Robert H. Grubbs
#5,568
Most Influential Person
Nobel prize winning American chemist
Why Is Robert H. Grubbs Influential?
(Suggest an Edit or Addition)Grubbs is the Victor and Elizabeth Atkins Professor of Chemistry at the California Institute of Technology (Caltech). He received his bachelor of science in Chemistry at the University of Florida in 1963. He received his master’s degree from Florida in 1965. Grubbs got his Ph.D. in Chemistry from Columbia University in New York City in 1968.
Grubbs’s work in chemistry has focused on organometallic chemistry, a relatively new field at the time of his initial research efforts in the late 1960s. He is also a specialist in synthetic chemistry, an exciting field that studies the structure, properties, and reactions of organic compounds. His work has important application for the creation of polymers, pharmaceuticals, and petrochemicals. He is known for developing a family of catalysts, one of which bears his name: the Grubbs catalyst.
Grubbs won the Nobel Prize in Chemistry in 2005, along with Richard R. Schrock and Yves Chauvin. In addition, Grubbs became a member of the National Academy of Sciences in 1989 and the American Academy of Arts and Sciences in 1994. In 2009, he became Fellow of the American Chemical Society.
Featured in Top Influential Chemists Today
According to Wikipedia, Robert Howard Grubbs ForMemRS was an American chemist and the Victor and Elizabeth Atkins Professor of Chemistry at the California Institute of Technology in Pasadena, California. He was a co-recipient of the 2005 Nobel Prize in Chemistry for his work on olefin metathesis.
Robert H. Grubbs's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- The development of L2X2Ru=CHR olefin metathesis catalysts: an organometallic success story. (2001) (2569)
- Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands. (1999) (2398)
- Safe and Convenient Procedure for Solvent Purification (1996) (1862)
- Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts. (2010) (1551)
- Recent advances in olefin metathesis and its application in organic synthesis (1998) (1509)
- Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity (1996) (1400)
- Handbook of metathesis (2003) (1203)
- A general model for selectivity in olefin cross metathesis. (2003) (1119)
- Living ring-opening metathesis polymerization (2007) (1083)
- A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR′)(PR3)2] and Its Reactions (1995) (1034)
- Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture). (2006) (888)
- Mechanism and activity of ruthenium olefin metathesis catalysts. (2001) (849)
- A practical and highly active ruthenium-based catalyst that effects the cross metathesis of acrylonitrile. (2002) (686)
- Ring-Closing Metathesis and Related Processes in Organic Synthesis (1995) (683)
- Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media (1992) (663)
- Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands (1999) (624)
- Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts (1993) (503)
- Prevention of undesirable isomerization during olefin metathesis. (2005) (500)
- Well-defined ruthenium olefin metathesis catalysts: Mechanism and activity (1997) (464)
- Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization (1998) (461)
- An "Endless" Route to Cyclic Polymers (2002) (455)
- Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses (2000) (423)
- Array-based vapor sensing using chemically sensitive, carbon black-Polymer resistors (1996) (411)
- Highly Efficient Synthesis of Covalently Cross-Linked Peptide Helices by Ring-Closing Metathesis. (1998) (395)
- Catalytic ring-closing metathesis of functionalized dienes by a ruthenium carbene complex (1993) (390)
- Efficient synthesis of narrowly dispersed brush copolymers and study of their assemblies: the importance of side chain arrangement. (2009) (386)
- Synthesis and activity of ruthenium alkylidene complexes coordinated with phosphine and N-heterocyclic carbene ligands. (2003) (371)
- PHENYL-PERFLUOROPHENYL STACKING INTERACTIONS : TOPOCHEMICAL 2+2 PHOTODIMERIZATION AND PHOTOPOLYMERIZATION OF OLEFINIC COMPOUNDS (1998) (342)
- Application of Ring-Closing Metathesis to the Synthesis of Rigidified Amino Acids and Peptides (1996) (335)
- Controlled living ring-opening-metathesis polymerization by a fast-initiating ruthenium catalyst. (2003) (325)
- Decomposition of ruthenium olefin metathesis catalysts. (2007) (325)
- Decomposition of a key intermediate in ruthenium-catalyzed olefin metathesis reactions. (2004) (319)
- New insights into the mechanism of ruthenium-catalyzed olefin metathesis reactions. (2001) (316)
- A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts (2001) (310)
- Polymer synthesis and organotransition metal chemistry. (1989) (308)
- Tandem catalysis: the sequential mediation of olefin metathesis, hydrogenation, and hydrogen transfer with single-component Ru complexes. (2001) (307)
- Improved ruthenium catalysts for Z-selective olefin metathesis. (2012) (305)
- Core-clickable PEG-branch-azide bivalent-bottle-brush polymers by ROMP: grafting-through and clicking-to. (2011) (298)
- Phenyl–Perfluorophenyl Stacking Interactions: A New Strategy for Supermolecule Construction (1997) (287)
- Enantioselective ruthenium-catalyzed ring-closing metathesis. (2001) (279)
- New Approaches to Olefin Cross-Metathesis (2000) (264)
- Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst (2015) (261)
- Highly active water-soluble olefin metathesis catalyst. (2006) (258)
- Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers (2009) (257)
- Drug-loaded, bivalent-bottle-brush polymers by graft-through ROMP. (2010) (256)
- Chelated ruthenium catalysts for Z-selective olefin metathesis. (2011) (249)
- Titanacyclobutanes derived from strained, cyclic olefins: the living polymerization of norbornene (1986) (249)
- Ruthenium Carbene-Based Olefin Metathesis Initiators: Catalyst Decomposition and Longevity (1999) (242)
- A Standard System of Characterization for Olefin Metathesis Catalysts (2006) (240)
- Synthesis, structure, and activity of enhanced initiators for olefin metathesis. (2003) (240)
- Eine Reihe definierter Metathesekatalysatoren – Synthese von und Reaktionen mit [RuCl2 ( CHR′)(PR3)2] (1995) (231)
- Recent advances in ruthenium-based olefin metathesis. (2018) (226)
- The application of catalytic ring-closing olefin metathesis to the synthesis of unsaturated oxygen heterocycles (1992) (224)
- Highly efficient ruthenium catalysts for the formation of tetrasubstituted olefins via ring-closing metathesis. (2007) (217)
- Synthesis of trisubstituted alkenes via olefin cross-metathesis. (1999) (214)
- 50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules (2017) (212)
- Array-based vapor sensing using chemically sensitive carbon black-polymer resistors (1997) (205)
- Living Ring-Opening Metathesis Polymerization in Aqueous Media Catalyzed by Well-Defined Ruthenium Carbene Complexes (1996) (202)
- Metathesis of Electron-Rich Olefins: Structure and Reactivity of Electron-Rich Carbene Complexes (2002) (197)
- The synthesis of nitrogen heterocycles via catalytic ring-closing metathesis of dienes (1992) (195)
- Rapid self-assembly of brush block copolymers to photonic crystals (2012) (191)
- Ring-closing metathesis of olefinic peptides: design, synthesis, and structural characterization of macrocyclic helical peptides. (2001) (190)
- Synthesis of isocyanate-based brush block copolymers and their rapid self-assembly to infrared-reflecting photonic crystals. (2012) (189)
- Titanium-mediated methylene-transfer reactions. Direct conversion of esters into vinyl ethers (1980) (189)
- Purification technique for the removal of ruthenium from olefin metathesis reaction products (1999) (188)
- Highly active chiral ruthenium catalysts for asymmetric ring-closing olefin metathesis. (2006) (187)
- Ring-Opening Metathesis Polymerization from Surfaces (1999) (184)
- Catalytic Ring-Closing Metathesis of Dienes: Application to the Synthesis of Eight-Membered Rings (1995) (184)
- Olefinmetathesekatalysatoren zur Synthese von Molekülen und Materialien (Nobel‐Vortrag) (2006) (182)
- Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes. (1997) (181)
- Catalytic reduction of olefins with a polymer-supported rhodium(I) catalyst (1971) (181)
- Synthesis and Characterization of New Ruthenium-Based Olefin Metathesis Catalysts Coordinated with Bidentate Schiff-Base Ligands (1998) (180)
- Precisely tunable photonic crystals from rapidly self-assembling brush block copolymer blends. (2012) (180)
- α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts (1996) (179)
- Catalytic organometallic chemistry in water: the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives (1988) (178)
- Synthesis of functionalized vinyl boronates via ruthenium-catalyzed olefin cross-metathesis and subsequent conversion to vinyl halides. (2003) (172)
- Tandem Ring Opening−Ring Closing Metathesis of Cyclic Olefins (1996) (166)
- Synthesis of Water-Soluble, Aliphatic Phosphines and Their Application to Well-Defined Ruthenium Olefin Metathesis Catalysts (1996) (166)
- Synthesis of Glycopolymers of Controlled Molecular Weight by Ring-Opening Metathesis Polymerization Using Well-Defined Functional Group Tolerant Ruthenium Carbene Catalysts (1995) (165)
- Catalytic Ring Closing Metathesis of Dienynes: Construction of Fused Bicyclic [n.m.0] Rings (1994) (165)
- High‐Yield Synthesis of [2] Catenanes by Intramolecular Ring‐Closing Metathesis (1997) (165)
- Linear Rheological Response of a Series of Densely Branched Brush Polymers (2011) (164)
- Water-Soluble Ruthenium Alkylidenes: Synthesis, Characterization, and Application to Olefin Metathesis in Protic Solvents (2000) (161)
- Latent ruthenium olefin metathesis catalysts that contain an N-heterocyclic carbene ligand (2004) (160)
- Ring-opening polymerization of norbornene by a living tungsten alkylidene complex (1987) (160)
- Reactions of Ruthenium Carbenes of the Type (PPh3)2(X)2Ru:CH-CH:CPh2 (X = Cl and CF3COO) with Strained Acyclic Olefins and Functionalized Olefins (1995) (159)
- Synthesis of Conformationally Restricted Amino Acids and Peptides Employing Olefin Metathesis (1995) (157)
- The ring opening metathesis polymerization of 7-oxabicyclo[2.2.1]hept-5-ene derivatives: a new acyclic polymeric ionophore (1988) (156)
- Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. (2011) (156)
- Thin Films of n-Si/Poly-(CH3)3Si-Cyclooctatetraene: Conducting-Polymer Solar Cells and Layered Structures (1990) (153)
