis(dimethyl sulfide) Complexes (2003) (0)
- By Addition of Olefinic and Acetylenic Linkages (Carboboration) (2007) (0)
- Reactions of Zirconacyclopentenes with Allyl and Alkenyl Ethers and Halides (2003) (0)
- Synthesis and Reactivity Zirconocene Derivatives (2004) (0)
- Protonolysis and Deuterolysis (2003) (0)
- Metal π-Complexes Containing η-Ligands Other than η-Cyclopentadienyl (2003) (0)
- Metal-Promoted Cyclization. Part 21. Palladium-Catalyzed Procedures for (3 + 2)Annulation via Intramolecular Alkenylpalladation and Arylpalladation. (1989) (0)
- The Negishi–Takahashi Protocol (2003) (0)
- A Convenient Procedure for Hydrozirconation of Alkynes with i-BuZrCp2Cl Generated in situ by Treatment of Cp2ZrCl2 with t-BuMgCl. (1991) (0)
- Metal–Triene Complexes (2003) (0)
- Metallic Palladium and Its Mixtures (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 36. PALLADIUM-CATALYZED ACYLATION OF ORGANOZINCS AND OTHER ORGANOMETALLICS AS A CONVENIENT ROUTE TO KETONES (1984) (0)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds: Palladium‐Catalyzed α‐Substitution Reactions of Enolates and Related Derivatives Other than the Tsuji–Trost Allylation Reaction (2003) (0)
- Nickel- or Palladium-Catalyzed Cross Coupling. Part 31. Palladium- or Nickel-Catalyzed Reactions of Alkenylmetals with Unsaturated Organic Halides as a Selective Route to Arylated Alkenes and Conjugated Dienes: Scope, Limitations, and (1987) (0)
- Copper-Catalyzed Conjugate Addition of Chlorobis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- Zirconium-Catalyzed Enantioselective Carboalumination of Alkenes (2003) (0)
- 5.3.2.6. From Organoboranes (2007) (0)
- Nickel-Catalyzed Conjugate Addition of Alkenylchlorobis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- By Isomerization and Displacement (2007) (0)
- C—C Bond Formation via Carbonylation and Other Migratory Insertion Reactions of Bis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- Metal–Mono(η-cyclopentadienyl) and –Tris(η-cyclopentadienyl) Complexes and Related Derivatives (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 22. SCOPE OF THE PALLADIUM-CATALYZED COUPLING REACTION OF ORGANOMETALLICS WITH ALLYLIC ELECTROPHILES. EFFECT OF THE LEAVING GROUP (1982) (0)
- Using Organozinc Reagents (2003) (0)
- An Efficient and Selective Synthesis of Nakienone A Involving a Novel Protocol for α‐Alkenylation of Ketones via Palladium‐Catalyzed Alkenyl‐Alkenyl Coupling. (1997) (0)
- Synthesis by Metal‐Mediated Coupling Reactions (2012) (0)
- Reactions of Bis(η-cyclopentadienyl)zirconium(IV) Derivatives with Alkynylmetals Containing Lithium and Magnesium (2003) (0)
- Vinylic Organoboranes. Part 6. A General Synthesis of (E)-Disubstituted Alkenes or Ketones via the (E)-(1-Substituted-1-Alkenyl)boronic Esters. (1987) (0)
- Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes by Alkyl Abstraction Using a Lewis Acid (2003) (0)
- Metal-Promoted Cyclization. Part 12. A Selective Method for the Synthesis of Stereodefined Exocyclic Alkenes via Allylmetalation of Propargyl Alcohols. (1987) (0)
- Copper-Catalyzed Allylation of Zirconacyclopentadienes (2003) (0)
- Reactions of Bis(η-cyclopentadienyl)zirconium(IV) Derivatives with Alkyl- and Arylmetals Containing Lithium or Magnesium, or with Metal Hydrides (2003) (0)
- Other Zirconium-Catalyzed Carbometalation Reactions of Alkynes and Alkenes (2003) (0)
- (E)‐1‐Bromo‐2‐iodoethylene (2003) (0)
- CARBOMETALATION. 13. SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 28. A SELECTIVE SYNTHESIS OF ALKENYLMERCURIC CHLORIDES VIA ALKENYLALANES (1982) (0)
- EFD and CFD Research of Water-Dropping Aerodynamics for Fire-Fighting Amphibian (2011) (0)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling. Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. Part 26. (1982) (0)
- Metal-Promoted Cyclization. Part 24. Synthesis of Cyclopentanol Derivatives via Palladium-Catalyzed Cyclic Allylmetalation-Dehydrometalation. (1989) (0)
- SYNTHESIS OF ALPHA -IODO-ALPHA , BETA -UNSATURATED KETONES BY THE REACTIONOF A-SILYL-ALPHA , BETA -UNSATURATED KETONES WITH ICL OR ICL-ALCL3 (1999) (0)
- Reactions with Organometals Containing Electropositive Metals (2003) (0)
- Organopalladium Compounds Containing Pd(0) and Pd(II). General Discussion of the Methods of Synthesis and in situ Generation of Organopalladium Compounds (2003) (0)
- Palladium-Catalyzed Hydrogenation: Palladium-Catalyzed Heterogeneous Hydrogenation (2003) (0)
- Migratory Insertion Reactions of Organometallics. Part 3. Carbon-Carbon Bond-Forming Reactions of Organotransition Metals with α- or γ-Haloorganolithium Reagents. (1989) (0)
- Coupling of Propene and 2-Methylpyridine Catalyzed by Cationic Bis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Bis(η-cyclopentadienyl)hydridometal(IV) Complexes (2003) (0)
- Reduction of Zirconium(IV) and Hafnium(IV) Compounds (2003) (0)
- Diastereoselective Zirconocene‐Promoted Bicyclization‐Carbonylation of Allylically Methyl‐Substituted Enynes. Synthesis of (+)‐Iridomyrmecin. (1992) (0)
- Di‐n‐butylbis(cyclopentadienyl)zirconium (2005) (0)
- Organometallic Reactions Catalyzed by Five-Membered Zirconacycles (2003) (0)
- Nickel- or Palladium-Catalyzed Cross Coupling of Alkenylchlorobis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Reactions of Five-Membered Zirconacycles Leading to the Formation of C—H(D) and C—X Bonds (2003) (0)
- Magical Power of d-Block Transition Metals as Catalysts for Organic Synthesis (2011) (0)
- 1‐Chloro‐2‐iodoethylene (2001) (0)
- Trimethylaluminum–Dichlorobis(η5‐cyclopentadienyl)zirconium (2001) (0)
- Frontispiece: Enantioselective Synthesis of Chiral Isotopomers of 1‐Alkanols by a ZACA–Cu‐Catalyzed Cross‐Coupling Protocol (2014) (0)
- By Insertion Reactions of Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Carbometalative Ring-Expansion Reactions of Three-Membered Zirconocene and Hafnocene Derivatives (2003) (0)
- Zirconium-Promoted Bicyclization of Enynes. Effects of Enyne Structure. (1987) (0)
- anti-Hydroalumination of Homo- and Bishomopropargyl Alcohols. (2010) (0)
- trans‐Dichlorobis(triphenylphosphine)palladium(II) (2008) (0)
- Using Grignard or Other Magnesium Reagents (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 7. A HIGHLY STEREO-, REGIO-, AND CHEMOSELECTIVE SYNTHESIS OF CONJUGATED DIENES BY THE PALLADIUM-CATALYZED REACTION OF (E)-1-ALKENYLZIRCONIUM DERIVATIVES WITH ALKEN (1978) (0)
- Outline of Aerial Firefighting and Firefighting Amphibian (2015) (0)
- SELECTIVE CARBON‐CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 35. A CONVENIENT SYNTHESIS OF UNSYMMETRICAL BIBENZYLS, HOMOALLYLARENES, AND HOMOPROPARGYLARENES VIA PALLADIUM‐CATALYZED CROSS COUPLING (1984) (0)
- Metal Promoted Cyclization. Part 10. A Novel Synthesis of Cyclopentenones and Cyclohexenones via Cycliacylation of Lithioalkenylcarboxamides. (1986) (0)
- Palladium- or Nickel-Catalyzed Cross Coupling Involving Proximally Heterofunctional Reagents (56 Literaturzitate). (1983) (0)
- Formation of Bis(η-cyclopentadienyl)zirconium–Benzyne Complexes (2003) (0)
- 5.8.2.11.3. by Transmetallation from Other Metal Organometallics to Metal Halides (2007) (0)
- PREPARARTION OF SECONDARY ALCOHOLS BY REACTION OF TRIALKYLBORANES WITH BIS(PHENYLTHIO)METHYL-LITHIUM (1976) (0)
- Reactions of Allylbis(η-cyclopentadienyl)zirconium Derivatives with Aldehydes (2003) (0)
- C—C Bond Formation via Polar Reactions of Five-Membered Zirconacycles with Carbon Electrophiles and Related π-Compounds (2003) (0)
- General Guidelines for References Pertaining to Palladium and Organopalladium Chemistry (2003) (0)
- Strictly Regiocontrolled Method for α‐Alkenylation of Cyclic Ketones via Palladium‐Catalyzed Cross‐Coupling. (1992) (0)
- Migratory Insertion of Isocyanides and Carbon Monoxide (2003) (0)
- Bis(η-cyclopentadienyl)monometallo- and Bis(η-cyclopentadienyl)dimetallozirconium Complexes (Excluding Hydrido Derivatives) (2003) (0)
- Carbon‐Carbon Bond Formation by the Reaction of Organolithiums with . alpha.‐Lithiated Cyclic Enol Ethers. Stereoselective Synthesis of . beta.‐ and γ‐Hydroxy Di‐ and Trisubstituted Alkenes. (1992) (0)
- Highly Stereo- and Regiocontrolled Cyclopentannulation via Allylphosphonate Conjugate Addition and Hydroboration-Oxidation- Elimination. Synthesis of Pentalenic Acid with Virtually Complete Stereo- and Regiocontrol. (1991) (0)
- The Erker–Buchwald Protocol (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 20. HIGHLY SELECTIVE SYNTHESIS OF ALLYLATED ARENES AND DIARYLMETHANES VIA PALLADIUM-CATALYZED CROSS COUPLING INVOLVING BENZYLIC DERIVATIVES (1981) (0)
- PART I. BASIC CLEAVAGE OF ARYLSULFONAMIDES. PART II. THE SYNTHESES OF SOME BICYCLIC COMPOUNDS DERIVED FROM PIPERAZINE WHICH CONTAIN BRIDGEHEAD NITROGEN ATOMS. (1963) (0)
- Synthesis of Bis(η-cyclopentadienyl)dihalometal(IV) Complexes (2003) (0)
- Palladium-Catalyzed Cyclic Acylmetalation of Allylic Electrophiles as a Route to Cyclopentenone Derivatives. (1989) (0)
- The rich and diverse spectrum of organic chemistry in the millennium: Report from the 37th National Organic Symposium (2001) (0)
- Anisotropic microwave complex conductivities in λ-(BEDT-TSF)2FeCl4 (2003) (0)
- C—C Bond Formation via Metal-Catalyzed Reactions of Bis(η-cyclopentadienyl)monoorganozirconium Complexes with Organic Electrophiles (2003) (0)
- Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes. (1995) (0)
- Palladium-Catalyzed Highly Diastereoselective Cyclic Carbopalladation—Carbonylative Esterification Tandem Reaction of Iododienes and Iodoarylalkenes. (1999) (0)
- CONTROLLED CARBOMETALATION. II. THE ADDITION REACTION OF TRIMETHYLALANE-TITANOCENE DICHLORIDE WITH ACETYLENES (1979) (0)
- Construction of Deoxypropionate Chains via Asymmetric Carboalumination (2006) (0)
- Magnetic response of microwave complex conductivities in antiferromagnetic insulating states of λ-(BEDT-TSF)2FeCl4 (2004) (0)
- A Novel Hydrogen Transfer Hydroalumination of Alkenes with Triisobutylaluminum Catalyzed by Pd and Other Late Transition Metal Complexes. (2001) (0)
