Keith Fagnou
#101,206
Most Influential Person Now
Canadian chemist
Keith Fagnou's AcademicInfluence.com Rankings
Download Badge
Chemistry
Why Is Keith Fagnou Influential?
(Suggest an Edit or Addition)According to Wikipedia, Keith Fagnou was a Canadian organic chemist and studied education and was a professor of chemistry at University of Saskatchewan and associate professor of organic chemistry at the University of Ottawa. His research focused on developing new reactions that avoid unnecessary activation of substrates and that can instead directly functionalize C–H bonds of simple molecules and introduce C–C bonds.
Keith Fagnou's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Overview of the Mechanistic Work on the Concerted Metallation-Deprotonation Pathway (2010) (820)
- Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds. (2003) (797)
- The Catalytic Cross-Coupling of Unactivated Arenes (2007) (756)
- Palladium-catalyzed benzene arylation: incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design. (2006) (741)
- Rhodium(III)-catalyzed heterocycle synthesis using an internal oxidant: improved reactivity and mechanistic studies. (2011) (735)
- Analysis of the concerted metalation-deprotonation mechanism in palladium-catalyzed direct arylation across a broad range of aromatic substrates. (2008) (729)
- Catalytic intermolecular direct arylation of perfluorobenzenes. (2006) (616)
- Rhodium(III)-catalyzed isoquinolone synthesis: the N-O bond as a handle for C-N bond formation and catalyst turnover. (2010) (590)
- Indole synthesis via rhodium catalyzed oxidative coupling of acetanilides and internal alkynes. (2008) (579)
- Rhodium(III)-catalyzed arene and alkene C-H bond functionalization leading to indoles and pyrroles. (2010) (541)
- Catalytic direct arylation with aryl chlorides, bromides, and iodides: intramolecular studies leading to new intermolecular reactions. (2006) (500)
- Elements of regiocontrol in palladium-catalyzed oxidative arene cross-coupling. (2007) (459)
- Establishment of broadly applicable reaction conditions for the palladium-catalyzed direct arylation of heteroatom-containing aromatic compounds. (2009) (446)
- Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules. (2006) (406)
- A solution to the 2-pyridyl organometallic cross-coupling problem: regioselective catalytic direct arylation of pyridine N-oxides. (2005) (404)
- Isoquinoline synthesis via rhodium-catalyzed oxidative cross-coupling/cyclization of aryl aldimines and alkynes. (2009) (372)
- Analysis of the palladium-catalyzed (aromatic)C-H bond metalation-deprotonation mechanism spanning the entire spectrum of arenes. (2012) (336)
- Palladium-catalyzed direct arylation of azine and azole N-oxides: reaction development, scope and applications in synthesis. (2009) (336)
- The vinyl moiety as a handle for regiocontrol in the preparation of unsymmetrical 2,3-aliphatic-substituted indoles and pyrroles. (2011) (298)
- Intramolecular Pd(II)-catalyzed oxidative biaryl synthesis under air: reaction development and scope. (2008) (294)
- Transition metal-catalyzed enantioselective ring-opening reactions of oxabicyclic alkenes. (2003) (282)
- Halide effects in transition metal catalysis. (2002) (281)
- High-yielding palladium-catalyzed intramolecular alkane arylation: reaction development and mechanistic studies. (2007) (280)
- Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials (2011) (276)
- Rhodium(III)-catalyzed intermolecular hydroarylation of alkynes. (2010) (267)
- Site-selective sp2 and benzylic sp3 palladium-catalyzed direct arylation. (2008) (263)
- Ruthenium-catalyzed dehydrogenation of ammonia boranes. (2008) (257)
- Modulating reactivity and diverting selectivity in palladium-catalyzed heteroaromatic direct arylation through the use of a chloride activating/blocking group. (2010) (248)
- Direct arylation reactions catalyzed by Pd(OH)2/C: evidence for a soluble palladium catalyst. (2005) (234)
- C2, C5, and C4 azole N-oxide direct arylation including room-temperature reactions. (2008) (220)
