Ei-ichi Negishi
#3,791
Most Influential Person
Japanese chemist
Why Is Ei-ichi Negishi Influential?
(Suggest an Edit or Addition)Negishi is the Herbert C. Brown Distinguished Professor and Director of the Negishi-Brown Institute at Purdue. Negishi received his bachelor’s degree in Chemistry from the University of Tokyo in 1958. He received his Ph.D. in Chemistry from the University of Pennsylvania in 1963. Negishi won the Nobel Prize in Chemistry in 2010, along with Richard F. Heck and Akira Suzuki.
Negishi is known for his discovery of the “Negishi coupling,” an important reaction that forms carbon-carbon bonds. The Negishi coupling has important applications for the synthesis of natural products. Negishi coupling has been investigated also for its use in medical applications such as in the treatment of asthma.
Negishi is world-renowned as a chemist. He has won numerous awards for his career in chemistry, including the Noble Prize in Chemistry in 2010. Negishi also received Japan’s high honors, in both the Chemical Society of Japan Award and the Order of Culture, in 1997 and 2010, respectively. Negishi became a Fellow of the American Academy of Arts and Sciences in 2011. The following year he became Fellow of the Royal Society of Chemistry.Featured in Top Influential Chemists Today
According to Wikipedia, Ei-ichi Negishi was a Japanese chemist who was best known for his discovery of the Negishi coupling. He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. He was awarded the 2010 Nobel Prize in Chemistry "for palladium catalyzed cross couplings in organic synthesis" jointly with Richard F. Heck and Akira Suzuki.
Ei-ichi Negishi's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- Handbook of organopalladium chemistry for organic synthesis (2002) (1992)
- Palladium-catalyzed alkynylation. (2003) (947)
- Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation (1982) (764)
- Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides (1977) (570)
- Magical power of transition metals: past, present, and future (Nobel Lecture). (2011) (517)
- Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes☆ (1986) (407)
- Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides (1977) (361)
- Recent advances in efficient and selective synthesis of di-, tri-, and tetrasubstituted alkenes via Pd-catalyzed alkenylation-carbonyl olefination synergy. (2008) (330)
- Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation (1989) (310)
- A novel stereospecific alkenyl-alkenyl cross-coupling by a palladium- or nickel-catalyzed reaction of alkenylalanes with alkenyl halides (1976) (260)
- Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest (1994) (254)
- Palladium-catalyzed cross-coupling reaction of homoallylic or homopropargylic organozincs with alkenyl halides as a new selective route to 1,5-dienes and 1,5-enynes (1980) (245)
- Organometallics in organic synthesis (1980) (242)
- Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins (1978) (223)
- Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism (1987) (210)
- Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins (1978) (207)
- Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis (2007) (202)
- Palladium-catalyzed acylation of organozincs and other organometallics as a convenient route to ketones☆ (1983) (184)
- Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses (1981) (184)
- Controlled carbometalation. 20. Carbometalation reaction of alkynes with organoalene-zirconocene derivatives as a route to stereo-and regiodefined trisubstituted alkenes (1985) (178)
- Regio- and stereoselective synthesis of ?-alkylidenebutenolides and related compounds (1997) (165)
- Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes (1985) (136)
- Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization (1987) (125)
- Clean and convenient procedure for converting primary alkyl iodides and .alpha.,.omega.-diiodoalkanes into the corresponding alkyllithium derivatives by treatment with tert-butyllithium (1990) (124)
- Selective carbon-carbon bond formation via transition metal catalysis. 4. A novel approach to cross-coupling exemplified by the nickel-catalyzed reaction of alkenylzirconium derivatives with aryl halides (1977) (124)
- Remarkably pair- and regioselective carbon-carbon bond-forming reaction of zirconacyclopentane derivatives with Grignard reagents (1991) (123)
- Facile cleavage of the CβCβ′ bond of zirconacyclopentenes. Convenient method for selectively coupling alkynes with alkynes, nitriles, and aldehydes (1993) (123)
- A versatile and selective route to difunctional trisubstituted (E)-alkene synthons via zirconium-catalyzed carboalumination of alkynes (1981) (123)
- Palladium-Catalyzed Cyclization of .omega.-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation (1995) (118)
- Metal-promoted cyclization. 25. Palladium-catalyzed cascade carbometalation of alkynes and alkenes as an efficient route to cyclic and polycyclic structures (1989) (115)
- Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C−H Activation (1996) (115)
- Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism (1996) (114)
- Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations. (1998) (111)
- Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" way. (2010) (110)
- Conversion of methyl ketones into terminal acetylenes and (E)-trisubstituted olefins of terpenoid origin (1980) (109)
- Selective carbon-carbon bond formation via transition-metal catalysis. Part 18. Palladium-catalyzed stereo- and regiospecific coupling of allylic derivatives with alkenyl- and arylmetals. A highly selective synthesis and 1,4-dienes (1981) (107)
- Organozirconium Compounds in Organic Synthesis (1988) (107)
- ZIRCONIUM-CATALYZED ENANTIOSELECTIVE METHYLALUMINATION OF MONOSUBSTITUTED ALKENES (1995) (104)
- Novel stereoselective alkenyl–aryl coupling via nickel-catalysed reaction of alkenylanes with aryl halides (1976) (103)
- Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes (1989) (102)
- Selective carbon-carbon bond formation via transition metal catalysis. 37. Controlled carbometalation. 16. Novel syntheses of .alpha.,.beta.-unsaturated cyclopentenones via allylzincation of alkynes (1983) (99)
- A novel, highly selective, and general methodology for the synthesis of 1,5-diene-containing oligoisoprenoids of all possible geometrical combinations exemplified by an iterative and convergent synthesis of coenzyme Q(10). (2002) (97)
- Pd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materials (2014) (94)
- Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes (1996) (90)
- ONE-STEP CONSTRUCTION OF FUSED TRICYCLIC AND TETRACYCLIC STRUCTURES FROM ACYCLIC PRECURSORS VIA CYCLIC CARBOPALLADATION (1990) (89)
- Highly stereoselective synthesis of (1E)-2-methyl-1,3-dienes by palladium-catalyzed trans-selective cross-coupling of 1,1-dibromo-1-alkenes with alkenylzinc reagents. (2004) (89)
- A quarter of a century of explorations in organozirconium chemistry. (2005) (88)
- Metal-promoted cyclization. 28. Regioselective and diastereoselective alkyl-alkene and alkene-alkene coupling promoted by zirconocene and hafnocene (1989) (84)
- Clean inversion of configuration in the Pd-catalyzed cross-coupling of 2-bromo-1,3-dienes. (2003) (83)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling (1982) (82)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling (1982) (82)
- A palladium-catalyzed stereospecific substitution reaction of homoallylzincs with .beta.-bromo-substituted .alpha.,.beta.-unsaturated carbonyl derivatives. A highly selective synthesis of mokupalide (1980) (82)
- A genealogy of Pd-catalyzed cross-coupling (2002) (81)
- Zipper-mode cascade carbometallation for construction of polycyclic structures (1992) (81)
- Metal-promoted cyclization. 26. Palladium-catalyzed cyclization of benzyl halides and related electrophiles containing alkenes and alkynes as a novel route to carbocycles (1989) (79)
- Zirconium-catalyzed, highly regioselective hydrosilation reaction of alkenes and X-ray structures of silyl(hydrido)zirconocene derivatives (1991) (79)
- Apparent endo-mode cyclic carbopalladation with inversion of alkene configuration via exo-mode cyclization-cyclopropanation rearrangement (1992) (77)
- All-catalytic, efficient, and asymmetric synthesis of alpha,omega-diheterofunctional reduced polypropionates via "one-pot" Zr-catalyzed asymmetric carboalumination-Pd-catalyzed cross-coupling tandem process. (2005) (77)
- Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-.beta.-Iodoenones and Related Derivatives Producing .gamma.-Lactones and .gamma.-Lactams (1995) (76)
- Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with .alpha.- or .gamma.-haloorganolithium reagents (1989) (75)
- Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling. (2009) (74)
- Selective carbon-carbon bond formation via transition-metal catalysis. 33. Palladium-catalyzed cross-coupling reaction of .alpha.-heterosubstituted alkenylmetals. A stereoselective route to heterosubstituted dienes suitable for the Diels-Alder reaction (1983) (74)
- Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the sonogashira alkynylation. (2003) (72)
- An efficient and general route to reduced polypropionates via Zr-catalyzed asymmetric CC bond formation. (2004) (72)
- Anti-Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non-Chelation-Controlled Syn-Carbometalation and Chelation-Controlled Isomerization† (1997) (71)
- Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade (1994) (71)
- Widely applicable Pd-catalyzed trans-selective monoalkylation of unactivated 1,1-dichloro-1-alkenes and Pd-catalyzed second substitution for the selective synthesis of E or Z trisubstituted alkenes. (2006) (70)
- Cyclic cascade carbopalladation reactions as a route to benzene and fulvene derivatives (1992) (70)
- Metal promoted cyclization. 9. Controlled and catalytic acylpalladation. A novel route to cyclopentenone and cyclohexenone derivatives (1985) (70)
- An odyssey from stoichiometric carbotitanation of alkynes to zirconium-catalysed enantioselective carboalumination of alkenes (1996) (69)
- Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β‘ Carbon−Carbon Bond Cleavage of Zirconacyclopentenes (1998) (68)
- Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol. (2006) (66)
- Metal promoted cyclization. 18. Novel cyclialkylation reactions of (.omega.-halo-1-alkenyl)metal derivatives. Synthetic scope and mechanism (1988) (64)
- Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones (1982) (64)
- Metal-promoted cyclization. 17. A novel bicyclization methodology via cyclialkylation of .omega.-halo-1-metallo-1-alkynes containing aluminum and zinc (1988) (64)
- Catalytic and selective conversion of (Z)-2-en-4-ynoic acids to either 2H-pyran-2-ones in the presence of ZnBr2 or (Z)-5-alkylidenefuran-2(5H)-ones in the presence of Ag2CO3 (2002) (64)
- Strictly regio-controlled method for α-alkenylation of cyclic ketones via palladium-catalyzed cross coupling (1991) (62)
- A novel, selective, and efficient route to carotenoids and related natural products via Zr-catalyzed carboalumination and Pd- and Zn-catalyzed cross coupling. (2001) (61)
- Highly Efficient and Selective Procedures for the Synthesis of γ-Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E (1997) (61)
- Stereo- and regioselective routes to allylic silanes☆ (1982) (60)
- Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations (1997) (60)
- A highly efficient and selective synthesis of lissoclinolide featuring hydrogen transfer hydrozirconation,trans-selective Pd-catalyzed cross coupling of alkenylzirconiums with 1,1-dibromoalkenes and Ag-catalyzed lactonization providing(Z)-γ-alkylidenebutenolides (1999) (60)
- A method for the preparation of terminal and internal conjugated diynes via palladium-catalyzed cross-coupling (1984) (60)
- Highly selective synthesis of allylated arenes and diarylmethanes via palladium-catalyzed cross coupling involving benzylic derivatives (1981) (59)
- Reaction of 3-zircona-1-cyclopentenes and zirconacyclopentanes with aldehydes. A selective and convenient synthesis of 4-penten-1-ols, (Z)-5-iodo-4-penten-1-ols, and related alkanols (1994) (58)
- Palladium-Catalyzed Cyclization of 1-Iodo-Substituted 1,4-, 1,5-, and 1,6-Dienes as Well as of 5-Iodo-1,5-dienes in the Presence of Carbon Monoxide (1996) (58)
- Highly selective synthesis of vitamin A and its derivatives. Critical comparison of some known palladium-catalyzed alkenyl-alkenyl coupling reactions (1991) (57)
- Efficient and selective synthesis of siphonarienolone and related reduced polypropionates via Zr-catalyzed asymmetric carboalumination. (2004) (57)
- An efficient and general method for the synthesis of alpha,omega-difunctional reduced polypropionates by Zr-catalyzed asymmetric carboalumination: synthesis of the scyphostatin side chain. (2004) (56)
- Zirconium-promoted bicyclization of enynes. Effects of enyne structure (1987) (56)
- Effects of organometals on the palladium-catalyzed tandem carbopalladation-cross coupling for preparing stereodefined exocyclic alkenes (1990) (56)
- Highly stereo- and regiocontrolled cyclopentannulation via allylphosphonate conjugate addition and hydroboration-oxidation-elimination. Synthesis of pentalenic acid with virtually complete stereo- and regiocontrol (1991) (56)
- Palladium-catalyzed cross-coupling reaction of alkynylzincs with benzylic electrophiles (2005) (56)
- A convenient and asymmetric protocol for the synthesis of natural products containing chiral alkyl chains via Zr-catalyzed asymmetric carboalumination of alkenes. Synthesis of phytol and vitamins E and K. (2001) (55)
- Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2. (2003) (55)
- ‘Bis(triphenylphosphine)palladium:’ its generation, characterization, and reactions (1986) (54)
- Palladium-catalyzed or -promoted reductive carbon−carbon coupling. Effects of phosphines and carbon ligands (1987) (54)
- anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles (1982) (54)
- Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes (1994) (52)
- An efficient and stereoselective synthesis of xerulin via Pd-catalyzed cross coupling and lactonization featuring (E)-lodobromoethylene as a novel two-carbon synthon. (2000) (52)
- Novel silicon-promoted cycloalkylation of alkenylmetal derivatives (1983) (52)
- Zirconium-catalyzed carboalumination of alkynes and enynes as a route to aluminacycles and their conversion to cyclic organic compounds (1998) (51)
- Palladium-catalyzed reactions of allylic electrophiles with organometallic reagents. A regioselective 1,4-elimination and a regio- and stereoselective reduction of allylic derivatives (1982) (51)
- A general and convenient procedure for the preparation of zirconocene complexes of alkenes and conjugated dienes (1991) (51)
- Highly stereoselective and general synthesis of (z)-3-methyl-2-alken-1-ols via palladium-catalyzed cross coupling of (z)-3-iodo-2-buten-1-ol with organozincs and other organometals (1993) (50)
- A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols (1986) (49)
- Convenient preparative method of α,β-disubstituted cyclopentenone by zirconium promoted intermolecular coupling of an alkyne, EtMgBr (or ethylene) and CO (1997) (48)
- Principle of Activation of Electrophiles by Electrophiles through Dimeric Association—Two Are Better than One (1999) (48)
- Complete reversal of regiochemistry in cyclic acylpalladation. Novel synthesis of quinones. (1986) (47)
- Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group☆ (1981) (47)
- Novel zirconocene-promoted carbon-carbon bond formation via a 1,2-migration reaction of alkynylzirconium derivatives (1991) (47)
- Fully reagent-controlled asymmetric synthesis of (-)-spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). (2007) (47)
- Palladium-catalyzed carbonylative cyclization via trapping of acylpalladium derivatives with internal enolates. Its scope and factors affecting the C-to-O ratio (1994) (46)
- Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions (1987) (45)
- Stereoselective synthesis of the side chains of mycolactones A and B featuring stepwise double substitutions of 1,1-dibromo-1-alkenes. (2006) (45)
- The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetals (1986) (45)
- Diastereoselective zirconocene-promoted bicyclization-carbonylation of allylically methyl-substituted enynes. Synthesis of (+)-iridomyrmecin (1992) (45)
- A Selective Synthesis of (E)-2-Methyl-1-alkenyl Iodides via Zirconium-Catalyzed Carboalumination (1979) (45)
- Use of InCl(3) as a cocatalyst and a Cl(2)Pd(DPEphos)-P(2-furyl)(3) catalyst system for one-pot hydrometalation-cross-coupling and carbometalation-cross-coupling tandem processes. (2004) (43)
- Highly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration-Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol. (2011) (43)
- Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals (2003) (43)
- A mild and selective synthesis of cyclopropene and cyclopropane derivatives via cycliallylation of alkenyllithiums (1985) (43)
- Carbonylative cyclization via intramolecular trapping of acylmetal derivatives by carbon nucleophiles catalyzed by late transition metals (1989) (43)
- Convenient method for the tertiary alkyl-alkynyl coupling via organoalanes (1975) (42)
- Highly stereoselective total synthesis of fully hydroxy-protected mycolactones A and B and their stereoisomerization upon deprotection. (2011) (42)
- Efficient synthesis of carbobicyclic and carbopolycyclic compounds via intramolecular carbopalladation catalyzed by palladium-phosphine complexes (1988) (42)
- Strictly Regiocontrolled α-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd-Catalyzed Coupling of Cyclic α-Iodoenones with Organozincs. (2000) (41)
- A New Protocol for the Enantioselective Synthesis of Methyl‐Substituted Alkanols and Their Derivatives through a Hydroalumination/Zirconium‐Catalyzed Alkylalumination Tandem Process (2002) (41)
- Zirconium-catalyzed allylalumination and benzylalumination of alkynes (1984) (41)
- Metal promoted cyclization. 5. Mechanistic duality in cyclialkylation of alkenylmetal derivatives (1984) (40)
- A convenient synthesis of unsymmetrical bibenzyls homoallylarenes, and homopropargylarenes via palladium-catalyzed cross coupling☆ (1983) (40)
- Reaction of alkenes and dienes with t-butylmagnesium halides and zirconocene dihalides. A convenient procedure for hydrozirconation and a novel t-butylzirconation of conjugated alkenes (1984) (40)
- Efficient and selective synthesis of 6,7-Dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs. (2004) (40)
- A strictly "pair"-selective synthesis of conjugated diynes via Pd-catalyzed cross coupling of 1,3-diynylzincs: a superior alternative to the Cadiot-Chodkiewicz reaction. (2000) (40)
- Novel 1,2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with .alpha.-haloorganolithiums (1988) (39)
- Highly selective synthesis of conjugated dienoic and trienoic esters via alkyne elementometalation–Pd-catalyzed cross-coupling (2011) (39)
- 1,4- and 1,5-Diketones via palladium-catalyzed allylation of potassium enoxyborates (1983) (37)
- Selective carbon-carbon bond formation via transition metal catalysis. 31. Controlled carbometalation. 15. Zirconium-promoted carbozincation of alkynes (1983) (37)
- Synthesis of enol esters and enol lactones via palladium-catalyzed carbonyiation of ary land alkenyl halides (1990) (37)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Aluminum, and Zirconium: The Negishi Coupling (2005) (37)
- Novel and selective α-substitution of ketones and other carbonyl compounds based on Pd-catalyzed cross coupling of α,β-unsaturated carbonyl derivatives containing α-halogen or α-metal groups ☆ (1999) (36)
- Highly regioselective generation of “thermodynamic” enolates and their direct characterization by NMR☆ (1983) (36)
- Synthesis of benzofurans, tetrahydrobenzopyrans, and related cyclic ethers via cyclic carbopalladation (1989) (36)
- Novel head-to-tail alkyl-alkene or alkene-alkene coupling via zirconium-catalyzed reaction of alkylmagnesium derivatives with monosubstituted alkenes (1992) (36)
- Selective synthesis of epolactaene featuring efficient construction of methyl (Z)-2-iodo-2-butenoate and (2R,3S,4S)-2-trimethylsilyl-2,3-epoxy-4-methyl- gamma-butyrolactone. (2006) (36)
- Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes (1994) (36)
- Selective carbon-carbon bond formation via transition-metal catalysis. 34. Countercation effects on the palladium-catalyzed allylation of enolates (1983) (35)
- Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes (1990) (35)
- Palladium-catalyzed allylation of lithium 3-alkenyl-1-cyclopentenolates-triethylborane and its application to a selective synthesis of methyl (z)-jasmonate1 (1985) (35)
- A convenient procedure for hydrozirconation of alkynes with iso-BuZrCp2Cl generated in situ by treatment of Cp2ZrCl2 with tert-butylmagnesium chloride (1991) (35)
