Jaqueline Kiplinger
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American inorganic chemist
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Jaqueline Kiplingerchemistry Degrees
Chemistry
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Inorganic Chemistry
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Chemistry
Jaqueline Kiplinger's Degrees
- PhD Inorganic Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Jaqueline Kiplinger Influential?
(Suggest an Edit or Addition)According to Wikipedia, Jaqueline Kiplinger is an American inorganic chemist who specializes in organometallic actinide chemistry. Over the course of her career, she has done extensive work with fluorocarbons and actinides. She is currently a Fellow of the Materials Synthesis and Integrated Devices group in the Materials Physics and Applications Division of Los Alamos National Laboratory . Her current research interests are focused on the development of chemistry for the United States’ national defense and energy needs.
Jaqueline Kiplinger's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Activation of Carbon-Fluorine Bonds by Metal Complexes (1994) (526)
- Uranium azide photolysis results in C-H bond activation and provides evidence for a terminal uranium nitride. (2010) (164)
- Organometallic uranium(V)-imido halide complexes: from synthesis to electronic structure and bonding. (2008) (142)
- Pentavalent uranium chemistry: synthetic pursuit of a rare oxidation state. (2009) (130)
- A lanthanide phosphinidene complex: synthesis, structure, and phospha-Wittig reactivity. (2008) (114)
- Thorium(IV) and Uranium(IV) Ketimide Complexes Prepared by Nitrile Insertion into Actinide−Alkyl and −Aryl Bonds (2004) (111)
- Cation-cation interactions, magnetic communication, and reactivity of the pentavalent uranium ion [U(NtBu)2]+. (2009) (105)
- Group IV Metallocene-Mediated Synthesis of Fluoroaromatics via Selective Defluorination of Saturated Perfluorocarbons (1996) (101)
- Trends in Electronic Structure and Redox Energetics for Early-Actinide Pentamethylcyclopentadienyl Complexes (2004) (100)
- Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes. (2008) (90)
- UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry (2011) (90)
- A new mode of reactivity for pyridine N-oxide: C-H activation with uranium(IV) and thorium(IV) bis(alkyl) complexes. (2005) (90)
- Convenient Synthesis, Structure, and Reactivity of (C5Me5)U(CH2C6H5)3: A Simple Strategy for the Preparation of Monopentamethylcyclopentadienyl Uranium(IV) Complexes (2002) (85)
- Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials. (2010) (83)
- Probing the chemistry, electronic structure and redox energetics in organometallic pentavalent uranium complexes. (2008) (82)
- Systematic studies of early actinide complexes: uranium(IV) fluoroketimides. (2007) (74)
- Facile access to pentavalent uranium organometallics: one-electron oxidation of uranium(IV) imido complexes with copper(I) salts. (2007) (71)
- Synthesis, structure, spectroscopy and redox energetics of a series of uranium(IV) mixed-ligand metallocene complexes (2010) (70)
- Molecular quadrangle formation from a diuranium μ-η6,η6-toluene complex. (2011) (64)
- The First f-Element Ketimido Complex: Synthesis and Characterization of (C5Me5)2U(−NCPh2)2 (2002) (64)
- Challenging the metallocene dominance in actinide chemistry with a soft PNP pincer ligand: new uranium structures and reactivity patterns. (2009) (63)
- Actinide redox-active ligand complexes: reversible intramolecular electron-transfer in U(dpp-BIAN)2/U(dpp-BIAN)2(THF). (2010) (56)
- Triammineruthenium(II) complexes bound with the novel bridging ligand 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) (1989) (51)
- Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuCCPh (2008) (50)
- Enhancing the reactivity of uranium(VI) organoimido complexes with diazoalkanes. (2002) (50)
- Dearomatization and functionalization of terpyridine by lutetium(III) alkyl complexes. (2006) (48)
- Selective room temperature hydrogenolysis of aromatic fluorocarbons mediated by a low-valent zirconium complex (1996) (47)
- A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide (2008) (43)
- Direct comparison of the magnetic and electronic properties of samarocene and ytterbocene terpyridine complexes. (2008) (41)
- Comparative study of f-element electronic structure across a series of multimetallic actinide and lanthanoid-actinide complexes possessing redox-active bridging ligands. (2010) (41)
- [(C5Me5)2U(Me)(OTf)]2: A New Reagent for Uranium Metallocene Chemistry. Preparation of the First Actinide Hydrazonato Complexes (2002) (40)
- Noble reactions for the actinides: safe gold-based access to organouranium and azide complexes (2009) (40)
- 1,4-dicyanobenzene as a scaffold for the preparation of bimetallic actinide complexes exhibiting metal-metal communication. (2008) (38)
- Selenate and tellurate complexes of pentavalent uranium. (2009) (37)
- Molecular spectroscopy of uranium(IV) bis(ketimido) complexes. rare observation of resonance-enhanced raman scattering from organoactinide complexes and evidence for broken-symmetry excited states. (2005) (37)
- 4f-5f heterotrimetallic complexes exhibiting electrochemical and magnetic communication. (2006) (37)
- Titanium(IV) Trifluoromethyl Complexes: New Perspectives on Bonding from Organometallic Fluorocarbon Chemistry (2012) (37)
- Tuning the Oxidation State, Nuclearity, and Chemistry of Uranium Hydrides with Phenylsilane and Temperature: The Case of the Classic Uranium(III) Hydride Complex [(C5Me5)2U(μ-H)]2 (2016) (35)
- Phenylsilane as a safe, versatile alternative to hydrogen for the synthesis of actinide hydrides. (2015) (35)
- Mixed valency in a uranium multimetallic complex. (2008) (34)
- What a difference a 5f element makes: trivalent and tetravalent uranium halide complexes supported by one and two bis[2-(diisopropylphosphino)-4-methylphenyl]amido (PNP) ligands. (2009) (34)
- Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle. (2007) (32)
- Reactivity of (C5Me5)Lu(CH2SiMe3)2(THF) with Pyridine Ring Systems: Synthesis and Structural Characterization of an η2-(N,C)-Pyridyl (Mono)pentamethylcyclopentadienyl Lutetium(III) Complex (2007) (31)
- Systematic studies of early actinide complexes: thorium(IV) fluoroketimides. (2007) (31)
- Actinide-mediated cyclization of 1,2,4,5-tetracyanobenzene: synthesis and characterization of self-assembled trinuclear thorium and uranium macrocycles. (2006) (30)
- Carbon-nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(IV) complexes. (2005) (29)
- Toward actinide molecular magnetic materials: coordination polymers of U(IV) and the organic acceptors TCNQ and TCNE. (2007) (28)
- Actinide 2-metallabiphenylenes that satisfy Hückel’s rule (2020) (28)
- Thorium(IV) and Uranium(IV) Halide Complexes Supported by Bulky β-Diketiminate Ligands (2013) (28)
- Thorium-mediated ring-opening of tetrahydrofuran and the development of a new thorium starting material: preparation and chemistry of ThI4(DME)2. (2012) (27)
- Uncommon η3-(N,C,C‘)-1-Azaallyl Bonding Mode for the Nacnac Ligand: A Bis(β-diketiminato)uranium(III) Iodide Complex (2004) (27)
- Early transition-metal perfluoroalkyl complexes. (2003) (26)
- Electronic structure, excited states, and photoelectron spectra of uranium, thorium, and zirconium bis(Ketimido) complexes (C5R5)2M[-NCPh2]2 (M = Th, U, Zr; R = H, CH3). (2005) (24)
- A comparative study of the reactivity of Zr(IV), Hf(IV) and Th(IV) metallocene complexes: Thorium is not a Group IV metal after all (2007) (24)
- Organometallics Roundtable 2013–2014 (2014) (24)
- Organometallic uranium(IV) fluoride complexes: preparation using protonolysis chemistry and reactivity with trimethylsilyl reagents. (2010) (24)
- Synthesis, Characterization, and Density Functional Theory Analysis of Uranium and Thorium Complexes Containing Nitrogen-Rich 5-Methyltetrazolate Ligands. (2016) (23)
- Synthesis and characterization of a new and electronically unusual uranium metallacyclocumulene, (C 5 Me 5 ) 2 U(η 4 -1,2,3,4-PhC 4 Ph) (2017) (22)
