Elias James Corey
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American chemist
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Why Is Elias James Corey Influential?
(Suggest an Edit or Addition)According to Wikipedia, Elias James Corey is an American organic chemist. In 1990, he won the Nobel Prize in Chemistry "for his development of the theory and methodology of organic synthesis", specifically retrosynthetic analysis. Regarded by many as one of the greatest living chemists, he has developed numerous synthetic reagents, methodologies and total syntheses and has advanced the science of organic synthesis considerably.
Elias James Corey's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Inhibition of proteasome activities and subunit-specific amino-terminal threonine modification by lactacystin (1995) (1588)
- Protection of hydroxyl groups as tert-butyldimethylsilyl derivatives (1972) (1577)
- Dimethyloxosulfonium Methylide ((CH3)2SOCH2) and Dimethylsulfonium Methylide ((CH3)2SCH2). Formation and Application to Organic Synthesis (1965) (1190)
- Effect of dietary enrichment with eicosapentaenoic and docosahexaenoic acids on in vitro neutrophil and monocyte leukotriene generation and neutrophil function (1985) (1103)
- PYRIDINIUM CHLOROCHROMATE, AN EFFICIENT REAGENT FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS TO CARBONYL COMPOUNDS (1975) (1071)
- Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications (1987) (1059)
- A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′) (1972) (949)
- Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method. (1998) (910)
- Structural requirements of ligands for the oxysterol liver X receptors LXRalpha and LXRbeta. (1999) (881)
- The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters. (1998) (787)
- A stable and easily prepared catalyst for the enantioselective reduction of ketones. Applications to multistep syntheses (1987) (673)
- Catalytic enantioselective Diels--Alder reactions: methods, mechanistic fundamentals, pathways, and applications. (2002) (638)
- Useful procedures for the oxidation of alcohols involving pyridinium dichromate in aprotic media (1979) (608)
- Comparative airway and vascular activities of leukotrienes C-1 and D in vivo and in vitro. (1980) (604)
- The Logic of Chemical Synthesis (1989) (544)
- Local Effects of Synthetic Leukotrienes (LTC4, LTD4, and LTB4) in Human Skin (1983) (530)
- A Rational Approach to Catalytic Enantioselective Enolate Alkylation Using a Structurally Rigidified and Defined Chiral Quaternary Ammonium Salt under Phase Transfer Conditions (1997) (494)
- Stereo-controlled synthesis of dl-prostaglandins F2.alpha. and E2 (1969) (466)
- Generation and metabolism of 5-lipoxygenase pathway leukotrienes by human eosinophils: predominant production of leukotriene C4. (1983) (462)
- Computer-assisted design of complex organic syntheses. (1969) (448)
- Methylsulfinyl Carbanion (CH3-SO-CH2-). Formation and Applications to Organic Synthesis (1965) (432)
- New methods for the oxidation of aldehydes to carboxylic acids and esters (1968) (427)
- Generation and synthetic applications of 2-lithio-1,3-dithianes (1975) (426)
- Docosahexaenoic acid is a strong inhibitor of prostaglandin but not leukotriene biosynthesis. (1983) (412)
- Novel acetoxylation and C-C coupling reactions at unactivated positions in alpha-amino acid derivatives. (2006) (404)
- Bronchoconstrictor effects of leukotriene C in humans. (1982) (385)
- Efficient and mild lactonization method for the synthesis of macrolides (1974) (384)
- Slow reacting substances of anaphylaxis: identification of leukotrienes C-1 and D from human and rat sources. (1980) (377)
- Enantioselective synthesis of alpha-amino nitriles from N-benzhydryl imines and HCN with a chiral bicyclic guanidine as catalyst. (1999) (363)
- Oxidative hydrolysis of 1,3-dithiane derivatives to carbonyl compounds using N-halosuccinimide reagents (1971) (362)
- The Stereochemistry of Complex Inorganic Compounds. XXII. Stereospecific Effects in Complex Ions1 (1959) (342)
- General methods for the construction of complex molecules (1967) (333)
- Strategic applications of named reactions in organic synthesis: background and detailed mechanisms (2005) (331)
- Letter: Preparation of an optically active prostaglandin intermediate via asymmetric induction. (1975) (330)
- Studies with trialkylsilyltriflates: new syntheses and applications (1981) (327)
- Stereospecific total synthesis of a "slow reacting substance" of anaphylaxis, leukotriene C-1 (1980) (326)
- Effect of dietary enrichment with eicosapentaenoic and docosahexaenoic acids on in vitro neutrophil and monocyte leukotriene generation and neutrophil function. (1986) (318)
- Designed catalyst for enantioselective Diels-Alder addition from a C2-symmetric chiral bis(oxazoline)-iron(III) complex (1991) (304)
- Characterization and biologic properties of 5,12-dihydroxy derivatives of eicosapentaenoic acid, including leukotriene B5 and the double lipoxygenase product. (1984) (299)
- An efficient and catalytically enantioselective route to (S)-(−)-phenyloxirane (1988) (294)
- Selective cleavage of allyl ethers under mild conditions by transition metal reagents (1973) (294)
- The Wittig Reaction Using Methylsulfinyl Carbanion-Dimethyl Sulfoxide 1 (1963) (283)
- The Logic of Chemical Synthesis: Multistep Synthesis of Complex Carbogenic Molecules (Nobel Lecture)† (1991) (282)
- A New, Stereospecific Olefin Synthesis from 1,2-Diols (1963) (281)
- Effects of exogenous arachidonic, eicosapentaenoic, and docosahexaenoic acids on the generation of 5-lipoxygenase pathway products by ionophore-activated human neutrophils. (1984) (280)
- A Study of the Photochemical Reactions of 2-Cyclohexenones with Substituted Olefins (1964) (279)
- Practical enantioselective Diels-Alder and aldol reactions using a new chiral controller system (1989) (278)
- Effects of leukotriene D on the airways in asthma. (1983) (273)
- Structure of leukotriene C. Identification of the amino acid part. (1979) (263)
- Carbanions of 1,3-Dithianes. Reagents for CC Bond Formation by Nucleophilic Displacement and Carbonyl Addition (1965) (261)
- Enantioselective Total Synthesis of Ecteinascidin 743 (1996) (258)
- New and highly effective method for the oxidation of primary and secondary alcohols to carbonyl compounds (1972) (252)
- Leukotriene B4 action on endothelium mediates augmented neutrophil/endothelial adhesion. (1984) (250)
- Highly selective, kinetically controlled enolate formation using lithium dialkylamides in the presence of trimethylchlorosilane (1984) (241)
- Identification of the C(6)-S-conjugate of leukotriene A with cysteine as a naturally occurring slow reacting substance of anaphylaxis (SRS-A). Importance of the 11-cis-geometry for biological activity. (1980) (238)
- Evidence for a reversible d, π-complexation, β-cupration sequence in the conjugate addition reaction of Gilman reagents with α,β-enones. (1985) (230)
- re- and si-Face-Selective Nitroaldol Reactions Catalyzed by a Rigid Chiral Quaternary Ammonium Salt: A Highly Stereoselective Synthesis of the HIV Protease Inhibitor Amprenavir (Vertex 478). (1999) (229)
- Phenylthiomethyllithium and Bis(phenylthio)methyllithium (1966) (225)
- A total synthesis of ( )-fumagillin. (1972) (221)
- Mixed cuprate reagents of type R1R2CuLi which allow selective group transfer (1972) (220)
- Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis (1999) (213)
- A beta-lactone related to lactacystin induces neurite outgrowth in a neuroblastoma cell line and inhibits cell cycle progression in an osteosarcoma cell line. (1994) (207)
- Isolation of an Arabidopsis thaliana gene encoding cycloartenol synthase by functional expression in a yeast mutant lacking lanosterol synthase by the use of a chromatographic screen. (1993) (204)
- A practical and efficient method for enantioselective allylation of aldehydes (1989) (203)
- Stimulation of Renin Release from Rabbit Renal Cortex by Arachidonic Acid and Prostaglandin Endoperoxides (1976) (203)
- A Study of the Peroxidation of Organic Compounds by Externally Generated Singlet Oxygen Molecules (1964) (201)
- A short enantioselective pathway for the synthesis of the anti-influenza neuramidase inhibitor oseltamivir from 1,3-butadiene and acrylic acid. (2006) (200)
- A new system for catalytic enantioselective reduction of achiral ketones to chiral alcohols. Synthesis of chiral α-hydroxy acids (1990) (198)
- A short synthetic route to (+)-austamide, (+)-deoxyisoaustamide, and (+)-hydratoaustamide from a common precursor by a novel palladium-mediated indole --> dihydroindoloazocine cyclization. (2002) (197)
- A general, catalytic, and enantioselective synthesis of .alpha.-amino acids (1992) (197)
- New stereospecific synthesis of trisubstituted olefins. Stereospecific synthesis of farnesol (1967) (193)
- IgE-mediated release of leukotriene C4, chondroitin sulfate E proteoglycan, beta-hexosaminidase, and histamine from cultured bone marrow-derived mouse mast cells (1983) (191)
- The reactions of combined organocuprate-chlorotrimethylsilane reagents with conjugated carbonyl compounds (1985) (189)
- Enantioselective catalysis based on cationic oxazaborolidines. (2009) (188)
- Selective formation of carbon-carbon bonds between unlike groups using organocopper reagents (1967) (186)
- First application of attractive intramolecular interactions to the design of chiral catalysts for highly enantioselective Diels-Alder reactions (1991) (185)
- Asymmetric Diels-Alder reactions catalyzed by a triflic acid activated chiral oxazaborolidine. (2002) (185)
- Leukotrienes C4, D4 and E4: effects on human and guinea-pig cardiac preparations in vitro. (1982) (185)
- The mechanism of vascular leakage induced by leukotriene E4. Endothelial contraction. (1987) (183)
- Highly enantioselective catalytic Diels-Alder addition promoted by a chiral bis(oxazoline)-magnesium complex (1992) (182)
- Local effects of synthetic leukotrienes (LTC4, LTD4, LTE4, and LTB4) in human skin. (1983) (181)
- Highly enantioselective synthesis of cyclic and functionalized α-amino acids by means of a chiral phase transfer catalyst (1998) (180)
- Virtual long-range spin-spin couplings in NMR (1962) (180)
- A new synthesis of conjugated nitro cyclo olefins, unusually versatile synthetic intermediates (1978) (179)
- NAME REACTIONS IN HETEROCYCLIC CHEMISTRY (2009) (177)
- A Novel Chiral Super-Lewis Acidic Catalyst for Enantioselective Synthesis (1996) (176)
- Stereoelectronic Control in Enolization-Ketonization Reactions1 (1956) (171)
- A new general method for protection of the hydroxyl function (1976) (170)
- Total synthesis of prostaglandins F2-alpha and E2 as the naturally occurring forms. (1970) (170)
- Dimethylsulfonium Methylide, a Reagent for Selective Oxirane Synthesis from Aldehydes and Ketones (1962) (169)
- Leukotriene B. Total synthesis and assignment of stereochemistry (1980) (168)
- Stereospecific Syntheses of Olefins from 1,2-Thionocarbonates and 1,2-Trithiocarbonates. trans-Cycloheptene (1965) (168)
- Mechanism and Conditions for Highly Enantioselective Epoxidation of α,β-Enones Using Charge-Accelerated Catalysis by a Rigid Quaternary Ammonium Salt (1999) (166)
- Chemical and enzymic syntheses of 5-HPETE, a key biological precursor of slow-reacting substance of anaphylaxis (SRS), and 5-HETE (1980) (166)
- ENANTIOSELECTIVE TOTAL SYNTHESIS OF ASPIDOPHYTINE (1999) (163)
- Enantioselective Michael Addition of Nitromethane to α,β-Enones Catalyzed by Chiral Quaternary Ammonium Salts. A Simple Synthesis of (R)-Baclofen (2000) (162)
- A new chiral Rh(II) catalyst for enantioselective [2 + 1]-cycloaddition. mechanistic implications and applications. (2004) (161)
- Proteasome Inhibitors Block Development ofPlasmodium spp (1998) (160)
- Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition. (2003) (160)
- Stereospecific total synthesis of gibberellic acid. A key tricyclic intermediate (1978) (159)
- Robert Robinson Lecture. Retrosynthetic thinking—essentials and examples (1988) (158)
- Total synthesis and biological activity of lactacystin, omuralide and analogs. (1999) (157)
- New reagents for stereoselective carbonyl reduction. An improved synthetic route to the primary prostaglandins. (1971) (157)
- Airway constriction in normal humans produced by inhalation of leukotriene D. Potency, time course, and effect of aspirin therapy. (1983) (156)
- Effects of leukotrienes C4 and D4 on glycoprotein and lysozyme secretion by human bronchial mucosa. (1983) (156)
- New reagents for the intermolecular and intramolecular pinacolic coupling of ketones and aldehydes (1976) (156)
- Enantioselective Mukaiyama-aldol and aldol-dihydropyrone annulation reactions catalyzed by a tryptophan-derived oxazaborolidine (1992) (155)
- Stereospecific synthesis of trisubstituted and tetrasubstituted olefins. Conjugate addition of dialkylcopper-lithium reagents to .alpha.,.beta.-acetylenic esters (1969) (152)
- Renal and Systemic Hemodynamic Responses to Intravenous Infusion of Leukotriene C4 in the Rat (1984) (152)
- Phthalascidin, a synthetic antitumor agent with potency and mode of action comparable to ecteinascidin 743. (1999) (146)
- Enantioselective and practical syntheses of R- and S-fluoxetines (1989) (145)
- Enantioselective cyanosilylation of ketones catalyzed by a chiral oxazaborolidinium ion. (2005) (145)
- Enantioselective synthesis of β-hydroxy-α-amino acid esters by aldol coupling using a chiral quaternary ammonium salt as catalyst (1999) (145)
- Computer-assisted analysis in organic synthesis. (1985) (143)
- Total Synthesis of (±)-Ginkgolide B. (1988) (143)
- Renal actions of prostacyclin (1978) (143)
- The Synthesis of Olefins from O,O'-Dialkyl β-Lithioalkylphosphonothioate Esters (1966) (142)
- The formyl C–H⋯O hydrogen bond as a critical factor in enantioselective Lewis-acid catalyzed reactions of aldehydes (2001) (142)
- Method for catalytic dehalogenations via trialkyltin hydrides (1975) (138)
- Leukotriene E4-induced airway hyperresponsiveness of guinea pig tracheal smooth muscle to histamine and evidence for three separate sulfidopeptide leukotriene receptors. (1984) (138)
- Selective epoxidation of eicosa-cis-5,8,11,14-tetraenoic (arachidonic) acid and eicosa-cis-8,11,14-trienoic acid (1979) (138)
- Conversion of ketones having δ, ϵ-π-functions to cyclopentanols by zinc-trimethylchlorosilane (1983) (136)
- Enantioselective vicinal hydroxylation of terminal and E-1,2-disubstituted olefins by a chiral complex of osmium tetraoxide. An effective controller system and a rational mechanistic model (1989) (136)
- Short, enantioselective total synthesis of okaramine N. (2003) (134)
- A Study of the Formation of Haloamines and Cyclic Amines by the Free Radical Chain Decomposition of N-Haloammonium Ions (Hofmann-Löffler Reaction)1 (1960) (134)
- Leukotriene A: stereochemistry and enzymatic conversion to leukotriene B. (1980) (132)
- A practical and general enantioselective synthesis of chiral propa-1,2-dienyl and propargyl carbinols (1990) (132)
- Stereospecific total synthesis of the dl-C18 Cecropia juvenile hormone (1968) (132)
- Bronchoconstrictor effects of leukotriene E4 in normal and asthmatic subjects. (1987) (130)
- Broad-spectrum enantioselective diels-alder catalysis by chiral, cationic oxazaborolidines. (2002) (129)
- New enantioselective routes to biologically interesting compounds (1990) (129)
- A mild, catalytic, and highly selective method for the oxidation of α, β-enones to 1,4-enediones (2003) (128)
- Total synthesis of lactacystin (1992) (128)
- Carbon-carbon bond formation by selective coupling of n-alkylcopper reagents with organic halides (1968) (125)
- Total Synthesis of Erythromycins. 4. Total Synthesis of Erythronolide B1 (1978) (125)
- Internal Photoaddtion Reactions of 2-Pyrone and N-Methyl-2-pyridone: A New Synthetic Approach to Cyclobutadiene (1964) (124)
- Enantioselective conjugate addition of rationally designed chiral cuprate reagents to 2-cycloalkenones (1986) (124)
- Highly enantioselective Michael reactions catalyzed by a chiral quaternary ammonium salt. Illustration by asymmetric syntheses of (S)-ornithine and chiral 2-cyclohexenones. (2000) (124)
- Oxidation of primary amines to ketones (1969) (123)
- Highly Enantioselective Alkynylation of Aldehydes Promoted by Chiral Oxazaborolidines (1994) (122)
- MICROBIOLOGICAL DEGRADATION OF (+)-CAMPHOR (1959) (121)
- Total Synthesis of Longifolene (1964) (120)
- Total synthesis of (.+-.)-aphidicolin (1980) (118)
- A new general synthetic route to bridged carboxylic ortho esters (1984) (117)
- Functional characterization of synthetic leukotriene B and its stereochemical isomers (1981) (117)
- Total synthesis of (±)-forskolin (1988) (116)
- Total synthesis of prostaglandins. Synthesis of the pure dl-E1, -F(sub 1.alpha.), -F(sub 1.beta.), -A1, and -B1 hormones (1968) (116)
- Conversion of leukotriene D4 to leukotriene E4 by a dipeptidase released from the specific granule of human polymorphonuclear leucocytes. (1983) (115)
- Useful new organometallic reagents for the synthesis of allylic alcohols by nucleophilic vinylation (1975) (115)
- Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketones (1970) (115)
- Total synthesis of erythromycins. 5. Total synthesis of erythronolide A [41] (1979) (114)
- A general process for the haloamidation of olefins. Scope and mechanism. (2006) (114)
- Total synthesis of (S)-12-hydroxy-5,8,14-cis,-10-trans-eicosatetraenoic acid (Samuelsson's HETE) (1978) (114)
- Stereochemistry of leukotriene C-1. (1980) (113)
- Highly Enantioselective Phase Transfer Catalyzed Alkylation of a 3-Oxygenated Propionic Ester Equivalent; Applications and Mechanism (1998) (113)
- Leukotriene A. Isolation from human polymorphonuclear leukocytes. (1980) (111)
- d-Orbital stereoelectronic control of the stereochemistry of SN2' displacements by organocuprate reagents (1984) (111)
- Highly enantioselective [2+2]-cycloaddition reactions catalyzed by a chiral aluminum bromide complex. (2007) (111)
- Novel electronic effects of remote substituents on the oxazaborolidine-catalyzed enantioselective reduction of ketones (1995) (109)
- Total synthesis of the quinonoid alcohol dehydrogenase coenzyme (1) of methylotrophic bacteria (1981) (109)
- A new chiral catalyst for the enantioselective synthesis of secondary alcohols and deuterated primary alcohols by carbonyl reduction (1989) (108)
- Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols (1990) (108)
- Organonickel compounds as reagents for selective carbon-carbon bond formation between unlike groups (1967) (107)
- Generation of leukotriene C4 from a subclass of mast cells differentiated in vitro from mouse bone marrow. (1982) (106)
- A new and general synthesis of polycyclic .gamma.-lactones by double annulation (1984) (106)
- The origin of greater than 200:1 enantioselectivity in a catalytic Diels-Alder reaction as revealed by physical and chemical studies (1992) (105)
- Catalytic enantioselective diels-alder addition to furan provides a direct synthetic route to many chiral natural products (1993) (105)
- Name reactions for functional group transformations (2007) (104)
- A mild procedure for the conversion of 1,2-diols to olefins (1982) (104)
- New synthesis of .alpha.,.beta.-unsaturated aldehydes using 1,3-bis(methylthio)allyllithium (1971) (104)
- A stereoselective synthesis of (+-)-11-hydroxy-trans-8-dodecenoic acid lactone, a naturally occurring macrolide from Cephalosporium recifei (1976) (103)
- Efficient generation of the 15S configuration in prostaglandin synthesis. Attractive interactions in stereochemical control of carbonyl reduction. (1972) (103)
- Molecular cloning, characterization, and overexpression of ERG7, the Saccharomyces cerevisiae gene encoding lanosterol synthase. (1994) (103)
- A method for selective conversion of allylic and benzylic alcohols to halides under neutral conditions (1972) (102)
- Highly enantioselective and diastereoselective Ireland-Claisen rearrangement of achiral allylic esters (1991) (102)