- Efficient and selective synthesis of (S,R,R,S,R,S)-4,6,8,10,16,18-hexamethyl-docosane via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction). (2008) (35)
- Highly efficient and selective synthesis of conjugated triynes and higher oligoynes of biological and materials chemical interest via palladium-catalyzed alkynyl-alkenyl coupling. (2006) (34)
- Zirconium-Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes. (2016) (33)
- One-pot conversion of alkynes and alkenes into one-carbon homologated aldehydes via hydrozirconation-isocyanide insertion-hydrolysis (1988) (33)
- Palladium-Catalyzed Cross-Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs† (2005) (33)
- Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation (1988) (33)
- CATALYTIC GENERATION AND TRAPPING OF ACYLMETALS CONTAINING NI AND CU WITH ENOLATES (1998) (33)
- Titanium-Catalyzed Cascade Carboalumination of Dienes and Trienes (1994) (32)
- A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium-Catalyzed Carboalumination of Terminal Alkynes (1980) (32)
- Palladium-catalyzed reaction of organoalanes and organozincs with .alpha.,.beta.-unsaturated acetals and orthoesters as conjugate addition equivalents (1985) (32)
- A Highly Efficient, Selective, and General Method for the Synthesis of Conjugated (all-E)-Oligoenes of the (CHCH)n Type via Iterative Hydrozirconation−Palladium-Catalyzed Cross-Coupling (2002) (31)
- Highly efficient asymmetric synthesis of fluvirucinine A1 via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-lipase-catalyzed acetylation tandem process. (2008) (31)
- Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation (1988) (31)
- Zirconium-promoted Bicyclization of Enynes (1985) (31)
- Zirconocene–Alkene Complexes. An X-Ray Structure and a Novel Preparative Method (1989) (30)
- A selective procedure for α-alkenylation of enones involving Pd-catalyzed alkenyl-alkenyl coupling and its application to a convergent and efficient synthesis of nakienone B (1996) (29)
- Synthesis of cyclopentanol derivatives via palladium-catalyzed cyclic allylmetallation-dehydrometallation (1989) (28)
- Selective synthesis of benzene derivatives via palladium-catalyzed cascade carbometallation of alkynes (1993) (28)
- Palladium-catalyzed carbonylative cyclization of o-allylbenzyl halides to produce benzo-annulated enol lactones and/or bicyclo[3.3.0]hept-3-en-6-ones. An efficient route to U-68,215 (1991) (28)
- Pd-catalyzed selective tandem arylation–alkylation of 1,1-dihalo-1-alkenes with aryl- and alkylzinc derivatives to produce α-alkyl-substituted styrene derivatives (2003) (28)
- Synthesis of α-iodo-α,β-unsaturated ketones by the reaction of α-silyl-α,β-unsaturated ketones with ICl or IClAlCl3 (1999) (28)
- A novel intermolecular transfer reaction of alkenyltrialkylborates with aqueous bases and its application to the protonolysis of alkenylboron derivatives (1976) (28)
- Efficient and diastereoselective synthesis of (+)-Goniobutenolide A via palladium-catalyzed ene-yne cross coupling-lactonization cascade (1996) (27)
- Vinylic organoboranes. 6. A general synthesis of (E)-disubstituted-alkenes or ketones via the (E)-(1-substituted-1-alkenyl)boronic esters (1986) (27)
- Palladium-catalyzed highly diastereoselective cyclic carbopalladation-carbonylative esterification tandem reaction of iododienes and iodoarylalkenes. (1999) (27)
- Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes (1984) (27)
- Anomalous Dielectric Response in the π–d Correlated Metallic State of λ-(BEDT-TSF)2FeCl4 (2001) (27)
- A selective and convenient synthesis of β, β-dialkyl-substituted alkenylbroanes and alkenylzirconiums via carboalumination of alkynes1 (1982) (27)
- Metallic conductivity and ferromagnetic interaction of iron(III) d spins in the needle crystals of (ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)(2).FeBr(4) salt. (2002) (27)
- Palladium-catalyzed cyclic acylmetalation of allylic electrophiles as a route to cyclopentenone derivatives (1988) (26)
- Conversion of non-conjugated dienes into conjugated diene-zirconocenes via multipositional regioisomerization (1993) (26)
- Total synthesis of (+)-scyphostatin featuring an enantioselective and highly efficient route to the side-chain via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA). (2010) (25)
- Efficient and stereoselective synthesis of yellow scale pheromone via alkyne haloboration, Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction), and Pd-catalyzed tandem Negishi coupling. (2008) (25)
- Stereoselective synthesis of exocyclic alkenes via zirconium-promoted alkyl-diene coupling (1989) (25)
- Selective skeletal rearrangement by carbon–carbon bond activation (1990) (25)
- 1,4-Pentenyne as a five-carbon synthon for efficient and selective syntheses of natural products containing 2,4-dimethyl-1-penten-1,5-ylidene and related moieties by means of Zr-catalyzed carboalumination of alkynes and alkenes. (2008) (25)
- Stereoselective synthesis of partially substituted 1,2,3-butatriene derivatives via hydroboration (1974) (25)
- Catalytic Hydrogenation of Alkenes Using Zirconocene–Alkene Complexes (1991) (25)
- Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr−Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives (2000) (25)
- Carbon-carbon bond formation by the reaction of organolithiums with α-lithiated cyclic enol ethers. Stereoselective synthesis of β- and γ-hydroxy DI- and tri-substituted alkenes (1991) (25)
- Direct synthesis of heteroarylethynes via palladium-catalyzed coupling of heteroaryl halides with ethynylzinc halides. Its application to an efficient synthesis of a thiophenelactone from Chamaemelum nobile L (1997) (24)
- Enantioselective two-dimensional high-performance liquid chromatographic determination of N-methyl-D-aspartic acid and its analogues in mammals and bivalves. (2012) (24)
- Inhibition of reductive elimination of diorganopalladium species by formation of tetraorganopalladates (1987) (24)
- A new protocol for the enantioselective synthesis of methyl-substituted alkanols and their derivatives through a hydroalumination/ zirconium-catalyzed alkylalumination tandem process. (2002) (24)
- Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes: ZACA–Lipase-Catalyzed Acetylation Synergy (2007) (24)
- Arylethyne Bromoboration-Negishi Coupling Route to E- or Z-Aryl-Substituted Trisubstituted Alkenes of ≥98% IsomericPurity. New Horizon in the Highly Selective Synthesis of Trisubstituted Alkenes. (2010) (23)
- Carbozincation of Enynes Catalyzed by Titanium(IV) Alkoxides and Alkylmagnesium Derivatives (1998) (23)
- Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization (1995) (23)
- Palladium‐Catalyzed Carbonylative Cyclization Cascades with Iododienes and ‐trienes (1996) (23)
- Zirconium catalyzed CC bond formation reaction of conjugated diynes with EtMgBr (1993) (23)
- Anomalous Splitting of 1H-NMR Spectra in λ-(BEDT-TSF)2FeCl4 (2002) (22)
- Highly Chemo-, Regio-, and Stereoselective Carbon−Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5-Dienes and 1,5-Enynes (1999) (22)
- Strictly pair -selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations (2003) (22)
- Highly stereoselective and efficient synthesis of ω-heterofunctional di- and trienoic esters for Horner–Wadsworth–Emmons reaction via alkyne hydrozirconation and Pd-catalyzed alkenylation (2009) (22)
- Highly Selective Methods for α-Alkenylation and α-Arylation of Ketones via Palladium- or Nickel-Catalyzed Cross Coupling (1987) (22)
- Nickel- or palladium-catalyzed cross coupling. 28. A selective synthesis of a mixture of C-15 epimers of (.+-.)-11-deoxyprostaglandin E2 methyl ester (1985) (22)
- Widely applicable synthesis of enantiomerically pure tertiary alkyl-containing 1-alkanols by zirconium-catalyzed asymmetric carboalumination of alkenes and palladium- or copper-catalyzed cross-coupling. (2013) (22)
- Highly stereoselective synthesis of exocyclic alkenes via cyclialkylation (1987) (21)
- Carbon-carbon bond formation via opening of epoxysilanes with organometals containing lithium and copper (1989) (21)
- Synthesis and Reactivity of Zirconocene Derivatives (2003) (21)
- Factors Affecting the Unusual Reactivity Order in the β-Hydrogen Abstraction of Dialkylzirconocenes (1992) (21)
- Efficient and selective syntheses of (all-E)- and (6E,10Z)-2'-O-methylmyxalamides D via Pd-catalyzed alkenylation--carbonyl olefination synergy. (2008) (21)
- Zirconium-catalyzed and zirconium-promoted cyclization reactions of non-conjugated dienes with alkylmagnesium halides to give cycloalkylmethylmagnesium derivatives☆ (1998) (21)
- Termination of carbopalladation of alkynes via carbonylative amidation producing lactams (1995) (21)
- Some newer aspects of organozirconium chemistry of relevance to organic synthesis. Zr-Catalyzed enantioselective carbometallation (2001) (20)
- Stereoselective Synthesis of Exocyclic Alkenes by Cu‐Catalyzed Allylmagnesiation, Pd‐Catalyzed Alkylation, and Ru‐Catalyzed Ring‐Closing Metathesis: Highly Stereoselective Synthesis of (Z)‐ and (E)‐γ‐Bisabolenes (2001) (20)
- Preparation of a hafnocene–ethylene complex from bis(η5-cyclopentadienyl)hafnacyclopentane and its characterization (1989) (20)
- An efficient and selective synthesis of nakienone A involving a novel protocol for α-alkenylation of ketones via palladium-catalyzed alkenyl-alkenyl coupling (1997) (19)
- Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes (1990) (19)
- An intramolecular Michael reaction involving borate complexes. A novel synthesis of -hydroxycarboxylic acids. (1973) (18)
- Zirconium-catalyzed asymmetric carboalumination (ZACA reaction) of 1,4-dienes (2006) (18)
- Cyclic carbopalladation of alkynes terminated by carbonylative amidation (1996) (18)
- Titanium-catalyzed cascade carboalumination of 2-alkyl-substituted dienes and related trienes (1996) (17)
- Highly Enantiospecific Borylation for Chiral α-Amino Tertiary Boronic Esters. (2018) (17)
- Metal-promoted cyclization. 3. Highly selective synthesis of .alpha.-alkylidenetetrahydrofurans and .gamma.-alkylidenebutyrolactones via intramolecular opening of epoxysilanes (1983) (17)
- Stereoselective synthesis of β-hydroxy substituted trans-alkenes by the reaction of trans-alkenyltrialkylaluminates with epoxides (1976) (17)
- Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin (1998) (17)
- Facile and reversible displacement of η-C5H5 from Zr by organolithiums; formation of (η5-cyclopentadienyl) trialkylzirconiums and their reactions eith electrophiles and alkenes (1996) (16)
- Carbometalation Reactions of Diphenylacetylene and Other Alkynes with Methylalanes and Titanocene Derivatives (1997) (16)
- Highly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes. (2010) (16)
- Development of a Method for the Synthesis of a-Substituted a,b-Unsaturated Lactones Based on Stille-Type Pd-catalyzed Carbonylation of (Z)-w-Iodoalkenols. An Efficient and Selective Synthesis of (+)-Hamabiwa-lactone B (2000) (16)
- AlCl3-Promoted Facile E-to-Z Isomerization Route to (Z)-2-Methyl-1-buten-1,4-ylidene Synthons for Highly Efficient and Selective (Z)-Isoprenoid Synthesis. (2009) (16)
- Palladium-catalyzed trans-selective alkynylation-alkylation tandem process for the synthesis of (E)-3-alkyl-1-trialkylsilyl-3-alken-1-ynes (2005) (16)
- A stereoselective synthesis of disubstituted trans-alkenes by the reaction of trans-alkenyl trialkylaluminates with alkyl halides and sulfonates (1976) (16)
- Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid. (2015) (15)
- Hydrogen Transfer Hydrozirconation of Alkenes with iBuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, and Pd (1999) (15)
- Metal-promoted cyclization: VI. Palladium-catalyzed cyclization via intramolecular allylation of alkenylmetals (1985) (15)
- A novel highly enantio- and diastereoselective synthesis of vitamin E side-chain (2015) (14)
- Specific heat studies for ?-(BEDT-TSF) 2FeCl 4 (2003) (14)
- Palladium‐Catalyzed Alkenylation by the Negishi Coupling (2006) (14)
- Selective carbon-carbon bond formation via transition metal catalysis. 23. Highly selective and convenient method for the synthesis of 1,5-enynes and 1,5-dienes by the reaction of 1,3-dilithiopropargyl phenyl sulfide with allylic halides (1981) (14)
- Nondissociative mechanism for decomposition of dialkylzirconocenes to produce alkene–zirconocene–phosphine complexes (1990) (13)
- Zr-promoted ‘pair’-selective and regioselective synthesis of penta-substituted benzene derivatives (2004) (13)
- Palladium‐Catalyzed Aryl–Aryl Coupling (2003) (12)
- Anti-hydroalumination of Homo- and bishomopropargyl alcohols (1997) (12)
- Specific heat of organic superconductor λ-(BEDT-TSF)2GaCl4 (2003) (12)
- By Oxidative Addition (2003) (12)
- Palladium‐Catalyzed Heterogeneous Hydrogenation (2003) (12)
- Highly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)–Cu- or Pd-catalyzed cross-coupling (2014) (12)
- Design and synthesis of a novel pre-column derivatization reagent with a 6-methoxy-4-quinolone moiety for fluorescence and tandem mass spectrometric detection and its application to chiral amino acid analysis. (2015) (11)
- On the regiochemistry of cyclialkylation of regiodefined 4-halo-1-alkenylmetals producing cyclobutenes (1997) (11)
- Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes (2003) (11)
- Dielectric ordering and colossal magnetodielectricity in the antiferromagnetic insulating state of l-ÑBEDT-TSFÖ2FeCl4 (2005) (11)
- Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carboncarbon bond formation (2002) (11)
- A novel regiospecific aryl ketone synthesis by the reaction of arylborate anions with acyl chlorides (1975) (11)
- Evidence of the first-order nature of the metal-insulator phase transition in λ-(BEDT-TSF)2FeCl4 (2003) (11)
- Relaxor-like Behavior in λ-(BETS)2FeCl4 Studied by SR X-ray Diffraction (2004) (11)
- Intermolecular trapping of acylpalladium and related acylmetal derivatives with active C–H compounds (1999) (11)
- Syntheses of Chiral Heterocyclic Compounds via Zirconium-Catalyzed Asymmetric Carboalumination of Alkynes (ZACA Reaction) (2014) (10)
- 77Se NMR Evidence for the Development of Antiferromagnetic Spin Fluctuations of π-Electrons in λ-(BETS)2GaCl4 (2003) (10)
- Magnetic Field Effects on Nonlinear Electrical Transport in λ-(BEDT-TSF)2FeCl4, where BEDT-TSF is bis(ethylenedithio)tetraselenafulvalene (2003) (10)
- Zirconium-catalyzed methylalumination of heterosubstituted arylethynes. Factors affecting the regio-, stereo-, and chemoselectivities. (2007) (10)
- Historical Background of Organopalladium Chemistry (2003) (10)
- A selective synthesis of alkenylmercuric chlorides via alkenylalanes (1982) (9)
- Palladium‐Catalyzed Cross‐Coupling Involving Alkylmetals or Alkyl Electrophiles: Palladium‐Catalyzed Cross‐Coupling Involving Saturated Alkylmetals (2003) (9)
- Palladium‐Catalyzed Conjugate Substitution (2003) (9)
- A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes (2001) (9)
- Palladium‐Catalyzed Cross‐Coupling between Allyl, Benzyl, or Propargyl Groups and Unsaturated Groups (2003) (8)
- ZACA Reaction: Zr-Catalyzed Asymmetric Carboalumination of Alkenes (2010) (8)
- Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture) (2011) (8)
- Formation of Carbon ? Carbon and Carbon ? Heteroatom Bonds via Organoboranes and Organoborates (2004) (8)
- SELECTIVE CARBON‐CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 30. A SELECTIVE AND CONVENIENT SYNTHESIS OF β,β‐DIALKYL‐SUBSTITUTED ALKENYLBORANES AND ALKENYLZIRCONIUMS VIA CARBOALUMINATION OF ALKYNES (1983) (8)
- Novel synthesis of an ω-alkynylorganometallic reagent via triple bond isomerization with potassium 3-aminopropylamide: ω-(9-borabicyclo[3.3.1]nonan-9-yl)alkl-1-ynes (1977) (8)
- Enantioselective synthesis of chiral isotopomers of 1-alkanols by a ZACA-Cu-catalyzed cross-coupling protocol. (2014) (8)
- Antiferromagnetic resonance in λ-(BEDT-TSF) 2 FeCl 4 (2003) (8)
- Novel and regioselective aromatic double substitution involving borate anions and a regio- and stereo-selective route to dihydroaromatic derivatives (1975) (8)
- Pd(0) and Pd(II) Complexes Containing Phosphorus and Other Group 15 Atom Ligands (2003) (8)
- PALLADIUM- OR NICKEL-CATALYZED CROSS COUPLING INVOLVING PROXIMALLY HETEROFUNCTIONAL REAGENTS (1983) (7)
- Transition Metal Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis (2007) (7)
- Establishment of a Two-Dimensional HPLC-MS/MS Method Combined with DCl/D 2 O Hydrolysis for the Determination of Trace Amounts of D-Amino Acid Residues in Proteins (2015) (7)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling with Organometals Containing Zinc, Magnesium, Aluminum, and Zirconium (2007) (7)
- Asymmetric Synthesis of Chiral Cyclopentanes Bearing an All-Carbon Quaternary Stereocenter by Zirconium-Catalyzed Double Carboalumination. (2017) (7)
- Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism. (1996) (7)
- Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation (2007) (7)
- A novel synthesis of cyclopentenones and cyclohexenones via cycliacylation of lithioalkenylcarboxamides (1986) (7)
- Controlled Carbometalation. Part 20. Carbometalation Reaction of Alkynes with Organoalane‐Zirconocene Derivatives as a Route to Stereo‐ and Regiodefined Trisubstituted Alkenes. (2002) (6)
- Synthesis of Natural Products via Palladium-Catalyzed Cross-Coupling (2003) (6)
- Palladium- or Nickel-Catalyzed Cross-Coupling with Organometals Containing Zinc, Magnesium, Aluminum, and Zirconium (1998) (6)
- Catalysis in Organic Synthesis : edited by W.H. Jones Academic Press, New York, 1980, ix + 314 pages, $ 29.50. (1980) (6)
- By π-Complexation (2003) (6)
- Ferromagnetic ordering in a new nickel polyborate NiB12O14(OH)10. (2006) (6)
- Cyclization reactions of ω-tosyloxy-1-alkynyl- and ω-tosyloxy-1-alkenylborates and their ω-halo analogues† (1992) (6)
- Zirconium-Catalyzed Enantioselective Methylalumination of Monosubstituted Alkenes. (1996) (5)
- Palladium-Catalyzed Carbon—Carbon Cross-Coupling. Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals (2003) (5)
- NMR determination of n-butyllithium (1979) (5)
- Palladium‐ or Nickel‐Catalyzed Cross‐Coupling Reactions with Organozincs and Related Organometals (2009) (5)
- An Efficient and Stereoselective Synthesis of Xerulin via Pd-Catalyzed Cross Coupling and Lactonization Featuring (E)-Iodobromoethylene as a Novel Two-Carbon Synthon. (2000) (5)
- Catalysis with d-Block Transition Metals for Green Organic Synthesis and a Sustainable World (2011) (5)
- Regio- and Stereoselective Synthesis of γ-Alkylidenebutenolides and Related Compounds. (1997) (5)
- An Efficient and General Method for the Synthesis of α,ω‐Difunctional Reduced Polypropionates by Zr‐Catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Side Chain (I). (2004) (5)
- Enantiomerically pure zirconium and hafnium complexes containing a chiral cyclopentadiene derivative prepared from (−)-β-pinene (1997) (5)
- Superconductivity and pseudogap states studied by microwave conductivity measurements of λ-(BEDT-TSF)2GaCl4 (2006) (5)
- Cross coupling reactions in organic synthesis themed issue (2011) (5)
- Clean and Convenient Procedure for Converting Primary Alkyl Iodides and α,ω-Diiodoalkanes into the Corresponding Alkyllithium Derivatives by Treatment with tert-Butyllithium. (1991) (5)
- A tribute to Herbert C. Brown (1992) (4)
- Catalytic and Selective Conversion of (Z)‐2‐En‐4‐ynoic Acids to Either 2H‐Pyran‐2‐ones in the Presence of ZnBr2 or (Z)‐5‐Alkylidenefuran‐2(5H)‐ones in the Presence of Ag2CO3. (2002) (4)
- Convenient synthesis of diene-zirconocenes and regioselective partial reduction of the more highly substituted double bonds of conjugated dienes via complexation with zirconocenes and protonolysis (1993) (4)
- Remarkably “Pair”‐Selective and Regioselective Carbon‐Carbon Bond Forming Reaction of Zirconacyclopentane Derivatives with Grignard Reagents. (1991) (4)
- A general method for the synthesis of E and/or Z oligoisoprenoids based on Pd-catalyzed homoallyl-alkenyl and homopropargyl-alkenyl cross coupling and Zr-catalyzed carboalumination (2000) (4)
- HIGHLY GENERAL STEREO-, REGIO-, AND CHEMO-SELECTIVE SYNTHESIS OF TERMINAL AND INTERNAL CONJUGATED ENYNES BY THE PALLADIUM-CATALYZED REACTION OF ALKYNYLZINC REAGENTS WITH ALKENYL HALIDES (1978) (4)
- Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation—Carbonyl Olefination Synergy (2009) (4)
- Crystal structures and conducting/magnetic properties in two different crystals of (ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·MBr4 (M = Fe, Ga) (2003) (4)
- Enhancement of the 1H NMR relaxation rate at low temperatures and development of antiferromagnetic spin fluctuations of π-electrons in superconducting λ-(BETS)2GaCl4 (2003) (4)
- (−)‐Dichlorobis[(1,2,3,3a,7a‐η)‐1‐[(1S,‐2S,5R)‐5‐methyl‐2‐(1‐methylethyl)]cyclohexyl‐1H‐inden‐1‐yl]zirconium and Its (+)‐(1R,2R,5S)‐Isomer (2003) (4)
- Pd‐Catalyzed Cross‐Coupling with Organometals Containing Zn, Al, Zr, and so on – The Negishi Coupling and Its Recent Advances (2013) (4)
- Organic Syntheses Using Zirconium Compounds-Recent Developments (1989) (4)
- Magnetic susceptibility and electrical resistivity of a mesoporous carbon CMK-1 (2003) (4)
- Crystal Structures, and Electrical Conducting and Magnetic Properties in the Plate Crystals of (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2·MX4 (M=Fe, Ga, X=Br; M=Fe, X=C1) Salts (2002) (4)
- Diastereoselective, Enantioselective, and Regioselective Carboalumination Reactions Catalyzed by Zirconocene Derivatives (2006) (4)
- Catalytic enantioselective synthesis of chiral organic compounds of ultra-high purity of >99% ee (2015) (3)
- (E)-2-PHENYL-1-PROPENYLDIMETHYLALUMINUM (1986) (3)
- Reaction of Alkynes with Organometallic Reagents (1997) (3)
- Synthesis of Biaryls via Palladium‐Catalyzed Cross‐Coupling: 2‐Methyl‐4′‐Nitrobiphenyl (2003) (3)
- A Strictly “Pair”‐Selective Synthesis of Conjugated Diynes via Pd‐Catalyzed Cross Coupling of 1,3‐Diynylzincs: A Superior Alternative to the Cadiot‐Chodkiewicz Reaction. (2001) (3)
- A HIGHLY EFFICIENT CHEMO-, REGIO-, AND STEREOSELECTIVE SYNTHESIS OF (7E,9Z)-DODECADIEN-1-YL ACETATE, A SEX PHEROMONE OF LOBESIA BOTRANA, VIA A FUNCTIONALIZED ORGANOBORATE (1977) (3)
- One‐Step Construction of Fused Tricyclic and Tetracyclic Structures from Acyclic Precursors via Cyclic Carbopalladation. (1991) (3)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 23. HIGHLY SELECTIVE AND CONVENIENT METHOD FOR THE SYNTHESIS OF 1,5-ENYNES AND 1,5-DIENES BY THE REACTION OF 1,3-DILITHIOPROPARGYL PHENYL SULFIDE WITH ALLYLIC HALI (1982) (3)
- Palladium‐Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1‐Disubstituted Alkenes Terminated by Carbonylative Reactions (2003) (3)
- Metal–insulator transitions in magnetic conductor λ-(BEDT-TSF)2FeCl4 studied by and NMR (2003) (3)
- Alkene and Alkyne Complexes of Zirconocene. Their Preparation, Structure, and Novel Transformations (2010) (3)
- Reaction of Zirconocene Dichloride with Alkyllithiums or Alkyl Grignard Reagents as a Convenient Method for Generating of "Zirconocene" Equivalent and Its Use in Zirconium-Promoted Cyclization of Alkenes, Alkynes, Dienes, Enynes, and (1986) (3)
- Palladium‐Catalyzed Isomerization of Alkenes, Alkynes, and Related Compounds Without Skeletal Rearrangements (2003) (3)
- Palladium‐Catalyzed Alkenyl–Aryl, Aryl–Alkenyl, and Alkenyl–Alkenyl Coupling Reactions (2003) (3)
- Palladium-Catalyzed Cyclization of ω-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation. (1995) (3)
- NOVEL STEREOSELECTIVE ALKENYL-ARYL COUPLING VIA NICKEL-CATALYZED REACTION OF ALKENYLALANES WITH ARYL HALIDES (1976) (3)
- Highly Satisfactory Alkynylation of Alkenyl Halides via Pd‐Catalyzed Cross‐Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation. (2003) (3)
- Widely Applicable Pd‐Catalyzed trans‐Selective Monoalkylation of Unactivated 1,1‐Dichloro‐1‐alkenes and Pd‐Catalyzed Second Substitution for the Selective Synthesis of (E)‐ or (Z)‐Trisubstituted Alkenes. (2006) (3)
- Low frequency dielectric constant in the antiferromagnetic insulating state of λ-(BEDT-TSF)2FeCl4 (2003) (3)
- General Discussion of the Methods of Synthesis and In Situ Generation of Organopalladium Compounds (2003) (3)
- 2.19 – Vinyl- and Arylmetals (1995) (2)
- Facile Cleavage of the Cβ‐Cβ′ Bond of Zirconacyclopentenes. Convenient Method for Selectively Coupling Alkynes with Alkynes, Nitriles, and Aldehydes. (1993) (2)
- One-Step Homologation for the Catalytic Asymmetric Synthesis of Deoxypropionates. (2017) (2)
- Dielectric Slowing Down toward the Magnetically Ordered State in a Polar Conductor (EDT-TTFVO)2FeBr4 (2007) (2)
- Palladium‐Catalyzed Cross‐Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs. (2005) (2)
- ZACA-Lipase-Catalyzed Acetylation Synergy (2007) (2)
- Asymmetric Reactions and Processes in Chemistry (1982) (2)
- Palladium- and Nickel-Catalyzed Reactions of Organozinc Compounds (1999) (2)
- NMR evidence for antiferromagnetic spin fluctuations in superconducting λ-(BETS)2GaCl4 (2003) (2)
- Palladium‐Catalyzed Hydrometallation (2003) (2)
- Alkyne Elementometalation—Pd-Catalyzed Cross-Coupling. Toward Synthesis of All Conceivable Types of Acyclic Alkenes in High Yields, Efficiently, Selectively, Economically, and Safely: “Green” Way. (2010) (2)
- Zirconium‐Catalyzed Asymmetric Carboalumination of Unactivated Terminal Alkenes (2016) (2)
- General discussions, organometallics of main group metals in organic synthesis (1980) (2)
- Chemistry of Organo‐Boron Compounds. Part 60. Highly Stereoselective Syntheses of Conjugated E,E‐ and E,Z‐Dienes, E‐Enynes and E‐1,2,3‐Butatrienes via Alkenylborane Derivatives. (1991) (2)
- Palladium‐Catalyzed Cyclization of 1‐Iodo‐Substituted 1,4‐, 1,5‐, and 1,6‐Dienes as well as of 5‐Iodo‐1,5‐dienes in the Presence of Carbon Monoxide. (1996) (2)
- Palladium‐Catalyzed Alkynylation with Alkynylmetals and Alkynyl Electrophiles (2003) (2)
- Palladium-Catalyzed Cross-Coupling Substitution (2003) (2)
- Zirconium-Catalyzed Carboalumination of Alkynes and Enynes as a Route to Aluminacycles and Their Conversion to Cyclic Organic Compounds. (1998) (2)
- A STEREOSELECTIVE SYNTHESIS OF PARTIALLY SUBSTITUTED 1,2,3-BUTATRIENE DERIVATIVES VIA HYDROBORATION (1974) (2)
- By β-Hydrogen Abstraction (2003) (2)
- Search for highly efficient, stereoselective, and practical synthesis of complex organic compounds of medicinal importance as exemplified by the synthesis of the C21-C37 fragment of amphotericin B. (2013) (2)
- Highly Efficient and Selective Procedures for the Synthesis of γ- Alkylidenebutenolides via Palladium-Catalyzed Ene-Yne Coupling and Palladium- or Silver-Catalyzed Lactonization of (Z)-2-En-4-ynoic Acids. Synthesis of Rubrolides A, C, D, and E (1997) (2)
- Efficient and Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed Asymmetric Carboalumination and Pd-Catalyzed Cross-Coupling of Organozincs (2004) (2)
- Metal‐Promoted Cyclization. Part 18. Novel Cyclialkylation Reactions of (ω‐Halo‐1‐alkenyl)metal Derivatives. Synthetic Scope and Mechanism. (1988) (2)
- anti‐Carbometalation of Homopropargyl Alcohols and Their Higher Homologues via Non‐Chelation‐Controlled syn‐Carbometalation and Chelation‐Controlled Isomerization. (1997) (2)
- Palladium‐Catalyzed Cross‐Coupling Reaction of Alkynylzincs with Benzylic Electrophiles. (2005) (2)
- Direct Synthesis of Terminal Alkynes via Pd‐Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations. (1998) (2)
- Zirconacyclopropanes and Zirconacyclopropenes. Their Synthesis, Characterization, and Reactions. (1987) (2)
- Zirconium-Catalyzed, Highly Regioselective Hydrosilation Reaction of Alkenes and X-Ray Structures of Silyl(hydrido)zirconocene Derivatives. (1992) (2)
- Palladium‐Catalyzed Synthesis of 1,4‐Dienes by Allylation of Alkenylalanes:α‐Farnesene (2003) (2)
- Palladium Complexes Containing Halogen and Oxygen Ligands (2003) (1)
- Reviews and Accounts on Organopalladium Chemistry (as of September 1999) (2003) (1)
- The Tsuji–Trost Reaction and Related Carbon–Carbon Bond Formation Reactions: Palladium‐Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, Aldehydes, and Other Carbonyl Compounds (2003) (1)
- Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-β-Iodoenones and Related Derivatives Producing γ-Lactones and γ-Lactams. (1995) (1)
- Palladium‐Catalyzed Cross‐Coupling Involving Alkylmetals or Alkyl Electrophiles: Reactions between Homoallyl‐, Homopropargyl‐, or Homobenzylmetals and Alkenyl or Aryl Electrophiles (2003) (1)
- Low frequency dielectric properties in a ferromagnetic semiconductor (ED-TTFVO)${_{2}}$FeBr${_{4}}$ with permanent electric dipoles (2004) (1)
- Strictly Regiocontrolled α‐Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd‐Catalyzed Coupling of Cyclic α‐Iodoenones with Organozincs. (2001) (1)
- Convenient Preparative Method of α,β‐Disubstituted Cyclopentenone by Zirconium Promoted Intermolecular Coupling of an Alkyne, EtMgBr (or Ethylene) and CO. (1997) (1)
- Novel Zirconocene-Promoted Carbon-Carbon Bond Formation via a 1,2- Migration Reaction of Alkynylzirconium Derivatives. (1991) (1)
- Cyclic Cascade Carbopalladation Reactions as a Route to Benzene and Fulvene Derivatives. (1992) (1)
- Palladium‐Catalyzed Carbonylative Cyclization of o‐Allylbenzyl Halides to Produce Benzo‐Annulated Enol Lactones and/or Bicyclo(3.3.0)hept‐3‐ en‐6‐ones. An Efficient Route to U‐68,215. (1992) (1)
- Reactions of Acylpalladium Derivatives with Enolates and Related Amphiphilic Reagents (2003) (1)
- Use of InCl3 as a Cocatalyst and a Cl2Pd(DPEphos)—P(2-Furyl)3 Catalyst System for One-Pot Hydrometalation—Cross-Coupling and Carbometalation—Cross-Coupling Tandem Processes. (2004) (1)
- Palladium‐Catalyzed Cross‐Coupling between Allyl‐, Benzyl‐, or Propargylmetals and Allyl, Benzyl, or Propargyl Electrophiles (2003) (1)
- Conversion of Methyl Ketones into Terminal Alkynes: (E)‐Buten‐3‐ynyl‐2,6,6‐trimethyl‐1‐cyclohexene (2003) (1)
- Intramolecular Acylpalladation: Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds (2003) (1)
- Nonlinear electrical trnasport in ?-(BEDT-TSF) 2FeCl 4 under magnetic field (2003) (1)
- Synthesis of Five-Membered Heterocycles (2003) (1)
- Apparent Endo-Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo-Mode Cyclization-Cyclopropanation-Rearrangement. (1993) (1)
- Palladium-Catalyzed Cross-Coupling of Alkynylzincs with Allylic Electrophiles: An Efficient and Selective Synthesis of Stereo- and Regio-Defined 1,4-Enynes. (2005) (1)
- Multiple Mechanistic Pathways for Zirconium‐Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometalation Processes Involving C‐H Activation. (1997) (1)
- ‘One-Pot’ Zr-Catalyzed Asymmetric Carboalumination-Pd Cross-Coupling (2005) (1)
- Other Palladium‐Catalyzed or ‐Promoted Oxidation Reactions via 1,2‐ or 1,4‐Elimination (2003) (1)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 25. STEREO- AND REGIOSELECTIVE ROUTES TO ALLYLIC SILANES (1982) (1)
- Direct Synthesis of Heteroarylethynes via Palladium-Catalyzed Coupling of Heteroaryl Halides with Ethynylzinc Halides. Its Application to an Efficient Synthesis of a Thiophenelactone from Chamaemelum nobile L. (1998) (1)
- By Reductive Carbonylation (2003) (1)
- Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr—Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives. (2000) (1)
