Martyn Poliakoff
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British chemist
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Chemistry
Why Is Martyn Poliakoff Influential?
(Suggest an Edit or Addition)According to Wikipedia, Sir Martyn Poliakoff is a British chemist, working on fundamental chemistry, and on developing environmentally acceptable processes and materials. The core themes of his work are supercritical fluids, infrared spectroscopy and lasers. He is a research professor in chemistry at the University of Nottingham. As well as carrying out research at the University of Nottingham, he is a lecturer, teaching a number of modules including green chemistry.
Martyn Poliakoff's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Valorization of Biomass: Deriving More Value from Waste (2012) (1542)
- Green chemistry: science and politics of change. (2002) (700)
- New Directions in Inorganic and Metal-Organic Coordination Chemistry in Supercritical Fluids. (1999) (498)
- Sustainable technology: Green chemistry (2007) (307)
- Chemical recycling of carbon fibre reinforced composites in nearcritical and supercritical water (2008) (258)
- Principles of green chemistry: PRODUCTIVELY (2005) (229)
- Chemical recycling of carbon fibre composites using alcohols under subcritical and supercritical conditions (2008) (227)
- Reaction engineering: The supercritical water hydrothermal synthesis of nano-particles (2006) (222)
- The 24 Principles of Green Engineering and Green Chemistry: “IMPROVEMENTS PRODUCTIVELY” (2008) (196)
- The continuous hydrothermal synthesis of nano-particulate ferrites in near critical and supercritical water (2001) (192)
- Continuous hydrothermal synthesis of inorganicmaterials in a near-critical water flow reactor; the one-step synthesisof nano-particulate Ce1 − xZrxO2(x = 0–1)solid solutions (2001) (187)
- Chemical reactions in supercritical carbon dioxide: from laboratory to commercial plantThis work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002. (2003) (186)
- Maximising opportunities in supercritical chemistry: the continuous conversion of levulinic acid to gamma-valerolactone in CO(2). (2007) (167)
- Continuous reactions in supercritical carbon dioxide: problems, solutions and possible ways forward. (2012) (166)
- Synthesis of benzimidazoles in high-temperature water (2003) (151)
- A critical look at reactions in class I and II gas-expanded liquids using CO2 and other gases (2009) (139)
- Laser Induced Processes in Molecules (1979) (134)
- 1,2-Didehydroazepines from the photolysis of substituted aryl azides: analysis of their chemical and physical properties by time-resolved spectroscopic methods (1988) (131)
- Real-time product switching using a twin catalyst system for the hydrogenation of furfural in supercritical CO2. (2010) (125)
- Vibrational Spectroscopy in Supercritical Fluids: From Analysis and Hydrogen Bonding to Polymers and Synthesis (1995) (123)
- Selective catalytic hydrogenation of organic compounds in supercritical fluids as a continuous process (1998) (121)
- A principled stance (2001) (120)
- Applying green chemistry to the photochemical route to artemisinin. (2015) (117)
- Continuous catalytic reactions in supercritical fluids (2001) (114)
- Synthesis of metal–organic frameworks by continuous flow (2014) (109)
- Structure and reactions of matrix-isolated tetracarbonyliron(0) (1975) (107)
- Self-optimizing continuous reactions in supercritical carbon dioxide. (2011) (105)
- Continuous hydrogenation of organic compounds in supercriticalfluids (1997) (93)
- How does the critical point change during a chemical reaction in supercritical fluids? A study of the hydroformylation of propene in supercritical CO(2). (2001) (93)
- A continuous and clean one-step synthesis of nano-particulate Ce1−xZrxO2 solid solutions in near-critical water (2000) (91)
- Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst (2000) (90)
- Low temperature assembly of fullerene arrays in single-walled carbon nanotubes using supercritical fluids (2004) (80)
- Cleaner continuous photo-oxidation using singlet oxygen in supercritical carbon dioxide. (2009) (78)
- Nanosecond time-resolved infrared spectroscopy: a comparative view of spectrometers and their applications in organometallic chemistry (1994) (76)
- Structure and thermal reactions of dihydrogen complexes: the IR characterization of M(CO)5(H2) (M = chromium, molybdenum, and tungsten) and cis-Cr(CO)4(H2)2 in liquid xenon solution and the formation of HD during exchange of hydrogen and deuterium (1986) (75)
- The Continuous Acid-Catalyzed Dehydration of Alcohols in Supercritical Fluids: A New Approach to the Cleaner Synthesis of Acetals, Ketals, and Ethers with High Selectivity (1999) (75)
- Remarkable Stability of (η5-C5H5)Re(CO)2L (L = n-Heptane, Xe, and Kr): A Time-Resolved Infrared Spectroscopic Study of (η5-C5H5)Re(CO)3 in Conventional and Supercritical Fluid Solution (1997) (75)
- Shedding light on organometallic reactions: the characterization of tetracarbonyliron (Fe(CO)4), a prototypical reaction intermediate (1987) (74)
- Amorphous vanadium phosphate catalysts prepared using precipitation with supercritical CO2 as an antisolvent (2002) (74)
- Controlled continuous hydrothermal synthesis of cobalt oxide (Co3O4) nanoparticles (2012) (73)
- Photolysis and spectroscopy with polarized light: key to the photochemistry of pentacarbonylchromium and related species (1978) (72)
- Organometallic chemistry in supercritical fluids. The generation and detection of dinitrogen and nonclassical dihydrogen complexes of Group 6, 7, and 8 transition metals at room temperature (1990) (70)
- Photochemistry of aryl azides: detection and characterization of a dehydroazepine by time-resolved infrared spectroscopy and flash photolysis at room temperature (1987) (69)
- Remote-controlled experiments with cloud chemistry. (2015) (69)
- The Twelve Principles of CO2 CHEMISTRY. (2015) (68)
- Supercritical fluid-mediated alumination of mesoporous silica and its beneficial effect on hydrothermal stability. (2002) (68)
- Continuous kinetic resolution catalysed by cross-linked enzyme aggregates, ‘CLEAs’, in supercritical CO2 (2006) (65)
- A versatile flow visualisation technique for quantifying mixing in a binary system: application to continuous supercritical water hydrothermal synthesis (SWHS) (2004) (64)
- Selective host-guest interaction of single-walled carbon nanotubes with functionalised fullerenes. (2004) (64)
- Synthesis and characterization of the pentacarbonylmanganese(0) radical, Mn(CO)5, in low-temperature matrixes (1981) (63)
- Synthesis of mesoporous silica hollow spheres in supercritical CO2/water systems (2006) (60)
- An IR Study of Hydrogen Bonding in Liquid and Supercritical Alcohols (2002) (60)
- Photochemistry of the group VI hexacarbonyls in low temperature matrices. Part I. The pentacarbonyls of chromium, molybdenum, and tungsten (1971) (59)
- XAS (XANES and EXAFS) Investigations of Nanoparticulate Ferrites Synthesized Continuously in Near Critical and Supercritical Water (2007) (59)
- Infrared spectra and photochemistry of the complex pentacarbonyliron in solid matrices at 4 and 20 K: evidence for formation of the complex tetracarbonyliron (1973) (58)
- Friedel–Crafts alkylation in supercritical fluids: continuous, selective and clean (1998) (58)
- Immobilised photosensitisers for continuous flow reactions of singlet oxygen in supercritical carbon dioxide (2011) (58)
- Selective partial oxidation in supercritical water: the continuous generation of terephthalic acid from para-xylene in high yield (2002) (57)
- Infrared spectroscopic studies on the photocatalytic hydrogenation of norbornadiene by Group 6 metal carbonyls. 2. The role of the diene and the characterization of (.eta.4-norbornadiene)(.eta.2-norbornadiene)M(CO)3 complexes (1990) (57)
- Infrared spectroscopic studies on the photocatalytic hydrogenation of norbornadiene by Group 6 metal carbonyls. 1. The role of H2 and the characterization of nonclassical dihydrogen complexes, (.eta.4-norbornadiene)M(CO)3(.eta.2-H2) (1990) (56)
- Real-Time Feedback Control Using Online Attenuated Total Reflection Fourier Transform Infrared (ATR FT-IR) Spectroscopy for Continuous Flow Optimization and Process Knowledge (2013) (56)
- Continuous Asymmetric Hydrogenation in Supercritical Carbon Dioxide using an Immobilised Homogeneous Catalyst (2006) (56)
- Synthesis of siliceous hollow spheres with large mesopore wall structure by supercritical CO2-in-water interface templating. (2005) (54)
- Synthesis of nanoparticulate yttrium aluminum garnet in supercritical water–ethanol mixtures (2007) (54)
- Continuous catalytic asymmetric hydrogenation in supercritical CO2 (2004) (54)
- Can Organometallic Noble Gas Compounds Be Observed in Solution at Room Temperature? A Time-Resolved Infrared (TRIR) and UV Spectroscopic Study of the Photochemistry of M(CO)6 (M = Cr, Mo, and W) in Supercritical Noble Gas and CO2 Solution (1996) (53)
- Adaptive Process Optimization for Continuous Methylation of Alcohols in Supercritical Carbon Dioxide (2011) (52)
- The Structure of [Fe(CO)4 ]-An Important New Chapter in a Long-Running Story. (2001) (52)
- Cyclopentadienylidene. A matrix isolation study exploiting photolysis with unpolarized and plane-polarized light. (1981) (51)
- Detection of Transient Organometallic Species by Fast Time-Resolved IR Spectroscopy (1986) (51)
- Phase Boundaries of CO2 + Toluene, CO2 + Acetone, and CO2 + Ethanol at High Temperatures and High Pressures (2006) (51)
- The infrared laser induced isomerization of iron tetracarbonyl. The first non-Berry pseudorotation (1977) (49)
- Selective monoprotection of 1,n-terminal Diols in supercritical carbon dioxide: a striking example of solvent tunable desymmetrization. (2005) (49)
- Large-aperture variable-volume view cell for the determination of phase-equilibria in high pressure systems and supercritical fluids (2004) (49)
- Probing Vapor/Liquid Equilibria of Near-Critical Binary Gas Mixtures by Acoustic Measurements (1996) (48)
- Photochemistry of the Group 6 hexacarbonyls in low-temperature matrixes. V. Two routes to square pyramidal matrix isolated chromium pentacarbonyl (1975) (48)
- Hydroformylation of alkenes in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes (2002) (48)
- Enabling the Scale-Up of a Key Asymmetric Hydrogenation Step in the Synthesis of an API Using Continuous Flow Solid-Supported Catalysis (2016) (47)
- Photochemical substitution reactions of dinuclear iron complex [CpFe(CO)2]2 (Cp = .eta.5-C5H5) in hydrocarbon and tetrahydrofuran solution at room temperature: a mechanistic study with time-resolved infrared spectroscopy (1992) (47)
- Organic reactions in high-temperature and supercritical water (2006) (47)
- Matrix photochemistry of metal carbonyls (1977) (47)
- Structure and reactions of octacarbonyldiiron: An IR spectroscopic study using carbon-13 monoxide, photolysis with plane-polarized light, and matrix isolation (1986) (47)
- Amorphous vanadium phosphate catalysts from supercritical antisolvent precipitation (2001) (46)
- Near-critical water, a cleaner solvent for the synthesis of a metal–organic framework (2012) (46)
- The production and formulation of silver nanoparticles using continuous hydrothermal synthesis (2013) (45)
- Electronic stability of metal-dihydrogen and -polyhydrogen complexes (1987) (45)
- Supercritical hydrogenation and acid-catalysed reactions "without gases". (2004) (44)
- Maximising the efficiency of continuous photo-oxidation with singlet oxygen in supercritical CO2 by use of fluorous biphasic catalysis. (2012) (44)
- Continuous reactions in supercritical fluids; a cleaner, more selective synthesis of thymol in supercritical CO2 (2005) (44)
- Continuous catalytic upgrading of ethanol to n-butanol and >C4 products over Cu/CeO2 catalysts in supercritical CO2 (2015) (44)
- The photochemical synthesis of [Cr(CO)5(H2)]in solution: i.r. evidence for co-ordinated molecular dihydrogen (1985) (43)
- Structure and reactivity of (.eta.5-C5H5)Mn(CO)2 in room-temperature solution. Evidence for formation of a dinuclear intermediate detected by flash photolysis and time-resolved infrared spectroscopy (1987) (43)
- 15 years of Green Chemistry (2014) (42)
- Continuous Acid-Catalyzed Methylations in Supercritical Carbon Dioxide: Comparison of Methanol, Dimethyl Ether and Dimethyl Carbonate as Methylating Agents (2010) (42)
- Infrared spectrum and photochemistry of di-iron enneacarbonyl in matrices at 20 K: evidence for the formation of Fe2(CO)8 (1971) (41)
- Green Chemistry in Ethiopia: the cleaner extraction of essential oils from Artemisia afra: a comparison of clean technology with conventional methodology (2005) (41)
- On the role of the pore filling medium in photoluminescence from photochemically etched porous silicon (2000) (41)
- The fibre optic reflectometer: A new and simple probe for refractive index and phase separation measurements in gases, liquids and supercritical fluids (2004) (41)
- In situ generation of hydrogen for continuous hydrogenation reactions in high temperature water (2006) (41)
- Preparation of polymer–nanoparticle composite beads by a nanoparticle-stabilised suspension polymerisation (2007) (41)
- Densities of the carbon dioxide + hydrogen, a system of relevance to carbon capture and storage (2013) (41)
- Is it Possible to Achieve Highly Selective Oxidations in Supercritical Water? Aerobic Oxidation of Methylaromatic Compounds (2004) (41)
- Continuous Photo-Oxidation in a Vortex Reactor: Efficient Operations Using Air Drawn from the Laboratory (2017) (40)
- Synthesis and decay kinetics of tricarbonyldinitrogennickel (Ni(CO)3N2) in liquid krypton: approximate determination of the nickel-dinitrogen (Ni-N2) bond dissociation energy (1983) (40)
- How is hydrogen-bonding influenced by solvent density? The spectroscopic study and modeling of the interaction between a proton donor and acceptor from the gas phase to supercritical fluid states (1993) (39)
- Chemistry: A cleaner way to nylon? (2005) (39)
- The Effect of Self-Optimisation Targets on the Methylation of Alcohols Using Dimethyl Carbonate in Supercritical CO2 (2012) (39)
- Homogeneous photochemical oxidation via singlet O2 in supercritical CO2. (2008) (39)
- Photochemical oxidative addition reactions of (.eta.5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: formation and isolation of rhodium(III) and rhodium(V) hydrides (1988) (39)
- Automated Serendipity with Self-Optimizing Continuous-Flow Reactors (2015) (39)
- Simultaneous continuous partial oxidation of mixed xylenes in supercritical water (2005) (39)
- Peroxo and dioxo metal carbonyl intermediates in the photooxidation of matrix-isolated M(CO)6 (M = Cr, Mo, W) in the presence of dioxygen: a vibrational spectroscopic study using oxygen-18 (1986) (39)
- Infrared spectrum of matrix isolated tricarbonyliron (1974) (39)
- Supercritical fluid impregnation of polyethylene films, a new approach to studying equilibria in matrices; the hydrogen bonding of fluoroalcohols to (η5-C5Me5)Ir(CO)2 and the effect on CH activation (1993) (38)
- Infrared spectroscopic study of the photochemical substitution and oxidative addition reactions of (.eta.5-C5R5)M(CO)4 compounds of group 5 metals: characterization of the products of reaction with nitrogen, hydrogen and HSiEt3-xClx and the kinetic investigation of (.eta.5-C5R5)M(CO)3 intermediates (1993) (37)
- Flow Reactors for Preparative Chemistry in Supercritical Fluid Solution: "Solvent-Free" Synthesis and Isolation of Cr(CO)5(C2H4) and (.eta.5-C5H5)Mn(CO)2(.eta.2-H2) (1995) (37)
- New Directions in Inorganic and Metal‐Organic Coordination Chemistry in Supercritical Fluids (1999) (37)
- Friedel−Crafts Alkylation of Anisole in Supercritical Carbon Dioxide: A Comparative Study of Catalysts (2005) (37)
- Continuous heterogeneous catalytic oxidation of primary and secondary alcohols in scCO2 (2010) (37)
- Adsorption of Pd(hfac)2 on mesoporous silica SBA-15 using supercritical CO2 and its role in the performance of Pd–SiO2 catalyst (2012) (36)
- Complexes of iron and cobalt containing coordinated molecular dihydrogen: infrared evidence for Fe(CO)(NO)2(H2) and Co(CO)2(NO)(H2) in liquefied xenon solution (1986) (36)
- The continuous self aldol condensation of propionaldehyde in supercritical carbon dioxide: a highly selective catalytic route to 2-methylpentenal (2009) (36)
- Continuous hydrogenation reactions in supercritical CO2“without gases” (2005) (36)
- High-pressure reactions in polyethylene films, a new development in matrix isolation. The photochemical reaction of Fe (CO)5 with N2 and the thermal reaction of Fe (CO)4 (N2) with H2 (1993) (35)
- Magnetic circular dichroism evidence for the paramagnetism of tetracarbonyliron(0): low-temperature matrix studies (1977) (34)
- Continuous Flow Hydrogenation of a Pharmaceutical Intermediate, [4-(3,4-Dichlorophenyl)-3,4-dihydro-2H-naphthalenyidene]-methylamine, in Supercritical Carbon Dioxide (2007) (34)
- Time-resolved IR characterization of cis- and trans-[LW(CO)4(solvent)] [L = PPh3, P(OCHMe2)3, and P(OEt)3] in n-heptane solution. The solvent as a token ligand in short-lived reaction intermediates (1987) (34)
- Fast time-resolved infrared spectroscopy of organometallic intermediates; detection of [(η5-C5H5)Fe(CO)2] and [(η5-C5H5)Fe(µ-CO)3Fe(η5-C5H5)] in room-temperature solution (1984) (34)
- On-line monitoring of the hydrolysis of acetonitrile in near-critical water using Raman spectroscopy (2004) (34)
- Preparation of hybrid polymer nanocomposite microparticles by a nanoparticle stabilised dispersion polymerisation (2008) (34)
- Intermediates in chromium carbonyl photochemistry (1972) (33)
- II Fe(CO)4 (1978) (33)
- Catalytic selective partial oxidations using O2 in supercriticalwater: the continuous synthesis of carboxylic acids (2007) (33)
- The supercritical fluid antisolvent synthesis of C60(C2Hx) (x=4 or 6); the crystal structures of two materials which were thought unlikely to exist. (2002) (33)
- Photochemistry of matrix-isolated HMn(CO)5: evidence for two isomers of HMn(CO)4 (1983) (33)
- [Cr(CO)5Xe] in solution; the first spectroscopic evidence (1983) (32)
- Infrared spectroscopy and chemistry in liquid rare-gas solvents (1988) (31)
- Synthesis of antimalarial trioxanes via continuous photo-oxidation with 1O2 in supercritical CO2 (2013) (30)
- WHY THE CARBON-OXYGEN FACTORED FORCE FIELD WORKS SO WELL (1978) (30)
- Fast time-resolved FTIR detection of short-lived photochemical transient species in solution: a direct comparison with IR laser spectroscopy (1985) (29)
- The immobilisation of phenoxaphosphine-modified xanthene-type ligand on polysiloxane support and application thereof in the hydroformylation reaction (2004) (29)
- The automation of continuous reactions in supercritical CO2: the acid-catalysed etherification of short chain alcohols (2005) (29)
- A Simple and Versatile Reactor for Photochemistry (2016) (29)
- Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide (2009) (29)
- Rapid and clean synthesis of phthalimide derivatives in high-temperature, high-pressure H2O/EtOH mixtures (2007) (28)
- Formation of trans-M(O)2(CO)4 (M=Mo and W): intermediates in the photooxidation of matrix-isolated (M(CO)6 (1984) (28)
- Precipitation of Solvent-Free C60(CO2)0.95 from Conventional Solvents: A New Antisolvent Approach to Controlled Crystal Growth Using Supercritical Carbon Dioxide (2000) (28)
- Efficient H-D exchange of aromatic compounds in near-critical D2O catalysed by a polymer-supported sulphonic acid (1999) (28)
- Acoustic Determination of the Critical Surfaces in the Ternary Systems CO2 + CH2F2 + CF3CH2F and CO + C2H4 + CH3CHCH2 and in Their Binary Subsystems (1997) (27)
- Photochemistry and photoisomerization of five- and six-coordinate d6 transition metal thiocarbonyl complexes in low-temperature matrixes (1976) (26)
- Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors (2015) (26)
- Acoustic Determination of the Helium Content of Carbon Dioxide from He Head Pressure Cylinders and FT-IR Studies of the Density of the Resulting Supercritical CO2: Implications for Reproducibility in Supercritical Experiments (1996) (26)
- Rhodium-Catalyzed Hydroformylation of Alkenes Using in Situ High-Pressure IR and Polymer Matrix Techniques (2003) (26)
- Valorisation of lignin by depolymerisation and fractionation using supercritical fluids and conventional solvents (2017) (26)
- A mechanism for the photochemical conversion of FpSi2Me5 to FpSiMe3 (Fp = (.eta.5-C5H5)Fe(CO)2). Infrared evidence for an intermediate iron-silylene complex (1991) (26)
- Modelling residence time distribution in chemical reactors : A novel generalised n-laminar model Application to supercritical CO2 and subcritical water tubular reactors (2007) (25)
- Selective aerobic oxidation of para-xylene in sub- and supercritical water. Part 2. The discovery of better catalysts (2011) (24)
- Preparation of quinolines by reduction of ortho-nitroarenes with zinc in near-critical water (1999) (24)
- The catalytic oxidation of benzoic acid to phenol in high temperature water (2006) (24)
- Could the energy cost of using supercritical fluids be mitigated by using CO2 from carbon capture and storage (CCS) (2011) (24)
- “Happy silver anniversary”: Green Chemistry at 25 (2016) (24)
- Organometallic photochemistry in supercritical fluids: the reaction of H2 with [(η5-C5H5)M(CO)3](M Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I) (1989) (24)
- The 13 Principles of Green Chemistry and Engineering for a Greener Africa (2011) (24)
- Infrared spectral evidence for the formation of the new complexes dicarbonyldinitrosylosmium and tetracarbonylcobalt in frozen gas matrices at 20 K (1973) (23)
- Coating carbon nanotubes with polymer in supercritical carbon dioxide. (2006) (23)
- The Periodic Table of Videos (2011) (23)
- The continuous synthesis of ε-caprolactam from 6-aminocapronitrile in high-temperature water (2008) (23)
- Scalable Continuous Vortex Reactor for Gram to Kilo Scale for UV and Visible Photochemistry (2020) (23)
- Synthesis and Properties of Polyether Adducts of Hexafluoropentanedionatosilver(I). (1998) (23)
- Homogeneous biocatalysis in both fluorous biphasic and supercritical carbon dioxide systems. (2007) (23)
- UN sustainable development goals: How can sustainable/green chemistry contribute? By doing things differently (2018) (23)
- Chemistry of Reactive Organometallic Compounds at Low Temperatures and High Pressures: Reactions of M(CO)6 (M = Cr, Mo, W), (η6-C6H3Me3)M(CO)3 (M = Cr and Mo), and W(CO)5CS with H2 and N2 in Polyethylene Matrices (1998) (23)
- Fast time-resolved IR spectroscopy: the photolysis of trans-(eta-C/sub 5/Me/sub 5/Fe(CO)/sub 2/)/sub 2/, the detection of cis-(eta-C/sub 5/Me/sub 5/Fe(CO)/sub 2/)/sub 2/, and the activation energy for cis to trans isomerization (1986) (23)
- A New Approach To Studying the Mechanism of Catalytic Reactions: An Investigation into the Photocatalytic Hydrogenation of Norbornadiene and Dimethylfumarate Using Polyethylene Matrices at Low Temperature and High Pressure (2001) (23)
- The synthesis of o-cyclohexylphenol in supercritical carbon dioxide: towards a continuous two-step reaction (2007) (22)
- A new route to matrix isolated iron atoms (1974) (22)
- Selective aerobic oxidation of para-xylene in sub- and supercritical water. Part 1. Comparison with ortho-xylene and the role of the catalyst (2011) (22)
- Comparison between IR absorption and raman scattering spectra of liquid and supercritical 1-butanol. (2006) (22)
- Selective reductions of nitroarenes to anilines using metallic zinc in near-critical water (1999) (22)
- New experimental approach to the identification of rearrangement modes in fluxional square-pyramidal molecules. Photolysis of matrix-isolated trans-(13CO)W(CO)4CS (1976) (21)
- Spectroscopic probes for hydrogen bonding, extraction impregnation and reaction in supercritical fluids (1993) (21)
- Measurement of the vapour–liquid equilibrium of binary and ternary mixtures of CO2, N2 and H2, systems which are of relevance to CCS technology (2015) (21)
- Hydrogen-bonding and photochemistry of organometallics in liquid xenon solution in the presence of proton donors : a low temperature infrared study of the interaction of (CF3)3COH with (C5Me5)M(CO)2L (M=Mn and Re; L=CO, N2, and H2) and with (C5Me5)V(CO)4 (1994) (21)
- Encapsulation and IR probing of cube-shaped octasilasesquioxane H8Si8O12 in carbon nanotubes. (2006) (20)
- Hydrolysis and saponification of methyl benzoates (1999) (20)
- Continuous niobium phosphate catalysed Skraup reaction for quinoline synthesis from solketal (2017) (20)
- Photochemistry of an ozone-bromine complex; the IR spectrum of matrix isolated Br2O (1987) (20)
- A laboratory-scale annular continuous flow reactor for UV photochemistry using excimer lamps for discrete wavelength excitation and its use in a wavelength study of a photodecarboxlyative cyclisation (2017) (20)
- Study of the reaction of Rh(acac)(CO)2 with alkenes in polyethylene films under high-pressure hydrogen and the Rh-catalysed hydrogenation of alkenes (2003) (20)
- IR LASER INDUCED ISOMERIZATION OF IRON TETRACARBONYL (FE(CO)4): A UNIQUE EXAMPLE OF THE JAHN-TELLER EFFECT (1984) (19)
- Thermal Exchange Reactions of (η5-C5R5)Mn(CO)2(wL) Compounds (wL = Weakly-Bound Ligand) in Supercritical Fluid Solution and the Isolation of (η5-C5R5)Mn(CO)2(η2-H2) Using High-Pressure Flow and Semiflow Reactors (1998) (19)
- How does the critical point change during the hydrogenation of propene in supercritical carbon dioxide (2002) (19)
- Determining phase boundaries and vapour/liquid critical points in supercritical fluids: a multi-technique approach (2004) (19)
- A Continuous and Clean One‐Step Synthesis of Nano‐Particulate Ce1‐xZrxO2 Solid Solutions in Near‐Critical Water. (2000) (18)
- The Continuous Acid-Catalysed Etherification of Aliphatic Alcohols Using Stoichiometric Quantities of Dialkyl Carbonates (2010) (18)
- Impact of reactor geometry on continuous hydrothermal synthesis mixing (2010) (18)
- Understanding the solubility of water in carbon capture and storage mixtures: An FTIR spectroscopic study of H2O + CO2 + N2 ternary mixtures (2015) (18)
- Comparative matrix isolation and time-resolved infrared studies on the photochemistry of decacarbonylmanganeserhenium and decacarbonyldirhenium: evidence for carbonyl-bridged nonacarbonylmanganeserhenium (1986) (18)
- A New Approach to Sustainability: A Moore's Law for Chemistry. (2018) (18)
- Green Chemistry: What Is the Way Forward? (2011) (18)
- Method for locating the vapor-liquid critical point of multicomponent fluid mixtures using a shear mode piezoelectric sensor. (2005) (17)
- Hexafluoropentanedionatosilver(I) complexes stabilised by multidentate N-donor ligands: Crystal structure of a charge-separated salt species soluble in supercritical carbon dioxide (1997) (17)
- Mixed carbonyl-dinitrogen compounds: synthesis and thermal stability of Cr(CO)6-x(N2)x in liquid xenon solution and low-temperature matrixes (1983) (17)
- Photoacoustic Calorimetry at High Pressure: A New Approach to Determination of Bond Strengths. Estimation of the M-L Bond Dissociation Energy of M(CO)5L (M = Cr, Mo; L = H2, N2) in n-Heptane Solution (1995) (17)
- Continuous N-alkylation reactions of amino alcohols using γ-Al2O3 and supercritical CO2: unexpected formation of cyclic ureas and urethanes by reaction with CO2 (2017) (16)
- Continuous Reactions in Supercritical Water: A New Route to La2CuO4 with a High Surface Area and Enhanced Oxygen Mobility (2000) (16)
- Polarized photochemistry and photo-orientation of pentacarbonylchromium in low-temperature matrices (1975) (16)
- Infrared spectra of trimetal dodecacarbonyl species in frozen gas matrices at 20 K (1971) (16)
- “Solvent-Free” Photochemical Activation of CH4, C2H4, and C2H6 by (C5Me5)Ir(CO)2 in Supercritical Fluid Solution (1996) (16)
- Preparative-scale organometallic chemistry in supercritical fluids; isolation of [Cr(CO)5(C2H4)] as a stable solid at room temperature (1993) (16)
- A system for traceable measurement of the microwave complex permittivity of liquids at high pressures and temperatures (2009) (16)
- The photochemistry of dinuclear osmium carbonyl complexes; characterisation of Os2(CO)8 using matrix isolation (1990) (15)
- Apparatus for fast time-resolved infrared dectection of reaction intermediates in the solution photochemistry of transition-metal carbonyls (1986) (15)
- Freezing out the fluxional behavior in iron pentacarbonyl and other metal carbonyls (1976) (15)
- Novel methods of instrumental analysis using supercritical fluid based systems. An overview (1991) (15)
- Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study. (2007) (15)
- Photochemical Generation of Polymer-Bound CpMn(CO)2(.eta.2-C:C) Complexes in Polyethylene Film: A Diagnostic Probe for Investigating the Unsaturation of the Polymer (1994) (15)
- Orientational and site selectivity in low temperature infrared laser-induced photochemistry (1977) (15)
- Supercritical fluids: green solvents for green chemistry? (2015) (15)
- Investigating Scale-Up and Further Applications of DABAL-Me3 Promoted Amide Synthesis (2015) (15)
- The infrared spectra of trimetal carbonyl species in frozen gas matrices at 20°K (1970) (15)
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- Photochemistry and photophysics of metal complexes: D.M. Roundhill, Plenum, New York, 356 pages. ISBN 0-306-44694-4 (1996) (0)
- VIBRATIONAL SPECTRUM OF CHLORODIFLUOROMETHANE IN LIQUID ARGON (1982) (0)
- Professor Dr Roger A. Sheldon—65 years on (2008) (0)
- High-Productivity Single-Pass Electrochemical Birch Reduction of Naphthalenes in a Continuous Flow Electrochemical Taylor Vortex Reactor (2022) (0)
- Electronic Stability of Metal-Dihydrogen and -Polyhydrogen Complexes. (1987) (0)
- CCDC 1051346: Experimental Crystal Structure Determination (2017) (0)
- Daniel Douglas Eley. 1 October 1914—3 September 2015 (2022) (0)
- Front Cover: Photooxidation of Fulvenes in a Continuous Flow Photoreactor using Carbon Dioxide as a Solvent (ChemPhotoChem 7/2018) (2018) (0)
- Old Solvents – New Solutions (0)
- Home from home (2009) (0)
- Photochemistry of Dinuclear Osmium Carbonyl Complexes; Characterization of Os2(CO)8 Using Matrix Isolation. (1990) (0)
- COMBI-CLEA FOR REACTIONS IN CONTINUOUS FLOW SUPERCRITICAL CO 2 (2008) (0)
- CYCLOPENTADIENYLIDENE. A MATRIX ISOLATION STUDY EXPLOITING PHOTOLYSIS WITH UNPOLARIZED AND PLANE-POLARIZED LIGHT (1981) (0)
- Synthesis of small metal and metal oxide particles in supercritical water. (1998) (0)
- Contribution from MARTYN POLIAKOFF, MICHAEL GEORGE and JAMES TURNER (2006) (0)
- High-pressure Methods and Equipment (2010) (0)
- Photolysis of Benzo[c]-1,2,5-thiadiazole 2-Oxide. Spectroscopic Evidence for the Reversible Formation of 2-Thionitrosonitrosobenzene. (1978) (0)
- The Structure of [Fe(CO)4] — An Important New Chapter in a Long‐Running Story (2001) (0)
- Time-Resolved IR Characterization of cis- and trans-(LW(CO)4(solvent)) (L = PPh3, P(O-i-Pr)3, and P(OEt)3) in n-Heptane Solution: The Solvent as a Token Ligand in Short-Lived Reaction Intermediates. (1987) (0)
- Collaborations. Empowering green chemists in Ethiopia. (2007) (0)
- Organic reactions in supercritical fluids: Continuous, selective, and green. (1999) (0)
- Consequent Capture of Strange Fish (2011) (0)
- SUPERCRITICAL WATER HYDROTHERMAL SYNTHESIS OF METAL OXIDE NANOPARTICLES (2004) (0)
- Investigating Scale‐Up and Further Applications of DABAL‐Me3 Promoted Amide Synthesis. (2015) (0)
- AN ENVIRONMENTAL EFFECT IN A PHOTOCHEMICAL REACTION‐ PHOTOLYSIS OF MATRIX‐ISOLATED 4‐PHENYL‐1,3,2‐OXATHIAZOLYLIO ‐OXIDE (1976) (0)
- scCO2-Flow Asymmetric Hydrogenation (2006) (0)
- Continuous Photo-Oxidation of Fulvenes in a Continuous Flow Photoreactor using Carbon Dioxide as a Solvent (2020) (0)
- Editorial: Auf YouTube für Chemie begeistern (2013) (0)
- UEBERGANGSZUSTAENDE BEI DER PHOTOLYSE VON CHROMCARBONYL (I) (1972) (0)
- IR-SPEKTRUM UND PHOTOCHEMIE VON DIEISENENNEACARBONYL IN MATRIZEN BEI 20 GRAD K, BEWEIS FUER DIE BLDG. VON DIEISENOKTACARBONYL (1971) (0)
- Visa Labyrinth (2014) (0)
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