Robert G. Bergman
#44,843
Most Influential Person
American chemist
Why Is Robert G. Bergman Influential?
(Suggest an Edit or Addition)Robert Bergman is the Gerald E. K. Branch Professor of Chemistry at the University of California, Berkeley and a researcher at the Lawrence Berkeley National Laboratory. He earned a bachelor’s degree in chemistry from Carleton College and a Ph.D. from the University of Wisconsin at Madison. He completed his post-doctoral research at Columbia University.
Bergman’s work in organic chemistry has yielded important insights into the thermal cyclization of cis-1, 5-hexadiyne-3-ene to 4, 4-dehydrobenzene diradicals – a process which is now known as Bergman cyclization. He has also studied the synthesis of organometallic compounds and their reactions to transition metals such as metal-oxygen and metal-nitrogen.
Bergman’s work began gaining attention and recognition before he even graduated, receiving a Camille and Henry Dreyfus Foundation Teacher-Scholar Award. He has received a number of awards for his work, including the American Chemical Society’s Award in Organometallic Chemistry, the Arthur C. Cope Award, a National Institutes of Health Merit Award, the James Flack Norris Award in Physical Organic Chemistry and a Wolf Prize in Chemistry.
He is a member of the National Academy of Sciences, the American Academy of Arts and Sciences, the California Academy of Sciences and the American Association for the Advancement of Science.
Featured in Top Influential Chemists Today
According to Wikipedia, Robert George Bergman is an American chemist. He is Professor of the Graduate School and Gerald E. K. Branch Distinguished Professor Emeritus at the University of California, Berkeley. Early life and education Born in Chicago, Robert Bergman was the son of Joseph J. and Stella Bergman, née Horowitz. In 1963 he graduated from Carleton College with a degree in chemistry. Under the supervision of Jerome A. Berson, he received a PhD in 1966 from the University of Wisconsin-Madison. From 1966 to 1967 he was a NATO postdoctoral fellow at Ronald Breslow's laboratory at Columbia University, New York City.
Robert G. Bergman's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation. (2010) (2965)
- Rhodium catalyzed chelation-assisted C-H bond functionalization reactions. (2012) (1147)
- Organometallic chemistry: C–H activation (2007) (940)
- Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution (1995) (883)
- Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation. (2008) (763)
- Supramolecular catalysis in metal-ligand cluster hosts. (2015) (744)
- Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. (2004) (737)
- Acid Catalysis in Basic Solution: A Supramolecular Host Promotes Orthoformate Hydrolysis (2007) (571)
- Reactive 1,4-dehydroaromatics (1973) (507)
- Proton-mediated chemistry and catalysis in a self-assembled supramolecular host. (2009) (493)
- p-Benzyne. Generation as an intermediate in a thermal isomerization reaction and trapping evidence for the 1,4-benzenediyl structure (1972) (459)
- Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H) (1982) (413)
- Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation. (2008) (318)
- Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers. (2010) (309)
- Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2 (1992) (282)
- Mechanistic investigation of the staudinger ligation. (2005) (281)
- A supramolecular microenvironment strategy for transition metal catalysis (2015) (264)
- Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation. (2010) (263)
- A supramolecular approach to combining enzymatic and transition metal catalysis (2013) (261)
- Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups (1983) (258)
- Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization. (2011) (252)
- Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates. (2011) (251)
- Rh(I)-catalyzed direct arylation of pyridines and quinolines. (2008) (248)
- Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture (2013) (247)
- Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation. (2011) (244)
- Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes (1988) (239)
- Safe Preparation and Purification of Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF24): Reliable and Sensitive Analysis of Water in Solutions of Fluorinated Tetraarylborates (2005) (237)
- Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation. (2007) (230)
- Unusually Mild and Selective Hydrocarbon C-H Bond Activation with Positively Charged Iridium(III) Complexes (1995) (218)
- Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host. (2004) (214)
- Activation of Alkanes with Organotransition Metal Complexes (1984) (211)
- Imidotitanium complexes as hydroamination catalysts: substantially enhanced reactivity from an unexpected cyclopentadienide/amide ligand exchange. (2001) (208)
- Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation. (2004) (200)
- Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base. (2003) (197)
- Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives. (2014) (184)
- Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight. (2008) (179)
- Formation, reactivity, and properties of nondative late transition metal-oxygen and -nitrogen bonds. (2002) (179)
- Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts. (2018) (179)
- Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly. (2009) (173)
- Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host. (2011) (171)
- Highly selective supramolecular catalyzed allylic alcohol isomerization. (2007) (170)
- Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency. (2005) (169)
- The Mechanism of a C-H Bond Activation Reaction in Room-Temperature Alkane Solution (1997) (168)
- Molecular recognition and stabilization of iminium ions in water. (2006) (166)
- Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation. (2005) (157)
- Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade. (2013) (156)
- Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization. (2004) (155)
- KINETIC EVIDENCE FOR THE FORMATION OF DISCRETE 1,4-DEHYDROBENZENE INTERMEDIATES. TRAPPING BY INTER- AND INTRAMOLECULAR HYDROGEN ATOM TRANSFER AND OBSERVATION OF HIGH-TEMPERATURE CIDNP (1981) (154)
- Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination. (2006) (150)
- Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates. (2013) (149)
- Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate. (2012) (149)
- Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst. (2001) (147)
- Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf) (1993) (146)
- Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles. (2013) (145)
- Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivity (1993) (143)
- Use of group 4 bis(sulfonamido) complexes in the intramolecular hydroamination of alkynes and allenes. (2003) (139)
- Monomeric (pentamethylcyclopentadienyl)iridium imido compounds : synthesis, structure, and reactivity (1991) (138)
- A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium (1986) (138)
- Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates. (2009) (136)
- Selective C-H bond activation by a supramolecular host-guest assembly. (2004) (135)
- Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent. (2010) (134)
- Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole. (2002) (132)
- Iridium-catalyzed H/D exchange into organic compounds in water. (2002) (132)
- 2,3-Di-propyl-1,4-dehydrobenzene (1980) (131)
- Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights. (2006) (129)
- Isomerization of the hydridoalkylrhodium complexes formed on oxidative addition of rhodium to alkane carbon-hydrogen bonds. Evidence for the intermediacy of .eta.2-alkane complexes (1986) (128)
- Selective transformations of organic compounds by imidozirconocene complexes. (2002) (126)
- Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature (1993) (126)
- Stabilization of reactive organometallic intermediates inside a self-assembled nanoscale host. (2006) (125)
- Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water. (2008) (125)
- Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenylphosphine)nickel. A cis insertion that leads to trans kinetic products (1981) (125)
- Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). (2006) (125)
- Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization. (2012) (121)
- NMR Shifts, Orbitals, and M···H−X Bonding in d8 Square Planar Metal Complexes (2006) (121)
- Reactivity of a Terminal Ti(IV) Imido Complex toward Alkenes and Alkynes: Cycloaddition vs C−H Activation (1998) (119)
- Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds. (2007) (117)
- Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly. (2004) (115)
- Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions. (2001) (115)
- Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme". (2008) (114)
- Parallel reaction pathways in the cobalt-catalyzed cyclotrimerization of acetylenes (1977) (113)
- Synthesis of .eta.1 oxygen-bound rhodium enolates. Applications to catalytic aldol chemistry (1989) (113)
- Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst. (2012) (113)
- Evidence for the reactive spin state of 1,4-dehydrobenzenes (1981) (111)
- Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex. (2006) (110)
- Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism. (2006) (109)
- Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation. (2002) (109)
- Stoichiometric and catalytic H/D incorporation by cationic iridium complexes: a common monohydrido-iridium intermediate. (2004) (108)
- Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation. (2006) (105)
- The mechanism of hydroamination of allenes, alkynes, and alkenes catalyzed by cyclopentadienyltitanium-imido complexes: a density functional study. (2001) (104)
- Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation. (2006) (103)
- Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascade. (2012) (101)
- Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation. (2008) (100)
- Synthesis and Properties of Seven Ionic Liquids Containing 1-Methyl-3-octylimidazolium or 1-Butyl-4-methylpyridinium Cations (2006) (100)
- Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. (2002) (98)
- Synthesis and reactions of (.eta.5-cyclopentadienyl)tricarbonylhydridovanadate. A comparative mechanistic study of its organic halide reduction reactions with those of tri-n-butyltin hydride (1978) (98)
- High-turnover supramolecular catalysis by a protected ruthenium(II) complex in aqueous solution. (2011) (98)
- Cp*MoO2Cl-catalyzed epoxidation of olefins by alkyl hydroperoxides (1991) (97)
- An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation. (2009) (96)
- A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. (2003) (96)
- A Mechanistic Study of the Cycloaddition-Cycloreversion Reactions of Zirconium-Imido Complex Cp2Zr(N-t-Bu)(THF) with Organic Imines and Organic Azides (1995) (95)
- Catalytic deprotection of acetals in basic solution with a self-assembled supramolecular "nanozyme". (2007) (94)
- Zirconium-mediated metathesis of imines: a study of the scope, longevity, and mechanism of a complicated catalytic system. (2000) (94)
- Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. (2007) (93)
- Exceptionally low-temperature carbon--hydrogen/carbon--deuterium exchange reactions of organic and organometallic compounds catalyzed by the Cp*(PMe(3))IrH(ClCH(2)Cl)(+) cation. (2001) (93)
- C-H bond activation of hydrocarbons by an imidozirconocene complex. (2004) (92)
- A highly reactive titanium precatalyst for intramolecular hydroamination reactions. (2002) (90)
- Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry. (2014) (89)
- Stereoselective Alkylation of α,β-Unsaturated Imines via C-H Bond Activation (2006) (89)
- Making amines strong bases: thermodynamic stabilization of protonated guests in a highly-charged supramolecular host1. (2007) (89)
- Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes. (2012) (88)
- Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines. (2007) (86)
- Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines. (2012) (85)
- Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands: Different Interactions with Different Transition Metals (2000) (85)
- Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation. (2003) (85)
- Preagostic Rh−H Interactions and C−H Bond Functionalization: A Combined Experimental and Theoretical Investigation of Rhodium(I) Phosphinite Complexes (2005) (84)
- Dihydrogen Activation by Titanium Sulfide Complexes. (1999) (84)
- Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles. (2003) (82)
- Stoichiometric and catalytic deuterium and tritium labeling of "unactivated" organic substrates with cationic Ir(III) complexes. (2004) (81)
- Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes. (2004) (81)
- Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation. (2008) (80)
- Tungsten and molybdenum 2-oxaallyl [.eta.1-(C)-enolate] complexes: functional group transformations, photochemical aldol reactions, and alkyne/carbon monoxide migratory insertion reactions (1987) (80)
- Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism. (2008) (80)
- Synthesis and reactions of nickel and palladium carbon-bound enolate complexes (1990) (79)
- Carbon-carbon activation of organic small ring compounds by arrangement of cycloalkylhydridorhodium complexes to rhodacycloalkanes. Synthesis of metallacyclobutanes, including one with a tertiary metal-carbon bond, by nucleophilic addition to .pi.-allyl complexes (1986) (79)
- Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization. (2015) (79)
- Generation, dative ligand trapping, and nitrogen-nitrogen bond cleavage reactions of the first monomeric .eta.1-hydrazido zirconocene complex, (Cp2Zr:NNPh2). A zirconium mediated synthesis of indoles (1991) (78)
- Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes (2002) (77)
- Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activation. (2013) (77)
- IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect (1994) (77)
- The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination (2000) (76)
- Generation of the highly reactive intermediates Cp*2Zr:O and Cp*2Zr:S: trapping reactions with alkynes, nitriles, and dative ligands (1992) (76)
- Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C–H Bond Functionalization (2014) (75)
- MONOMERIC CYCLOPENTADIENYLNICKEL METHOXO AND AMIDO COMPLEXES : SYNTHESIS, CHARACTERIZATION, REACTIVITY, AND USE FOR EXPLORING THE RELATIONSHIP BETWEEN H-X AND M-X BOND ENERGIES (1997) (75)
- A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni). (2011) (75)
- Rh(I)-catalyzed direct arylation of azines. (2010) (75)
- (Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compounds (1985) (75)
- Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates (1994) (75)
- COOPERATIVE REACTIVITY IN THE INTERACTIONS OF X-H BONDS WITH A ZIRCONIUM-IRIDIUM BRIDGING IMIDO COMPLEX (1994) (75)
- Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex (1992) (74)
- Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines. (2005) (74)
- A kinetic and x-ray diffraction study of the solid state rearrangement of methyl p-dimethylaminobenzenesulfonate. Reaction rate enhancement due to proper orientation in a crystal (1977) (74)
- Evidence for the Formation of Free 16-Electron Species Rather than Solvate Complexes in the Ultraviolet Irradiation of CpCo(CO)2 in Liquefied Noble Gas Solvents (1995) (73)
- Inter- and intramolecular insertion of rhenium into carbon-hydrogen bonds (1986) (72)
- Rhodium alkoxide complexes : formation of an unusually strong intermolecular hydrogen bond in (PMe3)3Rh-Otol(HOtol) (1987) (72)
- Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study (1988) (72)
- Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. (2015) (72)
- Suggested Modifications to a Distillation-Free Solvent Purification System (2001) (72)
- Iridium alkoxide and amide hydride complexes. Synthesis, reactivity, and the mechanism of oxygen-hydrogen and nitrogen-hydrogen reductive elimination (1991) (72)
- Structural Factors that Influence the Course of Overall [2 + 2] Cycloaddition Reactions between Imidozirconocene Complexes and Heterocumulenes (2000) (71)
- Synthesis, structure, and reactivity of a monomeric pentamethylcyclopentadienyliridium(III) imido complex (1989) (71)
- Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host. (2017) (70)
- Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal Bond. Direct Addition of Carbon Dioxide across a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate (1995) (70)
- Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis. (2016) (70)
- Reversible carbon-hydrogen bond insertion/reductive elimination in (.eta.5-pentamethylcyclopentadienyl)(trimethylphosphine)iridium complexes. Use in determining relative metal-carbon bond energies and thermally activating methane (1984) (70)
- Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization. (2011) (69)
- Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation. (2003) (69)
- Z-selective, catalytic internal alkyne semihydrogenation under H2/CO mixtures by a niobium(III) imido complex. (2011) (68)
- The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster. (2007) (67)
- Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer. (2015) (66)
- Rapid intramolecular rearrangement of a hydrido(cyclopropyl)rhodium complex to a rhodacyclobutane. Independent synthesis of the metallacycle by addition of hydride to the central carbon atom of a cationic rhodium .pi.-allyl complex (1984) (66)
- Advances in supramolecular host-mediated reactivity (2020) (65)
- Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand. (2010) (65)
- One-step synthesis of benzocyclobutenes involving cooligomerization of linear mono- and diacetylenes catalyzed by .eta.5-cyclopentadienylcobalt dicarbonyl (1974) (65)
- Insertion of iridium into the carbon-hydrogen bonds of alkenes: the .pi.-complex cannot be an intermediate (1985) (65)
- Zirconium-Mediated Imine Metathesis. Synthesis of 2,4-Diaza-1-zirconiacyclobutanes and the Mechanism of Their Reactions with Imines and Alkynes (1994) (64)
- Intermolecular coupling of alkenes to heterocycles via C-H bond activation. (2004) (64)
- A new method for 1,2-diamination of alkenes using cyclopentadienylnitrosylcobalt dimer/NO/LiAlH4 (1980) (64)
- NITROUS OXIDE MEDIATED SYNTHESIS OF MONOMERIC HYDROXORUTHENIUM COMPLEXES. REACTIVITY OF (DMPE)2RU(H)(OH) AND THE SYNTHESIS OF A SILICA-BOUND RUTHENIUM COMPLEX (1998) (63)
- Synthesis, exchange reactions, and metallacycle formation in osmium(II) imido systems: formation and cleavage of osmium-nitrogen bonds (1993) (63)
- Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation. (2007) (63)
- Synthesis and Structure of a Terminal Metal Azide Complex: An Isolated Intermediate in the Formation of Imidometal Complexes from Organic Azides (1995) (63)
- Reactivity of a titanium dinitrogen complex supported by guanidinate ligands: investigation of solution behavior and a novel rearrangement of guanidinate ligands. (2001) (63)
- Annulation of aromatic imines via directed C-H bond activation. (2005) (62)
- Adduct Formation and Single and Double Deprotonation of Cp*(PMe3)Ir(H)2 with Main Group Metal Alkyls and Aryls: Synthesis and Structure of Three Novel Ir−Al and Ir−Mg Heterobimetallics (1998) (62)
- Time-resolved IR spectroscopy in liquid rare gases: direct rate measurement of an intermolecular alkane carbon-hydrogen oxidative addition reaction (1989) (61)
- Inter- and intramolecular oxidative addition of phosphine, methane, alkane, and alkene carbon-hydrogen bonds to rhenium (1985) (60)
- Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration (1996) (60)
- Oxidative addition of rhodium to alkane carbon-hydrogen bonds: enhancement in selectivity and alkyl group functionalization (1984) (60)
- Examination of the hydrogen-bonding networks in small water clusters (n = 2-5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis. (2012) (60)
- COMPARATIVE REACTIVITIES OF TWO ISOELECTRONIC TRANSITION METAL HYDRIDES WITH TRANSITION METAL CARBONYLS AND ALKYLS (2013) (60)
- Highly Efficient Aluminum-Catalyzed Hydro-amination/-hydrazination of Carbodiimides (2010) (58)
- Direct evidence for solvent coordination in migratory CO insertion (1981) (58)
- Synthesis and reactivity of Cp2Ta(CH2)2Ir-CO)2 : an early-late heterobimetallic complex that catalytically hydrogenates, isomerizes, and hydrosilates alkenes (1990) (58)
- Synthesis, Structural Investigation, and Reactivity of Neutral and Cationic Bis(guanidinato)zirconium(IV) Complexes (2001) (58)
- Synthesis and chemistry of ruthenium hydrido aryloxides and arylamides. An investigation of structure, nitrogen-hydrogen and oxygen-hydrogen elimination processes, proton-catalyzed exchange reactions, and relative Ru-X bond strengths (1991) (58)
- Theoretical study of the rhenium–alkane interaction in transition metal–alkane σ-complexes (2007) (58)
- Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines. (2009) (58)
- Synthesis and reactivity of (pentamethylcyclopentadienyl)iridium bis(thiolate) and thiolate hydride complexes (1990) (56)
- Encapsulation of cationic ruthenium complexes into a chiral self-assembled cage. (2003) (56)
- Synthesis, Structures, and Kinetics and Mechanism of Decomposition of Terminal Metal Azide Complexes: Isolated Intermediates in the Formation of Imidometal Complexes from Organic Azides (1996) (56)
- The consequences of σ and π conjugative interactions in mono‐, di‐ and triacetylenes. A photoelectron spectroscopic investigation (1975) (55)
- Synthesis of trimethylphosphine-substituted (pentamethylcyclopentadienyl)iridium hydride complexes; protonation and deprotonation of (pentamethylcyclopentadienyl)(trimethylphosphine)iridium dihydride (1985) (55)
- Catalytic Dimerization Reactions of α-Olefins and α,ω-Dienes with Cp2ZrCl2/Poly(methylalumoxane): Formation of Dimers, Carbocycles, and Oligomers (1996) (55)
- Catalysis of 6pi electrocyclizations. (2008) (54)
- Room temperature generation of reactive intermediates Cp*Zr:O and Cp*2Zr:S: trapping reactions with unsaturated organic molecules and dative ligands (1990) (54)
- The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution. (2009) (54)
- Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B. (2006) (54)
- Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. (2002) (54)
- Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis (2013) (54)
- Application of the E-C Approach to Understanding the Bond Energies Thermodynamics of Late-Metal Amido, Aryloxo and Alkoxo Complexes: An Alternative to pπ/dπ Repulsion (1999) (53)
- The Effect of Alkane Structure on Rates of Photoinduced C−H Bond Activation by Cp*Rh(CO)2 in Liquid Rare Gas Media: An Infrared Flash Kinetics Study (1999) (53)
- Synthesis of a highly reactive (benzyne)ruthenium complex: C-C, C-H, N-H, and O-H activation reactions (1989) (52)
- Structural consequences of anionic host-cationic guest interactions in a supramolecular assembly. (2009) (52)
- Synthesis, structure, and carbon-carbon bond-forming reactions of carbon-bound molybdenum, tungsten, and rhenium enolates. Detection of an .eta.3-oxaallyl intermediate (1985) (52)
- Synthesis and reactions of monomeric late transition metal alkoxo, aryloxo and hydroxo complexes (1995) (52)
- Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline. (2006) (52)
- Synthesis, Structure, and Reactivity of η2-N2-Aryldiazoalkane Titanium Complexes: Cleavage of the N−N Bond (1998) (51)
- Liquid xenon: an effective inert solvent for carbon-hydrogen oxidative addition reactions (1989) (51)
- Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation. (2009) (51)
- Synthesis of an optically active cyclopropene and kinetics of its thermal racemization in the gas phase. Intermediacy of a vinylcarbene (1973) (50)
- Does size really matter? The steric isotope effect in a supramolecular host-guest exchange reaction. (2010) (50)
- Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes. (2002) (50)
- Structure, synthesis, and chemistry of ruthenium complex (PMe3)4Ru(.eta.2-benzyne). Reactions with arenes, alkenes, and heteroatom-containing organic compounds. Synthesis and structure of a monomeric hydroxide complex (1991) (50)
- Deconvoluting the Role of Charge in a Supramolecular Catalyst. (2018) (50)
- Carbon–fluorine bond cleavage in fluoroarenes via a niobium(III) imido complex: from stoichiometric to catalytic hydrodefluorination (2014) (49)
- Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes. (2010) (49)
- The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations† †Electronic supplementary information (ESI) available: Kinetics plots are available free of charge. See DOI: 10.1039/c4sc02735c Click here for additional data file. (2014) (49)
- Synthesis and Chemistry of the Aryliridium(III) Fluorides Cp'Ir(PMe3)(Aryl)F: High Reactivity due to Surprisingly Easy Ir-F Ionization (1995) (49)
- Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers. (2014) (49)
- A comprehensive investigation of the chemistry and basicity of a parent amidoruthenium complex. (2002) (49)
- Synthesis and reactivity of an iridium hydroxo complex. Insertion of ethylene into a metal-oxygen bond (1993) (48)
- Diniobium inverted sandwich complexes with μ-η6:η6-arene ligands: synthesis, kinetics of formation, and electronic structure. (2013) (48)
- Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. (2003) (48)
- Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution (2002) (47)
- A Useful Method for Preparing Iridium Alkoxides and a Study of Their Catalytic Decomposition by Iridium Cations: A New Mode of β-Hydride Elimination for Coordinatively Saturated Metal Alkoxides (1998) (47)
- Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization. (2010) (46)
- Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. (2001) (46)
- Encapsulation of protonated diamines in a water-soluble, chiral, supramolecular assembly allows for measurement of hydrogen-bond breaking followed by nitrogen inversion/rotation. (2008) (46)
- Independent mechanisms in the thermal rearrangement of mono- and bicylic 3,4-dimethylenecyclobutene derivatives (1972) (46)
- Computational Study of Methane Activation by TpRe(CO)2 and CpRe(CO)2 with a Stereoelectronic Comparison of Cyclopentadienyl and Scorpionate Ligands (2003) (46)
- Oxidative addition of soluble iridium and rhodium complexes to carbon-hydrogen bonds in methane and higher alkanes (1984) (46)
- Scope and mechanism of alkene hydrogenation/isomerization catalyzed by complexes of the type R2E(CH2)2M(CO)(L) (R = Cp, Me, Ph; E = phosphorus, tantalum; M = rhodium, iridium; L = CO, PPh3) (1993) (46)
- Aluminium-catalyzed intramolecular hydroamination of aminoalkenes. (2010) (46)
- X-ray Crystal Structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p-C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3+]. Understanding Distortions and Trans Influences in Cyclopentadienyl Complexes (1997) (46)
- Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host (2009) (45)
- Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes. (2004) (45)
- A reactive organometallic oxo intermediate, Cp*2Zr=O: generation and subsequent trapping reactions forming alkyne and nitrile addition products (1989) (45)
- Synthesis and C−H Activation Reactions of Cyclometalated Complexes of Ir(III): Cp*(PMe3)Ir(CH3)+Does Not Undergo Intermolecular C−H Activation in Solution via a Cyclometalated Intermediate (1997) (45)
- Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex (2012) (45)
- Synthesis and reaction chemistry of a new class of .mu.-alkylidene dicobalt complexes. Crystal and molecular structure of (.mu.-methylene)bis[.eta.5-(methylcyclopentadienyl)carbonylcobalt] (1983) (45)
- Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions (1991) (45)
- Structure and reactions of oxametallacyclobutanes and oxametallacyclobutenes of ruthenium (1991) (45)
- Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds (1991) (45)
- A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. (2013) (44)
- Deprotonation of the Transition Metal Hydride (η5-C5Me5)(PMe3)IrH2. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η5-C5Me5)(PMe3)Ir(H)(Li) (1999) (44)
- A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation. (2001) (44)
- Synthesis of monomeric ruthenium hydroxo complexes (PMe3)4Ru(R)(OH) (R = H, Me) and a unique dimeric ruthenium hydroxo-water complex [trans-Ru(H)(OH)(DMPE)2.cntdot.H2O]2 (1993) (44)
- Synthesis of an Iron Parent Amido Complex and a Comparison of Its Reactivity with the Ruthenium Analog (2004) (43)
- Highly Efficient Aluminum-Catalyzed Ring-Opening Polymerization of Cyclic Carbonates, Lactones, and Lactides, Including a Unique Crystallographic Snapshot of an Intermediate (2011) (43)
- Femtosecond IR Studies of Alkane C-H Bond Activation by Organometallic Compounds: Direct Observation of Reactive Intermediates in Room Temperature Solutions (1996) (43)
- Synthesis, Characterization, and Reactivity of Aluminum Alkyl/Amide Complexes Supported by Guanidinate and Monoanionic OCO-Pincer Ligands (2010) (43)
- Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer. (2014) (43)
- Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. (2002) (43)
- Encapsulated guest-host dynamics: guest rotational barriers and tumbling as a probe of host interior cavity space. (2010) (42)
- Photochemistry of η5 cylclopentadienylcobalt) tricarbonyl, tris(η5-cyclopentadienylcobalt monocarbonyl) and tetra(η5-cyclopentadienylcobalt) dicarbonyl* (1975) (42)
- Synthesis of an η2-N2-Titanium Diazoalkane Complex with Both Imido- and Metal Carbene-Like Reactivity Patterns (1998) (42)
- Synthesis of an (.eta.3-allyl)(hydrido)iridium complex and its reactions with arenes and alkanes. Sequential intermolecular carbon-hydrogen oxidative addition and hydride-to-alkene migratory insertion reactions (1988) (42)
- KINETICS AND MECHANISM OF THE FORMATION OF NITROSOALKANE COMPLEXES BY MIGRATORY INSERTION OF COORDINATED NITRIC OXIDE INTO COBALT-CARBON BONDS (1983) (42)
- Modeling the Proposed Intermediate in Alkane Carbon-Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes (1999) (42)
- Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond. (2003) (42)
- C-H bond activation by a rare cationic iridium dinitrogen complex. An important electronic effect in the chemistry of the hydridotris(pyrazolyl)borate ligand (2000) (42)
- Synthesis and characterization of [(.eta.5-C5H5)V(CO)3H]-, a new anionic vanadium carbonyl hydride, and a study of its reduction reaction with organic halides. Observation of a free-radical chain process having an extremely rapid metal-to-carbon hydrogen transfer step (1978) (41)
- Rate and equilibrium study of the reversible oxidative addition of silanes to the iridium center in Cp2Ta(.mu.-CH2)2Ir(CO)2 and of alkene hydrosilylation/isomerization catalyzed by this system (1993) (41)
- Addition of Organic 1,3‐Dipolar Compounds across a Heterobinuclear Bond between Early and Late Transition Metals: Mechanism of Nitrogen Loss from an Organoazido Complex To Form a Bridging Imido Complex (1996) (41)
- Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds (2014) (41)
- Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl−Phosphine Ligands as C−H Activation Catalysts for the Deuteration of Hydrocarbons in D2O (2002) (41)
- A facile, metal- and solvent-free, autoxidative coupling of quinolines with indoles and pyrroles. (2011) (41)
- Preparation of monomeric (.eta.6-arene)OsNR complexes and their exchange reactions with amines, alcohols, and thiols (1991) (40)
- Reaction of η5-cyclopentadienylbis(triphenylphosphine)cobalt(I) with alkadiynes. Preparation and reactions of bicyclic cobalt metallocycles and a stable trimethylsilyl-substituted mono-complexed alkadiyne. Comments on the mechanism of cobalt-catalyzed alkyne cooligomerization (1978) (40)
- Reactivity of alkyne tungsten and molybdenum complexes. Heterolytic carbon-hydrogen bond activation in coordinated alkynes (1980) (40)
- C−C and C−H Bond Activation at Ruthenium(II): The Stepwise Degradation of a Neopentyl Ligand to a Trimethylenemethane Ligand (1997) (40)
- Carbon-carbon bond formation in dinuclear dialkyl complexes. Reactions of [CpCo(CO)R]2 (R = methyl, ethyl, or 2,2,2-trifluoroethyl) and (C11H10)Co2(CO)2(CH3)2 with carbon monoxide and triphenylphosphine (1984) (40)
- Synthesis, crystal and molecular structure, and reactions of a benzodicobaltacyclohexene, a thermally derived mononuclear o-xylylene complex, and an unsymmetrical phosphine-derived dinuclear complex (1983) (40)
- Synthesis and cyclization reactions of alkynyl (.eta.5-cyclopentadienyltricarbonylmolybdenum and -tungsten) complexes (1979) (40)
- The thermodynamic driving force for CH activation at iridium (1988) (40)
- Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)]. (2004) (40)
- Heats of reaction of Cp*(PMe3)Ir(R)(H) (R = C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I : a solution thermochemical study of the C-H insertion reaction (1987) (40)
- REACTIONS OF AN IMIDOZIRCONOCENE COMPLEX WITH CYCLOPENTADIENYLMETAL CARBONYL COMPLEXES. C-H ACTIVATION VERSUS OXYGEN ATOM ABSTRACTION (1995) (40)
- Silicon−Hydrogen Bond Activation and Formation of Silane Complexes Using a Cationic Rhodium(III) Complex (2004) (39)
- Kinetic control and multiple mechanisms for C-H bond activation by a Zr=N complex. (2007) (39)
- Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. (2016) (39)
- Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism. (2000) (38)
- Substitution, alkyl-transfer, and thermal decomposition reactions of .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III) (1980) (38)
- Reactions of (PMe3)4Ru(C2H4) and (DMPE)2Ru(C2H4) with Weak Proton-Donating Electrophiles HX (X = OAr, SAr, NHPh, PHPh). Synthesis of Complexes with Metal-Heteroatom Single Bonds (1995) (38)
- Mechanistic Investigation of Cycloreversion/Cycloaddition Reactions between Zirconocene Metallacycle Complexes and Unsaturated Organic Substrates. (2001) (38)
- Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation. (2014) (38)
- Alkylation of Iridium via tandem carbon-hydrogen bond. Activation/decarbonylation of aldehydes. Access to complexes with tertiary and highly hindered metal-carbon bonds (2000) (38)
- Generation of Oxozirconocene Complexes from the Reaction of Cp2(THF)ZrN-t-Bu with Organic and Metal Carbonyl Functionalities: Apparently Divergent Behavior of Transient [Cp2ZrO] (1996) (38)
- Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions. (2006) (37)
- Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systems. (2013) (37)
- Synthesis of ruthenium enolate (PMe3)4Ru(Me)(OC(CH2)Me) as an equilibrium mixture of oxygen- and carbon-bound transition-metal enolates. Thermal elimination of methane to form an .eta.4-oxatrimethylenemethane complex (1990) (37)
- Simultaneously bound guests and chiral recognition: a chiral self-assembled supramolecular host encapsulates hydrophobic guests (2008) (36)
- A transition-metal-based method for 1,2-diamination of alkenes. Synthesis of cobalt dinitrosoalkanes from alkenes, nitric oxide, and (.eta.5-cyclopentadienyl)(nitrosyl)cobalt dimer and their reduction to primary vicinal diamines (1983) (36)
- Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study (2010) (36)
- Reactions of uranium complex (MeC5H4)3U(t-Bu): intermolecular fluorine atom abstraction from fluorocarbons including saturated perfluorocarbons (1993) (36)
- A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length. (2019) (36)
- Synthesis and chemistry of a dinuclear iridium bis-.mu.-oxo complex. Observation of oxygen transfer and phosphorus-carbon bond cleavage (1988) (35)
- Synthesis, molecular structure, and thermal chemistry of (.eta.5-cyclopentadienyl)dicarbonylrhenacyclopentane (1985) (35)
- Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host. (2013) (35)
- Dis-assembly of a benzylic CF3 group mediated by a niobium(III) imido complex. (2013) (35)
- Synthesis of isoquinuclidines from highly substituted dihydropyridines via the Diels-Alder reaction. (2013) (35)
- Double Cycloaromatization of (Z,Z)-Deca-3,7-diene-1,5,9-triyne: Evidence for the Intermediacy and Diradical Character of 2,6- Didehydronaphthalene. (1992) (35)
- Synthesis and solvolysis of 1-cyclopropyl-1-iodoethylene. Generation of an unusually stable vinyl cation (1969) (35)
- Reversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediate (1983) (35)
- Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp(PMe(3))IrPh(OH) and [Cp(PMe(3))Ir(Ph)NCR](+). (1999) (35)
- Equilibrium isotope effects on noncovalent interactions in a supramolecular host-guest system. (2012) (34)
- High-precision measurement of isotope effects on noncovalent host-guest interactions. (2010) (34)
- Asymmetric induction in reactions employing enolates generated from cyclic organo transition metal acyl complexes (1982) (34)
- Synthesis and reactions of a binuclear cobalt bridging methylene (.mu.-CH2) complex. Conversion to .mu.-CH2 rhodium/cobalt and rhodium/rhodium complexes and methylene transfer to ethylene involving activation by a second metal complex (1981) (34)
- Kinetics of racemization and cis-trans isomerization of the optically active 1-ethyl-2-methylcyclopropanes in the gas phase. An estimate of relative rates of bond rotation and ring closure in diradical intermediates (1969) (34)
- Preparation and reactivity of terminal gold(I) amides and phosphides (2013) (34)
- Ten‐Membered Ring Enediynes with Remarkable Chemical and Biological Profiles (1992) (34)
- Reactivity of a parent amidoruthenium complex: a transition metal amide of exceptionally high basicity. (2000) (34)
- Synthesis of alkylruthenium nitrosyl complexes. Migratory insertion to coordinated nitric oxide and the mechanism of the conversion of the resultant nitrosoalkyl compounds to oximate, carboxamide, and cyano compounds (1989) (34)
- Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination. (2017) (34)
- Zirconocene-alumoxane (1:1) — a catalyst for the selective dimerization of α-olefins (1998) (34)
- Reproducibility in Chemical Research. (2016) (34)
- Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes. (2004) (33)
- Cycloaddition and Cycloreversion Reactions of a Monomeric Ti(IV) Oxo Complex with Terminal and Internal Alkynes. A Reversible Oxametallacyclobutene/Hydroxoacetylide Interconversion (1995) (33)
- ENHANCEMENT OF A CHEMICAL REACTION RATE BY PROPER ORIENTATION OF REACTING MOLECULES IN THE SOLID STATE (1975) (33)
- TRANSFER OF OXYGEN AND SULFUR FROM ORGANIC MOLECULES TO A ZR-IR BOND. EVIDENCE FOR AN UNUSUALLY RAPID ATOM ABSTRACTION REACTION (1995) (33)
- Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics. (2019) (33)
- Application of the extended Hueckel molecular orbital method to the properties of vinyl cations. Conformational energies of some 1-cyclopropylvinyl cations and a comparison of SN2 displacements at saturated and vinyl carbon (1971) (33)
- Thermal decomposition of 2H-azirines. Formation of products resulting from carbon-carbon bond cleavage (1976) (33)
- Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation. (2008) (33)
- Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins. (2008) (33)
- Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction. (2011) (32)
- Synthesis, insertion and reductive elimination reactions of a hydrido(alkoxy)iridium complex (1985) (32)
- Zirconium-mediated conversion of amides to nitriles: a surprising additive effect. (2004) (32)
- 1H NMR chemical shift calculations as a probe of supramolecular host-guest geometry. (2011) (32)
- Mechanism and regiochemistry of azametallacyclobutene formation from imidozirconocene complexes and alkynes (1995) (32)
- Preparation and reactions of tetrahydrido (pentamethylcyclopentadienyl)iridium: a novel iridium(V) polyhydride (1983) (31)
- Comparison of the reactivity of (CO)3L2ReOR, (CO)3L2ReOAr and (CO)3L2ReNHAr with carbon dioxide and other electrophiles (1992) (31)
- Multiple mechanisms in the thermal and photochemical decomposition of 2,3-diazabicyclo[3.1.0]hex-2-enes (1972) (31)
- Insertion of (.eta.5-C5Me5)(PMe3)Ir into the carbon-hydrogen bonds of functionalized organic molecules: a C-H activation route to 2-oxa- and 2-azametallacyclobutanes, potential models for olefin oxidation intermediates (1988) (31)
- Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines. (2015) (31)
- Group 5 chemistry supported by β-diketiminate ligands. (2016) (31)
- Synthesis of a Novel Volatile Platinum Complex for Use in CVD and a Study of the Mechanism of Its Thermal Decomposition in Solution (1996) (31)
- Synthesis, structure, and exchange reactions of rhenium alkoxide and aryloxide complexes. Evidence for both proton and hydrogen atom transfer in the exchange transition state (1993) (31)
- Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)2 (1998) (31)
- Use of Steric Hindrance and a Metallacyclobutene Resting State to Develop Robust and Kinetically Characterizable Zirconium-Based Imine Metathesis Catalysts (1998) (31)
- The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization. (2008) (31)
- Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization. (2014) (31)
- Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide (1995) (30)
- Synthesis and chemistry of a bridging vinylidenedicobalt complex. Evidence for a nonchain radical mechanism in its reaction with metal hydrides to give heteronuclear clusters (1985) (30)
- A direct, biomass-based synthesis of benzoic acid: formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid. (2010) (30)
- SYNTHESIS, CHARACTERIZATION, ISOMERIZATION, AND REACTIVITY OF DIMERIC CYCLOPENTADIENYLNICKEL AMIDO COMPLEXES (1996) (30)
- Synthesis of metallacyclopentanes containing two metals in the ring. Thermal decomposition to cyclopropane and ligand-induced conversion to stable mononuclear metallacyclopentanones (1980) (30)
- Chemical and electrochemical reduction of .eta.5-cyclopentadienyldicarbonylcobalt(I) and .eta.5-cyclopentadienyl(triphenylphosphine)carbonylcobalt(I). Synthesis, crystal structure, and chemistry of sodium and bis(triphenylphosphine)iminium bis(.eta.5-cyclopentadienyl)di-.mu.-carbonyl-dicobaltate (1977) (30)
- Use of isotope crossover experiments in investigating carbon-carbon bond-forming reactions of binuclear dialkylcobalt complexes (1980) (30)
- Synthesis of dialkyl- and alkyl(acyl)rhenium complexes by alkylation of anionic rhenium complexes at the metal center. Mechanism of a double carbonylation reaction that proceeds via the formation of free methyl radicals in solution (1989) (30)
- C-H activation (2007) (30)
- Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands (2002) (29)
- Activation of carbon-hydrogen bonds in alkanes and other organic molecules by Ir(I), Rh(I) and Ir(III) complexes (1995) (29)
- Nitrous Oxide Mediated Oxygen Atom Insertion into a Ruthenium−Hydride Bond. Synthesis and Reactivity of the Monomeric Hydroxoruthenium Complex (DMPE)2Ru(H)(OH) (1997) (29)
- A physical organic road to organometallic CH oxidative addition reactions (1990) (29)
- Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism (2016) (29)
- Reaction of alkynes with a methylnickel complex: observation of a cis insertion mechanism capable of giving kinetically controlled trans products (1979) (29)
- The Use of a Planar Chiral Ligand to Effect C−H Activation with Asymmetric Induction at an Iridium Center. Dramatically Different C−H Activation Stereoselectivities for Benzene and Cyclohexane (1998) (29)
- Reductive elimination leading to transient (.eta.5-C5Me5)Ru(NO). Trapping, dimerization and oxidative addition reactions of this intermediate and the effect of structural variation on its generation (1987) (29)
- Heterocumulene metathesis by iridium guanidinate and ureylene complexes: catalysis involving reversible insertion to form six-membered metallacycles. (2002) (29)
- Disambiguation of Metal and Brønsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts (2011) (29)
- Efficient Bipedal Robots Based on Passive-Dynamic Walkers (2005) (29)
- New routes to transition metal-carbido species: synthesis and characterization of the carbon-centered trigonal prismatic clusters [W(6)CCl(18)](n)(-) (n = 1, 2, 3). (2003) (29)
- Rhenium 2-oxoalkyl (enolate) complexes: Synthesis and carbon-carbon bond-forming reactions with nitriles (1990) (29)
- Synthesis of an early-late heterobimetallic imido complex: cooperative reactivity with nitrogen-, oxygen-, and sulfur-hydrogen bonds and formation of a novel aminophosphine complex (1993) (28)
- An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex. (2008) (28)
- Mechanisms of allene stereoinversion by imidozirconium complexes. (2003) (28)
- The Mechanism of Addition of an Ir−OH bond to Ethylene. Catalytic Tandem Activation by Two [η5-Cp*(Ph)IrPMe3]+ Complex Fragments (1997) (28)
- Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). (2012) (28)
- Synthesis, X-ray Structure Determination, and Reactions of (Pentamethylcyclopentadienyl)(nitrosyl)ruthenium η2-Arene Complexes (1996) (28)
- Synthesis, Structure, and Reactivity Studies of an η2-N2-Titanium Diazoalkane Complex. Generation and Trapping of a Carbene Complex Intermediate (1996) (28)
- Synthesis and Reactivity of Bridging Imido and Imido-Oxo Complexes of Iridium. Water-Catalyzed and -Uncatalyzed Dimerization of Terminal Iridium Imido Complexes (1994) (28)
- Stereochemistry of solvolytic displacement at vinyl carbon. Reactions of 1-cyclopropyl-2-methylvinyl cations formed on silver-catalyzed ionization of cis- and trans-1-cyclopropyl-1-iodopropenes and 3,4-hexadien-1-yl iodide (1971) (27)
- Late Transition-Metal Sulfido Complexes: Reactivity Studies and Mechanistic Analysis of Their Conversion into Metal-Sulfur Cubane Complexes (1994) (27)
- Synthesis and reactions of a dimetallacyclohexene. Thermal conversion to an o-xylylene complex and phosphine-induced conversion to free o-xylylene and a new reactive dinuclear cobalt complex (1981) (27)
- Mechanism and Catalytic Impact of Ir–Ta Heterobimetallic and Ir–P Transition Metal/Main Group Interactions on Alkene Hydrogenation (2015) (27)
- Deprotonation of a Cp* methyl group by an iridium anilide: formation, structure, and solution dynamics of an .eta.4-tetramethylfulvene complex (1990) (26)
- Insertion of Nitriles into a Zirconium−Iridium Heterobimetallic Complex: A Mechanistic Study (2000) (26)
- Silica as a Ligand: Reactivity of the Iridium-Oxygen Bond of Cp*Ir[silica](Ph)(PMe3) (1994) (26)
- Organometallic CO substitution kinetics in liquid Xe by fast time-resolved IR spectroscopy (1993) (26)
- Reaction of a bridged binuclear dialkylcobalt complex with carbon monoxide and phosphines. Observation of competing inter- and intramolecular metal to metal methyl transfer (1979) (26)
- DOUBLE GROUP TRANSFER REACTIONS OF AN UNSATURATED TANTALUM METHYLIDENE COMPLEX WITH PYRIDINE N-OXIDES (1999) (26)
- Intramolecular B−H Bond Activation from a Dihydridobis(dimethylpyrazolyl)borate Ligand: Formation of a Rhodium(III) Carbene Hydride and a Rare Example of Reverse α-Hydride Migration (2000) (26)
- Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals. (2012) (26)
- Synthesis of Tertiary and Other Sterically Demanding Alkyl and Aryl Complexes of Iridium by Aldehyde C−H Bond Activation (1997) (26)
- Some problems in the oxidative addition and binding of an ethylene to a transition-metal center (1986) (25)
- Synthesis and absolute configurations of some optically active cis- and trans-1,2-disubstituted cyclopropanes (1969) (25)
- Competition between sulfur extrusion and thermal synthesis of thienocyclobutadiene in the pyrolysis of cis- and trans-1,2-diethynylthiiranes. Dimerization of the rearrangement product to bisthienocyclooctatetraene (1973) (25)
- 3,6-dehydrooxepin, a furocyclobutadiene (1972) (25)
- Synthesis of trinuclear alkylidyne complexes from dinuclear alkyne complexes and metal hydrides. CIDNP evidence for vinyl radical intermediates in the hydrogenolysis of these clusters (1983) (25)
- Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids. (2016) (25)
- Pt-catalyzed C-C activation induced by C-H activation. (2013) (25)
- Mechanism of the carbon-carbon cleavage of acetone by the ruthenium benzyne complex (PMe3)4Ru(.eta.2-C6H4): formation and reactivity of an oxametallacyclobutane complex (1990) (25)
- Effects of phosphine ligand chelation on the reactivity of monomeric parent amido ruthenium complexes: synthesis and reactivity of such a complex bearing monodentate ligands. (2002) (25)
- Alkyl, aryl, hydrido, and acetate complexes of (DMPM)2Ru [DMPM = bis(dimethylphosphino)methane]: reductive elimination and oxidative addition of carbon-hydrogen bonds (1991) (24)
- Stereochemistry of the Cope rearrangement and mechanism of thermal aromatization of 3,3'-bicyclopropenyls (1977) (24)
- A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction. (2020) (24)
- Acceleration of amide bond rotation by encapsulation in the hydrophobic interior of a water-soluble supramolecular assembly. (2008) (24)
- SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND CHEMISTRY OF A MONOMERIC CATIONIC IRIDIUM CARBYNE COMPLEX (1998) (24)
- Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands. (2011) (24)
- Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex. (2016) (24)
- Rearrangements and stereomutations of metallacycles derived from allenes and imidozirconium complexes. (2005) (24)
- Dissociation of carbanions from acyl iridium compounds: an experimental and computational investigation. (2004) (23)
- ULTRAFAST DYNAMICS OF CP*M(CO)2 (M = IR, RH) IN SOLUTION : THE ORIGIN OF THE LOW QUANTUM YIELDS FOR C-H BOND ACTIVATION (1996) (23)
- Generation and rearrangements of the 1-cyclopropylvinyl cation. Comparison of the intermediates formed upon ionization of 1-cyclopropyl-1-iodoethylene and 3,4-pentadien-1-yl iodide (1971) (23)
- Insertion of alkynes into zirconium-nitrogen bonds leading to 2,3-diazametallacyclopentenes. Generation and reactivity of Cp2Zr(N2Ph2) (1992) (23)
- Isolation of unstable bis(.eta.5-cyclopentadienylcobalt) tricarbonyl from the irradiation of .eta.5-cyclopentadienylcobalt dicarbonyl. Thermal reactions of this binuclear complex leading to starting material and trinuclear and tetranuclear cobalt(I) complexes (1974) (23)
- Heteroatom exchange reactions in imidoosmium(II) systems : cleavage of Os-N multiple bonds and formation of Os-X bonds (X = O, S, C) (1994) (23)
- Generation and trapping of the diphenylhydrazido(2-) complex Cp2Zr(N2Ph2). Insertion of internal alkynes into a metal-nitrogen bond, leading to 2,3-diazametallacyclopentenes (1990) (23)
- Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer. (2008) (23)
- Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition (2004) (23)
- IR flash kinetic spectroscopy of transients generated by irradiation of cyclopentadienylcobalt dicarbonyl in the gas phase and in solution. (1988) (22)
- Mechanistic investigations of the acid-catalyzed cyclization of a vinyl ortho-quinone methide. (2008) (22)
- Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex (1981) (22)
- Synthesis and reactivity of (.eta.5-C5Me5)(PMe3)Ir(CH2): a monomeric (pentamethylcyclopentadienyl)iridium methylene complex (1989) (22)
- SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF LATE TRANSITION METAL PARENT AMIDO (LNM-NH2) COMPLEXES : AN ACID/CONJUGATE BASE METATHESIS APPROACH (1998) (22)
- Mechanism of the reaction between organo transition metal alkyls and hydrides. A model for the aldehyde-forming step in the oxo process (1979) (22)
- Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes. (2003) (22)
- Optical isomerization during the pyrolysis of alkylcyclopropanes. Evidence for diradical intermediates and an estimate of their relative rates of bond rotation and ring closure (1968) (22)
- Characterization and evidence for alkylation of hydridodicarbonylcyclopentadienylrhenate(1-) ion [CpRe(CO)2H-] in the conversion of dihydrodicarbonylcyclopentadienylrhenium [CpRe(CO)2H2] to CpRe(CO)2R2. Synthesis of a rhenacyclopentane and its thermolysis to methylcyclopropane (1983) (22)
- Formation of 1,4-pentadiene and vinylcyclopropane in the thermal and photochemical decomposition of 2,3-diazabicyclo[3.2.0]hept-2-ene (1972) (22)
- Conversion of epoxides to rhodium enolates: Direct evidence for a mechanism involving initial C-H activation (1989) (22)
- Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex (1988) (22)
- Chemical reduction of .eta.5-cyclopentadienyldicarbonylrhodium. Crystal and molecular structure of an anionic trinuclear rhodium cluster with "semi-triple-bridging" carbonyl ligands (1978) (22)
- Base-catalyzed rearrangement of 3-bromobicyclo[3.2.1]octa-2,6-diene to endo-6-ethynylbicyclo[3.1.0]hex-2-ene. Possible intermediacy of a homoconjugated carbene (1970) (22)
- An Observable Silene/Silylene Rearrangement in a Cationic Iridium Complex (2001) (21)
- Synthesis and reactions of a dinuclear iron nitrosyl radical anion, and di- and mononuclear dimethylnitrosyliron complexes. Migratory insertion of coordinated nitric oxide (1983) (21)
- Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines. (2009) (21)
- Solvolytic reactivity of 4-tricyclyl, 1-apocamphyl, and 1-methyl-4-tricyclo[2.2.2.02,6]octyl trifluoromethanesulfonates. Observations on the interaction of the face of the cyclopropane ring with electrophiles and on the interpretation of activation parameters for solvolytic reactions (1972) (21)
- Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes. (2010) (21)
- Interconversion of a 3,3-Dimethylruthenacyclobutane and a Methyl(2-methallyl)ruthenium Complex: The First Direct Observation of Reversible .beta.-Methyl Elimination/Migratory Insertion (1995) (21)
- Carbon-carbon bond forming reactions of rhenium enolates with terminal alkynes. Evidence for an alkyne C-H oxidative addition mechanism and observation of highly stereoselective base-catalyzed proton transfer reactions in rhenium metallacycles (1990) (21)
- A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2 (1990) (21)
- Synthesis of a doubly alkylated binuclear cobalt carbonyl complex. Generation of acetone, a process involving the formation of two new carbon-carbon bonds, in its thermal decomposition (1976) (21)
- Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate. (2019) (20)
- Synthesis, structure and reactivity of (.eta.5-cyclopentadienyl)nitrosylcobalt (1984) (20)
- Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes. (2007) (20)
- Migratory insertion reactions of indenyliridium dialkyls and alkyl and aryl hydrides (1992) (20)
- Electron localization in a mixed-valence diniobium benzene complex (2014) (20)
- Platinum Group Thiophenoxyimine Complexes: Syntheses and Crystallographic/Computational Studies (2007) (20)
- A rational synthesis of organometallic bridging sulfur dimers and their conversion into homo- and heterometallic cubane complexes. Evidence for a mechanism involving dimerization of doubly unsaturated dinuclear intermediates (1992) (20)
- Vinylmethylene: theoretical investigations (1977) (20)
- Electrophilic cleavage of rhenium-oxygen bonds by Broensted and Lewis acids (1992) (20)
- Carbon-Carbon bond forming reactions of organotransition metal enolate complexes (1988) (20)
- LASER-POWERED HOMOGENEOUS DISSOCIATION OF TETRALIN (1981) (20)
- PHOSPHINE SUBSTITUTION IN n5-CYCLOPENTADIENYL-BIS-TRIPHENYLPHOSPHINECOBALT (I): EVIDENCE FOR A DISSOCIATIVE MECHANISM (1981) (20)
- Inter- and intramolecular carbon-hydrogen bond forming and cleavage reactivity of two different types of poly(trimethylphosphine)ruthenium intermediates (1991) (20)
- Tantalum-Mediated Cleavage of an NN Bond in an Organic Diazene (Azoarene) To Produce an Imidometal (MNR) Complex: An η2-Diazene Complex Is Not an Intermediate. (1999) (20)
- C-H oxidative addition and reductive elimination reactions in a dinuclear iridium complex (1988) (20)
- Synthesis and reactions of hydrido(eta/sup 1/-allyl)- and hydrido(eta/sup 3/-allyl)iridium complexes (1985) (20)
- Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes. (2005) (19)
- Chemistry of methylnorbornyl cations. VI. The stereochemistry of vicinal hydride shift. Evidence for the nonclassical structure of 3-methyl-2-norbornyl cations (1967) (19)
- Detection of cyclobutadienocyclopentadienyl anion (1969) (19)
- Mechanistic Investigations of Cp-Loss Reactions in an Early-Late Heterobimetallic Complex. Isolation of a Cationic Tantalum-Palladium Compound with a Free Cyclopentadienyl Counteranion (1994) (19)
- Protein-like proton exchange in a synthetic host cavity (2015) (19)
- New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks. (2016) (19)
- Crystal and molecular structure, spectroscopic properties, and redox behavior of [.eta.5-C5H5CoCO]2.-, a "mixed-valence" organometallic radical anion having a high degree of intramolecular delocalization and cobalt in formal oxidation state +0.5 (1976) (19)
- Formation of .alpha.,.beta.-Unsaturated Imines and Successful Trapping of Oxozirconocene in a [4 + 2] Azaoxametallacyclohexene Retrocycloaddition (1995) (19)
- Secondary .beta.-deuterium isotope effects on the rates and equilibria of organometallic oxidative addition/reductive elimination reactions (1992) (18)
- Reduction of .eta.5-cyclopentadienyldicarbonylcobalt. Formation of tetracarbonylcobaltate and [.eta.5-C5H5CoCO]2.-. A binuclear cobalt radical anion (1976) (18)
- Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. (2004) (18)
- Synthesis and carbon-hydrogen activation reactions of .eta.5-indenyl(trimethylphosphine)iridium alkyl and hydride complexes (1992) (18)
- Complete determination of the stereochemistry of a 3,5-dialkylpyrazoline thermal decomposition. Synthesis, absolute configuration, and pyrolysis of (+)-(3R,5R)- and (+)-(3R,5S)-3-ethyl-5-methyl-1-pyrazolines (1977) (18)
- Synthesis of Novel Group 4 Complexes Bearing the Tropidinyl Ligand: Investigations of Dynamic Behavior, Reactivity, and Catalytic Olefin Polymerization (2000) (18)
- Synthesis of mono-substituted 2,2'-bipyridines. (2002) (18)
- A study of the silanolysis of triphenylsilane and p-methoxyphenol catalysed by (PMe3)4RuH2 and the stoichiometric reactions of (PMe3)4Ru(H)(OC6H4-p-X) (X = Me, OMe) with Ph3SiH (1994) (18)
- Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines. (2015) (18)
- Thermal conversion of 1-methyl-1,2-diethynylcyclopropane to 2-methylbicyclo[3.2.0]hepta-1,4,6-triene (1969) (18)
- Regioselective [2+2] and [4+2] cycloaddition reactivity in an asymmetric niobium(bisimido) moiety towards unsaturated organic molecules. (2015) (17)
- NMR spectra of (C5(CH3)5)IrH2SiMe3Li(pmdeta) and (C5(CH3)5)IrH3Li(pmdeta): the first direct observation of resolved lithium-7-proton coupling (1985) (17)
- Cycloaddition and Nucleophilic Substitution Reactions of the Monomeric Titanocene Sulfido Complex (η5-C5Me5)2(C5H5N)TiS (1998) (17)
- Synthesis of Alkyltantalocene Oxide, Sulfide, and Imide Derivatives: Stereospecific Heteroatom and -group Transfers from Oxiranes, Thiiranes, and Aziridines to Methyltantalocene (1996) (17)
- Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors (2014) (17)
- CARBON-CARBON BOND CLEAVAGE AND IMINOCARBENE FORMATION IN THE THERMAL DECOMPOSITION OF 2H-AZIRINES (1974) (17)
- Kinetically linear vinyl cations in the solvolysis of stereoisomeric 1-iodo-1-cyclopropylpropenes (1970) (17)
- Stereochemistry of olefinic cyclization and solvolytic displacement at vinyl carbon (1974) (17)
- Synthesis of dialkylruthenium nitrosyls and thermal conversion to ruthenium oximate, carboxamide, and cyano complexes (1984) (17)
- Rapid reduction of nitric oxide to dinitrogen by zirconium(II): Kinetic studies on a reaction controlled by gas-liquid transport (1999) (17)
- Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex. (2014) (17)
- A Dramatic Difference in the Reactivities of Alkoxido‐ and Aryloxidorhenium Complexes in Insertion Reactions (1992) (17)
- Mechanism of ligand substitution in an iridium amide complex (1991) (17)
- Synthesis, Structure, and Hydrosilylation Catalysis of a Chiral A-Frame Rhodium(I) Dimer with Cis Diphosphite Ligands (2001) (17)
- Synthesis and reactions of enantiopure (neomenthylcyclopentadienyl)iridium(III) halides with silver salts. A dramatic steric effect on the competition between inter- and intramolecular C-H activation (1994) (16)
- Physical organic studies of organometallic reactions (1980) (16)
- Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes. (2004) (16)
- Application of physical organic methods to the investigation of organometallic reaction mechanisms. (2003) (16)
- Flow pyrolysis and direct and silicon tetrafluoride-sensitized laser-induced decomposition of tetralin. Identification of retro-[2 + 4] cleavage as the primary homogeneous thermal decomposition channel (1980) (16)
- Synthesis of bridging iridium bis(imido) and imido-oxo complexes. Imide and oxygen transfer reactions and hydrogenation of an imido ligand (1993) (16)
- Rapid racemization of an optically active cyclopropene derivative via ring opening, bond rotation, and ring closure (1972) (16)
- Regio- and stereospecific formation of protected allylic alcohols via zirconium-mediated S(N)2' substitution of allylic chlorides. (2007) (16)
- Reactivity of Zirconocene Azametallacyclobutenes: Insertion of Aldehydes, Carbon Monoxide, and Formation of alpha,beta-Unsaturated Imines. Formation and Trapping of [Cp(2)Zr=O] in a [4 + 2] Retrocycloaddition(1). (1996) (16)
- Synthesis and Reactivity of the First Structurally Characterized Heterobimetallic Complex Containing an Unsupported Bridging Sulfur Atom (1989) (16)
- Evidence for the Intervention of Different C−H Activating Intermediates in the Irradiation of (η5-C5Me5)(PMe3)IrH2 and the Reaction of (η5-C5Me5)(PMe3)Ir(H)(Cl) with Strong Base. Detection and Spectroscopic Characterization of (η5-C5Me5)(PMe3)Ir(Li)(Cl), an Intermediate in the Dehydrohalogenation Re (2001) (16)
- Diastereomeric and isotopic scrambling in (hydrido)alkyliridium complexes. Evidence for the presence of a common `alkane complex` intermediate (1995) (16)
- Synthesis, Structure, and Reactivity of the Remarkably Stable Early-Late Binuclear Metal Hydride Cp2Ta(.mu.-CH2)2Ir(Cp*)(H). A Warning Concerning Catalyst Identification in Homogeneous Catalytic Reactions (1994) (15)
- The neighboring group effect of fluorine in the tritium labeling of organic substrates with [Cp*(PMe3)IrMe(CH2Cl2)]+[BArf]−, a cationic iridium(III) complex (2006) (15)
- Photoelectron Spectra of 2,5-Dehydrotropylidene, 3,6-Dehydrooxepin, and Fulvenallene (1979) (15)
- Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. (2017) (15)
- Oxygen-centered hexatantalum tetradecaimido cluster complexes. (2008) (15)
- Reactions of Cp2Ta(CH2)(CH3) with Substituted and Unsubstituted Metal Carbonyls (Groups 7, 8, and 9). Evidence for Intermediates Involved in the Carbon−Carbon Bond-Forming Steps of the Reduction and Deoxygenation of CO (1996) (15)
- Binding of chlorohydrocarbons to metal centers: quantitative evaluation of relative binding constants and structural characterization of the first isolable transition metal-chloromethane adduct. (2001) (15)
- Photo-activation of d(0) niobium imido azides: en route to nitrido complexes. (2016) (15)
- Kinetics and mechanism of decomposition of a benzodicobaltacyclohexene: reversible dinuclear elimination of o-xylylene via a dimetalla-Diels―Alder reaction (1983) (14)
- Vinylmethylene and the ring opening of cyclopropene. Ab initio generalized valence bond and configuration interaction studies (1976) (14)
- Evidence for competitive carbene and diradical pathways in the thermal decomposition of 6,7-dimethyl-2,3-diazabicyclo[3.2.0)hept-2-enes. Absence of a di-.pi.-methane pathway (1972) (14)
- Evidence against the involvement of 0,0-diradical intermediates in the pyrolysis of five-membered ring azo compounds (1972) (14)
- Mild, reversible C-H oxidative addition/reductive elimination in a dinuclear iridium complex (1986) (14)
- Stereospecific Heteroatom and Hetero Group Transfer from Oxiranes, Thiiranes, and Aziridines by a Simple Alkyl Tantalocene (1994) (14)
- Olefination and group transfer reactions of an electron deficient tantalum methylidene complex. (2006) (14)
- Synthesis, crystal and molecular structure, and reactions of the bridging vinylidenedicobalt complex (.mu.-CCH2)(CpCoCO)2. Reaction with molybdenum hydrides to give a heteronuclear cluster complex (1984) (13)
- Effect of surfactant micelles on the stereochemistry and rate of "amsylate" solvolytic displacement reactions in water (1976) (13)
- REVERSIBLE METAL-TO-METAL METHYL TRANSFER IN n5-CYCLOPENTADIENYL(TRIPHENYLPHOSPHINE)DIMETHYLCOBALT(III) (1980) (13)
- Synthesis of Organometallic Heterodinuclear µ-Oxo Complexes by Extrusion of Alkenes from Zirconium/Tungsten Oxaalkyl Complexes (1986) (13)
- CARBON-HYDROGEN ACTIVATION IN COMPLETELY SATURATED HYDROCARBONS: DIRECT OBSERVATION OF M + R-H → M(R)(H) (1982) (13)
- Cyclopentadienyl and Imide Ligand Transfer from Zirconium to Iridium: Can Early Transition Metal Imido Compounds Be Used as Imide Transfer Reagents? (1998) (13)
- Synthesis, Structural Characterization, and Reactivity of Novel Zirconium(IV) Complexes Containing the Tropidinyl Ligand (1997) (13)
- Synthesis and carbon-carbon bond-forming reactions of tungsten, molybdenum, and rhenium enolates (1985) (13)
- C-H ACTIVATION IN COMPLETELY SATURATED HYDROCARBONS: DIRECT OBSERVATION OF M + R-H -> M(R)(H) (1981) (13)
- Inversion component in the solvolytic displacement reactions of alkyl-substituted vinyl trifluoromethanesulfonates (1972) (13)
- Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes. (2004) (13)
- H2 Activation and Direct Access to Terminal Nitride and cyclo-P3 Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate. (2019) (13)
- [(TMEDA)Co(NO)2][BPh4]: A versatile synthetic entry point to four and five coordinate {Co(NO)2}10 complexes (2011) (12)
- Elimination of R-H from iridium acyl hydrides without loss of CO: evidence for the intervention of metal cation/carbanion pairs. (2004) (12)
- Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes. (2011) (12)
- An azo compound route to spiropentane thermolysis intermediates. Formation of vibrationally excited organic molecules in the thermal decomposition of pyrazolines, and evidence concerning the distribution of excess energy in reaction products (1977) (12)
- Mechanisms of energy storage and release. Chemiluminescent valence isomerizations. Evidence for a Dewar benzene intermediate in a biscyclopropenyl to benzene rearrangement (1975) (12)
- Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers. (2020) (12)
- Reaction of Cp2Ta(CH2)CH3 with methyl- and phenylrhenium pentacarbonyl : Wittig-like metathesis of bound carbon monoxide to a C=CH2 (vinylidene) group and NMR evidence for the intervention of a zwitterionic intermediate (1993) (12)
- Stoichiometric carbon–carbon bond formation mediated by well defined Nb(III) complexes (2014) (12)
- Mechanistic Investigation of the Reaction of Iridium Dihydride Complexes with Organic Acid Chlorides (2000) (12)
- Formation of planar-chiral alkylphosphine- and aniline-substituted cyclopentadienyl metal complexes and their reactivity toward electrophiles (2002) (11)
- Regiocontrol of Cyclometalation in a P4Ru(II) System. Unusual Base-Induced Metalation within a Chelate Ring versus Activation of a Methyl Group (2002) (11)
- Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles. (2008) (11)
- Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. (2016) (11)
- Photochemical Reactivity of Group 9 Metal Pinacolate Complexes (2001) (11)
- Activation of Organic Disulfides by a Paramagnetic Heterobimetallic Tantalum/Cobalt Complex and a Comparison of Their Reactions with Cobaltocene. Evidence for a Dependence of Mechanism on the Electronic Properties of the Disulfide (1996) (11)
- An iridium difluoroketene complex: synthesis and isolation. (2004) (11)
- Evidence for the formation of 1,3-dehydrobenzene diradicals by silicon shift in 1,4-dehydrobenzenes at high temperature (1979) (11)
- Reactivity of an early-late heterobimetallic complex toward phosphines: synthesis, structure, and reactivity of a cationic tantalum-palladium compound with a free cyclopentadienyl counteranion (1993) (11)
- Memory effects in multiple carbonium ion rearrangements. IV. Solvolytic studies of the tricyclo[3.2.1.02,7]oct-4-yl system (1969) (11)
- Stereochemistry of metallacycle formation in the double alkylation of bis(triphenylphosphine)nitrogen(1+) bis(.eta.5-cyclopentadienyl)-di-.mu.-carbonyldicobaltate with .alpha.,.gamma.-diiodoalkanes (1983) (10)
- Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes. (2018) (10)
- Reaction of a Tantalum Alkylidene Complex with Dinuclear Metal Carbonyls: Formation of C3 ligands (1993) (10)
- Ozonolysis-based route to the in situ formation of aldehyde-bearing self-assembled monolayer surfaces. (2008) (10)
- Effect of micelles on the rate and stereochemistry of solvolytic displacement reactions (1975) (10)
- An x-ray photoelectron spectroscopic study of transition metal .mu.-methylene complexes and related compounds (1982) (10)
- On the nature of diradical intermediates formed during the thermal and photochemical decomposition of bicyclic azo-compounds (1971) (10)
- Synthesis of tantalum fluoride complexes supported by bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [PhC(NSiMe3)2]2TaF3 and [PhC(NSiMe3)2]2TaFPh2 (2000) (10)
- Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic amines. (2005) (10)
- An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage (2020) (10)
- Zehngliedrige cyclische Endiine mit bemerkenswerten chemischen und biologischen Eigenschaften (1992) (10)
- Stereoselective Synthesis of Chiral Zirconocenes from Doubly Substituted, Donor Functionalized Cyclopentadienes via Helical Chelate Complexes (1995) (10)
- Enantioselective Kinetic Resolution/Desymmetrization of Para-Quinols: A Case Study in Boronic-Acid-Directed Phosphoric Acid Catalysis. (2019) (10)
- Addition organischer 1,3‐dipolarer Verbindungen an eine Bindung zwischen frühem und spätm Übergangsmetall (Zr‐Ir): Mechanismus der Stickstoffabspaltung aus einem Organoazido‐Komplex unter Bildung eines Komplexes mit verbrückenden Imidoliganden (1996) (10)
- C-F sp(2) bond functionalization mediated by niobium complexes. (2015) (9)
- Stereoselektive Synthese chiraler Zirconocene aus disubstituierten, donorfunktionalisierten Cyclopentadien-Derivaten über helicale Chelatkomplexe† (1995) (9)
- Insertion of unactivated acetylenes into the metal-aryl bond of bis(triphenylphosphine)phenylbromonickel(II) (1977) (9)
- Reproduzierbarkeit in der chemischen Forschung (2016) (9)
- Formation of dinuclear rhodium dialkyl complexes by alkylation of a new dinuclear dianion and by nucleophilic addition of alkyllithium reagents across a metal-metal double bond (1985) (9)
- Synthesis, structural characterization, and quantitative basicity studies of lithium zirconimidate complexes. (2008) (9)
- Reductions of a Rhenium(III) Terminal Oxo Complex by Isocyanides and Carbon Monoxide (2018) (9)
- Synthesis and physical properties of a dinuclear tantalum/cobalt radical with spin localized at one metal center (1988) (9)
- Stereospecific double alkylation of diphenylacetylene by .eta.5-cyclopentadienyl(triphenylphosphine)dimethylcobalt(III). Evidence for noninterconvertible diastereomeric complexes in cobalt-catalyzed isomerization of alkenes, and comments on factors effecting rates of reductive elimination reactions (1978) (9)
- Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy. (2013) (9)
- Chemistry of methylnorbornyl cations. V. Solvent capture and hydride shift in the 3-endo-methyl series (1967) (9)
- Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine-Borane Cofactor. (2021) (9)
- Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. (2019) (8)
- Synthesis, nuclear magnetic resonance observation, basicity, and reactions of bicyclo[3.2.0]heptatrienide iron complexes (1977) (8)
- Synthesis and coordination chemistry of tri-substituted benzamidrazones. (2011) (8)
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- BEWEIS FUER EINEN KOMPETITIVEN CARBEN- UND DIRADIKAL-MECHANISMUS BEI DER THERMISCHEN ZERS. VON 6,7-DIMETHYL-2,3-DIAZABICYCLO(3,2,0)HEPTENEN-(2), ABWESENHEIT EINES ′DI-PI-METHAN′-MECHANISMUS (1972) (0)
- BLDG. VON 1,4-PENTADIEN UND VINYLCYCLOPROPAN BEI DER THERMISCHEN UND PHOTOCHEMISCHEN ZERS. VON 2,3-DIAZABICYCLO(3,2,0)HEPTEN-(2) (1972) (0)
- ANWENDUNG DER EHT-MO AUF EIGENSCHAFTEN VON VINYLKATIONEN, KONFORM.-ENERGIEN EINIGER 1-CYCLOPROPYL-VINYLKATIONEN UND VERGLEICH DER S(N)2-SUBSTITUTIONEN AM GESAETTIGTEN UND VINYL-KOHLENSTOFF (1971) (0)
- P-BENZYN, ERZEUGUNG ALS INTERMEDIAERPRODUKT BEI EINER THERMISCHEN ISOMERISIERUNGSRK. UND BEWEIS DER BENZOLDIYL-(1,4)-STRUKTUR DURCH ABFANGREAKTIONEN (1972) (0)
- STEREOCHEMIE DER SOLVOLYTISCHEN SUBSTITUTION AM VINYLKOHLENSTOFF, REAKTIONEN DES DURCH AG-KATALYSIERTE IONISATION VON CIS- UND TRANS-1-CYCLOPROPYL-1-JOD-PROPEN UND HEXADIEN-(3,4)-YL-(1)-JODID GEBILDETEN 1-CYCLOPROPYL-2-METHYL-VINYLKAT (1971) (0)
- 3,6-DEHYDROOXEPIN, EIN FUROCYCLOBUTADIEN (1973) (0)
- INVERSIONSKOMPONENTE BEI SOLVOLYTISCHEN SUBSTITUTIONSREAKTIONEN VON ALKYLSUBSTITUIERTEN VINYLTRIFLUORMETHANSULFONATEN (1972) (0)
- BASENKATALYSIERTE UMLAGERUNG VON 3‐BROM‐BICYCLO(3,2,1)OCTADIEN‐(2,6) ZU ENDO‐6‐AETHINYL‐BICYCLO(3,1,0)HEXEN‐(2), MOEGLICHE ZWISCHENSTUFE EINES HOMOKONJUGIERTEN CARBENS (1970) (0)
- LANGSAME SOLVOLYSE VON 4-TRICYCLYL-TRIFLUORMETHANSULFONAT, WECHSELWIRKUNG ZWISCHEN DER FLAECHE EINES CYCLOPROPANRINGES MIT POSITIV GELADENEM KOHLENSTOFF (1970) (0)
- Scope and Mechanism of Alkene Hydrogenation/Isomerization Catalyzed by Complexes of the Type R2E(CH2)2M(CO)(L) (R: Cp, Me, Ph; E: P, Ta; M: Rh, Ir; L: CO, PPh3). (1993) (0)
- A Phosphorus-Carbon Bond Cleavage Reaction of Coordinated Trimethylphosphine in (PMe3)4Ru(OC6H4Me)2. (1990) (0)
- Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title High Precision Measurement of Isotope Effects on Noncovalent Host-Guest Interactions Permalink (2010) (0)
- An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation w (2009) (0)
- Heats of Reaction of Cp*(PMe3)Ir(R)(H) (R: C6H5, C6H11, and H) with HCl, CCl4, CBr4, and CH3I. A Solution Thermochemical Study of the C-H Insertion Reaction. (1987) (0)
- A Reactive Organometallic Oxo Intermediate, Cp*2Zr=O: Generation and Subsequent Trapping Reactions Forming Alkyne and Nitrile Addition Products. (1990) (0)
- Synthesis of P-Stereogenic Phosphines (2006) (0)
- Synthesis of Alkylruthenium Nitrosyl Complexes. Migratory Insertion to Coordinated Nitric Oxide and the Mechanism of the Conversion of the Resultant Nitrosoalkyl Compounds to Oximate, Carboxamide, and Cyano Compounds. (1989) (0)
- Carbon-carbon bond forming process mediated by organotransition metal complexes (1980) (0)
- Rhenium 2-Oxoalkyl (Enolate) Complexes: Synthesis and Carbon-Carbon Bond-Forming Reactions with Nitriles. (1990) (0)
- Enantioselective Intramolecular Hy droarylation of Alkenes via Directed C-H Bond Activation (2009) (0)
- Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation. (2006) (0)
- Lawrence Berkeley National Laboratory Recent Work Title ACTIVATION OF ALKANES IN HOMOGENEOUS SOLUTION USING ORGANOTRANSITION METAL COMPLEXES Permalink (2013) (0)
- CCDC 1505082: Experimental Crystal Structure Determination (2016) (0)
- SYNTHESIS AND REACTIONS OF HYDRIDO(η1-ALLYL)- AND HYDRIDO(η3-ALLYL)IRIDIUM COMPLEXES (1985) (0)
- Synthesis of Dinuclear Anionic Complexes (Cp*Rh(CO))- 2 and (Cp*Rh(CO))2- 2 by Dissolving Metal Reduction and R(Cp*Rh(CO))- 2 by Addition of Alkyllithium Reagents Across the Metal-Metal Double Bond of (Cp*Rh(CO))2. Stereoselective Syn (1987) (0)
- Conversion of Epoxides to Rhodium Enolates: Direct Evidence for a Mechanism Involving Initial C-H Activation. (1990) (0)
- Heterobimetallic-Mediated Dinitrogen Functionalization: N-C Bond Formation at Rhenium-Group 9 Diazenido Complexes. (2022) (0)
- Lawrence Berkeley National Laboratory Recent Work Title MECHANISM OF TOE REACTION OF MOLYBDENUM CARBONYL ALKYLS WITH MOLYBDENUM HYDRIDES : A MODEL FOR THE ALDEHYDE-PRODUCING STEP OF THE OXO PROCESS Permalink (2013) (0)
- Inter- and Intramolecular Insertion of Rhenium into Carbon-Hydrogen Bonds. (1986) (0)
- CHARACTERIZATION AND EVIDENCE FOR ALKYLATION OF HYDRIDODICARBONYLCYCLOPENTADIENYLRHENATE(1-) ION (CPRE(CO)2H-) IN THE CONVERSION OF DIHYDRODICARBONYLCYCLOPENTADIENYLRHENIUM (CPRE(CO)2H2) TO CPRE(CO)2R2. SYNTHESIS OF A RHENACYCLOPENTAN (1984) (0)
- Insertion of (η5-C5Me5)(PMe3)Ir into the C-H Bonds of Functionalized Organic Molecules: A C-H Activation Route to 2-Oxa- and 2-Azametallacyclobutanes, Potential Models for Olefin Oxidation Intermediates. (1988) (0)
- Asymmetric Catalytic Synthesis of P‐Stereogenic Phosphines via a Nucleophilic Ruthenium Phosphido Complex. (2006) (0)
- Molecular Recognition of Iminium Ions in Water (2008) (0)
- DIE NATUR DER DIRADIKAL-ZWISCHENSTUFEN WAEHREND DER THERMISCHEN UND PHOTOCHEMISCHEN ZERS. VON BICYCLISCHEN AZO-VERBINDUNGEN (1971) (0)
- Title Deconvoluting the Role of Charge in a Supramolecular Catalyst Permalink (2018) (0)
- Encapsulated water in a supramolecular $Ga_4$$L_6$$^{-12}$ cage is neither ice- nor bulk water-like (2020) (0)
- Rhodium Alkoxide Complexes: Formation of an Unusually Strong Intermolecular Hydrogen Bond in (PMe3)3Rh-Otol(HOtol). (1988) (0)
- SYNTHESIS AND REACTIONS OF A BINUCLEAR COBALT BRIDGING METHYLENE (μ-CH2) COMPLEX. CONVERSION TO μ-CH2 RHODIUM/COBALT AND RHODIUM/RHODIUM COMPLEXES AND METHYLENE TRANSFER TO ETHYLENE INVOLVING ACTIVATION BY A SECOND METAL COMPLEX (1981) (0)
- Rhodium-Catalyzed Direct C—H Addition of 4,4-Dimethyl-2-oxazoline to Alkenes. (2004) (0)
- Synthesis and Chemistry of a Dinuclear Iridium Bis‐μ‐oxo Complex: Observation of Oxygen Transfer and Phosphorus‐Carbon Bond Cleavage. (1989) (0)
- Catalytic Deprotection of Acetals in Basic Solution with a Self‐Assembled Supramolecular “Nanozyme”. (2008) (0)
- Pt‐Catalyzed C—C Activation Induced by C—H Activation. (2014) (0)
- Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title Simultaneously Bound Guests and Chiral Recognition : a Chiral Self-Assembled Supramolecular Host Encapsulates Hydrophobic (2009) (0)
- Application of Fundamental Organometallic Chemistry to the Development of a Gold‐Catalyzed Synthesis of Sulfinate Derivatives. (2014) (0)
- Rh-Catalyzed C-H Activation Route to Bicyclic Imidazoles (2007) (0)
- NMR Spectra of (C5(CH3)5)IrH2SiMe3Li (pmdeta) and (C5(CH3)5)IrH3Li(pmdeta): The First Direct Observation of Resolved7Li -1H Coupling (1986) (0)
- REVERSIBLE METAL-TO-METAL METHYL TRANSFER IN η5-CYCLOPENTADIENYL(TRIPHENYLPHOSPHINE)DIMETHYLCOBALT(III) (1980) (0)
- Synthesis of (+)-Lithospermic Acid (2006) (0)
- Synthesis of Dialkyl- and Alkylacylrhenium Complexes by Alkylation of Anionic Rhenium Complexes at the Metal Center. Mechanism of a Double Carbonylation Reaction That Proceeds via the Formation of Free Methyl Radicals in Solution. (1989) (0)
- Application of Physical Organic Methods to the Investigation of Organometallic Reaction Mechanisms (2003) (0)
- Evidence for the intervention of different C-H activating intermediates in the irradiation of (eta(5)-C5Me5)(PMe3)IrH2 and the reaction of(eta(5)-C5Me5)(PMe3)Ir(H)(Cl) with strong base. Detection and spectroscopic characterization of (eta 5-C5Me5)(PMe3)Ir(Li)(Cl), an intermediate in the dehydrohalog (2000) (0)
- Mild, Reversible C-H Oxidative Addition/Reductive Elimination in a Dinuclear Iridium Complex. (1987) (0)
- Rh-Catalyzed C-H Addition of Quinazolines to Alkenes (2006) (0)
- Titelbild: Supramolecular Catalysis of a Unimolecular Transformation: Aza-Cope Rearrangement within a Self-Assembled Host (Angew. Chem. 48/2004) (2004) (0)
- Reaction of a Tantalum Alkylidene Complex with Dinuclear Metal Carbonyls: Formation of C3 Ligands. (1993) (0)
- C-H Oxidative Addition and Reductive Elimination Reactions in a Dinuclear Iridium Complex. (1989) (0)
- Synthesis of Allylic Amines from Allylic Ethers and Zirconocene Imides (2006) (0)
- CATIONIC CYCLIZATION INVOLVING A REMOTE ALLENE FUNCTION IN THE TRIFLUOROETHANOLYSIS OF HEPTA-5,6-DIENYL TOLUENE-P-SULPHONATE (1973) (0)
- Letter Written by Robert G. Bergman to the Bryant College Service Club Dated January 14, 1945 (1943) (0)
- Enantioselective Synthesis of C2 and C1 Dienes (2011) (0)
- Synthesis of Mono‐Substituted 2,2′‐Bipyridines. (2002) (0)
- Selective Organic and Organometallic Reactions in Water-Soluble Host-Guest Supramolecular Systems (2008) (0)
- Platinum Group Thiophenoxyimine Complexes: Syntheses, Crystallographic and Computational Studies of Structural Properties (2006) (0)
- Asymmetric Intramolecular Alkylation of Chiral Aromatic Imines via Catalytic C—H Bond Activation. (2008) (0)
- Total Synthesis of (+)‐Lithospermic Acid by Asymmetric Intramolecular Alkylation via Catalytic C—H Bond Activation. (2006) (0)
- Personal Statement for Eric Jacobsen Special Issue of ASC on the Occasion of his 60th Birthday (2020) (0)
- Executive compensation and transparency (2004) (0)
- PHOTOCHEMISTRY OF ETA(5)-CYCLOPENTADIENYLCOBALT DICARBONYL AND THERMAL DECOMPOSITION OF DERIVED COBALT CLUSTER COMPLEXES, ISOLATION OF BIS(ETA(5)-CYCLOPENTADIENYLCOBALT)TRICARBONYL, TRIS(ETA(5)-CYCLOPENTADIENYLCOBALT MONOCARBONYL) AND (1975) (0)
- Synthesis and Characterization of [(η5- C5H5)V(CO)3H]- , a New Anionic Vanadium Carbonyl Hydride, and a Study of Its Reduction Reaction with Organic Halides. Oberservation of a Free-Radical Chain Process Having an Extremely Rapid Meta (1978) (0)
- STEREOCHEMISTRY OF METALLACYCLE FORMATION IN THE DOUBLE ALKYLATION OF BIS(TRIPHENYLPHOSPHINE)NITROGEN(1+) BIS(η5-CYCLOPENTADIENYL)-DI-μ-CARBONYLDICOBALTATE WITH α,Γ-DIIODOALKANES (1983) (0)
- Regio- and Stereospecific Formation of Protected Allylic Alcohols via Zirconium-Mediated SN2′ Substitution of Allylic Chlorides. (2008) (0)
- OXIDATIVE ADDITION OF ORGANOTRANSITION METAL COMPLEXES TO THE C-H BONDS IN ORGANIC MOLECULES (1985) (0)
- Intermolecular Coupling of Isomerizable Alkenes to Heterocycles via Rhodium-Catalyzed C—H Bond Activation. (2003) (0)
- Cover Picture: Supramolecular Catalysis of a Unimolecular Transformation: Aza‐Cope Rearrangement within a Self‐Assembled Host (Angew. Chem. Int. Ed. 48/2004) (2004) (0)
- Intermolecular Coupling of Alkenes to Heterocycles via C—H Bond Activation. (2005) (0)
- Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with α,β- Unsaturated Ketones and Imines (2009) (0)
- Catalytic Deprotection of Acetals In Strongly Basic Solution Using a Self-Assembled Supramolecular "Nanozyme" (2008) (0)
- Synthesis of a Highly Reactive (Benzyne)ruthenium Complex: C-C, C-H, N-H, and O-H Activation Reactions. (1989) (0)
- Enantioselective Hydroarylation of Alkenes via C-HActivation (2008) (0)
- Reversible CH activation of an N-methyl group in a bis-Zr(IV) diazametallacycle: generation of an end-on, side-on coordinated bridging alkylideneamido ligand (1999) (0)
- REAKTIONSFAEHIGE 1,4‐DEHYDRO‐AROMATEN (1973) (0)
- Rapid, Reversible Intramolecular C-H Oxidative Addition and Hydrogen Exchange in a Heterodinuclear “Early-Late” Transition-Metal Complex. (1988) (0)
- CHEMICAL AND ELECTROCHEMICAL REDUCTION OF (1977) (0)
- Rh-Catalyzed De Novo Synthesis of Pyridines from Terminal Alkynes and Ketoximes (2012) (0)
- Stoichiometric and Catalytic Deuterium and Tritium Labeling of “Unactivated” Organic Substrates with Cationic Ir(III) Complexes. (2004) (0)
- Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation Permalink (2010) (0)
- Reductive Elimination Leading to Transient (η5-C5Me5)Ru(NO). Trapping, Dimerization, and Oxidative Addition Reactions of This Intermediate and the Effect of Structural Variation on Its Generation. (1987) (0)
- Group 5 Chemistry Supported by β‐Diketiminate Ligands (2016) (0)
- Synthesis of a First-Row Transition Metal Parent Amido Complex and Carbon Monoxide Insertion into the Amide N−H Bond [J. Am. Chem. Soc. 2003, 125, 8984−8985]. (2003) (0)
- Protected Allylic Alcohols via Selective SN2′ Substitution of Allylic Chlorides (2008) (0)
- Additions and Corrections - Synthesis and Reactions of a Binuclear Cobalt Bridging Methylene (μ-CH2) Complex. Conversion to μ-CH2 Rh/Co and Rh/Rh Complexes and Methylene Transfer to Ethylene Involving Activation by a Second Metal Complex (1981) (0)
- Expedient Synthesis of N-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinylic C—H Bonds with Isocyanates. (2011) (0)
- A MODEL THE ALDEHYDE-PRODUCING THE (2013) (0)
- MECHANISM OF THE THERMAL CONVERSION OF 3,3′‐BICYCLOPROPENYLENE INTO BENZENE DERIVATIVES (1976) (0)
- SYNTHESIS OF AN OPTICALLY ACTIVE CYCLOPROPENE AND KINETICS OF ITS THERMAL RACEMIZATION IN THE GAS PHASE, EVIDENCE FOR THE INTERMEDIACY OF A VINYLCARBENE (1973) (0)
- FLOW PYROLYSIS AND DIRECT AND SILICON TETRAFLUORIDE-SENSITIZED LASER-INDUCED DECOMPOSITION OF TETRALIN. IDENTIFICATION OF RETRO-(2 + 4) CLEAVAGE AS THE PRIMARY HOMOGENEOUS THERMAL DECOMPOSITION CHANNEL (1980) (0)
- Zirconium-Mediated SN2′ Substitution of Allylic Ethers: Regio- and Stereospecific Formation of Protected Allylic Amines. (2006) (0)
- Reactions of (MeC{sub 5}H{sub 4}){sub 3}U({italic t}-Bu): Intermolecular Fluorine Atom Abstraction from Fluorocarbons Including Saturated Perfluorocarbons (1993) (0)
- MECHANISM OF TOE REACTION OF MOLYBDENUM CARBONYL ALKYLS WITH MOLYBDENUM HYDRIDES: A MODEL FOR THE ALDEHYDE-PRODUCING STEP OF THE OXO PROCESS (1983) (0)
- SYNTHESIS, STRUCTURE AND REACTIVITY OF (η5-CYCLOPENTADIENYL)NITROSYLCOBALT (1985) (0)
- Lawrence Berkeley National Laboratory Recent Work Title DIRECT EVIDENCE FOR SOLVENT COORDINATION IN MIGRATORY CO INSERTION Permalink (2012) (0)
- Supramolecular Catalysis in Metal-Ligand Cluster Hosts (2015) (0)
- STEREOSPECIFIC DOUBLE ALKYLATION OF DIPHENY (1978) (0)
- Synthesis of Organometallic Heterodinuclear μ-Oxo Complexes by Extrusion of Alkenes from Zirconium/Tungsten Oxaalkyl Complexes. (1987) (0)
- Title An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol (2009) (0)
- Palladium-Catalyzed Arylation of Silylphosphines (2008) (0)
- Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory Title Acid Catalysis in Basic Solution : A Supramolecular Host Promotes Orthoformate Hydrolysis Permalink (2007) (0)
- Synthesis and Reactivity of the First Structurally Characterized Heterobimetallic Complex Containing an Unsupported Bridging Sulfur Atom. (1989) (0)
- ACTIVATION OF ALKANES IN HOMOGENEOUS SOLUTION USING ORGANOTRANSITION METAL COMPLEXES (1983) (0)
- Synthesis of (-)-Incarvillateine (2008) (0)
- Rhodium‐Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines. (2012) (0)
- Additions and Corrections - The Chemistry of Methylnorbornyl Cations. V. Solvent Capture and Hydride Shift in the 3-endo-Methyl Series (1967) (0)
- Intramolecular Double C-H Activation in FvM (2004) (0)
- Rhodium(III)‐Catalyzed Indazole Synthesis by C—H Bond Functionalization and Cyclative Capture. (2013) (0)
- Ma_terials & Molecular Research OXIDATIVE ADDITION OF RHODIUM TO ALKANE C-H BONDS: ENHANCEMENT IN SELECTIVITY AND ALKYL GROUP FUNCTIONALIZATION, AND THE FIRST STRUCTURALLY CHARACTERIZED DERIVATIVE OF A C-H INSERTION PROPUCT (2013) (0)
- Analysis of the Rate Retardation by 6 Substituents in exo-Norbornyl Solvolyses1 (1966) (0)
- Activation ofAlkanes with Organotransition MetalComplexes (2016) (0)
- REACTION OF η5‐CYCLOPE (1979) (0)
- SYNTHESIS, NUCLEAR MAGNETIC RESONANCE OBSERVATION, BASICITY, AND REACTIONS OF BICYCLO(3.2.0)HEPTATRIENIDE IRON COMPLEXES (1977) (0)
- SCHNELLE RACEMISIERUNG VON OPTISCH AKTIVEM 1,3-DIAETHYL-CYCLOPROPEN DURCH RINGOEFFNUNG, BINDUNGSROTATION UND RINGSCHLUSS (1972) (0)
- Tungsten and Molybdenum 2-Oxaallyl (η1-(C)-Enolate) Complexes: Functional Group Transformations, Photochemical Aldol Reactions, and Alkyne/CO Migratory Insertion Reactions. (1987) (0)
- Letter Written by Robert G. Bergman to the Bryant College Service Club Dated December 9, 1942 (1942) (0)
- Synthesis and Physical Properties of a Dinuclear Tantalum-Cobalt Radical with Spin Localized at One Metal Center. (1988) (0)
- PREPARATION AND REACTIONS OF TETRAHYDRIDO (PENTAMETHYL-CYCLOPENTADIENYL) IRIDIUM: A NOVEL IRIDIUM(V) (1983) (0)
- Synthesis, crystal and molecular structure, and chemistry of (.mu.-(trimethylene)bis(.eta.-cyclopentadienyl)bis(.mu.-carbonyl)dicobalt, a five-membered dicobaltacycle (1982) (0)
- Carbon-Carbon Bond Forming Reactions of Rhenium Enolates with Terminal Alkynes. Evidence for an Alkyne C-H Oxidative Addition Mechanism and Observation of Highly Stereoselective Base-Catalyzed Proton Transfer Reactions in Rhenium Meta (1990) (0)
- Lawrence Berkeley Laboratory Materials & Molecular Research Division OXIDATIVE ADDITION OF SOLUBLE IRIDIUM AND RHODIUM COMPLEXES TO CARBON-HYDROGEN BONDS IN ALKANES (2013) (0)
- Rh-Catalyzed C-H Activation Route to 2-Alkylpyridines and 2-Alkylquinolines (2007) (0)
- Direct Arylation of a-Substituted Pyridines and Quinolines (2009) (0)
- Engendering reactivity at group 5-heteroatom multiple bonds via π-loading (2022) (0)
- Heidelberg Forum of Molecular Catalysis Molecular Catalysis (2009) (0)
- Synthesis, Structural Characterization and Chemistry of aMonomeric Iridium Carbyne Complex (1998) (0)
- Nitrogen-Containing Heterocycle Synthesis Initiated by Rh(III)-Catalyzed C−H Activation (2013) (0)
- Does Size Really Matter? The Steric Isotope Effect in a Supramolecular Host- Guest System** (2009) (0)
- CHEMICAL REDUCTION OF η5‐CYCLOPENTADIENYLDICARBONYLRHODIUM. CRYSTAL AND MOLECULAR STRUCTURE OF AN ANIONIC TRINUCLEAR RHODIUM CLUSTER WITH “SEMI‐TRIPLE‐BRIDGING” CARBONYL LIGANDS (1979) (0)
- Synthesis of an (η3-Allyl)(hydrido)iridium Complex and Its Reactions with Arenes and Alkanes. Sequential Intermolecular C-H Oxidative Addition and Hydride-to-Alkene Migratory Insertion Reactions. (1988) (0)
- Conversion de glycérol issu de la production de biodiesel en alcool allylique (2008) (0)
- Selective Transformations of Organic Compounds by Imidozirconocene Complexes (2003) (0)
- Does Size Really Matter? The Steric Isotope Effect in a Supramolecular Host- Guest System** (2009) (0)
- Synthesis and Reactivity of (η5-C5Me5)(PMe3)Ir(CH2): A Monomeric (Pentamethylcyclopentadienyl)iridium Methylene Complex. (1989) (0)
- (NII) Novel Catalytic, Synthesis Methods for Main Group (2014) (0)
- Generation and Trapping of the Diphenylhydrazido(2-) Complex Cp2Zr(N2Ph2). Insertion of Internal Alkynes into a Metal-Nitrogen Bond, Leading to 2,3-Diazametallacyclopentenes. (1990) (0)
- A Physical Organic Road to Organometallic C-H Oxidative Addition Reactions (1991) (0)
- Oxidative addition of C--H bonds in organic molecules to transition metal centers (1989) (0)
- Inside Cover: Does Size Really Matter? The Steric Isotope Effect in a Supramolecular Host–Guest Exchange Reaction (Angew. Chem. Int. Ed. 21/2010) (2010) (0)
- Rhodium‐Catalyzed Enantioselective Cyclization of Substituted Imidazoles via C—H Bond Activation. (2009) (0)
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