- Investigation of the mechanism of C(sp3)-H bond cleavage in Pd(0)-catalyzed intramolecular alkane arylation adjacent to amides and sulfonamides. (2010) (213)
- Biaryl synthesis via direct arylation: establishment of an efficient catalyst for intramolecular processes. (2004) (205)
- Palladium-catalyzed cross-coupling reactions of diazine N-oxides with aryl chlorides, bromides, and iodides. (2006) (199)
- Mechanistic analysis of azine N-oxide direct arylation: evidence for a critical role of acetate in the Pd(OAc)2 precatalyst. (2010) (180)
- High-yielding intramolecular direct arylation reactions with aryl chlorides. (2005) (169)
- Intramolecular palladium-catalyzed alkane C-H arylation from aryl chlorides. (2010) (169)
- Applications of and alternatives to pi-electron-deficient azine organometallics in metal catalyzed cross-coupling reactions. (2007) (166)
- Mild and general conditions for the cross-coupling of aryl halides with pentafluorobenzene and other perfluoroaromatics. (2006) (161)
- Room-temperature direct arylation of polyfluorinated arenes under biphasic conditions. (2010) (160)
- Predictable and site-selective functionalization of poly(hetero)arene compounds by palladium catalysis. (2011) (135)
- Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids. (2002) (134)
- Rhodium-catalyzed coupling reactions of arylboronic acids to olefins in aqueous media. (2001) (134)
- Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: application of halide effects in the development of a general process. (2003) (126)
- Mild and efficient palladium-catalyzed intramolecular direct arylation reactions (2008) (116)
- Mechanistic considerations in the development and use of azine, diazine and azole N-oxides in palladium-catalyzed direct arylation. (2010) (115)
- Site-selective azaindole arylation at the azine and azole rings via N-oxide activation. (2009) (113)
- Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides. (2008) (108)
- Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air (2008) (100)
- Domino palladium-catalyzed Heck-intermolecular direct arylation reactions. (2009) (99)
- Allocolchicinoid synthesis via direct arylation. (2005) (96)
- Palladium-catalyzed benzylation of heterocyclic aromatic compounds. (2009) (92)
- Catalyst and base controlled site-selective sp2 and sp3 direct arylation of azine N-oxides (2009) (88)
- Direct arylation of azine N-oxides with aryl triflates. (2009) (77)
- Effects of halide ligands and protic additives on enantioselectivity and reactivity in rhodium-catalyzed asymmetric ring-opening reactions. (2001) (76)
- Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: catalyst and substrate studies leading to a mechanistic working model. (2004) (76)
- An expedient enantioselective route to diaminotetralins: application in the preparation of analgesic compounds. (2002) (74)
- Evaluation of Electron‐Deficient Phosphine Ligands for Direct Arylation of Heterocycles (2010) (69)
- Palladium(0)-catalyzed cyclopropane C–H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives (2012) (69)
- Decarboxylative ketone aldol reactions: development and mechanistic evaluation under metal-free conditions. (2009) (59)
- Heck, direct arylation, and hydrogenation: two or three sequential reactions from a single catalyst. (2006) (55)
- Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles (2001) (53)
- Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles (2001) (51)
- Aporphine alkaloid synthesis and diversification via direct arylation (2007) (45)
- Direct intramolecular arylation of unactivated arenes: application to the synthesis of aporphine alkaloids. (2004) (42)
- Kinetic resolution of quaternary and tertiary beta-hydroxy esters. (2009) (18)
- The Discovery and Development of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of Two Unactivated Arenes (2012) (16)
- The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3‐Aliphatic‐Substituted Indoles and Pyrroles. (2011) (13)