- Synthesis of Natural Products via Nucleophilic Attack on π‐Ligands of Palladium–Alkene, Palladium–Alkyne, and Related π‐Complexes (2003) (1)
- Palladium‐Catalyzed Carbon Skeletal Rearrangements: Palladium‐Catalyzed Carbon Skeletal Rearrangements Other than [3,3] Rearrangements (2003) (1)
- Carbozincation of Enynes Catalyzed by Titanium(IV) Alkoxides and Alkylmagnesium Derivatives. (1998) (1)
- WATER-DROPPING AERODYNAMICS FOR FIRE-FIGHTING AMPHIBIAN (2010) (1)
- Other Miscellaneous Palladium‐Catalyzed or ‐Promoted Oxidation Reactions (2003) (1)
- ONE‐STEP CONVERSION OF TERMINAL ACETYLENES INTO TERMINALLY FUNCTIONALIZED (E)‐3‐METHYL‐2‐ALKENES VIA ZIRCONIUM‐CATALYZED CARBOALUMINATION. A SIMPLE AND SELECTIVE ROUTE TO TERPENOIDS (1978) (1)
- Zirconium‐Catalyzed C‐C Bond Formation Reaction of Conjugated Diynes with EtMgBr. (1994) (1)
- Titanium‐Catalyzed Cascade Carboalumination of 2‐Alkyl‐Substituted Dienes and Related Trienes. (1996) (1)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds: Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds Other than Enolates (2003) (1)
- Antiferromagnetic resonance in ?-(BEDT-TSF) 2FeCl 4 (2003) (1)
- Catalytic Generation and Trapping of Acylmetals Containing Ni and Cu with Enolates. (1998) (1)
- Organometallic Complexes of Zirconium and Hafnium (2004) (1)
- Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes. (1992) (1)
- Highly Efficient Asymmetric Synthesis of Fluvirucinine A1 via Zr‐Catalyzed Asymmetric Carboalumination of Alkenes (ZACA)—Lipase‐Catalyzed Acetylation Tandem Process. (2008) (1)
- Highly Efficient and Selective Synthesis of Conjugated Triynes and Higher Oligoynes of Biological and Materials Chemical Interest via Palladium‐Catalyzed Alkynyl—Alkenyl Coupling. (2007) (1)
- An Odyssey from Stoichiometric Carbotitanation of Alkynes to Zirconium‐ Catalyzed Enantioselective Carboalumination of Alkenes (1997) (1)
- Scientific Contributions of Professor Herbert C. Brown (1978) (1)
- A profile of Professor Richard F. Heck (1999) (1)
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- Zirconocene-Promoted Stereoselective Bicyclization of 1,6- and 1,7-Dienes to Produce trans-Zirconabicyclo(3.3.0)octanes and cis-Zirconabicyclo(4.3.0)nonanes. (1990) (0)
- Short Biographical Sketch - Ei-ichi Negishi (2012) (0)
- By β,γ-C—C Bond Cleavage (2003) (0)
- "Ate" Complexes of Metal–Bis(η-cyclopentadienyl) and Other Derivatives (2003) (0)
- METAL-PROMOTED CYCLIZATION. VI. PALLADIUM-CATALYZED CYCLIZATION VIA INTRAMOLECULAR ALLYLATION OF ALKENYLMETALS (1985) (0)
- Migratory Insertion Reactions of Zirconacycles with Carbon Monoxide and Isocyanides (2003) (0)
- Aldol-Type Reactions of 1-Naphthol Catalyzed by Trichloro(η-cyclopentadienyl)zirconium Derivatives (2003) (0)
- The Erker–Buchwald Protocol (2003) (0)
- C—C Bond Formation via Polar Reactions of Five-Membered Zirconacycles with Carbon Electrophiles and Related π-Compounds (2003) (0)
- Diastereoselective Zirconocene‐Promoted Bicyclization‐Carbonylation of Allylically Methyl‐Substituted Enynes. Synthesis of (+)‐Iridomyrmecin. (1992) (0)
- Principle of Activation of Electrophiles by Electrophiles Through Dimeric Association — Two Are Better than One (1999) (0)
- Formation of Zirconium–Carbene Complexes (2003) (0)
- SYNTHESES OF CHIRAL HETEROCYCLIC COMPOUNDS VIA ZIRCONIUM-CATALYZED ASYMMETRIC CARBOALUMINATION OF ALKYNES (ZACA REACTION) (Dedicated to Professor Victor Snieckus on the occasion of his 77th birthday) (2014) (0)
- VIII. Organozirconium Chemistry (2013) (0)
- Cationic Metal–Bis(η-cyclopentadienyl) Derivatives of Oxidation State Four (2003) (0)
- Catalytic Oligomerization of Terminal Alkynes (2003) (0)
- Formation of Zirconium Complexes Containing an Amido-Linked Cyclopentadienyl Ligand (2003) (0)
- Highly Stereo- and Regiocontrolled Cyclopentannulation via Allylphosphonate Conjugate Addition and Hydroboration-Oxidation- Elimination. Synthesis of Pentalenic Acid with Virtually Complete Stereo- and Regiocontrol. (1991) (0)
- C—C Bond Formation via Metal-Catalyzed Reactions of Bis(η-cyclopentadienyl)monoorganozirconium Complexes with Organic Electrophiles (2003) (0)
- Palladium-Catalyzed Carbon Skeletal Rearrangements Other than [3,3] Rearrangements (2003) (0)
- Method for evaluating ultraviolet light protection effect, evaluation device, and computer-readable storage medium (2013) (0)
- Zirconium-Catalyzed Enantioselective Carboalumination of Alkenes (2003) (0)
- Vinylic Organoboranes. Part 6. A General Synthesis of (E)-Disubstituted Alkenes or Ketones via the (E)-(1-Substituted-1-Alkenyl)boronic Esters. (1987) (0)
- Superconductivity and Pseudogap States in λ-(BEDT-TSF)2GaCl4 : Microwave Conductivity Measurements (2006) (0)
- trans‐Dichlorobis(triphenylphosphine)palladium(II) (2008) (0)
- Metal-Promoted Cyclization. Part 12. A Selective Method for the Synthesis of Stereodefined Exocyclic Alkenes via Allylmetalation of Propargyl Alcohols. (1987) (0)
- Metal π-Complexes Containing η-, η-, and η-Ligands (2003) (0)
- Organozirconium Compounds as New Reagents and Intermediates (1986) (0)
- A dielectric metal λ-(BEDT-TSF)2FeCl4 (2003) (0)
- Copper-Catalyzed Acylation of Zirconacycles (2003) (0)
- Palladium- or Nickel-Catalyzed Cross Coupling Involving Proximally Heterofunctional Reagents (56 Literaturzitate). (1983) (0)
- Synthesis of α‐Iodo‐α,β‐Unsaturated Ketones by the Reaction of α‐Silyl‐α,β‐Unsaturated Ketones with ICl or ICl—AlCl3. (1999) (0)
- Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes. (1995) (0)
- Using Grignard or Other Magnesium Reagents (2003) (0)
- Strictly Regio‐ and Stereo‐Controlled α‐Alkenylation of Bicyclic Enone Derivatives via Palladium‐Catalyzed Cross Coupling and Its Application to a Formal Synthesis of (.+‐.)‐Carbacyclin. (1998) (0)
- Zirconate Complexes of Bis(η-cyclopentadienyl)zirconium(II) Derivatives (2003) (0)
- Background for Part II (2003) (0)
- Highly Chemo‐, Regio‐, and Stereoselective Carbon—Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynyl Metals Containing Li and Mg. Novel Synthesis of 1,5‐Dienes and 1,5‐Enynes. (2000) (0)
- Formation of Bis(η-cyclopentadienyl)zirconium Complexes with Allenes, Silenes, Imines, and Diphenyldiazene Derivatives (2003) (0)
- By Ligand Exchange of Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Novel and Selective α-Substitution of Ketones and Other Carbonyl Compounds Based on Pd-Catalyzed Cross-Coupling of α,β-Unsaturated Carbonyl Derivatives Containing α-Halogen or α-Metal Groups (1999) (0)
- Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2- alkenylbenzenes. (2010) (0)
- Hydrozirconation and Hydrogen-Transfer Hydrozirconation (2003) (0)
- Zirconium-Catalyzed Carboalumination of Alkynes (2003) (0)
- Organometallic Reactions Catalyzed by Five-Membered Zirconacycles (2003) (0)
- Hydroamination of Internal Alkynes Catalyzed by Zirconium–Nitrene Complexes (2003) (0)
- Highly Selective Synthesis of Vitamin A and Its Derivatives. Critical Comparison of Some Known Palladium‐Catalyzed Alkenyl‐Alkenyl Coupling Reactions. (1992) (0)
- Use of Alkenes and Grignard Reagents (2012) (0)
- C—C Bond Formation via Polar Reactions of Chlorobis(η-cyclopentadienyl)monoorganozirconium Complexes with Carbon Electrophiles (2003) (0)
- A Convenient Procedure for Hydrozirconation of Alkynes with i-BuZrCp2Cl Generated in situ by Treatment of Cp2ZrCl2 with t-BuMgCl. (1991) (0)
- Reaction of 3-Zircona-1-cyclopentenes and Zirconacyclopentanes with Aldehydes. A Selective and Convenient Synthesis of 4-Penten-1-ols, (Z)- 5-Iodo-4-penten-1-ols, and Related Alkanols. (2010) (0)
- Effects of Organometals on the Palladium-Catalyzed Tandem Carbopalladation - Cross Coupling for Preparing Stereodefined Exocyclic Alkenes. (1991) (0)
- Nickel- or Palladium-Catalyzed Cross Coupling. Part 31. Palladium- or Nickel-Catalyzed Reactions of Alkenylmetals with Unsaturated Organic Halides as a Selective Route to Arylated Alkenes and Conjugated Dienes: Scope, Limitations, and (1987) (0)
- Metal–η-Arene and –η-Arene Complexes (2003) (0)
- Synthesis and Reactivity Zirconocene Derivatives (2004) (0)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐Hetero‐Substituted Compounds: Palladium‐Catalyzed α‐Substitution Reactions of Enolates and Related Derivatives Other than the Tsuji–Trost Allylation Reaction (2003) (0)
- By Reductive Elimination or Migration (2003) (0)
- Bis(η-cyclopentadienyl)metal(IV) Complexes Containing Two Electronegative Heteroatom Groups (2003) (0)
- Metal Promoted Cyclization. Part 10. A Novel Synthesis of Cyclopentenones and Cyclohexenones via Cycliacylation of Lithioalkenylcarboxamides. (1986) (0)
- Development of a Method for the Synthesis of α‐Substituted α,β‐Unsaturated Lactones Based on Stille‐Type Pd‐Catalyzed Carbonylation of (Z)‐ω‐Iodoalkenols. An Efficient and Selective Synthesis of (+)‐Hamabiwalactone B. (2000) (0)
- Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds (1996) (0)
- One‐Pot Conversion of Alkynes and Alkenes into One‐Carbon Homologated Aldehydes via Hydrozirconation ‐ Isocyanide Insertion ‐ Hydrolysis. (1988) (0)
- The Negishi–Takahashi Protocol (2003) (0)
- Reactions of Zirconocene–Conjugated Diene Complexes with π-Compounds (2003) (0)
- anti-Hydroalumination of Homo- and Bishomopropargyl Alcohols. (2010) (0)
- Oxo-, Thioxo-, Selenoxo-, or Telluroxozirconium Complexes by the Oxidative Reaction of a Zirconium(II) Complex (2003) (0)
- Palladium-catalyzed acetylene syntheses (1979) (0)
- Highly Selective Methods for α‐Alkenylation and α‐Arylation of Ketones via Palladium‐ or Nickel‐Catalyzed Cross Coupling. (1988) (0)
- Metal-Promoted Cyclization. Part 25. Palladium-Catalyzed Cascade Carbometalation of Alkynes and Alkenes as an Efficient Route to Cyclic and Polycyclic Structures. (1989) (0)
- Five-Membered Metallocycle–Bis(η-cyclopentadienyl) Derivatives of Oxidation State Four (2003) (0)
- Di‐n‐butylbis(cyclopentadienyl)zirconium (2005) (0)
- (E)‐1‐Bromo‐2‐iodoethylene (2003) (0)
- Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes by Halogen Abstraction from Bis(η-cyclopentadienyl)halo(methyl)zirconium (2003) (0)
- Metal-Promoted Cyclization. Part 21. Palladium-Catalyzed Procedures for (3 + 2)Annulation via Intramolecular Alkenylpalladation and Arylpalladation. (1989) (0)
- Cyclic Carbopalladation of Alkynes Terminated by Carbonylative Amidation. (1996) (0)
- Reactions of Five-Membered Zirconacycles Leading to the Formation of C—H(D) and C—X Bonds (2003) (0)
- Formation of Trichloromono(η-cyclopentadienyl)metal Derivatives from Metal(IV) Tetrachloride–Bis(dimethyl sulfide) Complexes (2003) (0)
- A Genealogy of Pd-Catalyzed Cross-Coupling. (2002) (0)
- Ring Expansion of Zirconacyclopentenes and Zirconacyclopentanes with Aldehydes (2003) (0)
- Synthesis of Enol Esters and Enol Lactones via Palladium-Catalyzed Carbonylation of Aryl and Alkenyl Halides. (1991) (0)
- Bis(η-cyclopentadienyl)monoorganometal Complexes (2003) (0)
- Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via β,β′ Carbon—Carbon Bond Cleavage of Zirconacyclopentenes. (1999) (0)
- Using Organozinc Reagents (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 33. PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF α-HETEROSUBSTITUTED ALKENYLMETALS. A STEREOSELECTIVE ROUTE TO HETEROSUBSTITUTED DIENES SUITABLE FOR THE DIELS-AL (1983) (0)
- The rich and diverse spectrum of organic chemistry in the millennium: Report from the 37th National Organic Symposium (2001) (0)
- Metal–η-Arene Complexes (2003) (0)
- Nickel- or Palladium-Catalyzed Cross Coupling of Alkenylchlorobis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Metal π-Complexes Containing η-Ligands Other than η-Cyclopentadienyl (2003) (0)
- Metal-Promoted Cyclization. Part 24. Synthesis of Cyclopentanol Derivatives via Palladium-Catalyzed Cyclic Allylmetalation-Dehydrometalation. (1989) (0)
- Catalytic Reactions Involving Bis(η-cyclopentadienyl)hydridozirconium Derivatives (2003) (0)
- Metal-Promoted Cyclization. Part 28. Regioselective and Diastereoselective Alkyl-Alkene and Alkene-Alkene Coupling Promoted by Zirconocene and Hafnocene. (1990) (0)
- Formation of Tris(η-cyclopentadienyl)metal Complexes (2003) (0)
- PART I. BASIC CLEAVAGE OF ARYLSULFONAMIDES. PART II. THE SYNTHESES OF SOME BICYCLIC COMPOUNDS DERIVED FROM PIPERAZINE WHICH CONTAIN BRIDGEHEAD NITROGEN ATOMS. (1963) (0)
- Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes by Alkyl Abstraction Using a Lewis Acid (2003) (0)
- By Halogen or Alkyl Abstraction from Bis(η-cyclopentadienyl)organozirconium Complexes (2003) (0)
- A Novel Hydrogen Transfer Hydroalumination of Alkenes with Triisobutylaluminum Catalyzed by Pd and Other Late Transition Metal Complexes. (2001) (0)
- Protonolysis, Deuterolysis, and Halogenolysis (2003) (0)
- (E)‐1‐Bromo‐4‐trimethylsilyl‐1‐buten‐3‐yne and (E)‐1‐Bromo‐4‐(tert‐butyldimethylsilyl)‐1‐buten‐3‐yne (2003) (0)
- Trimethylaluminum–Dichlorobis(η5‐cyclopentadienyl)zirconium (2001) (0)
- Metal-Promoted Cyclization. Part 22. Synthesis of Benzofurans, Tetrahydrobenzopyrans, and Related Cyclic Ethers via Cyclic Carbopalladation. (1989) (0)
- Other Zirconium-Catalyzed Carbometalation Reactions of Alkynes and Alkenes (2003) (0)
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- A PALLADIUM-CATALYZED STEREOSPECIFIC SUBSTITUTION REACTION OF HOMOALLYLZINCS WITH β-BROMO-SUBSTITUTED α,β-UNSATURATED CARBONYL DERIVATIVES. A HIGHLY SELECTIVE SYNTHESIS OF MOKUPALIDE (1981) (0)
- 15pWH-4 ESR study of λ-(BEDT-TSF)_2Fe_ Ga_xCl_4 (x=0, 0.4, 1.0) (2004) (0)
- A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling. Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. Part 26. (1982) (0)
- NOVEL SYNTHESIS OF AN Ω-ALKYNYLORGANONMETALLIC REAGENT VIA TRIPLE BOND ISOMERIZATION WITH POTASSIUM 3-AMINOPROPYLAMIDE- Ω-(9-BORABICYCLO(3.3.1)NONAN-9-YL)ALKL-YNES (1977) (0)
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- Using Organoaluminum Reagents (2003) (0)
- Total Synthesis of (+)‐Scyphostatin Featuring an Enantioselective and Highly Efficient Route to the Side‐Chain via Zr‐Catalyzed Asymmetric Carboalumination of Alkenes (ZACA). (2010) (0)
- On the Origin of the Configurational Instability of (l-Silyl-1-alkenyl)lithiums and Related Alkenylmetals. (1986) (0)
- 5.8.2.11.3. by Transmetallation from Other Metal Organometallics to Metal Halides (2007) (0)
- Some Newer Aspects of Organozirconium Chemistry of Relevance to Organic Synthesis: Zr‐Catalyzed Enantioselective Carbometalation (2001) (0)
- Bis(η-cyclopentadienyl)hydridometal(IV) Complexes (2003) (0)
- Synthesis of Bis(η-cyclopentadienyl)diorganometal Complexes and Their Derivatives (2003) (0)
- Formation of Oxo-, Thioxo-, or Phosphinidenezirconium Complexes (2003) (0)
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- Metal–Triene Complexes (2003) (0)
- Formation of Trichloro(η-cyclopentadienyl)zirconium from Thallium(I) Methylcyclopentadienide and Zirconium(IV) Chloride–Bis(tetrahydrofuran) Complex (2003) (0)
- Metal‐Promoted Cyclization. Part 19. Novel Bicyclization of Enynes and Diynes Promoted by Zirconocene Derivatives and Conversion of Zirconabicycles into Bicyclic Enones via Carbonylation. (1989) (0)
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- Formation of Imido- or Hydrazidozirconium Complexes (2003) (0)
- Metallic Palladium and Its Mixtures (2003) (0)
- ESR Study on λ-(BEDT-TSF)2Fe1-xGaxCl4 (2005) (0)
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- Zr-Catalyzed Carboalumination: A New Route to Tocotrienols (2011) (0)
- 1‐Chloro‐2‐iodoethylene (2001) (0)
- Copper-Catalyzed Allylation of Zirconacyclopentadienes (2003) (0)
- Organopalladium Compounds Containing Pd(0) and Pd(II). General Discussion of the Methods of Synthesis and in situ Generation of Organopalladium Compounds (2003) (0)
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- Efficient and Diastereoselective Synthesis of (+)-Goniobutenolide A via Palladium-Catalyzed Ene-Yne Cross Coupling-Lactonization Cascade. (1997) (0)
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- C—C Bond Formation by the Reactions of Five-Membered Zirconacycles with Carbon Monoxide, Isocyanides, and Related Carbon Nucleophiles (2003) (0)
- Carbometalative Ring-Expansion Reactions of Three-Membered Zirconocene and Hafnocene Derivatives (2003) (0)
- Metal σ-Complexes of Oxidation States below Four (2003) (0)
- Copper-Catalyzed Conjugate Addition of Chlorobis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- By Radical Chlorination of Dichlorobis(η-cyclopentadienyl)zirconium (2003) (0)
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- By Isomerization and Displacement (2007) (0)
- C—C Bond Formation by the Transition-Metal-Catalyzed Reaction of Five-Membered Zirconacycles (2003) (0)
- By Addition of Olefinic and Acetylenic Linkages (Carboboration) (2007) (0)
- An Efficient and Selective Synthesis of Nakienone A Involving a Novel Protocol for α‐Alkenylation of Ketones via Palladium‐Catalyzed Alkenyl‐Alkenyl Coupling. (1997) (0)
- Coupling of Propene and 2-Methylpyridine Catalyzed by Cationic Bis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Stoichiometric Reactions of Bis(η-cyclopentadienyl)hydridozirconium(IV) and Bis(η-cyclopentadienyl)dihydridozirconium(IV) Complexes and Related Reagents (2003) (0)
- Formation of 1-Phenyl-1-indole from a Hydrazidozirconium Complex (2003) (0)
- LIST OF PUBLICATIONS BY EI-ICHI NEGISHI (2012) (0)
- (2E)-1-TRIMETHYLSILYL-3,7-DIMETHYL-2,6-OCTADIENE (GERANYLTRIMETHYLSILANE) (1986) (0)
- By Pyrolytic Elimination of H2 (2007) (0)
- π-d Correlation in λ-(BEDT-TSF)_2Fe_ Ga_xCl_4 by ESR Measurements(Condensed matter: electronic structure and electrical, magnetic, and optical properties) (2006) (0)
- Reactions of Bis(η-cyclopentadienyl)metal(IV) Derivatives with α- and γ-Hetero-Substituted Alkyl- and Alkenyllithiums (2003) (0)
- Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometalation-Carbonylation Cascade. (1995) (0)
- Highly Satisfactory Procedures for the Pd‐Catalyzed Cross Coupling of Aryl Electrophiles with in situ Generated Alkynylzinc Derivatives. (2002) (0)
- Construction of Deoxypropionate Chains via Asymmetric Carboalumination (2006) (0)
- Reactions of Bis(η-cyclopentadienyl)zirconium(IV) Derivatives with Alkyl- and Arylmetals Containing Lithium or Magnesium, or with Metal Hydrides (2003) (0)
- Metal–Bis(η-cyclopentadienyl) Derivatives Containing Carbene, Nitrene, and Other Doubly Bonded Ligands (2003) (0)
- Protonolysis and Deuterolysis (2003) (0)
- Reactions of Zirconacyclopentenes with Allyl and Alkenyl Ethers and Halides (2003) (0)
- EFD and CFD Research of Water-Dropping Aerodynamics for Fire-Fighting Amphibian (2011) (0)
- C—C Bond Formation Reactions of Organometals Catalyzed by Bis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- Metal-Promoted Cyclization. Part 26. Palladium-Catalyzed Cyclization of Benzyl Halides and Related Electrophiles Containing Alkenes and Alkynes as a Novel Route to Carbocycles. (1989) (0)
- Pd‐Catalyzed Selective Tandem Arylation—Alkylation of 1,1‐Dihalo‐1‐alkenes with Aryl‐ and Alkylzinc Derivatives to Produce α‐Alkyl‐substituted Styrene Derivatives. (2004) (0)
- Palladium-Catalyzed Carbonylative Cyclization Cascade with Iododienes and -trienes. (1997) (0)
- Other Protocols for the Synthesis of Five-Membered Zirconacycles and Hafnacycles (2003) (0)
- A STEREOSELECTIVE SYNTHESIS OF DISUBSTITUTED TRANS-ALKENES BY THE REACTION OF TRANS-ALKENYLTRIALKYLALUMINATES WITH ALKYL HALIDES AND SULFONATES (1976) (0)
- By α-Hydrogen Elimination (2003) (0)
- Magnetic response of microwave complex conductivities in antiferromagnetic insulating states of λ-(BEDT-TSF)2FeCl4 (2004) (0)
- Stereoselective Cyclic Carbolithiation of Alkyne Derivatives. A Stereoselective Synthesis of Exocyclic Alkenes. (1990) (0)
- Reactions with Organometals Containing Electropositive Metals (2003) (0)
- Novel Head‐to‐Tail Alkyl‐Alkene or Alkene‐Alkene Coupling via Zirconium‐Catalyzed Reaction of Alkylmagnesium Derivatives (II) with Monosubstituted Alkenes (I). (1992) (0)
- Zirconium-Promoted Bicyclization of Enynes. Effects of Enyne Structure. (1987) (0)
- Zirconium‐Catalyzed Asymmetric Carboalumination (ZACA Reaction) of 1,4‐Dienes. (2006) (0)
- Metal σ-Complexes without π-Ligands of Oxidation State Four (2003) (0)
- Synthesis of (+)-Scyphostatin (2010) (0)
- Bis(η-cyclopentadienyl)zirconium(II)-Catalyzed Hydrosilylation of Alkenes (2003) (0)
- Metal–Bis(η-cyclopentadienyl) Complexes and Related Derivatives of Oxidation State Four (2003) (0)
- Convenient and General Synthesis of 1‐Monoorganyl‐ and 1,2‐ Diorganylcyclobutenes via Cyclialkylation. (1997) (0)
- Carbon‐Carbon Bond Formation by the Reaction of Organolithiums with . alpha.‐Lithiated Cyclic Enol Ethers. Stereoselective Synthesis of . beta.‐ and γ‐Hydroxy Di‐ and Trisubstituted Alkenes. (1992) (0)
- Compounds of Groups 7-3 (Mn..., Cr..., V..., Ti..., Sc..., La..., Ac...) (2003) (0)
- Titanium‐Catalyzed Cascade Carboalumination of Dienes and Trienes. (1995) (0)
- Profile of Professor H. C. Brown (1982) (0)
- Le palladium, magique des chimistes (2010) (0)
- Palladium-Catalyzed Highly Diastereoselective Cyclic Carbopalladation—Carbonylative Esterification Tandem Reaction of Iododienes and Iodoarylalkenes. (1999) (0)
- Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes. (1995) (0)
- A Highly Efficient and Selective Synthesis of Lissoclinolide Featuring Hydrogen Transfer Hydrozirconation, trans-Selective Pd-Catalyzed Cross Coupling of Alkenylzirconiums with 1,1-Dibromoalkenes and Ag-Catalyzed Lactonization Providing (Z)-γ-Alkylidenebutenolides. (1999) (0)
- Nickel-Catalyzed Conjugate Addition of Alkenylchlorobis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Formation of Carbon-Carbon and Carbon- Heteroatom Bonds via Organoboranes and Organoborates (1986) (0)
- SELECTIVE CARBON‐CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 35. A CONVENIENT SYNTHESIS OF UNSYMMETRICAL BIBENZYLS, HOMOALLYLARENES, AND HOMOPROPARGYLARENES VIA PALLADIUM‐CATALYZED CROSS COUPLING (1984) (0)
- C—C Bond Formation via Stoichiometric Transmetalation (2003) (0)
- Co-condensation of Metal Vapors with Arenes (2003) (0)
- Professor Ei-ichi Negishi (2001) (0)
- Convenient Synthesis of Diene-Zirconocenes and Regioselective Partial Reduction of the More Highly Substituted Double Bonds of Conjugated Dienes via Complexation with Zirconocenes and Protonolysis. (1994) (0)
- Conversion of Non-Conjugated Dienes into Conjugated Diene-Zirconocenes via Multipositional Regioisomerization. (1993) (0)
- Stereoselective Synthesis of Exocyclic Alkenes by Cu‐Catalyzed Allylmagnesiation, Pd‐Catalyzed Alkylation, and Ru‐Catalyzed Ring‐Closing Metathesis: Highly Stereoselective Synthesis of (Z)‐(V) and (E)‐(IX)‐γ‐Bisabolenes. (2002) (0)
- Synthesis of Bis(η-cyclopentadienyl)metal(IV) Complexes Containing Monohalo and/or Group 16 or 15 Atom Ligands and Their Derivatives with Modified Cyclopentadienyl Ligands (2003) (0)
- By Insertion Reactions of Cationic Alkylbis(η-cyclopentadienyl)zirconium Complexes (2003) (0)
- Other Migratory Insertion Reactions (2003) (0)
- Strictly Regiocontrolled Method for α‐Alkenylation of Cyclic Ketones via Palladium‐Catalyzed Cross‐Coupling. (1992) (0)
- Synthesis of Hydrazulenes via Zr-Promoted Bicyclization of Enynes and Transition Metal-Catalyzed or Radical Cyclization of Alkenyl Iodides. Efficient Synthesis of (.+-.)-7-epi-β-Bulnesene. (1997) (0)
- Anisotropic microwave complex conductivities in λ-(BEDT-TSF)2FeCl4 (2003) (0)
- Toothy spinning process and apparatus for performing the method (1975) (0)
- Light metal hydrides and superconductivity (1991) (0)
- Metal-Promoted Cyclization. Part 20. Palladium-Catalyzed Cyclization of Alkenyl and Aryl Halides Containing α,β-Unsaturated Carbonyl Groups via Intramolecular Carbopalladation. (1989) (0)
- By Amine Elimination (2003) (0)
- Synthesis of Arenes from Three Different Alkynes by Copper- or Nickel-Mediated Reactions of Alkynes with Zirconacyclopentadienes (2003) (0)
- Reactions of (η-Cyclooctatetraene)zirconium Derivatives (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. PART 20. HIGHLY SELECTIVE SYNTHESIS OF ALLYLATED ARENES AND DIARYLMETHANES VIA PALLADIUM-CATALYZED CROSS COUPLING INVOLVING BENZYLIC DERIVATIVES (1981) (0)
- Novel Bicyclization Methodology via Cyclialkylation of ω-Halo-1-metallo-1-alkynes Containing Aluminum and Zinc. (1988) (0)
- Other Reactions of Bis(η-cyclopentadienyl)diorganozirconium Complexes (2003) (0)
- Highly Stereoselective Synthesis of Exocyclic Alkenes via Cyclialkylation. (1988) (0)
- Synthesis of Bis(η-cyclopentadienyl)dihalometal(IV) Complexes and Their Derivatives with Modified Cyclopentadienyl Ligands (2003) (0)
- Back Cover: Widely Applicable Synthesis of Enantiomerically Pure Tertiary Alkyl-Containing 1-Alkanols by Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes and Palladium- or Copper-Catalyzed Cross-Coupling (Chem. Asian J. 8/2013) (2013) (0)
- Synthesis of Bis(η-cyclopentadienyl)metal(IV) "Ate" Complexes (2003) (0)
- Zwitterionic Bis(η-cyclopentadienyl)zirconium(IV) Derivatives (2003) (0)
- Complexation with Activated Zirconium(IV) and Hafnium(IV) Compounds of Low Electron Count (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 36. PALLADIUM-CATALYZED ACYLATION OF ORGANOZINCS AND OTHER ORGANOMETALLICS AS A CONVENIENT ROUTE TO KETONES (1984) (0)
- Palladium-Catalyzed Cyclic Acylmetalation of Allylic Electrophiles as a Route to Cyclopentenone Derivatives. (1989) (0)
- Highly Stereoselective and General Synthesis of Z‐3‐Methyl‐2‐alken‐1‐ ols via Palladium‐Catalyzed Cross Coupling of Z‐3‐Iodo‐2‐buten‐1‐ol with Organozincs and Other Organometals. (2010) (0)
- Metal-Promoted Cyclization. Part 29. Carbonylative Cyclization via Intramolecular Trapping of Acylmetal Derivatives by Carbon Nucleophiles Catalyzed by Late Transition Metals. (1990) (0)
- Palladium-Catalyzed Hydrogenation: Palladium-Catalyzed Heterogeneous Hydrogenation (2003) (0)
- Protonolysis, Halogenolysis, Oxidation, and Related Heteroatom—Carbon Bond Formation (2003) (0)
- Synthesis by Metal‐Mediated Coupling Reactions (2012) (0)
- By Protonation with Carborane (2003) (0)
- Pd-catalyzed cross-coupling reactions exhibiting catalystturnover numbers (TONs) exceeding one million (2012) (0)
- Acylpalladation and Related Addition Reactions—Intramolecular Acylpalladation: Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds (2003) (0)
- Migratory Insertion of Isocyanides and Carbon Monoxide (2003) (0)
- POTASSIUM (2-METHYL-l-CYCLOHEXENYLOXY)TRIETHYLBORATE (1986) (0)
- Frontispiece: Enantioselective Synthesis of Chiral Isotopomers of 1‐Alkanols by a ZACA–Cu‐Catalyzed Cross‐Coupling Protocol (2014) (0)
- Addition of Alkyl(chloro)bis(η-cyclopentadienyl)zirconium Complexes to Aldehydes (2003) (0)
- 5.3.2.6. From Organoboranes (2007) (0)
- Reactions of Allylbis(η-cyclopentadienyl)zirconium Derivatives with Aldehydes (2003) (0)
- Carbonyl Addition and Related Addition Reactions of σ-Organozirconium Complexes (2003) (0)
- Reactions of Bis(η-cyclopentadienyl)zirconium(IV) Derivatives with Alkynylmetals Containing Lithium and Magnesium (2003) (0)
- Palladium-Catalyzed Cross-Coupling Involving Alkylmetals or Alkyl Electrophiles (2003) (0)
- Cyclization Reactions of ω-Tosyloxy-1-alkynyl- and ω- Tosyloxy-1-alkenylborates and Their ω-Halo Analogues. (1993) (0)
- Efficient and Stereoselective Synthesis of Freelingyne (IX) via Pd-Catalyzed Cross Coupling and Lactonization. (1998) (0)
- ACS PRF Funding Leads to Nobel Prize in Chemistry for Two 2010 Laureates (2010) (0)
- Palladium-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, Aldehydes, and Other Carbonyl Compounds (2003) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS; 15. CONTROLLED CARBOMETALLATION; 6. A SELECTIVE AND EFFICIENT SYNTHESIS OF (E)-4-METHYL-3-ALKEN-1-OLS VIA ZIRCONIUM-CATALYZED CARBOALUMINATION OF TERMINAL ALKYNES (1981) (0)
- Efficient Synthesis of Carbobicyclic and Carbopolycyclic Compounds via Intramolecular Carbopalladation Catalyzed by Palladium-Phosphine Complexes. (1988) (0)
- Bis(η-cyclopentadienyl)zirconium(II)-Catalyzed C—C Bond Formation (2003) (0)
- Termination of Carbopalladation of Alkynes via Carbonylative Amidation Producing Lactams. (1995) (0)
- Selective Synthesis of Benzene Derivatives via Palladium-Catalyzed Cascade Carbometalation of Alkynes. (1993) (0)
- C—C Bond Formation via Carbonylation and Other Migratory Insertion Reactions of Bis(η-cyclopentadienyl)monoorganozirconium Complexes (2003) (0)
- Dielectric Slowing Down toward the Magnetically Ordered State in a Polar Conductor (EDT-TTFVO)_2FeBr_4(Condensed matter: electronic structure and electrical, magnetic, and optical properties) (2007) (0)
- Hydrogen Transfer Hydrozirconation of Alkenes with iBuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, and Pd. (2010) (0)
- Palladium‐Catalyzed trans‐Selective Alkynylation—Alkylation Tandem Process for the Synthesis of (E)‐3‐Alkyl‐1‐trialkylsilyl‐3‐alken‐1‐ynes. (2006) (0)
- Microwave response in the antiferromagnetic insulating states of λ-(BEDT-TSF)2FeCl4 (2003) (0)
- Highly Stereoselective and Efficient Synthesis of ω‐Heterofunctional Di‐ and Trienoic Esters for Horner—Wadsworth—Emmons Reaction via Alkyne Hydrozirconation and Pd‐Catalyzed Alkenylation. (2009) (0)
- Metal–Mono(η-cyclopentadienyl) and –Tris(η-cyclopentadienyl) Complexes and Related Derivatives (2003) (0)
- Reduction of Zirconium(IV) and Hafnium(IV) Compounds (2003) (0)
- Magical Power of d-Block Transition Metals as Catalysts for Organic Synthesis (2011) (0)
- SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSIS. 22. SCOPE OF THE PALLADIUM-CATALYZED COUPLING REACTION OF ORGANOMETALLICS WITH ALLYLIC ELECTROPHILES. EFFECT OF THE LEAVING GROUP (1982) (0)
- Reactions Between Homoallyl‐, and Homopropargyl‐, or Homobenzyl and Alkenyl or Aryl Electrophiles (2003) (0)
- By Reduction with Metals (2003) (0)
- Migratory Insertion Reactions of Organometallics. Part 3. Carbon-Carbon Bond-Forming Reactions of Organotransition Metals with α- or γ-Haloorganolithium Reagents. (1989) (0)
- Palladium‐Catalyzed Cross‐Coupling Involving β‐hetero‐ Substituted Compounds Other than Enolates (2003) (0)
- Novel Structures and Reaction Patterns in Organozirconium and Related Chemistry (1996) (0)
- Bis(η-cyclopentadienyl)monometallo- and Bis(η-cyclopentadienyl)dimetallozirconium Complexes (Excluding Hydrido Derivatives) (2003) (0)
- Zirconocene-Alkene Complexes: Their Formation, Structure, and Reactions (1993) (0)
- Coupling Reaction of Diiodobenzene with Zirconacyclopentadienes (2003) (0)
- Superconductivity and pseudogap states in λ-(BEDT-TSF)2GaCl4: Microwave conductivity measurements (2006) (0)
- Carbon-Carbon Bond Formation via Opening of Epoxysilanes with Organometals Containing Lithium and Copper. (1989) (0)
- Synthesis of Bis(η-cyclopentadienyl)dihalometal(IV) Complexes (2003) (0)
- Other Stoichiometric Reactions (2003) (0)
- A Selective Procedure for α‐Alkenylation of Enones Involving Pd‐ Catalyzed Alkenyl‐Alkenyl Coupling and Its Application to a Convergent and Efficient Synthesis of Nakienone B. (1996) (0)
- Palladium‐Catalyzed Synthesis of Conjugated Dienes: (5Z,7E)‐5,7‐Hexadecadiene (2003) (0)
- CARBOMETALATION. 13. SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION-METAL CATALYSIS. 28. A SELECTIVE SYNTHESIS OF ALKENYLMERCURIC CHLORIDES VIA ALKENYLALANES (1982) (0)
- Metal–Bis(η-cyclopentadienyl) Derivatives of Oxidation States Two and Three (2003) (0)
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