- Z-Selectivity in olefin metathesis with chelated Ru catalysts: computational studies of mechanism and selectivity. (2012) (153)
- Tandem Catalysis: Three Mechanistically Distinct Reactions from a Single Ruthenium Complex (2000) (151)
- Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis (2011) (149)
- Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene‐Catalyzed Ring‐Closing Metathesis. (1994) (148)
- Small-molecule N-heterocyclic-carbene-containing olefin-metathesis catalysts for use in water. (2007) (148)
- Living Ring-Opening Metathesis Polymerization in Water (1998) (148)
- Relative Reaction Rates of Olefin Substrates with Ruthenium(II) Carbene Metathesis Initiators1 (1998) (147)
- Synthesis of cyclic polybutadiene via ring-opening metathesis polymerization: the importance of removing trace linear contaminants. (2003) (147)
- Synthesis of Norbornenyl Polymers with Bioactive Oligopeptides by Ring-Opening Metathesis Polymerization (2000) (145)
- Application of Bottlebrush Block Copolymers as Photonic Crystals. (2017) (143)
- Rate acceleration in olefin metathesis through a fluorine-ruthenium interaction. (2006) (142)
- A neutral, water-soluble olefin metathesis catalyst based on an N-heterocyclic carbene ligand (2005) (141)
- Inhibition of cell adhesion to fibronectin by oligopeptide-substituted polynorbornenes. (2001) (141)
- New Triarylamine-Containing Polymers as Hole Transport Materials in Organic Light-Emitting Diodes: Effect of Polymer Structure and Cross-Linking on Device Characteristics (1998) (141)
- The mechanism of aqueous ruthenium(II)-catalyzed olefin isomerization (1994) (139)
- Synthesis of Cycloalkenes via Alkylidene‐Mediated Olefin Metathesis and Carbonyl Olefination. (1993) (139)
- The catalytic asymmetric total synthesis of elatol. (2008) (136)
- A new class of chelating n-heterocyclic carbene ligands and their complexes with palladium (2004) (135)
- Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. (2015) (135)
- Z-selective homodimerization of terminal olefins with a ruthenium metathesis catalyst. (2011) (135)
- Ring-Opening Metathesis Polymerization of Functionalized Cyclooctenes by a Ruthenium-Based Metathesis Catalyst (1995) (135)
- Highly active iron imidazolylidene catalysts for atom transfer radical polymerization (2000) (134)
- Mechanism of the olefin metathesis reaction (1975) (133)
- Highly active ruthenium metathesis catalysts exhibiting unprecedented activity and Z-selectivity. (2013) (132)
- Cp2TiCH2 complexes in synthetic applications (1983) (132)
- Cis-selective ring-opening metathesis polymerization with ruthenium catalysts. (2012) (131)
- Titanium metallacarbene-metallacyclobutane reactions: stepwise metathesis (1980) (131)
- Increased efficiency in cross-metathesis reactions of sterically hindered olefins. (2008) (131)
- Synthesis of symmetrical trisubstituted olefins by cross metathesis. (2002) (130)
- Late metal carbene complexes generated by multiple C-H activations: examining the continuum of M=C bond reactivity. (2009) (130)
- Synthesis of end-functionalized poly(norbornene)s via ring-opening metathesis polymerization (2001) (129)
- Highly selective ruthenium metathesis catalysts for ethenolysis. (2011) (129)
- Synthesis of Catenane Structures via Ring-Closing Metathesis. (1999) (129)
- Application of (1)H DOSY for Facile Measurement of Polymer Molecular Weights. (2012) (128)
- Utility of a Ruthenium Metathesis Catalyst for the Preparation of End-Functionalized Polybutadiene (1997) (125)
- Synthesis and Investigation of Homo- and Heterobimetallic Ruthenium Olefin Metathesis Catalysts Exhibiting Increased Activities (1998) (122)
- A direct route to cyclic organic nanostructures via ring-expansion metathesis polymerization of a dendronized macromonomer. (2009) (122)
- ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties (2015) (121)
- The syntheses and activities of polystyrene-supported olefin metathesis catalysts based on Cl2(PR3)2Ru = CH−CH = CPh2 (1995) (121)
- Polystyrene attached titanocene species. Preparation and reactions (1975) (121)
- Activation of homogeneous catalysts by polymer attachment (1973) (118)
- Synthesis ofα,β-Unsaturated Amides by Olefin Cross-Metathesis (2001) (117)
- In situ preparation of a highly active N-heterocyclic carbene-coordinated olefin metathesis catalyst. (2000) (117)
- Z-selective cross metathesis with ruthenium catalysts: synthetic applications and mechanistic implications. (2015) (117)
- Linear functionalized polyethylene prepared with highly active neutral Ni(II) complexes (2002) (117)
- Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium (1984) (117)
- Solar cell efficiency enhancement via light trapping in printable resonant dielectric nanosphere arrays (2013) (117)
- Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. (2008) (115)
- Ruthenium-catalyzed ring-closing metathesis to form tetrasubstituted olefins. (2007) (114)
- Self-assembly of symmetric brush diblock copolymers. (2013) (114)
- Double C--H activation of an N-heterocyclic carbene ligand in a ruthenium olefin metathesis catalyst. (2007) (114)
- Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study. (2017) (113)
- Switching and extension of a [c2]daisy-chain dimer polymer. (2009) (113)
- Stereoselective access to Z and E macrocycles by ruthenium-catalyzed Z-selective ring-closing metathesis and ethenolysis. (2013) (113)
- Room-temperature cycling of metal fluoride electrodes: Liquid electrolytes for high-energy fluoride ion cells (2018) (112)
- Ring-Closing Metathesis in Methanol and Water (1998) (111)
- Magic ring catenation by olefin metathesis. (2005) (110)
- Template-Directed Ring-Closing Metathesis: Synthesis and Polymerization of Unsaturated Crown Ether Analogs† (1997) (108)
- A Highly Efficient and Practical Synthesis of Chromene Derivatives Using Ring-Closing Olefin Metathesis. (1998) (108)
- Consideration of the mechanism of the metal catalyzed olefin metathesis reaction (1976) (108)
- Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. (2007) (107)
- Well-defined silica-supported olefin metathesis catalysts. (2009) (106)
- Polycyclooctatetraene (polyacetylene): synthesis and properties (1988) (106)
- Magic ring rotaxanes by olefin metathesis. (2003) (106)
- Highly active chiral ruthenium catalysts for asymmetric cross- and ring-opening cross-metathesis. (2006) (105)
- Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides: New Methodology To Give Metathesis-Active Ruthenium Carbenes (1997) (104)
- Formation of Covalently Attached Polymer Overlayers on Si(111) Surfaces Using Ring-Opening Metathesis Polymerization Methods (2001) (102)
- Control of Grafting Density and Distribution in Graft Polymers by Living Ring-Opening Metathesis Copolymerization. (2017) (102)
- Cyclic ruthenium-alkylidene catalysts for ring-expansion metathesis polymerization. (2008) (101)
- Ruthenium‐Based Four‐Coordinate Olefin Metathesis Catalysts (2000) (99)
- Ring-opening metathesis polymerization of substituted bicyclo[2.2.2]octadienes : a new precursor route to poly(1,4-phenylenevinylene) (1992) (99)
- The development of well-defined catalysts for ring-opening olefin metathesis polymerizations (ROMP) (1992) (99)
- Effects of NHC-backbone substitution on efficiency in ruthenium-based olefin metathesis. (2009) (98)
- Olefin metathesis involving ruthenium enoic carbene complexes. (2001) (97)
- Improving brush polymer infrared one-dimensional photonic crystals via linear polymer additives. (2014) (97)
- Synthesis of fluorine-18 functionalized nanoparticles for use as in vivo molecular imaging agents. (2008) (97)
- Synthesis and activity of ruthenium olefin metathesis catalysts coordinated with thiazol-2-ylidene ligands. (2008) (97)
- Ruthenium metallacycles derived from 14-electron complexes. New insights into olefin metathesis intermediates. (2006) (96)
- A stable four-membered N-heterocyclic carbene. (2004) (96)
- Synthesis and direct imaging of ultrahigh molecular weight cyclic brush polymers. (2011) (96)
- Synthesis of (.+-.)-.DELTA.9,12-capnellene using titanium reagents (1986) (95)
- The relationship between metallacyclopentanes and bis(olefin)-metal complexes (1978) (95)
- Rapidly Cross-Linkable DOPA Containing Terpolymer Adhesives and PEG-Based Cross-Linkers for Biomedical Applications (2012) (94)
- Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene. (2008) (94)
- Preparation and reactions of phosphine nickelocyclopentanes (1978) (93)
- Possible intermediate in the tungsten-catalyzed olefin metathesis reaction (1972) (93)
- Synthesis of ABA Triblock Copolymers via a Tandem Ring-Opening Metathesis Polymerization: Atom Transfer Radical Polymerization Approach (2000) (93)
- Reaction between Ruthenium(0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts (1997) (92)
- Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. (2011) (92)
- Strained rings as a source of unsaturation: polybenzvalene, a new soluble polyacetylene precursor (1988) (92)
- Lewis-base silane activation: from reductive cleavage of aryl ethers to selective ortho-silylation (2013) (92)
- Conformations of N-heterocyclic carbene ligands in ruthenium complexes relevant to olefin metathesis. (2009) (91)
- Handbook of Metathesis: Grubbs/Handbook of Metathesis, Set (2015) (91)
- Synthesis of polymer dielectric layers for organic thin film transistors via surface-initiated ring-opening metathesis polymerization. (2004) (91)
- Formation of macrocycles via ring-closing olefin metathesis. (2001) (90)
- Synthesis of neutral nickel catalysts for ethylene polymerization--the influence of ligand size on catalyst stability. (2003) (90)
- Ring-expansion metathesis polymerization: catalyst-dependent polymerization profiles. (2009) (89)
- Chemoselective construction of substituted conjugated dienes using an olefin cross-metathesis protocol. (2005) (89)
- Ruthenium-based olefin metathesis catalysts coordinated with unsymmetrical N-heterocyclic carbene ligands: synthesis, structure, and catalytic activity. (2008) (89)
- Soluble, chiral polyacetylenes : syntheses and investigation of their solution conformation (1991) (89)
- Organic Two-Layer Light-Emitting Diodes Based on High-Tg Hole-Transporting Polymers with Different Redox Potentials (1999) (88)
- Synthesis and Reactivity of Neutral and Cationic Ruthenium(II) Tris(pyrazolyl)borate Alkylidenes (1998) (88)
- Ring-Opening Metathesis Polymerization of Functionalized Low-Strain Monomers with Ruthenium-Based Catalysts (2005) (88)
- Bifunctional [c2]daisy-chains and their incorporation into mechanically interlocked polymers. (2007) (87)
- Synthesis of A,B-alternating copolymers by ring-opening-insertion-metathesis polymerization. (2002) (87)
- Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes (2006) (86)
- Decomposition pathways of Z-selective ruthenium metathesis catalysts. (2012) (85)
- Design, Synthesis, and Self-Assembly of Polymers with Tailored Graft Distributions. (2017) (85)
- Carbenes As Catalysts for Transformations of Organometallic Iron Complexes (2009) (84)
- A Ring-Opening Metathesis Polymerization (ROMP) Approach to Carboxyl- and Amino-Terminated Telechelic Poly(butadiene)s (2000) (84)
- On the self-assembly of brush block copolymers in thin films. (2013) (84)
- Soluble, Highly Conjugated Derivatives of Polyacetylene from the Ring-Opening Metathesis Polymerization of Monosubstituted Cyclooctatetraenes: Synthesis and the Relationship Between Polymer Structure and Physical Properties (1993) (83)
- The Living ROMP of trans-Cyclooctene. (2009) (83)
- Ionic and Neutral Mechanisms for C-H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide. (2017) (83)
- Highly selective 1,3-isomerization of allylic alcohols via rhenium oxo catalysis. (2005) (82)
- Efficient and highly aldehyde selective Wacker oxidation. (2012) (82)
- Well-defined liquid crystal gels from telechelic polymers. (2008) (82)
- Ruthenium Alkylidene Initiated Living Ring-Opening Metathesis Polymerization (ROMP) of 3-Substituted Cyclobutenes (1997) (80)
- Synthesis of block copolymers of silicon-containing norbornene derivatives via living ring-opening metathesis polymerization catalyzed by a ruthenium carbene complex (1995) (80)
- Synthesis of highly cis, syndiotactic polymers via ring-opening metathesis polymerization using ruthenium metathesis catalysts. (2013) (78)
- A simple method to polyhydroxylated olefinic molecules using ring-closing olefin metathesis (1997) (78)
- Highly Sensitive Detection and Discrimination of Biogenic Amines Utilizing Arrays of Polyaniline/Carbon Black Composite Vapor Detectors (2000) (77)
- Rearrangement of N-Heterocylic Carbenes Involving Heterocycle Cleavage (2006) (77)
- A facile preparation of imidazolinium chlorides. (2008) (76)
- Consequences of Grafting Density on the Linear Viscoelastic Behavior of Graft Polymers. (2018) (75)
- Electronic properties of junctions between silicon and organic conducting polymers (1990) (74)
- Use of compatible polymer blends to fabricate arrays of carbon black-polymer composite vapor detectors. (1998) (73)
- Direct synthesis of soluble, end-functionalized polyenes and polyacetylene block copolymers. (2003) (73)
- Aldehyde-selective Wacker-type oxidation of unbiased alkenes enabled by a nitrite co-catalyst. (2013) (73)
- Rearrangement of bicyclo[2.2.1]heptane ring systems by titanocene alkylidene complexes to bicyclo[3.2.0]heptane enol ethers. Total synthesis of (±)-Δ^(9(12))-capnellene (1990) (72)
- Metallacyclopentanes as catalysts for the linear and cyclodimerization of olefins (1978) (72)
- A Ruthenium Olefin Metathesis Catalyst with a Four-Membered N-Heterocyclic Carbene Ligand (2005) (72)
- Catalyst-controlled Wacker-type oxidation: facile access to functionalized aldehydes. (2014) (72)
- Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush. (2017) (72)
- EPR study of spin labeled brush polymers in organic solvents. (2011) (72)
- Concise syntheses of insect pheromones using Z-selective cross metathesis. (2013) (71)
- Asymmetric Ring-Closing Metathesis: Kinetic Resolution Catalyzed by a Chiral Molybdenum Alkylidene Complex (1996) (71)
- Structure and reactivity of titanium-platinum and -palladium heterobinuclear complexes with .mu.-methylene ligands (1989) (71)
- Low catalyst loadings in olefin metathesis: synthesis of nitrogen heterocycles by ring-closing metathesis. (2010) (70)
- A tandem approach to photoactivated olefin metathesis: combining a photoacid generator with an acid activated catalyst. (2009) (70)
- Preparation of hydroxytelechelic poly(butadiene) via ring-opening metathesis polymerization employing a well-defined metathesis catalyst (1993) (70)
- Highly Unsaturated Oligomeric Hydrocarbons: α-(Phenylethynyl)-ω-phenylpoly[1,2-phenylene(2,1-ethynediyl)] (1993) (70)
- Aqueous ruthenium(II) complexes of functionalized olefins: the x-ray structure of Ru(H2O)2(.eta.1(O):.eta.2(C,C')-OCOCH2CH=CHCH3)2 (1991) (69)
- Origins of initiation rate differences in ruthenium olefin metathesis catalysts containing chelating benzylidenes. (2015) (69)
- Tunable, temperature-responsive polynorbornenes with side chains based on an elastin peptide sequence. (2009) (69)
- Synthesis of N-Heterocylic Carbene-Containing Metal Complexes from 2-(Pentafluorophenyl)imidazolidines (2007) (69)
- Die Ringschluß‐Olefin‐Metathese als hocheffiziente Methode zur Synthese kovalent querverbrückter Peptide (1998) (68)
- Preparation of Alternating Copolymers from the Ring-Opening Metathesis Polymerization of 3-Methylcyclobutene and 3,3-Dimethylcyclobutene (1995) (68)
- Facile and E-selective intramolecular ring-closing metathesis reactions in 3(10)-helical peptides: a 3D structural study. (2007) (68)
- Practical and general palladium-catalyzed synthesis of ketones from internal olefins. (2013) (68)
- Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis (2004) (68)
- Increasing the Initiation Efficiency of Ruthenium-Based Ring-Opening Metathesis Initiators: Effect of Excess Phosphine (2001) (67)
- A titanium vinylidene route to substituted allenes (1983) (67)
- Ruthenium-Catalyzed Polycyclization Reactions (1998) (67)
- Recent Advancements in Stereoselective Olefin Metathesis Using Ruthenium Catalysts (2017) (67)
- Z-Selective Olefin Metathesis on Peptides: Investigation of Side-Chain Influence, Preorganization, and Guidelines in Substrate Selection (2014) (67)
- Synthetic applications of titanocene methylene complexes: selective formation of ketone enolates and their reactions (1983) (67)
- Structures of titanacyclobutanes (1981) (67)
- Synthesis of discotic columnar side-chain liquid crystalline polymers by ring-opening metathesis polymerization (ROMP) (1997) (66)
- Terminal ruthenium carbido complexes as ??-donor ligandsElectronic supplementary information (ESI) available: additional crystallographic information. See http://www.rsc.org/suppdata/cc/b2/b207903h/ (2002) (66)
- Aqueous ring-opening metathesis polymerization of carboximide-functionalized 7-oxanorbornenes (1992) (66)
- Z-Selective ethenolysis with a ruthenium metathesis catalyst: experiment and theory. (2013) (66)
- Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins. (2014) (65)
- Hyperbranched macromolecules via olefin metathesis. (2007) (64)
- Synthesis of a molecular charm bracelet via click cyclization and olefin metathesis clipping. (2010) (64)
- ROMP-ATRP Block Copolymers Prepared from Monotelechelic Poly(oxa)norbornenes Using a Difunctional Terminating Agent (2008) (64)
- Efficient removal of ruthenium byproducts from olefin metathesis products by simple aqueous extraction. (2007) (64)
- Highly ordered dielectric mirrors via the self-assembly of dendronized block copolymers. (2013) (64)
- Oxygen-atom transfer from carbon dioxide to a Fischer carbene at (PNP)Ir. (2008) (63)
- An investigation of the reaction of bis(cyclopentadienyl)titanium dichlorides with trimethylaluminum. Mechanism of an .alpha.-hydrogen abstraction reaction (1984) (63)
- End capping ring-opening olefin metathesis polymerization polymers with vinyl lactones. (2008) (63)
- Properties of vapor detector arrays formed through plasticization of carbon black-organic polymer composites. (2002) (63)
- Formal Vinyl CH Activation and Allylic Oxidation by Olefin Metathesis (2002) (63)
- Ruthenium Olefin Metathesis Catalysts Bearing Carbohydrate-Based N-Heterocyclic Carbenes. (2010) (62)
- KINETICS AND STEREOCHEMISTRY OF THE TITANACYCLOBUTANE-TITANAETHYLENE INTERCONVERSION. INVESTIGATION OF A DEGENERATE OLEFIN METATHESIS REACTION (1982) (61)
- Ruthenium Olefin Metathesis Catalysts Bearing an N-Fluorophenyl-N-Mesityl-Substituted Unsymmetrical N-Heterocyclic Carbene (2007) (61)
- Novel η^3- Vinylcarbene Complexes Derived from Ruthenium-Based Olefin Metathesis Catalysts (2001) (61)
- The preparation and reactions of nickelocyclopentanes (1977) (61)
- The Preparation and Selectivity of a Polymer-Attached Rhodium(l) Olefin Hydrogenation Catalyst (1973) (61)
- Synthesis and cell adhesive properties of linear and cyclic RGD functionalized polynorbornene thin films. (2012) (60)
- Substituent Effects on the Cleavage Rates of Titanocene Metallacyclobutanes (1988) (59)
- POLYMER ATTACHED METALLOCENES. EVIDENCE FOR SITE ISOLATION (1977) (59)
- The Development of Functional Group Tolerant Romp Catalysts (1994) (58)
- Pulsed-addition ring-opening metathesis polymerization: catalyst-economical syntheses of homopolymers and block copolymers. (2009) (58)
- Arene–Perfluoroarene Interactions as Physical Cross‐Links for Hydrogel Formation (2002) (58)
- The methylenation of enolizable ketones and esters using organotitanium chemistry (1985) (58)
- Effiziente Synthese von [2]‐Catenanen durch intramolekulare Olefinmetathese (1997) (58)
- A New Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1,3-Dimesityl-1,4,5,6-tetrahydropyrimidin-2-ylidene: Synthesis, X-ray Structure, and Reactivity (2004) (58)
- Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS-Bottlebrush Block Copolymers (2018) (57)
- Alkali Metal-Hydroxide-Catalyzed C(sp)-H Bond silylation. (2017) (57)
- Olefin insertion in a metal alkyl in a Ziegler polymerization system (1985) (57)
- Rhenium-catalyzed 1,3-isomerization of allylic alcohols: scope and chirality transfer. (2006) (57)
- New donor-acceptor materials based on random polynorbornenes bearing pendant phthalocyanine and fullerene units. (2006) (56)
- Modeling Ring-Chain Equilibria in Ring-Opening Polymerization of Cycloolefins (1995) (56)
- Carboxylate-Assisted C(sp3)–H Activation in Olefin Metathesis-Relevant Ruthenium Complexes (2014) (56)
- Block copolymers containing monodisperse segments produced by ring-opening metathesis of cyclic olefins (1988) (56)
- Influence of Backbone Rigidity on the Thermotropic Behavior of Side-Chain Liquid Crystalline Polymers Synthesized by Ring-Opening Metathesis Polymerization (1997) (56)
- Routes to Conjugated Polymers with Ferrocenes in Their Backbones: Synthesis and Characterization of Poly(ferrocenylenedivinylene) and Poly(ferrocenylenebutenylene) (1995) (56)
- Synthesis of tungsten vinyl alkylidene complexes via the reactions of WCl2(NAr)(PX3)3 (X = R, OMe) precursors with 3,3-disubstituted cyclopropenes (1993) (56)
- Living ring-opening metathesis polymerization of bicyclo[3.2.0]heptene catalyzed by a ruthenium alkylidene complex (1993) (55)
- Degradable Cyclooctadiene/Acetal Copolymers: Versatile Precursors to 1,4-Hydroxytelechelic Polybutadiene and Hydroxytelechelic Polyethylene (1995) (55)
- Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins (2013) (55)
- Synthesis of ABA triblock copolymers of norbornenes and 7-oxanorbornenes via living ring-opening metathesis polymerization using well-defined, bimetallic ruthenium catalysts (1996) (55)
- The exclusivity of multivalency in dynamic covalent processes. (2004) (55)
- Alkene chemoselectivity in ruthenium-catalyzed Z-selective olefin metathesis. (2013) (55)
- Ruthenium catalyzed equilibrium ring-opening metathesis polymerization of cyclopentene (2013) (54)
- Organic light-emitting diode with 20 lm/W efficiency using a triphenyldiamine side-group polymer as the hole transport layer (1999) (54)
- Highly efficient syntheses of acetoxy- and hydroxy-terminated telechelic poly(butadiene)s using ruthenium catalysts containing N-heterocyclic ligands (2001) (54)
- Nonproductive events in ring-closing metathesis using ruthenium catalysts. (2010) (53)
- A novel route to block copolymers by changing the mechanism from living ring-opening metathesis polymerization of cyclic olefins to aldol condensation polymerization of silyl vinyl ethers (1989) (53)
- Synthesis, Reactivity and Kinetic Studies of Bis(η5-cyclopentadienyl)titanium Methylidene Phosphine Complexes (1989) (53)
- Crystal structure of bis(triphenylphosphine)tetramethyleneplatinum(II) (1973) (53)
- Catalytic Dehalogenation of Aryl Chlorides Mediated by Ruthenium(II) Phosphine Complexes (1999) (52)
- Carbon-carbon bond cleavage reactions in the decomposition of metallacycles (1978) (52)
- Carbon−hydrogen bond activation through a binuclear C−H bond complex (1986) (51)
- Monofunctional metathesis polymers via sacrificial diblock copolymers. (2006) (51)
- Protecting group directed ring-closing metathesis (RCM): the first total synthesis of an anti-malarial nonenolide (2007) (51)
- Tandem ring-closing metathesis reaction with a ruthenium catalyst containing a N-heterocyclic ligand (2001) (51)
- Living ring-opening metathesis polymerization of cyclobutene: the thermodynamic effect of a reversibly binding ligand (1992) (51)
- Model compounds of ruthenium-alkene intermediates in olefin metathesis reactions. (2006) (51)
- Receptor-mediated endocytosis of poly(acrylic acid)-conjugated liposomes by macrophages. (1996) (51)
- Functionalized 3D Architected Materials via Thiol‐Michael Addition and Two‐Photon Lithography (2017) (51)
- Stereoretentive Olefin Metathesis: An Avenue to Kinetic Selectivity. (2017) (51)
- Olefin Metathesis with 1,1-Difluoroethylene (2001) (51)
- Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. (2011) (50)
- Synthesis of Functionalized Polyethers by Ring-Opening Metathesis Polymerization of Unsaturated Crown Ethers (1999) (49)
- Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins (2004) (49)
- Spezifische Phenyl-Perfluorphenyl-Stapelwechselwirkungen: eine neue Strategie zum Aufbau supramolekularer Strukturen† (1997) (49)
- Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes. (2016) (48)
- Ruthenium‐Catalyzed Olefin Cross Metathesis of Styrenes as an Alternative to the Heck and Cross‐Coupling Reactions (2002) (48)
- Synthesis and structure of ketene complexes of permethylzirconocene and their hydrogenation to zirconium enolate hydrides (1983) (48)
- Correction of myopia after cataract surgery with a light-adjustable lens. (2009) (48)
- High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention. (2016) (48)
- Synthesis and properties of a novel cross-conjugated conductive polymer precursor: poly(3,4-diisopropylidenecyclobutene) (1987) (48)
- Multiple Olefin Metathesis Polymerization That Combines All Three Olefin Metathesis Transformations: Ring-Opening, Ring-Closing, and Cross Metathesis. (2015) (47)
- Synthesis of coumarins by ring-closing metathesis (2003) (47)
- Combinatorial approaches to the synthesis of vapor detector arrays for use in an electronic nose. (2000) (47)
- A one-pot cross-metathesis/allylboration reaction: a three-component coupling for the synthesis of functionalized homoallylic alcohols. (2002) (46)
- Synthesis of Cross-Linkable Telechelic Poly(butenylene)s Derived from Ring-Opening Metathesis Polymerization (2000) (46)
- Synthesis of Vinyl- and Allylphosphonates by Olefin Cross-Metathesis (2001) (46)
- ASYMMETRIC HYDROGENATION BY AN ATROPISOMERIC DIPHOSPHINITE RHODIUM COMPLEX (1977) (46)
- A titanacyclobutane precursor to alkyl-substituted titanium carbene complexes (1986) (46)
- Titanacyclobutanes: substitution pattern and stability (1982) (46)
- Functionalized Hyperbranched Polymers via Olefin Metathesis (2009) (45)
- Multiple C−H Activations of Methyl tert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1 (2008) (45)
- Quantitative Ring-Closing Metathesis of Polyolefins (1996) (45)
- Facile tungsten alkylidene synthesis: alkylidene transfer from a phosphorane to a tungsten imido complex (1990) (45)
- Total synthesis of (−)- and (±)-frontalin via ring-closing metathesis (1999) (45)
- Monotelechelic Poly(oxa)norbornenes by Ring-Opening Metathesis Polymerization using Direct End-Capping and Cross Metathesis. (2010) (45)
- Ring expansion via olefin metathesis. (2002) (45)
- Ring-closing metathesis approaches for the solid-phase synthesis of cyclic peptoids. (2011) (44)
- Metal-Catalyzed Addition Polymers for 157 nm Resist Applications. Synthesis and Polymerization of Partially Fluorinated, Ester-Functionalized Tricyclo[4.2.1.02,5]non-7-enes (2003) (44)
- Using EPR To Compare PEG-branch-nitroxide “Bivalent-Brush Polymers” and Traditional PEG Bottle–Brush Polymers: Branching Makes a Difference (2012) (44)
- Characterization and dynamics of substituted ruthenacyclobutanes relevant to the olefin cross-metathesis reaction. (2011) (44)
- Selective CO2 Electrochemical Reduction Enabled by a Tricomponent Copolymer Modifier on a Copper Surface. (2021) (44)
- A series of ruthenium(II) ester-carbene complexes as olefin metathesis initiators: metathesis of acrylates (2000) (44)
- Synthesis of Well-Defined Poly((vinyl alcohol)2-alt-methylene) via Ring-Opening Metathesis Polymerization (2002) (44)
- Asymmetric Ring-Closing Metathesis Catalyzed by Chiral Molybdenum Alkylidene Complexes. (1998) (44)
- Facile Synthesis of Effcient and Selective Ruthenium Olefin Metathesis Catalysts with Sulfonate and Phosphate Ligands (2010) (44)
- Synthesis of Organic and Water Soluble Poly(1,4-phenylenevinylenes) Containing Carboxyl Groups: Living Ring-Opening Metathesis Polymerization (ROMP) of 2,3-Dicarboxybarrelenes (1997) (43)
- In situ preparation of (.mu.-chloro)(.mu.-methylene)bis(cyclopentadienyl)(dimethylaluminum)titanium (Tebbe's reagent) (1985) (43)
- One-pot synthesis of polyrotaxanes via acyclic diene metathesis polymerization of supramolecular monomers. (2011) (43)
- Synthesis of Telechelic Polyisoprene via Ring-Opening Metathesis Polymerization in the Presence of Chain Transfer Agent (2010) (43)
- Chain Transfer in the Ring-Opening Metathesis Polymerization of Cyclooctadiene Using Discrete Metal Alkylidenes (1995) (42)
- Manipulating the ABCs of self-assembly via low-χ block polymer design (2017) (42)
- Poly(trimethylsilylcyclooctatetraene): a soluble conjugated polyacetylene via olefin metathesis (1989) (42)
- Mechanism of titanocene metallacyclobutane cleavage and the nature of the reactive intermediate (1987) (42)
- Probing the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir (2009) (41)
- Synthesis and Characterization of Stereoregular Ethylene-Vinyl Alcohol Copolymers Made by Ring-Opening Metathesis Polymerization (2005) (41)
- A catalytic cycle for oxidation of tert-butyl methyl ether by a double C-H activation-group transfer process. (2008) (41)
- 54 – Alkene and Alkyne Metathesis Reactions (1982) (41)
- Catalytic C–H bond silylation of aromatic heterocycles (2015) (40)
- H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex (2012) (40)
- Functional group diversity by ruthenium-catalyzed olefin cross-metathesis (2002) (40)
- Low pressure ethenolysis of renewable methyl oleate in a microchemical system. (2011) (40)
- Thermally Stable, Latent Olefin Metathesis Catalysts. (2011) (40)
- Metal-Catalyzed Vinyl Addition Polymers for 157 nm Resist Applications. 2. Fluorinated Norbornenes: Synthesis, Polymerization, and Initial Imaging Results (2002) (40)
- Polymer-supported organometallic compounds of titanium, zirconium and hafnium as hydrogenation catalysts (1976) (40)
- A potassium tert -butoxide and hydrosilane system for ultra-deep desulfurization of fuels (2017) (39)
- Convenient synthesis of ruthenium(II) dihydride phosphine complexes Ru(H)2(PP)2 and Ru(H)2(PR3)x (x = 3 and 4) (1997) (39)
- Conjugated Polymers: The Interplay Between Synthesis, Structure, and Properties (1991) (39)
- Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation. (2016) (39)
- Precise Synthesis of Bottlebrush Block Copolymers from ω-End-Norbornyl Polystyrene and Poly(4-tert-butoxystyrene) via Living Anionic Polymerization and Ring-Opening Metathesis Polymerization (2018) (39)
- Fast-Initiating, Ruthenium-based Catalysts for Improved Activity in Highly E-Selective Cross Metathesis. (2017) (39)
- Transition-metal-catalyzed polymerization of heteroatom-functionalized cyclohexadienes: stereoregular precursors to poly(p-phenylene) (1992) (39)
- Regioselective Wacker oxidation of internal alkenes: rapid access to functionalized ketones facilitated by cross-metathesis. (2013) (39)
- Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C. (2015) (38)
- Cellular uptake and anticancer activity of carboxylated gallium corroles (2016) (38)
- Self-assembly with block copolymers through metal coordination of SCS-Pd(II) pincer complexes and pseudorotaxane formation. (2006) (38)
- Photolithographic olefin metathesis polymerization. (2013) (37)
- Template-directed one-step synthesis of cyclic trimers by ADMET. (2006) (37)
- Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene (1994) (37)
- Selective ring opening cross metathesis of cyclooctadiene and trisubstituted cycloolefins. (2002) (37)
- A general enantioselective route to the chamigrene natural product family. (2010) (37)
- Synthesis and Reactions of Tungsten Oxo Vinylalkylidene Complexes: Reactions of WCl2(O)(PX3) (X = OMe, R) Precursors with 3,3-Diphenylcyclopropene† (1996) (36)
- Cyclometalated Z-Selective Ruthenium Metathesis Catalysts with Modified N-Chelating Groups (2015) (36)
- Light-adjustable lens: customizing correction for multifocality and higher-order aberrations. (2006) (35)
- Mechanism of olefin metathesis over a supported molybdenum catalyst (1980) (35)
- Examining the Effects of Monomer and Catalyst Structure on the Mechanism of Ruthenium-Catalyzed Ring-Opening Metathesis Polymerization. (2019) (35)
- Stereoregular Precursors to Poly(p-phenylene) via Transition-Metal-Catalyzed Polymerization. 1. Precursor Design and Synthesis (1994) (35)
- Einfluß von Perfluoraren‐Aren‐Wechselwirkungen auf das Phasenverhalten von flüssigkristallinen und polymeren Materialien (1999) (35)
- Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite. (2015) (35)
- Ruthenium-olefin complexes: effect of ligand variation upon geometry. (2008) (35)
- One-Pot Synthesis of Poly(vinyl alcohol) (PVA) Copolymers via Ruthenium Catalyzed Equilibrium Ring-Opening Metathesis Polymerization of Hydroxyl Functionalized Cyclopentene (2014) (35)
- Sacrificial Synthesis of Hydroxy-Functionalized ROMP Polymers: An Efficiency Study (2008) (35)
- Ring‐opening metathesis polymerization of exo‐dicyclopentadiene: Reversible crosslinking by a metathesis catalyst (1992) (35)
- Template-directed olefin cross metathesis. (2005) (35)
- Reactions of Cp2Ti=CH2 sources with acid anhydrides and imides (1985) (35)
- Red-orange electroluminescence with new soluble and air-stable poly(naphthalene-vinylene)s (1995) (35)
- Microstructural studies of poly(7-oxabicyclo[2.2.1]hept-2-ene) derivatives prepared from selected ruthenium catalysts (1992) (34)
- Trinuclear Zr2,Al .mu.-ketene complexes containing bridging ligands. Implications for transmetalation reactions and carbonyl reduction chemistry (1986) (34)
- Light-adjustable lens: development of in vitro nomograms. (2004) (34)
- Highly Active Platinum Catalysts for Nitrile and Cyanohydrin Hydration: Catalyst Design and Ligand Screening via High-Throughput Techniques. (2018) (34)
- Catalytic activity of a well-defined binuclear ruthenium alkylidene complex (1992) (34)
- Main-chain ferroelectric liquid crystal oligomers by acyclic diene metathesis polymerization (1996) (34)
- 1,3-Dimetallacyclobutanes in metal-methylidene dimerization reactions (1981) (34)
- Array-based vapor sensing using chemically sensitive, polymer composite resistors (1997) (33)
- Synthesis, structure, and reactions of heterobinuclear .mu.-methylene complexes (1989) (33)
- Chain transfer during the aqueous ring-opening metathesis polymerization of 7-oxanorbornene derivatives (1993) (33)
- Formal Anti-Markovnikov Hydroamination of Terminal Olefins. (2014) (33)
- Polymer-supported metallocenes and their applications to the catalysis of olefin isomerization, oligomerization, epoxidation and dinitrogen fixation reactions (1981) (33)
- Self-Assembly of ABC Bottlebrush Triblock Terpolymers with Evidence for Looped Backbone Conformations. (2018) (33)
- Probing the origin of degenerate metathesis selectivity via characterization and dynamics of ruthenacyclobutanes containing variable NHCs. (2011) (33)
- Di- and tetrafunctional initiators for the living ring-opening olefin metathesis polymerization of strained cyclic olefins (1989) (32)
- Initiation of ring-opening metathesis polymerization in protic media. Extension of [Ru(H2O)6]2+ catalyzed polymerizations to less-strained cyclic monomers (1993) (32)
- Bis-ligated Ti and Zr complexes of chelating N-heterocyclic carbenes (2011) (32)
- Bis-ligated Ti and Zr complexes of chelating N-heterocyclic carbenes (2011) (32)
- Decomposition and ligand substitution reaction mechanisms for organometallic radicals (1984) (32)
- Enhanced sensitivity to and classification of volatile carboxylic acids using arrays of linear poly(ethylenimine)-carbon black composite vapor detectors. (2003) (32)
- SYNTHESIS OF NEW CHIRAL LIGANDS AND THEIR GROUP VI METAL ALKYLIDENE COMPLEXES (1996) (31)
- The preparation and some catalytic activity of polymer-supported η5-cyclopentadienyl-rhoduim and -cobalt dicarbonyls (1979) (31)
- New Morphologies of Polyacetylene from the Precursor Polymer Polybenzvalene (1989) (30)
- Alkylidene transfer from phosphoranes to tungsten(IV) imido complexes (1993) (30)
- Preparation and isomerization reactions of 2-nickelahydrindanes (1978) (30)
- Latent ruthenium olefin metathesis catalysts featuring a phosphine or an N-heterocyclic carbene ligand. (2010) (30)
- Highly Z-selective and enantioselective ring-opening/cross-metathesis catalyzed by a resolved stereogenic-at-Ru complex. (2013) (30)
- Stereoselective synthesis of macrocyclic peptides via a dual olefin metathesis and ethenolysis approach (2015) (30)
- Preparation and reaction of metal ketene complexes of Zr and Ti (1982) (30)
- Catalytic, enantioselective synthesis of 1,2-anti-diols by asymmetric ring-opening/cross-metathesis. (2014) (30)
- Synthesis of Poly(1,4-naphthylenevinylenes): Metathesis Polymerization of Benzobarrelenes† (1996) (29)
- Trigonal-bipyramidal methyl group bridging two zirconocene-ketene centers (1984) (29)
- Use of the light-adjustable lens to correct astigmatism after cataract surgery (2010) (29)
- Block and graft copolymers by living ring-opening olefin metathesis polymerization (1991) (29)
- Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications. (2016) (29)
- Stereoregular Precursors to Poly(p-phenylene) via Transition-Metal-Catalyzed Polymerization. 2. The Effects of Polymer Stereochemistry and Acid Catalysts on Precursor Aromatization: A Characterization Study (1994) (29)
- Quantitative assessment of the antiaromatic city of cyclobutadiene by electrochemical studies on quinone derivatives (1973) (29)
- Synthesis, Structure, and Reactivity of a Rhenium Oxo-Vinylalkylidene Complex (1994) (29)
- Novel reactivity of ruthenium alkylidenes in protic solvents: degenerate alkylidene proton exchange. (2001) (29)
- Catalyst-Dependent Routes to Ring-Opening Metathesis Alternating Copolymers of Substituted Oxanorbornenes and Cyclooctene (2013) (29)
- Electrochemical evidence for the antiaromaticity of cyclobutadiene (1970) (29)
- Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study. (2016) (28)
- A Highly Efficient Synthesis of Z-Macrocycles Using Stereoretentive, Ruthenium-Based Metathesis Catalysts. (2017) (28)
- Rapid access to β-trifluoromethyl-substituted ketones: harnessing inductive effects in Wacker-type oxidations of internal alkenes. (2014) (28)
- Reactions of nickel—carbene complexes generated from nickelacycle complexes (1981) (28)
- Ruthenium‐Catalyzed Olefin Metathesis (2005) (28)
- Preparation of heteronuclear bridging methylene complexes (1984) (27)
- CONSIDERATION OF THE MECHANISM OF THE TRANSITION METAL CATALYZED OLEFIN METATHESIS REACTION. METATHESIS OF CIS,CIS-2,8-DECADIENE (1979) (27)
- Polycyclooctatetraene (polyacetylene) produced with a ruthenium olefin metathesis catalyst (2001) (27)
- Stereocomplex Formation of Densely Grafted Brush Polymers. (2014) (27)
- Elucidation of heterocumulene activation by a nucleophilic-at-metal iridium(I) carbene (2009) (27)
- An iridium-based catalyst system for metathesis/isomerization of acyclic olefins, including methyl oleate (1994) (27)
- Chemistry of Olefin-Terminated Homogeneous and Mixed Monolayers on Scribed Silicon (2007) (27)
- The synthesis of cyclic polymers by olefin metathesis: Achievements and challenges (2018) (26)
- Alternative routes to pterulone (2002) (26)
- Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes (2008) (26)
- Increased Ring Closing Metathesis Activity of Ruthenium-Based Olefin. Metathesis Catalysts Coordinated with Imidazolin-2-ylidene Ligands. (2010) (26)
- An alternate path to reductive elimination for Group IVB metals: mechanism of cyclopropane formation from titanacyclobutanes (1984) (26)
- Cyclobutadiene as an intermediate in the oxidative decomposition of cyclobutadienyliron tricarbonyl (1973) (26)
- The metallacyclopentane–olefin interchange reaction (1977) (26)
- Reaction of Diazoalkanes with Iron Phosphine Complexes Affords Novel Phosphazine Complexes (2001) (26)
- Ring closing metathesis in protic media by means of a neutral and polar ruthenium benzylidene complex. (2002) (25)
- Intramolecular Diels-Alder reaction of .alpha.,.beta.-unsaturated ester dienophiles with cyclopentadiene and the dependence on tether length (1989) (25)
- Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol. (2017) (25)
- Ruthenium carbene complexes bearing an anionic carboxylate chelated to a hemilabile ligand. (2008) (25)
- End capping of polynorbornene produced by titanacyclobutanes (1987) (25)
- Initiation of olefin metathesis: reaction of deca-2,8-diene with catalysts formed from Me4Sn–WCl6 and Me3Al2Cl3–(Ph3P)2(NO)2Cl2Mo (1977) (25)
- Ru-Based Z-Selective Metathesis Catalysts with Modified Cyclometalated Carbene Ligands. (2014) (25)
- An S(N)Ar approach to sterically hindered ortho-alkoxybenzaldehydes for the synthesis of olefin metathesis catalysts. (2015) (25)
- Reactions of 3,3-diphenylcyclopropene with iridium(I) complexes: Probing the mechanism of cyclopropene rearrangements at transition metal centers (1994) (24)
- Molecular Weight Distribution of Living Polymerization Involving Chain-Transfer Agents: Computational Results, Analytical Solutions, and Experimental Investigations Using Ring-Opening Metathesis Polymerization (1995) (24)
- On the mechanism of the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide. (2006) (24)
- TEMPLATE-PROMOTED DIMERIZATION OF C-ALLYLGLYCINE : A CONVENIENT SYNTHESIS OF (S, S)-2,7-DIAMINOSUBERIC ACID (1998) (24)
- (α,β-Substituted bis(cyclopentadienyl)titanacyclobutanes and their role in productive metathesis (1985) (24)
- Voltammetric Characterization of Soluble Polyacetylene Derivatives Obtained from the Ring-Opening Metathesis Polymerization (ROMP) of Substituted Cyclooctatetraenes (1993) (23)
- Tandem Olefin Metathesis/Oxidative Cyclization: Synthesis of Tetrahydrofuran Diols from Simple Olefins. (2016) (23)
- Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes (2014) (23)
- Drug capture materials based on genomic DNA-functionalized magnetic nanoparticles (2018) (23)
- Band structures of polyfulvene and related polymers. A model for the effects of benzannelation on the band structures of polythiophene, polypyrrole, and polyfulvene (1988) (23)
- Resist materials for 157-nm microlithography: an update (2001) (23)
- Structure and reactivity of a titanocene (.eta.2-thioformaldehyde) trimethylphosphine complex (1990) (23)
- Chapter 4 – Transition Metal–Carbene Complexes in Olefin Metathesis and Related Reactions (2003) (23)
- Terminal olefin cross-metathesis with acrolein acetals (1999) (23)
- Synthesis of telechelic polyacrylates with unsaturated end-groups (2003) (23)
- Iron tricarbonyl cyclooctatetraene complexes (1967) (23)
- Brush polymer ion gels (2016) (22)
- Toward Perfect Regiocontrol for β-Selective Cyclopolymerization Using a Ru-Based Olefin Metathesis Catalyst (2018) (22)
- Bidentate N,O-prolinate ruthenium benzylidene catalyst highly active in RCM of disubstituted dienes. (2007) (22)
- From ring-opening metathesis polymerization to Ziegler—Natta polymerization: A method for obtaining polynorbornene—polyethylene block copolymers (1993) (22)
- Synthesis of Polypentenamer and Poly(Vinyl Alcohol) with a Phase‐Separable Polyisobutylene‐Supported Second‐Generation Hoveyda–Grubbs Catalyst (2016) (22)
- Investigations into Ruthenium Metathesis Catalysts with Six-Membered Chelating NHC Ligands: Relationship between Catalyst Structure and Stereoselectivity. (2013) (22)
- The preparation of polymeric organophosphorus ligands for catalyst attachment (1976) (22)
- Cyclobutadieneiron tricarbonyl complexes (1970) (22)
- Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate. (2016) (22)
- Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis. (2018) (22)
- An Initiation Kinetics Prediction Model Enables Rational Design of Ruthenium Olefin Metathesis Catalysts Bearing Modified Chelating Benzylidenes. (2018) (21)
- Structure and reactivity of the zirconaenolate anion [Cp2Zr(C,O-.eta.2-OCCH2)CH3]Na.2THF. Synthesis of homo- and heterobinuclear ketene complexes (1984) (21)
- Insertion of Carbon–Heteroatom Multiple Bonds into Bis(η5-cyclopentadienyl)titanacyclobutenes (1988) (21)
- Ruthenium Olefin Metathesis Catalysts Featuring a Labile Carbodicarbene Ligand (2017) (21)
- Alkene Metathesis and Related Reactions (1991) (21)
- Stereochemical mechanistic probe of substituted .alpha.-methylenetitanacyclobutane reactivity (1988) (21)
- Reactivity of Group 4 acyl complexes with alkylaluminum reagents: synthesis of zirconium ketone complexes (1986) (21)
- Post implantation adjustable intraocular lenses. (2001) (21)
- Concerning the mechanism of Ziegler-Natta polymerization: isotope effects on propagation rates (1982) (21)
- Hybrid catalyst-metathesis catalysts attached to polystyrene copolymer (1977) (20)
- Carbonylation of titanocene cyclobutenes. Synthesis and characterization of a titanocene-vinylketene complex (1986) (20)
- Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols. (2015) (20)
- Cross metathesis assisted solid-phase synthesis of glycopeptoids. (2012) (20)
- Chemical synthesis with metal atoms: the reaction of chromium and nickel atoms with styrene (1976) (20)
- Living Polymerization Caught in the Act: Direct Observation of an Arrested Intermediate in Metathesis Polymerization. (2019) (19)
- Linear Rheology of a Series of Second-Generation Dendronized Wedge Polymers (2019) (19)
- THERMOCHEMICAL INVESTIGATION OF PHOSPHINE LIGAND SUBSTITUTION REACTIONS INVOLVING TRANS-(PR3)2CL2RU=CH-CH-CPH2 COMPLEXES (1998) (19)
- Stereochemical consequence of the interaction of alkylaluminums with titanacyclobutanes and its relationship to the olefin metathesis reaction (1982) (19)
- Synthesis and Structures of Bimetallic Titanium and Chromium Carbene Complexes of the Type Cp2Ti(Cl)O(CH3)CCr(CO)5 (1988) (19)
- Conversion of methanol to 2,2,3-trimethylbutane (triptane) over indium(III) iodide. (2007) (19)
- Ring‐Closing Metathesis Synthesis of N‐Boc‐3‐Pyrroline (2003) (19)
- THE STRUCTURE OF TITANIUM-RHODIUM HETEROBINUCLEAR COMPLEXES WITH MU -PHENYL LIGANDS (1991) (19)
- Decorating metal oxide surfaces with fluorescent chlorosulfonated corroles. (2013) (19)
- Reaction of Tp(PPh3)Ru(η2-O2CCHPh2) with Carbene and Vinylidene Precursors (2001) (19)
- Synthesis and controlled cross-linking of polymers derived from ring-opening metathesis-polymerization (ROMP) (1996) (18)
- Microprobe Analysis of Polystyrene-Attached Catalysts (1975) (18)
- Synthesis and Structure of Fused N-Heterocylic Carbenes and Their Rhodium Complexes. (2010) (18)
- Ru-Catalyzed, cis-Selective Living Ring-Opening Metathesis Polymerization of Various Monomers, Including a Dendronized Macromonomer, and Implications to Enhanced Shear Stability. (2020) (18)
- Application of Wittig-type reactions of titanacyclobutane end groups for the formation of block and graft copolymers (1989) (18)
- Electrocatalysis of CO2 Reduction in Brush Polymer Ion Gels. (2016) (18)
- Synthesis and structures of titanaoxacyclobutanes (1988) (17)
- Factors Dictating Carbene Formation at (PNP)Ir (2010) (17)
- Templatgesteuerte Ringschlußmetathesen: Synthese und Polymerisation ungesättigter Kronenether (1997) (17)
- Polymer attached catalysts: A comparison between polystyrene attached and homogeneous Rh(I) Hydro- genation catalysts (1978) (16)
- The stereochemistry of norbornene polymerization by titanametallacyclobutanes (1988) (16)
- Hole Transport Polymers with Improved Interfacial Contact to the Anode Material (2000) (16)
- Substituted polyacetylenes through the ring-opening metathesis polymerization (ROMP) of substituted cyclooctatetraenes: A route into soluble polyacetylene (1991) (16)
- Structure of a trinuclear dizirconium-aluminum (Zr_2Al) µ-ketone complex with a bridging trigonal-bipyramidal methyl group (1990) (16)
- The preparation and catalytic applications of supported zirconocene and hafnocene complexes (1985) (16)
- Efficient Z-Selective Olefin-Acrylamide Cross-Metathesis Enabled by Sterically Demanding Cyclometalated Ruthenium Catalysts. (2020) (16)
- IN SITU PREPARATION OF (μ‐CHLORO)(μ‐METHYLENE)BIS(CYCLOPENTADIENYL)(DIMETHYLALUMINUM)TITANIUM (TEBBE′S REAGENT) (1985) (16)
- Chemical synthesis with metal Atoms. Cyclodimerization of norbornadiene via nickela-cyclopentane intermediates. (1979) (16)
- Radical-mediated anti-Markovnikov hydrophosphonation of olefins. (2011) (15)
- Origins of the Stereoretentive Mechanism of Olefin Metathesis with Ru-Dithiolate Catalysts. (2017) (15)
- Fluoropolymer Resist Materials for 157nm Microlithography (2001) (15)
- Highly Active Metathesis Catalysts Generated In Situ from Inexpensive and Air-Stable Precursors. (2001) (15)
- Confined organization of fullerene units along high polymer chains (2013) (15)
- Hydroxyl-Directed, Stereoselective Olefination of Ketones by Transition Metal Alkylidenes (1995) (15)
- Reaction of dicyclopentadienylmethylenetitanium with organic halides: Evidence for a radical mechanism (2002) (15)
- Synthesis of perfect rubber using ring-opening metathesis polymerization of 1-methylcyclobutene (1994) (15)
- Direct Access to β-Fluorinated Aldehydes by Nitrite-Modified Wacker Oxidation. (2016) (14)
- Synthesis and catalytic activity of supported acenaphthoimidazolylidene N-heterocyclic carbene ruthenium complex for ring closing metathesis (RCM) and ring opening metathesis polymerization (ROMP) (2016) (14)
- Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid. (2007) (14)
- Third-order susceptibilities of soluble polymers derived from the ring opening metathesis copolymerization of cyclooctatetraene and 1,5-cyclooctadiene (1989) (14)
- Neutral, Single‐Component Nickel (II) Polyolefin Catalysts that Tolerate Heteroatoms (2000) (14)
- Chelating N-heterocyclic carbene group IV complexes for the polymerization of ethylene and styrene (2013) (14)
- Cellular uptake and cytotoxicity of a near-IR fluorescent corrole-TiO2 nanoconjugate. (2014) (14)
- Photolysis and photoinduced isomerization of cis-trans diethylbis(tertiary phosphine)palladium(II) (1982) (14)
- Olefin Cross‐Metathesis (2007) (14)
- Synthesis and Activity of Six-Membered Cyclic Alkyl Amino Carbene–Ruthenium Olefin Metathesis Catalysts (2020) (14)
- The linear rheological responses of wedge-type polymers (2015) (14)
- Photochemistry of titanacyclobutanes. Evidence for a metal-centered 1,4-biradical intermediate (1987) (14)
- 2, 2‐Dimethylpropylidyne Tungsten(VI) Complexes and Precursors for their Syntheses (2007) (13)
- Z‐Selektive Kreuzmetathese mit Ruthenium‐Katalysatoren: Anwendung in der Synthese und mechanistische Aspekte (2015) (13)
- In Situ Catalyst Modification in Atom Transfer Radical Reactions with Ruthenium Benzylidene Complexes. (2016) (13)
- Ring‐opening metathesis copolymerization employing ruthenium‐based metathesis catalysts (1995) (13)
- An inelastic electron tunneling spectroscopic investigation of the interaction of molybdenum hexacarbonyl with an aluminum oxide surface (1987) (13)
- Reactions of Metallacycles of Nickel, Metallacyclopentanes, Hexanes and Butanes (1979) (13)
- New Syntheses of Benzobarrelenes (1994) (13)
- Disentangling Ligand Effects on Metathesis Catalyst Activity: Experimental and Computational Studies of Ruthenium-Aminophosphine Complexes. (2018) (12)
- Application of Ring-Closing Metathesis to the Synthesis of Rigidified Amino Acids and Peptides. (1997) (12)
- Metathesis and Decomposition of Fischer Carbenes of Cyclometalated Z-Selective Ruthenium Metathesis Catalysts (2018) (12)
- The mechanism of the oxidative decomposition of cyclobutadienyliron tricarbonyl complexes: intramolecular trapping (1977) (12)
- Nucleophilic activation of CO for reduction by hydrogen (1981) (12)
- High T/sub g/ hole transport polymers for the fabrication of bright and efficient organic light-emitting devices with an air-stable cathode (2000) (12)
- Living Ring-Opening Olefin Metathesis Polymerization (2012) (12)
- The pharmacology of a new nitric oxide donor: B-NOD. (2000) (12)
- Thermomechanical Behavior and Local Dynamics of Dendronized Block Copolymers and Constituent Homopolymers (2015) (12)
- Light-triggered modulation of cellular electrical activity by ruthenium diimine nanoswitches. (2013) (12)
- Development of the metathesis method in organic synthesis (2005) (11)
- Cyclometalated Ruthenium Alkylidene Complexes: A Powerful Family of Z -Selective Olefin Metathesis Catalysts (2014) (11)
- Conversion of acid chlorides to substituted acetylenes with tungsten alkylidynes (2005) (11)
- Synthesis, characterization, and equilibrium studies of Group VIB intramolecular metalloesters: crystal structure of trans-(.eta.5-C5H4)CH2CH2O2CW(CO)2PPh3 (1984) (11)
- The Concentration Dependence of the Size and Symmetry of a Bottlebrush Polymer in a Good Solvent. (2020) (11)
- Chemical synthesis with metal atoms: The reaction of 1,4- and 1,3-cyclohexadiene with chromium atoms and trifluorophosphine (1976) (11)
- Control of Oligomerization and Oxidation Steps in the Synthesis of Tris(pentafluorophenyl)corrole (2015) (11)
- Disordered and oriented polyacetylene-block-polynorbornene-block-polyacetylene (1991) (11)
- Synthesis of Substituted Bicyclo[2.2.2]octatrienes (1997) (11)
- Condensed phase route to polyacetylene (1989) (11)
- Partial Kinetic Resolution of Oxanorbornenes by Ring-Opening Metathesis Polymerization with a Chiral Ruthenium Initiator. (2014) (11)
- Mechanism of rearrangement of titanacyclobutanes (1985) (11)
- 1,3‐DIMETALLACYCLOBUTANES IN METAL‐METHYLIDENE DIMERIZATION REACTIONS (1982) (11)
- Synthesis and properties of polyacetylene-polynorbornene-polyacetylene triblock copolymers (1991) (10)
- Facile intramolecular coupling of alkyl and acyl ligands induced by Lewis acids: Mechanistic studies on the formation of zirconium ketone complexes (1988) (10)
- A Neutral, Water‐Soluble Olefin Metathesis Catalyst Based on an N‐Heterocyclic Carbene Ligand. (2005) (10)
- Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses. (2000) (10)
- α‐Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts (1996) (10)
- Application of [superscript 1]H DOSY for Facile Measurement of Polymer Molecular Weights (2012) (10)
- Synthesis of substituted dihydrobenzofurans via tandem S(N)Ar/5-exo-trig cyclization. (2015) (10)
- Assessment of a Siloxane Poly(urethane‐urea) Elastomer Designed for Implantable Heart Valve Leaflets (2020) (10)
- Chapter 6. Living Ring-Opening Metathesis Polymerization (2010) (10)
- Realizing the Promise of Olefin Metathesis (2007) (10)
- The Development of L2X2R=CHR Olefin Metathesis Catalysts: An Organometallic Success Story (2001) (10)
- Aqueous electrocatalytic CO2 reduction using metal complexes dispersed in polymer ion gels. (2020) (10)
- Reverse methyl migration from a methyliron complex to trimethylaluminum forming an ionic complex [Fe(dmpe)2(acac)]+[AlMe4]− (1984) (9)
- STRUCTURE AND REACTIVITY OF THE ZIRCONAENOLATE ANION (CP2ZR(C,O-η2-OCCH2)CH3)NA.2THF. SYNTHESIS OF HOMO- AND HETEROBINUCLEAR KETENE COMPLEXES (1984) (9)
- Arene-perfluoroarene interactions as physical cross-links for hydrogel formation. (2002) (9)
- Tuning the formal potential of ferrocyanide over a 2.1 V range. (2019) (9)
- Intramolecular trapping of cyclobutadiene (1974) (9)
- Synthesis of PNV Homo- and Copolymers by a ROMP Precursor Route (1997) (9)
- Transition Metal Catalyzed Reactions of Olefins in Water: Olefin Metathesis and Isomerization (1995) (9)
- Confinement and Processing Can Alter the Morphology and Periodicity of Bottlebrush Block Copolymers in Thin Films. (2020) (9)
- Synthesis of polymer-attached niobium and tantalum complexes and their applications to the catalysis of olefin hydrogenation, isomerization and ethylene dimerization (1985) (9)
- Synthesis and Evaluation of Sterically Demanding Ruthenium Dithiolate Catalysts for Stereoretentive Olefin Metathesis (2017) (9)
- Using stereoretention for the synthesis of E-macrocycles with ruthenium-based olefin metathesis catalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc00435h (2018) (8)
- Electron transfer triggered by optical excitation of phenothiazine-tris(meta-phenylene-ethynylene)-(tricarbonyl)(bpy)(py)rhenium(I). (2013) (8)
- Stereoretentive Olefinmetathese: ein Weg zur kinetischen Selektivität (2017) (8)
- Kinetic control in the polymerization of a feast monomer: A route into finite polyenes (1988) (8)
- Transition metal carbonyl compounds containing intramolecular nucleophiles: Crystal structure of [(η5-C5H4(CH2)3OH)Mo(CO)3]2 (1985) (8)
- REACTIONS OF “CP2TI:CH2” SOURCES WITH ACID ANHYDRIDES AND IMIDES (1985) (8)
- A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. (2016) (7)
- Vacuum-UV influenced design of polymers and dissolution inhibitors for next generation photolithography (2003) (7)
- Applications in polymer synthesis (2003) (7)
- CATALYTIC RING CLOSING METATHESIS OF DIENYNES : CONSTRUCTION OF FUSED BICYCLIC RINGS (1994) (7)
- The synthesis of low crystallinity polyacetylene from the precursor polymer polybenzvalene (1989) (7)
- Thermal rearrangements in the tetra-arylcyclopropene series (1967) (7)
- Catalytic Ring-Closing Metathesis of Dienes: Application to the Synthesis of Eight-Membered Rings. (1995) (7)
- Electroluminescence and photoluminescence of conjugated polymers and oligomers (1995) (7)
- Enantioselective Synthesis of 15-Deoxy-Δ12,14-Prostaglandin J2. (2019) (7)
- Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron (1977) (7)
- Electronic Structures, Spectroscopy, and Electrochemistry of [M(diimine)(CN-BR3)4]2- (M = Fe, Ru; R = Ph, C6F5) Complexes. (2020) (6)
- Polynorbornene and poly(exo‐dicyclopentadiene) with aldehyde end groups (1989) (6)
- POLYMER ATTACHED CATALYSTS (1980) (6)
- Fluoride-ion solvation in non-aqueous electrolyte solutions (2019) (6)
- Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties (1997) (6)
- CONSIDERATION OF THE MECHANISM OF THE OLEFIN METATHESIS REACTION (1975) (6)
- Olefin Metathesis: A Powerful Reaction Begins to Reach Its Potential (2002) (6)
- The Application of Catalytic Ring-Closing Olefin Metathesis to the Synthesis of Unsaturated Oxygen Heterocycles. (1992) (6)
- Chiral tricarbonylcyclobutadieneiron complexes (1973) (6)
- The Preparation of Cyclobutadienyliron Tricarbonyl Complexes Using Disodium Tetracarbonylferrate (-2) (1978) (6)
- Palladium‐Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins. (2014) (6)
- Metallocycles as Intermediates in Organotransition-Metal Reactions (1975) (5)
- Synthesis of Tri-Substituted Vinyl Boronates via Ruthenium-Catalyzed Olefin Cross-Metathesis. (2005) (5)
- Cationic ruthenium alkylidene catalysts bearing phosphine ligands (2016) (5)
- Addressing the challenges of modeling the scattering from bottlebrush polymers in solution. (2020) (5)
- Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes. (2015) (5)
- Metathesis “rainbow” polymerizations--a systematic route into polyene sequences (1989) (5)
- Formation of bridged bicycloalkenes via ring closing metathesis (1998) (5)
- Soluble, Chiral Polyacetylenes: Syntheses and Investigation of Their Solution Conformation. (1991) (4)
- A New Method for Cross-Metathesis of Terminal Olefins. (1998) (4)
- Organic, Organometallic and Polymeric Materials with Nonlinear Optical Properties, (1989) (4)
- Novel positioning sensor with real-time feedback for improved postoperative positioning: pilot study in control subjects (2017) (4)
- Mechanism of Ruthenium Based Olefin Metathesis Catalysts (2002) (4)
- Electrochemistry in ionic liquids: Case study of a manganese corrole (2017) (4)
- Correction to Self-Assembly of Symmetric Brush Diblock Copolymers. (2015) (4)
- Z-Selective Ruthenium Metathesis Catalysts: Comparison of Nitrate and Nitrite X-type Ligands. (2014) (4)
- 24. Conversion of Titanacyclobutane Complexes for Ring Opening Metathesis Polymerization into Ziegler-Natta Catalysts (1990) (4)
- Synthesis of (±)-Δ(9,12)-Capnellene Using Titanium Reagents. (1986) (4)
- New Approaches to Olefin Cross-Metathesis. (2000) (4)
- Ruthenium alkylidene complexes coordinated with tricyclohexylphosphine and heterocyclic N-donor ligands (2003) (4)
- Catalysis-Enabled Concise and Stereoselective Total Synthesis of the Tricyclic Prostaglandin D2 Metabolite Methyl Ester. (2021) (4)
- Recent Advances on Olefin Metathesis and Its Application in Organic Synthesis. (1998) (4)
- Potassium tert-Butoxide-Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes (2016) (4)
- Approaches to Magnetic Organic Materials (1991) (3)
- Highly Conjugated, Substituted Polyacetylenes via the Ring‐Opening Metathesis Polymerization of Substituted Cyclooctatetraenes (1989) (3)
- Ruthenium-Catalyzed Olefin Cross Metathesis of Styrenes as an Alternative to the Heck and Cross-Coupling Reactions. (2010) (3)
- Living Ring-Opening Metathesis Polymerization of Cyclobutene: The Thermodynamic Effect of a Reversibly Binding Ligand. (1992) (3)
- Template‐Promoted Dimerization of C‐Allylglycine: A Convenient Synthesis of (S,S)‐2,7‐Diaminosuberic Acid. (1998) (3)
- Formal Vinyl C—H Activation and Allylic Oxidation by Olefin Metathesis. (2003) (3)
- (Dicyclohexylphosphino)borane, BH3PH(C6H11)2, a Precursor to Water‐Soluble Phosphine Ligands (1996) (3)
- THE OLEFIN METATHESIS REACTION (2007) (3)
- Palladium‐Catalyzed Decarbonylative Dehydration for the Synthesis of α‐Vinyl Carbonyl Compounds and Total Synthesis of (‐)‐Aspewentins A, B, and C. (2015) (3)
- Bulky Cyclometalated Ruthenium Nitrates for Challenging Z-Selective Metathesis: Efficient One-Step Access to α-Oxygenated Z-Olefins from Acrylates and Allyl Alcohols. (2021) (3)
- Synthesis, Characterization, and Applications of Substituted Polyacetylenes Derived from Ring-Opening Metathesis Polymerization of Cyclooctatetraenes (1990) (3)
- Tandem Ring Opening‐Ring Closing Metathesis of Cyclic Olefins. (1996) (3)
- Highly Efficient Ruthenium Catalysts for the Formation of Tetrasubstituted Olefins via Ring‐Closing Metathesis. (2007) (3)
- An Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization. (2020) (3)
- Intramolecular Diels-Alder Reaction of α,β-Unsaturated Ester Dienophiles with Cyclopentadiene and the Dependence on Tether Length. (1989) (3)
- New Polymeric Materials with Cubic Optical Nonlinearities Derived from Ring-Opening Metathesis Polymerization (1991) (3)
- Ring‐Closing Metathesis in Methanol and Water. (1999) (3)
- Ring opening metathesis polymerization catalysts (1995) (3)
- Validation of sensor for postoperative positioning with intraocular gas (2016) (3)
- Insights into the Nature of Self‐Extinguishing External Donors for Ziegler‐Natta Catalysis: A Combined Experimental and DFT Study (2020) (3)
- Soluble polyacetylenes derived from the ring-opening metathesis polymerization of substituted cyclooctatetraenes: electrochemical characterization and Schottky barrier devices (1991) (3)
- The Role of the “Tebbe Complex” in Olefin Metathesis (2008) (3)
- Metal Carbene Complexes in Polymer Synthesis (1987) (3)
- Synthesis of Vinyl‐ and Allylphosphonates by Olefin Cross‐Metathesis. (2001) (3)
- The Application of Ring-Opening Metathesis Polymerization to the Synthesis of Substituted Polyacetylenes (1990) (3)
- Monofunktionalisierte Metathesepolymere durch Abbau von Diblockcopolymeren (2006) (3)
- Synthesis and Ring-Opening Metathesis Polymerization of Second-Generation Dendronized Poly(ether) Monomers Initiated by Ruthenium Carbenes (2016) (3)
- Second And Third Order Nonlinear Optical Properties Of Conjugated Molecules And Polymers (1988) (3)
- Processing Effects on the Self-Assembly of Brush Block Polymer Photonic Crystals. (2021) (3)
- Carbonylation of Titanocene Cyclobutenes. Synthesis and Characterization of a Titanocene - Vinylketene Complex. (1986) (3)
- Highly Active Water‐Soluble Olefin Metathesis Catalyst. (2006) (3)
- Living β-selective cyclopolymerization using Ru dithiolate catalysts† †Electronic supplementary information (ESI) available: Experimental procedures, characterizations, 1H and 13C NMR spectra for new compounds and polymers, SEC traces, and other supporting experi-ments. See DOI: 10.1039/c9sc01326a (2019) (3)
- Ruthenium Carbene-Based Olefin Metathesis Initiators: Catalyst Decomposition and Longevity. (2000) (3)
- Cover Picture: Precisely Tunable Photonic Crystals From Rapidly Self‐Assembling Brush Block Copolymer Blends (Angew. Chem. Int. Ed. 45/2012) (2012) (2)
- Aldehyde-Functionalized Magnetic Particles to Capture Off-Target Chemotherapeutic Agents (2020) (2)
- Surgery-Guided Removal of Ovarian Cancer Using Up-Converting Nanoparticles. (2020) (2)
- Discussion Addendum for: Ring-closing Metathesis Synthesis of N-Boc-3-pyrroline (2014) (2)
- PD22-11 ABSENCE OF URETERAL/RENAL INJURY FOLLOWING LOW INTENSITY EXTRACORPOREAL ACOUSTIC ENERGY LITHOTRIPSY WITH STONE-TARGETING MICROBUBBLES IN AN IN VIVO SWINE MODEL (2018) (2)
- Cascade Cyclopolymerization of 5-Ethynyl-1,8-Nonadiyne Derivatives to Synthesize Low Band Gap Conjugated Polyacetylenes Containing Fused Bicyclic Structure. (2022) (2)
- Dichlorobis(η5-Chlorocyclopentadienyl)-Titanium, (ClC5H4)2TiCl2 (2007) (2)
- EFFICIENT SYNTHESES OF BRUSH POLYMERS VIA LIVING RING OPENING METATHESIS POLYMERIZATION OF MACROMONOMERS (2009) (2)
- Living b -selective cyclopolymerization using Ru dithiolate catalysts † (2019) (2)
- Terminal Olefin Cross-Metathesis with Acrolein Acetals. (1999) (2)
- Ring‐Opening Metathesis Polymerization (ROMP) and Related Processes (2013) (2)
- Synthesis of high-Tg hole-transporting polymers with different redox potentials and their performance in organic two-layer LEDs (1998) (2)
- Ru(II)-Catalyzed Asymmetric Ring-Closing Metathesis (2006) (2)
- Rearrangement of Bicyclo(2.2.1)heptane Ring Systems by Titanocene Alkylidene Complexes to Bicyclo(3.2.0)heptane Enol Ethers. Total Synthesis of (.+-.)-δ9(12)-Capnellene. (1990) (2)
- Catalytic Ring Closing Metathesis of Dienynes: Construction of Fused Bicyclic (n.m.0) Rings. (2010) (2)
- Sequence-Controlled Polymers by Ruthenium-Mediated Ring-Opening Metathesis Polymerization (2014) (2)
- Asymmetric Ring-Closing Metathesis: Kinetic Resolution Catalyzed by a Chiral Molybdenum Alkylidene Complex. (1996) (2)
- Cross metathesis of functionalized olefins (2002) (2)
- Catalyst development and mechanism (2015) (2)
- An inelastic electron-tunneling spectroscopic investigation of the reaction of molybdenum oxychlorides with a hydroxylated aluminum oxide surface (1987) (2)
- Highly conjugated, substituted polyacetylenes via the ring-opening metathesis polymerization of substituted cyclooctatetraenes† (1989) (2)
- Aqueous Ring-Opening Metathesis Polymerizations of 7-Oxanorbornene Derivatives Using Ruthenium Catalysts (1990) (2)
- Applications in Organic Synthesis (2021) (2)
- Correction to "Consequences of Grafting Density on Linear Viscoelastic Behavior of Graft Polymers". (2018) (2)
- Ring-Opening Metathesis Polymerization of Substituted Bicyclo(2.2.2) octadienes: A New Precursor Route to Poly(1,4-phenylenevinylene). (1993) (2)
- Ruthenium‐Catalyzed Polycyclization Reactions. (1998) (2)
- Jim Feast: a career in polymer science (2005) (2)
- Synthesis of Substituted Bicyclo[2.2.2]octatrienes. (1998) (2)
- Olefin Metathesis and Related Reactions in Organic Synthesis: Introduction to Metal‐Carbon Double Bonds in Organic Synthesis (2008) (2)
- Titanacyclobutanes Derived from Strained Cyclic Olefins: The Living Polymerization of Norbornene. (1986) (2)
- New catalysts for olefin metathesis (2001) (2)
- Mechanistic studies of olefin metathesis (1979) (1)
- Frontier Areas between Homogeneous and Heterogeneous Catalysts (1977) (1)
- Synthesis of α,β‐Unsaturated Amides by Olefin Cross‐Metathesis. (2001) (1)
- Imaging Novel Ruthenium bipyridine-based Nanophotoswitches in Retina (2015) (1)
- MECHANISM OF THE FLUXIONAL BEHAVIOR IN (1-5-η-CYCLOHEPTADIENYL)(1-5-η-CYCLOHEPTATRIENYL)IRON (1978) (1)
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- Simple Method for Hyperbranched Polymers (2008) (0)
- Synthesis and self-assembly of brush block polymers with low T_g side chains (2017) (0)
- Self-Assembly of Narrowly Dispersed Brush Diblock Copolymers with Domain Spacing more than 100 nm (2012) (0)
- Improving Post-Operative Positioning Compliance: A Novel Device (2016) (0)
- Z-to-E isomerization processes in reactions catalyzed by cyclometalated ruthenium alkylidenes (2015) (0)
- Biodegradable polymer scaffolds for stem-cell based treatment of age-related macular degeneration (2012) (0)
- Initiator control of the tacticity of ROMP polymers (2013) (0)
- Functionalizing iron oxide with genomic DNA: Materials for drug capture (2017) (0)
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- In Situ X ray scattering for investing morphology of bottle brush BCP with Solvent annealing (2014) (0)
- Synthesis and self-assembly of graft polymers with variable grafting density (2017) (0)
- Polynorbornene-polyethylene glycol based polymers as electrolyte materials for rechargeable lithium batteries (2012) (0)
- ynthesis of macrocyclic peptides via a dual ole fi n metathesis and ethenolysis approach † (2015) (0)
- The Royal Society of Con fi ned organization of fullerene units along high polymer chains † (2013) (0)
- Model compounds for olefin metathesis intermediates: Synthesis and characterization of ruthenium-olefin complexes (2006) (0)
- Front Matter, Volume 3: Polymer Synthesis (2015) (0)
- Viscoelastic Properties of Metathesis Synthesized Linear and Cyclic Macromolecules (2006) (0)
- Z-Selective Ruthenium-CatalyzedOlefin Cross Metathesis (2011) (0)
- Tandem metathesis- dihydroxylation and metathesis- oxidative cyclization reactions (2016) (0)
- Synthesis of Highly Cis , Syndiotactic ROMP Polymers Using Ruthenium Metathesis Catalysts (2013) (0)
- Design and synthesis of new ruthenium-based catalysts for improved activity in challenging Z-selective metathesis reactions (2013) (0)
- Materials for drug capture: An approach for removing off-target chemotherapy from the bloodstream (2017) (0)
- POLYMER-SUPPORTED METALLOCENES AND THEIR APPLICATIONS TO THE CATALYSIS OF OLEFIN ISOMERIZATION, OLIGOMERIZATION, EPOXIDATION, AND DINITROGEN FIXATION REACTIONS (1981) (0)
- Silylation of C—H Bonds in Aromatic Heterocycles by an Earth‐Abundant Metal Catalyst. (2015) (0)
- Ruthenium-based olefin metathesis catalysts bearing new N-heterocyclic carbenes (2005) (0)
- Genomic DNA functionalized architected materials fabricated via two-photon lithography for drug capture (2017) (0)
- Functionalized Corroles as Theranostics for Prostate Cancer (2014) (0)
- Back Cover: Solar cell efficiency enhancement via light trapping in printable resonant dielectric nanosphere arrays (Phys. Status Solidi A 2/2013) (2013) (0)
- Heterogeneous Catalysis and Characterization of Catalyst Surfaces (2018) (0)
- Z-selective ethenolysis using a ruthenium catalyst: Applications and mechanisticimplications (2013) (0)
- Methathesesynthese of pheromones or their ingredients (2000) (0)
- Transport spectroscopy and modeling of a clean MOS point contact tunnel barrier (2014) (0)
- Consequences of low-χ block copolymer design (2016) (0)
- The linear rheological responses of cyclic polyoctenamer melt (2008) (0)
- Ru-Based Metathesis Catalysts Yield Highly cis, Syndiotactic Polymers (2013) (0)
- POST-SYNTHETIC FUNCTIONALIZATION OF HYPERBRANCHED POLYMERS PREPARED BY OLEFIN METATHESIS (2008) (0)
- EPR study of nitroxide-labeled brush polymers (2013) (0)
- Self-Assembly of brush block copolymer photonic crystals featuring low T_g side chains (2017) (0)
- Hybrid bilayer organic light-emitting devices based on high Tg hole transport polymers (1999) (0)
- REACTIONS OF NICKEL-CARBENE COMPLEXES GENERATED FROM NICKELACYCLE COMPLEXES (1981) (0)
- Synthesis and self-assembly of brush block copolymers with various grafting densities (2017) (0)
- Self-assembly of brush block copolymers to nanostructured materials (2016) (0)
- Molecular Weight Dependence of the Viscosity of Polyethylene Macrocycles (2005) (0)
- POLYMER‐SUPPORTED ORGANOMETALLIC COMPOUNDS OF TITANIUM, ZIRCONIUM AND HAFNIUM AS HYDROGENATION CATALYSTS (1977) (0)
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- Polyisobutylene (PIB)-NHC Supported Catalysts for Cross-Coupling Reactions: A Green and Sustainable Protocol (2016) (0)
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- Design of selective catalysts for olefin metathesis (2013) (0)
- Strained Ring Energetic Binders (1993) (0)
- Consequences of Grafting Density on Bottlebrush Rheology (2018) (0)
- Ruthenium catalyzed synthesis of functionalized polypentenamers (2014) (0)
- Selective formation of olefins using olefin metathesis (2014) (0)
- ntion for the synthesis of E-macrocycles with ruthenium-based ole fi n metathesis catalysts † (2018) (0)
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- Synthesis and Reactivity of Backfluorinated NHC Carbene Complexes (Briefing Charts) (2015) (0)
- Metalcarbenmetatesekatalysatorer high activity, which is obtained by the use of a thermally activated N-heterocyclic carbenforstadium (2002) (0)
- CHEMICAL SYNTHESIS WITH METAL ATOMS- THE REACTION OF 1,4- AND 1,3-CYCLOHEXADIENE WITH CHROMIUM ATOMS AND TRIFLUOROPHOSPHINE (1977) (0)
- Dynamic Mechanical Behavior of Second-Generation Dendronized Wedge-Type Polymer (2018) (0)
- Treatment of myopia (1984) (0)
- Die Darstellung und Selektivität eines Olefinhydrierungskatalysators, der Rh(I) an Polymeres gebunden enthält (1975) (0)
- Titanium and zirconium complexes of chelating N-heterocyclic carbenes as polymerization catalysts (2014) (0)
- Scalable and continuous access to pure cyclic polymers enabled by ‘quarantined’ heterogeneous catalysts (2021) (0)
- AKTIVIERUNG HOMOGENER KATALYSATOREN DURCH POLYMER-BINDUNG (1973) (0)
- KATALYTISCHE RED. VON OLEFINEN AN EINEM RHODIUM(I)-KATALYSATOR AUF EINEM POLYMEREN TRAEGER (1971) (0)
- Silylation of Aromatic Heterocycles with Potassium tert-Butoxide Catalyst (2015) (0)
- Kreuz-metathese von funktionalisierten und substituierten olefinen unter einsatz von gruppe 8 übergangsmetall-carben-komplexe als methatese-katalysatoren (2002) (0)
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