- Novel Head‐to‐Tail Alkyl‐Alkene or Alkene‐Alkene Coupling via Zirconium‐Catalyzed Reaction of Alkylmagnesium Derivatives (II) with Monosubstituted Alkenes (I). (1992) (0)
- Cyclization Reactions of ω-Tosyloxy-1-alkynyl- and ω- Tosyloxy-1-alkenylborates and Their ω-Halo Analogues. (1993) (0)
- Professor Ei-ichi Negishi (2001) (0)
- Profile of Professor H. C. Brown (1982) (0)
- Toothy spinning process and apparatus for performing the method (1975) (0)
- (2E)-1-TRIMETHYLSILYL-3,7-DIMETHYL-2,6-OCTADIENE (GERANYLTRIMETHYLSILANE) (1986) (0)
- C—C Bond Formation Reactions of Organometals Catalyzed by Bis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- Highly enantioselective synthesis of γ-, δ-, and e-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)–Cu- or Pd-catalyzed cross-coupling (2014) (0)
- Background for Part II (2003) (0)
- Short Biographical Sketch - Ei-ichi Negishi (2012) (0)
- With work we need to continue our hobby (2016) (0)
- LIST OF PUBLICATIONS BY EI-ICHI NEGISHI (2012) (0)
- By Pyrolytic Elimination of H2 (2007) (0)
- Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β′ Carbon—Carbon Bond Cleavage of Zirconacyclopentenes. (1999) (0)
- "Ate" Complexes of Metal–Bis(η-cyclopentadienyl) and Other Derivatives (2003) (0)
- Efficient Synthesis of Carbobicyclic and Carbopolycyclic Compounds via Intramolecular Carbopalladation Catalyzed by Palladium-Phosphine Complexes. (1988) (0)
- Metal π-Complexes Containing η-, η-, and η-Ligands (2003) (0)
- Formation of Zirconium–Carbene Complexes (2003) (0)
- Zirconium–Nitrene Complexes by Cleavage of Metallacycles (2003) (0)
- Formation of Imido- or Hydrazidozirconium Complexes (2003) (0)
- SYNTHESES OF CHIRAL HETEROCYCLIC COMPOUNDS VIA ZIRCONIUM-CATALYZED ASYMMETRIC CARBOALUMINATION OF ALKYNES (ZACA REACTION) (Dedicated to Professor Victor Snieckus on the occasion of his 77th birthday) (2014) (0)
- By Protonation with Carborane (2003) (0)
- π-d Correlation in λ-(BEDT-TSF)_2Fe_ Ga_xCl_4 by ESR Measurements(Condensed matter: electronic structure and electrical, magnetic, and optical properties) (2006) (0)
- Migratory Insertion Reactions of Zirconacycles with Carbon Monoxide and Isocyanides (2003) (0)
- Protonolysis, Halogenolysis, Oxidation, and Related Heteroatom—Carbon Bond Formation (2003) (0)
- Metal‐Promoted Cyclization. Part 19. Novel Bicyclization of Enynes and Diynes Promoted by Zirconocene Derivatives and Conversion of Zirconabicycles into Bicyclic Enones via Carbonylation. (1989) (0)
- Palladium-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, Aldehydes, and Other Carbonyl Compounds (2003) (0)
- Metal–Bis(η-cyclopentadienyl) Derivatives Containing Carbene, Nitrene, and Other Doubly Bonded Ligands (2003) (0)
- Synthesis of (+)-Scyphostatin (2010) (0)
- A Convenient and Genuine Equivalent to HZrCp2Cl Generated in situ from ZrCp2Cl2—DIBAL‐H. (2006) (0)
- Metal–Bis(η-cyclopentadienyl) Complexes and Related Derivatives of Oxidation State Four (2003) (0)
- Organoboron Compounds: Organoborane Chemistry . Thomas Onak. Academic Press, New York, 1975. xii, 360 pp., illus. $38. Organometallic Chemistry. (1976) (0)
- Formation of Zirconium Complexes Containing an Amido-Linked Cyclopentadienyl Ligand (2003) (0)
- Cationic Metal–Bis(η-cyclopentadienyl) Derivatives of Oxidation State Four (2003) (0)
- Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2- alkenylbenzenes. (2010) (0)