- Proteasome activity is required for the stage-specific transformation of a protozoan parasite (1996) (102)
- Synthesis of 1,n‐Dicarbonyl Derivates Using Carbanions from 1,3‐Dithianes (1965) (101)
- TOTAL SYNTHESIS OF LEUKOTRIENE B5 (1984) (100)
- The Stereochemistry of α-Haloketones. I. The Molecular Configurations of Some Monocyclic α-Halocyclanones (1953) (100)
- Diisopropylsilyl ditriflate and di--butysilyl ditriflate: new reagents for the protection of diols (1982) (100)
- A new process for the enantioselective synthesis of chiral α-aryloxy- and α-hydroxy acids (1992) (98)
- Enantioselective and structure-selective Diels-Alder reactions of unsymmetrical quinones catalyzed by a chiral oxazaborolidinium cation. Predictive selection rules. (2004) (98)
- Direct Catalytic Enantioselective Reduction of Achiral α,β-Ynones. Strong Remote Steric Effects Across the C−C Triple Bond (1996) (98)
- Enantioselective conversion of aldehydes to cyanohydrins by a catalytic system with separate chiral binding sites for aldehyde and cyanide components (1993) (98)
- Diverse pathways for the palladium(II)-mediated oxidation of olefins by tert-butylhydroperoxide. (2002) (98)
- Chiral oxazaborolidine-aluminum bromide complexes are unusually powerful and effective catalysts for enantioselective Diels-Alder reactions. (2007) (97)
- A New Synthesis of Ketones (1964) (97)
- Nucleophilic ethynyl group equivalent and its use in conjugate addition to .alpha.,.beta.-enones (1974) (97)
- Synthesis and biological properties of a 9,11-azo-prostanoid: highly active biochemical mimic of prostaglandin endoperoxides. (1975) (96)
- An effective enantioselective route to the platensimycin core. (2007) (96)
- Efficient Synthesis and Intramolecular Cyclopropanation of Unsaturated Diazoacetic Esters (1984) (96)
- CHEMISTRY OF DIIMIDE. II. STEREOCHEMISTRY OF HYDROGEN TRANSFER TO CARBON-CARBON MULTIPLE BONDS (1961) (96)
- Reaction of 1,3-dithienium fluoroborate with 1,3-dienes. Synthesis of .DELTA.3-cyclopenten-1-ones (1972) (95)
- First enantiospecific total synthesis of the antitubercular marine natural product pseudopteroxazole. Revision of assigned stereochemistry. (2003) (95)
- Immunologically induced generation of tetraene and pentaene leukotrienes in the peritoneal cavities of menhaden-fed rats. (1984) (95)
- Calculation of Molecular Geometry by Vector Analysis. Application to Six-membered Alicyclic Rings1 (1955) (95)
- Polyfunctional, structurally defined catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes (1990) (94)
- Total synthesis of (.+-.)-antheridium-inducing factor (AAn) of the Fern Anemia phyllitidis. Clarification of stereochemistry (1985) (94)
- Studies on the asymmetric synthesis of alpha-amino acids. I. A new approach. (1970) (93)
- Catalytic Diastereoselective Synthesis of Cis-1,2-Disubstituted Cyclopropanols from Esters Using a Vicinal Dicarbanion Equivalent (1994) (93)
- Intermediacy of 8-(R)-HPETE in the conversion of arachidonic acid to pre-clavulone a by Clavularia viridis. Implications for the biosynthesis of marine prostanoids (1987) (93)
- The application of a mechanistic model leads to the extension of the Sharpless asymmetric dihydroxylation to allylic 4-methoxybenzoates and conformationally related amine and homoallylic alcohol derivatives. (1995) (92)
- A new chiral catalyst for the enantioselective Strecker synthesis of alpha-amino acids. (2004) (92)
- A Stereospecific Total Synthesis of α-Santalol (1970) (92)
- Pharmacological activity of leukotrienes A4, B4, C4 and D4 on selected guinea-pig, rat, rabbit and human smooth muscles. (1981) (91)
- New synthetic route to cyclic mono- and diketone derivatives via bisthiocarbanions (1968) (91)
- Total synthesis of (+/-)-pentacycloanammoxic acid. (2004) (91)
- Stereospecific total synthesis of prostaglandins E3 and F3 alpha. (1971) (91)
- Magnesium and zinc-catalyzed thioketalization (1983) (89)
- Transformations in the 1,10-Phenanthroline Series (1965) (89)
- Conversion of Torgov's synthesis of estrone into a highly enantioselective and efficient process. (2007) (88)
- Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis. (2005) (88)
- Total synthesis of erythromycins. 3. Stereoselective routes to intermediates corresponding to C(1) to C(9) and C(10) to C(13) fragments of erythronolide B (1978) (88)
- Base-catalyzed carboxylation of organic halides by nickel carbonyl in protic media (1969) (87)
- Superoxide ion as a synthetically useful oxygen nucleophile (1975) (87)
- The myeloperoxidase-dependent metabolism of leukotrienes C4, D4, and E4 to 6-trans-leukotriene B4 diastereoisomers and the subclass-specific S-diastereoisomeric sulfoxides. (1983) (86)
- Rigid and highly enantioselective catalyst for the dihydroxylation of olefins using osmium tetraoxide clarifies the origin of enantiospecificity (1993) (86)
- A Convenient and Versatile Route to Hydroquinolines by Inter- and Intramolecular Aza-Diels-Alder Pathways. (1999) (86)
- Computer-assisted synthetic analysis. Facile man-machine communication of chemical structure by interactive computer graphics (1972) (85)
- Enantioselective total synthesis of a protosterol, 3.beta.,20-dihydroxyprotost-24-ene (1990) (84)
- Controlled chemical synthesis of the enzymatically produced eicosanoids 11-, 12-, and 15-HETE from arachidonic acid and conversion into the corresponding hydroperoxides(HPETE) [13] (1980) (83)
- General methods of synthetic analysis. Strategic bond disconnections for bridged polycyclic structures (1975) (82)
- A Critical Analysis of the Mechanistic Basis of Enantioselectivity in the Bis-Cinchona Alkaloid Catalyzed Dihydroxylation of Olefins (1996) (82)
- The first enantioselective synthesis of the chemotactic factor sirenin by an intramolecular [2 + 1] cyclization using a new chiral catalyst (1995) (82)
- Immunologic and ionophore-induced generation of leukotriene B4 from mouse bone marrow-derived mast cells. (1983) (81)
- Concise total syntheses of palominol, dolabellatrienone, beta-araneosene, and isoedunol via an enantioselective Diels-Alder macrobicyclization. (2006) (81)
- A Useful Method for the Conversion of Azides to Amines (1975) (81)
- A CATALYTIC ENANTIOSELECTIVE SYNTHESIS OF DENOPAMINE, A USEFUL DRUG FOR CONGESTIVE HEART FAILURE (1991) (81)
- Total synthesis of a C15 ginkgolide, (.+-.)-bilobalide (1987) (80)
- An Efficient and Concise Enantioselective Total Synthesis of Lactacystin. (1998) (80)
- Two effective procedures for the synthesis of trichloromethyl ketones, useful precursors of chiral α-amino and α-hydroxy acids (1992) (80)
- Total synthesis of (.+-.)-atractyligenin (1987) (80)
- The Structures of the Triterpenes Friedelin and Cerin1,2 (1956) (80)
- Cardiovascular responses to PGI2 (prostacyclin) in the dog. (1978) (80)
- Construction of ring systems containing the gemdimethylcyclopropane unit using diphenylsulfonium isopropylide (1967) (80)
- Antitumor activity- and gene expression-based profiling of ecteinascidin Et 743 and phthalascidin Pt 650. (2001) (80)
- A new, more efficient, and effective process for the synthesis of a key pentacyclic intermediate for production of ecteinascidin and phthalascidin antitumor agents. (2000) (79)
- An experimental demonstration of the stereochemistry of enzymic cyclization of 2,3-oxidosqualene to the protosterol system, forerunner of lanosterol and cholesterol (1991) (79)
- Catalytic enantioselective synthesis of the second generation histamine antagonist cetirizine hydrochloride (1996) (78)
- New synthetic route for the enantioselective total synthesis of salinosporamide A and biologically active analogues. (2005) (78)
- Chromium trioxide-3, 5-dimethylpyrazole complex as a reagent for oxidation of alcohols to carbonyl compounds (1973) (78)
- Asymmetric synthesis of (S)-carbinoxamine. New aspects of oxazaborolidine-catalyzed enantioselective carbonyl reduction (1996) (78)
- Studies on the Substrate Binding Segments and Catalytic Action of Lanosterol Synthase. Affinity Labeling with Carbocations Derived from Mechanism-Based Analogs of 2,3-Oxidosqualene and Site-Directed Mutagenesis Probes (1997) (78)
- Applications of N,N-dimethylhydrazones to synthesis. Use in efficient, positionally and stereochemically selective CC bond formation; oxidative hydrolysis to carbonyl compounds (1976) (78)
- A New Magnesium-Catalyzed Doubly Diastereoselective anti-Aldol Reaction Leads to a Highly Efficient Process for the Total Synthesis of Lactacystin in Quantity (1998) (78)
- THE STEREOCHEMISTRY OF 7α-HYDROXYLATION IN THE BIOSYNTHESIS OF CHOLIC ACID FROM CHOLESTEROL (1958) (77)
- X-Ray crystal structure of a chiral oxazaborolidine catalyst for enantioselective carbonyl reduction (1992) (77)
- Useful synthetic reagents derived from 1-triisopropylsilylpropyne and 1,3-[triisopropylsilyl]propyne, direct, stereoselective synthesis of either or enynes (1982) (77)
- Short, enantioselective total synthesis of aflatoxin B2 using an asymmetric [3+2]-cycloaddition step. (2005) (77)
- Simple Total Synthesis of the Pentacyclic Cs-Symmetric Structure Attributed to the Squalenoid Glabrescol and Three Cs-Symmetric Diastereomers Compel Structural Revision (2000) (76)
- Total synthesis of (.+-.)-ovalicin (1985) (76)
- Enantiospecific total synthesis of pseudopterosins A and E (1989) (76)
- Radioimmunoassay of the leukotrienes of slow reacting substance of anaphylaxis. (1981) (76)
- The origin of high enantioselectivity in the dihydroxylation of olefins using osmium tetraoxide and cinchona alkaloid catalysts (1993) (75)
- Studies on the mechanism of formation of the 5S, 12S-dihydroxy-6,8,10,14(E,Z,E,Z)-icosatetraenoic acid in leukocytes. (1982) (75)
- Modification of the Wittig reaction to permit the stereospecific synthesis of certain trisubstituted olefins. Stereospecific synthesis of .alpha.-santalol (1970) (75)
- The application of the formyl CH--O hydrogen bond postulate to the understanding of enantioselective reactions involving chiral boron lewis acids and aldehydes (1997) (75)
- Highly enantioselective and diastereoselective synthesis of β-amino acid esters and β-lactams from achiral esters and imines (1991) (74)
- Total synthesis of (+-)-.alpha.- and (+-)-.beta.-copaenes and ylangenes (1973) (74)
- Antiarthritic gold compounds effectively quench electronically excited singlet oxygen. (1987) (74)
- A method for deoxygenation of allylic and benzylic alcohols (1969) (74)
- Total Synthesis of d,l-Caryophyllene and d,l-Isocaryophyllene (2002) (74)
- Zinc complexes of chiral phenols as catalysts for enantioselective addition of organozinc reagents to aldehydes (1987) (74)
- Hepoxilin A3 induces changes in cytosolic calcium, intracellular pH and membrane potential in human neutrophils. (1990) (74)
- A simple and highly effective route to α,β-unsaturated aldehydes (1976) (73)
- Stereocontrolled total synthesis of (+)- and (-)-epibatidine (1993) (73)
- Reagent for the .alpha.,.beta. reduction of conjugated nitriles (1975) (73)
- Simple Enantioselective Total Synthesis of Glabrescol, a Chiral C2-Symmetric Pentacyclic Oxasqualenoid (2000) (73)
- Enantioselective synthesis of pentacycloanammoxic acid. (2006) (73)
- Water induced dismutation of superoxide anion generates singlet molecular oxygen. (1987) (72)
- Total synthesis of humulene (1967) (72)
- Chemistry of diimide. Some new systems for the hydrogenation of multiple bonds (1961) (72)
- Application of chiral cationic catalysts to several classical syntheses of racemic natural products transforms them into highly enantioselective pathways. (2004) (72)
- 1,4 Addition of acyl groups to conjugated enones (1969) (72)
- A simple total synthesis of (plus of minus)-perhydrohistrionicotoxin. (1975) (72)
- Centenary lecture. Computer-assisted analysis of complex synthetic problems (1971) (72)
- LHASA—Logic and Heuristics Applied to Synthetic Analysis (1977) (71)
- Contractile activities of structural analogs of leukotrienes C and D: role of the polar substituents. (1981) (71)
- Synthesis of Vane's prostaglandin X, 6,9alpha-oxido9alpha,15alpha-dihydroxyprosta-(Z)5,(E)13-dienoic acid. (1977) (71)
- A new total synthesis of prostaglandins of the E1 and F1 series including 11-epiprostaglandins. (1968) (71)
- Kinetic Investigations Provide Additional Evidence That an Enzyme-like Binding Pocket Is Crucial for High Enantioselectivity in the Bis-Cinchona Alkaloid Catalyzed Asymmetric Dihydroxylation of Olefins (1996) (71)
- Convenient synthesis of (S)-(-)-pulegone from (-)-citronellol (1976) (71)
- Pd(OH)2/C-Mediated Selective Oxidation of Silyl Enol Ethers by tert-Butylhydroperoxide, a Useful Method for the Conversion of Ketones to α,β-Enones or β-Silyloxy-α,β-enones (2005) (71)
- Total synthesis of dl-sirenin (1969) (71)
- Total synthesis of (+)-alpha-onocerin in four steps via four-component coupling and tetracyclization steps. (2002) (71)
- Recent studies on the chemical synthesis of eicosanoids. (1980) (70)
- Short Enantioselective Synthesis of (-)-Ovalicin, a Potent Inhibitor of Angiogenesis, Using Substrate-Enhanced Catalytic Asymmetric Dihydroxylation (1994) (70)
- Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis. (2010) (70)
- Molecules and Medicine (2007) (70)
- A Stereocontrolled and effective synthesis of leukotriene B (1). (1981) (70)
- Evidence in favor of an organoiron-mediated pathway for lipoxygenation of fatty acids by soybean lipoxygenase (1987) (70)
- Highly enantioselective routes to Darzens and acetate aldol products from achiral aldehydes and t-butyl bromoacetate (1991) (70)
- Stereospecific total synthesis of gibberellic acid (1978) (69)
- A method for the selective oxidation of 1,4-diols to lactols (1995) (69)
- X-ray crystallographic and NMR studies on the origins of high enantioselectivity in diels-alder reactions catalyzed by a chiral diazaaluminolidine (1992) (69)
- ENANTIOSELECTIVE TOTAL SYNTHESIS OF GRACILINS B AND C USING CATALYTIC ASYMMETRIC DIELS-ALDER METHODOLOGY (1995) (69)
- (+)-1(S), 5(R), 8(S)-8-phenyl-2-azabicyclo[3.3.0]octan-8-ol n,o-methylboronate (2) and its enantiomer, chiral chemzymes which serve as catalysts for their own enantioselective synthesis (1989) (68)
- Application of bisthiocarbanions to the elaboration of 2-cyclohexenone systems (1968) (68)
- Total synthesis of (.+-.)-retigeranic acid (1985) (68)
- Enantioselective total synthesis of oleanolic acid, erythrodiol, .beta.-amyrin, and other pentacyclic triterpenes from a common intermediate (1993) (68)
- Enantioselective route to a key intermediate in the total synthesis of ginkgolide B (1988) (68)
- Catalytic enantioselective conjugate addition of trimethylsilylacetylene to 2-cyclohexen-1-one. (2004) (68)
- A new stereocontrolled synthesis of prostaglandins via prostaglandin A. (1973) (68)
- Total synthesis of venustatriol (1988) (68)
- Chiral catalysts for the enantioselective addition of organometallic reagents to aldehydes (1987) (68)
- Synthesis of brefeldin A, carpaine, vertaline, and erythronolide B from nonmacrocyclic precursors (1975) (68)
- Total synthesis of maytansine (1980) (68)
- Improved synthetic routes to prostaglandins utilizing sulfide-mediated oxidation of primary and secondary alcohols. (1973) (67)
- RATIONALLY DESIGNED, POTENT COMPETITIVE INHIBITORS OF LEUKOTRIENE BIOSYNTHESIS (1984) (67)
- Synthesis of racemic .alpha.-trans- and .beta.-trans-bergamotene (1971) (67)
- Letter: A total synthesis of natural 20(S)-camptothecin. (1975) (67)
- The Mechanism of the Decarboxylation of α,β- and β,γ-Unsaturated Malonic Acid Derivatives and the Course of Decarboxylative Condensation Reactions in Pyridine1 (1952) (67)
- A short enantioselective total synthesis of the fundamental pentacyclic triterpene lupeol. (2009) (67)
- Identification of a high affinity leukotriene C4-binding protein in rat liver cytosol as glutathione S-transferase. (1986) (67)
- Evidence for the importance of π-π-attractive interactions in Enantioselective Diels-Alder reactions chiral catalysts of type (RO)2TiCl2 (1991) (67)
- The total synthesis of dihydrocostunolide. (1963) (66)
- Letter: Total synthesis of (plus or minus)-vermiculine. (1975) (66)
- New Insights Regarding the Cyclization Pathway for Sterol Biosynthesis from (S)-2,3-Oxidosqualene (1995) (66)
- .alpha.-Lithiomethylenetriphenylphosphorane, a highly reactive ylide equivalent (1982) (65)
- One-step conversion of primary alcohols in the carbohydrate series to the corresponding carboxylic tert-butyl esters (1984) (65)
- The Synthesis of d,l-β-Santalene and d,l-epi-β-Santalene by Stereospecific Routes (1962) (65)
- Notes. A Novel Preparation of Isonitriles (1958) (65)
- Bioconversion of C-6 sulfidopeptide leukotrienes by the responding guinea pig ileum determines the time course of its contraction. (1983) (65)
- 2,3-iminosqualene, a potent inhibitor of the enzymic cyclization of 2,3-oxidosqualene to sterols. (1967) (65)
- Molecular cloning of the human gene encoding lanosterol synthase from a liver cDNA library. (1995) (65)
- Actions of arachidonic acid and hepoxilin A3 on mammalian hippocampal CA1 neurons (1989) (65)
- Formation and Photochemical Rearrangement of β′-Ketosulfoxonium Ylides (1964) (64)
- Methodology for the Preparation of Pure Recombinant S. cerevisiae Lanosterol Synthase Using a Baculovirus Expression System. Evidence That Oxirane Cleavage and A-Ring Formation Are Concerted in the Biosynthesis of Lanosterol from 2,3-Oxidosqualene (1997) (64)
- Oxidative inactivation of leukotriene C4 by stimulated human polymorphonuclear leukocytes. (1982) (64)
- Highly enantioselective proton-initiated polycyclization of polyenes. (2012) (64)
- Specific reduction of E prostaglandins to F.alpha. prostaglandins and prostaglandin E2 to prostaglandin E1 (1971) (63)
- Enantioselective total synthesis of miroestrol (1993) (63)
- A new and highly enantioselective synthetic route to P-chiral phosphines and diphosphines (1993) (62)
- Total synthesis of (.+-.)-N-methylmaysenine (1978) (62)
- Simple, catalytic enantioselective syntheses of estrone and desogestrel. (2004) (62)
- The Formation of Carbonium Ions by Oxidative Decarboxylation of Carboxylic Acids with Lead Tetraacetate (1963) (62)
- Demonstration of the Synthetic Power of Oxazaborolidine-Catalyzed Enantioselective Diels-Alder Reactions by Very Efficient Routes to Cassiol and Gibberellic Acid (1994) (62)
- Biosynthesis of 8-R-HPETE and preclavulone-A from arachidonate in several species of caribbean coral. A widespread route to marine prostanoids. (1988) (61)
- Contractile activities of structural analogs of leukotrienes C and D: necessity of a hydrophobic region. (1981) (61)
- Stereospecific total synthesis of (.+-.)-cafestol (1987) (61)
- (3-Methyl-3-methoxy-1-butynyl)copper, a useful reagent for the generation of mixed cuprates (1978) (61)
- THE SYNTHESIS OF DIHYDROCONESSINE. A METHOD FOR FUNCTIONALIZING STEROIDS AT C18 (1958) (60)
- Studies on the symmetric synthesis of alpha-amino acids. II. New systems for highly specific asymmetric synthesis with conservation of the Chiral reagent. (1970) (60)
- Specific receptors for leukotriene C4 on a smooth muscle cell line. (1983) (60)
- Proteasome-dependent cyst formation and stage-specific ubiquitin mRNA accumulation in Entamoeba invadens. (1999) (60)
- Sulfur-bridged carbocycles. II. Extrusion of the sulfur bridge (1969) (60)
- An efficient, stereocontrolled synthesis of a potent omuralide-salinosporin hybrid for selective proteasome inhibition. (2005) (60)
- Method for stereospecific synthesis of 1,3- and 1,4-dienes via organocopper reagents (1972) (60)
- Molecular cloning of a Schizosaccharomyces pombe cDNA encoding lanosterol synthase and investigation of conserved tryptophan residues. (1996) (60)
- Efficient Method for Selective Introduction of Substituents as C(5) of Isoleucine and Other α-Amino Acids (2006) (59)
- Total synthesis of prostaglandins F1-alpha, E1, F2-alpha, and E2 (natural forms) from a common synthetic intermediate. (1970) (59)
- Total synthesis of (.+-.)-5,6-oxido-7,9-trans,11,14-cis-eicosapentaenoic acid, a possible precursor of SRSA (1979) (59)
- A catalytic enantioselective synthetic route to the important antidepressant sertraline (1994) (59)