- Transition Metal Catalyzed Enantioselective Ring-Opening Reactions of Oxabicyclic Alkenes (2003) (12)
- The Catalytic Cross‐Coupling of Unactivated Arenes. (2007) (11)
- Applications of and Alternatives to π-Electron-Deficient Azine Organometallics in Metal-Catalyzed Cross-Coupling Reactions (2007) (8)
- Intramolecular Pd(II)‐Catalyzed Oxidative Biaryl Synthesis under Air: Reaction Development and Scope. (2008) (7)
- Investigation of the Mechanism of C(sp3)—H Bond Cleavage in Pd(0)‐Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides. (2011) (6)
- Rhodium‐Catalyzed Nucleophilic Ring Cleaving Reactions of Allylic Ethers and Amines (2005) (5)
- Rhodium‐Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon—Heteroatom Bond Forming Process. (2000) (5)
- Palladium‐Catalyzed Cross‐Coupling Reactions of Diazine N‐Oxides with Aryl Chlorides, Bromides, and Iodides. (2007) (4)
- Synthesis of 2‐Aryl Pyridines by Palladium‐Catalyzed Direct Arylation of Pyridine N‐Oxides (2012) (4)
- Site-Selective sp 2 and Benzylic sp 3 Palladium-Catalyzed Direct Arylation (2008) (4)
- The Negishi Cross-Coupling Reaction (2010) (3)
- Domino Palladium‐Catalyzed Heck‐Intermolecular Direct Arylation Reactions. (2010) (3)
- Intramolecular Palladium‐Catalyzed Alkane C—H Arylation from Aryl Chlorides. (2011) (3)
- C–H Functionalization: A New Strategy for the Synthesis of Biologically Active Natural Products (2012) (2)
- Palladium(0)-Catalyzed Cyclopropane C—H Bond Functionalization: Synthesis of Quinoline and Tetrahydroquinoline Derivatives. (2012) (2)
- Rhodium‐Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles. (2001) (2)
- Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Phenols. (2000) (2)
- Aporphine Alkaloid Synthesis and Diversification via Direct Arylation. (2007) (2)
- High‐Yielding Palladium‐Catalyzed Intramolecular Alkane Arylation: Reaction Development and Mechanistic Studies. (2008) (2)
- Palladium‐Catalyzed Direct Arylation of Nitro‐Substituted Aromatics with Aryl Halides. (2009) (2)
- Halide Effects in Transition Metal Catalysis (2002) (1)
- Evaluation of Electron-Deficient Phosphine Ligands for Direct Arylation of Heterocycles. (2011) (1)
- Catalyst and Base Controlled Site-Selective sp2 and sp3 Direct Arylation of Azine N-Oxides. (2009) (1)
- Overview of the Mechanistic Work on the Concerted Metallation—Deprotonation Pathway (2011) (1)
- Effects of Halide Ligands and Protic Additives on Enantioselectivity and Reactivity in Rhodium‐Catalyzed Asymmetric Ring‐Opening Reactions. (2001) (1)
- Reactivity of mesoporous palladium yttria- stablilized zirconia for solution phase reactions (2006) (1)
- Indole Synthesis via Rhodium‐Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes. (2009) (1)
- Heterocycles from Transition Metal Catalysis: Formation and Functionalization. Catalysis by Metal Complexes, Volume 28 (2006) (1)
- Synthesis of Paullone (2011) (1)
- Rhodium‐Catalyzed Carbon—Carbon Bond Forming Reactions of Organometallic Compounds (2003) (1)
- Site‐Selective Azaindole Arylation at the Azine and Azole Rings via N‐Oxide Activation. (2009) (1)
- Palladium-Catalyzed Domino/Cascade Reactions Involving Direct Arylation (2010) (0)
- Using Organotin Reagents (2010) (0)
- Stille Cross-Coupling Reaction (2010) (0)
- Without Directing Groups (2010) (0)
- Synthesis of Hindered Biaryls Using the Kumada–Corriu Cross-Coupling Reaction (2010) (0)
- (1R*,2R*)-2-(Methylphenylamino)-1,2-dihydronaphthalen-1-ol–water (4/1) (2002) (0)
- Aryl Bromides in Suzuki Cross-Coupling Reactions (2010) (0)
- Palladium-Catalyzed Direct Arylation of Simple Arenes in Synthesis of Biaryl Molecules (2006) (0)
- Elements of Regiocontrol in Palladium‐Catalyzed Oxidative Arene Cross‐Coupling. (2008) (0)
- In the Presence of Directing Groups (2010) (0)
- Intermolecular Direct Arylation (2010) (0)
- Isoquinoline Synthesis via Rhodium‐Catalyzed Oxidative Cross‐Coupling/Cyclization of Aryl Aldimines and Alkynes. (2010) (0)
- Rhodium catalysed asymmetric ring opening of oxabicyclic alkenes and diastereoselective ring opening of epoxides with heteroatom nucleophiles (2000) (0)
- Rhodium-Catalyzed Ring Opening of Vinyl Epoxides with Alcohols and Aromatic Amines. (2000) (0)
- Aryl Chlorides in Stille Cross-Coupling Reactions (2010) (0)
- Bis(acetonitrile)(η4‐1,5‐cyclooctadiene) Rhodium(I) Tetrafluoroborate (2008) (0)
- Direct Arylation of Azine N‐Oxides with Aryl Triflates. (2009) (0)
- The Kumada–Corriu Cross-Coupling Reaction (2010) (0)
- Palladium‐Catalyzed Benzylation of Heterocyclic Aromatic Compounds. (2010) (0)
- Mild and Efficient Palladium‐Catalyzed Intramolecular Direct Arylation Reactions. (2008) (0)
- Synthesis of Oligoaromatics Using the Kumada–Corriu Coupling Reaction (2010) (0)
- Synthesis of Indoles via Oxidative Coupling of Acetanilideswith Acetylenes (2009) (0)
- The Ullmann Reaction (2010) (0)
- Benzenesulfonyl(1-hydroxy-1,2-dihydronaphthalen-2-yl)acetonitrile (2002) (0)
- Using Alkyl Halides (2010) (0)
- Synthesis of Oligoaromatics Using the Hiyama Cross-Coupling Reaction (2010) (0)
- Aryl Chlorides in Suzuki Cross-Coupling Reactions (2010) (0)
- Kumada Cross-Coupling Reaction (2010) (0)
- Synthesis of Product Class 14 (2010) (0)
- Aryl Iodides in Hiyama Cross-Coupling Reactions (2010) (0)
- Aryl Chlorides in Kumada–Corriu Cross-Coupling Reactions (2010) (0)
- (1R,2R,5R,6S)-5,6-Bis(4-methoxybenzyloxymethyl)-2-(methylphenylamino)cyclohex-3-enyl 4-bromobenzoate (2002) (0)
- Pd-Catalyzed ortho-Arylation of Nitroaromaticswith Aryl Halides (2009) (0)
- (1R,2R)‐2‐(2‐Bromophenoxy)‐1,2‐dihydronaphthalen‐1‐ol (2002) (0)
- Aryl Chlorides in Negishi Cross-Coupling Reactions (2010) (0)
- Aryl Bromides in Negishi Cross-Coupling Reactions (2010) (0)
- Friedel–Crafts Alkylation (2010) (0)
- Aryl 4-Toluenesulfonates and Trifluoromethanesulfonates in Suzuki Cross-Coupling Reactions (2010) (0)
- Aryl Chlorides in Hiyama Cross-Coupling Reactions (2010) (0)
- Synthesis of Hindered Biaryls Using the Negishi Cross-Coupling Reaction (2010) (0)
- Aryl Iodides in Stille Cross-Coupling Reactions (2010) (0)
- Asymmetric Friedel–Crafts Alkylation (2010) (0)
- Hiyama Cross-Coupling Reaction (2010) (0)
- Hidronaftalenicos new compounds prepared by a reaction opening rhodium catalyzed in the presence of a phosphine ligand ring. (2000) (0)
- Rhodium(III)‐Catalyzed Intermolecular Hydroarylation of Alkynes. (2010) (0)
- Aryl Bromides in Stille Cross-Coupling Reactions (2010) (0)
- Aryl Bromides in Hiyama Cross-Coupling Reactions (2010) (0)
- Aryl Iodides in Negishi Cross-Coupling Reactions (2010) (0)
- Synthesis Using Copper Catalysis (2010) (0)
- Product Class 13 : (2009) (0)
- Using Boronic Acids (2010) (0)
- Pd(II)-Catalyzed Direct Benzylation of Heteroarenes (2009) (0)
- Diazonium Salts in Suzuki Cross-Coupling Reactions (2010) (0)
- Alkylation of Aromatic Ketones with Alkenes by C—H Activation (2010) (0)
- Aryl Iodides in Suzuki Cross-Coupling Reactions (2010) (0)
- The Stille Cross-Coupling Reaction (2010) (0)
- Mechanisms Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation (2011) (0)
- Alkylation via Transition-Metal-Catalyzed Cross-Coupling Reactions with Alkyl Electrophiles (2010) (0)
- The Suzuki Cross-Coupling Reaction (2010) (0)
- Aryl Trifluoromethanesulfonates in Negishi Cross-Coupling Reactions (2010) (0)
- C1SC00458A 244..248 (2011) (0)
- Palladium-Catalyzed Intramolecular Coupling of Arenes and Unactivated Alkanes in Air. (2009) (0)
- Aryl Trifluoromethanesulfonates and Arenesulfonates in Kumada–Corriu Cross-Coupling Reactions (2010) (0)
- Cross-Coupling Reactions of Diazine N -Oxides with Aryl Halides (2007) (0)
- Monocyclic arenes, quasiarenes, and annulenes (2010) (0)
- Rhodium‐Catalyzed Asymmetric Ring Opening Reactions of Oxabicyclic Alkenes: Application of Halide Effects in the Development of a General Process. (2004) (0)
- Rhodium-Catalyzed Synthesis of Isoquinolones (2010) (0)
This paper list is powered by the following services:
Other Resources About Keith Fagnou
What Schools Are Affiliated With Keith Fagnou?
Keith Fagnou is affiliated with the following schools:
