Martyn Poliakoff
#24,353
Most Influential Person
British chemist
Why Is Martyn Poliakoff Influential?
(Suggest an Edit or Addition)Martyn Poliakoff is a research professor in the chemistry department at the University of Nottingham. He attended Westminster School before earning a bachelor’s degree and Ph.D. from King’s College in Cambridge.
Best known for his video series, The Periodic Table of Videos, Poliakoff is a leading researcher in green chemistry, with a particular focus on supercritical fluids. His video series features more than 600 videos discussing the various elements of the periodic table, and more recently, molecules and other chemistry topics.
He has received numerous honors in the field, including the Meldola Medal and Prize and the Nyholm Prize. He is a fellow of the Royal Society, the Royal Society of Chemistry, the Institution of Chemical Engineers, and a foreign member of the Russian Academy of Sciences. He was named an Associate Fellow of the Ethiopian Academy of Sciences.
In 2008, he was appointed Commander of the Order of the British Empire for his substantial contributions to the field of chemistry. Most recently, he was honored with the Royal Society of London Michael Faraday Prize and the Longstaff Prize.
He has provided critical leadership as well, serving in leadership positions for the Royal Society and through his work with the Advisory Council for the Campaign for Science and Engineering.
Featured in Top Influential Chemists Today
According to Wikipedia, Sir Martyn Poliakoff is a British chemist, working on gaining insights into fundamental chemistry, and on developing environmentally acceptable processes and materials. The core themes of his work are supercritical fluids, infrared spectroscopy and lasers. He is a research professor in chemistry at the University of Nottingham. His group comprises several members of staff, postdoctoral research fellows, postgraduate students and overseas visitors. As well as carrying out research at the University of Nottingham, he is a lecturer, teaching a number of modules including green chemistry.
Martyn Poliakoff's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- Valorization of Biomass: Deriving More Value from Waste (2012) (1477)
- Green chemistry: science and politics of change. (2002) (694)
- New Directions in Inorganic and Metal-Organic Coordination Chemistry in Supercritical Fluids. (1999) (493)
- Sustainable technology: Green chemistry (2007) (302)
- Chemical recycling of carbon fibre reinforced composites in nearcritical and supercritical water (2008) (245)
- Principles of green chemistry: PRODUCTIVELY (2005) (225)
- Reaction engineering: The supercritical water hydrothermal synthesis of nano-particles (2006) (218)
- Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions (2008) (218)
- The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water (2001) (191)
- The 24 Principles of Green Engineering and Green Chemistry: “IMPROVEMENTS PRODUCTIVELY” (2008) (191)
- Continuous hydrothermal synthesis of inorganicmaterials in a near-critical water flow reactor; the one-step synthesisof nano-particulate Ce1 − xZrxO2(x = 0–1)solid solutions (2001) (186)
- Chemical reactions in supercritical carbon dioxide: from laboratory to commercial plantThis work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002. (2003) (186)
- Maximising opportunities in supercritical chemistry: the continuous conversion of levulinic acid to gamma-valerolactone in CO(2). (2007) (166)
- Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward. (2012) (162)
- Synthesis of benzimidazoles in high-temperature water (2003) (150)
- A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases (2009) (136)
- Laser Induced Processes in Molecules (1979) (134)
- 1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods (1988) (131)
- Real-time product switching using a twin catalyst system for the hydrogenation of furfural in supercritical CO2. (2010) (124)
- Vibrational Spectroscopy in Supercritical Fluids: From Analysis and Hydrogen Bonding to Polymers and Synthesis (1995) (123)
- Selective catalytic hydrogenation of organic compounds in supercritical fluids as a continuous process (1998) (121)
- A principled stance (2001) (119)
- Continuous catalytic reactions in supercritical fluids (2001) (114)
- Applying green chemistry to the photochemical route to artemisinin. (2015) (114)
- Synthesis of metal–organic frameworks by continuous flow (2014) (107)
- Structure and reactions of matrix-isolated tetracarbonyliron(0) (1975) (107)
- Self-optimizing continuous reactions in supercritical carbon dioxide. (2011) (102)
- Continuous hydrogenation of organic compounds in supercriticalfluids (1997) (93)
- How does the critical point change during a chemical reaction in supercritical fluids? A study of the hydroformylation of propene in supercritical CO(2). (2001) (92)
- A continuous and clean one-step synthesis of nano-particulate Ce1−xZrxO2 solid solutions in near-critical water (2000) (90)
- Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst (2000) (90)
- Cleaner continuous photo-oxidation using singlet oxygen in supercritical carbon dioxide. (2009) (78)
- Low temperature assembly of fullerene arrays in single-walled carbon nanotubes using supercritical fluids (2004) (76)
- Nanosecond time-resolved infrared spectroscopy: a comparative view of spectrometers and their applications in organometallic chemistry (1994) (76)
- Structure and thermal reactions of dihydrogen complexes: the IR characterization of M(CO)5(H2) (M = chromium, molybdenum, and tungsten) and cis-Cr(CO)4(H2)2 in liquid xenon solution and the formation of HD during exchange of hydrogen and deuterium (1986) (75)
- The Continuous Acid-Catalyzed Dehydration of Alcohols in Supercritical Fluids: A New Approach to the Cleaner Synthesis of Acetals, Ketals, and Ethers with High Selectivity (1999) (75)
- Remarkable Stability of (η5-C5H5)Re(CO)2L (L = n-Heptane, Xe, and Kr): A Time-Resolved Infrared Spectroscopic Study of (η5-C5H5)Re(CO)3 in Conventional and Supercritical Fluid Solution (1997) (75)
- Shedding light on organometallic reactions: the characterization of tetracarbonyliron (Fe(CO)4), a prototypical reaction intermediate (1987) (74)
- Amorphous vanadium phosphate catalysts prepared using precipitation with supercritical CO2 as an antisolvent (2002) (72)
- Photolysis and spectroscopy with polarized light: key to the photochemistry of pentacarbonylchromium and related species (1978) (72)
- Organometallic chemistry in supercritical fluids. The generation and detection of dinitrogen and nonclassical dihydrogen complexes of Group 6, 7, and 8 transition metals at room temperature (1990) (70)
- Controlled continuous hydrothermal synthesis of cobalt oxide (Co3O4) nanoparticles (2012) (69)
- Photochemistry of aryl azides: detection and characterization of a dehydroazepine by time-resolved infrared spectroscopy and flash photolysis at room temperature (1987) (69)
- Supercritical fluid-mediated alumination of mesoporous silica and its beneficial effect on hydrothermal stability. (2002) (68)
- The Twelve Principles of CO2 CHEMISTRY. (2015) (67)
- Remote-controlled experiments with cloud chemistry. (2015) (66)
- Continuous kinetic resolution catalysed by cross-linked enzyme aggregates, ‘CLEAs’, in supercritical CO2 (2006) (65)
- A versatile flow visualisation technique for quantifying mixing in a binary system: application to continuous supercritical water hydrothermal synthesis (SWHS) (2004) (64)
- Synthesis and characterization of the pentacarbonylmanganese(0) radical, Mn(CO)5, in low-temperature matrixes (1981) (63)
- Selective host-guest interaction of single-walled carbon nanotubes with functionalised fullerenes. (2004) (62)
- An IR Study of Hydrogen Bonding in Liquid and Supercritical Alcohols (2002) (60)
- Synthesis of mesoporous silica hollow spheres in supercritical CO2/water systems (2006) (60)
- Photochemistry of the group VI hexacarbonyls in low temperature matrices. Part I. The pentacarbonyls of chromium, molybdenum, and tungsten (1971) (59)
- XAS (XANES and EXAFS) Investigations of Nanoparticulate Ferrites Synthesized Continuously in Near Critical and Supercritical Water (2007) (59)
- Infrared spectra and photochemistry of the complex pentacarbonyliron in solid matrices at 4 and 20 K: evidence for formation of the complex tetracarbonyliron (1973) (58)
- Friedel–Crafts alkylation in supercritical fluids: continuous, selective and clean (1998) (58)
- Selective partial oxidation in supercritical water: the continuous generation of terephthalic acid from para-xylene in high yield (2002) (57)
- Immobilised photosensitisers for continuous flow reactions of singlet oxygen in supercritical carbon dioxide (2011) (57)
- Infrared spectroscopic studies on the photocatalytic hydrogenation of norbornadiene by Group 6 metal carbonyls. 2. The role of the diene and the characterization of (.eta.4-norbornadiene)(.eta.2-norbornadiene)M(CO)3 complexes (1990) (57)
- Infrared spectroscopic studies on the photocatalytic hydrogenation of norbornadiene by Group 6 metal carbonyls. 1. The role of H2 and the characterization of nonclassical dihydrogen complexes, (.eta.4-norbornadiene)M(CO)3(.eta.2-H2) (1990) (56)
- Continuous Asymmetric Hydrogenation in Supercritical Carbon Dioxide using an Immobilised Homogeneous Catalyst (2006) (56)
- Real-Time Feedback Control Using Online Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy for Continuous Flow Optimization and Process Knowledge (2013) (55)
- Synthesis of siliceous hollow spheres with large mesopore wall structure by supercritical CO2-in-water interface templating. (2005) (54)
- Synthesis of nanoparticulate yttrium aluminum garnet in supercritical water–ethanol mixtures (2007) (54)
- Can Organometallic Noble Gas Compounds Be Observed in Solution at Room Temperature? A Time-Resolved Infrared (TRIR) and UV Spectroscopic Study of the Photochemistry of M(CO)6 (M = Cr, Mo, and W) in Supercritical Noble Gas and CO2 Solution (1996) (53)
- Continuous catalytic asymmetric hydrogenation in supercritical CO2 (2004) (53)
- The Structure of [Fe(CO)4 ]-An Important New Chapter in a Long-Running Story. (2001) (52)
- Cyclopentadienylidene. A matrix isolation study exploiting photolysis with unpolarized and plane-polarized light. (1981) (51)
- Detection of Transient Organometallic Species by Fast Time-Resolved IR Spectroscopy (1986) (51)
- Phase Boundaries of CO2 + Toluene, CO2 + Acetone, and CO2 + Ethanol at High Temperatures and High Pressures (2006) (51)
- Adaptive Process Optimization for Continuous Methylation of Alcohols in Supercritical Carbon Dioxide (2011) (50)
- The infrared laser induced isomerization of iron tetracarbonyl. The first non-Berry pseudorotation (1977) (49)
- Selective monoprotection of 1,n-terminal Diols in supercritical carbon dioxide: a striking example of solvent tunable desymmetrization. (2005) (49)
- Large-aperture variable-volume view cell for the determination of phase-equilibria in high pressure systems and supercritical fluids (2004) (49)
- Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. V. Two routes to square pyramidal matrix isolated chromium pentacarbonyl (1975) (48)
- Probing Vapor/Liquid Equilibria of Near-Critical Binary Gas Mixtures by Acoustic Measurements (1996) (48)
- Hydroformylation of alkenes in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes (2002) (48)
- Photochemical substitution reactions of dinuclear iron complex [CpFe(CO)2]2 (Cp = .eta.5-C5H5) in hydrocarbon and tetrahydrofuran solution at room temperature: a mechanistic study with time-resolved infrared spectroscopy (1992) (47)
- Matrix photochemistry of metal carbonyls (1977) (47)
- Structure and reactions of octacarbonyldiiron: An IR spectroscopic study using carbon-13 monoxide, photolysis with plane-polarized light, and matrix isolation (1986) (47)
- Organic reactions in high-temperature and supercritical water (2006) (47)
- Enabling the Scale-Up of a Key Asymmetric Hydrogenation Step in the Synthesis of an API Using Continuous Flow Solid-Supported Catalysis (2016) (46)
- Amorphous vanadium phosphate catalysts from supercritical antisolvent precipitation (2001) (46)
- Electronic stability of metal-dihydrogen and -polyhydrogen complexes (1987) (45)
- Near-critical water, a cleaner solvent for the synthesis of a metal–organic framework (2012) (45)
- Maximising the efficiency of continuous photo-oxidation with singlet oxygen in supercritical CO2 by use of fluorous biphasic catalysis. (2012) (44)
- Supercritical hydrogenation and acid-catalysed reactions "without gases". (2004) (44)
- Continuous reactions in supercritical fluids; a cleaner, more selective synthesis of thymol in supercritical CO2 (2005) (44)
- The production and formulation of silver nanoparticles using continuous hydrothermal synthesis (2013) (44)
- Continuous catalytic upgrading of ethanol to n-butanol and >C4 products over Cu/CeO2 catalysts in supercritical CO2 (2015) (43)
- Structure and reactivity of (.eta.5-C5H5)Mn(CO)2 in room-temperature solution. Evidence for formation of a dinuclear intermediate detected by flash photolysis and time-resolved infrared spectroscopy (1987) (43)
- The photochemical synthesis of [Cr(CO)5(H2)]in solution: i.r. evidence for co-ordinated molecular dihydrogen (1985) (43)
- Infrared spectrum and photochemistry of di-iron enneacarbonyl in matrices at 20 K: evidence for the formation of Fe2(CO)8 (1971) (41)
- 15 years of Green Chemistry (2014) (41)
- Preparation of polymer–nanoparticle composite beads by a nanoparticle-stabilised suspension polymerisation (2007) (41)
- In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water (2006) (41)
- The fibre optic reflectometer: A new and simple probe for refractive index and phase separation measurements in gases, liquids and supercritical fluids (2004) (41)
- Is it Possible to Achieve Highly Selective Oxidations in Supercritical Water? Aerobic Oxidation of Methylaromatic Compounds (2004) (40)
- Synthesis and decay kinetics of tricarbonyldinitrogennickel (Ni(CO)3N2) in liquid krypton: approximate determination of the nickel-dinitrogen (Ni-N2) bond dissociation energy (1983) (40)
- Continuous Acid-Catalyzed Methylations in Supercritical Carbon Dioxide: Comparison of Methanol, Dimethyl Ether and Dimethyl Carbonate as Methylating Agents (2010) (40)
- On the role of the pore filling medium in photoluminescence from photochemically etched porous silicon (2000) (40)
- Green Chemistry in Ethiopia: the cleaner extraction of essential oils from Artemisia afra: a comparison of clean technology with conventional methodology (2005) (40)
- Densities of the carbon dioxide + hydrogen, a system of relevance to carbon capture and storage (2013) (39)
- The Effect of Self-Optimisation Targets on the Methylation of Alcohols Using Dimethyl Carbonate in Supercritical CO2 (2012) (39)
- Simultaneous continuous partial oxidation of mixed xylenes in supercritical water (2005) (39)
- Photochemical oxidative addition reactions of (.eta.5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: formation and isolation of rhodium(III) and rhodium(V) hydrides (1988) (39)
- Infrared spectrum of matrix isolated tricarbonyliron (1974) (39)
- Peroxo and dioxo metal carbonyl intermediates in the photooxidation of matrix-isolated M(CO)6 (M = Cr, Mo, W) in the presence of dioxygen: a vibrational spectroscopic study using oxygen-18 (1986) (39)
- How is hydrogen-bonding influenced by solvent density? The spectroscopic study and modeling of the interaction between a proton donor and acceptor from the gas phase to supercritical fluid states (1993) (39)
- Continuous Photo-Oxidation in a Vortex Reactor: Efficient Operations Using Air Drawn from the Laboratory (2017) (39)
- Homogeneous photochemical oxidation via singlet O2 in supercritical CO2. (2008) (38)
- Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η5-C5Me5)Ir(CO)2 and the effect on CH activation (1993) (38)
- New Directions in Inorganic and Metal‐Organic Coordination Chemistry in Supercritical Fluids (1999) (38)
- Flow Reactors for Preparative Chemistry in Supercritical Fluid Solution: "Solvent-Free" Synthesis and Isolation of Cr(CO)5(C2H4) and (.eta.5-C5H5)Mn(CO)2(.eta.2-H2) (1995) (37)
- Infrared spectroscopic study of the photochemical substitution and oxidative addition reactions of (.eta.5-C5R5)M(CO)4 compounds of group 5 metals: characterization of the products of reaction with nitrogen, hydrogen and HSiEt3-xClx and the kinetic investigation of (.eta.5-C5R5)M(CO)3 intermediates (1993) (37)
- Automated Serendipity with Self-Optimizing Continuous-Flow Reactors (2015) (37)
- Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO2 (2010) (37)
- Friedel−Crafts Alkylation of Anisole in Supercritical Carbon Dioxide: A Comparative Study of Catalysts (2005) (36)
- Complexes of iron and cobalt containing coordinated molecular dihydrogen: infrared evidence for Fe(CO)(NO)2(H2) and Co(CO)2(NO)(H2) in liquefied xenon solution (1986) (36)
- Continuous hydrogenation reactions in supercritical CO2“without gases” (2005) (36)
- High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)5 with N2 and the thermal reaction of Fe (CO)4 (N2) with H2 (1993) (35)
- Chemistry: A cleaner way to nylon? (2005) (35)
- The continuous self aldol condensation of propionaldehyde in supercritical carbon dioxide: a highly selective catalytic route to 2-methylpentenal (2009) (35)
- Magnetic circular dichroism evidence for the paramagnetism of tetracarbonyliron(0): low-temperature matrix studies (1977) (34)
- On-line monitoring of the hydrolysis of acetonitrile in near-critical water using Raman spectroscopy (2004) (34)
- Continuous Flow Hydrogenation of a Pharmaceutical Intermediate, [4-(3,4-Dichlorophenyl)-3,4-dihydro-2H-naphthalenyidene]-methylamine, in Supercritical Carbon Dioxide (2007) (34)
- Time-resolved IR characterization of cis- and trans-[LW(CO)4(solvent)] [L = PPh3, P(OCHMe2)3, and P(OEt)3] in n-heptane solution. The solvent as a token ligand in short-lived reaction intermediates (1987) (34)
- Adsorption of Pd(hfac)2 on mesoporous silica SBA-15 using supercritical CO2 and its role in the performance of Pd–SiO2 catalyst (2012) (34)
- Fast time-resolved infrared spectroscopy of organometallic intermediates; detection of [(η5-C5H5)Fe(CO)2] and [(η5-C5H5)Fe(µ-CO)3Fe(η5-C5H5)] in room-temperature solution (1984) (34)
- The supercritical fluid antisolvent synthesis of C60(C2Hx) (x=4 or 6); the crystal structures of two materials which were thought unlikely to exist. (2002) (33)
- Photochemistry of matrix-isolated HMn(CO)5: evidence for two isomers of HMn(CO)4 (1983) (33)
- Intermediates in chromium carbonyl photochemistry (1972) (33)
- II Fe(CO)4 (1978) (33)
- Preparation of hybrid polymer nanocomposite microparticles by a nanoparticle stabilised dispersion polymerisation (2008) (33)
- Catalytic selective partial oxidations using O2 in supercriticalwater: the continuous synthesis of carboxylic acids (2007) (32)
- [Cr(CO)5Xe] in solution; the first spectroscopic evidence (1983) (32)
- Infrared spectroscopy and chemistry in liquid rare-gas solvents (1988) (31)
- Synthesis of antimalarial trioxanes via continuous photo-oxidation with 1O2 in supercritical CO2 (2013) (30)
- WHY THE CARBON-OXYGEN FACTORED FORCE FIELD WORKS SO WELL (1978) (30)
- The immobilisation of phenoxaphosphine-modified xanthene-type ligand on polysiloxane support and application thereof in the hydroformylation reaction (2004) (29)
- Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide (2009) (29)
- Precipitation of Solvent-Free C60(CO2)0.95 from Conventional Solvents: A New Antisolvent Approach to Controlled Crystal Growth Using Supercritical Carbon Dioxide (2000) (28)
- A Simple and Versatile Reactor for Photochemistry (2016) (28)
- Formation of trans-M(O)2(CO)4 (M=Mo and W): intermediates in the photooxidation of matrix-isolated (M(CO)6 (1984) (28)
- Efficient H-D exchange of aromatic compounds in near-critical D2O catalysed by a polymer-supported sulphonic acid (1999) (28)
- Rapid and clean synthesis of phthalimide derivatives in high-temperature, high-pressure H2O/EtOH mixtures (2007) (28)
- Fast time-resolved FTIR detection of short-lived photochemical transient species in solution: a direct comparison with IR laser spectroscopy (1985) (28)
- The automation of continuous reactions in supercritical CO2: the acid-catalysed etherification of short chain alcohols (2005) (28)
- Acoustic Determination of the Critical Surfaces in the Ternary Systems CO2 + CH2F2 + CF3CH2F and CO + C2H4 + CH3CHCH2 and in Their Binary Subsystems (1997) (27)
- Rhodium-Catalyzed Hydroformylation of Alkenes Using in Situ High-Pressure IR and Polymer Matrix Techniques (2003) (26)
- Acoustic Determination of the Helium Content of Carbon Dioxide from He Head Pressure Cylinders and FT-IR Studies of the Density of the Resulting Supercritical CO2: Implications for Reproducibility in Supercritical Experiments (1996) (26)
- Photochemistry and photoisomerization of five- and six-coordinate d6 transition metal thiocarbonyl complexes in low-temperature matrixes (1976) (26)
- Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors (2015) (26)
- A mechanism for the photochemical conversion of FpSi2Me5 to FpSiMe3 (Fp = (.eta.5-C5H5)Fe(CO)2). Infrared evidence for an intermediate iron-silylene complex (1991) (26)
- Modelling residence time distribution in chemical reactors : A novel generalised n-laminar model Application to supercritical CO2 and subcritical water tubular reactors (2007) (25)
- Could the energy cost of using supercritical fluids be mitigated by using CO2 from carbon capture and storage (CCS) (2011) (24)
- Valorisation of lignin by depolymerisation and fractionation using supercritical fluids and conventional solvents (2017) (24)
- The catalytic oxidation of benzoic acid to phenol in high temperature water (2006) (24)
- Organometallic photochemistry in supercritical fluids: the reaction of H2 with [(η5-C5H5)M(CO)3](M Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I) (1989) (24)
- Selective aerobic oxidation of para-xylene in sub- and supercritical water. Part 2. The discovery of better catalysts (2011) (24)
- Preparation of quinolines by reduction of ortho-nitroarenes with zinc in near-critical water (1999) (24)
- The 13 Principles of Green Chemistry and Engineering for a Greener Africa (2011) (24)
- The Periodic Table of Videos (2011) (23)
- The continuous synthesis of ε-caprolactam from 6-aminocapronitrile in high-temperature water (2008) (23)
- Homogeneous biocatalysis in both fluorous biphasic and supercritical carbon dioxide systems. (2007) (23)
- Fast time-resolved IR spectroscopy: the photolysis of trans-(eta-C/sub 5/Me/sub 5/Fe(CO)/sub 2/)/sub 2/, the detection of cis-(eta-C/sub 5/Me/sub 5/Fe(CO)/sub 2/)/sub 2/, and the activation energy for cis to trans isomerization (1986) (23)
- Synthesis and Properties of Polyether Adducts of Hexafluoropentanedionatosilver(I). (1998) (23)
- Chemistry of Reactive Organometallic Compounds at Low Temperatures and High Pressures: Reactions of M(CO)6 (M = Cr, Mo, W), (η6-C6H3Me3)M(CO)3 (M = Cr and Mo), and W(CO)5CS with H2 and N2 in Polyethylene Matrices (1998) (23)
- A New Approach To Studying the Mechanism of Catalytic Reactions: An Investigation into the Photocatalytic Hydrogenation of Norbornadiene and Dimethylfumarate Using Polyethylene Matrices at Low Temperature and High Pressure (2001) (23)
- Coating carbon nanotubes with polymer in supercritical carbon dioxide. (2006) (23)
- Scalable Continuous Vortex Reactor for Gram to Kilo Scale for UV and Visible Photochemistry (2020) (22)
- The synthesis of o-cyclohexylphenol in supercritical carbon dioxide: towards a continuous two-step reaction (2007) (22)
- Selective reductions of nitroarenes to anilines using metallic zinc in near-critical water (1999) (22)
- A new route to matrix isolated iron atoms (1974) (22)
- Selective aerobic oxidation of para-xylene in sub- and supercritical water. Part 1. Comparison with ortho-xylene and the role of the catalyst (2011) (22)
- Comparison between IR absorption and raman scattering spectra of liquid and supercritical 1-butanol. (2006) (22)
- Infrared spectral evidence for the formation of the new complexes dicarbonyldinitrosylosmium and tetracarbonylcobalt in frozen gas matrices at 20 K (1973) (22)
- “Happy silver anniversary”: Green Chemistry at 25 (2016) (22)
- UN sustainable development goals: How can sustainable/green chemistry contribute? By doing things differently (2018) (21)
- Spectroscopic probes for hydrogen bonding, extraction impregnation and reaction in supercritical fluids (1993) (21)
- New experimental approach to the identification of rearrangement modes in fluxional square-pyramidal molecules. Photolysis of matrix-isolated trans-(13CO)W(CO)4CS (1976) (21)
- Hydrogen-bonding and photochemistry of organometallics in liquid xenon solution in the presence of proton donors : a low temperature infrared study of the interaction of (CF3)3COH with (C5Me5)M(CO)2L (M=Mn and Re; L=CO, N2, and H2) and with (C5Me5)V(CO)4 (1994) (21)
- Encapsulation and IR probing of cube-shaped octasilasesquioxane H8Si8O12 in carbon nanotubes. (2006) (20)
- Hydrolysis and saponification of methyl benzoates (1999) (20)
- Photochemistry of an ozone-bromine complex; the IR spectrum of matrix isolated Br2O (1987) (20)
- A laboratory-scale annular continuous flow reactor for UV photochemistry using excimer lamps for discrete wavelength excitation and its use in a wavelength study of a photodecarboxlyative cyclisation (2017) (20)
- Continuous niobium phosphate catalysed Skraup reaction for quinoline synthesis from solketal (2017) (20)
- Study of the reaction of Rh(acac)(CO)2 with alkenes in polyethylene films under high-pressure hydrogen and the Rh-catalysed hydrogenation of alkenes (2003) (20)
- IR LASER INDUCED ISOMERIZATION OF IRON TETRACARBONYL (FE(CO)4): A UNIQUE EXAMPLE OF THE JAHN-TELLER EFFECT (1984) (19)
- Determining phase boundaries and vapour/liquid critical points in supercritical fluids: a multi-technique approach (2004) (19)
- How does the critical point change during the hydrogenation of propene in supercritical carbon dioxide (2002) (19)
- Thermal Exchange Reactions of (η5-C5R5)Mn(CO)2(wL) Compounds (wL = Weakly-Bound Ligand) in Supercritical Fluid Solution and the Isolation of (η5-C5R5)Mn(CO)2(η2-H2) Using High-Pressure Flow and Semiflow Reactors (1998) (19)
- Measurement of the vapour–liquid equilibrium of binary and ternary mixtures of CO2, N2 and H2, systems which are of relevance to CCS technology (2015) (19)
- A Continuous and Clean One‐Step Synthesis of Nano‐Particulate Ce1‐xZrxO2 Solid Solutions in Near‐Critical Water. (2000) (18)
- The Continuous Acid-Catalysed Etherification of Aliphatic Alcohols Using Stoichiometric Quantities of Dialkyl Carbonates (2010) (18)
- Green Chemistry: What Is the Way Forward? (2011) (18)
- Comparative matrix isolation and time-resolved infrared studies on the photochemistry of decacarbonylmanganeserhenium and decacarbonyldirhenium: evidence for carbonyl-bridged nonacarbonylmanganeserhenium (1986) (18)
- Impact of reactor geometry on continuous hydrothermal synthesis mixing (2010) (18)
- Hexafluoropentanedionatosilver(I) complexes stabilised by multidentate N-donor ligands: Crystal structure of a charge-separated salt species soluble in supercritical carbon dioxide (1997) (17)
- Mixed carbonyl-dinitrogen compounds: synthesis and thermal stability of Cr(CO)6-x(N2)x in liquid xenon solution and low-temperature matrixes (1983) (17)
- A New Approach to Sustainability: A Moore's Law for Chemistry. (2018) (17)
- Method for locating the vapor-liquid critical point of multicomponent fluid mixtures using a shear mode piezoelectric sensor. (2005) (17)
- Understanding the solubility of water in carbon capture and storage mixtures: An FTIR spectroscopic study of H2O + CO2 + N2 ternary mixtures (2015) (17)
- Photoacoustic Calorimetry at High Pressure: A New Approach to Determination of Bond Strengths. Estimation of the M-L Bond Dissociation Energy of M(CO)5L (M = Cr, Mo; L = H2, N2) in n-Heptane Solution (1995) (17)
- Preparative-scale organometallic chemistry in supercritical fluids; isolation of [Cr(CO)5(C2H4)] as a stable solid at room temperature (1993) (16)
- A system for traceable measurement of the microwave complex permittivity of liquids at high pressures and temperatures (2009) (16)
- “Solvent-Free” Photochemical Activation of CH4, C2H4, and C2H6 by (C5Me5)Ir(CO)2 in Supercritical Fluid Solution (1996) (16)
- Polarized photochemistry and photo-orientation of pentacarbonylchromium in low-temperature matrices (1975) (16)
- Infrared spectra of trimetal dodecacarbonyl species in frozen gas matrices at 20 K (1971) (16)
- Continuous Reactions in Supercritical Water: A New Route to La2CuO4 with a High Surface Area and Enhanced Oxygen Mobility (2000) (16)
- Orientational and site selectivity in low temperature infrared laser-induced photochemistry (1977) (15)
- Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study. (2007) (15)
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- Photochemistry and photophysics of metal complexes: D.M. Roundhill, Plenum, New York, 356 pages. ISBN 0-306-44694-4 (1996) (0)
- Chemical reactions in supercritical solvents (SCFs) (2001) (0)
- Home from home (2009) (0)
- scCO2-Flow Asymmetric Hydrogenation (2006) (0)
- Viscosity-Dependent Fluorescence and Low-Temperature Photochemistry of Mesoionic 4-Phenyl-1,3,2-oxathiazolylium-5-olate. (1987) (0)
- The Structure of (2001) (0)
- Science Diplomacy in the UK, Russia and Beyond (2018) (0)
- CCDC 1051346: Experimental Crystal Structure Determination (2017) (0)
- Contribution from MARTYN POLIAKOFF, MICHAEL GEORGE and JAMES TURNER (2006) (0)
- Generation of Re2(CO)9(N2) from Re2(CO)10: Identification of Photochemical Intermediates by Matrix Isolation and Liquid-Noble-Gas Techniques. (1988) (0)
- Collaborations. Empowering green chemists in Ethiopia. (2007) (0)
- RELATIVE QUANTUM YIELDS FOR THE FORMATION AND DESTRUCTION OF PENTACARBONYL MOLYBDENUM, MO(CO)5, IN LOW TEMPERATURE MATRIXES (1977) (0)
- Efficient H—D Exchange of Aromatic Compounds in Near‐Critical D2O Catalyzed by a Polymer‐Supported Sulfonic Acid. (1999) (0)
- New intercalation compounds of C 60 with ethene and ethane (2002) (0)
- Continuous Photo-Oxidation of Fulvenes in a Continuous Flow Photoreactor using Carbon Dioxide as a Solvent (2020) (0)
- INFRARED SPECTRA AND PHOTOCHEMISTRY OF THE COMPLEX PENTACARBONYLIRON IN SOLID MATRICES AT 4 AND 20 K, EVIDENCE FOR FORMATION OF THE COMPLEX TETRACARBONYLIRON (1973) (0)
- Tunable Laser Infrared Photochemistry at Cryogenic Temperatures (1977) (0)
- A process for the production of aromatic carboxylic acids (2001) (0)
- INFRAROTSPEKTREN VON TRIMETALLDODEKACARBONYLEN (I) UND (II) IN MATRIZEN AUS GEFRORENEN GASEN BEI 20 GRAD K (1971) (0)
- The Photochemistry of Cyclopentadienyl Platinum Carbonyl Dimers: Characterization of (Pt2(μ-CO)(η5-C5R5)2) (R: H or Me) Using Matrix Isolation and Fast Time-Resolved Infrared Spectroscopy. (1988) (0)
- IR Detection and Characterization of Co(CO)2NO(η2-1-btn) and Fe(CO)2-x(NO)2(η2-1-btn)x (x = 1 or 2; 1-btn = 1-Butene) in Liquid Xenon Solution. (1987) (0)
- The Continuous Self Aldol Condensation of Propionaldehyde in Supercritical Carbon Dioxide: A Highly Selective Catalytic Route to 2‐Methylpentenal. (2009) (0)
- 1,2-Didehydroazepines from the Photolysis of Substituted Aryl Azides: Analysis of Their Chemical and Physical Properties by Time-Resolved Spectroscopic Methods. (1989) (0)
- COMBI-CLEA FOR REACTIONS IN CONTINUOUS FLOW SUPERCRITICAL CO 2 (2008) (0)
- UEBERGANGSZUSTAENDE BEI DER PHOTOLYSE VON CHROMCARBONYL (I) (1972) (0)
- Fast Time-Resolved IR Spectroscopy: The Photolysis of trans-[η-C5Me5Fe(CO)2]2, the Detection of cis-[η-C5Me5Fe(CO)2]2, and the Activation Energy for cis to trans Isomerization. (1986) (0)
- Yuri and high temperature water (2017) (0)
- Preparation of Quinolines by Reduction of ortho-Nitroarenes with Zinc in Near-Critical Water. (2010) (0)
- Organometallic Chemistry in Supercritical Fluids: The Generation and Detection of Dinitrogen and Nonclassical Dihydrogen Complexes of Group 6, 7, and 8 Transition Metals at Room Temperature. (1990) (0)
- Investigating Scale‐Up and Further Applications of DABAL‐Me3 Promoted Amide Synthesis. (2015) (0)
- Book review: Innovations in supercritical fluids: science and technology. Keith W. Hutchenson and Neil R. Foster. American Chemical Society, Washington, DC, 1995. pp. x+469, price US$125.95. ISBN 0‐8412‐3324‐1 (1998) (0)
- Chapter 9: Applications (2001) (0)
- Electronic Stability of Metal-Dihydrogen and -Polyhydrogen Complexes. (1987) (0)
- VIBRATIONAL SPECTRUM OF CHLORODIFLUOROMETHANE IN LIQUID ARGON (1982) (0)
- Consequent Capture of Strange Fish (2011) (0)
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