- An Exceptionally Short and Simple Enantioselective Total Synthesis of Pentacyclic Triterpenes of the β-Amyrin Family (1999) (59)
- Reaction of oxime O-acetates with chromous acetate. Method for the conversion of ketoximes to ketones under mild conditions (1970) (59)
- A powerful new construction of complex chiral polycycles by an indium(III)-catalyzed cationic cascade. (2011) (59)
- Total synthesis of (.+-.)-paeoniflorigenin and paeoniflorin (1993) (58)
- A mechanistic and structural analysis of the basis for high enantioselectivity in the oxazaborolidine-catalyzed reduction of trihalomethyl ketones by catecholborane (1992) (58)
- Method for the protection of lactones and esters against nucleophilic attack (1973) (58)
- Total synthesis and stereochemistry of hybridalactone (1984) (58)
- New extensions of the bicyclo[2.2.1]heptane route to prostaglandins. (1973) (58)
- Enantioselective Total Synthesis of the Potent Anti-HIV Agent Neotripterifordin. Reassignment of Stereochemistry at C(16) (1997) (58)
- Catalytic reactions of samarium (II) iodide (1997) (58)
- The Stereochemistry of α-Haloketones. V. Prediction of the Stereochemistry of α-Brominated Ketosteroids (1954) (57)
- Enantioselective Michael reactions. Stereoselective addition of enolates of phenmenthol esters to crotonates (1985) (57)
- Total synthesis of picrotoxinin (1979) (57)
- A NEW SYNTHETIC ROUTE TO PROSTAGLANDINS (1973) (57)
- Stereochemical course of 5-lipoxygenation of arachidonate by rat basophil leukemic cell (RBL-1) and potato enzymes (1983) (57)
- New reagents for the conversion of hydroxy acids to macrolactones by the double activation method (1976) (57)
- Convenient routes to symmetrical benzils and chiral 1,2-diaryl-1,2-diaminoethanes, useful controllers and probes for enantioselective synthesis (1995) (57)
- A soluble 2,3-oxidosqualene sterol cyclase. (1967) (57)
- A total synthesis of prostaglandin F2-alpha (dl) from 2-oxabicyclo[3.3.0]oct-6-en-3-one. (1970) (57)
- A HYPOTHESIS FOR CONFORMATIONAL RESTRICTION IN COMPLEXES OF FORMYL COMPOUNDS WITH BORON LEWIS ACIDS. EXPERIMENTAL EVIDENCE FOR FORMYL CH--O AND CH--F HYDROGEN BONDS (1997) (57)
- New Synthetic Approaches to Symmetrical Sulfur-Bridged Carbocycles (1966) (57)
- Enantioselective route to a key intermediate in the total synthesis of forskolin (1988) (56)
- Total synthesis of slow reacting substances (SRS). “Leukotriene C-2” (11--leukotriene C) (3) and leukotriene D (4) (1980) (56)
- Enantioselective Total Synthesis of .beta.-Elemene and Fuscol Based on Enantiocontrolled Ireland-Claisen Rearrangement (1995) (56)
- The first enantioselective syntheses of pure R- and S-isoproterenol (1990) (55)
- Inhibition of hatching of mouse blastocysts in vitro by various prostaglandin antagonists. (1981) (55)
- Proteasome inhibition by a totally synthetic beta-lactam related to salinosporamide A and omuralide. (2005) (55)
- Rapid and enantioselective synthetic approaches to germanicol and other pentacyclic triterpenes. (2008) (55)
- A Simple Enantioselective Synthesis of the Biologically Active Tetracyclic Marine Sesterterpene Scalarenedial (1997) (54)
- A practical process for large-scale synthesis of (S)-5-hydroxy-6-trans-8,11,14-cis-eicosatetraenoic acid (5-HETE) (1981) (54)
- Coordinattvely induced 1,4-diastereoselection in the reaction of acyclic α,β-enones with organocopper reagents. A new type of organocopper reagent (1989) (54)
- Enantioselective total synthesis of bilobalide, A C15 ginkgolide (1988) (54)
- Total synthesis of aplasmomycin. Stereocontrolled construction of the C(3)-C(17) fragment (1982) (53)
- trans-2-Cycloheptenone (1965) (53)
- Total Synthesis ofd,l-Caryophyllene andd,l-Isocaryophyllene (1963) (53)
- Origin of enantioselectivity in the Jacobsen epoxidation of olefins. (2009) (53)
- Synthetic routes to polyfunctional molecules via metallated N,N-dimethylhydrazones (1976) (53)
- Cleavage of allyloxycarbonyl protecting group from oxygen and nitrogen under mild conditions by nickel carbonyl (1973) (53)
- Reductive cleavage of tert-butyldimethylsilyl ethers by diisobutylaluminum hydride (1992) (53)
- Discovery of potent and practical antiangiogenic agents inspired by cortistatin A. (2009) (52)
- Reaction of δ- and ϵ-Halo Ketones with Certain Anionic Transition Metal Complexes. A Useful New Cyclization Method. (1970) (52)
- Homoconjugate addition of organocopper reagents to cyclopropanes and its application to the synthesis of prostanoids. (1972) (52)
- Methoxymethylation of thallous cyclopentadienide. A simplified preparation of a key intermediate for the synthesis of prostaglandins. (1971) (52)
- A direct,stereocontrolled total synthesis of the 9,11-azo analogue of the prostaglandin endoperoxide, PGH2. (1976) (51)
- Enantioselective routes to chiral benzylic thiols, sulfinic esters and sulfonic acids illustrated by the 1-phenylethyl series (1992) (51)
- Oxidative cationic cyclization reactions effected by pyridinium chlorochromate (1978) (51)
- Preferential formation of 8-epi-prostaglandin f2α via the corresponding endoperoxide by a biomimetic cyclization (1985) (50)
- A short, stereocontrolled, and practical synthesis of alpha-methylomuralide, a potent inhibitor of proteasome function. (2003) (50)
- New mechanistic and stereochemical insights on the biosynthesis of sterols from 2,3-oxidosqualene (1991) (50)
- Studies on the total synthesis of lactacystin. An improved aldol coupling reaction and a β-lactone intermediate in thiol ester formation (1993) (50)
- A simple synthesis of 8-methylprostaglandin C2. (1973) (50)
- An unconventional approach to the enantioselective synthesis of caryophylloids. (2008) (50)
- Irreversible inhibition of prostaglandin and leukotriene biosynthesis from arachidonic acid by 11,12-dehydro- and 5,6-dehydroarachidonic acids, respectively (1982) (50)
- Introduction of two carbon appendages at a carbonyl carbon. Application to double chain branching and spiro annulation operations (1970) (50)
- A short and efficient enantioselective route to a key intermediate for the total synthesis of forskolin (1989) (50)
- On the origin of enantioselectivity in the Katsuki-Sharpless epoxidation procedure (1990) (50)
- Convenient synthesis of a highly efficient and recyclable chiral director for asymmetric induction (1978) (50)
- Selective formation of six-membered oxa- and carbocycles by the In(III)-activated ring closure of acetylenic substrates. (2011) (49)
- Total synthesis of dl-cedrene and dl-cedrol (1969) (49)
- Carbolactonization of olefins under mild conditions by cyanoacetic and malonic acids promoted by manganese (III) acetate (1985) (49)
- Algorithm for machine perception of synthetically significant rings in complex cyclic organic structures (1972) (49)
- Enantioselective synthesis of saframycin A and evaluation of antitumor activity relative to ecteinascidin/saframycin hybrids. (1999) (48)
- Total synthesis of the complement inhibitor K-76 in racemic form. Structural assignment to "K-76 monocarboxylic acid" (1982) (48)
- Stereoselective methods for the synthesis of terminal and enyne units (1973) (48)
- A two-step total synthesis of the natural pentacycle trichodimerol, a novel inhibitor of TNF-alpha production. (1999) (48)
- Catalytic Enantioselective Diels−Alder Reactions of 1,4-Quinone Monoketals (2001) (47)
- Total synthesis and absolute configuration of 7,20-diisocyanoadociane (1987) (47)
- Highly enantioselective [4 + 2] cycloaddition reactions catalyzed by a chiral N-methyl-oxazaborolidinium cation. (2008) (47)
- Receptor-mediated action of hepoxilin A3 releases diacylglycerol and arachidonic acid from human neutrophils. (1990) (47)
- Ni(II)-catalyzed enantioselective conjugate addition of acetylenes to alpha,beta-enones. (2010) (47)
- An Enantioselective Synthetic Route to Atractyligenin Using the Oxazaborolidine-Catalyzed Reduction of β-Silyl- or β-Stannyl-Substituted α,β-Enones as a Key Step (1997) (47)
- Classics in total synthesis : targets, strategies, methods (1996) (47)
- On the failure of de novo-designed peptides as biocatalysts. (1996) (47)
- Endogenous release of hepoxilin A3 from isolated perifused pancreatic islets of Langerhans. (1985) (47)
- Total synthesis of bongkrekic acid (1984) (47)
- Enantioselective synthesis of the C(18) - C(35) segment of immunosuppressant FK-506 using efficient new methodology (1989) (47)
- A short and convergent enantioselective synthesis of (3S)-2,3-oxidosqualene (1993) (46)
- Molecular geometry of the norbornyl cation. I. Synthesis and acetolysis of the exo- and endo-4,5-exo-trimethylene-2-norbornyl p-toluenesulfonates (1967) (46)
- X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes (1994) (46)
- Useful enantioselective bicyclization reactions using an N-protonated chiral oxazaborolidine as catalyst. (2003) (46)
- Total synthesis of (.+-.)-clavulones (1984) (46)
- Stereocontrolled route to a key intermediate for the synthesis of maytansine (1975) (46)
- A mechanistically designed bis-cinchona alkaloid ligand allows position- and enantioselective dihydroxylation of farnesol and other oligoprenyl derivatives at the terminal isopropylidene unit (1995) (46)
- Chemistry of Diimide. III. Hydrogen Transfer to Multiple Bonds by Dissociation of the Diimide-Anthracene Adduct, Anthracene-9,10-Biimine (1962) (45)
- A method for the stereospecific synthesis of chiral cis-2-alkylcyclopropyllithium reagents (1984) (45)
- Drug discovery : practices, processes, and perspectives (2013) (45)
- Selective 4-arylation of pyridines by a nonmetalloorganic process. (2005) (45)
- GENERATION OF CATIONIC CARBON BY ANODIC OXIDATION OF CARBOXYLIC ACIDS (1960) (45)
- THE STEREOCHEMISTRY OF 11α-HYDROXYLATION OF STEROIDS (1958) (45)
- X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4 (1996) (45)
- t-Butoxymethyllithium: Direct preparation from t-butyl methyl ether and applications as a hydroxymethyl anion equivalent (1983) (45)
- A new cationic, chiral catalyst for highly enantioselective Diels-Alder reactions. (2003) (45)
- Nitrodestannylation. A new synthesis of conjugated nitro cyclo olefins (1980) (45)
- A glutathione conjugate of hepoxilin A3: formation and action in the rat central nervous system. (1990) (44)
- Computer-assisted synthetic analysis for complex molecules. Methods and procedures for machine generation of synthetic intermediates (1972) (44)
- On the Norbornyl Cation Problem (1963) (44)
- Stereospecific Syntheses of the 7-Deuterio- and 7-Tritiocholesterols. The Mechanism of Enzyme-catalyzed Hydroxylation at a Saturated Carbon Atom (1959) (44)
- A translactonization route to macrocyclic lactones (1977) (44)
- Enzymic synthesis of beta-amyrin from 2,3-oxidosqualene. (1967) (44)
- The formyl CH--O hydrogen bond as a key to transition-state organization in enantioselective allylation, aldol and Diels-Alder reactions catalyzed by chiral lewis acids (1997) (44)
- 1,4-Addition of the methylenecarbonyl unit (-CH2CO-) to dienes (1971) (43)
- Activation of methylenetriphenylphosphorane by reaction with t-butyl- or sec-butyllithium (1985) (43)
- A NEW SYNTHETIC APPROACH TO THE PENICILLINS. (1965) (43)
- TOTAL SYNTHESIS OF APLASMOMYCIN (1982) (43)
- Stereochemistry of the hygrolidins (1984) (43)
- Synthesis of olefins from .beta.-hydroxy phosphonamides. Stereochemistry and extension to the formation of conjugated dienes (1969) (43)
- Metabolic fate of 10,11-dihydrosqualene in sterol-producing rat liver homogenate. (1966) (43)
- L(+)-2,3-Butanedithiol: Synthesis and Application to the Resolution of Racemic Carbonyl Compounds (1962) (43)
- Enhancement of plasma levels of biologically active leukotriene B compounds during anaphylaxis in guinea pigs pretreated by indomethacin or by a fish oil-enriched diet. (1986) (43)
- Synthesis of prostaglandins via a 1,2-dioxabicyclo[2.2.1]heptane (endoperoxide) intermediate. Stereochemical divergence of enzymic and biomimetic chemical cyclization reactions (1984) (42)
- Remarkably effective and simple syntheses of enantiomerically pure secondary carbinols from achiral ketones (1991) (42)
- The effect of indomethacin on the contractile response of the guinea‐pig lung parenchymal strip to leukotrienes B4, C4, D4 and E4 (1983) (42)
- Studies on the prostaglandin A 2 synthetase complex from Plexaura homomalla. (1973) (42)
- Simple, stereocontrolled synthesis of thromboxane B2 from D-glucose (1977) (42)
- New methods for carbocyclic synthesis applicable to the gibberellic acids. Steroselective introduction of the angular vinyl grouping and pinacolic cyclization of keto aldehydes (1971) (42)
- A simplified synthesis of (±)-1,2-diphenyl-1,2-diaminoethane (1) from benzaldehyde and ammonia. Revision of the structures of the long-known intermediates “hydrobenzamide” and “amarine” (1997) (42)
- A short, scalable synthesis of the carbocyclic core of the anti-angiogenic cortistatins from (+)-estrone by B-ring expansion. (2008) (42)
- TOTAL SYNTHESIS OF (+-)-VERMICULINE (1975) (42)
- Enantiospecific synthesis of the proposed structure of the antitubercular marine diterpenoid pseudopteroxazole: revision of stereochemistry. (2001) (42)
- A new method for the synthesis of organic nitro compounds (1984) (42)
- A New Cr(VI) Reagent for the Catalytic Oxidation of Secondary Alcohols to Ketones. (1986) (42)
- Mechanism of the enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complexes. (2010) (42)
- Mn(III)-PROMOTED ANNULATION OF ENOL ETHERS AND ESTERS TO FUSED OR SPIRO 2-CYCLOPENTENONES. (1987) (41)
- Stereochemistry of the SN2' displacement of chiral 1,3-disubstituted bromoallenes to form chiral acetylenes (1984) (41)
- A mechanistic model for the selective oxidation of 1,4-diols to γ-lactols by o-iodoxybenzoic acid (1995) (41)
- A practical new chiral controller for asymmetric Diels-Alder and alkylation reactions. (1999) (41)
- The Synthesis of Olefins from Carbonyl Compounds and Phosphonic Acid Bisamides (1966) (41)
- A NEW CLASS OF IRREVERSIBLE INHIBITORS OF LEUKOTRIENE BIOSYNTHESIS (1985) (41)
- Total Synthesis of 6-Trans, 10-cis and (plus or minus) -6-Trans,8-cis Isomers of Leukotriene B (1980) (41)
- A new process for the generation of 1,3,2-oxazaborolidines, catalysts for enantioselective synthesis (1992) (41)
- Total synthesis of natural (levo) and enantiomeric (dextro) forms of prostaglandin El. (1969) (41)
- Simple enantioselective approach to synthetic limonoids. (2008) (40)
- Total synthesis of gibberellic acid. A simple synthesis of a key intermediate (1982) (40)
- Oculoparalytic Illusion : Visual-Field Dependent Spatial Mislocalizations by Humans Partially Paralyzed with Curare (2006) (40)
- Computer-assisted synthetic analysis. A rapid computer method for the semiquantitative assignment of conformation of six-membered ring systems. 2. Assessment of conformational energies (1980) (40)
- Highly stereoselective conversion of prostaglandin A2 to the 10, 11.alpha.-oxido derivative using a remotely placed exogenous directing group (1973) (40)
- Total synthesis of prostaglandins E2 and F2α () via a tricarbocyclic intermediate (1970) (40)
- A route for the enantioselective total synthesis of antheridic acid, the antheridium-inducing factor from anemia phyllitidis (1991) (40)
- Additions and Corrections - Stereospecific Total Synthesis of a "Slow Reacting Substance" of Anaphylaxis Leukotriene C-1 (1980) (40)
- An effective system for epoxide-initiated cation-olefin cyclization (1991) (40)
- Synthesis of 6,9α-oxido-11α, 15α-dihydroxyprosta-(E)5, (E)13-dienoic acid, an isomer of PGI2 (vane's PGX) (1977) (40)
- The course of allylic coupling reactions involving allylnickel complexes (1968) (40)
- Identification of a new eicosanoid from in vitro biosynthetic experiments with clavularia viridis. Implications for the biosynthesis of clavulones. (1985) (39)
- The Stereochemistry of α-Haloketones. VII. The Stereochemistry and Spectra of Some α-Chlotocyclohexanones (1955) (39)
- A new route to Z-disubstituted olefins. A simple synthesis of polyunsaturated fatty acids by reiterative coupling (1984) (39)
- Highly enantioselective Diels-Alder reactions of maleimides catalyzed by activated chiral oxazaborolidines. (2010) (39)
- Demonstration of a Common Concerted Mechanistic Pathway for the Acid-Catalyzed Cyclization of 5,6-Unsaturated Oxiranes in Chemical and Enzymatic Systems (1998) (39)
- Total synthesis of slow reacting substances (SRS's): 6-epi-leukotriene C and 6-epi-leukotriene D (1980) (39)
- Biological Activity of Synthetic Prostaglandins (1969) (39)
- Hepoxilins, potential endogenous mediators of insulin release. (1986) (39)
- Highly effective transition structure designed catalyst for the enantio- and position-selective dihydroxylation of polyisoprenoids. (2001) (39)
- Enantioselective total synthesis of isoedunol and beta-araneosene featuring unconventional strategy and methodology. (2005) (39)
- Enantioselective syntheses of georgyone, arborone, and structural relatives. Relevance to the molecular-level understanding of olfaction. (2006) (39)
- Kinetic Resolution by Enantioselective Dihydroxylation of Secondary Allylic 4-Methoxybenzoate Esters Using a Mechanistically Designed Cinchona Alkaloid Catalyst (1995) (39)
- A simple, efficient, and enantiocontrolled synthesis of a near-structural mimic of platensimycin. (2008) (38)
- Techniques for perception by a computer of synthetically significant structural features in complex molecules (1972) (38)
- The origin of enantioselectivity in the dihydroxylation of olefins by osmium tetroxide and cinchona alkaloid derivatives (1990) (38)
- Systemic hemodynamic effects of leukotrienes C4 and D4 in the rat. (1983) (38)
- A catalytic enantioselective synthesis of chiral monosubstituted oxiranes (1993) (38)
- Enantio- and diastereoselective michael reactions of silyl enol ethers and chalcones by catalysis using a chiral quaternary ammonium salt. (2001) (38)
- Formation of olefins via pyrolysis of sulfonate esters (1989) (38)
- Syntheses and stereochemical revision of pseudopterosin G-J aglycon and helioporin E. (2000) (38)
- Detection and structural analysis of furans by proton magnetic resonance (1958) (38)
- Theory-guided discovery of unique chemical transformations of cyclopropenes. (2006) (38)
- Simple synthetic route to the limonoid system (1987) (38)
- The formyl CH--O hydrogen bond as a critical factor in enantioselective reactions of aldehydes, part 4. Aldol, ethylation, hydrocyanation and Diels-Alder reactions catalyzed by chiral B, Ti and Al lewis acids (1997) (38)
- Total synthesis of the racemate of the sesquiterpenoid marine allomone 9-isocyanopupukeanane (1979) (38)
- Total synthesis of (.+-.)-stemodin and (.+-.)-stemodinone (1980) (38)
- Cationic Chiral Fluorinated Oxazaborolidines. More Potent, Second-Generation Catalysts for Highly Enantioselective Cycloaddition Reactions. (2016) (38)
- Strong conformational preferences of heteroaromatic ethers and electron pair repulsion. (2010) (38)
- The Synthesis of Dihydroconessine1 (1959) (38)
- Enantioselective synthesis of bridged- or fused-ring bicyclic ketones by a catalytic asymmetric Michael addition pathway. (2006) (38)
- Facile conversion of N,N-dimethylhydrazones to carbonyl compounds by cupric ion-catalyzed hydrolysis (1976) (37)
- First Example of a Highly Enantioselective Catalytic Diels-Alder Reaction of an Achiral C2v-Symmetric Dienophile and an Achiral Diene (1994) (37)
- Position-specific alkylation of lithio-1-trimethylsilylpropyne, a useful new route to acetylenes and 1, 5-dienes (1968) (37)
- Extension of carbon chains by .gamma.-alkylation of metalated .alpha.,.beta.-ynamines (1970) (37)
- Synthesis of a limonoid, azadiradione (1989) (37)
- 11-Trans leukotriene C: a naturally occurring slow reacting substance. (1980) (37)
- Enantioselective Total Synthesis of Nicandrenones (2000) (37)
- The first method for protection-deprotection of the indole 2,3-pi bond. (2003) (37)
- SRS-A, leukotrienes, and immediate hypersensitivity reactions of the heart. (1982) (37)
- Dual binding modes to the receptor for platelet activating factor (PAF) of anti-paf trans-2,5-diarylfurans (1988) (37)
- Inhibition of leukotriene B4-induced neutrophil degranulation by leukotriene B4-dimethylamide. (1982) (37)
- A simple and enantioselective synthesis of (+)-biotin (1988) (37)
- Total synthesis of gibberellic acid. A new and effective route to a key tricyclic intermediate (1979) (37)
- New process for enantioselective nucleophilic addition to aldehydes to form secondary alcohols (1990) (37)
- Comparative bronchoconstrictor effects of histamine, leukotriene C, and leukotriene D in normal human volunteers. (1982) (37)
- Total synthesis of enterobactin, a macrocyclic iron transporting agent of bacteria (1978) (37)
- A stereoselective and practical synthesis of 5,6(S,S)-epoxy-15(S)-hydroxy-7(E),9(E),11(Z),13(E)-eicosatetraenoic acid (4), possible precursor of the lipoxins (1986) (36)
- Enantioselective beta-lactone formation from ketene and aldehydes catalyzed by a chiral oxazaborolidine. (2006) (36)
- Methods for stereospecific synthesis of cis or trans hydrindanones (1984) (36)
- Biomimetic synthesis of a preclavulone a model (1987) (36)
- The Synthesis of Pentacyclosqualene (8,8'-Cycloönocerene) and the α- and β-Onoceradienes1 (1959) (36)
- Total synthesis of (+-)-porantherine (1974) (36)
- Identification and Characterization of Leukotriene C4 Receptors in Isolated Rat Renal Glomeruli (1985) (36)
- An analysis of the relationship between 5-lipoxygenase product generation and the secretion of preformed mediators from mouse bone marrow-derived mast cells. (1984) (36)
- A new synthetic approach to prostanoids via cyclopentene vinylation. (1972) (36)
- Synthesis of a new series of potent inhibitors of thromboxane A2 biosynthesis (1983) (36)
- Application of unreactive analogs of terpenoid pyrophosphates to studies of multistep biosynthesis. Demonstration that "presqualene pyrophosphate" is an essential intermediate on the path to squalene (1976) (36)
- TOTAL SYNTHESIS OF d,l-LONGIFOLENE (1961) (36)
- Irreversible inhibition of the enzymic oxidation of arachidonic acid to 15-hydroperoxy-5,8,11-Z,13-E-eicosatetraenoic acid (15-HPETE) by 14,15-dehydroarachidonic acid (1982) (35)
- Protection of primary hydroxyl groups as methylthiomethyl ethers (1975) (35)
- Benzothiazoles as carbonyl equivalents (1978) (35)
- Hepoxilin A3 increases vascular permeability in the rat skin. (1991) (35)
- The Stereochemistry of α-Haloketones. II.1 The Three α-Dibrominated Cyclohexanones (1953) (35)
- Computer-assisted synthetic analysis. Methods for machine generation of synthetic intermediates involving multistep look-ahead (1974) (35)
- Selective inhibition of prostaglandin synthetase by a bicyclo[2.2.1]heptene derivative. (1971) (35)
- A biogenetic approach to the synthesis of a prostanoid precursor. (1973) (35)
- The Synthesis of a-Santalene and of trans-?11,12-Iso-a-santalene (1957) (35)
- Stereospecific total synthesis of 11(R)-HETE (2), lipoxygenation product of arachidonic acid via the prostaglandin pathway (1981) (35)
- STUDIES ON THE TOTAL SYNTHESIS OF PROSTAGLANDINS (1971) (35)
- Oxidation of primary and secondary alcohols to carbonyl compounds using dimethyl sulfoxide--chlorine complex as reagent (1973) (35)
- Oxidative Rearrangements of Pentacyclic Triterpenes. A Method for the Synthesis of Certain Naturally Occurring Triterpenes from α- and β-Amyrin1 (1965) (35)
- Conversion of a C20 2,3-oxidosqualene analog to tricyclic structures with a five-membered C-ring by lanosterol synthase. Further evidence for a C-ring expansion step in sterol biosynthesis (1996) (35)
- Catalytic enantioselective synthesis of a key intermediate for the synthesis of prostanoids (1991) (35)
- A synthetic method for formyl->ethynyl conversion (1972) (35)
- The total synthesis of helminthosporal. (1965) (35)
- A simple convergent approach to the synthesis of the antiviral agent virantmycin. (1999) (35)
- Purification of the 2,3-oxidosqualene-lanosterol cyclase from Saccharomyces cerevisiae (1991) (35)
- Synthesis of large-ring 1,5-dienes by cyclization of allylic dibromides with nickel carbonyl (1967) (35)
- Synthesis and x-ray structure of a novel chiral trinuclear titanium-tetraol complex (1994) (35)
- Enantioselective total synthesis of ginkgolide derivatives lacking the tert-butyl group, an essential structural subunit for antagonism of platelet activating factor (1991) (34)
- Simple, stereocontrolled total synthesis fof a biologically active analog of the prostaglandin endoperoxides (PGH2, PGG2) (1976) (34)
- A new synthetic route to (+/-)-perhydrohistrionicotoxin. (1977) (34)
- Enantioselective rhodium(I)-triethylamine catalyzed addition of potassium isopropenyl trifluoroborate to enones (2008) (34)
- Enantioselective Diels-Alder reactions between cyclopentadiene and α,β-acetylenic aldehydes catalyzed by a chiral super Lewis acid (1997) (34)
- A Short Enantioselective Total Synthesis of the Third-Generation Oral Contraceptive Desogestrel (1999) (34)
- A short total synthesis of (+)-omaezakianol via an epoxide-initiated cationic cascade reaction. (2010) (34)
- New stereospecific synthetic routes to trisubstituted olefins (1970) (34)
- Generation of 1.DELTA.g oxygen from triethylsilane and ozone. (1986) (34)
- Hepoxilin A3 (HxA3) is formed by the rat aorta and is metabolized into HxA3-C, a glutathione conjugate. (1991) (34)
- Computer-assisted synthetic analysis. Synthetic strategies based on appendages and the use of reconnective transforms (1976) (34)
- Tetrafluorosilane is a mild and very selective reagent for the cleavage of silyl-protected alcohols (1992) (34)
- Useful catalytic enantioselective cationic double annulation reactions initiated at an internal π-bond: method and applications. (2014) (34)
- Short syntheses of (+/-)-delta-araneosene and humulene utilizing a combination of four-component assembly and palladium-mediated cyclization. (2002) (34)
- Synthetic entry into the prostaglandin C series. (1973) (34)
- A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins (1994) (33)
- Bis(dimethylaluminum) 1,3-propanedithiolate–a useful reagent in the conversion of esters to unsaturated aldehydes and ketones (1975) (33)
- The stereochemistry and biosynthesis of hybridalactone, an eicosanoid from (1984) (33)
- An enantioselective synthesis of (6R)-lactacystin (1993) (33)
- Enzymic lipoxygenation of arachidonic acid: mechanism, inhibition, and role in eicosanoid biosynthesis (1987) (33)
- The structural requirements for inhibition of proteasome function by the lactacystin-derived ?-lactone and synthetic analogs (1999) (33)
- A simplified synthesis of (+)-brefeldin A (1990) (33)
- 1-diphenylphosphonio-1-methoxymethyllithium, a useful reagent for the synthesis of aldehydes from hindered ketones (1981) (33)
- A new enantiospecific route to the pseudopterosins (1990) (33)
- [4 + 2] Cycloaddition reactions catalyzed by a chiral oxazaborolidinium cation. Reaction rates and diastereo-, regio-, and enantioselectivity depend on whether both bonds are formed simultaneously. (2010) (32)
- Specificity of the glutathione S-transferases in the conversion of leukotriene A4 to leukotriene C4. (1987) (32)
- SYNTHESIS OF THE SLOW REACTING SUBSTANCE OF ANAPHYLAXIS LEUKOTRIENE C-1 FROM ARACHIDONIC ACID (1980) (32)
- DISTINCTION BETWEEN CYCLOHEPTATRIENE AND BICYCLOHEPTADIENE STRUCTURES BY NUCLEAR MAGNETIC RESONANCE (1955) (32)
- The Methyl Group at C(10) of 2,3-Oxidosqualene is Crucial to the Correct Folding of This Substrate in the Cyclization-Rearrangement Step of Sterol Biosynthesis (1992) (32)
- The structure of the 2-methylacrolein boron trifluoride complex in the crystalline phase and in solution (1992) (32)
- A review of recent contributions on biologically active products of arachidonate conversion. (1982) (32)
- Generality of marine prostanoid biosynthesis by the 2-oxidopentadienylcation pathway (1987) (32)
- Diiodoindium(III) cation, InI₂⁺, a potent yneophile. Generation and application to cationic cyclization by selective π-activation of C≡C. (2014) (32)
- Facile air oxidation of the conjugate base of rofecoxib (VioXX), a possible contributor to chronic human toxicity (2005) (32)
- A method for the catalytic enantioselective synthesis of 6-silylated 2-cyclohexenones (2006) (31)
- A simple synthetic process for the elaboration of oligoprenols by stereospecific coupling of di-, tri-, or oligoisoprenoid units (1992) (31)
- The Deamination ofcis- andtrans-3-Bicyclo [3.1.0]hexylamines in Aqueous Solution (1963) (31)
- Synthesis of a stable analog of thromboxane A2 with methylene replacing the 9,11-bridging oxygen (1980) (31)
- Oxidative Cleavage of Amides. A Method for Selective Chemical Degradation of Peptides1,2 (1959) (31)
- A method for the oxidation of , -1,2-diols to α-hydroxy ketones without carbon-carbon cleavage (1974) (31)
- Short, stereocontrolled syntheses of irreversible eicosanoid biosynthesis inhibitors. 5,6- , 8,9- , and 11,12-dehydroarachidonic acid (1982) (31)
- A simple stereocontrolled synthesis of salinosporamide A. (2004) (31)
- Amide and l-amino derivatives of F prostaglandins as prostaglandin antagonists (1978) (31)
- Total synthesis of the major human urinary metabolite of prostaglandin D2, a key diagnostic indicator (1983) (31)
- Enantioselective total synthesis of eunicenone A. (2001) (31)
- Identification and quantitation of arachidonic-acid metabolic products in rabbit, rat and human saliva. (1983) (31)
- 2,4-Dinitrobenzenesulfonylhydrazine, a useful reagent for the Eschenmoser .alpha.,.beta. cleavage of .alpha.,.beta.-epoxy ketones. Conformational control of halolactonization (1975) (31)
- 3-Nitrocycloalkenones, synthesis and use as reverse affinity cycloalkynone equivalents (1981) (31)
- Total Synthesis of α-Caryophyllene Alcohol (1964) (31)
- Stereocontrolled synthesis of dafachronic acid A, the ligand for the DAF-12 nuclear receptor of Caenorhabditis elegans. (2007) (31)
- Name reactions for carbocyclic ring formations (2010) (31)
- Formation of Carene [Bicyclo(4.1.0)heptene] Derivatives from Eucarvone1,2 (1956) (31)
- Some New Reactions of Methylsulfinyl and Methylsulfonyl Carbanion1 (1963) (31)
- Lithium N-trityl-N-(R)-1-phenethylamide, a readily available and useful base for the enantioselective formation of chiral enolates from achiral ketones (2000) (30)
- Constitution of Antheridium-Inducing Factor of Anemia Phyllitidis (1986) (30)
- Preparation of trans-1,2-bis(tributylstannyl)ethylene (1975) (30)
- Synthesis of di-t-alkylamines (1984) (30)
- Chirally directed synthesis of (-)-methyl 5(S), 6(S)-oxido-7-hydroxyheptanoate, a key intermediate for the total synthesis of leukotrienes A, C, D and E (1981) (30)
- A simple route to Δ2-butenolides from conjugated aldehydes (1980) (30)
- Highly enantioselective cyanosilylation of aldehydes catalyzed by a chiral oxazaborolidinium ion. (2004) (30)
- Preparation of an optically active intermediate for the synthesis of prostaglandins. (1974) (30)
- A New Strategy for Stereocontrol of Cation−Olefin Cyclization. The First Chemical Emulation of the A/B-trans-9,10-syn-Folding Pathway of Steroid Biosynthesis from 2,3-Oxidosqualene (1996) (30)
- Organoiron-mediated oxygenation of allylic organotin compounds. A possible chemical model for enzymatic lipoxygenation (1987) (29)
- Highly Enantioselective Dimerization of α,β-Enones Catalyzed by a Rigid Quaternary Ammonium Salt (2004) (29)
- Generation of phosphite ylides from trithiocarbonates and trimethyl phosphite and their application to the extension of carbon chains (1967) (29)
- Conversion of arachidonic acid to the prostaglandin endoperoxide PGG2, a chemical analog of the biosynthetic pathway (1994) (29)
- New, practical and effective sources of fluoride ion for desilylation to form carbon anions (1999) (29)
- Total synthesis of biologically active metabolites of arachidonic acid. The two 8-hydroxy-11,12(S,S)-epoxyeicosa-5,14(Z),9(E)-trienoic acids. (1984) (29)
- 3-hydroxy-2-pyrone as a vinylketene equivalent for the synthesis of dihydrophenols and cyclohexenones (1975) (29)
- Total synthesis of antheliolide A. (2006) (28)
- Total Synthesis of Glycinoeclepin A. (1990) (28)
- A study of cross coupling reactions between halides and anionic manganese, iron, and cobalt alkyls (1970) (28)
- First demonstration of a carbocation-olefin cyclization route to the lanosterol series (1994) (28)
- Two-Step Synthesis of Furans by Mn(III)-Promoted Annulation of Enol Ethers. (1987) (28)
- Spectral and Stereochemical Studies with Deuterated Cyclohexanes1 (1956) (28)
- A new and simple synthesis of alkoxy- and aryloxymethyllithium reagents (roch2li) (1983) (28)
- gamma. Condensation of an allylic phosphonium ylide (1974) (28)
- First stekeospecific synthesis of -γ-bisabolene. A method for the concurrent generation of a ring and a tetrasubstituted exocyclic double bond. (1986) (28)
- The Existence of a 1,2-Addition, 1,2-Elimination Mechanism for Decarboxylation1 (1953) (28)
- Experimental test of the [3+2]- and [2+2]-cycloaddition pathways for the bis-cinchona alkaloid-OsO4 catalyzed dihydroxylation of olefins by means of 12C13C kinetic isotope effects (1996) (28)
- Studies on leukotriene B4 omega-oxidation in human leukocytes. (1984) (28)
- Simple synthesis of the 11,12-oxido and 14,15-oxido analogs of leukotriene A and the corresponding conjugates with glutathione and cysteinylglycine, analogs of leukotrienes C and D (1980) (28)
- TOTAL SYNTHESIS OF ERYTHROMYCINS. 5. TOTAL SYNTHESIS OF ERYTHRONOLIDE A (1980) (28)
- New method for the synthesis of macrolides (1972) (28)
- Methods for the synthesis of chiral hindered amines (1985) (28)
- Enantioselective pathway for the synthesis of laurenditerpenol. (2010) (28)
- The Stereochemistry of the α-Amyrins (1956) (28)
- Radioimmunoassay for leukotriene B4. (1982) (28)
- Methods for the interconversion of protective groups. Transformation of mem ethers into isopropylthiomethyl ethers or cyanomethyl ethers (1984) (28)
- A simple synthesis of (±)-cedrene and (±)-cedrol using a synchronous double annulation process (1973) (27)
- Studies on the conformational mobility of arachidonic acid. Facile macrolactonization of 20-hydroxyarachidonic acid. (1983) (27)
- Structural requirement for the action of leukotriene B4 on the guinea-pig lung:importance of double bond geometry in the 6, 8, 10-triene unit. (1981) (27)
- Useful method for the conversion of alcohols to iodides (1967) (27)
- Studies on the total synthesis of rifamycin. Highly stereoselective synthesis of intermediates for construction of the C(15) to C(29) chain (1979) (27)
- Simple analogs of ginkgolide b which are highly active antagonists of platelet activating factor (1989) (27)
- Preparation, unusual spectral properties, and structural characterization of (terpyridine)(tetrahydroborato-H,H')cobalt (1982) (27)
- Conformational energetics of cationic backbone rearrangements in triterpenoid biosynthesis provide an insight into enzymatic control of product. (2008) (27)
- A method for the off-ring functionalization of carbon-substituted furans. Synthesis of kahweol from cafestol (1987) (27)
- Stereochemistry and mechanism of the biosynthesis of leukotriene A4 from 5(S)-hydroperoxy-6(E),8,11,14(Z)-eicosatetraenoic acid. Evidence for an organoiron intermediate (1989) (27)
- A simple route to a key intermediate for the synthesis of 11-desoxyprostaglandins (1971) (27)
- Mechanistic studies on the double activation method for the synthesis of macrocyclic lactones (1976) (27)
- One-step synthesis of γ-δ-unsaturated nitriles from allylic halides using cyanomethylcopper (1972) (27)
- A transition-state model for the mikami enantioselective ene reaction (1997) (27)
- Total synthesis of 5, 12-dihydroxy-6,10-,8,14--eicosatetraenoic acid (5,12-di-HETE) (), a new human metabolite of arachidonic acid (1981) (26)
- Name Reactions in Heterocyclic Chemistry: Li/Name Heterocyclic (2004) (26)
- Synthetic access to bent polycycles by cation-pi cyclization. (2010) (26)
- A systematic study of functionalized oxiranes as initiating groups for cationic polycyclization reactions. (2015) (26)
- Studies on the Total Synthesis of Gibberellic Acids. A Simple Route to the Tetracarbocyclic Network (1970) (26)
- STEREOCHEMISTRY OF ELECTRON DELOCALIZATION INVOLVING d-ORBITALS: α-SULFONYL CARBANIONS (1961) (26)
- Enzyme Mechanisms for Polycyclic Triterpene Formation (2000) (26)
- Formation of sterols by the action of 2,3-oxidosqualene-sterol cyclase on the factitious substrates 2,3:22,23-dioxidosqualene and 2,3-oxido-22,23-dihydrosqualene. (1967) (26)
- A synthetic method for the homologation of primary halides (1968) (26)
- Stereo-controlled synthesis of prostaglandins F-2a and E-2 (dl). (1969) (26)
- Simple total synthesis of (+-)-perhydrohistrionicotoxin (2002) (26)
- Specific binding of leukotriene C4 to ileal segments and subcellular fractions of ileal smooth muscle cells. (1984) (26)
- Exceptionally Simple Enantioselective Syntheses of Chiral Hexa- and Tetracyclic Polyprenoids of Sedimentary Origin. (1998) (26)
- The constitution of limonin (1960) (26)
- A new route to sulfonium ylides. Diphenylsulfonium isopbopylide (1967) (26)
- Simple and practical routes to enantiomerically pure 5-(trialkylsilyl)-2-cyclohexenones. (1999) (26)
- Total synthesis of 5-desoxyleukotriene D. A new and useful equivalent of the 4-formyl-, -1,3-butadienyl anion (1982) (26)
- Stereospecific total synthesis of 12-(r)- and 12- (s)-forms of 6-trans leukotriene B (1981) (26)
- Enantioselective route to α-hydroxy aldehyde and acid derivatives (1991) (26)
- Biomimetic total synthesis of colneleic acid and its function as a lipoxygenase inhibitor (1987) (26)
- Transfer of Alkyl-Substituted Methylenes from Sulfonium Alkylides to Carbonyl Groups (1964) (26)
- New products in the hepoxilin pathway: isolation of 11-glutathionyl hepoxilin A3 through reaction of hepoxilin A3 with glutathione S-transferase. (1989) (26)
- Stereospecific elaboration of the A ring of gibberellic acid by partial synthesis (1971) (26)
- Total synthesis of (±)-2-isocyanopupukeanane (1979) (26)
- A simple enantioselective synthesis of serratenediol. (2001) (25)
- An effective and mild method for the conversion of oximes to secondary nitro compounds (1980) (25)
- Simple, stereospecific syntheses of C17- and C18- Cecropia juvenile hormones (racemic) from a common intermediate (1970) (25)
- Studies on the action of 2,3-epoxysqualene-sterol cyclase on unnatural substrates produced by alkylidene transfer from sulfonium alkylides to 4,8,13,17,21-pentamethyldocosa-4,8,12,16,20-pentaenal (1968) (25)
- TOTAL SYNTHESIS OF (.+‐.)‐BREFELDIN A (1976) (25)
- A convergent enantioselective synthesis of the tetrahydroisoquinoline unit in the spiro ring of ecteinascidin 743 (1996) (25)
- THE TOTAL SYNTHESIS OF A 5-PHENYL PENICILLIN: METHYL 5-PHENYL-(2-CARBOMETHOXYETHYL)-PENICILLINATE (1950) (25)
- Catalytic enantioselective Diels-Alder reactions using titanium complexes of cis-N-sulfonyl-2-amino-1-indanols (1993) (25)
- Synthesis of olefins and ketones from carbonyl compounds and sulfinamides (1966) (25)
- A key intermediate for the synthesis of maytansine and related antitumor agents (1978) (25)
- Carboxylation reactions using the reagent lithium 4-methyl-2,6-di-tert-butylphenoxide (1973) (25)
- Indomethacin potentiates the pulmonary response to aerosol leukotriene C4 in the guinea pig. (1983) (25)
- Topical arachidonic acid: a model for screening anti-inflammatory agents. (1987) (25)
- Stereocontrolled syntheses of 24(S),25-epoxycholesterol and related oxysterols for studies on the activation of LXR receptors (1998) (24)
- A NEW METHOD FOR THE SYNTHESIS OF 2-PYRIDINETHIOL CARBOXYLIC ESTERS (1979) (24)
- An effective process for the isolation of Docosahexaenoic acid in quantity from cod liver oil (1987) (24)
- The Acetolysis of 1,5-Diphenyl-cis-3-bicyclo [3.1.0]hexylp-Toluenesulfonate (1963) (24)
- A Rhodium(II) catalytic approach to the synthesis of ethers of a minor component in a tautomeric set. (2000) (24)
- Localization of the site of the bronchoconstrictor effects of leukotriene C4 compared with that of histamine in asthmatic subjects. (1989) (24)
- Enantiospecific synthesis of a rigid, C2 symmetric, chiral guanidine by a new and direct method (1989) (24)
- A METHOD FOR THE PROTECTION OF LACTONES AND ESTERS AGAINST NUCLEOPHILIC ATTACK (2002) (24)
- The 1,3 O→C silyl rearrangement of silyl enol ether anions - synthesis of α-silyl ketones (1984) (24)
- A simple synthetic route to -sirenin (1970) (24)
- Biochemical catalysis involving coenzyme B-12: a rational stepwise mechanistic interpretation of vicinal interchange rearrangements. (1977) (24)
- Total synthesis of C22-prostanoids in the E and F series based on docosahexaenoic acid (1984) (24)
- Enantioselective synthesis of γ-hydroxysilanes, 1,3-diols and cyclopropanes by reaction of a chiral epoxide with a racemic α-silyl organolithium reagent (1994) (23)
- An efficient process for the bromolactamization of unsaturated acids (2007) (23)
- Di-tert-butylisobutylsilyl, another useful protecting group. (2011) (23)
- Concise total synthesis of (±)-palominol and (±)-dolabellatrienone via a dianion-accelerated oxy-cope rearrangement (1998) (23)
- Versatile approaches for the synthesis of fused-ring γ-lactones utilizing cyclopropane intermediates. (2013) (23)
- O,2-Dilithio derivative of allyl alcohol, a useful synthetic reagent (1975) (23)
- 11,15-Epiprostaglandin E 2 and its enantiomer. Biological activity and synthesis. (1972) (23)
- The Synthesis of cis and trans Olefins via β-Keto and β-Hydroxy Phosphonamides (1966) (23)
- Synthesis of three potential inhibitors of the biosynthesis of leukotrienes A–E (1980) (23)
- A total synthesis of (±)cerulenin (1977) (23)
- A possible transition state assembly for highly diastereoselective conjugate addition reactions of lithium dimethylcuprate with α,β-enones (1990) (23)
- Efficient enantioselective syntheses of chloramphenicol and (d)-threo- and (d)-erythro-sphingosine (2000) (23)
- A short and efficient synthesis of (-)-7-methylomuralide, a potent proteasome inhibitor. (2009) (23)
- Computer-assisted synthetic analysis. Techniques for efficient long-range retrosynthetic searches applied to the Robinson annulation process (1980) (22)
- A general stereocontrolled, convergent synthesis of oligoprenols that parallels the biosynthetic pathway. (2002) (22)
- Mechanism of the negative inotropic action of leukotrienes C4 and D4 on isolated rat heart. (1985) (22)
- New stereospecific synthetic routes to farnesol and its derivatives, including a biologically active position isomer of C17 Cecropia juvenile hormone (1970) (22)
- Simple stereospecific routes to 9-epi-prostaglandin F2α(PGF2β) and 11-epi-prostaglandin F2α (1975) (22)
- Studies of new indole alkaloid coupling methods for the synthesis of haplophytine. (2006) (22)
- A New Synthetic Approach to Medium-Size Carbocyclic Systems (1964) (22)
- 1-Mesityl-2,2,2-trifluoroethanol, an outstanding new chiral controller for catalyzed diels-alder reactions (1991) (22)
- Protection of carbonyl groups as bromomethylethylene ketals (1973) (22)
- Sulfur-bridged carbocycles. III. Photocyclization of .beta.,.beta.'-diphenyldivinyl sulfide (1969) (22)
- Direct, stereocontrolled synthesis of a prostaglandins using the bicyclo[2.2.1]heptene approach. (1973) (22)
- Nonparallelism between reaction rate and dienophile-catalyst affinity in catalytic enantioselective Diels-Alder reactions. (2005) (22)
- A simple and effective procedure for removal of tri-n-butyltin halides from reaction mixtures (1999) (21)
- Disparate pathways of prostaglandin biosynthesis in coral and mammalian systems (1975) (21)
- A mechanistically guided design leads to the synthesis of an efficient and practical new reagent for the highly enantioselective, catalytic dihydroxylation of olefins. (2003) (21)
- New annulation processes for fused and spiro rings based on the chemistry of benzothiazoles (1978) (21)
- The Decarboxylation of α,β-Unsaturated Malonic Acid Derivatives via β,γ-Unsaturated Intermediates. II. The Effect of α-Substituents upon Product Composition and Rate (1953) (21)
- Allylic 4-methoxybenzoates display excellent reagent-controlled double diastereoselection in the sharpless asymmetric dihydroxylation: Application to highly selective total syntheses of polyols (1997) (21)
- Simple synthesis and assignment of stereochemistry of lipoxin A (1985) (21)
- Chemical Emulation of the Biosynthetic Route to Glycinoeclepin from a Cycloartenol Derivative (1994) (21)
- Total synthesis of (±)-tricyclohexaprenol, a possible forerunner of sterols in the evolution of biomembranes (1987) (21)
- Interconversion of lower valence states of .pi.-allylnickel complexes. A new synthesis of .pi.-allylnickel derivatives (1968) (21)
- Relaxing effects of 15-lipoxygenase products of arachidonic acid on rat aorta. (1987) (21)
- An Efficient Catalytic Stereoselective Route to a Key Intermediate for the Synthesis of the Long-Lived PGI2 Analog ZK 96480 (CicaprostTM) (1997) (21)
- The Stereochemistry of α-Brominated α-Methyl-, α-Dimethyl- and α-Dibenzylcyclohexanones1 (1955) (21)
- Hepoxilin A3 blocks the release of norepinephrine from rat hippocampal slices. (1990) (21)
- A new method for stereospecific cis hydroxylation of olefins (1983) (20)
- HIGHLY ENANTIOSELECTIVE AND REGIOSELECTIVE CATALYTIC DIHYDROXYLATION OF HOMOALLYLIC ALCOHOL DERIVATIVES (1995) (20)
- Enantioselective Synthesis of α-Amino Nitriles from N-Benzhydryl Imines and HCN with a Chiral Bicyclic Guanidine as Catalyst. (1999) (20)
- An efficient, stereocontrolled synthesis of the 25-(R)-diastereomer of dafachronic acid A from beta-ergosterol. (2008) (20)
- Total synthesis of 12-(S)-10-hydroxy-trans-11,12-epoxyeicosa-5,9,14-(Z)-trienoic acids, metabolites of arachidonic acid in mammalian blood platelets (1984) (20)
- A stereospecific synthesis of chiral 1,3-disubstituted bromoallenes (1984) (20)
- Addition of organocopper reagents to Δ2,4-dienoic esters. A highly stereoselective route to tri- and tetrasubstituted olefins (1973) (20)
- STEREOSPECIFIC SYNTHESIS OF TETRASUBSTITUTED Z-ENOL SILYL ETHERS BY A THREE COMPONENT COUPLING PROCESS (1997) (20)
- Metal-ion Sensitive Protecting Groups in Synthesis. The Carbo-(8-quinoloxy) Substituent and its Removal by Accelerated Hydrolysis (1962) (20)
- Configuration at C-6 of 6,9α-oxido-bridged prostaglandins (1978) (20)
- Synthesis of the carbocyclic analog of enterobactin (1978) (20)
- Synthesis of 11.alpha.,9.alpha.-epoxymethanothromboxane A2: a stable, optically active TxA2 agonist (1981) (20)
- A short,three-component total synthesis of 12-hydroxyeicosa-5,8,14(Z), 10(E)-tetraenoic acid (12-HETE) via the corresponding ketone (1984) (20)
- Synthesis of three new dehydroarachidonic acid derivatives and their oxidation by soybean lipoxygenase (1987) (20)
- Effects of indomethacin on the guinea-pig pulmonary response to intravenous leukotrienes C4 and D4. (1983) (20)
- Enantioselective Chemical Synthesis: Methods, Logic, and Practice (2013) (20)
- Acid-catalyzed Cleavage of π-Substituted Tricyclenes. Synthesis of 3,8-Cyclocamphor1 (1959) (20)
- An efficient total synthesis of a new and highly active analog of lactacystin (1998) (20)
- Computer-assisted synthetic analysis. A rapid computer method for the semiquantitative assignment of conformation of six-membered ring systems. 1. Derivation of a preliminary conformational description of the six-membered ring (1980) (20)
- Useful new annulation reactions of vicinal dicarboxylic esters (1986) (20)
- A SHORT SYNTHETIC ROUTE TO PROSTAGLANDINS UTILIZING POSITION-SELECTIVE EPOXIDE OPENING BY THE VINYL GILMAN REAGENT (1974) (20)
- Cinnamyl as a protecting group. A mild method for the cleavage of cinnamyl esters. (1977) (19)
- Computer‐assisted synthetic analysis. Quantitative assessment of transform utilities (1992) (19)
- Chemical conversion of arachidonic acid to slow reacting substances (1982) (19)
- Separation of the cyclization and rearrangement processes of sterol biosynthesis. Enzymic formation of a protosterol derivative (1968) (19)
- The E/Z geometry of the enolate component determines face selection of the aldehyde component in chiral diazaborolidine-directed enantioselective aldol coupling (1993) (19)
- A Method for the Catalytic Enantioselective Synthesis of Chiral α-Azido and α-Amino Ketones from Racemic α-Bromo Ketones, and Its Generalization to the Formation of Bonds to C, O, and S. (2019) (19)
- Computer-assisted synthetic analysis. Selection of protective groups for multistep organic syntheses (1985) (19)
- On the synthesis and structure of lipoxin B (1985) (19)
- Proof of the Structure and Stereochemistry of α-Amyrin by Synthesis from a β-Amyrin Derivative, Glycyrrhetic Acid1,2 (1958) (19)
- New synthetic routes to ketones, haloölefins and acetylenes using aldehydes and phosphonium ylides (1970) (19)
- A tetradentate ligand for the enantioselective Ti(IV)-promoted oxidation of sulfides to sulfoxides: origin of enantioselectivity. (2012) (18)
- Stereochemistry of α-sulfonyl carbanions (1962) (18)
- Total synthesis of prostaglandins F1.alpha. and E1 (1972) (18)
- A structural analog of the protosterol cation is not a strong inhibitor of sterol biosynthesis (1996) (18)
- Sterically shielded secondary N-tritylamines and N-tritylamide bases, readily available and useful synthetic reagents (2000) (18)
- GAMMA CONDENSATION OF AN ALLYLIC PHOSPHONIUM YLIDE (1974) (18)
- Organic Synthesis: Concepts and Methods (2003) (18)
- Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method (1998) (18)
- Synthesis and properties of several isomers of the cardioactive steroid ouabain (2006) (18)
- The stereochemical course of protonation of α-sulfonyl carbanions (1965) (18)
- Total synthesis of 12-methylprostaglandin A2 (1975) (18)
- The Stereochemistry of α-Haloketones. IV. The Stable Orientation of Bromine in 2-Bromocholestane-3-one (1953) (18)
- Catalytic enantioselective Diels–Alder reactions of furans and 1,1,1-trifluoroethyl acrylate (2007) (18)
- α-functionalization of ketones via N, N-dimethylhydrazones (1976) (18)
- The Catalytic Enantioselective Construction of Molecules with Quaternary Carbon Stereocenters (1998) (18)
- A novel enantioselective synthetic route to omuralide analogues with the potential for species selectivity in proteasome inhibition. (2001) (18)
- Method for the Direct Enantioselective Synthesis of Chiral Primary α-Amino Ketones by Catalytic α-Amination. (2019) (17)
- Name Reactions in Heterocyclic Chemistry II: Li/Name (2011) (17)
- Potentiation of angiostatic steroids by a synthetic inhibitor of arylsulfatase. (1988) (17)
- A short catalytic enantioselective synthesis of the proinflammatory eicosanoid 12(R)-hydroxy- 5(Z),8(Z),10(E),14(Z)-eicosatetraenoic acid (12(R)-HETE). (2000) (17)
- A strategy for position-selective epoxidation of polyprenols. (2008) (17)
- Computer-Assisted Synthetic Analysis. Long-Range Search Procedures for Antithetic Simplification of Complex Targets by Application of the Halolactonization Transform (1980) (17)
- Isozyme specificity in the conversion of hepoxilin A3 (HxA3) into a glutathionyl hepoxilin (HxA3-C) by the Yb2 subunit of rat liver glutathione S-transferase. (1990) (17)
- Studies on the total synthesis of rifamycin. A method for the stereospecific synthesis of the carbonyl-conjugated 1,3-diene unit [C(15) to C(20)] (1979) (17)
- Generation and metabolism of 5-lipoxygenase pathway leukotrienes by human eosinophils : Predominant production of leukotriene C 4 ( neutrophils / oxidative metabblism / polymorphonuclear leukocytes / inflammatory mediators / arachidonic acid ) (17)
- Directed conversion of the phenoxy grouping into a variety of cyclic polyfunctional systems (1969) (17)
- A simple stereoselective synthesis of Z-γ-bisabolene (1986) (17)
- Total synthesis of leukotrienes. An effective procedure for the synthesis of conjugated dienals by four-carbon homologation (1983) (17)
- Irreversible inhibition of the leukotriene pathway by 4,5-dehydroarachidonic acid (1983) (17)
- Catalytic enatioselective synthesis of (3S)-2,3-oxidosqualene (1992) (17)
- Stereochemistry of the lipoxygenase-catalyzed allylic hydroperoxide→oxiranylcarbinol rearrangements (1983) (17)
- A new irreversible inhibitor of soybean lipoxygenase: relevance to mechanism (1986) (17)
- Mechanism of the nitrous acid-induced dealkylation of trisubstituted (terminal isopropylidene) olefins to form acetylenes (1987) (17)
- - and -2-methoxycyclopropyllithium: novel reagents for the stereoselective syntheses of -βγ-unsaturated aldehydes (1975) (17)
- A catalytic enantioselective total synthesis of (-)-wodeshiol. (1999) (16)
- The stereochemical course of anionic decarboxylation of α-sulfonyl carboxylic acids (1965) (16)
- Photochemical studies on ladderane formation from conjugated esters in solution or solid phase (2006) (16)
- Computer-assisted synthetic analysis. Performance of long-range strategies for stereoselective olefin synthesis (1978) (16)
- COMPUTER‐ASSISTED SYNTHETIC ANALYSIS. A RAPID COMPUTER METHOD FOR THE SEMIQUANTITATIVE ASSIGNMENT OF CONFORMATION OF SIX‐MEMBERED RING SYSTEMS. 1. DERIVATION OF A PRELIMINARY CONFORMATIONAL DESCRIPTION OF THE SIX‐MEMBERED RING (1980) (16)
- A simple and efficient synthesis of (7E, 9E, 11Z, 13E)-(5S, 6R, 15S)-trihydroxyeicosatetraenoic acid (6R-lipoxin A) (1989) (16)
- A new method for protection of carbonyl compounds as 5-methylene-1,3-dioxanes (1975) (16)
- Enantioselective synthesis of a chiral C(3)-symmetric bridgehead amine. (2010) (16)
- The mechanistic basis for diastereoselectivity in the Matteson rearrangement (1997) (16)
- Synthetic imino analogs of Cecropia juvenile hormones as potentiators of juvenile hormone activity (1971) (16)
- Highly enantioselective oxazaborolidine-catalyzed reduction of 1,3-dicarbonyl compounds: role of the additive diethylaniline. (2009) (16)
- A dramatic change in the balance between SN2 and E2 pathways with formate and oxalate as nucleophile (1972) (16)
- Enantioselective Conversion of Achiral Cyclohexadienones to Chiral Cyclohexenones by Desymmetrization. (2016) (16)
- A simple enantioselective synthesis of (1S,4R)-bicyclo[2.2.1]hept-2-ene-2-methanol (1992) (16)
- Short and simple synthesis of chelating bis-ethers and bis-amines in the bicyclo[3.3.1]nonane series (2006) (16)
- Application of benzothiazoles to carbon-carbon bond formation in organic synthesis (1978) (16)
- Effects of leukotriene E on pulmonary mechanics in the guinea pig. (1982) (16)
- Bislactonization of unsaturated diacids using lead tetraacetate (1980) (15)
- Correlation of the structure of chiral o,o′-bisphenol-Ti(IV) complexes with ligand electronic effects. A relationship between Lewis acidity and angle strain (1994) (15)
- Effect of prostaglandin I2 and analogs on platelet aggregation and smooth muscle contraction. (1978) (15)
- INTRAMOLECULAR AND INTERMOLECULAR HYDROXYL REACTIVITY DIFFERENCES IN GINKGOLIDES A, B AND C AND THEIR CHEMICAL APPLICATIONS. (1992) (15)
- Mechanism of the irreversible deactivation of arachidonate 5-lipoxygenase by 5,6-dehydroarachidonate (1984) (15)
- Synthesis of (6R,7S)-lactacystin and 6-deoxylactacystin from a common intermediate (1993) (15)
- A biomimetic chemical synthesis of humulene from farnesol (1993) (15)
- Acceleration of Enantioselective Cycloadditions Catalyzed by Second-Generation Chiral Oxazaborolidinium Triflimidates by Biscoordinating Lewis Acids. (2016) (15)
- The Condensation Products of Oxalyl Chloride with Monosubstituted Amides: Structure and Reactions (1952) (15)
- The direct synthesis of optically active -cyclooctene. Optically active -bicyclo[6.1.0]nonane (1968) (15)
- The Stereochemistry of Santonin, β-Santonin and Artemisin (1955) (15)
- Stereospecific synthesis of a biologically active dehydro derivative of the C18-juvenile hormone of cecropia. New routes to a key C12-intermediate (1971) (15)
- IMPROVED ENANTIOSELECTIVE DIHYDROXYLATION OF BISHOMOALLYLIC ALCOHOL DERIVATIVES USING A MECHANISTICALLY INSPIRED BIS-CINCHONA ALKALOID CATALYST (1996) (15)
- Useful stereoselective and position-selective transformations of brefeldin A and derivatives at carbons 4, 7 and 15 (1976) (15)
- PROOF OF THE CONSTITUTION OF FRIEDELIN BY MULTI-GROUP REARRANGEMENT OF FRIEDELAN-3β-OL TO OLEAN-13(18)-ENE (1955) (15)
- Synthesis of a β-Amyrin Derivative, Olean-11,12;13,18-diene (1963) (15)
- Enantioselective total synthesis of (−)-preclavulone-A (1988) (15)
- THE APPLICATION OF A SHAPIRO REACTION - SUZUKI COUPLING SEQUENCE TO THE STEREOSELECTIVE SYNTHESIS OF E-TRISUBSTITUTED OLEFINS (1997) (15)
- A total synthesis of (±)-occidentalol (1972) (14)
- Formation of macrocyclic structures by use of the diels-alder reaction (1975) (14)
- Controlled hydroxymethylation of ketones (1971) (14)
- THE APPLICATION OF THE SHAPIRO REACTION TO THE STEREOSELECTIVE SYNTHESIS OF E-TRISUBSTITUTED OLEFINS FOR CATION-OLEFIN CYCLIZATION BY THREE COMPONENT COUPLING (1997) (14)
- α-Dithiomethylene ketones: Generation and application to synthesis (1973) (14)
- Computer-assisted synthetic analysis. Generation of synthetic sequences involving sequential functional group interchanges (1976) (14)
- PREPARATION OF AN OPTICALLY ACTIVE PROSTAGLANDIN INTERMEDIATE VIA ASYMMETRIC INDUCTION (1976) (14)
- A new and unusually flexible scheme for annulatton to form fused cyclohexenone units (1978) (14)
- Separation of the cyclization and rearrangement processes of lanosterol biosynthesis. Enzymic conversion of 20,21-dehydro-2,3-oxidosqualene to a dehydroprotosterol. (1969) (14)
- Coupling and cyclization of dihalides using nickel carbonyl; a one-step synthesis of 1,4,7-thimethylenecyclononane from 1,1-bischloromethylethylene (1966) (14)
- (2-methoxyphenyl)dimethylsilyl lithium and cuprate reagents offer unique advantages in multistep synthesis. (2001) (14)
- The Nature of the Ring-bridging Step in the Transformation of Eucarvone to Carene Derivatives (1956) (14)
- Highly reactive equivalents of allylidenetriphenylphosphoranes for the stereospecific synthesis of 1,3-dienes by cis-olefination of hindered aldehydes (1985) (14)
- Preparation of O‐Allyl‐N‐(9‐Anthracenylmethyl)cinchonidinium Bromide as a Phase Transfer Catalyst for the Enantioselective Alkylation of Glycine Benzophenone Imine tert‐Butyl Ester: (4S)‐2‐(Benzhydrylidenamino)pentanedioic Acid, 1‐tert‐Butyl Ester‐5‐Methyl Ester (2003) (14)
- Dimethylaluminum methyltellurate, a new reagent for the cleavage of hindered methyl esters under exceptionally mild conditions by a novel mechanism (2005) (14)
- (8-R)- and (8-S)-Hepoxilin A3. Assignment of configuration and conversion to biologically active conjugates with glutathione. (1990) (13)
- Studies on the total synthesis of rifamycin. A method for the closure of the macrocyclic unit (1980) (13)
- The control of diastereoselectivity in the Michael reaction of ketonic enolates with crotonic acid derivatives (1993) (13)
- Studies on the Mechanism of Oxidation of Ketones by Selenium Dioxide (Part I) (1960) (13)
- Catalytic Enantioselective Diels—Alder Reactions: Methods, Mechanistic Fundamentals, Pathways, and Applications (2002) (13)
- The role of the symbiotic algae of Plexaura homomalla in prostaglandin biosynthesis. (1974) (13)
- Total synthesis of (+)-brefeldin A (Part IV)1 (1977) (13)
- Simple Enantioselective Syntheses of (2R,6R)-Hydroxynorketamine and Related Potential Rapid-Onset Antidepressants. (2017) (13)
- Structure, function, and metabolism of leukotriene constituents of SRS-A. (1982) (13)
- Direct biosynthesis of the 29,30-bisnoramyrin system from 29,30-bisnor-2,3-oxidosqualene in pea seedlings (1968) (13)
- Synthesis of new lipoxygenase inhibitors 13-thia- and 10-thiaarachidonic acids (1985) (13)
- A short, stereospecific route to chiral trans-2,6-disubstituted quinuclidines (1989) (13)
- Impossible dreams. (2004) (13)
- A direct total synthesis of thromboxane B2 ( (1977) (13)
- A highly efficient route to a key intermediate for the synthesis of prostaglandins (1972) (12)
- Syntheses and Reactions of Acyclic N,N-Diacylglycines (1952) (12)
- In vivo distribution and activity of aphidicolin on dividing and quiescent cells. (1985) (12)
- Concerning the reaction of sulfonium methylides with conjugated carbonyl compounds (1963) (12)
- Synthesis of two position isomers of leukotriene C having the S-peptide at C(12) (1981) (12)
- Total Synthesis of Natural Products: At the Frontiers of Organic Chemistry (2012) (12)
- Highly Enantioselective Proton‐Initiated Polycyclization of Polyenes. (2013) (12)
- Regioselective aldol condensations of a cholestanone-derived dialdehyde: new twists on a classic reaction (2006) (12)
- X-ray diffraction studies of crystalline trihalomethyl ketones (RCOCX3) reveal an unusual structural deformation about the carbonyl group (1992) (12)
- Total synthesis of picrotin (1980) (12)
- Direct synthesis of sesquicarene from -farnesol (1969) (12)
- A SIMPLE PROCESS FOR THE PURIFICATION OF ARACHIDONIC ACID (1984) (12)
- Transformation of prostaglandin A2 into prostaglandin C2 (1974) (12)
- The Ionization and Dissociation of Certain Weakly Acidic Substances in Pyridine (1953) (11)
- A novel, one-step annulation process for the synthesis of ring-fused 2-cyclopentenones (1987) (11)
- An efficient and simple method for the conversion of 15-HPETE to 14,15-EPETE (lipotriene A) and 5-HPETE to leukotriene a as the methyl esters (1984) (11)
- A new method for the 1,4-oxygenation of 1-alkylated cyclopentadienes (1985) (11)
- Effects of stimulation and inhibition of the renal prostaglandin synthetase system on renin release in vivo and in vitro. (1976) (11)
- Studies of the stereochemistry of [2+2]-photocycloaddition reactions of 2-cyclohexenones with olefins. (2007) (11)
- A METHOD FOR THE STEREOSPECIFIC SYNTHESIS OF THE A AND B RINGS OF GIBBERELLIC ACID (1974) (11)
- Novel cyclization mediated by organocopper reagents (1972) (11)
- Stereoselective synthesis of woody fragrances related to georgyone and arborone. (2008) (11)
- Total synthesis of colneleic acid (1990) (11)
- A simple stereoselective synthesis of a tetracyclic C14 ginkgolide (1990) (11)
- Selective antagonism of prostaglandin F2 alpha-mediated vascular responses by N-dimethylamino substitution of prostaglandin F2 alpha. (1982) (11)
- COMPUTER-ASSISTED SYNTHETIC ANALYSIS. THE IDENTIFICATION AND PROTECTION OF INTERFERING FUNCTIONALITY IN MACHINE-GENERATED SYNTHETIC INTERMEDIATES (1976) (11)
- Conversion of des-6-methyl-2,3-oxidosqualene to 19-norlanosterol by 2,3-oxidosqualene-sterol cyclase. (1971) (11)
- Notes: New Synthesis of α-Keto Esters (1959) (11)
- 12-methylidene-10(Z), 13(Z)-nonadecadienoic acid, a new irreversible inhibitor of soybean lipoxygenase (1986) (11)
- The Synthesis of Substituted Penicillins and Simpler Structural Analogs. VI. The Synthesis of a 6-Phenylacetylamino-β-lactam-thiazolidine (1951) (11)
- Proteasome function is required for encystation of Entamoeba invadens. (1997) (11)
- The Preparation of 1,3,4-Thiadiazoline-2,5-dione and Its Use as a Dienophilic Reagent (1973) (11)
- A short catalytic enantioselective synthesis of the vascular antiinflammatory eicosanoid (11R,12S)-oxidoarachidonic acid. (2000) (11)
- Preparation of a benzenoid intermediate For use in the synthesis of Maytansine (1977) (10)
- A simple route to α,β-unsaturated aldehydes from propargylic alcohols (1972) (10)
- Heavy atom quenching of the singlet delta dioxygen molecule (1Δg O2) (1990) (10)
- CATIONIC DISPLACEMENT OF HYDROGEN BY OXYGEN AT A SATURATED CARBON ATOM (1958) (10)
- Notes- Synthesis of 3,8-Endomethylene-3-azabicyclo[3.2.1]-octane (Cyclocamphidine) (1959) (10)
- PULMONARY PHARMACOLOGY OF THE SRS-A LEUKOTRIENES (1983) (10)
- A TOTAL SYNTHESIS OF NATURAL 20(S)‐CAMPTOTHECIN (1975) (10)
- Novel bicyclization reaction leading to a fused beta-lactone. (2006) (10)
- Chiral diazaborolidine-mediated enantioselective aldol reactions of phenylthioacetate esters (2000) (10)
- Useful Applications of Enantioselective (4 + 2)-Cycloaddition Reactions to the Synthesis of Chiral 1,2-Amino Alcohols, 1,2-Diamines, and β-Amino Acids. (2017) (10)
- Total synthesis of -elemol (1969) (10)
- A synthesis of optically active 1, 3-DI--butylallene from propargylic derivatives by hydride displacement (1969) (9)
- A New, Short, and Stereocontrolled Synthesis of C2-Symmetric 1,2-Diamines. (2017) (9)
- New synthetic routes to leukotrienes and other arachidonate derived epoxy eicosatetraenoic acids (epete's). Exclusion of the hydroxy epoxide pathway for leukotriene biosynthesis (1983) (9)
- Thioacetal-hemithioacetal-acetal interchange under mild conditions (1975) (9)
- THE STRUCTURE OF FRIEDELIN. DEGRADATIVE STUDIES (1955) (9)
- Synthetic route to neurotoxins in the 2,7-epi-histrionicotoxin series (1976) (9)
- Enantioselective Conversion of Oligoprenol Derivatives to Macrocycles in the Germacrene, Cembrene, and 18-Membered Cyclic Sesterterpene Series. (2018) (9)
- New Stereospecific Synthetic Routes to the Bicyclo[3.2.1]octane Subunit of the Kaurenoids and Gibberellins (1997) (9)
- The effects of a fish-oil-enriched diet on pulmonary mechanics during anaphylaxis. (1985) (9)
- A CONVENIENT SYNTHESIS OF O-ALKYL THIOESTERS FROM ESTERS (1984) (9)
- Preference for photodissociation over internal [2 + 2]-cycloaddition during irradiation of an unsaturated α,β-enone (1994) (8)
- A Stable and Easily Prepared Catalyst for the Enantioselective Reduction of Ketones. Applications to Multistep Syntheses. (1988) (8)
- Proton magnetic resonance spectra of leukotriene a methyl ester (I), leukotriene B methyl ester diacetate (II) and 12-epi-6-E,8-Z-leukotriene B methyl ester diacetate (III; 5-S,12-di-HETE) (1982) (8)
- Remarkably complex and unpredictable cyclization and rearrangement reactions of cations derived from unsaturated oxiranes (1997) (8)
- The Stereochemistry of the Non-radical Halogen Exchange between Active sec-Octyl Iodide and Chlorine1 (1954) (8)
- Total synthesis of a potent thromboxane A2 antagonist (1990) (8)
- The First Method for Protection—Deprotection of the Indole 2,3‐π Bond. (2003) (8)
- Biological activity of antheridic acid, an antheridiogen of anemia phyllitidis (1987) (8)
- The stereochemistry of the 1,2-elimination of .beta.-hydroxy sulfinamides to form olefins (1968) (8)
- Catalytic enantioselective synthesis of (14R)-14-hydroxy-4,14-retro-retinol from retinyl acetate (1995) (8)
- A study of the epoxidation of cycloolefins by the t-BuOH copper-permanganate system. (2009) (8)
- Prediction of the stereochemistry of α-brominated ketosteroids (1953) (8)
- A study of oligoprenyl coupling reactions with allylic stannanes. (2002) (8)
- Additions and Corrections - Modification of the Wittig Reaction to Permit the Stereospecific Synthesis of Certain Trisubstituted Olefins. Stereospecific Synthesis of α-Santalol (1970) (8)
- The synthesis of large-ring methylenecycloalkanes by the cyclization of allylic dibromides with nickel carbonyl (1975) (8)
- Stereoselective synthesis of an important prostaglandin synthetic intermediate (1991) (8)
- Polar Effects in N-Bromosuccinimide Brominations (1953) (8)
- The nature of scandol. (1957) (8)
- THE STRUCTURE OF THE TRANSITION STATE FOR ELECTROPHILIC AROMATIC SUBSTITUTION (1957) (8)
- Biology of the C-6-sulfidopeptide leukotrienes. (1983) (8)
- Science Over Politics (1999) (8)
- Convenient method for the recovery of eicosapentaenoic acid from cod liver oil (1988) (8)
- (1R,2R)‐(+)‐ and (1S,2S)‐(−)‐ 1,2‐Diphenyl‐1,2‐Ethylenediamine (2003) (8)
- Novel annulation products derived by selective attack on the C(18) angular methyl group of the cardenolide ouabain (1999) (8)
- Acylation by a Metal-ion Salt-Quinone System (1962) (8)
- Stereospecific total synthesis of -sesquicarene (1969) (8)
- Syntheses and biological evaluation of B-ring-modified analogues of dafachronic acid A. (2008) (8)
- SYNTHESIS OF A STABLE ANALOG OF THROMBOXANE A2 WITH METHYLENE REPLACING THE 9,11 BRIDGING OXYGEN (1980) (8)
- A General, Catalytic, and Enantioselective Synthesis of α-Amino Acids. (1992) (8)
- Aromatic Annulation: Two New Methods for the Synthesis of Chiral Bicyclic Phenols (1997) (8)
- The Stereochemistry of the 3-Carboxy-, 3-Carboxymethyl- and 3-Acetylcholestanes and ▵5-Cholestenes (1953) (8)
- Simple enantiospecific syntheses of the C(2)-diastereomers of omuralide and 3-methylomuralide. (2005) (7)
- Enantioselective synthesis of the (5S, 6R, 9R) and (5S, 6R, 9S) analogs of lactacystin β-lactone (1998) (7)
- A Mild, Catalytic, and Highly Selective Method for the Oxidation of α,β‐Enones to 1,4‐Enediones. (2003) (7)
- The vasodilatation induced by hydroperoxy metabolites of arachidonic acid in the rat mesenteric and pulmonary circulation (1987) (7)
- On the origin of stereo- and position selectivity in the synthesis of allylic alcohols from β-oxido ylides (1977) (7)
- Position and enantioselective dihydroxylation of 2-hydroxymethyl- and 2-hydroxyethyl-1,3-butadiene derivatives using bis-cinchona alkaloid catalysts (1996) (7)
- A Simple Enantioselective Synthesis of the Biologically Active Tetracyclic Marine Sesterterpene Scalarenedial. (1998) (7)
- Antagonism of the pulmonary vasoconstrictor response to prostaglandin F2alpha by N-dimethylamino substitution of prostaglandin F2alpha. (1978) (7)
- Highly Enantioselective Alkynylation of Aldehydes Promoted by Chiral Oxazaborolidines. (1994) (7)
- A New Steroid Coupling Product from Cholesterol (1955) (7)
- Selective chromic acid oxidation of alcohols in the erythromycin series in consequence of conformational immobility (1975) (7)
- Pathways for migration and cleavage of the S-peptide unit of the leukotrienes (1983) (7)
- Synthesis and structure elucidation of leukotrienes. (1987) (7)
- Stereodivergent synthesis of novel chiral C2-symmetric bis-trifluoromethyl-2-oxazolidinones (2018) (7)
- TOTAL SYNTHESIS OF ERYTHROMYCINS. 6. FACILE TRANSFORMATION OF ERYTHRONOLIDE A A INTO A TRICYCLIC INTERNAL KETAL (2002) (7)
- A new synthetic route to (±)-perhydrohistrionicotoxin (1975) (6)
- FORMATION OF BICYCLO(4.1.0)HEPTANE DERIVATIVES FROM EUCARVONE (1954) (6)
- Brain hepoxilins: formation and action. (1989) (6)
- Diaxial conformers of trans-1,2-dithiacyclohexane derivatives (1999) (6)
- COMPUTER-ASSISTED SYNTHETIC ANALYSIS, METHODS FOR MACHINE GENERATION OF SYNTHETIC INTERMEDIATES INVOLVING MULTISTEP LOOK-AHEAD (1974) (6)
- Simple, stereocontrolled syntheses of 24(S),25-epoxy-22(R)-hydroxycholesterol, 22(R),24(S)-dihydroxycholesterol and diastereomers, new ligands for binding and activation of LXRs (1998) (6)
- 2 – Structure Elucidation and Total Synthesis of the Leukotrienes (1984) (6)
- Novel Hepoxilin Glutathione Conjugates with Biological Activity (1990) (6)
- A new protecting group for the carbonyl function (1977) (6)
- Enantioselective synthesis of a simple benzenoid analogue of glycinoeclepin A. (2008) (6)
- New Mechanistic and Stereochemical Insights on the Biosynthesis of Sterols from 2,3‐Oxidosqualene. (1992) (6)
- Preparation of an optically active intermediate for the synthesis of prostaglandins (1974) (6)
- Method for Highly Enantioselective Ligation of Two Chiral C(sp3) Stereocenters. (2017) (5)
- DIISOPROPYLSILYL DITRIFLATE AND DI-TERT-BUTYLSILYL DITRIFLATE: NEW REAGENTS FOR THE PROTECTION OF DIOLS (1983) (5)
- A Useful Method for the Conversion of Olefins to Nitro Olefins. (2021) (5)
- Highly Enantioselective Synthesis of Cyclic and Functionalized α-Amino Acids by Means of a Chiral Phase-Transfer Catalyst. (1998) (5)
- Chemical studies on slow reacting substances/leukotrienes (1982) (5)
- TOTAL SYNTHESIS OF PENTACYCLOSQUALENE1 (1957) (5)
- A Test for Hydrogen Rearrangement in the Deamination of Cyclopropylamine to Allyl Alcohol (1964) (5)
- SYNTHESIS OF NOVEL MACROCYCLIC LACTONES IN THE PROSTAGLANDIN AND POLYETHER ANTIBIOTIC SERIES (1975) (5)
- Useful Catalytic Enantioselective Cationic Double Annulation Reactions Initiated at an Internal π‐Bond: Method and Applications. (2014) (5)
- A NEW AND GENERAL SYNTHESIS OF POLYCYCLIC Γ-LACTONES BY DOUBLE ANNULATION (1984) (5)
- Tricyclo[23,6.1.1.0]pyran-2-one (1967) (5)
- STUDIES DIRECTED TOWARD THE TOTAL SYNTHESIS OF PERHYDROHISTRIONICOTOXIN (1976) (5)
- A practical synthesis of S-quinuclidine-2-carboxylic acid and its enantiomer (2006) (5)
- CONTROLLED CHEMICAL SYNTHESIS OF THE ENZYMICALLY PRODUCED EICOSANOIDS 11-, 12-, AND 15-HETE FROM ARACHIDONIC ACID AND CONVERSION INTO THE CORRESPONDING HYDROPEROXIDES (HPETE) (1980) (5)
- Correlation of a protosterol from 20,21-dehydro-2,3-oxidosqualene and 2,3-oxidosqualene-sterol cyclase with dihydrolanosterol. (1970) (5)
- Synthesis of Chiral Cyclic Alcohols from Chiral Epoxides by H or N Substitution with Frontside Displacement. (2018) (5)
- TOTAL SYNTHESIS OF ERYTHROMYCINS. 4. TOTAL SYNTHESIS OF ERYTHRONOLIDE B (1978) (5)
- Total Synthesis of (+)-α-Onocerin in Four Steps via Four-Component Coupling and Tetracyclization Steps. (2003) (4)
- STRUCTURE ELUCIDATION AND TOTAL SYNTHESIS OF THE LEUKOTRIENES (1985) (4)
- Priestley medal address: Impossible dreams (2004) (4)
- A method for the stereospecific synthesis of trisubstituted olefins by 1,5-prototropic shift (1971) (4)
- TOTAL SYNTHESIS OF 6-TRANS,10-CIS AND (.+-.)-6-TRANS,8-CIS ISOMERS OF LEUKOTRIENE B (1981) (4)
- Short Syntheses of (.+‐.)‐δ‐Araneosene and Humulene Utilizing a Combination of Four‐Component Assembly and Palladium‐Mediated Cyclization. (2002) (4)
- A proposal for the biosynthesis of the clavulones, a new family of eicosanoids (1983) (4)
- USEFUL SYNTHETIC REAGENTS DERIVED FROM 1-(TRIISOPROPYLSILYL)PROPYNE AND 1,3-BIS(TRIISOPROPYLSILYL)PROPYNE. DIRECT, STEREOSELECTIVE SYNTHESIS OF EITHER Z OR E ENYNES (1982) (4)
- Effects of synthetic prostaglandin analogues on platelet aggregation and secretion [proceedings]. (1977) (4)
- TOTAL SYNTHESIS OF A -AMYRIN DERIVATIVE2 OLEAN-11,12;13,18-DIENE (V) (1959) (4)
- Unraveling the C2-Symmetric Azatetraquinane System. Simple, Enantioselective Syntheses. (2021) (4)
- Enantioselective Total Synthesis of Gracilins B and C Using Catalytic Asymmetric Diels-Alder Methodology. (1996) (4)
- Total Synthesis of Helminthosporal (2002) (4)
- A Short and Convergent Enantioselective Synthesis of (3S)-2,3- Oxidosqualene. (1994) (4)
- Identification of a crucial substructural unit for thromboxane A2 receptor binding (1990) (4)
- A simple synthetic route to a proposed intermediate in the biosynthesis of squalene from farnesyl pyrophosphate (1968) (4)
- Enantioselective Total Synthesis of Oleanolic Acid, Erythrodiol, β ‐Amyrin, and Other Pentacyclic Triterpenes from a Common Intermediate. (1994) (4)
- Inhibition of homogeneous human eosinophil arylsulfatase B by sulfidopeptide leukotrienes. (1986) (4)
- Conversion of Torgov′s Synthesis of Estrone into a Highly Enantioselective and Efficient Process. (2008) (4)
- A New Chiral Rh(II) Catalyst for Enantioselective [2 + 1]‐Cycloaddition. Mechanistic Implications and Applications. (2004) (4)
- TOTAL SYNTHESIS OF GINKGOLIDE A. (2022) (4)
- Total Synthesis of (.+‐.)‐Pentacycloanammoxic Acid. (2005) (4)
- Formation and Application to Organic Synthesis (2001) (4)
- Total Synthesis of Natural Product (2012) (4)
- Stereo-controlled synthesis of prostaglandins F2 alpha and E2 (Dl). [Letter] (1969) (3)
- GENERATION AND SYNTHETIC USE OF METALATED DIMETHYLHYDRAZONES. REGIO AND STEREOSELECTIVE ALKYLATION OF CARBONYL COMPOUNDS (1978) (3)
- Additions and Corrections, "A Reagent for the αβ Reduction of Conjugated Nitriles." (1975) (3)
- Nobel laureates' letter to President Bush. (2001) (3)
- TOTAL SYNTHESIS OF SLOW REACTING SUBSTANCES (SRS). “LEUKOTRIENE C-2” (11-TRANS-LEUKOTRIENE C) AND LEUKOTRIENE D (1980) (3)
- The Formyl C—H×××O Hydrogen Bond as a Critical Factor in Enantioselective Lewis-Acid Catalyzed Reactions of Aldehydes (2010) (3)
- Enantioselective Total Synthesis of Gracilins B and C Using Catalytic Asymmetric Diels-Alder Methodology. [Erratum to document cited in CA123:340457] (1995) (3)
- X-Ray Crystallographic and NMR Studies on the Origins of High Enantioselectivity in Diels-Alder Reactions Catalyzed by a Chiral Diazaaluminolidine. (1993) (3)
- A Novel Synthesis of the Fluorene Skeleton (1997) (3)
- Quantitation and characterization of leukotriene products released following immunologic stimulation of human lung cells in vitro. (1983) (3)
- Enantioselective Route to α-Hydroxy Aldehyde and Acid Derivatives. (1992) (3)
- Additions and Corrections - A New Total Synthesis of Prostaglandins of the E2 and F1 Series Including 11-Epiprostaglandins (1968) (3)
- The Synthesis of β‐Lactams (2011) (3)
- COMPUTER‐ASSISTED SYNTHETIC ANALYSIS. A RAPID COMPUTER METHOD FOR THE SEMIQUANTITATIVE ASSIGNMENT OF CONFORMATION OF SIX‐MEMBERED RING SYSTEMS. 2. ASSESSMENT OF CONFORMATIONAL ENERGIES (1980) (3)
- Enantioselective Total Synthesis of Miroestrol. (1994) (3)
- Kinetic Investigations Provide Additional Evidence That an Enzyme‐Like Binding Pocket Is Crucial for High Enantioselectivity in the Bis‐ Cinchona Alkaloid Catalyzed Asymmetric Dihydroxylation of Olefins. (1996) (3)
- Stereospecific Syntheses of 11-Deuterated Steroids (1959) (3)
- tert‐Butyl‐tert‐Octylamine (2003) (3)
- Synthesis of a new prostaglandin endoperoxide (PGH2) analog and its function as an inhibitor of the biosynthesis of thromboxane A2 (TBXA2) (1979) (3)
- A theory for the stereospecific polymerization of propylene oxide by ferric chloride (1959) (3)
- Sterically Shielded Secondary N‐Tritylamines and N‐Tritylamide Bases, Readily Available and Useful Synthetic Reagents. (2000) (3)
- Enantioselective Total Synthesis of β-Elemene and Fuscol Based on Enantiocontrolled Ireland-Claisen Rearrangement. (1995) (3)
- X‐Ray Crystallographic Studies Provide Additional Evidence That an Enzyme‐Like Binding Pocket is Crucial to the Enantioselective Dihydroxylation of Olefins by OsO4‐Bis‐cinchona Alkaloid Complexes. (1994) (3)
- A Method for the Catalytic Enantioselective Synthesis of 6-Silylated 2-Cyclohexenones. (2006) (3)
- A study of the effect of Z- and E-olefinic geometry on the rates of ring closure of 13-membered dienes. (2008) (3)
- SYNTHESIS OF VANE′S PROSTAGLANDIN X, 6,9α-OXIDO-9α,15α-DIHYDROXYPROSTA-(Z)5,(E)13-DIENOIC ACID (1977) (3)
- Highly Diastereoselective Cationic Cyclization Reactions Convert a Common Monocyclic Enone to Bicyclic Precursors for the Synthesis of Retigeranic Acids A and B. (2017) (3)
- Highly Enantioselective Phase Transfer Catalyzed Alkylation of a 3‐Oxygenated Propionic Ester Equivalent: Applications and Mechanism. (1999) (3)
- 2,6-Bis(triisopropylsilyl)pyridine, an extreme example of the effect of strong steric screening on basicity (1998) (3)
- Ni(II)‐Catalyzed Enantioselective Conjugate Addition of Acetylenes to α,β‐Enones. (2010) (3)
- Enantioselective and Practical Syntheses of (R)- and (S)-Fluoxetines. (1990) (3)
- An Exceptionally Short and Simple Enantioselective Total Synthesis of Pentacyclic Triterpenes of the β‐Amyrin Family. (2000) (3)
- Total Synthesis of (.+-.)-Paeoniflorigenin and Paeoniflorin. (1994) (3)
- In memorium Igor Torgov: Torgov's way to total steroid synthesis (2009) (3)
- Catalytic Reactions of Samarium(II) Iodide. (1997) (3)
- Enantioselective Michael addition of nitromethane to alpha, beta-enones catalyzed by chiral quaternary ammonium salts. A simple synthesis of (R)-baclofen. (2000) (3)
- A New, More Efficient, and Effective Process for the Synthesis of a Key Pentacyclic Intermediate (I) for Production of Ecteinascidin and Phthalascidin (II) Antitumor Agents. (2000) (3)
- SIMPLE, STEREOCONTROLLED TOTAL SYNTHESIS OF A BIOLOGICALLY ACTIVE ANALOG OF THE PROSTAGLANDIN ENDOPEROXIDES (PGH2, PGG2) (1976) (3)
- Formation of a glutathionyl-conjugate of hepoxilin A3 and its action in rat brain. (1991) (2)
- rel-Methyl (3R,3aR,4aS,5S,7R,8R,8aS,9aS)-5-bromododecahydro-3-isopropyl-8,9a-dimethyl-10-oxo-4a,8-(epoxymethano)-4aH-benz[f]indene-7-carboxylate (1) and rel-methyl (3R,3aS,4aS,5S,7R,8R,8aS,9aS)-5-bromododecahydro-3-isopropyl-8,9a-dimethyl-10-oxo-4a,8-(epoxymethano)-4aH-benz[f]indene-7-carboxylate (2 (1985) (2)
- A New Enantiospecific Route to the Pseudopterosins. (1991) (2)
- Catalytic Diastereoselective Synthesis of cis-1,2-Disubstituted Cyclopropanols from Esters Using a Vicinal Dicarbanion Equivalent. (1995) (2)
- A SIMPLE TOTAL SYNTHESIS OF (+-)-PERHYDROHISTRIONICOTOXIN (1975) (2)
- Short, Enantioselective Total Synthesis of Aflatoxin B2 Using an Asymmetric [3 + 2]‐Cycloaddition Step. (2006) (2)
- Total Synthesis of (±)-Antheridium-Inducing Factor (A M) of the Fern Anemia phyllitidis. (1986) (2)
- CHROMIUM TRIOXIDE-3,5-DIMETHYLPYRAZOLE COMPLEX AS A REAGENT FOR OXIDATION OF ALCOHOLS TO CARBONYL COMPOUNDS (1974) (2)
- Catalytic Enantioselective Diels-Alder Addition to Furan Provides a Direct Synthetic Route to Many Chiral Natural Products. (1993) (2)
- Total Synthesis of Biologically Active Metabolites of Arachidonic Acid. The Two 8-Hydroxy-11,12(S,S)-epoxyeicosa-5,l4(Z),9(E)-trienoic Acids. (1985) (2)
- on a Smooth Muscle Cell Line (1983) (2)
- THE ROLE OF THE SYMBIOTIC ALGAE OF PLEXAURA HOMOMALLA IN PROSTAGLANDIN BIOSYNTHESIS (1974) (2)
- Enantioselective Total Synthesis of a Protosterol, 3β,20-Dihydroxyprotost-24-ene. (1990) (2)
- APPLICATIONS OF N,N-DIMETHYLHYDRAZONES TO SYNTHESIS. USE IN EFFICIENT, POSITIONALLY AND STEREOCHEMICALLY SELECTIVE CARBON-CARBON BOND FORMATION, OXIDATIVE HYDROLYSIS TO CARBONYL COMPOUNDS (1976) (2)
- Highly Enantioselective Catalytic Diels‐Alder Addition Promoted by a Chiral Bis(oxazoline)‐Magnesium Complex. (1993) (2)
- Differential Effects of Leukotriene B4 and Its Analogues on Suppressor and Helper Cell Function (1985) (2)
- Preferential Geminal Bis-silylation of 3,4-Benzothiophane Is Caused by the Dominance of Electron Withdrawal by R3Si over Steric Shielding Effects (2014) (2)
- A Novel Chiral Super-Lewis Acidic Catalyst for Enantioselective Synthesis. (1996) (2)
- A Mechanistic Model for the Selective Oxidation of 1,4‐Diols to γ ‐Lactols by o‐Iodoxybenzoic Acid. (1996) (2)
- Synthesis and x-ray structure of a potent superpositional analog of the enantiomeric forms of fluoxetine (1993) (2)
- A NUCLEOPHILIC ETHYNYL GROUP EQUIVALENT AND ITS USE IN CONJUGATE ADDITION TO ALPHA,BETA-ENONES (1974) (2)
- An Efficient Process for the Bromolactamization of Unsaturated Acids. (2008) (2)
- Enantioselective Michael Addition of Nitromethane to α,β‐Enones Catalyzed by Chiral Quaternary Ammonium Salts. A Simple Synthesis of (R)‐Baclofen. (2001) (2)
- Remarkably Effective and Simple Syntheses of Enantiomerically Pure Secondary Carbinols from Achiral Ketones. (1992) (2)
- Syntheses and Stereochemical Revision of Pseudopterosin G—J Aglycon and Helioporin E. (2000) (2)
- Prostacyclin, a potent vasodepressor in primates. (1977) (2)
- Convenient Routes to Symmetrical Benzils and Chiral 1,2-Diaryl-1,2- diaminoethanes, Useful Controllers and Probes for Enantioselective Synthesis. (1995) (2)
- Identification of a New Eicosanoid from in vitro Biosynthetic Experiments with Clavularia viridis. (1986) (2)
- Total synthesis of prostaglandins. Synthesis of the pure dl-E1, -F1-alpha-F1-beta, -A1, and -B1 hormones. (1968) (2)
- Enantioselective Vicinal Hydroxylation of Terminal and E-1,2-Disubstituted Olefins by a Chiral Complex of Osmium Tetraoxide. An Effective Controller System and a Rational Mechanistic Model. (1990) (2)
- Reversal of the importance of steric and electronic effects in the base-promoted α-silylation of sulfides. (2015) (2)
- Highly Reactive Equivalents of Allylidenetriphenylphosphoranes for the Stereospecific Synthesis of 1,3-Dienes by cis-Olefination of Hindered Aldehydes. (1986) (2)
- AN EFFICIENT AND MILD LACTONIZATION METHOD FOR THE SYNTHESIS OF MACROLIDES (1974) (2)
- Nitrosyl Triflate and Nitrous Anhydride, Same Mode of Generation, but Very Different Reaction Pathways. Direct Synthesis of 1,2-Oxazetes, Nitroso or Bisoxazo Compounds from Olefins. (2022) (2)
- Asymmetric Synthesis of (S)‐Carbinoxamine. New Aspects of Oxazaborolidine‐Catalyzed Enantioselective Carbonyl Reduction. (1996) (2)
- Methods for the Synthesis of Chiral Hindered Amines. (1986) (2)
- TOTAL SYNTHESIS OF SLOW REACTING SUBSTANCES (SRS′S): 6-EPI-LEUKOTRIENE C AND 6-EPI-LEUKOTRIENE D (1980) (2)
- SYNTHESIS OF BREFELDIN A, CARPAINE, VERTALINE AND ERYTHRONOLIDE B FROM NONMACROCYCLIC PRECURSORS (1975) (2)
- The structure of the product C21H12O6 from o-phenylene thionocarbonate and trimethyl phosphite (1965) (2)
- Catalytic Enantioselective Diels—Alder Reactions of 1,4‐Quinone Monoketals. (2001) (2)
- Total Synthesis of 5S, 12S-Dihydroxy-6,1O-E,8,14-2-eicosatraenoic Acid (5S,12S-di-HETE) (2), a New Human Metabolite of Arachidonic Acid. (1982) (2)
- Radioimmunoassay of the 6-sulfido-peptide-leukotrienes and serologic specificity of the anti-leukotriene D4 plasma. (1982) (2)
- Planning Enantioselective Synthesis (2010) (2)
- Improved Enantioselective Dihydroxylation of Bishomoallylic Alcohol Derivatives Using a Mechanistically Inspired Bis-cinchona Alkaloid Catalyst. (1996) (2)
- STUDIES WITH TRIALKYLSILYLTRIFLUOROMETHYLSULFONATES: NEW SYNTHESES AND APPLICATIONS (1982) (2)
- Computer-Assisted Synthetic Analysis. Quantitative Assessment of Transform Utilities. (1992) (2)
- A DIRECT, STEREOCONTROLLED TOTAL SYNTHESIS OF THE 9,11-AZO ANALOG OF THE PROSTAGLANDIN ENDOPEROXIDE, PGH2 (1977) (1)
- SYNTHESIS OF 6,9α-OXIDO-11α,15α-DIHYDROXYPROSTA-(E)5,(E)13-DIENOIC ACID, AN ISOMER OF PGI2 (VANE′S PGX) (1977) (1)
- Synthesis of Estrone Methyl Ether (2009) (1)
- Other Six-Membered Heterocycles (2004) (1)
- LEUKOTRIENES AND OTHER EICOSANOIDS: SYNTHESES AND SYNTHETIC METHODS (1983) (1)
- Enantioselective Synthesis of β-Lactone Catalyzed by a Chiral Oxazaborolidine (2007) (1)
- Carbon-carbon bond formation by O → C rearrangement of allylideneoxyphosphoranes (1990) (1)
- Stereospecificity of the prostaglandin 15-dehydrogenase from swine lung (1970) (1)
- Enantioselective Total Synthesis of Ecteinascidin 743. (1997) (1)
- Mechanism and Conditions for Highly Enantioselective Epoxidation of α,β‐Enones Using Charge‐Accelerated Catalysis by a Rigid Quaternary Ammonium Salt. (2000) (1)
- Comprar Molecules and Medicine | E. J. Corey | 9780470260968 | Wiley (2007) (1)
- A Simplified Synthesis of (.+-.)-1,2-Diphenyl-1,2-diaminoethane from Benzaldehyde and Ammonia. Revision of the Structures of the Long-Known Intermediates “Hydrobenzamide” and “Amarine”. (1998) (1)
- Carboxylic Acid Derivatives Synthesis (2007) (1)
- A novel and selective photoisomerization of allylic benzoates. (2001) (1)
- Mechanism of the Reaction of Olefins with Nitrous Anhydride (O═N-O-N═O) to Form 1,2-Oxazetes. (2022) (1)
- The First Enantioselective Synthesis of the Chemotactic Factor Sirenin by an Intramolecular (2 + 1) Cyclization Using a New Chiral Catalyst. (1996) (1)
- Practical, stable standards for the reversed phase HPLC analysis of peptidic leukotrienes (1987) (1)
- Concise Total Synthesis of (.+-.)-Palominol and (.+-.)-Dolabellatrienone via a Dianion-Accelerated Oxy-Cope Rearrangement. (1998) (1)
- Enantioselective Diels-Alder Reactions Between Cyclopentadiene and . alpha.,β-Acetylenic Aldehydes Catalyzed by a Chiral Super Lewis Acid. (1997) (1)
- A Short, Stereocontrolled, and Practical Synthesis of α-Methylomuralide (I), a Potent Inhibitor of Proteasome Function. (2003) (1)
- Contrasting Diastereoselectivity between Cyclic Nitrones and Azomethine Ylides. Stereocontrolled Pathways to cis-anti-anti-cis-Oxazatetraquinanes from a Bicyclic Nitrone. (2021) (1)
- A Practical and Efficient Method for Enantioselective Allylation of Aldehydes. (1989) (1)
- Radioimmunoassays (RIA) of the slow reacting substance of anaphylaxis (SRS-A) leukotrienes (1982) (1)
- 2,6-Bis(triisopropylsilyl)pyridine, an Extreme Example of the Effect of Strong Steric Screening on Basicity. (1998) (1)
- heterogeneity of receptors for the C-6-sulfidopeptide leukotrienes (1984) (1)
- Chiral Oxazaborolidine—Aluminum Bromide Complexes Are Unusually Powerful and Effective Catalysts for Enantioselective Diels—Alder Reactions. (2007) (1)
- A New System for Catalytic Enantioselective Reduction of Achiral Ketones to Chiral Alcohols. Synthesis of Chiral α-Hydroxy Acids. (1990) (1)
- Examples of Enantioselective Synthesis (2010) (1)
- Involvement of icosanoids in endothelium-derived relaxing factor. (1987) (1)
- First Stereospecific Synthesis of E‐γ‐Bisabolene. A Method for the Concurrent Generation of a Ring and a Tetrasubstituted Exocyclic Double Bond. A Simple Stereoselective Synthesis of Z‐γ‐Bisabolene. (1986) (1)
- Inhibition of the soluble 5-lipoxygenase of the rat basophilic leukemic (RBL-1) cells by 5-lipoxygenase products and 15-hete (1984) (1)
- Enantioselective β‐Lactone Formation from Ketene and Aldehydes Catalyzed by a Chiral Oxazaborolidine. (2007) (1)
- A TOTAL SYNTHESIS OF (+-)-PORANTHERINE (1974) (1)
- A Catalytic Enantioselective Synthesis of Denopamine, a Useful Drug for Congestive Heart Failure. (1991) (1)
- A STEREOCONTROLLED AND EFFECTIVE SYNTHESIS OF LEUKOTRIENE B (1981) (1)
- A Stereoselective and Practical Synthesis of 5,6(S,S)-Epoxy-15(S)-hydroxy-7(E),9(E),11(Z),13(E)-eicosatetraenoic Acid, Possible Precursor of the Lipoxins. (1987) (1)
- 143 Leukotriene E4(LTE4)-induced airway hyperresponsiveness to histamine (1985) (1)
- A METHOD FOR THE OXIDATION OF SEC,TERT-1,2-DIOLS TO ALPHA-HYDROXY KETONES WITHOUT CARBON-CARBON CLEAVAGE (1974) (1)
- Enantioselective Conversion of Aldehydes to Cyanohydrins by a Catalytic System with Separate Chiral Binding Sites for Aldehyde and Cyanide Components. (1993) (1)
- Diiodoindium(III) Cation, InI2+, a Potent Yneophile. Generation and Application to Cationic Cyclization by Selective π-Activation of CC. (2015) (1)
- Catalytic Enantioselective Diels—Alder Reactions of Furans and 1,1,1-Trifluoroethyl Acrylate. (2007) (1)
- Cover Picture: Angew. Chem. Int. Ed. 10/2002 (2002) (1)
- Enantioselective Total Synthesis of Nicandrenones. (2001) (1)
- Catalytic Enantioselective Synthesis of (3S)‐2,3‐Oxidosqualene (I). (1992) (1)
- TOTAL SYNTHESIS OF 5‐DESOXYLEUKOTRIENE D. A NEW AND USEFUL EQUIVALENT OF THE 4‐FORMYL‐TRANS,TRANS‐1,3‐BUTADIENYL ANION (1983) (1)
- A Short Enantioselective Total Synthesis of the Third-Generation Oral Contraceptive Desogestrel. (1999) (1)
- First Application of Attractive Intramolecular Interactions to the Design of Chiral Catalysts [cf.(III)] for Highly Enantioselective Diels—Alder Reactions. (1992) (1)
- Progress in Organic Chemistry. 5. (1962) (1)
- Enantioselective, Catalytic Diels‐Alder Reaction: (1S‐endo)‐3‐(Bicyclo[2.2.1]Hept‐5‐en‐2‐ylcarbonyl)‐2‐Oxazolidinone (2003) (1)
- A REAGENT FOR THE ALPHA,BETA-REDUCTION OF CONJUGATED NITRILES (1975) (1)
- A Method for the Off-Ring Functionalization of Carbon-Substituted Furans. Synthesis of Kahweol from Cafestol. (1988) (1)
- Direct Catalytic Enantioselective Reduction of Achiral α,β- Ynones. Strong Remote Steric Effects Across the C-C Triple Bond. (1997) (1)
- Selective Formation of Six‐Membered Oxa‐ and Carbocycles by the In(III)‐Activated Ring Closure of Acetylenic Substrates. (2012) (1)
- Inhibition of Collagen Hydroxylases by PQQ Reveals Its Domain Structure (1989) (1)
- SIMPLE STEREOSPECIFIC ROUTES TO 9-EPI-PROSTAGLANDIN F(2ALPHA)(PGF(2BETA)) AND 11-EPI-PROSTAGLANDIN F(2ALPHA) (1975) (1)
- STEREOCHEMISTRY OF THE LIPOXYGENASE-CATALYZED ALLYLIC HYDROPEROXIDE TO OXIRANYLCARBINOL REARRANGEMENT (1984) (1)
- Enantioselective Synthesis Based on Catalysis by Chiral Oxazaborolidinium Cations (2010) (1)
- HIGHLY STEREOSELECTIVE CONVERSION OF PROSTAGLANDIN A2 TO THE 10,11ALPHA-OXIDE DERIVATIVE USING A REMOTELY PLACED EXOGENOUS DIRCTING GROUP (1973) (1)
- A SIMPLE SYNTHESIS OF (+‐)‐CEDRENE AND (+‐)‐CEDROL USING A SYNCHRONOUS DOUBLE ANNULATION PROCESS (1973) (1)
- Coordinatively Induced 1,4-Diastereoselection in the Reaction of Acyclic α,β-Enones with Organocopper Reagents. A New Type of Organocopper Reagent. (1989) (1)
- A mild, catalytic, and highly selective method for the oxidation of alpha,beta-enones to 1,4-enediones. (2003) (1)
- The Application of a Mechanistic Model Leads to the Extension of the Sharpless Asymmetric Dihdroxylation to Allylic 4-Methoxybenzoates and Conformationally Related Amine and Homoallylic Alcohol Derivatives. (1996) (1)
- Comprar Name Reactions for Homologation, 2 Part Set | Brent Agin, MD | 9780470467213 | Wiley (2009) (1)
- Total synthesis of erythromycins. 6. Facile transformation of erythronolide A into a tricyclic internal ketal (1980) (1)
- Enantioselective α-Silylation of Enones (2006) (1)
- Highly Enantioselective Diels—Alder Reactions of Maleimides Catalyzed by Activated Chiral Oxazaborolidines. (2010) (1)
- Cardiovascular Responses to PGL (Prostacyclin) in the Dog (1978) (1)
- A Biomimetic Chemical Synthesis of Humulene from Farnesol. (1993) (1)
- Total Synthesis and Absolute Configuration of 7,20‐Diisocyanoadociane. (1987) (0)
- Enantioselective Synthesis of β-Hydroxy-α-Amino Acid Esters by Aldol Coupling Using a Chiral Quaternary Ammonium Salt as Catalyst. (1999) (0)
- DIRECT, STEREOCONTROLLED SYNTHESIS OF A PROSTAGLANDINS USING THE BICYCLO(2,2,1)HEPTENE APPROACH (1973) (0)
- A Direct and Efficient Stereocontrolled Synthetic Route to the Pseudopterosins, Potent Marine Antiinflammatory Agents. (1999) (0)
- Enantioselective Aziridination of C=C (2010) (0)
- Exceptionally Simple Enantioselective Syntheses of Chiral Hexa‐ and Tetracyclic Polyprenoids of Sedimentary Origin. (1998) (0)
- A Novel Synthesis of the Fluorene Skeleton. (1997) (0)
- Stereospecific Synthesis of Tetrasubstituted Z‐Enol Silyl Ethers by a Three Component Coupling Process. (1997) (0)
- Catalytic Enantioselective Diels-Alder Reactions Using Titanium Complexes of cis-N-Sulfonyl-2-amino-1-indanols. (1994) (0)
- New Process for Enantioselective Nucleophilic Addition to Aldehydes to Form Secondary Alcohols. (1991) (0)
- Highly Enantioselective and Diastereoselective Ireland‐Claisen Rearrangement of Achiral Allylic Esters. (1991) (0)
- A Practical New Chiral Controller for Asymmetric Diels—Alder and Alkylation Reactions. (2000) (0)
- Zinc Complexes of Chiral Phenols as Catalysts for Enantioselective Addition of Organozinc Reagents to Aldehydes. (1988) (0)
- An Efficient and Simple Method for the Conversion of 15-HPETE to 14,15-EPETE (Lipotriene A) and 5-HPETE to Leukotriene A as the Methyl Esters. (1985) (0)
- Notice to authors: Eicosanoid nomenclature (1989) (0)
- A New Irreversible Inhibitor of Soybean Lipoxygenase: Relevance to Mechanism. 12-Methylidene-10(Z),13(Z)-nonadecadienoic Acid, a New Irreversible Inhibitor of Soybean Lipoxygenase. (1986) (0)
- An Efficient System for Epoxide-Initiated Cation - Olefin Cyclization. (1992) (0)
- CIS- AND TRANS-2-METHOXYCYCLOPROPYLLITHIUM, NOVEL REAGENTS FOR THE STEREOSELECTIVE SYNTHESIS OF TRANS-β,Γ-UNSATURATED ALDEHYDES (1976) (0)
- Formation of C-O Bonds (2010) (0)
- Position and Enantioselective Dihydroxylation of 2‐Hydroxymethyl‐ and 2‐Hydroxyethyl‐1,3‐butadiene Derivatives Using Bis‐cinchona Alkaloid Catalysts. (1996) (0)
- New superconductor family has unusual features (1988) (0)
- An Efficient Total Synthesis of a New and Highly Active Analogue of Lactacystin. (1998) (0)
- PREPARATION, UNUSUAL SPECTRAL PROPERTIES, AND STRUCTURAL CHARACTERIZATION OF (TERPYRIDINE)(TETRAHYDROBORATO-H,H′)COBALT (1982) (0)
- SYNTHETIC ENTRY INTO THE PROSTAGLANDIN C SERIES (1973) (0)
- The Origin of High Enantioselectivity in the Dihydroxylation of Olefins Using Osmium Tetraoxide and Cinchona Alkaloid Catalysts. (1993) (0)
- Dimethylaluminum Methyltellurate, a New Reagent for the Cleavage of Hindered Methyl Esters under Exceptionally Mild Conditions by a Novel Mechanism. (2005) (0)
- Rhodium(I)-Triethylamine-Catalyzed 1,4-Additionof Enones (2008) (0)
- Synthesis and X-Ray Structure of a Potent Superpositional Analog of the Enantiomeric Forms of Fluoxetine. (1994) (0)
- SYNTHESIS OF LARGE-RING METHYLENE CYCLOALKANES BY THE CYCLIZATION OF ALLYLIC DIBROMIDES WITH NICKEL CARBONYL (1976) (0)
- Catalytic Enantioselective Synthesis of (14R)-14-Hydroxy-4,14-retro- retinol from Retinyl Acetate. (1995) (0)
- Guidelines for the nomenclature of: A. Leukotrienes and related hydroxy, hydroperoxy, epoxy, and oxo-fatty acids B. Enzymes involved in eicosanoid metabolism (1989) (0)
- Applications of the Asymmetric Diels-Alder Reaction (2008) (0)
- Stereocontrolled Total Synthesis of (+)- and (-)-Epibatidine. (2010) (0)
- A SIMPLE ROUTE TO Δ2‐BUTENOLIDES FROM CONJUGATED ALDEHYDES (1980) (0)
- Practical, Stable Standards (I) for the Reversed Phase HPLC Analysis of Peptidic Leukotrienes. (1987) (0)
- Synthesis of three New Dehydroarachidonic Acid Derivatives (I) and Their Oxidation by Soybean Lipoxygenase. (1988) (0)
- Lithium N‐Trityl‐N‐(R)‐1‐phenethylamide, a Readily Available and Useful Base for the Enantioselective Formation of Chiral Enolates from Achiral Ketones. (2000) (0)
- Highly Enantioselective [4 + 2] Cycloaddition Reactions Catalyzed by a Chiral N‐Methyl‐oxazaborolidinium Cation. (2008) (0)
- Remarkably Complex and Unpredictable Cyclization and Rearrangement Reactions of Cations Derived from Unsaturated Oxiranes. (1998) (0)
- Synthesis of (6R,7S)‐Lactacystin and 6‐Deoxylactacystin from a Common Intermediate. (2010) (0)
- Comprar Forensic Psychology and Law | Jie Jack Li | 9780470096239 | Wiley (2009) (0)
- SYNTHESIS OF DI-TERT-ALKYLAMINES (1984) (0)
- METHODS FOR STEREOSPECIFIC SYNTHESIS OF CIS- OR TRANS-HYDRINDANONES (1984) (0)
- Epoxides and Aziridines (2004) (0)
- A Catalytic Enantioselective Synthetic Route to the Important Antidepressant Sertraline (VII). (1994) (0)
- Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis. (1999) (0)
- A Catalytic Enantioselective Total Synthesis of (‐)‐Wodeshiol. (2000) (0)
- Enantiospecific Synthesis of a Rigid, C2 Symmetric, Chiral Guanidine by a New and Direct Method. (1990) (0)
- Synthesis of (-)-7-Methylomuralide (2009) (0)
- Oxidation of Alcohols by Methyl Sulfide‐ N‐Chlorosuccinimide‐ Triethylamine: 4‐tert‐Butylcyclohexanone (2003) (0)
- Synthesis of Palominol and Dolabellatrienone (2006) (0)
- A Short Enantioselective Total Synthesis of Dammarenediol II. (1997) (0)
- SHORT, STEREOCONTROLLED SYNTHESES OF IRREVERSIBLE EICOSANOID BIOSYNTHESIS INHIBITORS. 5,6-, 8,9-, AND 11,12-DEHYDROARACHIDONIC ACID (1982) (0)
- Studies on the Total Synthesis of Lactacystin. An Improved Aldol Coupling Reaction and a β‐Lactone Intermediate in Thiol Ester Formation. (1994) (0)
- (1S),(5R),(8S)-(+)-8-Phenyl-2-azabicyclo(3.3.0)octan-8-ol N,O-Methylboronate and Its Enantiomer, Chiral Chemzymes which Serve as Catalysts for Their Own Enantioselective Synthesis. (1990) (0)
- A Practical and General Enantioselective Synthesis of Chiral Propa-1,2-dienyl and Propargyl Carbinols. (1990) (0)
- The Application of the Shapiro Reaction — Suzuki Coupling Sequence to the Stereoselective Synthesis of E-Trisubstituted Olefins. (1998) (0)
- Formation of a novel glutathionyl conjugate of hepoxilin A3 by rat blood vessels (1990) (0)
- Enantioselective [2+2] Cycloaddition with Oxazaborolidine Catalysts (2008) (0)
- Enantioselective Synthesis of γ-Hydroxysilanes, 1,3-Diols and Cyclopropanes by Reaction of a Chiral Epoxide with a Racemic α- Silyl Organolithium Reagent. (1995) (0)
- A Simple and Enantioselective Synthesis of (+)‐Biotin (II). (1988) (0)
- Appendix 4: Table of Contents for Volume 3:Name Reactions for Homologations-Part II (2010) (0)
- Simple Synthesis of (±)-β-trans-Bergamotene. (1985) (0)
- Highly Enantioselective and Diastereoselective Synthesis of β- Amino Acid Esters and β-Lactams from Achiral Esters and Imines. (1992) (0)
- Chemical Emulation of the Biosynthetic Route to Glycinoeclepin from a Cycloartenol Derivative. (1994) (0)
- Other Five-Membered Heterocycles (2004) (0)
- A Convenient and Versatile Route to Hydroquinolines by Inter- and Intramolecular Aza-Diels—Alder Pathways. (1999) (0)
- Stereocontrolled Syntheses of 24(S),25-Epoxycholesterol and Related Oxysterols for Studies on the Activation of LXR Receptors. (1999) (0)
- An Enantioselective Synthetic Route to Atractyligenin Using the Oxazaborolidine-Catalyzed Reduction of β-Silyl- or β-Stannyl-Substituted α,β-Enones as a Key Step. (1998) (0)
- United States Patent ( 19 ) Ravindranathan et al . ( 54 PROCESS FOR SYNTHESIS OF D ( + ) BIOTIN 75 ) Inventors : (2017) (0)
- First Demonstration of a Carbocation-Olefin Cyclization Route to the Lanosterol Series. (1995) (0)
- STEREOSPECIFIC TOTAL SYNTHESIS OF A “SLOW REACTING SUBSTANCE” OF ANAPHYLAXIS, LEUKOTRIENE C-1 (1980) (0)
- A NEW SYNTHETIC ROUTE TO (.+-.)-PERHYDROHISTRIONICOTOXIN (1976) (0)
- A Transition-State Model for the Mikami Enantioselective Ene Reaction. (1997) (0)
- A Stereospecific Synthesis of Chiral 1,3-Disubstituted Bromoallenes. Stereochemistry of the SN2′ Displacement of Chiral 1,3-Disubstituted Bromoallenes to Form Chiral Acetylenes. d-Orbital Stereoelectronic Control of the Stereochemistr (1984) (0)
- Evidence for the Importance of .pi±pi.‐Attractive Interactions in Enantioselective Diels‐Alder Reactions Chiral Catalysts of Type (RO) 2TiCl2. (1992) (0)
- ERRATA: (modification to procedure originally published in Org. Synth. 2003, 80, 38; Coll. Vol. 11, 2009, 404.): Preparation of O‐Allyl‐N‐(9‐Anthracenyl‐Methyl)‐Cinchonidinium Bromide as a Phase Transfer Catalyst (2011) (0)
- Enantioselective Mukaiyama-Aldol and Aldol-Dihydropyrone Annulation Reactions Catalyzed by a Tryptophan-Derived Oxazaborolidine. (1993) (0)
- Mechanism of enzymic lipoxygenation of arachidonic acid key role of organoiron intermediates (1987) (0)
- A NEW AND UNUSUALLY FLEXIBLE SCHEME FOR ANNULATION TO FORM FUSED CYCLOHEXENONE UNITS (1979) (0)
- The condensation of citraconic and maleic anhydrides with chloroprene and ethoxyprene (1948) (0)
- Pd(OH)2/C-Mediated Selective Oxidation of Silyl Enol Ethers by tert-Butylhydroperoxide, a Useful Method for the Conversion of Ketones to α,β-Enones or β-Silyloxy-α,β-enones. (2005) (0)
- John Clark Sheehan - September 23, 1915-March 21, 1992. (1995) (0)
- A Short Synthetic Route to (+)‐Austamide, (+)‐Deoxyisoaustamide, and (+)‐Hydratoaustamide from a Common Precursor by a Novel Palladium‐Mediated Indole → Dihydroindoloazocine Cyclization. (2002) (0)
- Efficient method for selective introduction of substituents as C5 of isoleucine and other alpha-amino acids. (2006) (0)
- Formation of Olefins via Pyrolysis of Sulfonate Esters. (1989) (0)
- TOTAL SYNTHESIS OF (.+‐.)‐RETIGERANIC ACID (1985) (0)
- A Novel, One‐Step Annulation Process for the Synthesis of Ring‐Fused 2‐Cyclopentenones. (1988) (0)
- Highly enantioselective dimerization of alpha,beta-enones catalyzed by a rigid quaternary ammonium salt. (2004) (0)
- The Effects of a Fish-Oil-enriched Diet on Pulmonary Mechanics during Anaphylaxis1–3 (2015) (0)
- Total Synthesis of (.+-.)-Forskolin. (1988) (0)
- 1,3-Dithiane (2003) (0)
- Efficient Enantioselective Syntheses of Chloramphenicol and (D)-threo- and (D)-erythro-Sphingosine. (2000) (0)
- Asymmetric Conjugate Addition of Acetylene Nucleophiles (2010) (0)
- A Stereospecific Synthesis of a Dihydrofuran Analog (I) of Leukotriene A4. (1991) (0)
- X‐Ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2‐ Diamine‐OsO4 Complex, Formally a 20‐Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2‐Diamine‐Accelerated Dihydroxylation of Olefins by OsO4. (1996) (0)
- The Logic of Chemical Synthesis: Multistep Syntheses of Complex Carbogenic Molecules (Nobel-Lecture) (1991) (0)
- Simple Synthetic Route to the Limonoid System. (1987) (0)
- 1‐Mesityl‐2,2,2‐trifluoroethanol. An Outstanding New Chiral Controller for Catalyzed Diels‐Alder Reactions. (1992) (0)
- Comprar To Improve Health and Health Care, Volume XIII: The Robert Wood Johnson Foundation Anthology | Jie Jack Li | 9780470496633 | Wiley (2009) (0)
- Novel Electronic Effects of Remote Substituents on the Oxazaborolidine- Catalyzed Enantioselective Reduction of Ketones. (1996) (0)
- pH and membrane potential in human neutrophils (2005) (0)
- A Convergent Enantioselective Synthesis of the Tetrahydroisoquinoline Unit in the Spiro Ring of Ecteinascidin 743. (1997) (0)
- THE 1,3 O → C SILYL REARRANGEMENT OF SILYL ENOL ETHER ANIONS - SYNTHESIS OF α-SILYL KETONES (1985) (0)
- ALPHA-DITHIOMETHYLENE KETONES, GENERATION AND APPLICATION TO SYNTHESIS (1973) (0)
- Prediction of the stereochemistry of alpha-brominated ketosteroids. (1953) (0)
- Generation of 1Δg O2from Triethylsilane and Ozone. (1986) (0)
- NEW SYNTHETIC ROUTES TO LEUKOTRIENES AND OTHER ARACHIDONATE‐DERIVED EPOXYEICOSATETRAENOIC ACIDS (EPETE′S). EXCLUSION OF THE HYDROXY EPOXIDE PATHWAY FOR LEUKOTRIENE BIOSYNTHESIS (1984) (0)
- Evidence for a Reversible d,π-Complexation, β-Cupration Sequence in the Conjugate Addition Reaction of Gilman Reagents with α,β-Enones. (1986) (0)
- A METHOD FOR CATALYTIC DEHALOGENATIONS VIA TRIALKYLTIN HYDRIDES (1975) (0)
- A Short Catalytic Enantioselective Synthesis of the Vascular Antiinflammatory Eicosanoid (11R,12S)‐Oxidoarachidonic Acid. (2001) (0)
- Useful Enantioselective Bicyclization Reactions Using an N‐Protonated Chiral Oxazaborolidine as Catalyst. (2004) (0)
- Highly Enantioselective [2 + 2]‐Cycloaddition Reactions Catalyzed by a Chiral Aluminum Bromide Complex. (2008) (0)
- The role of angiotensin II (AII) and cyclooxygenase products in mediating the systemic and renal vascular responses to leukotriene C4 (LTC4) infusion in the rat (1984) (0)
- Versatile Chiral Reagent for the Highly Enantioselective Synthesis of Either Anti or Syn Ester Aldols. (1990) (0)
- SYNTHESIS OF 11α,9α-EPOXYMETHANOTHROMBOXANE A2: A STABLE, OPTICALLY ACTIVE TXA2 AGONIST (1982) (0)
- Highly Effective Transition Structure Designed Catalyst for the Enantio‐ and Position‐Selective Dihydroxylation of Polyisoprenoids. (2002) (0)
- A NOVEL ALPHA-ALKYLATION OF ALPHA,BETA-EPOXY KETONES (1975) (0)
- A New Cationic, Chiral Catalyst for Highly Enantioselective Diels—Alder Reactions. (2003) (0)
- A Simple Synthetic Process for the Elaboration of Oligoprenols by Stereospecific Coupling of Di-, Tri-, or Oligoisoprenoid Units. (2010) (0)
- Two Effective Procedures for the Synthesis of Trichloromethyl Ketones, Useful Precursors of Chiral α‐Amino and α‐Hydroxy Acids. (1992) (0)
- Radioimmunoassay oftheleukotrienes ofslowreacting substance ofanaphylaxis (1981) (0)
- Titelbild: Angew. Chem. 10/2002 (2002) (0)
- Broad-Spectrum Enantioselective Diels—Alder Catalysis by Chiral, Cationic Oxazaborolidines. (2003) (0)
- A BIOGENETIC APPROACH TO THE SYNTHESIS OF A PROSTANOID PRECURSOR (1974) (0)
- Appendix 3. Table of Contents for Volume 4: Name Reactions for Ring Formation (2007) (0)
- SYNTHESIS OF THREE POTENTIAL INHIBITORS OF THE BIOSYNTHESIS OF LEUKOTRIENES A-E (1981) (0)
- Simple Enantiospecific Syntheses of the C(2)-Diastereomers (II) and (III) of Omuralide (I) and 3-Methylomuralide (IV). (2005) (0)
- Preference for Photodissociation over Internal (2 + 2)‐cycloaddition During Irradiation of an Unsaturated α,β‐Enone. (1994) (0)
- A Catalytic Enantioselective Synthesis of Chiral Monosubstituted Oxiranes. (1993) (0)
- A Simple Synthesis of 4-Carboxyatractyligenin from Atractyligenin. (1999) (0)
- Useful New Annulation Reactions of Vicinal Dicarboxylic Esters. (1987) (0)
- Jeremy R. Knowles (1935–2008) (2008) (0)
- Convenient Method for the Recovery of Eicosapentaenoic Acid (I) from Cod Liver Oil. (1989) (0)
- Frank H. Westheimer (1912–2007) (2007) (0)
- A Simple Enantioselective Synthesis of (1S,4R)‐Bicyclo(2.2.1)hept‐2‐ ene‐2‐methanol. (1993) (0)
- Enantiospecific Total Synthesis of Pseudopterosins A and E. (1989) (0)
- Determinants for an Integrated Tissue Response to the Sulphidopeptide Leukotrienes (1983) (0)
- 261 Bioconversion of leukotriene (LT) C4 to LTD4 is not a prerequisite for its spasmogenic activity (1983) (0)
- NEUARTIGE METHODE DER 1,4-ADDITION DER METHYLENCARBONYLEINHEIT (-CH2-CO-) AN DIENE (1971) (0)
- Two Unprecedented Reactions of Nitrosyl Triflate: NO+-Induced Cationic Cascade Cyclization and C═C Oxidative Cleavage. (2023) (0)
- Formation of CC Bonds (2010) (0)
- Synthesis of Pentacycloanammoxic Acid (2006) (0)
- A New Chiral Catalyst for the Enantioselective Synthesis of Secondary Alcohols and Deuterated Primary Alcohols by Carbonyl Reduction. (1990) (0)
- NEW METHOD FOR PROTECTION OF CARBONYL COMPOUNDS AS 5-METHYLENE-1,3-DIOXANES (1976) (0)
- α-FUNCTIONALIZATION OF KETONES VIA N,N-DIMETHYLHYDRAZONES (1977) (0)
- Studies on Enantioselective Syntheses (1997) (0)
- Synthesis of Isoedunol and β-Araneosene (2006) (0)
- A New and Simple Synthesis of Alkoxy- and Aryloxymethyllithium Reagents (ROCH2Li). t-Butoxymethyllithium: Direct Preparation from t-Butyl Methyl Ether and Applications as a Hydroxymethyl Anion Equivalent. (1983) (0)
- Triflimide Activation of a Chiral Oxazaborolidine Leads to a More General Catalytic System for Enantioselective Diels—Alder Addition. (2003) (0)
- A Mechanistically Designed Mono‐cinchona Alkaloid Is an Excellent Catalyst for the Enantioselective Dihydroxylation of Olefins. (1995) (0)
- An Enantioselective Synthesis of (2S,3S)- and (2R,3S)-3-Hydroxyleucine. (1993) (0)
- Highly Enantioselective and Regioselective Catalytic Dihydroxylation of Homoallylic Alcohol Derivatives. (1995) (0)
- A process for the preparation of ecteinascidin compounds (1997) (0)
- Appendix 2. Table of Contents for Volume 3: Name Reactions for Chain Extension (2007) (0)
- Kinetic Resolution by Enantioselective Dihydroxylation of Secondary Allylic 4‐Methoxybenzoate Esters Using a Mechanistically Designed Cinchona Alkaloid Catalyst. (1996) (0)
- Convenient synthesis of 3-amino-3-deoxy-D-ribose (1968) (0)
- Tetrafluorosilane is a Mild and Very Selective Reagent for the Cleavage of Silyl-Protected Alcohols, e.g. (I). (1992) (0)
- Total Synthesis and Biological Activity of Lactacystin, Omuralide and Analogues (1999) (0)
- New, Practical and Effective Sources of Fluoride Ion for Desilylation to Form Carbon Anions. (1999) (0)
- Enantioselective Routes to Chiral Benzylic Thiols, Sulfinic Esters, and Sulfonic Acids Illustrated by the 1‐Phenylethyl Series. (1993) (0)
- Enantioselective Desymmetrization of Cyclohexadienones (2017) (0)
- Demonstration of the Synthetic Power of Oxazaborolidine-Catalyzed Enantioselective Diels-Alder Reactions by Very Efficient Routes to Cassiol and Gibberellic Acid. (1994) (0)
- An Effective Process for the Isolation of Docosahexaenoic Acid in Quantity from Cod Liver Oil. (1988) (0)
- Stereoselective Synthesis of an Important Prostaglandin Synthetic Intermediate. (1991) (0)
- New Synthetic Route for the Enantioselective Total Synthesis of Salinosporamide A (I) and Biologically Active Analogues. (2005) (0)
- SELEKTIVE INHIBITION VON PROSTAGLANDIN-SYNTHETASE DURCH EIN BICYCLO(2,2,1)HEPTEN-DERIVAT (1971) (0)
- A SIMPLE SYNTHESIS OF 8-METHYLPROSTAGLANDIN C2 (1974) (0)
- Cβ-Cγ CLEAVAGE OF A γ-HYDROXY ACID BY ELECTROLYTIC OXIDATION1 (1957) (0)
- Regioselective Aldol Condensation of Dialdehydes (2006) (0)
- The Application of the Shapiro Reaction to the Stereoselective Synthesis of E-Trisubstituted Olefins for Cation-Olefin Cyclization by Three Component Coupling. (1998) (0)
- The synthesis of N,N-diacylamino acids and analogs of penicillin (1951) (0)
- The Control of Diastereoselectivity in the Michael Reaction of Ketonic Enolates with Crotonic Acid Derivatives. (1993) (0)
- Appendix 5: Table of Contents for Volume 5: Name Reactions for Carbocyclic Ring Formations (2011) (0)
- Specific reduction of E prostaglandins to F prostaglandins and prostaglandin E 2 to prostaglandin E 1 . (1971) (0)
- NEW EXTENSIONS OF THE BICYCLO(2.2.1)HEPTANE ROUTE TO PROSTAGLANDINS (1974) (0)
- NEW ANNULATION FOR FUSED AND SPIRO RINGS BASED ON THE CHEMISTRY OF BENZOTHIAZOLES (1978) (0)
- ACTIVATION OF METHYLENETRIPHENYLPHOSPHORANE BY REACTION WITH TERT-BUTYL- OR SEC-BUTYLLITHIUM (1985) (0)
- Total synthesis of prostaglandins E2 and F2-alpha (dl) via a tricarbocyclic intermediate. (1970) (0)
- Asymmetric Diels—Alder Reactions Catalyzed by a Triflic Acid Activated Chiral Oxazaborolidine. (2002) (0)
- Biomimetic Synthesis of a Preclavulone A Model (I). (1988) (0)
- Highly Enantioselective Routes to Darzens and Acetate Aldol Products from Achiral Aldehydes and t‐Butyl Bromoacetate. (2010) (0)
- Enhancement of the sensitivity of hamster cheek pouch arterioles to beta-adrenergic stimulus during pregnancy (1982) (0)
- Chiral Diazaborolidine Mediated Enantioselective Aldol Reactions of Phenylthioacetate Esters. (2000) (0)
- SYNTHETIC ROUTES TO POLYFUNCTIONAL MOLECULES VIA METALATED DIMETHYLHYDRAZONES (1978) (0)
- Carbon-Carbon Bond Formation by O-C Rearrangement of Allylideneoxyphosphoranes. (1992) (0)
- Enantioselective Michael Reactions. Stereoselective Addition of Enolates of Phenmenthol Esters to Crotonates. (1986) (0)
- Total Synthesis of (f)-Ginkgolide B (1988) (0)
- 2,4-DINITROBENZENESULFONYLHYDRAZINE, A USEFUL REAGENT FOR THE ESCHENMOSER ALPHA,BETA-CLEAVAGE OF ALPHA,BETA-EPOXY KETONES, CONFORMATIONAL CONTROL OF HALOLACTONIZATION (1975) (0)
- A SHORT,THREE-COMPONENT TOTAL SYNTHESIS OF 12-HYDROXYEICOSA-5,8,14(Z),10(E)-TETRAENOIC ACID (12-HETE) VIA THE CORRESPONDING KETONE (1985) (0)
- Asymmetric Oxazaborolidine-Catalyzed Diels-AlderReaction of Maleimides (2010) (0)
- The First Enantioselective Syntheses of Pure (R)- and (S)-Isoproterenol. (1990) (0)
- Studies in the Mechanism of Bile Acid Formation. (1957) (0)
- Chiral Catalysts for the Enantioselective Addition of Organometallic Reagents to Aldehydes. (1988) (0)
- An Efficient and Catalytically Enantioselective Route to (S)-(-)-Phenyloxirane. (1988) (0)
- New Enantioselective Synthetic Method. (1993) (0)
- Preparation of Chiral-Bridged Dienes - Ligands forEnantioselective Catalysis (2010) (0)
- Highly Enantioselective Bornane Reduction of Ketones Catalyzed by Chiral Oxazaborolidines. Mechanism and Synthetic Implications. (1987) (0)
- New Stereospecific Synthetic Routes to the Bicyclo[3.2.1]octane Subunit of the Kaurenoids and Gibberellins. (1998) (0)
- Synthesis of (-)--Caryophyllene (2008) (0)
- CONVERSION OF KETONES HAVING Δ,.vepsiln±PI.-FUNCTIONS TO CYCLOPENTANOLS BY ZINC-TRIMETHYLCHLOROSILANE (1983) (0)
- A Simple and Effective Procedure for Removal of Tri‐n‐butyltin Halides from Reaction Mixtures. (1999) (0)
- A TOTAL SYNTHESIS OF (.+-.)-CERULENIN (1978) (0)
- Synthesis and X-Ray Structure of a Novel Chiral Trinuclear Titanium- Tetraol Complex. (1994) (0)
- STUDIES ON THE CONFORMATIONAL MOBILITY OF ARACHIDONIC ACID. FACILE MACROLACTONIZATION OF 20-HYDROXYARACHIDONIC ACID (1983) (0)
- Highly Enantioselective Dimerization of α,β‐Enones Catalyzed by a Rigid Quaternary Ammonium Salt. (2005) (0)
- A New Process for the Generation of 1,3,2‐Oxazaborolidines, Catalysts for Enantioselective Synthesis. (1993) (0)
- Total synthesis of natural products (2000) (0)
- TOTALSYNTH. VON (+-)-FUMAGILLIN (1972) (0)
- Comprar Molecules and Medicine | E. J. Corey | 9780470227497 | Wiley (2007) (0)
- Synthesis of Azabiaryls by a non-Cross-Coupling Method (2006) (0)
- Functionalization of Unactivated Positions in α-Amino Acid Derivatives (2006) (0)
- Carbolactonization of Olefins Under Mild Conditions by Cyanoacetic and Malonic Acids Promoted by Manganese(III) Acetate. (1986) (0)
- Frank Henry Westheimer. 15 January 1912—14 April 2007 (2018) (0)
- The E/Z Geometry of the Enolate Component Determines Face Selection of the Aldehyde Component in Chiral Diazaborolidine-Directed Enantioselective Aldol Coupling. (1993) (0)
- A New Strategy for Stereocontrol of Cation-Olefin Cyclization. The First Chemical Emulation of the A/B-trans-9,10-syn-Folding Pathway of Steroid Biosynthesis from 2,3-Oxidosqualene. (1997) (0)
- Mechanism and conditions for highly enantioselective epoxidation of alpha,beta-enones using charge-accelerated catalysis by a rigid quaternary ammonium salt. (1999) (0)
- Practical Enantioselective Diels-Alder and Aldol Reactions Using a New Chiral Controller System. (1989) (0)
- Enantioselective Rhodium(I)—Triethylamine Catalyzed Addition of Potassium Isopropenyl Trifluoroborate to Enones. (2008) (0)
- Stereospecific total synthesis of dl-sesquicarene (1969) (0)
- SYNTHESIS OF PROSTAGLANDINS VIA A 1,2-DIOXABICYCLO(2.2.1)HEPTANE (ENDOPEROXIDE) INTERMEDIATE. STEREOCHEMICAL DIVERGENCE OF ENZYMIC AND BIOMIMETIC CHEMICAL CYCLIZATION REACTIONS (1985) (0)
- TOTAL SYNTHESIS OF (.+-.)-BREFELDIN A. (PART IV) (1977) (0)
- Enantioselective Total Synthesis of Isoedunol (I) and β‐Araneosene (II) Featuring Unconventional Strategy and Methodology. (2006) (0)
- Catalytic Enantioselective Synthesis of a Key Intermediate (I) for the Synthesis of Prostanoids. (1992) (0)
- A New Process for the Enantioselective Synthesis of Chiral α‐ Aryloxy and α‐Hydroxy Acids. (1992) (0)
- Synthesis of Cortistatin Analogues (2009) (0)
- Reductive Cleavage of tert-Butyldimethylsilyl Ethers (I) by Diisobutylaluminum Hydride. (1992) (0)
- Enantioselective Conjugate Addition of Rationally Designed Chiral Cuprate Reagents to 2-Cycloalkenones. (1987) (0)
- Synthesis of Tetracyclic C2-Symmetric Ketiminium Salts and Evaluation as Catalysts for Epoxidation. (2023) (0)
- Aromatic Annulation: Two New Methods for the Synthesis of Chiral Bicyclic Phenols. (1997) (0)
- Synthesis of a β-Lactam Proteasome Inhibitor (2006) (0)
- Robert Robinson Lecture. Retrosynthetic Thinking - Essentials and Examples (1989) (0)
- Formation of CH Bonds (2010) (0)
- Supplementary material from "Frank Henry Westheimer. 15 January 1912 — 14 April 2007" (2018) (0)
- STEREOSPECIFIC TOTAL SYNTHESIS OF 12-(R)- AND 12-(S)-FORMS OF 6-TRANS-LEUKOTRIENE B (1981) (0)
- BIS-(DIMETHYLALUMINUM)1,3-PROPANEDITHIOLATE - A USEFUL REAGENT IN THE CONVERSION OF ESTERS TO UNSATURATED ALDEHYDES AND KETONES (1975) (0)
- Simple, Stereocontrolled Syntheses of 24(S),25‐Epoxy‐22(R)‐hydroxycholesterol, 22(R),24(S)‐Dihydroxycholesterol and Diastereomers, New Ligands for Binding and Activation of LXRs. (1999) (0)
- Formation of C H Bonds (2010) (0)
- STUDIES ON THE TOTAL SYNTHESIS OF RIFAMYCIN. A METHOD FOR THE STEREOSPECIFIC SYNTHESIS OF THE CARBONYL-CONJUGATED 1,3-DIENE UNIT (C(15) TO C(20)) (1979) (0)
- TOTALSYNTH. VON PROSTAGLANDIN F(2ALPHA)(D,L) AUS 2‐OXABICYCLO(3,3,0)OCT‐6‐EN‐3‐ON (1970) (0)
- CARBOXYLATION REACTIONS USING THE REAGENT LITHIUM 4-METHYL-2,6-DI-TERT.-BUTYLPHENOXIDE (1974) (0)
- Enantioselective Synthesis of the (5S,6R,9R) and (5S,6R,9S) Analogues of Lactacystin β-Lactone. (1999) (0)
- Synthesis of Aflatoxin B2 (2006) (0)
- FORMATION OF α,β-EPOXY SYSTEMS FROM β-PEROXY CARBON FREE RADICALS (1983) (0)
- Synthesis of a Fused β-Lactone via Pyridine-Assisted [2+2] Cycloaddition (2006) (0)
- Enantioselective and Structure‐Selective Diels—Alder Reactions of Unsymmetrical Quinones Catalyzed by a Chiral Oxazaborolidinium Cation. Predictive Selection Rules. (2004) (0)
- An Enantioselective Synthesis of (6R)-Lactacystin. (1994) (0)
- A j3-lactone related to lactacystin induces neurite outgrowth in a neuroblastoma cell line and inhibits cell cycle progression in an osteosarcoma cell line (0)
- An Efficient Catalytic Stereoselective Route to a Key Intermediate for the Synthesis of the Long‐Lived PGI2 Analogue ZK 96480 (CicaprostTM). (1998) (0)
- Characterisation of the prostanoid receptor profile of 9,10α-epoxy and 9,10β-epoxy prostadienoic acids in vitro (1990) (0)
- Polyfunctional, Structurally Defined Catalysts for the Enantioselective Addition of Dialkylzinc Reagents to Aldehydes. (1990) (0)
- C-C? CLEAVAGE OF A ?-HYDROXY ACID BY ELECTROLYTIC OXIDATION (1957) (0)
- A DIRECT TOTAL SYNTHESIS OF THROMBOXANE B2(. (1977) (0)
- Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to alpha,beta-enones or beta-silyloxy-alpha,beta-enones. (2005) (0)
- A General Process for the Haloamidation of Olefins, Scope and Mechanism. (2006) (0)
- First Enantioselective Total Synthesis of a Naturally Occurring Dolabellane. Revision of Absolute Configuration. (1996) (0)
- A Method for the Selective Oxidation of 1,4‐Diols to Lactols. (1995) (0)
- A Short, Stereospecific Route to Chiral trans-2,6-Disubstituted Quinuclidines. (1990) (0)
- Comprar Name Reactions of Functional Group Transformations | E. J. Corey | 9780471748687 | Wiley (2007) (0)
- Progress in Stereochemistry. (1955) (0)
- Synthesis of a Platensimycin Mimic (2009) (0)
- Role of Diethylaniline in the Reduction of 1,3-DicarbonylCompounds (2009) (0)
- Concise Total Syntheses of Palominol (I), Dolabellatrienone (II), β-Araneosene (III), and Isoedunol via an Enantioselective Diels—Alder Macrobicyclization. (2006) (0)
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