- sp3 versus sp2 C–H bond activation chemistry of 2-picoline by Th(IV) and U(IV) metallocene complexes (2007) (22)
- Synthesis and characterization of cyanoiron(II) complexes bound to the bridging ligand tetrakis(2-pyridyl)1,4-diazine (tpd) (1990) (20)
- Synthesis, Characterization, and Reactivity of the Thermally Stable Lutetium Tris(alkyl) Complex (tBu2bpy)Lu(CH2SiMe3)3 (2008) (19)
- An Investigation of Carbon−Fluorine Bond Functionalization. Versatile Reactivity of Tungsten(II) Fluoride Carbonyl Metallacycles with Alkynes (1996) (18)
- Influence of π-Conflict on Structure and Reactivity. Comparative Study of η2-Nitriles and η2-Alkynes as Four-Electron Donor Ligands in Tungsten(II) Fluoride Carbonyl Systems (1997) (18)
- Synthesis of actinide η2-pyridyl and η2-α-picolyl complexes by carbon–hydrogen bond activation (2006) (17)
- Metal-assisted functionalization of fluorocarbons : alkyne insertion versus carbon monoxide substitution in tungsten(II) metallacycles (1993) (16)
- A rare tetranuclear thorium(IV) μ4 -oxo cluster and dinuclear thorium(IV) complex assembled by carbon-oxygen bond activation of 1,2-dimethoxyethane (DME). (2014) (15)
- Catalytic Dehydrogenation of Dimethylamine Borane by Highly Active Thorium and Uranium Metallocene Complexes (2017) (14)
- Ligand substituent effect observed for ytterbocene 4'-cyano-2,2':6',2' '-terpyridine. (2005) (14)
- Lutetium Alkyls Supported by a Dearomatized and Functionalized Terpyridine Ligand: Preparation of Fluorinated Anilide Complexes (2008) (14)
- New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide. (2016) (13)
- Synthesis and Characterization of Highly Fluorinated Tungsten(II) Metallacyclopropene Complexes. Kinetics and Mechanism of an Unprecedented η2-Vinyl Isomerization (1996) (13)
- Straightforward and efficient oxidation of tris(aryloxide) and tris(amide) uranium(III) complexes using copper(I) halide reagents (2011) (12)
- Uncovering alternate reaction pathways to access uranium(IV) mixed-ligand aryloxide–chloride and alkoxide–chloride metallocene complexes: Synthesis and molecular structures of (C5Me5)2U(O-2,6-iPr2C6H3)(Cl) and (C5Me5)2U(O–tBu)(Cl) (2011) (11)
- NEW BONDING MODE FOR CYANOACETYLENE : A TUNGSTEN(II) FLUORIDE CARBONYL COMPLEX IN WHICH CYANOACETYLENE SERVES AS A FOUR-ELECTRON DONOR ALKYNE LIGAND (1995) (11)
- Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent (2018) (10)
- Preparation of molybdenum(II) η2-vinyl complexes via sequential CCl activation and alkyne insertion (1997) (10)
- Lutetium gets a crown: Synthesis, structure and reaction chemistry of the separated ion pair complex, [Li(12-crown-4)2][(C5Me5)2LuMe2] (2011) (9)
- Carbon monoxide–phosphaalkyne coupling and C–Hactivation of an N–Me group in the4e-η2-phosphaalkyne complex[WF(C6H4CH2NMeCH2CH2NMe2)(CO)(η2-PCBut)].Crystal and molecular structure of[WF{CH2N(CH2Ph)CH2CH2NMe2}(CO){η4-PCBut(CO)CButP}] (1997) (9)
- Recent Advances in Nuclear Forensic Chemistry. (2020) (9)
- Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et) (2016) (9)
- Synthesis and Molecular Structure of (C5Me5)2U(OtBu)(SePh): A Mixed-Ligand Alkoxide-Selenide Uranium(IV) Metallocene Complex Resulting from tert-Butoxy-Trimethylsilane Elimination (2011) (9)
- Synthesis, characterization, and reactivity of the first uranium metallocene 1,2-bis(diphenylphosphino)acetylene complexes (2018) (8)
- Ultrafast spectroscopy of the uranium(IV) and thorium(IV) bis(ketimide) complexes (C5Me5)2An[-N=C(Ph)(CH2Ph)]2 (An = Th, U). (2008) (8)
- Ca(BH 4 ) 2 as a simple tool for the preparation of thorium and uranium metallocene borohydride complexes: First synthesis and crystal structure of (C 5 Me 5 ) 2 Th( η 3 -H 3 BH) 2 (2017) (7)
- Synthesis and reactivity of tungsten(II) carbonyl η2-nitrile complexes: crystal structure of tetrafluoroterephthalonitrile as a four-electron donor ligand (1996) (7)
- Syntheses, structures, and (1)H, (13)C{(1)H} and (119)Sn{(1)H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds. (2015) (7)
- Actinide complexes with the Kläui tripodal oxygen ligand – crystal structure of [{η4-C5H5(CH2C(CH3)3)}Co{P(O)(OC2H5)2}3]2U (2005) (6)
- Revisiting the bis(dimethylamido) metallocene complexes of thorium and uranium: improved syntheses, structure, spectroscopy, and redox energetics of (C5Me5)2An(NMe2)2 (An = Th, U). (2017) (6)
- A New Actinide Bis(Ketimide) Platform for the Construction of Multimetallic Complexes: Synthesis and Crystal Structure of (C5Me5)2Th[-N=C(C6H5)(2,2′:6′,2″-terpyridine)]2 (2011) (5)
- Enhancing the synthetic efficacy of thorium tetrachloride bis(1,2-dimethoxyethane) with added 1,2-dimethoxyethane: Preparation of metallocene thorium dichlorides (2014) (4)
- Lutetium functionalities supported by a sterically encumbered β-diketiminate ligand (2018) (4)
- A sulphur and uranium fiesta! Synthesis, structure, and characterization of neutral terminal uranium(vi) monosulphide, uranium(vi) η2-disulphide, and uranium(iv) phosphine sulphide complexes. (2018) (4)
- Low-spin 1,1'-diphosphametallocenates of chromium and iron. (2020) (3)
- The Synthesis of Poly-Nitrile Aromatic and Oligopyridine Ligands Via Palladium-Catalyzed Cyanation of Aryl Halides (2005) (3)
- Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azido Complexes (Eur. J. Inorg. Chem. 11/2009) (2009) (1)
- Exploiting the reactivity of actinide fluoride bonds for the synthesis and characterization of a new class of monometallic bis(azide) uranium complexes (2017) (1)
- Triammineruthenium(II) Complexes Bound with the Novel Bridging Ligand 2,3,5,6-Tetrakis(2-pyridyl)pyrazine (tppz). (1989) (1)
- Pentafluorophenyl)Cyclopentadiene and its Sodium Salt (2014) (1)
- What a difference a 5f element makes: trivalent and tetravalent uranium halide complexes supported by one and two PNP ligands (2008) (0)
- A Sterically Biased Unsymmetrical Azobenzene Derivative: Synthesis, Molecular Structure, and 15N NMR Spectroscopic Analysis of (E)-1-(2,6-Diisopropylphenyl)-2-phenyldiazine (2017) (0)
- Pentavalent Uranium Chemistry—Synthetic Pursuit of a Rare Oxidation State (2009) (0)
- STABILIZATION OF URANIUM METAL BY CHLORIDE CONVERSION-ECONOMICAL, SAFE, SCALABLE (2020) (0)
- Electrochemical and magnetic studies of metal-metal interactions in actinide and mixed f-element complexes (2008) (0)
- Cover Picture: 1,4‐Dicyanobenzene as a Scaffold for the Preparation of Bimetallic Actinide Complexes Exhibiting Metal–Metal Communication (Chem. Eur. J. 26/2008) (2008) (0)
- Selective Room Temperature Hydrogenolysis of Aromatic Fluorocarbons Mediated by a Low-Valent Zirconium Complex. (1996) (0)
- The Synthesis of Polynitrile Aromatic and Oligopyridine Ligands via Palladium-Catalyzed Cyanation of Aryl Halides. (2006) (0)
- Neutral Uranium(VI) Sulfido Compound Isolated and Characterized for the First Time (2019) (0)
- Inside Cover: Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns (Angew. Chem. Int. Ed. 20/2009) (2009) (0)
- Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE) (2008) (0)
- Synthesis and characterization of cyanoiron(II) complexes bound to the bridging ligand tetrakis(2-pyridyl)-1,4-diazine (tpd) [Erratum to document cited in CA113(22):203865k] (1991) (0)
- Molecular spectroscopy of actinide-ketimido complexes (2004) (0)
- Actinide 2-metallabiphenylenes that satisfy Hückel’s rule (2020) (0)
- Neutron radiography through a SIFaN instrument (2021) (0)
- Innentitelbild: Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns (Angew. Chem. 20/2009) (2009) (0)
- Adventures in Actinide Chemistry: A Synthetic Journey at Los Alamos National Laboratory (2018) (0)
- Front Cover: Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent (Eur. J. Inorg. Chem. 11/2018) (2018) (0)
- Life and Mentoring at Los Alamos National Laboratory (2018) (0)
- Organometallic lanthanide and actinide complexes (2018) (0)
- Transforming the Uranium Fuel Cycle: Safe & Economical Conversion of DUF6 to DUF4 (2019) (0)
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