- AN INTERMOLECULAR ALKYL-TRANSFER REACTION OF TETRAORGANOBORATE ANIONS WITH ACYL HALIDES. A NOVEL METHOD FOR MODERATING THE CARBANION REACTIVITY (1975) (0)
- Pd-catalyzed cross-coupling reactions exhibiting catalystturnover numbers (TONs) exceeding one million (2012) (0)
- "Ate" Complexes of Bis(η-cyclopentadienyl)metal(IV) Derivatives (2003) (0)
- Metal–η-Arene Complexes (2003) (0)
- HYDROBORATION PART 37, STRUCTURAL STUDY OF THE HYDROBORATION OF OLEFINS WITH THEXYLBORANE IN THE MOLAR RATIO OF 1 TO 1, A CONVENIENT SYNTHESIS OF THEXYLMONOALKYLBORANES AND THEIR READY CONVERSION TO MONOALKYLBORANES (1975) (0)
- Le palladium, magique des chimistes (2010) (0)
- One‐Pot Conversion of Alkynes and Alkenes into One‐Carbon Homologated Aldehydes via Hydrozirconation ‐ Isocyanide Insertion ‐ Hydrolysis. (1988) (0)
- ORGANOBORANES AND ORGANOBORATE ANIONS, NEW CLASSES OF ELECTROPHILES AND NUCLEOPHILES IN ORGANIC SYNTHESIS (1975) (0)
- Cyclic Carbopalladation of Alkynes Terminated by Carbonylative Amidation. (1996) (0)
- Organozirconium Compounds as New Reagents and Intermediates (1986) (0)
- Formation of 1-Phenyl-1-indole from a Hydrazidozirconium Complex (2003) (0)
- Cp2ZrCl2-DIBAL-H As a Convenient in situ Equivalent to Cp2ZrHCl (2006) (0)
- Palladium-Catalyzed Carbonylative Cyclization Cascade with Iododienes and -trienes. (1997) (0)
- C—C Bond Formation by the Transition-Metal-Catalyzed Reaction of Five-Membered Zirconacycles (2003) (0)
- By Amine Elimination (2003) (0)
- Metal σ-Complexes of Oxidation States below Four (2003) (0)
- Dielectric Slowing Down toward the Magnetically Ordered State in a Polar Conductor (EDT-TTFVO)_2FeBr_4(Condensed matter: electronic structure and electrical, magnetic, and optical properties) (2007) (0)
- Zirconium-Catalyzed Carboalumination of Alkynes (2003) (0)
- Reaction of 3-Zircona-1-cyclopentenes and Zirconacyclopentanes with Aldehydes. A Selective and Convenient Synthesis of 4-Penten-1-ols, (Z)- 5-Iodo-4-penten-1-ols, and Related Alkanols. (2010) (0)
- Perhydro‐9b‐Boraphenalene and Perhydro‐9b‐Phenalenol (2003) (0)
- BIS-(BOROLAN), EIN SCHWER FASSBARES BIS-(BORACYCLAN) (1972) (0)
- By Ligand Exchange of Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- HYDROBORATION. 70. THE POLYCYCLIC HYDROBORATION OF ACYCLIC AND CYCLIC TRIENES S WITH BORANE IN TETRAHYDROFURAN AND TRIETHYLAMINE-BORANE. REEXAMINATION OF THE STEREOCHEMISTRY OF ISOMERIC PERHYDRO-9B-BORAPHENALENES (1985) (0)
- Other Reactions of Bis(η-cyclopentadienyl)diorganozirconium Complexes (2003) (0)
- Zirconium‐Catalyzed Asymmetric Carboalumination (ZACA Reaction) of 1,4‐Dienes. (2006) (0)
- POTASSIUM (2-METHYL-l-CYCLOHEXENYLOXY)TRIETHYLBORATE (1986) (0)
- Zirconate Complexes of Bis(η-cyclopentadienyl)zirconium(II) Derivatives (2003) (0)
- Convenient Synthesis of Diene-Zirconocenes and Regioselective Partial Reduction of the More Highly Substituted Double Bonds of Conjugated Dienes via Complexation with Zirconocenes and Protonolysis. (1994) (0)
- A Genealogy of Pd-Catalyzed Cross-Coupling. (2002) (0)
- By Reductive Elimination or Migration (2003) (0)
- On the Origin of the Configurational Instability of (l-Silyl-1-alkenyl)lithiums and Related Alkenylmetals. (1986) (0)
- Using Organoaluminum Reagents (2003) (0)
- Palladium-Catalyzed Cross-Coupling Involving Alkylmetals or Alkyl Electrophiles (2003) (0)
- A PALLADIUM-CATALYZED STEREOSPECIFIC SUBSTITUTION REACTION OF HOMOALLYLZINCS WITH β-BROMO-SUBSTITUTED α,β-UNSATURATED CARBONYL DERIVATIVES. A HIGHLY SELECTIVE SYNTHESIS OF MOKUPALIDE (1981) (0)
- C—C Bond Formation via Polar Reactions of Chlorobis(η-cyclopentadienyl)monoorganozirconium Complexes with Carbon Electrophiles (2003) (0)
- Novel Bicyclization Methodology via Cyclialkylation of ω-Halo-1-metallo-1-alkynes Containing Aluminum and Zinc. (1988) (0)
- Metal–η-Arene and –η-Arene Complexes (2003) (0)
- Palladium‐Catalyzed Synthesis of Conjugated Dienes: (5Z,7E)‐5,7‐Hexadecadiene (2003) (0)
- By α-Hydrogen Elimination (2003) (0)
- Other Migratory Insertion Reactions (2003) (0)
- By Radical Chlorination of Dichlorobis(η-cyclopentadienyl)zirconium (2003) (0)
- 15pWH-4 ESR study of λ-(BEDT-TSF)_2Fe_ Ga_xCl_4 (x=0, 0.4, 1.0) (2004) (0)
- Superconductivity and pseudogap states in λ-(BEDT-TSF)2GaCl4: Microwave conductivity measurements (2006) (0)
- Synthesis of Arenes from Three Different Alkynes by Copper- or Nickel-Mediated Reactions of Alkynes with Zirconacyclopentadienes (2003) (0)
- Synthesis of α‐Iodo‐α,β‐Unsaturated Ketones by the Reaction of α‐Silyl‐α,β‐Unsaturated Ketones with ICl or ICl—AlCl3. (1999) (0)
- Reactions of Bis(η-cyclopentadienyl)metal(IV) Derivatives with α- and γ-Hetero-Substituted Alkyl- and Alkenyllithiums (2003) (0)
- Efficient and Diastereoselective Synthesis of (+)-Goniobutenolide A via Palladium-Catalyzed Ene-Yne Cross Coupling-Lactonization Cascade. (1997) (0)
- Total Synthesis of (+)‐Scyphostatin Featuring an Enantioselective and Highly Efficient Route to the Side‐Chain via Zr‐Catalyzed Asymmetric Carboalumination of Alkenes (ZACA). (2010) (0)
- Synthesis of Bis(η-cyclopentadienyl)metal(IV) Complexes Containing Monohalo and/or Group 16 or 15 Atom Ligands and Their Derivatives with Modified Cyclopentadienyl Ligands (2003) (0)
- Principle of Activation of Electrophiles by Electrophiles Through Dimeric Association — Two Are Better than One (1999) (0)
- Complexation with Activated Zirconium(IV) and Hafnium(IV) Compounds of Low Electron Count (2003) (0)
- Other Stoichiometric Reactions (2003) (0)
- Copper-Catalyzed Acylation of Zirconacycles (2003) (0)
- Pd‐Catalyzed Selective Tandem Arylation—Alkylation of 1,1‐Dihalo‐1‐alkenes with Aryl‐ and Alkylzinc Derivatives to Produce α‐Alkyl‐substituted Styrene Derivatives. (2004) (0)
- Metal-Promoted Cyclization. Part 25. Palladium-Catalyzed Cascade Carbometalation of Alkynes and Alkenes as an Efficient Route to Cyclic and Polycyclic Structures. (1989) (0)
- Coupling Reaction of Diiodobenzene with Zirconacyclopentadienes (2003) (0)
- Synthesis of Bis(η-cyclopentadienyl)diorganometal Complexes and Their Derivatives (2003) (0)
- Bis(η-cyclopentadienyl)zirconium(II)-Catalyzed C—C Bond Formation (2003) (0)
- Synthesis of Hydrazulenes via Zr-Promoted Bicyclization of Enynes and Transition Metal-Catalyzed or Radical Cyclization of Alkenyl Iodides. Efficient Synthesis of (.+-.)-7-epi-β-Bulnesene. (1997) (0)
- Efficient and Stereoselective Synthesis of Freelingyne (IX) via Pd-Catalyzed Cross Coupling and Lactonization. (1998) (0)
- Titanium‐Catalyzed Cascade Carboalumination of Dienes and Trienes. (1995) (0)
This paper list is powered by the following services:
Other Resources About Ei-ichi Negishi
What Schools Are Affiliated With Ei-ichi Negishi?
Ei-ichi Negishi is affiliated with the following schools:
